{"id":37331,"date":"2016-08-31T08:00:25","date_gmt":"2016-08-31T00:00:25","guid":{"rendered":"\/\/m.iemloyee.com\/?p=37331"},"modified":"2017-03-18T21:56:40","modified_gmt":"2017-03-18T13:56:40","slug":"jacs%ef%bc%9a%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e9%aa%a8%e6%9e%b6%e5%8c%96%e5%90%88%e7%89%a9mofs%e5%8f%98%e5%bd%a2%e8%ae%b0-%e4%bb%8e%e6%b6%b2%e4%bd%93%e5%88%b0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=37331","title":{"rendered":"JACS\uff1a\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5316\u5408\u7269(MOFs)\u201c\u53d8\u5f62\u8bb0\u201d\u2014\u2014\u4ece\u6db2\u4f53\u5230\u56fa\u4f53\u518d\u5230\u6ce1\u6cab\u7684\u8f6c\u53d8"},"content":{"rendered":"

\u3010\u5f15\u8bed\u3011<\/strong><\/p>\n

2016\u5e748\u670811\u65e5\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u5316\u5b66\u5b66\u9662\u7684\u738b\u535a\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u5728\u671f\u520aJACS\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cShaping of metal-organic frameworks: from\u00a0fluid to shaped bodies and robust foams\u201d\u7684\u5b66\u672f\u8bba\u6587\uff0c\u62a5\u5bfc\u4e86\u5173\u4e8e\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5316\u5408\u7269(MOFs)\u6ce1\u6cab\u5236\u5907\u4ee5\u53ca\u5176\u6027\u80fd\u7684\u4ecb\u7ecd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

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\u7136\u800c\uff0c\u79d1\u5b66\u5bb6\u4eec\u53d1\u73b0\u8fde\u7eed\u76f8\u8f6c\u53d8\u52a0\u5de5\u65b9\u6cd5\u53ef\u4ee5\u628aMOFs\u52a0\u5de5\u4e3a\u53ef\u52a0\u5de5\u6d41\u4f53\u3001\u6709\u5f62\u56fa\u4f53\u751a\u81f3\u662f\u5728\u8fd9\u4e9b\u76f8\u4e2d\u53ef\u4ee5\u53d1\u751f\u53ef\u9006\u6539\u53d8\u7684MOF\u6ce1\u6cab\u3002\u57fa\u4e8e\u8fd9\u79cd\u65b9\u6cd5\uff0c\u7814\u7a76\u8005\u4eec\u7814\u5236\u51fa\u4e86\u676f\u72b6\u7684Cu-MOF\u590d\u5408\u6750\u6599\u548c\u5206\u5c42\u591a\u5b54MOF\u6ce1\u6cab\uff0c\u4ece\u800c\u5b9e\u73b0\u9ad8\u6548C-H\u952e\u6c27\u5316\u50ac\u5316\u3002<\/p>\n

\u901a\u8fc7\u8fd9\u79cd\u65b9\u6cd5\u53ef\u4ee5\u5f97\u5230\u5404\u79cd\u4f4e\u5bc6\u5ea6(<0.1 gcm-3)\u3001\u9ad8\u8d1f\u8f7d(80 wt%)\u7684MOF\u6ce1\u6cab\u3002\u7531\u4e8e\u5177\u6709\u5206\u5c42\u591a\u5b54\u7ed3\u6784\uff0c\u8fd9\u4e9bMOF\u6ce1\u6cab\u5448\u73b0\u51fa\u4f4e\u80fd\u91cf\u635f\u8017\u7684\u7279\u70b9\uff0c\u5177\u6709\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u548cC-H\u952e\u6c27\u5316\u50ac\u5316\u6027\u80fd\uff0c\u5f88\u6709\u6f5c\u529b\u5e94\u7528\u4e8e\u8584\u819c\u53cd\u5e94\u5668\u4e2d\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\uff1aMOF@Fe3O4\u7684\u5236\u5907\u8fc7\u7a0b\u548c\u76f8\u8f6c\u53d8\u5e94\u7528\u56fe\u89e3\u4ee5\u53ca\u7528\u8fd9\u79cd\u65b9\u6cd5\u7814\u5236\u7684\u5176\u4ed6\u6ce1\u6cab\u6210\u54c1\u793a\u610f\u56fe<\/strong><\/p>\n

\"\u56fe\u72471\"<\/p>\n

(a)\u4e3aHKUST-1@Fe3O4-MF\u7684\u5236\u5907\u8fc7\u7a0b\u56fe\u89e3\u548c\u8be5\u78c1\u6027\u6db2\u4f53\u7684\u4e00\u4e9b\u5e94\u7528\u3002\u56fe\u4e2d\u4e0a\u534a\u90e8\u5206\u662fMOF@Fe3O4\u7684\u5236\u5907\u8fc7\u7a0b\uff0c\u56fe\u4e2d\u7ea2\u8272\u5c0f\u7403\u4ee3\u8868\u7fa7\u57fa-COOH\uff0c\u7eff\u8272\u5c0f\u7403\u4ee3\u8868Cu2+\u79bb\u5b50\uff0c\u7d2b\u8272\u5c0f\u7403\u4ee3\u8868MOF@Fe3O4\u3002<\/p>\n

(b)\u4e3a\u7528\u8fd9\u79cd\u65b9\u6cd5\u5236\u9020\u51fa\u7684\u5176\u4ed6\u6ce1\u6cab\u6210\u54c1\u793a\u610f\u56fe\u3002<\/p>\n

[\u6ce8\uff1a<\/strong>BTC\uff1a\u5747\u82ef\u4e09\u7532\u9178\u3002 \u00a0CMC\uff1aCarboxymethyl Cellulose\uff0c\u5373\u7fa7\u7532\u57fa\u7ea4\u7ef4\u7d20\uff0c\u522b\u79f0E466\u3002]<\/p>\n

\u56fe2\uff1aHKUST-1@Fe3O4-MF\u5177\u6709\u4f18\u5f02\u6027\u80fd\u7684\u6837\u54c1\u5b9e\u9a8c\u4ee5\u53caC-H\u6c27\u5316\u50ac\u5316\u53cd\u5e94\u5668\u7684\u56fe\u89e3\u548c\u50ac\u5316\u6027\u80fd\u5206\u6790<\/strong><\/p>\n

\"\u56fe\u72472\"<\/p>\n

(a)\uff1aHKUST-1@Fe3O4-MF\u7684\u53cd\u76f8\u8f6c\u53d8\u56fe\u793a\u3002\u5728\u78c1\u6027\u6db2\u4f53\u4e2d\u52a0\u5165CH3CN\u53d8\u4e3a\u90c1\u91d1\u9999\u5f62\u72b6\u7684\u56fa\u4f53\uff0c\u7ee7\u800c\u52a0\u6c34\u540e\u6062\u590d\u6db2\u4f53\u5f62\u72b6\uff0c\u518d\u52a0\u5165CH3CN\u653e\u5165\u4e94\u89d2\u661f\u6a21\u5177\u53c8\u53d8\u4e3a\u53e6\u4e00\u5f62\u72b6\u7684\u56fa\u4f53\uff1b<\/p>\n

(b)\uff1aHKUST-1@Fe3O4-gel\u4f18\u5f02\u53ef\u6062\u590d\u6027\u80fd\u5b9e\u9a8c\u5c55\u793a\u3002\u56db\u7247HKUST-1@Fe3O4-gel\u7528\u78c1\u94c1\u53ef\u4ee5\u57285\u5206\u949f\u540e\u53c8\u6062\u590d\u5728\u4e00\u8d77\uff1b<\/p>\n

(c)\uff1a\u901a\u8fc7\u6eb6\u5242\u5f15\u53d1\u65b9\u6cd5\u5236\u5907\u7684\u676f\u72b6\u53cd\u5e94\u5668\uff1b \u00a0(d)\uff1a\u676f\u72b6\u53cd\u5e94\u5668\u5185\u8868\u9762\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(e)\uff1aC-H\u952e\u6c27\u5316\u50ac\u5316\u53cd\u5e94\u5668\u7684\u56fe\u50cf\u5c55\u793a\uff1b \u00a0 \u00a0 \u00a0 (f)\uff1a\u676f\u72b6\u53cd\u5e94\u5668\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

\u56fe3\uff1aHKUST-1@Fe3O4\u6ce1\u6cab\u7684\u5404\u79cd\u673a\u68b0\u6027\u80fd\u5b9e\u9a8c\u3001\u548cHKUST-1\u7247\u52a8\u529b\u50ac\u5316\u6027\u80fd\u7684\u6bd4\u8f83\u4ee5\u53ca\u6ce1\u6cab\u7684\u53ef\u56de\u6536\u6027\u80fd\u67f1\u72b6\u56fe<\/strong><\/p>\n

\"\u56fe\u72473\"<\/p>\n

(a)\uff1aHKUST-1@Fe3O4\u6ce1\u6cab\u7684\u6297\u538b\u5b9e\u9a8c\uff1b<\/p>\n

(b)\uff1aHKUST-1@Fe3O4\u6ce1\u6cab\u88ab\u7528\u5200\u5207\u6210\u8584\u7247\uff0c\u5c0f\u63d2\u56fe\u5c55\u793a\u4e86\u5c0f\u8584\u7247\u7684\u6297\u5f2f\u6027\u80fd\uff1b<\/p>\n

(c)\uff1a\u80f6\u5e26\u5b9e\u9a8c\u4e4b\u540e\u80f6\u5e26\u7684\u8868\u9762\u56fe\u793a\uff1b<\/p>\n

(d)\uff1aHKUST-1@Fe3O4\u6ce1\u6cab\u7684\u673a\u68b0\u7a33\u5b9a\u6027\u5b9e\u9a8c\uff1b<\/p>\n

(e)\uff1aHKUST-1@Fe3O4\u6ce1\u6cab\u548cHKUST-1\u7247\u52a8\u529b\u50ac\u5316\u6027\u80fd\u7684\u6bd4\u8f83\uff0c\u6a2a\u5750\u6807\u4e3a\u65f6\u95f4\uff0c\u7eb5\u5750\u6807\u4e3a\u8f6c\u5316\u7387\uff1b<\/p>\n

(f)\uff1aHKUST-1@Fe3O4\u6ce1\u6cab\u7684\u518d\u751f\u6027\u80fd\u3002<\/p>\n

\u56fe4\uff1a\u516d\u79cd\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5316\u5408\u7269\u7684\u539f\u5b50\u7c07\u3001\u6709\u673a\u94fe\u3001\u62d3\u6251\u7ed3\u6784\u3001\u6ce1\u6cab\u6837\u54c1\u4ee5\u53ca\u6837\u54c1\u7684\u626b\u63cf\u7535\u955c\u56fe\u7247<\/strong><\/p>\n

\"\u56fe\u72474\"<\/p>\n

(a)~(f)\u5206\u522b\u8868\u793aHKUST-1@CMC\u3001ZIF-8@CMC\u3001Mg-MOF-74\u3001Zn-MOF-74\u3001UIO-66\u3001NH2-UIO-66\u516d\u79cd\u6ce1\u6cab\uff1b<\/p>\n

\u56fe(\u2170)\u8868\u793a\u516d\u79cd\u6ce1\u6cab\u7684\u91d1\u5c5e\u539f\u5b50\u7c07\uff1b\u56fe(\u2171)\u8868\u793a\u516d\u79cd\u6ce1\u6cab\u7684\u6709\u673a\u94fe\uff1b<\/p>\n

\u56fe(\u2172)\u8868\u793a\u516d\u79cd\u6ce1\u6cab\u7684\u62d3\u6251\u7ed3\u6784\uff1b \u56fe(\u2173)\u4e3a\u516d\u79cd\u6ce1\u6cab\u7684\u6837\u54c1\uff1b<\/p>\n

\u56fe(\u2174)\u548c\u56fe(\u2175)\u4e3a\u516d\u79cd\u6ce1\u6cab\u6837\u54c1\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf\uff0c\u56fe(\u2174)\u4e2d\u4e3a100m\u6bd4\u4f8b\u5c3a\uff0c\u56fe(\u2175)\u4e2d\u4e3a10m\u6bd4\u4f8b\u5c3a\u3002<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u4e2d\uff0c\u7814\u7a76\u8005\u4eec\u901a\u8fc7HKUST-1@Fe3O4\u7eb3\u7c73\u9897\u7c92\u548cCMC\u6df7\u5408\u5f97\u5230\u78c1\u6027\u6db2\u4f53\uff0c\u7ee7\u800c\u8f6c\u53d8\u4e3a\u80f6\u4f53\u3001\u56fa\u4f53\u751a\u81f3\u662f\u6ce1\u6cab\uff0c\u7528\u8fd9\u79cd\u65b9\u6cd5\u5236\u6210\u7684MOF\u6ce1\u6cab\u5177\u6709\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u548cC-H\u952e\u6c27\u5316\u50ac\u5316\u6027\u80fd\u4ee5\u53ca\u4f18\u5f02\u7684\u53ef\u518d\u751f\u6027\u80fd\uff0c\u5728\u53ef\u6062\u590d\u6750\u6599\u9886\u57df\u548c\u8584\u819c\u53cd\u5e94\u5668\u7684\u5e94\u7528\u6781\u5177\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aShaping of metal-organic frameworks: from fluid to shaped bodies and robust foams<\/a>\u00a0\uff08J. Am. Chem. Soc. \uff0c2016\uff0cDOI: <\/strong>10.1021\/jacs.6b06959\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8MOF\u7ec4\u6728\u6728\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u53c2\u4e0eMOF\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3MOF\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09\u3002\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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