{"id":36637,"date":"2016-08-28T16:00:50","date_gmt":"2016-08-28T08:00:50","guid":{"rendered":"\/\/m.iemloyee.com\/?p=36637"},"modified":"2016-08-28T17:05:16","modified_gmt":"2016-08-28T09:05:16","slug":"adv-mater-%ef%bc%9a%e5%88%86%e5%ad%90%e5%86%85%e6%89%ad%e6%9b%b2%e7%9a%84%e5%87%8f%e5%b0%91%e8%83%bd%e5%a4%9f%e6%8f%90%e9%ab%98%e9%9d%9e%e5%af%8c%e5%8b%92%e7%83%af%e6%9c%89%e6%9c%ba%e5%a4%aa%e9%98%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=36637","title":{"rendered":"Adv. Mater.\uff1a\u5206\u5b50\u5185\u626d\u66f2\u7684\u51cf\u5c11\u80fd\u591f\u63d0\u9ad8\u975e\u5bcc\u52d2\u70ef\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u91cc3D\u5206\u5b50\u53d7\u4f53\u7684\u6027\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u76ee\u524d\uff0c\u5bcc\u52d2\u70ef\u884d\u751f\u6750\u6599\uff08\u4ee5PC61<\/sub>BM\u548c PC71<\/sub>BM\u4e3a\u4ee3\u8868\uff09\u7531\u4e8e\u9ad8\u7535\u5b50\u4f20\u8f93\u80fd\u529b\u548c\u5728\u5757\u72b6\u5f02\u8d28\u7ed3(BHJ)\u8584\u819c\u4e0a\u4f18\u826f\u7684\u5f62\u8c8c\u800c\u88ab\u5e7f\u4e3a\u5e94\u7528\u4e8e\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff08OSCs\uff09\u4e2d\u3002\u7136\u800c\u5bcc\u52d2\u70ef\u6750\u6599\u7684\u5438\u5149\u80fd\u529b\u5f31\uff0c\u5236\u5907\u6210\u672c\u9ad8\uff0c\u4e0e\u9ad8\u805a\u7269\u548c\u5c0f\u5206\u5b50\u53d7\u4f53\u7684\u7ed3\u5408\u80fd\u529b\u5dee\u7684\u7279\u70b9\u4fc3\u4f7f\u4eba\u4eec\u63a2\u7d22\u975e\u5bcc\u52d2\u70ef\u6750\u6599\u3002\u4f20\u7edf\u7684\u975e\u5bcc\u52d2\u70ef\u6750\u6599\u56e0\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff08PCEs\uff09\u4ec5\u67092-3%\u800c\u8868\u73b0\u4e0d\u4f73\u3002\u5176\u4e3b\u8981\u539f\u56e0\u4e3a\u5c0f\u5206\u5b50\u53d7\u4f53\u7684\u5927\u5c3a\u5bf8\u5f15\u8d77\u7684\u5f3a\u56e2\u805a\u548c\u8fc7\u5ea6\u5806\u53e0\uff08\u9ad8\u8fbe1 um\uff09\u3002\u4e3a\u4e86\u6291\u5236\u5206\u5b50\u4e4b\u95f4\u7684\u56e2\u805a\u548c\u5806\u53e0\u5c3a\u5bf8\uff0c\u626d\u66f2\u7ed3\u6784\u7684\u5c0f\u5206\u5b50\u53d7\u4f53\u88ab\u5e94\u7528\u5728OSCs\u4e0a\uff0c\u7136\u800c\u626d\u66f2\u7ed3\u6784\u901a\u5e38\u4f1a\u9020\u6210\u8f83\u4f4e\u7684\u7ed3\u6676\u5ea6\u4ee5\u53ca\u8f83\u5dee\u7684\u7535\u5b50\u4f20\u8f93\u80fd\u529b\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u7684\u989c\u6cb3\u6559\u6388\u7b49\u4eba\u5408\u6210\u4e86\u4e00\u79cd\u547d\u540d\u4e3aTPE-PDI4\u65b0\u578b3D\u7ed3\u6784\u7684\u5c0f\u5206\u5b50\u53d7\u4f53\uff0c\u8fd9\u79cd\u53d7\u4f53\u76f8\u6bd4\u4ee5\u5f80\u7535\u5bfc\u6027\u8f83\u5f3a\u7684\u53d7\u4f53\uff0c\u5177\u6709\u76f8\u5bf9\u8f83\u5f31\u7684\u5206\u5b50\u5185\u626d\u66f2\u7a0b\u5ea6\uff0c\u5c0f\u5806\u53e0\u5c3a\u5bf8\u3002\u57fa\u4e8eTPE-PDI4\u7ed3\u6784\u7684\u5668\u4ef6\uff0c\u5149\u7535\u8f6c\u5316\u6548\u7387\u8fbe\u52305.5%<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span>
\n<\/p>\n

\u56fe1<\/strong> a\uff09TPPz-PDI4<\/sub>\u7684\u5316\u5b66\u7ed3\u6784\u3002 \u00a0 b\uff09PffBT-T3(1,2)-2\u7684\u5316\u5b66\u7ed3\u6784\u3002<\/p>\n

c\uff09\u5206\u5b50\u5185\u626d\u66f2\u51cf\u5f31\u7684TPC-PDI4<\/sub>\uff0c TPE-PDI4<\/sub>\uff0c TPPz-PDI4<\/sub>\u7ed3\u6784\u3002
\n<\/p>\n

\u56fe2<\/strong> a-c\uff09\u4e09\u79cd\u5c40\u90e8\u4f18\u5316\u7684TPPz-PDI4\u7ed3\u6784\u3002\u51e0\u79cd\u5178\u578b\u7684\u76f8\u90bb\u5421\u55ea\u548c\u82ef\u73af\u4e4b\u95f4\u7684\u4e8c\u9762\u89d2\u7528\u7bad\u5934\u6807\u51fa
\n<\/p>\n

\u56fe3\u00a0<\/strong>a\uff09\u7eafPffBT-T3(1,2)-2\u8584\u819c\uff08\u5706\u5708\uff09\uff0c\u7eafTPPz-PDI4\uff08\u65b9\u5f62\uff09\u53ca\u5176\u6df7\u5408\u8584\u819c\uff08\u4e09\u89d2\u5f62\uff09\u7684\u6807\u51c6\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u56fe\u3002<\/p>\n

b\uff09TPPz-PDI4\u8584\u819c\uff08\u65b9\u5f62\uff09\u548c\u6c2f\u82ef\u6eb6\u6db2\uff08\u5706\u5708\uff09\u7684\u6807\u51c6\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u56fe\u3002<\/p>\n

c) TPPz-PDI4(\u4e09\u89d2\u5f62)\uff0cTPE-PDI4\uff08\u84dd\u8272\u6b63\u65b9\u5f62\uff09\u548cTPC-PDI4(\u7ea2\u8272\u5706\u5708)\u8584\u819c\u3002
\n\"adma201600997-fig-0004\"<\/p>\n

 <\/p>\n

\u56fe4<\/strong> a\uff09\u57fa\u4e8eTPPz-PDI4 (\u5706\u5708), TPE-PDI4 (\u6b63\u65b9\u5f62), and TPC-PDI4 (\u4e09\u89d2\u5f62)\u7684\u4f18\u5316\u5668\u4ef6\u7684J-V\u66f2\u7ebf\u3002<\/p>\n

b\uff09\u57fa\u4e8eTPPz-PDI4 (\u5706\u5708), TPE-PDI4 (\u6b63\u65b9\u5f62), and TPC-PDI4 (\u4e09\u89d2\u5f62)\u7684\u4f18\u5316\u5668\u4ef6\u7684\u5916\u90e8\u91cf\u5b50\u6548\u7387\u5149\u8c31\u3002<\/p>\n

\u5c0f\u7ed3<\/strong><\/span><\/p>\n

\u672c\u6587\u7cfb\u7edf\u5730\u7814\u7a76\u4e863D\u5206\u5b50\u53d7\u4f53\u5206\u5b50\u5185\u5728\u975e\u5bcc\u52d2\u70ef\u592a\u9633\u80fd\u7535\u6c60\u91cc\u7684\u5f71\u54cd\uff0c\u63ed\u793a\u4e863D\u5206\u5b50\u53d7\u4f53\u7cfb\u5217\u7684\u7ed3\u6784\u4e0e\u6027\u80fd\u7684\u5173\u7cfb\uff0c\u5bf9\u9ad8\u6027\u80fd\u5c0f\u5206\u5b50\u53d7\u4f53\u7684\u975e\u77f3\u58a8\u70ef\u592a\u9633\u80fd\u7535\u6c60\u7684\u8bbe\u8ba1\u548c\u53d1\u5c55\u5177\u6709\u91cd\u8981\u7684\u5f15\u5bfc\u610f\u4e49\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a Reduced Intramolecular Twisting Improves the Performance of 3D Molecular Acceptors in Non-Fullerene Organic Solar Cells<\/a> \uff08Adv. Mater., 2016, DOI: 10.1002\/adma.201600997\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 \u4e1c\u6d77\u6728\u5b50\u674e \u4f9b\u7a3f\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002\"\u65b0\u80fd\u6e90\u524d\u7ebf\"<\/p>\n","protected":false},"excerpt":{"rendered":"

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