{"id":36188,"date":"2016-08-26T08:00:23","date_gmt":"2016-08-26T00:00:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=36188"},"modified":"2016-08-25T18:51:43","modified_gmt":"2016-08-25T10:51:43","slug":"%e8%bf%9e%e8%80%bf%e7%9b%b4%e7%9a%84%e6%9c%89%e6%9c%ba%e6%99%b6%e4%bd%93%e4%b9%9f%e8%83%bd%e5%bc%af%e4%ba%86","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=36188","title":{"rendered":"\u8fde\u803f\u76f4\u7684\u6709\u673a\u6676\u4f53\u4e5f\u80fd\u5f2f\u4e86"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-36189\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/20160816lnp1-fig2bcd.jpg\" alt=\"20160816lnp1-fig2bcd\" width=\"700\" height=\"299\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/20160816lnp1-fig2bcd.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/20160816lnp1-fig2bcd-300x128.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u6750\u6599\u725b\u6ce8\uff1a<\/strong>\u7531\u4e8e\u76f8\u4e92\u4f5c\u7528\u529b\u7684\u5b58\u5728\uff0c\u4f7f\u5f97\u6676\u4f53\u5448\u73b0\u53c8\u786c\u53c8\u8106\u7684\u7269\u7406\u6027\u8d28\u3002\u6700\u8fd1\u6765\u81ea\u5370\u5ea6\u79d1\u5b66\u7406\u5de5\u5b66\u9662\u7684Reddy\u5229\u7528\u7eb8\u5f20\u6298\u53e0\u6210\u7b14\u8bb0\u7684\u539f\u7406\uff0c\u8d4b\u4e88\u4e86\u6676\u4f53\u5982\u7eb8\u5f20\u7684\u67d4\u8f6f\u7279\u6027\u3002<\/p>\n<p>\u6676\u4f53\u6750\u6599\uff0c\u6bd4\u5982\u94bb\u77f3\u6216\u8005\u5b9d\u77f3\uff0c\u4ee5\u53c8\u8106\u53c8\u786c\u4e3a\u7279\u5f81\uff0c\u4f46\u662f\u7531\u6709\u5e8f\u6392\u5217\u7684\u6709\u673a\u5206\u5b50\u5236\u6210\u7684\u6676\u4f53\u5374\u80fd\u5c48\u80fd\u4f38\u3002\u5c3d\u7ba1\u8fd9\u7c7b\u6676\u4f53\u6750\u6599\u4e4b\u524d\u662f\u5728\u5076\u7136\u7684\u6761\u4ef6\u4e0b\u88ab\u53d1\u73b0\u7684\uff0c\u73b0\u5982\u4eca\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u80fd\u901a\u8fc7\u524a\u5f31\u91cd\u590d\u5355\u5143\u7684\u4f5c\u7528\u529b\u6765\u8bbe\u8ba1\u6709\u673a\u5206\u5b50\uff0c\u90a3\u6837\u4fbf\u80fd\u5f62\u6210\u5177\u6709\u53ef\u5851\u6027\u7684\u6676\u4f53\u6750\u6599(J. Am. Chem. Soc. 2016, DOI: 10.1021\/jacs.6b05118)\u3002\u8be5\u8bbe\u8ba1\u539f\u7406\u80fd\u88ab\u7528\u4e8e\u4f17\u591a\u5de5\u7a0b\u6750\u6599\uff0c\u8bf8\u5982\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u548c\u53d1\u5149\u4e8c\u6781\u7ba1\uff0c\u4e5f\u53ef\u4ee5\u662f\u7528\u4e8e\u5236\u836f\u5de5\u4e1a\u7684\u52a9\u5242\uff0c\u76f8\u5173\u4eba\u5458\u8bf4\u9053\u3002<\/p>\n<p>\u5173\u4e8e\u6709\u673a\u6676\u4f53\u7684\u7ed3\u6784\u5982\u4f55\u5f71\u54cd\u6750\u6599\u7684\u673a\u68b0\u6027\u80fd\uff0c\u8fd9\u4e00\u70b9\u4eba\u4eec\u77e5\u4e4b\u751a\u5c11\u3002\u4f46\u662f\u5370\u5ea6\u79d1\u5b66\u7406\u5de5\u5b66\u9662\u548c\u52a0\u5c14\u5404\u7b54\u7814\u7a76\u6240\u7684C. Malla Reddy\u4e0e\u540c\u4e8b\u5408\u4f5c\uff0c\u4f7f\u7528\u4e00\u79cd\u8f83\u4e3a\u719f\u6089\u7684\u539f\u7406\u5236\u5f97\u53ef\u5851\u6027\u6676\u4f53\u3002\u8be5\u539f\u7406\u4e3a\uff1a\u5728\u673a\u68b0\u5e94\u529b\u4e0b\uff0c\u5f31\u8fde\u63a5\u662f\u80fd\u8f7b\u6613\u65ad\u88c2\u548c\u91cd\u7ec4\u7684\uff0c\u6709\u65f6\u4e5f\u80fd\u8ba9\u6750\u6599\u4ec5\u4ec5\u53d1\u751f\u5f2f\u66f2\u4e0d\u65ad\u88c2\u3002\u4e3a\u4e86\u89e3\u51b3\u5f31\u8fde\u63a5\u7684\u80fd\u91cf\u95ee\u9898\uff0c\u4ed6\u4eec\u4e8e\u662f\u8bbe\u8ba1\u4e86\u4e09\u79cd\u6709\u673a\u5206\u5b50\u4ee5\u5f62\u6210\u4e0d\u540c\u7684\u53ef\u5851\u6027\u6676\u4f53\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-36190\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/20160816lnp1-fig2h.jpg\" alt=\"20160816lnp1-fig2h\" width=\"700\" height=\"404\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/20160816lnp1-fig2h.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/20160816lnp1-fig2h-300x173.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u7b2c\u4e00\u7c7b\u4ee5\u8418\u4e8c\u4e9a\u80fa\u4e3a\u7ed3\u6784\u5355\u5143\uff0c\u4e24\u7aef\u8fde\u6709\u7403\u5f62\u7684\u7532\u57fa\u6216\u8005\u53d4\u4e01\u57fa\u57fa\u56e2\u3002\u6bcf\u4e2a\u7ed3\u6784\u5355\u5143\u4e2d\u5fc3\u7684\u82b3\u73af\u4e00\u4e2a\u63a5\u4e00\u4e2a\u5806\u53e0\u6210\u4e00\u7ef4\u7684\u6676\u4f53\u3002\u540c\u65f6\uff0c\u8fd9\u4e9b\u5806\u53e0\u5355\u5143\u7684\u76f8\u4e92\u4f5c\u7528\u662f\u5229\u7528\u70f7\u57fa\u57fa\u56e2\u95f4\u5fae\u5f31\uff0c\u77ed\u6682\u7684\u9759\u7535\u5438\u5f15\u3002\u8fd9\u4e9b\u76f8\u4e92\u4f5c\u7528\u751f\u6210\u4e86\u8d2f\u7a7f\u6676\u4f53\u7684\u5e73\u9762\uff0c\u6240\u5728\u7684\u5c42\u5728\u6676\u4f53\u88ab\u5f2f\u66f2\u7684\u65f6\u5019\u80fd\u591f\u64e6\u80a9\u800c\u8fc7\u3002Reddy\u5c06\u8fd9\u6837\u7684\u6ed1\u79fb\u6bd4\u55bb\u4e3a\u5c42\u53e0\u7684\u7eb8\u5f20\u6298\u53e0\u6210\u7b14\u8bb0\u672c\u3002\u5229\u7528\u8be5\u53ef\u5851\u6027\uff0c\u7814\u7a76\u5458\u4e8e\u662f\u5c06\u663e\u5fae\u955c\u4e0b\u7684\u6676\u4f53\u5851\u5f62\u6210\u5b57\u6bcd\u7684\u5f62\u72b6\u3002<\/p>\n<p>\u800c\u7b2c\u4e8c\u7c7b\u5206\u5b50\uff0c\u7814\u7a76\u5458\u628a\u82ef\u7532\u9178\u53d6\u4ee3\u7269\u7684\u7ed3\u6784\u5355\u5143\u5229\u7528\u76f8\u5bf9\u8f83\u5f3a\u7684\u6c22\u952e\u4f5c\u7528\u529b\u5728\u4e00\u4e2a\u65b9\u5411\u4e0a\u805a\u96c6\uff0c\u901a\u5e38\u5728\u6676\u4f53\u5de5\u7a0b\u4e2d\u88ab\u7528\u6765\u8fde\u63a5\u5404\u4e2a\u7ed3\u6784\u5355\u5143\u3002\u5728\u5176\u4ed6\u7ef4\u5ea6\u4e0a\uff0c\u4f4d\u4e8e\u7ed3\u6784\u5355\u5143\u672b\u7aef\u7684\u6c2f\u539f\u5b50\u548c\u6eb4\u539f\u5b50\u7684\u5f31\u5364\u7d20\u4f5c\u7528\u529b\u4ea7\u751f\u4e86\u6ed1\u79fb\u5c42\uff0c\u4f7f\u6676\u4f53\u95f4\u5177\u6709\u53ef\u5851\u6027\u3002<\/p>\n<p>\u7814\u7a76\u8005\u7528\u8fde\u63a5\u5364\u4ee3\u6216\u8005\u70f7\u57fa\u5316\u82ef\u80fa\u5316\u5408\u7269\u7684\u9999\u5170\u7d20\u5236\u5f97\u7b2c\u4e09\u7c7b\u7ed3\u6784\u5355\u5143\u3002\u8fd9\u7c7b\u5206\u5b50\u5f62\u6210\u7684\u6676\u4f53\u9047\u5230\u5149\u53d8\u8272\uff0c\u6216\u8005\u53d7\u70ed\u540e\u9a71\u4f7f\u81ea\u5df1\u79bb\u5f00\u8868\u9762\u2014\u2014\u8fd9\u4e9b\u6027\u8d28\u5728\u8bb0\u5fc6\u5149\u5b66\u4ee5\u53ca\u673a\u68b0\u6d3b\u6027\u6750\u6599\u7684\u5e94\u7528\u9886\u57df\u6709\u5f88\u5927\u4f5c\u7528\u3002\u8fd9\u6837\u7684\u60c5\u51b5\uff0c\u662f\u7531\u4e8e\u70f7\u57fa\u57fa\u56e2\u548c\u5364\u7d20\u57fa\u56e2\u7684\u5f31\u76f8\u4e92\u4f5c\u7528\u5f62\u6210\u4e86\u6ed1\u52a8\u3002<\/p>\n<p>\u5370\u5ea6\u79d1\u5b66\u7406\u5de5\u5b66\u9662\u7684Gautam R. Desiraju\u8868\u793a\u4e3a\u4e86\u5236\u5907\u53ef\u5f2f\u66f2\u6210\u5b57\u6bcd\u7684\u6676\u4f53\u4ecd\u9700\u8981\u5927\u91cf\u7684\u5316\u5b66\u7814\u7a76\u3002\u4ed6\u79f0\u5176\u4e3a\u6676\u4f53\u5de5\u7a0b\u4e2d\u7684\u201c\u7406\u60f3\u7814\u7a76\u201d\uff0c\u56e0\u4e3a\u7814\u7a76\u8005\u53ef\u4ee5\u901a\u8fc7\u81ea\u5df1\u7684\u8ba4\u77e5\uff0c\u5173\u4e8e\u6676\u4f53\u7684\u5206\u5b50\u5982\u4f55\u5f71\u54cd\u7ed3\u6784\u548c\u7269\u7406\u6027\u8d28\u6765\u8bbe\u8ba1\u548c\u6784\u9020\u6676\u4f53\u3002<\/p>\n<p>Reddy\u5e0c\u671b\u5176\u4ed6\u7814\u7a76\u8005\u5e94\u7528\u5f31\u76f8\u4e92\u4f5c\u7528\u529b\u4ee5\u8bbe\u8ba1\u53ef\u5851\u6027\u6709\u673a\u534a\u5bfc\u4f53\u5206\u5b50\u548c\u5236\u836f\u52a9\u5242\u3002\u5728\u5236\u836f\u8fc7\u7a0b\u4e2d\uff0c\u6d3b\u6027\u6210\u5206\u5e38\u5e38\u4e0e\u8f85\u836f\u7ed3\u5408\uff0c\u4f5c\u4e3a\u6784\u601d\u548c\u751f\u4ea7\u8fc7\u7a0b\u7684\u4e00\u90e8\u5206\u3002Reddy\u8ba4\u4e3a\u5982\u679c\u8f85\u836f\u5236\u6210\u4e86\u8106\u6027\u7c89\u672b\uff0c\u5b83\u4f1a\u5728\u6405\u62cc\u4e2d\u7834\u788e\uff0c\u5f97\u5230\u4e0d\u4e00\u81f4\u7684\u4ea7\u54c1\uff0c\u800c\u53ef\u5851\u6027\u6676\u4f53\u80fd\u5e2e\u52a9\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/cen.acs.org\/articles\/94\/web\/2016\/08\/Organic-crystals-designed-flexibility.html\" target=\"_blank\">Organic crystals designed for flexibility<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b05118?journalCode=jacsat\" target=\"_blank\">Mechanically Flexible Organic Crystals Achieved by Introducing Weak Interactions in Structure: Supramolecular Shape Synthons<\/a><\/p>\n<p>\u672c\u6587\u7531\u7f16\u8f91\u90e8\u6768\u6d2a\u671f\u63d0\u4f9b\u7d20\u6750\uff0c\u5f20\u8f76\u6d01\u7f16\u8bd1\uff0c<a href=\"http:\/\/cailiaoren.mikecrm.com\/6qSdMU\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6750\u6599\u725b\u6ce8\uff1a\u7531\u4e8e\u76f8\u4e92\u4f5c\u7528\u529b\u7684\u5b58\u5728\uff0c\u4f7f\u5f97\u6676\u4f53\u5448\u73b0\u53c8\u786c\u53c8\u8106\u7684\u7269\u7406\u6027\u8d28\u3002\u6700\u8fd1\u6765\u81ea\u5370\u5ea6\u79d1\u5b66\u7406\u5de5\u5b66\u9662\u7684Reddy\u5229\u7528\u7eb8\u5f20\u6298\u53e0\u6210\u7b14\u8bb0\u7684\u539f\u7406\uff0c\u8d4b\u4e88\u4e86\u6676\u4f53\u5982\u7eb8\u5f20\u7684\u67d4\u8f6f\u7279\u6027\u3002 \u6676\u4f53&#8230;<\/p>\n","protected":false},"author":718,"featured_media":36190,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[56,54],"class_list":["post-36188","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji","tag-crsytal","tag-making"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/36188"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/718"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=36188"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/36188\/revisions"}],"predecessor-version":[{"id":36454,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/36188\/revisions\/36454"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/36190"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=36188"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=36188"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=36188"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}