{"id":37205,"date":"2016-08-30T08:00:45","date_gmt":"2016-08-30T00:00:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=37205"},"modified":"2016-08-29T21:55:29","modified_gmt":"2016-08-29T13:55:29","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81-angewmacromolecules%e7%ad%89%e9%ab%98%e5%88%86%e5%ad%90%e6%9d%90%e6%96%99%e5%89%8d%e6%b2%bf%e6%9c%80%e6%96%b0%e7%a7%91%e7%a0%94%e6%88%90%e6%9e%9c%e7%b2%be","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=37205","title":{"rendered":"\u9876\u520a\u52a8\u6001 | Angew\/Macromolecules\u7b49\u9ad8\u5206\u5b50\u6750\u6599\u524d\u6cbf\u6700\u65b0\u79d1\u7814\u6210\u679c\u7cbe\u9009\u3010\u7b2c17\u671f\u3011"},"content":{"rendered":"

\u672c\u671f\u7cbe\u9009\u9884\u89c8\uff1a<\/strong>Angew. Chem. Int. Ed. \u5177\u6709\u9ad8\u5ea6\u7acb\u4f53\u9009\u62e9\u6027\u7684\u5b98\u80fd\u5316\u805a\u6742\u73af\uff1bAngew. Chem. Int. Ed. \u901a\u8fc7\u5bbf\u4e3b\u4e0e\u5ba2\u4f53\u4ea4\u4e92\u4f5c\u7528\u4ecb\u5bfc\u53ef\u8c03\u8282\u7eb3\u7c73\u8d85\u5206\u5b50\u805a\u96c6\u4f53\uff1bMacromolecules \u7b80\u5355\u7684\u540e\u805a\u5408\u6539\u6027\u5236\u5907\u591a\u91cd\u54cd\u5e94\u578b\u4e24\u6027\u7ec4\u88c5\u7269\uff1bAngew. Chem. Int. Ed. PCP \u94b3\u5f62\u914d\u4f53\u914d\u4f4d\u805a\u5408\u7269\u9009\u62e9\u6027\u6d3b\u5316CO\u4e2d\u7684CO2\uff1bMacromolecules \u901a\u8fc7\u70ed\u8bf1\u5bfc\u7f29\u805a\u53cd\u5e94\u5f62\u6210\u81ea\u751f\u82b3\u9999\u65cf\u70ed\u56fa\u6027\u805a\u916f\u6cab\uff1bMacromolecules \u53cc\u91cd\u6e29\u5ea6\u654f\u611f\u578b\u4e8c\u5d4c\u6bb5\u5171\u805a\u7269 PSPP430-b-PNIPAM200\u7684\u805a\u5408\u884c\u4e3a\uff1bMacromolecules \u6709\u5173\u6c34\u5408\u5168\u6c1f\u78fa\u9178\u819c\u7ea2\u5916\u5149\u8c31\u7684\u7406\u8bba\u4e0e\u5b9e\u8df5\u7814\u7a76\uff1bMacromolecules \u5e26\u6709\u94fe\u7f3a\u9677\u7684\u805a\uff08\u73af\u6c27\u4e59\u70f7\uff09\u7ed3\u6676\u884c\u4e3a\u3002<\/p>\n

1\u3001Angew. Chem. Int. Ed. \u5177\u6709\u9ad8\u5ea6\u7acb\u4f53\u9009\u62e9\u6027\u7684\u5b98\u80fd\u5316\u805a\u6742\u73af<\/strong><\/p>\n

\"1\"<\/p>\n

\u56fe1<\/strong> \u5177\u6709\u9ad8\u5ea6\u7acb\u4f53\u9009\u62e9\u6027\u7684\u8fde\u7eed\u73af\u5316\u53cd\u5e94<\/p>\n

\u8fde\u7eed\u73af\u5316\u53cd\u5e94\u662f\u5236\u5907\u7ed3\u6784\u53d1\u6563\u591a\u73af\u82b3\u70c3\u7684\u6709\u6548\u65b9\u6cd5\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u79d1\u5b66\u5bb6\u4eec\u81f4\u529b\u4e8e\u53d1\u5c55\u80fd\u591f\u9ad8\u6548\u6784\u5efa\u8fd9\u4e9b\u591a\u73af\u82b3\u70c3\u9aa8\u67b6\u7684\u65b9\u6cd5\uff0c\u5176\u4e2d\u901a\u8fc7\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5206\u5b50\u5185\u7684\u6210\u73af\u53cd\u5e94\u5341\u5206\u9ad8\u6548\uff0c\u7136\u800c\uff0c\u8fd9\u79cd\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u65b9\u6cd5\u4f9d\u8d56\u6602\u8d35\u7684\u914d\u4f53\uff0c\u5e76\u4e14\u53ea\u5bf9\u4e00\u5b9a\u7684\u57fa\u4f53\u6709\u4f5c\u7528\uff0c\u8fd9\u4e25\u91cd\u5730\u9650\u5236\u4e86\u6709\u673a\u7269\u548c\u836f\u7269\u7684\u5408\u6210\u3002\u56e0\u6b64\uff0c\u53d1\u5c55\u4e00\u79cd\u5168\u65b0\u7684\u65b9\u5f0f\u6765\u6784\u5efa\u591a\u73af\u82b3\u70c3\u7cfb\u7edf\u5341\u5206\u5fc5\u8981\u3002<\/p>\n

\u8fd1\u671f\uff0c\u5357\u5f00\u5927\u5b66\u7684\u9ec4\u6709(\u901a\u8baf\u4f5c\u8005)\u7b49\u7814\u7a76\u4eba\u5458\uff0c\u901a\u8fc7\u53cc\u5b98\u80fdN\u9170\u57fa\u81a6\u50ac\u5316\u7cd6\u7cbe\u4e2d\u5206\u79bb\u51fa\u6765\u7684\u03b3\u53d6\u4ee3\u4e19\u4e8c\u70ef\u916f\u548c\u916e\u4e9a\u80fa\uff0c\u4f7f\u4e24\u8005\u8fdb\u884c\u8fde\u7eed\u73af\u5316\u53cd\u5e94\uff0c\u5f97\u5230\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u805a\u6742\u73af\uff0c\u5176\u5177\u6709\u9ad8\u5ea6\u7684\u7acb\u4f53\u9009\u62e9\u6027\u548c\u4ea7\u7387(\u5206\u522b\u8fbe\u523099%\u548c98%)\u3002\u8fd9\u662f\u56fd\u5185\u5916\u9996\u6b21\u62a5\u9053\u4ee5\u975e\u5bf9\u79f0\u5206\u5b50\u6a21\u5f0f\u5408\u6210\u5f97\u5230\u7684\u805a\u6742\u73af\uff0c\u5b83\u5177\u6709\u56db\u4e2a\u8fde\u7eed\u7684\u624b\u6027\u4e2d\u5fc3(1\u4e2a\u56db\u7ea7\u548c3\u4e2a\u4e09\u7ea7\u78b3\u4e2d\u5fc3)\uff0c\u5e76\u4e14\u5728\u6240\u6709\u7684\u5408\u6210\u53cd\u5e94\u4e2d\u53ea\u5f97\u5230\u4e00\u4e2a\u5f02\u6784\u4f53\u3002\u8be5\u7814\u7a76\u56e2\u961f\u8fd1\u671f\u540c\u65f6\u5728\u7814\u7a76\u4e0d\u5bf9\u79f0\u5408\u6210\u5176\u4ed6\u7684\u542b\u6742\u5316\u539f\u5b50\u7684\u805a\u6742\u73af\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Bifunctional-Phosphine-Catalyzed Sequential Annulations of Allenoates and Ketimines: Construction of Functionalized Poly-heterocycle Rings<\/a>\uff08Angew. Chem. Int. Ed., 2016, DOI: 10.1002\/anie.201605189\uff09<\/p>\n

2\u3001Angew. Chem. Int. Ed. \u901a\u8fc7\u5bbf\u4e3b\u4e0e\u5ba2\u4f53\u4ea4\u4e92\u4f5c\u7528\u4ecb\u5bfc\u53ef\u8c03\u8282\u7eb3\u7c73\u8d85\u5206\u5b50\u805a\u96c6\u4f53<\/strong><\/p>\n

\"2\"<\/p>\n

\u56fe2<\/strong> \u5bbf\u4e3b\u548c\u5ba2\u4f53\u6df7\u5408\u7269\u7684\u5316\u5b66\u7ed3\u6784\u53ca\u8d28\u5b50\u5206\u914d<\/p>\n

\u7eb3\u7c73\u8d85\u5206\u5b50\u81ea\u7ec4\u88c5\u56e0\u5177\u6709\u53ef\u63a7\u5f62\u6001\u7684\u7279\u5f81\uff0c\u5728\u6750\u6599\u5236\u9020\u4e2d\u5177\u6709\u521b\u9020\u6027\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n

\u8fd1\u671f\uff0c\u7531\u5357\u5f00\u5927\u5b66\u5218\u80b2(\u901a\u8baf\u4f5c\u8005)\u5e26\u9886\u7684\u7814\u7a76\u56e2\u961f\u901a\u8fc7\u4f7f\u7528\u4e0d\u540c\u6c34\u6eb6\u6027\u5927\u73af\u53d7\u4f53BP-FF\u7edc\u5408\uff0c\u5236\u5907\u4e86\u4e0d\u540c\u5f62\u6001\u7684\u805a\u96c6\u4f53(\u5305\u62ec\u7eb3\u7c73\u68d2\uff0c\u516b\u9762\u4f53\u72b6\u7eb3\u7c73\u7ed3\u6784\uff0c\u7eb3\u7c73\u87ba\u65cb\u7ebf\u548c\u77e9\u5f62\u8584\u7247\u7b49)\u3002\u8fd9\u6574\u4e2a\u5236\u5907\u8fc7\u7a0b\u65e0\u9700\u4efb\u4f55\u7684\u5316\u5b66\u6539\u6027\uff0c\u5e76\u4e14\u5f97\u76ca\u4e8e\u8054\u5421\u5576\u7684\u9ad8\u5ea6\u4eb2\u548c\u6027\uff0c\u8fd9\u79cd\u8d85\u5206\u5b50\u6a21\u5f0f\u80fd\u591f\u6709\u6548\u5730\u6784\u5efa\u4e0d\u540c\u5f62\u8c8c\u7684\u7eb3\u7c73\u7ed3\u6784\uff0c\u53ea\u9700\u8981\u5229\u7528\u7b80\u6613\u7684\u5bbf\u4e3b\u548c\u5ba2\u4f53\u7684\u4ea4\u4e92\u4f5c\u7528\uff0c\u5c31\u53ef\u4ee5\u8fbe\u5230\u65b9\u4fbf\u63a7\u5236\u7684\u76ee\u7684\u3002\u7814\u7a76\u4eba\u5458\u5e0c\u671b\u83b7\u5f97\u7684\u8d85\u5206\u5b50\u805a\u5408\u4f53\u80fd\u591f\u63d0\u4f9b\u4e00\u4e2a\u6d45\u663e\u7684\u6a21\u5757\u5316\u7684\u7b56\u7565\uff0c\u4e3a\u8fdb\u4e00\u6b65\u521b\u9020\u5177\u6709\u65b0\u7684\u529f\u80fd\u7684\u5148\u8fdb\u751f\u7269\u76f8\u5bb9\u6027\u6750\u6599\u6253\u597d\u57fa\u7840\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Tunable Nanosupramolecular Aggregates Mediated by Host\u2013Guest Complexation<\/a>\uff08Angew. Chem. Int. Ed., 2016, DOI: 10.1002\/anie.201605420\uff09<\/p>\n

3\u3001Macromolecules \u7b80\u5355\u7684\u540e\u805a\u5408\u6539\u6027\u5236\u5907\u591a\u91cd\u54cd\u5e94\u578b\u4e24\u6027\u7ec4\u88c5\u7269<\/strong><\/p>\n

\"3\"<\/p>\n

\u56fe3<\/strong> \u901a\u8fc7\u4e8c\u786b\u9187\u4ea4\u6362\u5236\u5907\u591a\u91cd\u54cd\u5e94\u578b\u805a\u5408\u7269<\/p>\n

\u968f\u7740\u5bf9\u591a\u529f\u80fd\u6750\u6599\u7684\u9700\u6c42\u91cf\u4e0d\u65ad\u589e\u52a0\uff0c\u53ef\u7528\u4e8e\u50ac\u5316\u3001\u836f\u7269\u4f20\u9012\u53ca\u4f20\u611f\u7b49\u4f17\u591a\u9886\u57df\u7684\u523a\u6fc0\u54cd\u5e94\u578b\u5206\u5b50\u6216\u805a\u5408\u7269\u88ab\u5927\u91cf\u5236\u5907\u3002<\/p>\n

\u6700\u8fd1\uff0c\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u7684\u90ed\u65ed\u8679\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u5f90\u76ca\u5347\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u4ee5\u53ca\u7f8e\u56fd\u9a6c\u8428\u8bf8\u585e\u5927\u5b66\u963f\u9ed8\u65af\u7279\u5206\u6821\u7684 S.Thayumanavan\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u901a\u8fc7\u786b\u9187-\u4e8c\u786b\u5316\u7269\u4ea4\u6362\u5bf9\u5355\u4e2a\u805a\u5408\u7269\u652f\u67b6\u8fdb\u884c\u6539\u6027\uff0c\u5236\u5907\u4e86\u4e0d\u540c\u7684\u523a\u6fc0\u54cd\u5e94\u578b\u805a\u5408\u7269\u3002\u8be5\u7814\u7a76\u56e2\u961f\u5408\u6210\u4e86\u4e00\u79cd\u65e0\u89c4\u5171\u805a\u7269\uff0c\u53ef\u4ee5\u901a\u8fc7\u4e00\u4e2a\u7b80\u5355\u7684\u540e\u805a\u5408\u6539\u6027\u6b65\u9aa4\u8bbe\u8ba1\u5408\u6210\u4e00\u7cfb\u5217\u53cc\u91cd\u6216\u591a\u91cd\u54cd\u5e94\u7684\u7eb3\u7c73\u7ec4\u88c5\u4f53\u3002\u53cd\u5e94\u5b98\u80fd\u56e2\u4e3a\u4fa7\u94fe\u5355\u5421\u5576\u4e8c\u786b\u5316\u7269\u5355\u5143\uff0c\u5b83\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u80fd\u5feb\u901f\u4e14\u5b9a\u91cf\u5730\u4e0e\u5404\u79cd\u786b\u9187\u53cd\u5e94\u3002\u5df2\u7ecf\u8bc1\u660e\u5176\u5177\u6709\u7269\u7406\u3001\u5316\u5b66\u6216\u751f\u7269\u54cd\u5e94\u7279\u6027\u3002\u8fd9\u4e00\u65b9\u6cd5\u4e5f\u8bb8\u53ef\u4ee5\u7b80\u5316\u5728\u4f17\u591a\u751f\u7269\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u5e94\u7528\u7684\u591a\u529f\u80fd\u805a\u5408\u7269\u7684\u5408\u6210\u8fc7\u7a0b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Multi-Stimuli-Responsive Amphiphilic Assemblies through Simple Postpolymerization Modifications<\/a>\uff08Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b01397\uff09<\/p>\n

4\u3001Angew. Chem. Int. Ed. PCP\u94b3\u5f62\u914d\u4f53\u914d\u4f4d\u805a\u5408\u7269\u9009\u62e9\u6027\u6d3b\u5316CO\u4e2d\u7684CO2<\/strong><\/p>\n

\"4\"<\/p>\n

\u56fe4<\/strong> \u805aPCP\u94b3\u548c\u591a\u5b54PCP\u94b3\u7edc\u5408\u7269<\/p>\n

\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269(PCP)\u548c\u91d1\u5c5e\u6709\u673a\u7269\u6df7\u5408\u6846\u67b6(MOF)\u5e38\u5e38\u88ab\u7528\u6765\u5438\u9644\u9664\u53bb\u6df7\u5408\u7269\u4e2d\u7684\u5c0f\u5206\u5b50\uff0c\u4f8b\u5982N2\uff0cO2\uff0cH2\u548cCO2\u7b49\u3002\u4f46\u662f\u8fd9\u4e00\u7269\u7406\u5438\u9644\u548c\u89e3\u5438\u8fc7\u7a0b\u7684\u5438\u9644\u5bb9\u91cf\u5341\u5206\u6709\u9650\u5e76\u4e14\u5bf9\u6c14\u4f53\u7684\u5438\u9644\u4e0d\u5177\u6709\u9009\u62e9\u6027\u3002<\/p>\n

\u6700\u8fd1\u7f8e\u56fd\u5fb7\u5dde\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u7684\u7814\u7a76\u4eba\u5458Simon M. Humphrey(\u901a\u8baf\u4f5c\u8005)\u7b49\uff0c\u901a\u8fc7PCP\u94b3\u5f62\u914d\u4f53\u5408\u6210\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\u540e\uff0c\u5c06\u91d1\u5c5e\u5316\u7684Pd\u2161Cl\u4e0eCo\u2161\u539f\u5b50\u76f4\u63a5\u53cd\u5e94\uff0c\u5e76\u5728\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u4e0b\u5f62\u6210\u4e86\u7ed3\u6676\u7684\u4e09\u7ef4MOF\uff0c\u5176\u5b54\u6d1e\u4e2d\u7684Pd-CH3\u80fd\u591f\u5728CO2\u8fdb\u5165\u540e\u5c06\u5176\u6d3b\u5316\u5e76\u4e0e\u4e4b\u53cd\u5e94\u5f62\u6210Pd-OC(O)CH3\uff0c\u4ece\u800c\u8fbe\u5230\u9009\u62e9\u6027\u5438\u9644CO2\u5206\u5b50\u7684\u76ee\u7684\u3002\u5fae\u5b54\u6750\u6599\u8fd9\u4e00\u6027\u80fd\u80fd\u591f\u5e2e\u52a9\u50ac\u5316\u672a\u7cbe\u70bc\u7684\u539f\u6cb9\u6df7\u5408\u8bd5\u5242\uff0cMOF\u5728\u5176\u4e2d\u540c\u65f6\u8d77\u5230\u50ac\u5316\u548c\u8fc7\u6ee4\u7684\u4f5c\u7528\uff0c\u53ef\u9632\u6b62\u4ea7\u751f\u4e0d\u5fc5\u8981\u7684\u526f\u53cd\u5e94\u4e0e\u50ac\u5316\u6bd2\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO2 Gas over CO Gas in the Solid State<\/a>\uff08Angew. Chem. Int. Ed., 2016, DOI: 10.1002\/anie.201604730\uff09<\/p>\n

5\u3001Macromolecules \u901a\u8fc7\u70ed\u8bf1\u5bfc\u7f29\u805a\u53cd\u5e94\u5f62\u6210\u81ea\u751f\u82b3\u9999\u65cf\u70ed\u56fa\u6027\u805a\u916f\u6ce1\u6cab<\/strong><\/p>\n

\"5\"<\/p>\n

\u56fe5<\/strong> \u81ea\u751f\u53d1\u6ce1\u5242\u6ce1\u6cab\u7684\u5f62\u6210\u8fc7\u7a0b<\/p>\n

\u70ed\u56fa\u6027\u805a\u916f\u4e00\u822c\u7531\u6eb6\u89e3\u4e8e\u4ea4\u8054\u5355\u4f53\u4e2d\u7684\u4e0d\u9971\u548c\u805a\u916f\u6240\u7ec4\u6210\uff0c\u5e76\u52a0\u5165\u963b\u805a\u5242\u9632\u6b62\u5728\u4f7f\u7528\u524d\u53d1\u751f\u4ea4\u8054\u53cd\u5e94\u3002\u5b83\u7531\u4e8e\u5177\u6709\u521a\u6027\u5f3a\u3001\u56de\u5f39\u6027\u597d\u3001\u67d4\u6027\u597d\u3001\u6297\u8150\u8680\u6027\u5f3a\u7b49\u7279\u70b9\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u8239\u8247\u3001\u6dcb\u6d74\u95f4\u3001\u6587\u4f53\u5668\u6750\u3001\u6c7d\u8f66\u8f66\u4f53\u5916\u90e8\u5236\u4ef6\u3001\u7535\u6c14\u90e8\u4ef6\u3001\u4eea\u5668\u8bbe\u5907\u548c\u6d82\u6599\u7b49\u9886\u57df\u3002<\/p>\n

\u8fd1\u671f\uff0c\u6765\u81ea\u7f8e\u56fd\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66\u4e4c\u5c14\u74e6\u7eb3-\u9999\u69df\u5206\u6821Iwona Jasiuk(\u901a\u8baf\u4f5c\u8005)\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u5236\u5907\u65b0\u578b\u82b3\u9999\u65cf\u70ed\u56fa\u6027\u805a\u916f\u6ce1\u6cab\u7684\u65b9\u6848\uff0c\u5e76\u901a\u8fc7\u4ea4\u8054\u5bc6\u5ea6\u548c\u5206\u5b50\u8d28\u91cf\u7684\u6d4b\u5b9a\u8bc4\u4f30\u4e86\u8be5\u70ed\u56fa\u6027\u805a\u916f\u6ce1\u6cab\u7684\u70ed\u673a\u68b0\u6027\u80fd\u3002\u8be5\u82b3\u9999\u65cf\u70ed\u56fa\u6027\u805a\u916f\u6ce1\u6cab\u7684\u5236\u5907\u4e3a\u6211\u4eec\u63d0\u4f9b\u4e86\u4e00\u4e2a\u72ec\u7279\u7684\u70ed\u56fa\u6027\u805a\u5408\u7269\u5236\u9020\u7cfb\u7edf\uff0c\u8fd9\u4e00\u7cfb\u7edf\u4e3a\u8f7b\u91cf\u5316\u3001\u9ad8\u5f3a\u5ea6\u3001\u826f\u597d\u9ad8\u6e29\u7a33\u5b9a\u6027\u7684\u65b0\u578b\u6750\u6599\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u6280\u672f\u4e0a\u7684\u652f\u6301\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Heat-Induced Polycondensation Reaction with Self-Generated Blowing Agent Forming Aromatic Thermosetting Copolyester Foams<\/a>\uff08Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b00971\uff09<\/p>\n

6\u3001Macromolecules \u53cc\u91cd\u6e29\u5ea6\u654f\u611f\u578b\u4e8c\u5d4c\u6bb5\u5171\u805a\u7269PSPP430-b-PNIPAM200\u7684\u805a\u5408\u884c\u4e3a<\/strong><\/p>\n

\"6\"<\/p>\n

\u56fe6<\/strong> \u6e29\u5ea6\u548c\u7535\u89e3\u8d28\u6d53\u5ea6\u5bf9\u805a\u5408\u7269\u76f8\u53d8\u7684\u5f71\u54cd<\/p>\n

\u6c34\u6eb6\u6027\u6e29\u5ea6\u654f\u611f\u578b\u805a\u5408\u7269\u662f\u523a\u6fc0\u54cd\u5e94\u805a\u5408\u4f53\u7cfb\u7684\u4e00\u4e2a\u5206\u652f\uff08\u4e00\u822c\u88ab\u79f0\u4e3a\u667a\u80fd\u6750\u6599\uff09\uff0c\u5b83\u4eec\u7684\u6027\u80fd\u53ef\u4ee5\u968f\u7740\u6e29\u5ea6\u7684\u53d8\u5316\u800c\u53d8\u5316\u3002\u6b64\u7c7b\u805a\u5408\u7269\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u8272\u8c31\u5206\u6790\u3001\u667a\u80fd\u8868\u9762\u3001\u836f\u7269\u6216\u57fa\u56e0\u4f20\u9012\u4e0e\u7ec4\u7ec7\u5de5\u7a0b\u7b49\u751f\u7269\u533b\u5b66\u9886\u57df\u3002<\/p>\n

\u6700\u8fd1\uff0c\u5fb7\u56fd\u6ce2\u8328\u5766\u5927\u5b66\u7684Andr\u00e9 Laschewsky\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u5fb7\u56fd\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66\u7684Christine M. Papadakis\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u901a\u8fc7\u8fde\u7eed\u53ef\u9006\u52a0\u6210\u805a\u5408\u53cd\u5e94\u5236\u5907\u4e86\u7531\u4e24\u6027\u79bb\u5b50\u578b\u805a\u78fa\u9178\u751c\u83dc\u78b1\uff08PSPP\uff09\u548c\u975e\u79bb\u5b50\u578bN-\u5f02\u4e19\u57fa\u4e19\u70ef\u9170\u80fa\uff08PNIPAM\uff09\u7ec4\u6210\u7684\u53cc\u91cd\u6e29\u5ea6\u654f\u611f\u578b\u4e8c\u5d4c\u6bb5\u5171\u805a\u7269 PSPP430-b-PNIPAM200\u3002\u5728\u6c34\u6eb6\u6db2\u4e2d\uff0c\u76f8\u5e94\u7684\u5747\u805a\u7269PSPP\u548cPNIPAM\u5747\u5177\u6709\u4e0a\u4e34\u754c\u6eb6\u89e3\u6e29\u5ea6\uff08UCST\uff09\u548c\u4e0b\u4e34\u754c\u6eb6\u89e3\u6e29\u5ea6\uff08LCST\uff09\u3002\u8be5\u4e8c\u5d4c\u6bb5\u5171\u805a\u7269\u5728\u6c34\u6eb6\u6db2\u4e2d\u8868\u73b0\u51fa\u70ed\u81f4\u201c\u7cbe\u795e\u5206\u88c2\u578b\u201d\u805a\u5408\u884c\u4e3a\u3002\u6b64\u5916\uff0c\u4e24\u6027PSPP\u5d4c\u6bb5\u7684\u6d4a\u70b9\u5bf9\u79bb\u5b50\u5f3a\u5ea6\u548c\u76d0\u7684\u6027\u8d28\u7684\u79bb\u5b50\u7075\u654f\u5ea6\uff0c\u4e3a\u521b\u5efa\u5bf9\u6e29\u5ea6\u53d8\u5316\u53ca\u7535\u89e3\u8d28\u79cd\u7c7b\u548c\u6d53\u5ea6\u53d8\u5316\u54cd\u5e94\u7684\u53ef\u8f6c\u6362\u7cfb\u7edf\u63d0\u4f9b\u4e86\u53ef\u80fd\u6027\u3002\u901a\u8fc7\u6bd4\u6d4a\u6cd5\u548c\u5c0f\u89d2\u4e2d\u5b50\u6563\u5c04\u5bf9\u91cd\u6c34\u4e2d\u7684\u4e8c\u5d4c\u6bb5\u5171\u805a\u7269\u6eb6\u6db2\u968f\u6e29\u5ea6\u548c\u7535\u89e3\u8d28\u6210\u5206\u7684\u6539\u53d8\u800c\u4ea7\u751f\u7684\u76f8\u53d8\u884c\u4e3a\u548c\u81ea\u7ec4\u88c5\u7ed3\u6784\u8fdb\u884c\u4e86\u6d4b\u5b9a\u3002\u89c2\u5bdf\u5230\u5728\u4e0a\u4e34\u754c\u6eb6\u89e3\u6e29\u5ea6\u548c\u4e0b\u4e34\u754c\u6eb6\u89e3\u6e29\u5ea6\u4e4b\u95f4\u7684\u805a\u5408\u8f6c\u53d8\u5177\u6709\u663e\u8457\u7684\u5dee\u5f02\u3002\u5c11\u91cf\u7684\u6eb4\u5316\u94a0\uff080.004M\uff09\u5e76\u672a\u5f71\u54cd\u6574\u4f53\u7684\u884c\u4e3a\uff0c\u53ea\u662fUCST\u578b\u8f6c\u53d8\u548c\u805a\u5408\u7ed3\u6784\u7565\u6709\u6539\u53d8\uff0c\u4f53\u73b0\u4e86\u4e24\u6027\u79bb\u5b50\u578bPSPP\u5d4c\u6bb5\u8457\u540d\u7684\u79bb\u5b50\u654f\u611f\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Aggregation Behavior of Doubly Thermoresponsive Polysulfobetaine-b-poly(N-isopropylacrylamide) Diblock Copolymers<\/a>\uff08Macromolecules, 2016, DOI: 10.1021\/acs.macromol.6b01186\uff09<\/p>\n

7\u3001Macromolecules \u6709\u5173\u6c34\u5408\u5168\u6c1f\u78fa\u9178\u819c\u7ea2\u5916\u5149\u8c31\u7684\u7406\u8bba\u4e0e\u5b9e\u8df5\u7814\u7a76<\/strong><\/p>\n

\"7\"<\/p>\n

\u56fe7<\/strong> \u5728\u4e0d\u540c\u6e7f\u5ea6\u6761\u4ef6\u4e0bNafion\u7684ATR-FTIR<\/p>\n

\u71c3\u6599\u7535\u6c60\u4f5c\u4e3a\u4e0b\u4e00\u4ee3\u80fd\u91cf\u8f6c\u5316\u7cfb\u7edf\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u5168\u6c1f\u78fa\u9178(Nafion)\u8584\u819c\u662f\u5e94\u7528\u6700\u591a\u7684\u8d28\u5b50\u4ea4\u6362\u8584\u819c\uff0c\u4f46\u56e0\u4ef7\u683c\u6602\u8d35\u800c\u963b\u788d\u5176\u53d1\u5c55\u3002\u4e3a\u83b7\u5f97\u66f4\u4ef7\u5ec9\u3001\u66f4\u73af\u4fdd\uff0c\u5e76\u4e14\u5728\u4f4e\u6e7f\u5ea6\u4e0b\u6709\u8f83\u9ad8\u7684\u8d28\u5b50\u4f20\u5bfc\u7387\u7684\u8d28\u5b50\u4ea4\u6362\u8584\u819c\uff0c\u7814\u7a76\u8005\u4eec\u6b63\u5728\u5bfb\u627e\u5168\u6c1f\u78fa\u9178\u819c\u7684\u66ff\u4ee3\u54c1\u3002<\/p>\n

\u65e5\u672c\u5c71\u68a8\u5927\u5b66\u71c3\u6599\u7535\u6c60\u7eb3\u7c73\u6750\u6599\u7814\u7a76\u4e2d\u5fc3\u7684Takao Tsuneda\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u4e3a\u627e\u5230\u5168\u6c1f\u78fa\u9178\u8584\u819c\u7684\u66ff\u4ee3\u54c1\uff0c\u7814\u7a76\u5728\u4f4e\u6e7f\u5ea6\u7684\u60c5\u51b5\u4e0b\u5168\u6c1f\u78fa\u9178\u8584\u819c\u9ad8\u8d28\u5b50\u4f20\u5bfc\u7387\u7684\u6839\u672c\u539f\u56e0\u3002\u7814\u7a76\u4eba\u5458\u5229\u7528\u7ea2\u5916\u5149\u8c31\uff08IR\uff09\u4e0e\u8d28\u5b50\u4f20\u5bfc\u7387\u7684\u5173\u7cfb\uff0c\u5f97\u51fa\u8d28\u5b50\u7684\u4f20\u5bfc\u662f\u901a\u8fc7\u6c34\u5408\u6c34\u79bb\u5b50\u7c07\u4fa7\u94fe\u7a7f\u8fc7\u53cc\u91cd\u6c34\u5408\u786b\u9178\u57fa\u56e2\u5b9e\u73b0\u7684\u3002\u901a\u8fc7\u7814\u7a76\u53cc\u91cd\u6c34\u5408\u5168\u6c1f\u78fa\u9178\u8584\u819c\u7684IR\u56fe\u8c31\uff0c\u7814\u7a76\u4eba\u5458\u731c\u6d4bSO3-\u5cf0\u632f\u52a8\u6a21\u5f0f\u6e7f\u5ea6\u5bf9\u6e7f\u5ea6\u7684\u4f9d\u8d56\u6027\uff0c\u662f\u7531\u4e8e\u786b\u9178\u5b98\u80fd\u56e2\u9644\u8fd1\u7684\u8d28\u5b50\u79fb\u52a8\u5230\u4e86\u6c34\u5408\u6c34\u5206\u5b50\u7c07\u5468\u56f4\u3002\u4e0e\u5355\u6c34\u5408\u5168\u6c1f\u78fa\u9178\u76f8\u6bd4\uff0c\u53cc\u91cd\u6c34\u5408\u5168\u6c1f\u78fa\u9178\u5728\u4f4e\u6e7f\u5ea6\u73af\u5883\u4e0b\u6709\u66f4\u9ad8\u8d28\u5b50\u4f20\u5bfc\u7387\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u7ea2\u5916\u5149\u8c31\u4ece\u7406\u8bba\u548c\u5b9e\u8df5\u4e0a\u5bf9\u5168\u6c1f\u78fa\u9178\u8584\u819c\u7684\u9ad8\u8d28\u5b50\u4f20\u5bfc\u7387\u8fdb\u4e00\u6b65\u7684\u63a2\u7a76\uff0c\u5bf9\u5bfb\u627e\u8d28\u5b50\u4ea4\u6362\u8584\u819c\u7684\u66ff\u4ee3\u54c1\u505a\u51fa\u4e86\u91cd\u8981\u7684\u542f\u793a\u4f5c\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Experimental and Theoretical Infrared Spectroscopic Study on Hydrated Nafion Membrane<\/a>\uff08Macromolecules , 2016 , DOI : 10.1021\/acs.macromol.6b00999\uff09<\/p>\n

8\u3001Macromolecules \u5e26\u6709\u94fe\u7f3a\u9677\u7684\u805a\uff08\u73af\u6c27\u4e59\u70f7\uff09\u7ed3\u6676\u884c\u4e3a<\/strong><\/p>\n

\"8\"<\/p>\n

\u56fe8<\/strong> PEO11-TR-PEO11\u7684\u5408\u6210\u8def\u7ebf<\/p>\n

\u805a\uff08\u73af\u6c27\u4e59\u70f7\uff09\uff08PEO\uff09\u662f\u4e00\u79cd\u5341\u5206\u91cd\u8981\u7684\u5408\u6210\u9ad8\u5206\u5b50\uff0c\u6709\u7740\u4f18\u826f\u7684\u751f\u7269\u76f8\u5bb9\u6027\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u751f\u7269\uff0c\u533b\u836f\u548c\u79bb\u5b50\u7535\u5bfc\u9886\u57df\u3002PEO\u662f\u4e00\u79cd\u534a\u7ed3\u6676\u805a\u5408\u7269\uff0c\u7194\u70b9\u6e29\u5ea6\uff08Tm\uff09\u548c\u7ed3\u6676\u5ea6\uff08X\uff09\u5bf9\u6539\u53d8\u5176\u6027\u80fd\u5341\u5206\u7684\u91cd\u8981\u3002\u805a\u5408\u7269\u94fe\u4e2d\u5f15\u5165\u7279\u5b9a\u7684\u7f3a\u9677\uff0c\u5bf9Tm\u548cX\u90fd\u80fd\u5e26\u6765\u5f88\u5927\u7684\u5f71\u54cd\u3002\u5728PEO\u94fe\u4e2d\u5f15\u5165\u7f3a\u9677\uff0c\u662f\u4e00\u79cd\u6539\u53d8PEO\u6027\u80fd\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6700\u8fd1\u5fb7\u56fd\u54c8\u52d2\uff0d\u7ef4\u817e\u8d1d\u683c\u5927\u5b66\u7684J\u00f6rg Kressler \uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u8bbe\u8ba1\u51fa\u4e00\u79cd1,2,3-\u82ef\u4e09\u5511\uff08TR\uff09\u7684PEO\u76841,4\u53d6\u4ee3\u540e\uff0c\u5f97\u5230PEO11-TR-PEO11\u5d4c\u6bb5\u5171\u805a\u7269\u3002\u5927\u91cf\u7684\u82ef\u4e09\u5511\u73af\u57fa\u56e2\u7684\u52a0\u5165\uff0c\u4f1a\u9650\u5236PEO\u7ed3\u6676\uff1b\u7531\u4e8e\u82ef\u4e09\u5511\u73af\u57fa\u56e2\u5177\u6709\u03c0\u7ed3\u6784\uff0c\u6240\u4ee5\u6709\u7740\u826f\u597d\u7684\u79bb\u5b50\u7279\u6027\u3002\u5f15\u5165\u82ef\u4e09\u5511\u73af\u57fa\u56e2\uff0c\u53ef\u4ee5\u964d\u4f4e\u7ed3\u6676\u5ea6\uff0c\u5e76\u589e\u52a0\u4ee5PEO\u4e3a\u57fa\u7840\u7684\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002PEO11-TR-PEO11\u7684\u7ed3\u6784\u7279\u70b9\u8fd8\u8868\u73b0\u4e3a\u57280\u2103\u51b7\u5374\u540e\uff0c\u8868\u73b0\u4e3a\u7247\u6676\u7ed3\u6784\uff0c\u5728\u5347\u6e29\u81f3\u7194\u70b9\u8fc7\u7a0b\u4e2d\uff0cT>8\u2103\u540e\u7247\u6676\u7ed3\u6784\u53d1\u751f\u4e86\u8f6c\u53d8\uff0c\u5e76\u4e14\u8fd9\u79cd\u8f6c\u53d8\u4e3a\u975e\u53ef\u9006\u8f6c\u53d8\u3002PEO11-TR-PEO11\u5728\u592a\u9633\u80fd\u7535\u6c60\u3001\u71c3\u6599\u7535\u6c60\u7b49\u9886\u57df\u6709\u5f88\u5927\u7684\u5e94\u7528\u524d\u666f\uff0c\u503c\u5f97\u7814\u7a76\u5de5\u4f5c\u8005\u7ee7\u7eed\u52aa\u529b\u7814\u7a76\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Crystallization of Poly(ethylene oxide) with a Well-Defined Point Defect in the Middle of the Polymer Chain<\/a>\uff08Macromolecules , 2016 , DOI : 10.1021\/acs.macromol.6b01107\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u6750\u6599\u5b66\u4e60\u5c0f\u7ec4\u6210\u5458Lynn\u3001Simon\u3001Andy_chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u6750\u6599\u5b66\u4e60\u5c0f\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u672c\u671f\u7cbe\u9009\u9884\u89c8\uff1aAngew. Chem. Int. Ed. \u5177\u6709\u9ad8\u5ea6\u7acb\u4f53\u9009\u62e9\u6027\u7684\u5b98\u80fd\u5316\u805a\u6742\u73af\uff1bAngew. Chem. Int. Ed. \u901a\u8fc7\u5bbf\u4e3b\u4e0e\u5ba2\u4f53\u4ea4\u4e92\u4f5c\u7528\u4ecb…<\/p>\n","protected":false},"author":393,"featured_media":37206,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[67],"tags":[42],"class_list":["post-37205","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhoubao","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/37205"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/393"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=37205"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/37205\/revisions"}],"predecessor-version":[{"id":37299,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/37205\/revisions\/37299"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/37206"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=37205"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=37205"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=37205"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}