{"id":38378,"date":"2016-09-11T14:00:50","date_gmt":"2016-09-11T06:00:50","guid":{"rendered":"\/\/m.iemloyee.com\/?p=38378"},"modified":"2016-09-11T14:36:10","modified_gmt":"2016-09-11T06:36:10","slug":"nano-letter%ef%bc%9a%e9%87%91%e5%b1%9e%e7%ba%b3%e7%b1%b3%e7%b2%92%e5%ad%90%e5%9c%a8%e9%92%99%e9%92%9b%e7%9f%bf%e5%9f%ba%e4%bd%93%e4%b8%8a%e7%9a%84%e5%8e%9f%e4%bd%8d%e6%9e%90%e5%87%ba","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=38378","title":{"rendered":"Nano Lett. : \u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u5728\u9499\u949b\u77ff\u57fa\u4f53\u4e0a\u7684\u539f\u4f4d\u6790\u51fa"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60\uff08solid oxide fuel cell\uff0cSOFC\uff09\u7684\u9633\u6781\u6750\u6599\u5e94\u5177\u6709\uff1a1\uff09\u591a\u5b54\u6027\u3002\u5141\u8bb8\u53cd\u5e94\u6c14\u4f53\u6269\u6563\u5230\u4e09\u76f8\u754c\u9762\uff0c\u5e76\u589e\u5927\u50ac\u5316\u53cd\u5e94\u8868\u9762\uff1b2) \u9ad8\u7684\u7535\u5b50\u5bfc\u7535\u6027\uff1b3) \u4e0eY2<\/sub>O3<\/sub>\u7a33\u5b9a\u7684\u6c27\u5316\u9506\uff08YSZ\uff09\u6709\u9ad8\u5ea6\u7684\u5316\u5b66\u548c\u70ed\u76f8\u5bb9\u6027\u4ee5\u53ca\u76f8\u8fd1\u7684\u70ed\u81a8\u80c0\u7cfb\u6570\u3002\u9499\u949b\u77ff\u578b\u6750\u6599\u7ed3\u6784\u7279\u6b8a\uff0c\u5316\u5b66\u7a33\u5b9a\u6027\u597d\uff0c\u662f\u7406\u60f3\u7684\u7535\u6781\u6750\u6599\u3002\u5176\u8868\u9762\u539f\u4f4d\u6790\u51fa\u7684\u91d1\u5c5e\u7c92\u5b50\uff0c\u6210\u4e3a\u589e\u5f3a\u50ac\u5316\u6d3b\u6027\u7684\u79d8\u5bc6\u6b66\u5668\u3002<\/p>\n

\u65b0\u80fd\u6e90\u5b66\u4e60\u5c0f\u7ec4\uff08pamperhey \u30101<\/a>\u3011\uff09\u8fd1\u671f\u62a5\u9053\u4e86\u5317\u4eac\u79d1\u6280\u5927\u5b66\u8d75\u6d77\u96f7\u6559\u6388\u8bfe\u9898\u7ec4\u5173\u4e8e\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60\u7684\u6700\u65b0\u6210\u679c\u2014\u2014\u539f\u4f4d\u6790\u51faFeNi\u5408\u91d1\u7684\u9499\u949b\u77ff\u6750\u6599\u30102<\/a>\u3011\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u5177\u6709\u9ad8\u50ac\u5316\u6d3b\u6027\u7684\u9499\u949b\u77ff\u578b\u6750\u6599\u662f\u7531\u4e8e\u5176\u8868\u9762\u8131\u6eb6\u7684\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\uff0c\u4f46\u8fd9\u5176\u4e2d\u7684\u673a\u7406\u5e76\u672a\u83b7\u5f97\u6e05\u6670\u7684\u8ba4\u8bc6\u3002\u65e5\u524d\u53d1\u8868\u5728Nano Letter\u7684\u6587\u7ae0\u501f\u52a9\u539f\u4f4d\u73af\u5883\u900f\u5c04\u7535\u955c\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u63ed\u5f00\u4e86\u6790\u51fa\u7684\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\uff0c\u5728\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60\uff08SOFC\uff09\u9633\u6781\u50ac\u5316\u6c27\u5316\u548c\u56fa\u4f53\u6c27\u5316\u7269\u9ad8\u6e29CO2<\/sub>\u7535\u89e3\uff08SOEC\uff09\u7684\u9886\u57df\u589e\u52a0\u50ac\u5316\u7684\u795e\u79d8\u9762\u7eb1\u3002\u8be5\u6587\u7ae0\u7531\u53a6\u95e8\u5927\u5b66\u674e\u5efa\u8f89\u8bfe\u9898\u7ec4\u3001\u52a0\u62ff\u5927\u963f\u5c14\u4f2f\u5854\u5927\u5b66Bin Hua\u548cJing-Li Luo\u8054\u5408\u53d1\u8868\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe1 10% H2<\/sub>\u2212N2<\/sub>\u6c14\u6c1b\u4e2d\u7684PBMCo\u70ed\u91cd\u5206\u6790\u3002<\/strong><\/p>\n

<\/p>\n

\u7814\u7a76\u4eba\u5458\u4ee5Co\u63ba\u6742 Pr0.5<\/sub>Ba0.5<\/sub>MnOx<\/sub>\u4e3a\u7814\u7a76\u5bf9\u8c61\uff0c\u5728\u6c22\u6c14\u6c2e\u6c14\u6df7\u5408\u6c14\u6c1b\u4e0b\uff0c\u901a\u8fc7\u70ed\u91cd\u5206\u6790\uff0c\u5f97\u51fa\u4e86\u8be5\u6750\u6599\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\uff0c\u76f8\u5173\u7684\u6676\u578b\u8f6c\u53d8<\/p>\n

\u6587\u7ae0\u4e2d\u8ba4\u4e3a\u5728\u7a0b\u5e8f\u5347\u6e29\u8fd8\u539f\u6c14\u6c1b\u4e2d\uff0cCo\u7b49\u8fc7\u6e21\u91d1\u5c5e\u63ba\u6742\u7684Pr0.5<\/sub>Ba0.5<\/sub>MnOx-\u03b4<\/sub>\u9499\u949b\u77ff\u6c27\u5316\u7269\u4ea7\u751f\u6676\u683c\u91cd\u6784\uff0c\u7acb\u65b9\u76f8\u5411\u659c\u65b9\u76f8\u8f6c\u53d8\uff0c\u5e76\u5f62\u6210\u5c42\u72b6\u7ed3\u6784\u3002\u540c\u65f6\uff0c\u6676\u683c\u4e2d\u6c27\u7531\u4e8e\u76f8\u53d8\u5927\u91cf\u7f3a\u5931\uff0c\u5f62\u6210\u6709\u5e8f\u7684\u6c27\u7a7a\u7a74\u3002<\/p>\n

\u56fe2 \u539f\u4f4d\u900f\u5c04\u56fe\u7247\u3002<\/strong><\/p>\n

<\/p>\n

\u56fe\u7247\u6e05\u6670\u53cd\u6620\u51fa\u968f\u7740\u6e29\u5ea6\u53d8\u5316\uff0c\u8868\u9762\u7684Co\u7eb3\u7c73\u7c92\u5b50\u6790\u51fa\uff0c\u65f6\u95f4\u4ece0\u79d2\u5f00\u59cb\uff0c\u6301\u7eed\u7ea68\u5206\u949f\u3002<\/p>\n

a-c\u4e0d\u540c\u6e29\u5ea6\u65f6\u7684\u900f\u5c04\u56fe\u7247\uff1bd-f\u4e0d\u540c\u65f6\u95f4\u65f6\u7684\u900f\u5c04\u56fe\u7247\u3002<\/p>\n

\u56fe3\u00a0\u6676\u578b\u8f6c\u53d8\u6d3b\u5316\u80fd\u7406\u8bba\u8ba1\u7b97\u3002<\/strong><\/p>\n

\u56fe3\u662f\u6676\u578b\u8f6c\u53d8\u65f6\uff0c\u7406\u8bba\u8ba1\u7b97\u5f97\u51fa\u7684\u4e0d\u540c\u9636\u6bb5\u7684\u6d3b\u5316\u80fd\uff0c\u5bf9\u5e94\u6676\u683c\u91cd\u6784\u7684\u4e24\u4e2a\u4e0d\u540c\u6676\u578b\u3002\u8ba1\u7b97\u8868\u660e\uff0c\u6676\u578b\u53d8\u6362\u65f6\u6c27\u7a7a\u7a74\u7684\u5f62\u6210\u964d\u4f4e\u4e86Co2+<\/sup>\u79bb\u5b50\u7684\u6c27\u79bb\u5b50\u914d\u4f4d\u6570\uff0c\u8fdb\u800c\u660e\u663e\u964d\u4f4e\u4e86\u5176\u8fd8\u539f\u4e3a\u91d1\u5c5eCo\u7684\u6d3b\u5316\u80fd\u3002<\/p>\n

\u56fe<\/strong>4<\/strong> \u7535\u5b66\u6027\u80fd\u6d4b\u8bd5\u7ed3\u679c\u3002<\/strong><\/p>\n

<\/p>\n

a:\u5728\u4e59\u70f7\u548c\u5408\u6210\u6c14\uff08C2<\/sub>H6<\/sub>\u548csyngas fuels\uff09\u6761\u4ef6\u4e0b\u6d4b\u8bd5\uff0c\u7535\u538b\u4ee5\u53ca\u529f\u7387\u5bc6\u5ea6\u548c\u7535\u6d41\u5bc6\u5ea6\u7684\u66f2\u7ebf\u56fe\u3002<\/p>\n

b:\u5728800\u00b0C-900\u00b0C\u4e0b\u4e8c\u6c27\u5316\u78b3\u7535\u89e3\u8fc7\u7a0b\u4e2d\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\u56fe4a\u663e\u793a900\u2103\u65f6\u529f\u7387\u5bc6\u5ea6\u4e5f\u8fbe900 mW cm\u22122<\/sup>\u3002\u540c\u65f6\uff0c\u56fe4b\u770b\u51fa\uff0c\u7531\u4e8e\u6709\u5e8f\u7684\u6c27\u7a7a\u7a74\u63d0\u4f9b\u4e86\u5feb\u7684\u6c27\u79bb\u5b50\u8fc1\u79fb\u7387\uff0c\u4ee5\u53ca\u5927\u91cf\u7684\u6c27\u7a7a\u4f4d\uff0c \u5728\u7535\u538b\u7b49\u4e8e1.5 V\u65f6\uff0cCO2<\/sub>\u7535\u89e3\u7535\u6d41\u5bc6\u5ea6\u5206\u522b\u662f2.5\uff08900\u2103\uff09\uff0c1.6\uff08850\u2103\uff09\u548c0.85\uff08800\u2103\uff09A cm\u22122<\/sup>\u3002\u8868\u9762\u7684Co\u7eb3\u7c73\u7c92\u5b50\u4fc3\u8fdb\u4e86\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u7535\u5b50\u8f6c\u79fb\u3002<\/p>\n

\u3010\u5c55\u671b\u3011<\/strong><\/span><\/p>\n

\u8fd9\u7bc7\u6587\u7ae0\u501f\u52a9\u539f\u4f4d\u73af\u5883\u900f\u5c04\u7535\u955c\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u63ed\u793a\u4e86\u9ad8\u6d3b\u6027\u7eb3\u7c73\u91d1\u5c5e\u7c92\u5b50\u7684\u5728\u5c42\u72b6\u9499\u949b\u77ff\u578b\u6c27\u5316\u7269\u4e0a\u539f\u4f4d\u6790\u51fa\u7684\u673a\u7406\u3002\u8868\u9762\u6790\u51fa\u7684\u7eb3\u7c73\u7c92\u5b50\u548c\u5f62\u53d8\u4ea7\u751f\u7684\u6c27\u7a7a\u4f4d\u65e2\u589e\u5f3a\u4e86\u7535\u5b50\u8f6c\u79fb\u53c8\u662f\u63d0\u9ad8\u4e86\u50ac\u5316\u6d3b\u6027\uff0c\u5236\u5907\u8be5\u9499\u949b\u77ff\u578b\u6750\u6599\u5728SOFC\u9633\u6781\u50ac\u5316\u6c27\u5316\u548cSOEC\u9634\u6781\u8fd8\u539f\u7b49\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u8be5\u5de5\u4f5c\u89e3\u91ca\u4e86\u5168\u65b0\u89c6\u89d2\u4e0b\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u5927\u91cf\u539f\u4f4d\u6790\u51fa\u7684\u673a\u7406\uff0c\u4e3a\u7814\u7a76CO2<\/sub>\u7684\u7535\u89e3\u8fd8\u539f\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7684\u65b9\u5411\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>New Opportunity for in Situ Exsolution of Metallic Nanoparticles on Perovskite Parent<\/a>\uff08Nano Lett., 2016, DOI: 10.1021\/acs.nanolett.6b02757\uff09<\/p>\n

\u76f8\u5173\u6587\u7ae0\u94fe\u63a5\uff1a<\/strong><\/p>\n

1. \u00a0ACS Nano\uff1a\u9499\u949b\u77ff\u5728\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60\u821e\u53f0\u4e0a\u7684\u8de8\u754c\u660e\u661f\u8868\u6f14\u8d5b<\/a>\u00a0\uff08\u6750\u6599\u725b\u5bfc\u8bfb\u6587\u7ae0\uff0c2016.\uff09<\/p>\n

2.\u00a0High-Performance Anode Material Sr2FeMo0.65Ni0.35O6\u2212\u03b4 with In Situ Exsolved Nanoparticle Catalyst. <\/a>\uff08ACS Nano\uff0c<\/em>2016\uff0cDOI: 10.1021\/acsnano.6b03979\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 pamperhey \u4f9b\u7a3f\uff0c\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u52a0\u5165\u6211\u4eec\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\uff0c\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002\"new<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60\uff08solid oxide fuel cell\uff0cSOFC\uff09\u7684\u9633\u6781\u6750\u6599\u5e94\u5177\u6709\uff1a1\uff09\u591a\u5b54\u6027\u3002\u5141\u8bb8\u53cd\u5e94\u6c14\u4f53\u6269\u6563\u5230\u4e09\u76f8\u754c\u9762\uff0c\u5e76\u589e\u5927\u50ac\u5316\u53cd\u5e94\u8868\u9762…<\/p>\n","protected":false},"author":1311,"featured_media":38383,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[244],"class_list":["post-38378","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-gaitaikuang"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/38378"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1311"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=38378"}],"version-history":[{"count":19,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/38378\/revisions"}],"predecessor-version":[{"id":40135,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/38378\/revisions\/40135"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/38383"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=38378"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=38378"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=38378"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}