{"id":35359,"date":"2016-08-22T14:00:41","date_gmt":"2016-08-22T06:00:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=35359"},"modified":"2016-08-22T12:10:32","modified_gmt":"2016-08-22T04:10:32","slug":"chem-soc-rev-%e5%b4%94%e5%b1%b9%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e9%ab%98%e8%83%bd%e9%94%82%e7%a1%ab%e7%94%b5%e6%b1%a0%e7%9a%84%e8%ae%be%e8%ae%a1","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=35359","title":{"rendered":"Chem. Soc. Rev. \u5d14\u5c79\u6700\u65b0\u7efc\u8ff0\uff1a\u9ad8\u80fd\u9502\u786b\u7535\u6c60\u7684\u8bbe\u8ba1"},"content":{"rendered":"

\u3010\u5f15\u8bed\u3011 \u8fd1\u65e5\uff0c\u65af\u5766\u798f\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u7684\u5d14\u5c79<\/strong>\u6559\u6388<\/span>\u548cSun Yongming<\/strong>\u535a\u58eb<\/span>\u3001\u65b0\u52a0\u5761\u6750\u6599\u7814\u7a76\u4e0e\u5de5\u7a0b\u7814\u7a76\u6240\u7684Zhi Wei She<\/strong><\/span>\u548c\u5317\u4eac\u822a\u5929\u822a\u7a7a\u5927\u5b66\u5f20\u5343\u5e06<\/strong>\u6559\u6388<\/span>\u4eba\u8054\u5408\u5728Chem. Soc. Rev.\u4e0a\u53d1\u6587\uff0c\u4e00\u7bc7\u5173\u4e8e\u9ad8\u80fd\u9502\u786b\u7535\u6c60\u8bbe\u8ba1<\/strong><\/span>\u7684\u7efc\u8ff0\u6a2a\u7a7a\u51fa\u4e16\uff0c\u9898\u4e3a\u201cDesigning high-energy lithium<\/strong>\u2013sulfur batteries<\/strong><\/span>\u201d\u3002<\/p>\n

1.Introduction<\/strong><\/span><\/p>\n

\u968f\u7740\u4e16\u754c\u4eba\u53e3\u7684\u4e0d\u65ad\u589e\u957f\uff0c\u80fd\u6e90\u9700\u6c42\u7684\u589e\u52a0\u548c\u6c14\u5019\u7684\u53d8\u5316\uff0c\u6211\u4eec\u5fc5\u987b\u5c06\u91cd\u70b9\u653e\u5728\u4e3a\u4eba\u7c7b\u521b\u9020\u4e00\u4e2a\u53ef\u6301\u7eed\u7684\u80fd\u6e90\u672a\u6765\u7684\u540c\u65f6\uff0c\u8fd8\u8981\u4fdd\u62a4\u6211\u4eec\u8106\u5f31\u7684\u73af\u5883\u3002\u4e3a\u4e86\u5b9e\u73b0\u8fd9\u4e00\u76ee\u6807\uff0c\u6211\u4eec\u9700\u8981\u51cf\u5c11\u6211\u4eec\u5bf9\u5316\u77f3\u71c3\u6599\u7684\u4f9d\u8d56\uff0c\u5e76\u8f6c\u5411\u6e05\u6d01\u3001\u53ef\u518d\u751f\u80fd\u6e90\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u53ef\u518d\u751f\u80fd\u6e90\u9700\u8981\u5148\u8fdb\u80fd\u6e90\u5b58\u50a8\u7cfb\u7edf\uff0c\u53ef\u4ee5\u5f53\u5b83\u5904\u5728\u8fc7\u91cf\u72b6\u6001\u65f6\u50a8\u5b58\uff0c\u5728\u88ab\u9700\u6c42\u65f6\u91ca\u653e\u56de\u7535\u7f51\uff0c\u4ee5\u7ef4\u6301\u5bb6\u5ead\u548c\u5de5\u4e1a\u7a33\u5b9a\u7684\u7535\u6e90\u4f9b\u5e94\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u65e0\u6cd5\u6ee1\u8db3\u56fa\u5b9a\u5f0f\u7535\u7f51\u50a8\u80fd\u7684\u9ad8\u80fd\u91cf\u8981\u6c42\u3002\u7535\u6c60\u6709\u9650\u7684\u80fd\u91cf\u5bc6\u5ea6\u4e5f\u963b\u788d\u4e86\u4ed6\u4eec\u5728\u5404\u79cd\u65b0\u5174\u79fb\u52a8\u8fd0\u8f93\u5de5\u5177\u4e0a\u7684\u8fd0\u7528\u3002\u8fd9\u4fbf\u5f15\u53d1\u4e86\u5168\u7403\u63a2\u7d22\u8d85\u8d8a\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u7684\u65b0\u7535\u6c60\u6280\u672f\u3002<\/p>\n

\u9502-\u786b\u7535\u6c60\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u50a8\u80fd\u7cfb\u7edf\uff0c\u5176\u76f8\u6bd4\u73b0\u6709\u7684\u9502\u79bb\u5b50\u7535\u6c60\u5177\u6709\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u8fd9\u4e24\u79cd\u5f62\u5f0f\u7684\u7535\u6c60\u4e4b\u95f4\u7684\u4e3b\u8981\u533a\u522b\u5728\u4e8e\u5b83\u4eec\u7684\u80fd\u91cf\u5b58\u50a8\u673a\u5236\u3002\u9502\u79bb\u5b50\u7535\u6c60\u57fa\u4e8e\u9502\u79bb\u5b50\u63d2\u5165\u5c42\u72b6\u7535\u6781\u6750\u6599\u4e2d\u3002\u56e0\u4e3a\u9502\u79bb\u5b50\u53ea\u80fd\u63d2\u5165\u5230\u67d0\u4e9b\u7279\u5b9a\u7684\u70b9\u4f4d\u4e2d\uff0c\u56e0\u6b64\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u901a\u5e38\u9650\u5236\u5728\u7ea6420 Wh kg-1<\/sup>\u62161400 Wh L-1<\/sup>\uff08\u56fe1\uff09\uff0c\u9502\u786b\u7535\u6c60\u57fa\u4e8e\u9502\u8d1f\u6781\u4fa7\u91d1\u5c5e\u7684\u7535\u9540\u4e0e\u5265\u79bb\u548c\u6b63\u6781\u4fa7\u786b\u7684\u8f6c\u5316\u53cd\u5e94\u3002\u8fd9\u4e9b\u53cd\u5e94\u7684\u975e\u62d3\u6251\u6027\u8d28\u8d4b\u4e88\u4e86\u9502\u8d1f\u6781\u548c\u786b\u6b63\u6781\u5206\u522b\u4e3a3860 mA h g-1<\/sup>\u548c1673 mA h g-1<\/sup>\u7684\u9ad8\u7406\u8bba\u6bd4\u5bb9\u91cf\u30022.15 V\u7684\u5e73\u5747\u7535\u6c60\u7535\u538b\u7ed9\u4e88\u4e86\u9502-\u786b\u7535\u6c60\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea62500 Wh kg-1<\/sup> \u62162800 Wh L-1<\/sup>\uff08\u56fe1\uff09\u3002\u6b64\u5916\uff0c\u786b\u5728\u5730\u7403\u7684\u8868\u5c42\u50a8\u91cf\u4e30\u5bcc\u4e14\u5341\u5206\u5ec9\u4ef7\uff0c\u8fd9\u4f7f\u5f97\u9502-\u786b\u7535\u6c60\u6210\u4e3a\u4e00\u79cd\u5bcc\u6709\u5438\u5f15\u529b\u7684\u4e14\u6210\u672c\u4f4e\u7684\u50a8\u80fd\u6280\u672f\u3002
\n\"fig1\"<\/p>\n

\u56fe1\uff1a\u9502-\u786b\u7535\u6c60\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u56fe\uff08\u57fa\u4e8e\u77f3\u58a8\u8d1f\u6781\u548cLiNi1\/3<\/sub>Co1\/3<\/sub>Mn1\/3<\/sub>O2<\/sub>\u6b63\u6781\uff09\u3002<\/p>\n

\u9502-\u786b\u7535\u6c60\u6280\u672f\u5728\u4e0a\u4e2a\u4e16\u7eaa60\u5e74\u4ee3\u5f00\u59cb\u88ab\u7814\u7a76\uff0c\u867d\u7136\u7ecf\u8fc7\u4e86\u51e0\u5341\u5e74\u7684\u53d1\u5c55\uff0c\u4f46\u5374\u4e00\u76f4\u53d7\u5230\u4f4e\u653e\u7535\u5bb9\u91cf\u548c\u5bb9\u91cf\u5feb\u901f\u8870\u51cf\u7684\u95ee\u9898\u56f0\u6270\u30022009\u5e74Nazar\u7b49\u63d0\u51fa\u4e86\u4e00\u79cd\u9ad8\u5ea6\u6709\u5e8f\u7684\u4ecb\u5b54\u78b3-\u786b\u6b63\u6781\u6750\u6599\uff0c\u901a\u8fc7\u5c06\u786b\u5c01\u88c5\u5728\u4ecb\u5b54CMK-3\u4e2d\uff0c\u8fd9\u4e00\u7ed3\u6784\u4f7f\u5f97\u9502-\u786b\u7535\u6c60\u5728\u653e\u7535\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u4e0a\u53d6\u5f97\u7a81\u7834\u6027\u53d1\u5c55\u3002\u4ece\u6b64\uff0c\u9502-\u786b\u7535\u6c60\u9886\u57df\u7684\u6587\u7ae0\u5448\u73b0\u4e95\u55b7\u5f0f\u53d1\u5c55\u3002<\/p>\n

\u8fd9\u9879\u5de5\u4f5c\u7684\u4e3b\u8981\u5185\u5bb9\u4e3a<\/strong>\uff1a<\/span>\u672c\u6587\u603b\u7ed3\u9502\u786b\u7535\u6c60\u9886\u57df\u7684\u91cd\u5927\u53d1\u5c55\u3002\u9996\u5148\u662f\u9502-\u786b\u7535\u6c60\u7684\u7535\u5316\u5b66\u6982\u8ff0\uff0c\u9762\u4e34\u7684\u6280\u672f\u6311\u6218\u548c\u6f5c\u5728\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u4ee5\u53ca\u4e00\u4e9b\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u4ee5\u4fc3\u8fdb\u6211\u4eec\u5bf9\u5176\u4e2d\u6240\u6d89\u53ca\u7684\u7269\u8d28\u76f8\u4e92\u4f5c\u7528\u7684\u7406\u89e3\u3002\u5176\u6b21\uff0c\u672c\u6587\u7814\u7a76\u4e86\u6700\u5e7f\u6cdb\u4f7f\u7528\u7684\u8bbe\u8ba1\u7b56\u7565\uff1a\u5c06\u786b\u6b63\u6781\u5c01\u88c5\u5728\u78b3\u5bbf\u4e3b\u6750\u6599\u4e2d\u3002\u540c\u65f6\u5bf9\u5176\u4ed6\u65b0\u5174\u7684\u5bbf\u4e3b\u6750\u6599\uff08\u4f8b\u5982\u805a\u5408\u7269\u548c\u65e0\u673a\u6750\u6599\uff09\u8fdb\u884c\u4e86\u8ba8\u8bba\u3002\u7136\u540e\u672c\u6587\u5bf9\u65b0\u578b\u7684\u7535\u6c60\u6784\u9020\u8fdb\u884c\u4e86\u8c03\u67e5\uff08\u5305\u62ec\u786b\u5316\u9502\u6b63\u6781\u548c\u9502\u786b\u9634\u6781\u7535\u89e3\u6db2\u7684\u4f7f\u7528\uff09\uff0c\u4ee5\u53ca\u6700\u8fd1\u5728\u9694\u819c\u6539\u8fdb\u548c\u9502\u91d1\u5c5e\u8d1f\u6781\u4fdd\u62a4\u6cd5\u65b9\u9762\u7684\u52aa\u529b\u3002\u6700\u540e\uff0c\u6587\u7ae0\u5bf9\u9502-\u786b\u7535\u6c60\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\u548c\u524d\u666f\u8fdb\u884c\u4e86\u603b\u7ed3\u548c\u5c55\u671b\u3002<\/p>\n

2.Electrochemistry, challenges and solutions<\/strong><\/span><\/p>\n

\u7535\u5316\u5b66\u539f\u7406<\/strong><\/span><\/p>\n

\u9502-\u786b\u7535\u6c60\u57fa\u4e8e\u7535\u5316\u5b66\u53cd\u5e94\uff1aS8<\/sub> + 16Li2<\/sub>\u21928Li2<\/sub>S\uff0c\u8fd9\u7ed9\u4e88\u4e86\u786b\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff081673 mA h g-1<\/sup>\uff09\u3002\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u9502\u91d1\u5c5e\u9633\u6781\uff08\u8d1f\u7535\u6781\uff09\u88ab\u6c27\u5316\u5f62\u6210\u9502\u79bb\u5b50\u548c\u7535\u5b50\uff0c\u5b83\u4eec\u5206\u522b\u901a\u8fc7\u7535\u89e3\u8d28\u548c\u5916\u90e8\u7535\u8def\u5230\u8fbe\u786b\u9634\u6781\uff08\u6b63\u6781\uff09\u3002\u5728\u6b63\u6781\u4e0a\uff0c\u786b\u4e0e\u9502\u79bb\u5b50\u548c\u7535\u5b50\u53d1\u751f\u53cd\u5e94\u8fd8\u539f\u6210\u786b\u5316\u9502\u3002\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u53d1\u751f\u76f8\u53cd\u7684\u53cd\u5e94\uff08\u56fe2\uff09\u3002<\/p>\n

\"fig2\"<\/p>\n

\u56fe2\uff1a\uff08a\uff09\u9502-\u786b\u7535\u6c60\u7535\u5316\u5b66\u539f\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff09\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u7684\u9502\u786b\u7535\u6c60\uff1a\u4e00\u4e2a\u5178\u578b\u7684\u53cc\u5e73\u53f0\u5145\u7535\/\u653e\u7535\u7535\u538b\u5206\u5e03\u66f2\u7ebf\u3002<\/p>\n

\u00a0\u56fe\u4e2d\u7684\u5145\u653e\u7535\u53cd\u5e94\u770b\u4f3c\u7b80\u5355\uff0c\u5b9e\u5219\u590d\u6742\u3002\u6211\u4eec\u770b\u5230\u9502-\u786b\u7535\u6c60\u7ecf\u5386\u4e86\u56fa\u4f53-\u6db2\u4f53-\u56fa\u4f53\u8fc7\u6e21\u7684\u53cd\u5e94\uff0c\u8fd9\u662f\u975e\u5e38\u4e0d\u540c\u4e8e\u5176\u4ed6\u7535\u6c60\u7cfb\u7edf\u7684\uff0c\u8fd9\u4e5f\u662f\u9502-\u786b\u7535\u6c60\u4e3a\u4ec0\u4e48\u66f4\u5177\u6311\u6218\u6027\u7684\u539f\u56e0\u4e4b\u4e00\u3002<\/p>\n

\u00a0\u9762\u4e34\u7684\u6311\u6218<\/strong><\/span><\/p>\n

1<\/strong>\u3001\u786b\u6b63\u6781\u7684\u89d2\u5ea6<\/strong><\/span><\/p>\n

\uff08a\uff09\u4e2d\u95f4\u9502\u591a\u786b\u5316\u7269\u6eb6\u89e3\u4e8e\u7535\u89e3\u8d28\u3002\uff08b\uff09\u786b\u548c\u786b\u5316\u9502\u7684\u4f4e\u7535\u5bfc\u7387\u3002\uff08c\uff09\u786b\u5728\u9502\u5316\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u81a8\u80c0\u3002<\/p>\n

2<\/strong>\u3001\u9502\u8d1f\u6781\u7684\u89d2\u5ea6<\/strong><\/span><\/p>\n

\uff08a\uff09\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6548\u5e94\u3002\uff08b\uff09\u975e\u5747\u5300\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u3002\uff08c\uff09\u9502\u91d1\u5c5e\u7684\u679d\u6676\u751f\u957f\u3002<\/p>\n

\u89e3\u51b3\u65b9\u6848<\/strong><\/span><\/p>\n

\u9996\u5148\uff0c\u89e3\u51b3\u7684\u786b\u9634\u6781\u4fa7\u7684\u6311\u6218\u6240\u505a\u7684\u5de5\u4f5c\u3002\u5178\u578b\u7684\u7b56\u7565\u662f\u5c06\u786b\u6b63\u6781\u5206\u88c5\u5728\u5bfc\u7535\u5bbf\u4e3b\u6750\u6599\u4e2d\u4ee5\u63d0\u9ad8\u5176\u7535\u5bfc\u7387\uff0c\u4ee5\u53ca\u7269\u7406\u5730\u5c06\u9502\u591a\u786b\u5316\u7269\u9650\u5236\u5728\u5bbf\u4e3b\u6750\u6599\u5185\u3002\u5176\u4e2d\u6700\u5e38\u89c1\u7684\u5c01\u88c5\u6750\u6599\u662f\u78b3\u3002\u7136\u800c\uff0c\u78b3\u548c\u9502\u591a\u786b\u5316\u7269\uff08\u975e\u6781\u6027\u548c\u6781\u6027\uff09\u4e4b\u95f4\u6781\u6027\u7684\u5de8\u5927\u5dee\u5f02\u5bfc\u81f4\u4e86\u4e24\u8005\u4e4b\u95f4\u4ea7\u751f\u8f83\u5f31\u7684\u5316\u5b66\u7ed3\u5408\uff0c\u4ece\u800c\u524a\u5f31\u4e86\u5bf9\u591a\u786b\u5316\u7269\u7684\u6355\u6349\u6548\u679c\u3002\u5728\u8fc7\u53bb\u76843\u5e74\u4e2d\u4e5f\u5df2\u7ecf\u8bc1\u660e\u4e86\u7eaf\u78b3\u786e\u5b9e\u4e0d\u662f\u6700\u7406\u60f3\u7684\u5bbf\u4e3b\u6750\u6599\u3002\u8fd9\u5c31\u7ed9\u6211\u4eec\u5e26\u6765\u4e86\u4e00\u4e2a\u95ee\u9898\uff1a\u6211\u4eec\u5982\u4f55\u9009\u62e9\u6709\u524d\u9014\u7684\u6781\u6027\u57fa\u8d28\u6750\u6599\u5462\uff1f\u4e3a\u4e86\u63ed\u793a\u8fd9\u4e2a\u95ee\u9898\uff0c\u7814\u7a76\u4eba\u5458\u5f00\u59cb\u6c42\u52a9\u57fa\u4e8e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7684\u8ba1\u7b97\u3002<\/p>\n

3.Theoretical ab initio calculations<\/strong><\/span><\/p>\n

\u7531\u4e8e\u5176\u9ad8\u901a\u91cf\u7684\u6027\u8d28\u4f7f\u5f97\u7406\u8bba\u8ba1\u7b97\u6210\u4e3a\u4e86\u4e00\u79cd\u975e\u5e38\u5f3a\u5927\u4e14\u6709\u6548\u7684\u5e2e\u52a9\u63ed\u793a\u9502\u786b\u5316\u7269\u548c\u5404\u79cd\u6750\u6599\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u7684\u5de5\u5177\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u4ed6\u4eec\u4e3a\u6211\u4eec\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5408\u7406\u7684\u6307\u5bfc\u65b9\u9488\uff0c\u6211\u4eec\u53ef\u4ee5\u7b5b\u9009\u3001\u8bc6\u522b\u548c\u9009\u62e9\u6709\u524d\u666f\u7684\u786b\u6b63\u6781\u5c01\u88c5\u6750\u6599\u3002<\/p>\n

\"fig3\"<\/p>\n

\u56fe3\uff1a\u8868\u683c\u663e\u793aLiS\u548cLi2<\/sub>S\u4e0e\u5404\u79cd\u5b98\u80fd\u56e2\u7684\u7ed3\u5408\u80fd\u8ba1\u7b97\u7ed3\u679c\uff0c\u6309\u7167\u4e0eLIS\u7ed3\u5408\u80fd\u5927\u5c0f\u7684\u964d\u5e8f\u6392\u5217\u3002<\/p>\n

\"fig4\"<\/p>\n

\u56fe4\uff1a\u4ece\u5934\u8ba1\u7b97\u8868\u660eLiS\u7cfb\u5217\u7269\u8d28\u548c\u5bcc\u6c27\u3001\u5bcc\u6c2e\u3001\u5bcc\u786b\u7684\u5b98\u80fd\u56e2\u80fd\u5f62\u6210\u6700\u7a33\u5b9a\u7684\u7ed3\u5408\u3002<\/p>\n

\u00a0\u6211\u4eec\u6ce8\u610f\u5230\uff0c\u8fd9\u4e9b\u8ba1\u7b97\u7ed3\u679c\u662f\u4e0d\u5f7b\u5e95\u7684\uff0c\u53ea\u8ba9\u6211\u4eec\u80fd\u591f\u4e00\u7aa5\u53ef\u80fd\u7684\u5b98\u80fd\u56e2\uff0c\u7279\u522b\u662f\u7528\u4e8e\u63d0\u9ad8\u9502\u786b\/\u786b\u5316\u7269\u7ed3\u5408\u5bcc\u6c27\u3001\u5bcc\u6c2e\u548c\u5bcc\u786b\u7684\u5b98\u80fd\u56e2\u3002\u4e8b\u5b9e\u4e0a\uff0c\u8fd9\u4e9b\u90fd\u662f\u5728\u4eca\u5929\u4f7f\u7528\u7684\u4e09\u4e2a\u6700\u5e38\u89c1\u7684\u539f\u5b50\u3002\u5728\u8ba8\u8bba\u78b3\u57fa\u8d28\u6750\u6599\u3001\u5bfc\u7535\u805a\u5408\u7269\u548c\u65e0\u673a\u6750\u6599\u7684\u8fc7\u7a0b\u4e2d\uff0c\u8fd9\u4e9b\u4ece\u5934\u8ba1\u7b97\u7684\u7ed3\u679c\u4e5f\u5c06\u88ab\u603b\u7ed3\uff0c\u4ece\u800c\u6211\u4eec\u63d0\u4f9b\u4e86\u4e00\u4e2a\u8f83\u4e3a\u5b8c\u6574\u7684\u6d89\u53ca\u9502\u591a\u786b\u5316\u7269\u548c\u5404\u79cd\u6742\u539f\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u7684\u6982\u5ff5\u3002<\/p>\n

4.Carbon host materials for sulfur cathodes<\/strong><\/span><\/p>\n

2009\u5e74Nazar\u7b49\u63d0\u51fa\u4e86\u4e00\u79cd\u9ad8\u5ea6\u6709\u5e8f\u7684\u4ecb\u5b54\u78b3-\u786b\u6b63\u6781\u6750\u6599\uff0c\u901a\u8fc7\u5c06\u786b\u5c01\u88c5\u5728\u4ecb\u5b54CMK-3\u4e2d\uff0c\u8fd9\u4e00\u7ed3\u6784\u4f7f\u5f97\u9502-\u786b\u7535\u6c60\u5728\u653e\u7535\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u4e0a\u53d6\u5f97\u7a81\u7834\u6027\u53d1\u5c55\u3002\u8fd9\u9879\u5de5\u4f5c\u63a8\u52a8\u4e86\u9502-\u786b\u7535\u6c60\u9886\u57df\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u7279\u522b\u662f\u5728\u4f7f\u7528\u9ad8\u5bfc\u7535\u6027\u7684\u78b3\u6750\u6599\u5c01\u88c5\u786b\u6b63\u6781\u65b9\u9762\u3002<\/p>\n

\u4e00\u7ef4\u78b3\u6750\u6599<\/strong><\/span><\/p>\n

\uff081<\/strong>\uff09\u78b3\u7eb3\u7c73\u7ba1<\/strong><\/span><\/p>\n

\"fig5\"<\/p>\n

\u56fe5\uff1a\uff08a\uff09\u9ad8\u5ea6\u6709\u5e8f\u7684\u4ecb\u5b54\u78b3\uff08CMK-3\uff09\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\uff08b\uff09\u5728155\u2103\u4e0b\uff0c\u786b\u901a\u8fc7\u7194\u878d\u6269\u6563\u6d78\u6da6\u4e8e\u9ad8\u5ea6\u6709\u5e8f\u7684\u4ecb\u5b54\u78b3\uff08CMK-3\uff09\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\"fig6\"<\/p>\n

\u56fe6\uff1a\uff08a\uff0cb\uff09\u5782\u76f4\u6392\u5217\u78b3\u7eb3\u7c73\u7ba1\u5728\u786b\u6e17\u5165\uff08a\uff09\u524d\u548c\uff08b\uff09\u540e\u7684\u4f4e\u500d\u653e\u5927\u548c\u9ad8\u500d\u653e\u5927\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf\u3002<\/p>\n

\u00a0\u5206\u6790\uff1a<\/span>\u7531\u4e8e\u4e00\u7ef4\u7684\u78b3\u7eb3\u7c73\u7ba1\u7684\u9ad8\u7eb5\u6a2a\u6bd4\u80fd\u591f\u5f62\u6210\u76f8\u4e92\u8fde\u63a5\u7684\u7f51\u7edc\uff0c\u5e76\u8d4b\u4e88\u786b\u6b63\u6781\u6750\u6599\u957f\u7a0b\u5bfc\u7535\u6027\uff0c\u4f7f\u5b83\u4eec\u5728\u9502-\u786b\u7535\u6c60\u4e2d\u975e\u5e38\u6709\u5438\u5f15\u529b\u3002\u7136\u800c\uff0c\u786b\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u95f4\u7684\u6574\u4f53\u63a5\u89e6\u5dee\u53ef\u80fd\u9650\u5236\u7535\u6781\u7684\u653e\u7535\u5bb9\u91cf\u3002\u6709\u6548\u7684\u529e\u6cd5\u5c31\u662f\uff1a\u5229\u7528\u786b\u5728155\u2103\u4e0b\u7684\u4f4e\u7c98\u5ea6\uff0c\u901a\u8fc7\u7194\u878d\u6269\u6563\u5c06\u786b\u6d78\u6da6\u4e8e\u78b3\u7eb3\u7c73\u7ba1\u4e2d\u4ee5\u6539\u5584\u786b\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u95f4\u7684\u6574\u4f53\u63a5\u89e6\uff0c\u6216\u8005\u901a\u8fc7\u4e0d\u540c\u5f62\u6001\u7684\u78b3\u7eb3\u7c73\u7ba1\u6765\u63d0\u9ad8\u786b\u6b63\u6781\u7684\u6027\u80fd\u3002<\/p>\n

\u4f18\u70b9\uff1a\u78b3\u7eb3\u7c73\u7ba1\u80fd\u591f\u5f62\u6210\u76f8\u4e92\u8fde\u63a5\u7684\u7f51\u7edc\uff0c\u5e76\u8d4b\u4e88\u786b\u6b63\u6781\u6750\u6599\u957f\u7a0b\u5bfc\u7535\u6027\u3002<\/p>\n

\u7f3a\u70b9\uff1a\u786b\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u95f4\u7684\u6574\u4f53\u63a5\u89e6\u5dee\u53ef\u80fd\u9650\u5236\u7535\u6781\u7684\u653e\u7535\u5bb9\u91cf\u3002<\/p>\n

\u00a0\uff082<\/strong>\uff09\u7a7a\u5fc3\u78b3\u7ba1<\/strong><\/span><\/p>\n

\"fig7\"<\/p>\n

\u56fe7\uff1a\uff08a\uff0cb\uff09\u5206\u522b\u4e3aS\u5c01\u88c5\u5728\u672a\u6539\u6027\u7684\u7a7a\u5fc3\u78b3\u7ba1\u4e2d\u653e\u7535\uff081.7 V vs. Li+\/Li.\uff09\uff08a\uff09\u524d\u548c\uff08b\uff09\u540e\u7684TEM\u56fe\u3002<\/p>\n

\uff08c\uff0cd\uff09\u5206\u522b\u4e3aS\u5c01\u88c5\u5728PVP\u4fee\u9970\u7684\u7a7a\u5fc3\u78b3\u7ba1\u4e2d\u653e\u7535\uff081.7 V vs. Li+\/Li.\uff09\uff08a\uff09\u524d\u548c\uff08b\uff09\u540e\u7684TEM\u56fe\u3002<\/p>\n

\uff08a\uff09\u548c\uff08c\uff09\u56fe\u4e2d\u7684\u9ec4\u7ebf\u4ee3\u8868\u80fd\u91cf\u5f25\u6563 X \u5c04\u7ebf\u5bf9S\u7684\u626b\u63cf\u7ed3\u679c\uff0c\uff08a-d\uff09\u7684\u6bd4\u4f8b\u5c3a\u4e3a500 nm\u3002<\/p>\n

\u5206\u6790\uff1a<\/span><\/p>\n

\u7531\u4e8e\u78b3\u7eb3\u7c73\u7ba1\u7684\u76f4\u5f84\u975e\u5e38\u5c0f\u548c\u5176\u58c1\u7684\u4e0d\u6e17\u900f\u6027\uff0c\u56e0\u6b64\u5f88\u96be\u5c06\u786b\u6e17\u900f\u5230\u78b3\u7eb3\u7c73\u7ba1\u7684\u5185\u90e8\u4e2d\u7a7a\u7a7a\u95f4\u4e2d\u3002\u5728\u5927\u90e8\u5206\u7684\u5de5\u4f5c\u4e2d\u4f7f\u7528\u78b3\u7eb3\u7c73\u7ba1\uff0c\u53d1\u73b0\u786b\u53ea\u6709\u5916\u8868\u9762\u88ab\u5305\u8986\u800c\u4e0d\u662f\u91cc\u9762\uff0c\u7559\u4e0b\u786b\/\u9502\u591a\u786b\u5316\u7269\u66b4\u9732\u5728\u7535\u89e3\u8d28\u4e2d\u3002\u8fd9\u65f6\uff0c\u4f7f\u7528\u5177\u6709\u66f4\u5927\u7684\u76f4\u5f84\u7a7a\u5fc3\u78b3\u7ba1\u6765\u5c01\u88c5\u548c\u9650\u5236\u786b\/\u9502\u591a\u786b\u5316\u7269\u5c31\u663e\u5f97\u66f4\u6709\u4f18\u52bf\u3002\u4f46\u662f\u653e\u7535\u4ea7\u7269\u3001\u9502\u786b\u5316\u7269\u4ece\u7a7a\u5fc3\u78b3\u7ba1\u7684\u5185\u58c1\u5206\u79bb\u53c8\u4f1a\u5bfc\u81f4\u7535\u63a5\u89e6\u635f\u8017\u3002\u4e3a\u4e86\u7ed3\u5408\u78b3\u7eb3\u7c73\u7ba1\u548c\u76f4\u5f84\u8f83\u5927\u7684\u7a7a\u5fc3\u78b3\u7ba1\u7684\u4f18\u52bf\uff0c\u7ba1\u4e2d\u7ba1\u7ed3\u6784\u6709\u5229\u4e8e\u6539\u5584\u8fd9\u4e00\u95ee\u9898\u3002<\/p>\n

\u4f18\u70b9\uff1a\u7a7a\u5fc3\u78b3\u7ba1\u5177\u6709\u66f4\u5927\u7684\u76f4\u5f84\u6709\u5229\u4e8e\u5c01\u88c5\u548c\u9650\u5236\u786b\/\u9502\u591a\u786b\u5316\u7269\u3002<\/p>\n

\u7f3a\u70b9\uff1a\u653e\u7535\u4ea7\u7269\u3001\u9502\u786b\u5316\u7269\u4ece\u7a7a\u5fc3\u78b3\u7ba1\u7684\u5185\u58c1\u5206\u79bb\u4f1a\u5bfc\u81f4\u7535\u63a5\u89e6\u635f\u8017\u3002<\/p>\n

\uff083\uff09\u6742\u539f\u5b50\u4fee\u9970<\/strong><\/span><\/p>\n

\"fig8\"<\/p>\n

\u56fe8\uff1a\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u7ba1\/\u77f3\u58a8\u70ef\uff08N-ACNT\/G\uff09\u6df7\u5408\u652f\u67b6\u7684\uff08a\uff09\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\u3001\uff08b\uff09\u626b\u63cf\u7535\u955c\u56fe\u50cf\u548c\uff08c\uff09\u900f\u5c04\u7535\u955c\u56fe\u50cf\u3002<\/p>\n

\u00a0\u4e8c\u7ef4\u78b3\u6750\u6599<\/strong><\/span><\/p>\n

\uff081<\/strong>\uff09\u77f3\u58a8\u70ef\u548c\u6c27\u5316\u77f3\u58a8\u70ef\uff082<\/strong>\uff09\u72ec\u7279\u7684\u5f62\u6001\uff083<\/strong>\uff09\u6742\u539f\u5b50\u4fee\u9970<\/strong><\/span><\/p>\n

\u00a0<\/strong>\u57fa\u4e8e\u77f3\u58a8\u70ef\u7684\u4e8c\u7ef4\u78b3\u2013\u786b\u7ed3\u6784\u662f\u7814\u7a76\u4e3a\u6b62\u6700\u5e7f\u6cdb\u7684\u9502-\u786b\u7535\u6c60\u7cfb\u7edf\u4ee3\u8868\u4e4b\u4e00\u3002\u77f3\u58a8\u70ef\u4f18\u5f02\u7684\u7535\u5b50\u5bfc\u7535\u6027\u548c\u6613\u529f\u80fd\u5316\u7684\u7279\u70b9\u4f7f\u5b83\u6210\u4e3a\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u786b\u6b63\u6781\u5c01\u88c5\u6750\u6599\u3002\u786b\u9897\u7c92\u88c5\u8f7d\u5728\u4e8c\u7ef4\u7eb3\u7c73\u7247\u8868\u9762\uff0c\u53ef\u4ee5\u4f9d\u8d56\u4e8e\u8868\u9762\u4e0a\u7684\u5b98\u80fd\u56e2\u548c\u77f3\u58a8\u6750\u6599\u7684\u8868\u9762\u79ef\u6765\u6355\u83b7\u4e2d\u95f4\u805a\u786b\u7269\u3002
\n\"fig9\"<\/p>\n

\u56fe9\uff1a\uff08a\uff09\u4f4e\u500d\u653e\u5927\u548c\uff08b\uff09\u9ad8\u500d\u653e\u5927\u7684\u77f3\u58a8\u70ef\u5305\u8986\u786b\u590d\u5408\u6750\u6599\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf\u3002<\/p>\n

\u00a0\"fig10\"<\/p>\n

\u56fe10\uff1a\uff08a\uff09\u901a\u8fc7\u786b\u80fa\u5316\u5b66\u6cd5\u5236\u5907\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef(rGO)\u8d1f\u8f7d\u8d85\u5c0f\u578b\u7eb3\u7c73\u786b\u9897\u7c92\u7684\u5408\u6210\u793a\u610f\u56fe\u3002\uff08b\u2013f\uff09\u5206\u522b\u4e3a\u7eb3\u7c73\u786b\u9897\u7c92\u5927\u5c0f\u4e3a\uff08b\uff09150 nm\uff0c\uff08c\uff0940 nm\uff0c\uff08d\uff0920 nm\uff0c\uff08e\uff0910 nm\u548c\uff08f\uff095 nm\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf\u3002<\/p>\n

\u6587\u7ae0\u8fd8\u4e3e\u4f8b\u4e86\u6700\u8fd1\u4ee4\u4eba\u6b23\u559c\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u901a\u8fc7\u5408\u6210\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef(rGO)\u8d1f\u8f7d\u8d85\u5c0f\u578b\u7eb3\u7c73\u786b\u9897\u7c92\u6765\u8fbe\u5230S\u7684\u7406\u8bba\u5bb9\u91cf\uff0c\u4ee5\u53ca\u4e3e\u4f8b\u4e86\u51e0\u79cd\u72ec\u7279\u7684\u5f62\u6001\u7684\u77f3\u58a8\u70ef\u57fa\u7ed3\u6784\u6750\u6599\u548c\u5bf9\u77f3\u58a8\u70ef\u7684\u6742\u539f\u5b50\u4fee\u9970\u3002<\/p>\n

\u4e09\u7ef4\u78b3\u6750\u6599<\/strong><\/span><\/p>\n

\uff081<\/strong>\uff09\u591a\u5b54\u78b3\u7403<\/strong><\/span><\/p>\n

\u4e09\u7ef4\u78b3\u6750\u6599\u662f\u4f18\u826f\u7684\u5bbf\u4e3b\u6750\u6599\uff0c\u5b83\u53ef\u4ee5\u5c06\u786b\u5305\u542b\u5728\u5176\u5b54\u6d1e\u4e4b\u4e2d\u4ee5\u9650\u5236\u4e2d\u95f4\u591a\u786b\u5316\u7269\u3002\u5c06\u78b3\u7ecf\u8fc7\u9002\u5f53\u7684\u8868\u9762\u5b98\u80fd\u5316\uff0c\u786b\u6b63\u6781\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u5f97\u5230\u8fdb\u4e00\u6b65\u63d0\u9ad8\u3002\u6b64\u5916\uff0c\u5927\u5b54\u9699\u7387\u548c\u5b54\u9699\u4f53\u79ef\u7684\u591a\u5b54\u78b3\u53ef\u4ee5\u8d1f\u8f7d\u66f4\u591a\u7684\u6d3b\u6027\u6750\u6599\u4f7f\u5f97\u9762\u79ef\u5bb9\u91cf\u66f4\u9ad8\u3002\u5176\u4e2d\u6700\u5177\u4ee3\u8868\u6027\u7684\u5c01\u88c5\u6750\u6599\u5c31\u662f\u4e09\u7ef4\u591a\u5b54\u78b3\u7403\u3002<\/p>\n

\"fig11\"<\/p>\n

\u56fe11\uff1a\uff08a\uff0cb\uff09\u5206\u522b\u4e3a\u7403\u5f62\u6709\u5e8f\u4ecb\u5b54\u78b3\u7eb3\u7c73\u9897\u7c92TEM\u56fe\u50cf\uff08a\uff09\u6cbf\u67f1\u6295\u5f71\u548c\uff08b\uff09\u503e\u659c\u7684\u67f1\u72b6\u6295\u5f71\uff0c\u63d2\u56fe\u4e3a\u76f8\u5e94\u7684\u5feb\u901f\u5085\u91cc\u53f6\u53d8\u6362\u884d\u5c04\u56fe\u6848\u3002
\n\"fig12\"<\/p>\n

\u56fe12\uff1a\u5fae\u5b54\u78b3\u7403\u7684\uff08a\uff09\u4f4e\u500d\u653e\u5927\u7387\u548c\uff08b\uff09\u9ad8\u500d\u7387\u900f\u5c04\u7535\u955c\u56fe\u50cf\u3002\uff08c\uff0942 wt%\u786b\u7684\u5fae\u5b54\u78b3-\u786b\u590d\u5408\u6750\u6599\u7684\u5178\u578b\u7684\u5145\u653e\u7535\u7535\u538b\u66f2\u7ebf\uff0c\u663e\u793a\u51fa\u4e00\u4e2a\u5355\u659c\u5761\u7535\u538b\u5e73\u53f0\u3002<\/p>\n

\u4e3a\u4e86\u7ed3\u5408\u4e2d\u5b54\u548c\u5fae\u5b54\u7684\u4f18\u70b9\uff0c\u4e00\u4e9b\u7814\u7a76\u5c0f\u7ec4\u8fd8\u5f00\u53d1\u4e86\u5177\u6709\u53cc\u5cf0\u5b54\u5206\u5e03\u7684\u78b3\u7403\u3002\u4f8b\u5982\uff0c\u4e00\u4e2a\u7cbe\u5fc3\u8bbe\u8ba1\u7684\u5206\u7ea7\u591a\u5b54\u78b3\u7ed3\u6784\u2014\u2014\u5185\u90e8\u7684\u5927\u5b54\u548c\u4e2d\u5b54\u88ab\u5916\u90e8\u7684\u5fae\u5b54\u6240\u5305\u56f4\u3002\u8fd9\u79cd\u7ed3\u6784\u7684\u4f18\u70b9\u662f\uff0c\u786b\u80fd\u6ce8\u5165\u5230\u5185\u90e8\u7684\u5927\u5b54\u548c\u4e2d\u5b54\u7ed3\u6784\u4e2d\uff0c\u800c\u5916\u90e8\u8f83\u5c0f\u7684\u5fae\u5b54\u4f5c\u4e3a\u9650\u5236\u9502\u591a\u786b\u5316\u7269\u7684\u4e00\u4e2a\u7269\u7406\u5c4f\u969c\u3002<\/p>\n

\u00a0\uff082<\/strong>\uff09\u7a7a\u5fc3\u78b3\u7403<\/strong><\/span><\/p>\n

\u4e3a\u4e86\u5bb9\u7eb3\u786b\u5728\u9502\u5316\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u81a8\u80c0\uff0880%\uff09\uff0c\u5236\u5907\u7a7a\u5fc3\u78b3\u7403\u6765\u56fa\u786b\u662f\u4e00\u4e2a\u975e\u5e38\u6709\u5438\u5f15\u529b\u7684\u65b9\u6cd5\u3002\u7136\u800c\u786b\u5728\u78b3-\u786b\u590d\u5408\u6750\u6599\u4e2d\u7684\u4f4d\u7f6e\u4ecd\u7136\u4e0d\u6e05\u695a\uff1a\u5728\u5185\u90e8\u7684\u4e2d\u7a7a\u7a7a\u95f4\u6216\u5728\u591a\u5b54\u78b3\u58f3\u4e0a\u3002\u8be6\u7ec6\u7684\u7814\u7a76\u5229\u7528STEM\u548c\u5143\u7d20\u6620\u5c04\u53d1\u73b0\u867d\u7136\u7a7a\u5fc3\u78b3\u7403\u7684\u5185\u4fa7\u57fa\u672c\u5145\u6ee1\u4e86\u786b\uff0c\u4f46\u6709\u90e8\u5206\u786b\u7a7f\u8fc7\u591a\u5b54\u78b3\u58f3\u3002\u7136\u800c\uff0c\u7531\u4e8e\u786b\u5bf9\u7535\u5b50\u675f\u7684\u654f\u611f\u6027\uff0c\u4e00\u4e9b\u786b\u5728\u6d4b\u91cf\u8fc7\u7a0b\u4e2d\u5347\u534e\u4e86\u3002\u4e3a\u4e86\u514b\u670d\u8fd9\u4e2a\u95ee\u9898\uff0c\u901a\u8fc7\u7ed9\u7a7a\u5fc3\u78b3-\u786b\u590d\u5408\u6750\u6599\u5305\u8986\u4e00\u5c42\u8584\u8584\u7684\u805a\u591a\u5df4\u80fa\u4ee5\u9632\u6b62\u786b\u5347\u534e\u3002\u4f7f\u7528\u8fd9\u79cd\u7ed3\u6784\uff0c\u53ef\u4ee5\u786e\u5b9a\u786b\u66f4\u503e\u5411\u4e8e\u6269\u6563\u5230\u78b3\u7403\u7684\u5185\u90e8\u7a7a\u95f4\u4e2d\uff0c\u800c\u4e0d\u662f\u505c\u7559\u5728\u78b3\u58f3\u7684\u5b54\u6d1e\u4e2d\uff08\u56fe14\uff09\u3002\u6700\u8fd1\uff0c\u8f83\u4e3a\u65b0\u9896\u7ed3\u6784\u4e3a\u586b\u5145\u786b\u9897\u7c92\u7684\u78b3-\u786b\u86cb\u9ec4\u58f3\u7ed3\u6784\u3002
\n\"fig13\"<\/p>\n

\u56fe13\uff1a\uff08a-c\uff09\u7a7a\u5fc3\u4ecb\u5b54\u78b3\u7403\u5728\u586b\u5145\u786b\uff08a\uff09\u524d\u548c\uff08b\uff09\u540e\u7684\u900f\u5c04\u7535\u955c\u56fe\u4ee5\u53ca\uff08b\uff09\u4e2d\u590d\u5408\u6750\u6599\u7684\u80fd\u8c31\uff08EDX\uff09\u5206\u6790\u56fe
\n\"fig14\"<\/p>\n

\u56fe14\uff1a\u805a\u591a\u5df4\u80fa\u5305\u8986\u7a7a\u5fc3\u78b3-\u786b\u590d\u5408\u6750\u6599\u7684\uff08a\uff09\u4f4e\u500d\u548c\uff08b\uff09\u9ad8\u500dSTEM\u56fe\u50cf\u4ee5\u53ca\u76f8\u5e94\u7684\u4e3a\uff08c\uff09\u5355\u8d28\u786b\u548c\uff08d\uff09\u78b3\u7684\u5143\u7d20\u6620\u5c04\u3002\uff08b\uff09\u590d\u5408\u6750\u6599\u5728\u5143\u7d20\u6620\u5c04\u540e\u7684\uff08e\uff09STEM\u56fe\u50cf\u548c\uff08f\uff09X\u5c04\u7ebf\u80fd\u8c31\uff08EDX\uff09\u56fe\u3002<\/p>\n

\uff083<\/strong>\uff09\u6742\u539f\u5b50\u4fee\u9970<\/strong><\/span><\/p>\n

\u4e0e\u77f3\u58a8\u70ef\u7684\u60c5\u51b5\u7c7b\u4f3c\uff0c\u591a\u5b54\u70ad\u7684\u8868\u9762\u53ef\u91c7\u7528\u6742\u539f\u5b50\u6765\u4fee\u9970\u4ee5\u63d0\u9ad8\u5bf9\u9502\u591a\u786b\u5316\u7269\u7684\u4eb2\u548c\u529b\u3002\u5176\u4e2d\u6c2e\u63ba\u6742\u591a\u5b54\u78b3\u88ab\u8fd0\u7528\u5f97\u6700\u4e3a\u5e7f\u6cdb\u3002\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u5bf9\u9502\u79bb\u5b50\u548c\u6c2e\u63ba\u6742\u78b3\uff08\u5728\u7fa7\u57fa\u548c\u7fb0\u57fa\u4e2d\uff09\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u8fdb\u884c\u4e86\u63a2\u7a76\u3002\u53d1\u73b0\u6c2e\u63ba\u6742\u6bd4\u672a\u63ba\u6742\u7684\u60c5\u51b5\u4e0b\u663e\u8457\u63d0\u5347\u4e86\u9502\u79bb\u5b50\u7684\u5438\u9644\u80fd\u3002\u65e0\u8bba\u662f\u6c2e\u539f\u5b50\u8fd8\u662f\u6c27\u539f\u5b50\uff08\u5728\u7fa7\u57fa\u548c\u7fb0\u57fa\u4e2d\uff09\u90fd\u4e3a\u63d0\u5347\u4e0e\u9502\u79bb\u5b50\u7684\u7ed3\u5408\u80fd\u505a\u51fa\u4e86\u8d21\u732e\u3002\u867d\u7136\u7531\u4e8e\u6c27\u7684\u7535\u8d1f\u6027\u9ad8\uff0cLi\u2013O\u7ed3\u5408\u7684\u8d21\u732e\u5927\u4e8eLi\u2013N\u7ed3\u5408\u3002\u4e3a\u4e86\u5229\u7528\u8fd9\u4e9b\u5f3a\u70c8\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u6c2e\u63ba\u6742\u4ecb\u5b54\u78b3\u7403\u88ab\u5408\u6210\u5e76\u8fdb\u4e00\u6b65\u8d2f\u901a\u78b3\u7eb3\u7c73\u7ba1\u4ee5\u589e\u5f3a\u957f\u7a0b\u7535\u5b50\u5bfc\u7535\u6027\u3002\u8fd9\u79cd\u9ad8\u5bfc\u7535\u7eb3\u7c73\u7ed3\u6784\u4f5c\u4e3a\u786b\u6b63\u6781\u7684\u5c01\u88c5\u6750\u6599\u7684\u8fd0\u7528\u524d\u666f\u4ee4\u4eba\u9f13\u821e\u3002<\/p>\n

5.Polymeric host materials for sulfur cathodes<\/strong><\/span><\/p>\n

\u5bfc\u7535\u805a\u5408\u7269\u662f\u4e00\u7c7b\u5f88\u6709\u524d\u9014\u7684\u786b\u6b63\u6781\u5c01\u88c5\u6750\u6599\uff1a\uff08a\uff09\u5176\u5bfc\u7535\u6027\u6709\u5229\u4e8e\u7535\u5b50\u4f20\u5bfc\uff08b\uff09\u5f39\u6027\u548c\u7075\u6d3b\u7684\u6027\u8d28\u53ef\u4ee5\u5bb9\u7eb3\u90e8\u5206\u786b\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u53d8\u5316\uff08c\uff09\u79cd\u7c7b\u4e30\u5bcc\u7684\u5b98\u80fd\u56e2\u5bf9\u4e8e\u9502\u591a\u786b\u5316\u7269\u6709\u5f88\u5f3a\u7684\u4eb2\u548c\u529b\u3002<\/p>\n

\u4e3a\u4e86\u66f4\u597d\u5730\u9650\u5236\u591a\u786b\u5316\u7269\u548c\u63d0\u5347\u7535\u6781\u7684\u5faa\u73af\u5bff\u547d\uff0c\u4e3e\u4f8b\u5206\u6790\u4e86\u805a\u5421\u54af\uff08PPy\uff09\u3001\u805a\u567b\u5429\uff08PT\uff09\u3001\u805a\u82ef\u80fa\uff08PANI\uff09\u3001\u805a\uff083,4-\u4e59\u6491\u4e8c\u6c27\u567b\u5429\uff09\uff08PEDOT\uff09\u7b49\u5bfc\u7535\u805a\u5408\u7269\u4f5c\u4e3a\u5c01\u88c5\u6750\u6599\u7684\u4f5c\u7528\u3002\u5e76\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u5f97\u51faPEDOT\u662f\u5176\u4e2d\u6700\u4f73\u7684\u9009\u62e9\u3002<\/p>\n

\"fig15\"<\/p>\n

\u56fe15\uff1a\uff08a\u2013d\uff09\u5206\u522b\u4e3a\u805a\u82ef\u80fa\u7eb3\u7c73\u7ba1\u901a\u8fc7\u786b\u5316\u53cd\u5e94\u6e17\u786b\uff08a\u548cb\uff09\u524d\u548c\uff08c\u548cd\uff09\u540e\u7684SEM\u548cTEM\u56fe\u50cf\u3002<\/p>\n

\"fig16\"<\/p>\n

\u56fe16\uff1a\uff08a\uff09\u5bfc\u7535\u805a\u5408\u7269\u5305\u88f9\u7a7a\u5fc3\u786b\u7eb3\u7c73\u7c92\u5b50\u7684\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\u3002\uff08b\u548cc\uff09\u6d82\u5c42\u4e4b\u524d\u7684SEM\u548cTEM\u56fe\u50cf\uff0c\u4ee5\u53ca\u5305\u8986\uff08d\u548ce\uff09PPY\u3001\uff08f\uff09PEDOT\u548c\uff08g\uff09PANI\u7684SEM\u6216TEM\u56fe\u50cf\u3002\u63d2\u56fe\uff08e\u2013g\uff09\u7528\u7532\u82ef\u6eb6\u89e3\u786b\u540e\u663e\u793a\u51fa\u7684\u805a\u5408\u7269\u58f3\uff08RT\uff1a\u5ba4\u6e29\uff09\u3002<\/p>\n

6.Inorganic host materials for sulfur cathodes<\/strong><\/span><\/p>\n

\u65e0\u673a\u6750\u6599\u662f\u4e00\u7c7b\u6781\u6709\u5438\u5f15\u529b\u7684\u786b\u6b63\u6781\u5bbf\u4e3b\u6750\u6599\uff0c\u8fd9\u662f\u7531\u4e8e\u5b83\u4eec\u7684\u8bb8\u591a\u5305\u62ec\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u6c2e\u5316\u7269\u548c\u786b\u5316\u7269\uff0c\u5176\u672c\u8eab\u542b\u6709\u4e30\u5bcc\u7684\u6c2e\u3001\u6c27\u3001\u786b\u539f\u5b50\u5bf9\u4e8e\u9502\u591a\u786b\u5316\u7269\u5177\u6709\u5f88\u5f3a\u7684\u4eb2\u548c\u529b\u3002
\n\"fig17\"<\/p>\n

\u56fe17\uff1a\uff08a\uff09\u786b-\u6c27\u5316\u949b\u86cb\u9ec4-\u58f3\u7eb3\u7c73\u7ed3\u6784\u7684\u5408\u6210\u793a\u610f\u56fe\uff08b\uff09SEM\u56fe\uff08c\uff09TEM\u56fe\uff0c\uff08b\uff09\u548c\uff08c\uff09\u4e2d\u7684\u6bd4\u4f8b\u5c3a\u5206\u522b\u4e3a2 mm\u548c1 mm\u3002
\n\"fig18\"<\/p>\n

\u56fe18\uff1a\uff08a\u2013i\uff09\u5206\u522b\u4e3aX\u5c04\u7ebf\u884d\u5c04\u56fe\u3001\u900f\u5c04\u7535\u955c\u56fe\u3001\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c\u56fe\uff08a\u2013c\uff09\u91d1\u7ea2\u77f3\u7ed3\u6784TiO2<\/sub>\u7eb3\u7c73\u7ba1\uff08d\u2013f\uff09Magne\u00b4li\u76f8Ti6<\/sub>O11<\/sub>\u7eb3\u7c73\u7ebf\u548c\uff08g\u2013i\uff09Magne\u00b4li\u76f8Ti4<\/sub>O7<\/sub>\u7eb3\u7c73\u7c92\u5b50\u3002\uff08b, e \u548ch\uff09\u4e2d\u7684\u63d2\u56fe\u4e3a\u7c89\u672b\u7684\u6570\u5b57\u7167\u7247\u548c\uff08c, f \u548c i\uff09\u4e2d\u7684\u63d2\u56fe\u4e3a\u5feb\u901f\u5085\u91cc\u53f6\u53d8\u6362\u663e\u793a\u76f8\u5e94\u7684\u884d\u5c04\u56fe\u6848\u3002<\/p>\n

\"fig19\"<\/p>\n

\u56fe19\uff1a\uff08a\uff09Li2<\/sub>S4<\/sub>\u548cTi4<\/sub>O7<\/sub>\u95f4\u7535\u5b50\u5bc6\u5ea6\u8f6c\u79fb\u793a\u610f\u56fe\uff0c\uff08b\uff09\u4e2d\u88c5\u6709\uff081\uff09Li2<\/sub>S4<\/sub>\u56db\u6c22\u544b\u5583\u6eb6\u6db2\u4e0e\uff082\uff09\u77f3\u58a8\u70ef\u3001\uff083\uff09VC\u78b3\u4ee5\u53ca\uff084\uff09Ti4<\/sub>O7<\/sub>\u76f4\u63a5\u63a5\u89e6\u540e\u7684\u5bc6\u5c01\u74f6\uff0c\uff08c\uff09\u4e2d\u88c5\u6709\uff081\uff09Li2<\/sub>S4<\/sub>\u56db\u6c22\u544b\u5583\u6eb6\u6db2\u4e0e\uff082\uff09\u77f3\u58a8\u70ef\u3001\uff083\uff09VC\u78b3\u4ee5\u53ca\uff084\uff09Ti4<\/sub>O7<\/sub>\u6405\u62cc1\u5c0f\u65f6\u540e\u7684\u5bc6\u5c01\u74f6<\/p>\n

\u00a07<\/strong>\uff0eLithium sulfide cathodes<\/strong><\/span><\/p>\n

\u6700\u8fd1\uff0c\u786b\u5316\u9502\u6b63\u6781\u7531\u4e8e\u5176\u6709\u7406\u60f3\u7684\u9884\u9502\u5316\u6027\u548c\u9ad8\u7406\u8bba\u6bd4\u5bb9\u91cf(1166 mA h g-1<\/sup>)\u800c\u6210\u4e3a\u4e00\u65b0\u5174\u7684\u53d1\u5c55\u65b9\u5411\u3002\u56e0\u4e3a\u786b\u5316\u9502\u5728\u5176\u5b8c\u5168\u9502\u5316\u72b6\u6001\uff08\u4e0d\u50cf\u786b\uff09\u4e0b\uff0c\u5b83\u53ef\u4ee5\u642d\u914d\u975e\u9502\u91d1\u5c5e\u8d1f\u6781\u6750\u6599\uff08\u4f8b\u5982\u7845\u6216\u9521\uff09\u4ece\u800c\u89c4\u907f\u91d1\u5c5e\u9502\u679d\u6676\u7684\u5f62\u6210\u4ee5\u53ca\u76f8\u5173\u7684\u5b89\u5168\u95ee\u9898\u3002\u9664\u4e86\u5b83\u4e0e\u975e\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u517c\u5bb9\u6027\uff0c\u4f7f\u7528\u786b\u5316\u9502\uff08\u800c\u975e\u786b\uff09\u4f5c\u4e3a\u6b63\u6781\u6750\u6599\u8fd8\u6709\uff1a<\/p>\n

\uff08a\uff09\u4e0e\u786b\u5728\u9502\u5316\u8fc7\u7a0b\u4e2d\u4f53\u79ef\u81a8\u80c080%\u4e0d\u540c\uff0c\u786b\u5316\u9502\u5904\u4e8e\u786b\u5145\u5206\u81a8\u80c0\u72b6\u6001\u3002\u56e0\u6b64\uff0c\u786b\u5316\u9502\u5728\u6700\u521d\u7684\u8131\u9502\u8fc7\u7a0b\u4e2d\u6536\u7f29\u4ee5\u4ea7\u751f\u7a7a\u95f4\u6765\u5bb9\u7eb3\u968f\u540e\u9502\u5316\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u81a8\u80c0\u3002\u8fd9\u4e0d\u4ec5\u6709\u52a9\u4e8e\u51cf\u8f7b\u5bf9\u6574\u4e2a\u7535\u6781\u7684\u7ed3\u6784\u635f\u4f24\uff0c\u800c\u4e14\u8fd8\u6d88\u9664\u4e86\u6709\u610f\u521b\u5efa\u5185\u90e8\u7a7a\u9699\u7a7a\u95f4\u7684\u9700\u8981\uff0c\u4ece\u800c\u5927\u5927\u7b80\u5316\u4e86\u5408\u6210\u8fc7\u7a0b\u3002<\/p>\n

\uff08b\uff09\u786b\u5316\u9502\uff08938\u2103\uff09\u76f8\u6bd4\u786b\uff08115\u2103\uff09\u5177\u6709\u66f4\u9ad8\u7684\u7194\u70b9\u3002\u7531\u4e8e\u5728\u78b3\u5316\u8fc7\u7a0b\u901a\u5e38\u53d1\u751f\u5728\u9ad8\u6e29\u4e0b\uff0c\u8fd9\u4f7f\u5f97\u9502\u786b\u2013\u78b3\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u66f4\u6613\u4e8e\u5904\u7406\u3002<\/p>\n

\uff081<\/strong>\uff09\u6fc0\u6d3b\u8fc7\u7a0b<\/strong><\/span><\/p>\n

\"fig20\"<\/p>\n

\u56fe20\uff1a\u786b\u5316\u9502\u6b63\u6781\u524d\u4e09\u6b21\u5145\u653e\u7535\u7535\u538b\u66f2\u7ebf\uff0c\u53ef\u4ee5\u770b\u51fa\u5728\u9996\u6b21\u5faa\u73af\u4e2d\u6709\u7ea63.5V\uff08vs. Li+\/Li\uff09\u7684\u52bf\u5792\u8981\u514b\u670d\u3002<\/p>\n

\u00a0\uff082<\/strong>\uff09\u63a5\u4e0b\u6765\u63cf\u8ff0\u4e86\u7528\u78b3\u6750\u6599\u3001\u5bfc\u7535\u805a\u5408\u7269\u4ee5\u53ca\u65e0\u673a\u6750\u6599\u6700\u4e3a\u786b\u5316\u9502\u6b63\u6781\u5c01\u88c5\u6750\u6599\u7684\u6700\u65b0\u8fdb\u5c55\u3002<\/strong><\/span><\/p>\n

\"fig21\"<\/p>\n

\u56fe21\uff1a\uff08a\uff092 mm\uff0c\uff08b\uff091 mm\u548c\uff08c\uff09500nm\u7684\u786b\u5316\u9502\u7c92\u5b50\u5355\u5206\u6563SEM\u56fe\u50cf\u548c\uff08d\u2013f\uff09\u91c7\u7528\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u78b3\u5c42\u540e\u76f8\u5e94\u7684\u6838\u5fc3\u2013\u58f3\u7ed3\u6784\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\"fig22\"<\/p>\n

\u56fe22\uff1a\uff08a-c\uff09Li2<\/sub>S\u2013TiS2<\/sub>\u6838\u5fc3\u2013\u58f3\u7eb3\u7c73\u7ed3\u6784\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\uff0c\uff08b\uff09\u626b\u63cf\u7535\u955c\u56fe\u50cf\u548c\uff08c\uff09\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u56fe\u50cf\u3002\uff08b\uff09\u548c\uff08c\uff09\u4e2d\u6bd4\u4f8b\u5c3a\u5206\u522b\u4e3a5 mm\u548c500 nm\uff08RT\uff1a\u5ba4\u6e29\uff09\u3002<\/p>\n

8.Lithium polysulfide catholytes<\/strong><\/span><\/p>\n

\uff081<\/strong>\uff09\u78b3\u5bbf\u4e3b\u6750\u6599<\/strong><\/span><\/p>\n

\u4e0e\u4f7f\u7528\u56fa\u786b\u6216\u786b\u5316\u9502\u6b63\u6781\u4e0d\u540c\u7684\u662f\uff0c\u78b3\u5bbf\u4e3b\u6750\u6599\u4e5f\u53ef\u4ee5\u4f7f\u7528\u6eb6\u89e3\u7684\u9502\u786b\u4e8c\u4ef7\u91d1\u5c5e\u79bb\u5b50\u4f5c\u4e3a\u8d77\u59cb\u6750\u6599\u4ee5\u53ca\u5c06\u5bfc\u7535\u591a\u5b54\u57fa\u6750\u4e3a\u4e3b\u4f53\u6750\u6599\u3002\u8fd9\u79cd\u7ed3\u6784\u4e0d\u4ec5\u4f7f\u6eb6\u89e3\u7684\u9502\u591a\u786b\u5316\u7269\u548c\u591a\u5b54\u57fa\u677f\u63a5\u89e6\u7d27\u5bc6\uff0c\u800c\u4e14\u907f\u514d\u4e86\u4eceS8<\/sub>\u5230Li2<\/sub>S8<\/sub>\u7684\u521d\u59cb\u56fa-\u6db2\u76f8\u53d8\uff0c\u8fd9\u6709\u671b\u52a0\u5feb\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u63d0\u9ad8\u786b\u7684\u5229\u7528\u7387\u3002<\/p>\n

\u00a0\uff082<\/strong>\uff09\u6742\u539f\u5b50\u4fee\u9970<\/strong><\/span><\/p>\n

\u4e0e\u786b\u548c\u786b\u5316\u9502\u6b63\u6781\u7c7b\u4f3c\uff0c\u6eb6\u89e3\u4e86\u9502\u7684\u591a\u786b\u5316\u7269\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u4e5f\u53ef\u4ee5\u7528\u6742\u539f\u5b50\u4fee\u9970\u78b3\u4e3b\u4f53\u6750\u6599\u589e\u5f3a\uff0c\u4f8b\u5982\uff0c\u5229\u7528\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\u7eb8\u7b49\u3002<\/p>\n

9.Modification of separators<\/strong><\/span><\/p>\n

\uff081\uff09\u78b3\u5143\u7d20\u4fee\u9970\uff1b\uff082<\/strong>\uff09\u805a\u5408\u7269\u4fee\u9970\uff1b\uff083<\/strong>\uff09\u65e0\u673a\u7269\u4fee\u9970<\/strong><\/span><\/p>\n

\"fig23\"<\/p>\n

\u56fe23\uff1a\uff08a\uff09\u901a\u8fc7\u591a\u786b\u5316\u7269\u6b63\u6781\u7535\u89e3\u6db2\u5c06ITO\u5fae\u6a21\u578b\u6c89\u79ef\u5728\u73bb\u78b3\u57fa\u5e95\u7684\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\uff0c\u663e\u793a\u591a\u786b\u5316\u7269\u7684\u6c89\u79ef\u6027\u8d28\u3002\uff08b\uff09\u4e00\u4e2a\u65b0\u7684ITO\u5fae\u6a21\u578b\u7684\u626b\u63cf\u7535\u955c\u56fe\uff0c\uff08c\uff09ITO\u5fae\u6a21\u578b\u5728\u591a\u786b\u5316\u7269\u6b63\u6781\u7535\u89e3\u6db2\u7684\u626b\u63cf\u7535\u955c\u56fe\u3002\uff08b\u548cc\uff09\u7684\u6bd4\u4f8b\u5c3a\u662f20 mm\u3002\uff08d\uff09\u653e\u7535\u81f31.7 V\uff08vs. Li+\/Li.\uff09\u65f6\u7684\u78b3\u3001\u94df\u548c\u786b\u7684\u5143\u7d20\u6620\u5c04\u548c\uff08e\uff09\u5145\u7535\u81f32.6 V\uff08vs. Li+\/Li.\uff09\u65f6\u7684\u78b3\u3001\u94df\u548c\u786b\u7684\u5143\u7d20\u6620\u5c04\uff0c\uff08d\u548ce\uff09\u7684\u6bd4\u4f8b\u5c3a\u662f50mm\u3002<\/p>\n

\"fig24\"<\/p>\n

\u56fe24\uff1a\uff08a\uff09\u5728\u786b\u6b63\u6781\u548c\u9694\u819c\u4e4b\u95f4\u63d2\u5165\u4e00\u4e2a\u5fae\u5b54\u78b3\u5c42\u7684\u9502-\u786b\u7535\u6c60\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff09\u5fae\u5b54\u78b3\u5c42\u8868\u9762\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf\u3002\u6bd4\u4f8b\u5c3a\u4e3a\u4e3a500 nm\u3002<\/p>\n

\u00a0\u5206\u6790\uff1a<\/strong><\/span>\u72ec\u7acb\u7684\u78b3\u5c422\u4e2a\u91cd\u8981\u7684\u529f\u80fd\uff1a\uff08a\uff09\u5e2e\u52a9\u9650\u5236\u9502\u786b\u5316\u7269\u5728\u786b\u6b63\u6781\u4fa7\uff0c\u9632\u6b62\u5176\u6269\u6563\u5230\u8d1f\u6781\uff08b\uff09\u4f5c\u4e3a\u4e0a\u96c6\u6d41\u4f53\u4ee5\u63d0\u9ad8\u6d3b\u6027\u7269\u8d28\u5229\u7528\u7387\u3002
\n10. Lithium metal anodes<\/strong><\/span><\/p>\n

\u9502\u591a\u786b\u5316\u7269\u5728\u919a\u57fa\u7535\u89e3\u8d28\u4e2d\u7684\u6eb6\u89e3\u5ea6\u9ad8\uff0c\u8fd9\u4f7f\u5f97\u9502\u91d1\u5c5e\u8d1f\u6781\u7279\u522b\u5bb9\u6613\u53d7\u5230\u6eb6\u89e3\u7684\u786b\u5316\u7269\u7684\u4f24\u5bb3\uff0c\u5e38\u5e38\u5bfc\u81f4\u7a7f\u68ad\u6548\u5e94\u548c\u7535\u6781\u7684\u5e93\u4ed1\u6548\u7387\u53d8\u4f4e\u3002\u5728\u8fd9\u4e00\u90e8\u5206\u56de\u987e\u4e86\u5728\u4fdd\u62a4\u9502\u91d1\u5c5e\u8d1f\u6781\u514d\u53d7\u6eb6\u89e3\u7684\u786b\u5316\u7269\u7684\u635f\u5bb3\u548c\u4e13\u95e8\u9488\u5bf9\u7f13\u89e3\u9502\u786b\u7535\u6c60\u4e2d\u7a7f\u68ad\u6548\u5e94\u6240\u505a\u7684\u52aa\u529b\u3002\u8fd9\u4e9b\u4fdd\u62a4\u7b56\u7565\u53ef\u4ee5\u5206\u4e3a\u539f\u4f4d\u548c\u975e\u539f\u4f4d\u65b9\u6cd5\u3002<\/p>\n

\u00a0\uff081<\/strong>\uff09\u539f\u4f4d\u4fdd\u62a4\u6cd5<\/strong><\/span><\/p>\n

\u4fdd\u62a4\u9502\u91d1\u5c5e\u8d1f\u6781\u8868\u9762\u514d\u53d7\u6eb6\u89e3\u7684\u786b\u5316\u7269\u7684\u635f\u5bb3\u7684\u65b9\u6cd5\u4e4b\u4e00\u662f\u4f7f\u7528\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u5f62\u6210\u539f\u4f4d\u7684\u949d\u5316SEI\u819c\u3002\u5728\u8fd9\u4e00\u9886\u57df\u7684\u4e3b\u8981\u7a81\u7834\u662f\u785d\u9178\u9502\u7684\u53d1\u73b0\uff08LiNO3<\/sub>\uff09\u3002\u5728\u8fd9\u4e4b\u4e2d\uff0cLiNO3<\/sub>\u4e3b\u8981\u626e\u6f14\u7740\u4e24\u79cd\u89d2\u8272\uff08a\uff09\u5b83\u4f1a\u8fd8\u539f\u5f62\u6210Lix<\/sub>NOy<\/sub> \u7c7b\u7269\u8d28\uff1b\uff08b\uff09\u5b83\u80fd\u6c27\u5316\u786b\u5316\u7269\uff08\u5728\u6eb6\u6db2\u548c\u8868\u9762\u4e0a\uff09\u5f62\u6210Lix<\/sub>SOy<\/sub>\u7c7b\u7269\u8d28\u3002\u8fd9\u4e24\u8005\u90fd\u6709\u52a9\u4e8e\u4f7f\u9502\u91d1\u5c5e\u8868\u9762\u949d\u5316\u4ee5\u62b5\u5fa1\u6eb6\u89e3\u7684\u9502\u591a\u786b\u5316\u7269\uff0c\u4ece\u800c\u51cf\u5f31\u7a7f\u68ad\u6548\u5e94\u5f71\u54cd\u5e76\u5408\u7406\u63d0\u5347\u9ad8\u5e93\u4ed1\u6548\u7387\uff08\u4e00\u822c\u4e3a90\u523098%\uff09\u3002\u7136\u800c\uff0cLiNO3<\/sub>\u662f\u4e00\u79cd\u5f3a\u6c27\u5316\u5242\uff0c\u5728\u9ad8\u6d53\u5ea6\u548c\u9ad8\u6e29\u4e0b\u5177\u6709\u7206\u70b8\u6027\uff0c\u4ece\u800c\u5bfc\u81f4\u5b89\u5168\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u79d1\u7814\u4eba\u5458\u4e5f\u5728\u7ee7\u7eed\u7814\u7a76\u66f4\u5b89\u5168\u7684\u6dfb\u52a0\u5242\uff0c\u4e94\u786b\u5316\u4e8c\u78f7\uff08P2<\/sub>S5<\/sub>\uff09\u5c31\u662f\u5176\u4e2d\u4e4b\u4e00\uff0c\u5b83\u80fd\u5bf9\u5728\u9502\u91d1\u5c5e\u8868\u9762\u5f62\u6210\u4e00\u4e2aLi3<\/sub>PS4<\/sub>\u7684SEI\u4fdd\u62a4\u819c\u3002<\/p>\n

\u00a0\uff082<\/strong>\uff09\u975e\u539f\u4f4d\u4fdd\u62a4\u6cd5<\/strong><\/span><\/p>\n

\u975e\u539f\u4f4d\u4fdd\u62a4\u6cd5\u4e0e\u539f\u4f4d\u6cd5\u4e0d\u540c\uff0c\u5b83\u662f\u5728\u9502\u91d1\u5c5e\u8868\u9762\u5916\u5f62\u6210\u4e00\u4e2a\u7269\u7406\u4fdd\u62a4\u819c\u3002\u4f8b\u5982\uff0c\u653e\u7f6e\u9502\u8d1f\u6781\u548c\u9694\u819c\u4e4b\u95f4\u7684\u77f3\u58a8\u8584\u819c\u53ef\u4ee5\u5e2e\u52a9\u51cf\u5c11\u91d1\u5c5e\u9502\u548c\u6eb6\u89e3\u7684\u786b\u5316\u7269\u4e4b\u95f4\u7684\u76f4\u63a5\u63a5\u89e6\u7b49\u3002<\/p>\n

\"fig25\"<\/p>\n

\u56fe25\uff1a\u94a0\u91d1\u5c5e\u6b63\u6781\u57281 M NaPF6\u7684\u4e8c\u7518\u9187\u4e8c\u7532\u919a\u6eb6\u6db2\u4e2d\u5faa\u73af\u57280.5 mA cm-2 <\/sup>\u548c1 mA h cm-2<\/sup>\u7684\uff08a\uff09\u7535\u9540-\u5265\u79bb\u7684\u5e93\u4ed1\u6548\u7387\u56fe\uff08b\u548cc\uff09\u5206\u522b\u4e3a\u94a0\u91d1\u5c5e\u6b63\u6781\u7684\u4f4e\u500d\u653e\u5927\u548c\u9ad8\u653e\u5927\u500d\u7387\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u00a011.Prospects and outlook<\/strong><\/span><\/p>\n

\u00a0<\/strong>\u4f5c\u8005\u6587\u7ae0\u5728\u8fd9\u4e00\u90e8\u5206\u5bf9\u4ee5\u4e0b5\u5404\u65b9\u9762\u63d0\u51fa\u4e86\u81ea\u5df1\u7684\u89c2\u70b9\u548c\u5c55\u671b<\/p>\n

\uff081\uff09\u73b0\u6709\u7684\u548c\u65b0\u5174\u7684\u5bbf\u4e3b\u6750\u6599<\/p>\n

\uff082\uff09\u5148\u8fdb\u7684\u8868\u5f81\u624b\u6bb5\u548c\u7535\u89e3\u8d28\u7684\u53d1\u5c55<\/p>\n

\uff083\uff09\u9502\u91d1\u5c5e\u4e0e\u975e\u91d1\u5c5e\u9633\u6781<\/p>\n

\uff084\uff09\u4f18\u5316\u548c\u5546\u4e1a\u5316<\/p>\n

\uff085\uff09\u5ba4\u6e29\u94a0-\u786b\u7535\u6c60<\/p>\n

\u00a012.Conclusion<\/strong><\/span><\/p>\n

\u00a0<\/strong>\u8fd1\u5e74\u6765\uff0c\u4eba\u4eec\u5bf9\u9ad8\u80fd\u9502\u786b\u7535\u6c60\u7684\u53d1\u5c55\u4ea7\u751f\u4e86\u65b0\u7684\u5174\u8da3\u3002\u5927\u91cf\u901a\u8fc7\u5404\u79cd\u78b3\u6750\u6599\u3001\u805a\u5408\u7269\u548c\u65e0\u673a\u6750\u6599\u6765\u8bbe\u8ba1\u65b0\u9896\u7684\u786b\u6b63\u6781\u7684\u7814\u7a76\u6210\u679c\u7684\u63d0\u51fa\u5c31\u8bc1\u660e\u4e86\u8fd9\u4e00\u70b9\u3002\u7136\u800c\uff0c\u8981\u5b9e\u73b0\u4e00\u4e2a\u91cd\u5927\u7684\u7a81\u7834\uff0c\u5c31\u5fc5\u987b\u5c3d\u5feb\u5145\u5206\u4e86\u89e3\u9502\u2013\u786b\u7535\u6c60\u7684\u57fa\u7840\u7535\u5316\u5b66\u548c\u9502\u786b\u5316\u7269\u4e0e\u73b0\u6709\u7684\u548c\u65b0\u5174\u7684\u5bbf\u4e3b\u6750\u6599\u4e4b\u95f4\u76f8\u4e92\u4f5c\u7528\u3002\u5728\u8fd9\u4e2a\u65b9\u5411\u4e0a\u7684\u8fdb\u5c55\u53ef\u4ee5\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u548c\u5b9e\u9a8c\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\u3002\u4e3a\u4e86\u8ddf\u4e0a\u786b\u6b63\u6781\u4fa7\u7684\u5feb\u901f\u8fdb\u5c55\uff0c\u9700\u8981\u5bf9\u9502\u8d1f\u6781\u65b9\u5411\u505a\u51fa\u76f8\u540c\u7684\u52aa\u529b\u4ee5\u53d1\u6325\u9502-\u786b\u7535\u6c60\u7684\u5168\u90e8\u6f5c\u80fd\u3002\u603b\u4f53\u800c\u8a00\uff0c\u968f\u7740\u5bf9\u7535\u6781\u8fdb\u4e00\u6b65\u7684\u4e86\u89e3\u548c\u4f18\u5316\u8bbe\u8ba1\uff0c\u53ef\u4ee5\u8bbe\u60f3\u5728\u4e0d\u4e45\u7684\u5c06\u6765\u53d1\u5c55\u5546\u4e1a\u5316\u9502-\u786b\u7535\u6c60\u3002\u8fd9\u4e9b\u9ad8\u80fd\u91cf\u7535\u6c60\u5728\u4f17\u591a\u7684\u6e05\u6d01\u80fd\u6e90\u65b9\u9762\u7684\u5e94\u7528\u2014\u2014\u4ece\u7535\u7f51\u50a8\u80fd\u5230\u7535\u52a8\u6c7d\u8f66\u7684\u6210\u529f\u5e94\u7528\u2014\u2014\u5c06\u6709\u52a9\u4e8e\u6211\u4eec\u521b\u9020\u4e00\u4e2a\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u793e\u4f1a\u3002<\/p>\n

\u00a0\u5c0f\u7f16\u603b\u7ed3\uff1a<\/span>\u672c\u6587\u4ece\u9502-\u786b\u7535\u6c60\u7684\u591a\u4e2a\u89d2\u5ea6\u6c47\u603b\u4e86\u4e0e\u6b63\u6781\u3001\u8d1f\u6781\u3001\u9694\u819c\u7b49\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u53ca\u5176\u610f\u4e49\u5e76\u8be6\u7ec6\u7684\u9610\u8ff0\uff0c\u53ef\u4ee5\u8bf4\u662f\u4e00\u7bc7\u76f8\u5f53\u597d\u7684\u5173\u4e8e\u9502-\u786b\u7535\u6c60\u7684\u6587\u7ae0\uff0c\u975e\u5e38\u503c\u5f97\u5b66\u4e60\u3002\u7531\u4e8e\u6587\u7ae0\u7684\u6bcf\u4e2a\u90e8\u5206\u5185\u5bb9\u4e30\u5bcc\uff0c\u518d\u52a0\u4e0a\u5c0f\u7f16\u7684\u80fd\u529b\u6709\u9650\uff0c\u56e0\u6b64\u53ea\u662f\u5bf9\u5176\u8fdb\u884c\u4e86\u9ad8\u5ea6\u603b\u7ed3\uff0c\u66f4\u52a0\u8be6\u7ec6\u5185\u5bb9\u8fd8\u9700\u8981\u5404\u4f4d\u8bfb\u8005\u81ea\u884c\u54c1\u5473\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDesigning high-energy lithium\u2013sulfur batteries<\/a>\uff08Chem. Soc. Rev.\uff0c2016\uff0cDOI: 10.1039\/C5CS00410A\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 \u80cc\u9006\u65f6\u5149 \u4f9b\u7a3f\uff0c\u70b9\u8fd9\u91cc<\/a>\u52a0\u5165\u6211\u4eec\u3002\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002<\/p>\n

<\/p>\n","protected":false},"excerpt":{"rendered":"

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