{"id":35237,"date":"2016-08-23T08:00:13","date_gmt":"2016-08-23T00:00:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=35237"},"modified":"2016-08-22T14:19:18","modified_gmt":"2016-08-22T06:19:18","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81-amjacs%e7%ad%89%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6mof%e6%9d%90%e6%96%99%e6%9c%80%e6%96%b0%e7%a0%94%e7%a9%b6%e8%bf%9b%e5%b1%95%e7%b2%be","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=35237","title":{"rendered":"\u9876\u520a\u52a8\u6001 | AM\/JACS\u7b49\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOF)\u6750\u6599\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u7cbe\u9009\u3010\u7b2c8\u671f\u3011"},"content":{"rendered":"

1\u3001Adv. Mater. MOF\u884d\u751f\u7684\u4e0d\u542b\u8d35\u91d1\u5c5e\u7684\u8702\u7a9d\u72b6\u50ac\u5316\u5242\u7528\u4e8e\u6c27\u7684\u9ad8\u6548\u7535\u8fd8\u539f<\/strong><\/p>\n

\u6c27\u7535\u89e3\u8fd8\u539f\uff08ORR\uff09\u5728\u9ad8\u5206\u5b50\u7535\u89e3\u8d28\u71c3\u6599\u7535\u6c60\u7684\u9634\u6781\u4e0a\u662f\u975e\u5e38\u91cd\u8981\u7684\u8fc7\u7a0b\u3002\u9ad8\u6548\u7684\u6c27\u7535\u89e3\u8fd8\u539f\u50ac\u5316\u5242\u5bf9\u4e8e\u71c3\u6599\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u662f\u975e\u5e38\u5fc5\u7136\u7684\u3002Pt\u6750\u6599\u88ab\u8ba4\u4e3a\u662fORR\u7535\u50ac\u5316\u5242\u4e2d\u6700\u4e3a\u9ad8\u6548\u7684\uff0c\u7136\u800c\u7531\u4e8e\u9ad8\u6602\u7684\u6210\u672c\u548c\u94c2\u91d1\u5c5e\u7684\u7a00\u7f3a\u6027\u4e25\u91cd\u963b\u788d\u4e86\u8bf8\u5982\u6e05\u6d01\u80fd\u6e90\u5e94\u7528\u7684\u5e7f\u6cdb\u63a8\u5e7f\u3002\u63ba\u6742N \u6216 S\u7684\u78b3\u6750\u6599\u5f15\u5165\u8fc7\u6e21\u91d1\u5c5e\u540e\uff0c\u7531\u4e8e\u591a\u79cd\u6d3b\u6027\u7269\u8d28\u7684\u534f\u540c\u4f5c\u7528\u4f1a\u6539\u5584ORR\u50ac\u5316\u5242\u6d3b\u6027\u3002<\/p>\n

\u65e5\u672c\u4ea7\u4e1a\u6280\u672f\u7efc\u5408\u7814\u7a76\u6240\uff08AIST\uff09\u5f90\u5f3a\u6559\u6388\u548c\u5317\u4eac\u5927\u5b66\u5de5\u5b66\u9662\u7279\u8058\u7814\u7a76\u5458\u90b9\u5982\u5f3a\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u9996\u6b21\u62a5\u9053\u4e86N\u548c S\u53cc\u63ba\u6742\u7684\u8702\u7a9d\u72b6\u591a\u5b54\u77f3\u58a8\uff0c\u5e76\u56fa\u5316\u4e86\u7531MOF\u884d\u751f\u7684Co9S8 \u5316\u5408\u7269\u3002\u7531\u4e8e\u7279\u6b8a\u7684\u7eb3\u7c73\u7ed3\u6784\u548c\u8fd9\u4e9b\u6d3b\u6027\u7ec4\u5206\u7684\u534f\u540c\u4f5c\u7528\uff0c\u4f7f\u5f97\u5230\u7684\u590d\u5408\u7269\u6210\u4e3a\u6c27\u7535\u8fd8\u539f\u7684\u4f18\u826f\u50ac\u5316\u5242\u3002\u540c\u65f6\u8be5\u7814\u7a76\u7ec4\u63d0\u4f9b\u4e86\u53ef\u63a7\u548c\u591a\u5143\u6d3b\u6027\u7269\u8d28\u4fee\u9970\u7684\u591a\u5b54\u78b3\u7eb3\u7c73\u6750\u6599\u7684\u5408\u6210\uff0c\u4ee5\u5e94\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u53ca\u5176\u5b83\u79d1\u6280\u8bbe\u5907\u3002<\/p>\n

\"\u56fe\u724711\"<\/p>\n

\u56fe1<\/strong> \u57fa\u4e8eMOF\u7684Co9S8@CNST \u50ac\u5316\u5242\u5236\u5907<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Metal-Organic Framework-Derived Honeycomb-Like Open\u00a0Porous Nanostructures as Precious-Metal-Free Catalysts for Highly Efficient Oxygen Electroreduction<\/a> (Adv. Mater.\uff0c2016\uff0cDOI: 10.1002\/adma.201600979)<\/p>\n

2\u3001J. Am. Chem. Soc.\u00a0\u5f15\u5165\u201c\u975e\u914d\u4f4d\u201d\u9634\u79bb\u5b50\u7684\u65b0\u65b9\u6cd5\uff1a\u589e\u52a0\u4e24\u6027\u79bb\u5b50\u578bMOF\u4e2d\u7684\u6251\u5549\u91d1\u5c5e\u4e2d\u5fc3\u7684\u8def\u6613\u65af\u9178\u6027<\/strong><\/p>\n

\u9633\u79bb\u5b50\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\u7ecf\u5e38\u7528\u4e8e\u50ac\u5316\u6709\u673a\u53cd\u5e94\u3002\u5176\u4e2d\uff0c\u91d1\u5c5e\u4e2d\u5fc3\u548c\u5e73\u8861\u9634\u79bb\u5b50\u4e4b\u95f4\u7684\u79bb\u5b50\u5bf9\u4f5c\u7528\u901a\u5e38\u5f71\u54cd\u57fa\u8d28\u7684\u6d3b\u5316\u548c\u50ac\u5316\u5242\u7684\u6d3b\u6027\u3002\u901a\u8fc7\u5438\u7535\u5b50\u57fa\u5f15\u5165\u7684\u5f31\u914d\u4f4d\u9634\u79bb\u5b50\u53ef\u4ee5\u589e\u52a0\u9633\u79bb\u5b50\u91d1\u5c5e\u4e2d\u5fc3\u7684\u51c0\u6b63\u7535\u8377\uff0c\u63d0\u9ad8\u8def\u6613\u65af\u9178\u6027\u3002\u53e6\u4e00\u79cd\u5f15\u4eba\u6ce8\u76ee\u7684\u65b9\u5f0f\u662f\u7531\u9633\u79bb\u5b50\u91d1\u5c5e\u5355\u5143\u548c\u5e26\u8d1f\u7535\u8377\u8f85\u52a9\u914d\u4f53\u952e\u5408\u8fbe\u5230\u5f62\u5f0f\u4e0a\u7684\u7535\u8377\u5206\u79bb\uff0c\u5f62\u6210\u4e24\u6027\u79bb\u5b50\u578b\u91d1\u5c5e\u914d\u5408\u7269\u3002<\/p>\n

\u5185\u5e03\u62c9\u65af\u52a0\u5927\u5b66\u6797\u80af\u5206\u6821Jian Zhang\u7814\u7a76\u7ec4\u62a5\u9053\u4e86\u7531\u9634\u79bb\u5b50\u578b[In(CO2)4]\u2013 \u6b21\u7ea7\u7ed3\u6784\u5355\u5143\uff08SBUs\uff09\u548c\u9633\u79bb\u5b50\u578b\u91d1\u5c5e\u6251\u5549\u6784\u6210\u7684\u4e24\u6027\u79bb\u5b50\u578bMOFs\uff0c\u4ece\u800c\u5f15\u5165\u201c\u975e\u914d\u4f4d\u201d\u9634\u79bb\u5b50\uff0c\u8fbe\u5230\u63d0\u9ad8\u91d1\u5c5e\u4e2d\u5fc3\u8def\u6613\u65af\u9178\u6027\u7684\u76ee\u7684\u3002\u7814\u7a76\u7ec4\u5229\u7528\u4e09\u7c7b\u5178\u578b\u7684\u7684\u7535\u73af\u5316\u53cd\u5e94\u9a8c\u8bc1\u4e86MnIII-\u548c FeIII-\u6251\u5549\u7684\u8def\u6613\u65af\u9178\u53d8\u5316\u3002\u8fd9\u4e09\u7c7b\u7535\u73af\u5316\u53cd\u5e94\u6709\u70ef\u7094\u7684[2+1]\u73af\u5f02\u6784\u5316\u3001\u6c2e\u6742\u73af\u4e19\u70f7\u548c\u70ef\u5c5e\u70c3\u7684[3+2]\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u919b\u548c\u4e8c\u70ef\u70c3\u7684[4+2]\u5f02-\u72c4\u5c14\u65af-\u4f0d\u5c14\u5fb7\u73af\u52a0\u6210\u53cd\u5e94\u3002\u8be5\u9879\u5de5\u4f5c\u4e3a\u53ef\u63a7\u5316\u5b66\u50ac\u5316\u5242MOF\u7684\u529f\u80fd\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u65b9\u5f0f\u3002<\/p>\n

\"\u56fe\u724722\"
\n\u56fe2<\/strong> \u4e24\u6027\u79bb\u5b50\u578bMOF\u7528\u4e8e\u591a\u79cd\u53cd\u5e94\u7684\u50ac\u5316\u5242<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A New Approach to Non-coordinating Anions: Lewis Acid Enhancement of Porphyrin Metal Centers in a Zwitterionic Metal-Organic Framework<\/a> (J. Am. Chem. Soc.\uff0c2016\uff0cDOI: 10.1021\/jacs.6b05626)<\/p>\n

3\u3001J. Am. Chem. Soc.\u00a0\u00a0MOF\u7684\u5916\u5f62\u5851\u9020\uff1a\u4ece\u6d41\u4f53\u5230\u6210\u5f62\u4f53\u548c\u6ce1\u6cab<\/strong><\/p>\n

MOF\u5728\u5de5\u4e1a\u5206\u79bb\u3001\u50ac\u5316\u5242\u3001\u4f20\u611f\u548c\u4e00\u4e9b\u7cbe\u5bc6\u8bbe\u5907\u7684\u5e94\u7528\u4f1a\u7531\u4e8e\u5176\u5185\u5728\u7684\u8106\u5f31\u6027\u548c\u8f83\u4f4e\u7684\u52a0\u5de5\u6027\u80fd\u800c\u53d7\u5230\u5f71\u54cd\u3002\u4e0d\u50cf\u6709\u673a\u805a\u5408\u7269\uff0cMOF\u50ac\u5316\u5242\u4e0d\u6eb6\u4e8e\u6eb6\u5242\u4e14\u6ca1\u6709\u70ed\u5851\u6027\u3002\u8fd9\u4e5f\u610f\u5473\u7740\u57fa\u4e8e\u6eb6\u89e3\u548c\u878d\u5316\u7684\u52a0\u5de5\u6280\u672f\u5e76\u4e0d\u9002\u7528\u4e8eMOF\u3002<\/p>\n

\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u7814\u7a76\u7ec4\u901a\u8fc7\u8fde\u7eed\u76f8\u8f6c\u53d8\u6280\u672f\u5c06MOF\u6784\u5efa\u548c\u5851\u9020\u6210\u6d41\u4f53\u3001\u6210\u5f62\u4f53\u3001\u6ce1\u6cab\uff0c\u5e76\u5b9e\u73b0\u8fd9\u4e9b\u72b6\u6001\u7684\u53ef\u9006\u8f6c\u5316\u3002\u57fa\u4e8e\u4e0a\u8ff0\u7b56\u7565\u5f97\u5230\u7684\u676f\u5f62Cu-MOF \u4e0e\u5206\u5c42\u591a\u5b54MOF\u6ce1\u6cab\u5bf9C-H\u6c27\u5316\u5177\u6709\u9ad8\u6548\u7684\u50ac\u5316\u6027\uff08\u676f\u5f62Cu-MOF\uff1a\u4ea7\u7387\u4e3a6%\uff0c\u9009\u62e9\u6027\u4e3a93%\uff1b\u591a\u5b54MOF\u6ce1\u6cab\uff1a\u4ea7\u7387\u4e3a 92%\uff0c\u9009\u62e9\u6027\u4e3a 97% \uff09\u5e76\u4e14\u5bb9\u6613\u56de\u6536\u3002\u5e76\u4e14\u57fa\u4e8eMOF\u7684\u6ce1\u6cab\u5177\u6709\u4f4e\u5bc6\u5ea6\u548c\u8f83\u9ad8\u7684MOF\u8d1f\u8f7d\u91cf\uff0c\u540c\u65f6\u8868\u73b0\u51fa\u4f4e\u80fd\u8017\u3002\u6709\u671b\u6210\u4e3a\u9ad8\u6548\u7684\u819c\u5206\u79bb\u5668\u3002<\/p>\n

\"33\"<\/p>\n

\u56fe3<\/strong> (a) HKUST-1@Fe3O4-MF \u5408\u6210\u793a\u610f\u56fe\u53ca\u4ece\u78c1\u6027\u6d41\u4f53\u5230\u51dd\u80f6\u3001\u6210\u5f62\u4f53\u5230\u591a\u5b54\u6ce1\u6cab(b)\u8fd0\u7528\u8be5\u7b56\u7565\u7684\u5f97\u5230\u7684\u5178\u578bMOF\u7684\u6ce1\u6cab<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Shaping of metal-organic frameworks: from fluid to shaped bodies and robust foams<\/a>\u00a0(J. Am. Chem. Soc.\uff0c2016\uff0cDOI: 10.1021\/jacs.6b06959)<\/p>\n

4\u3001J. Am. Chem. Soc. \u5728\u591a\u4f4d\u7d20\u914d\u4f53\u548c\u65e0\u9650SBU\u6784\u5efa\u7684MOF\u5185\u5173\u4e8e\u6846\u67b6\u5316\u5b66\u7684\u4e24\u4e2a\u539f\u5219<\/strong><\/p>\n

MOF \u7ed3\u6784\u7684\u591a\u6837\u6027\u591a\u6765\u6e90\u4e8e\u914d\u4f53\u4e2d\u542b\u6709\u7684\u6700\u591a\u4e24\u79cd\u914d\u4f4d\u57fa\u56e2\uff0c\u6784\u5efaMOF\u7684\u914d\u4f53\u542b\u6709\u4e09\u79cd\u751a\u81f3\u66f4\u591a\u79cd\u914d\u4f4d\u57fa\u56e2\u7684\u60c5\u51b5\u672a\u89c1\u62a5\u9053\u8fc7\u3002<\/p>\n

\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u7814\u7a76\u7ec4\u9996\u6b21\u62a5\u9053\u4e00\u4f8b\u542b\u6709\u4e09\u79cd\u914d\u4f4d\u57fa\u56e2\u7684\u57fa\u56e2\u7684\u914d\u4f53\u6784\u5efa\u7684\u591a\u5b54\u6676\u4f53MOF\uff0cZn3(PBSP)2\u6216 MOF-910\u3002\u8be5MOF\u542b\u6709\u4ece\u672a\u6709\u8fc7\u7684\u62d3\u6251\u7ed3\u6784\u6210\u4e3atto\u3002\u7814\u7a76\u8bf4\u660e\u7b80\u6613\u3001\u5bf9\u79f0\u7684\u914d\u4f53\u4e0d\u662f\u6784\u5efa\u591a\u6837\u6027\u6676\u4f53\u7ed3\u6784\u7684\u5fc5\u7136\uff0c\u65b0\u578b\u590d\u6742\u7684\u62d3\u6251\u7ed3\u6784\u53ef\u4ee5\u901a\u8fc7\u4e0d\u89c4\u5219\u7684\u5f02\u4f4d\u5143\u7d20\u914d\u4f53\u83b7\u5f97\u3002\u8be5\u9879\u5de5\u4f5c\u8868\u660e\u6846\u67b6\u5316\u5b66\u7684\u4e24\u4e2a\u539f\u5219\uff1a\u7b2c\u4e00\uff0c\u5f02\u4f4d\u7d20\u914d\u4f53\u5bf9\u87ba\u65cb\u578b\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u7684\u9009\u62e9\u6027\u5927\u4e8e\u76f4\u94fe\u578b\uff1b\u7b2c\u4e8c\uff0c\u87ba\u65cb\u578b\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u7684\u87ba\u77e9\u53ef\u6839\u636e\u5f02\u4f4d\u7d20\u914d\u4f53\u8c03\u8c10\u3002<\/p>\n

\"\u56fe\u724744\"
\n\u56fe4<\/strong> PBSP\u914d\u4f53\u4e0e\u87ba\u65cb\u578b\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u6784\u5efa\u6210\u65b0\u9896\u7684MOF\u7ed3\u6784<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Two Principles of Reticular Chemistry Uncovered in a Metal-Organic Framework of Heterotritopic Linkers and Infinite Secondary Building Units<\/a>\u00a0(J. Am. Chem. Soc.\uff0c2016\uff0cDOI: 10.1021\/jacs.6b07267)<\/p>\n

5\u3001J. Am. Chem. Soc. \u7531\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u4fee\u9970\u7684\u53ef\u6eb6\u7684\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\u7528\u4e8e\u5f02\u76f8\u50ac\u5316\u5242\u7684\u5747\u5316<\/strong><\/p>\n

\u4e2d\u79d1\u9662\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240\u66f9\u8363\u8bfe\u9898\u7ec4\u5c06\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u4fee\u9970\u5230\u53ef\u6eb6\u7684\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\u4e0a\u63d0\u9ad8\u5176\u91d1\u5c5e\u8d1f\u8f7d\u91cf\u3002\u590d\u5408\u7269\u7684\u6eb6\u89e3\u6027\u548c\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u53ef\u6839\u636e\u524d\u4f53\u7684\u6bd4\u4f8b\u6765\u8c03\u63a7\u3002\u53ef\u6eb6\u6027\u914d\u4f4d\u805a\u5408\u7269\u4f7f\u5f97\u5f02\u76f8\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\u5747\u5300\u5316\uff0c\u5e76\u4e14\u5728C\u2212H\u6d3b\u5316\u548cSuzuki\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u975e\u5e38\u9ad8\u7684\u50ac\u5316\u6027\u548c\u53ef\u56de\u6536\u6027\u3002\u8fd9\u79cd\u7b56\u7565\u7efc\u5408\u4e86\u5747\u76f8\u548c\u5f02\u76f8\u50ac\u5316\u5242\u7684\u4f18\u52bf\uff0c\u4e3a\u50ac\u5316\u5242\u7814\u7a76\u63d0\u4f9b\u65b0\u7684\u7075\u611f\u3002<\/p>\n

\"\u56fe\u724755\"
\n\u56fe5<\/strong> \u7531\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u4fee\u9970\u7684\u53ef\u6eb6\u7684\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\u5bf9C\u2212H\u6d3b\u5316\u548cSuzuki\u53cd\u5e94\u7684\u50ac\u5316<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Soluble Metal-Nanoparticle-Decorated Porous Coordination Polymers for the Homogenization of Heterogeneous Catalysis<\/a>\u00a0(J. Am. Chem. Soc.\uff0c2016\uff0cDOI: 10.1021\/jacs.6b06185)<\/p>\n

6\u3001Angew. Chem. Int. Ed. \u00a0\u6a21\u677f\u8c03\u63a7\u5408\u6210\u591a\u5b54\u9632\u62a4\u6027\u6838-\u58f3\u751f\u7269\u7eb3\u7c73\u7c92\u5b50<\/strong><\/p>\n

\u5fb7\u514b\u8428\u65af\u5927\u5b66\u8fbe\u62c9\u65af\u5206\u6821Jeremiah J. Gassensmith\u7814\u7a76\u7ec4\u4ee5\u86cb\u767d\u8d28\u6a21\u677f\uff0c\u70df\u8349\u82b1\u53f6\u75c5\u6bd2 (TMV)\u7528\u4e8e\u8c03\u63a7MOF\u6750\u6599\u7684\u5c3a\u5bf8\u548c\u5f62\u72b6\u5e76\u5f97\u5230\u6838-\u58f3\u751f\u7269\u7eb3\u7c73\u6df7\u5408\u7269TMV@MOF\u3002TMV@MOF\u5177\u6709\u826f\u597d\u7684\u5206\u6563\u6027\uff0c\u5e76\u4e14\u5b54\u5f84\u53ef\u7531\u5408\u6210\u6761\u4ef6\u6765\u8c03\u8282\u3002\u66f4\u6709\u8da3\u7684\u662f\uff0c\u5728MOF\u58f3\u5185\u90e8\u7684\u75c5\u6bd2\u9897\u7c92\u53ef\u7531\u751f\u7269\u5076\u8054\u53cd\u5e94\u8fdb\u884c\u5316\u5b66\u4fee\u9970\uff0c\u5728MOF\u58f3\u4e0a\u8868\u73b0\u51fa\u8d28\u91cf\u4f20\u9012\u3002<\/p>\n

\"\u56fe\u724766\"
\n\u56fe6<\/strong> TMV@ZIF-8 \u68d2\u72b6\u7eb3\u7c73\u590d\u5408\u7269\u7684\u5408\u6210<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Template-Directed Synthesis of Porous and Protective Core\u2013Shell Bionanoparticles<\/a>\u00a0(Angew. Chem. Int. Ed.\uff0c2016\uff0cDOI: 10.1002\/ange.201604879)<\/p>\n

7\u3001Angew. Chem. Int. Ed. \u5728MOF\u4e2d\u901a\u8fc7\u91d1\u5c5e\u79bb\u5b50\u4ea4\u6362\u5b9e\u73b0\u91d1\u5c5e\u5316\u8f6c\u79fb\u7528\u4e8e\u6eb6\u6db2\u4e2d\u78f7\u9178\u76d0\u7684\u9009\u62e9\u6027\u4f20\u611f<\/strong><\/p>\n

\u5370\u5ea6\u79d1\u5b66\u6559\u80b2\u7814\u7a76\u6240Sukhendu Mandal\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u62a5\u9053\u4e86\u901a\u8fc7\u91d1\u5c5e\u5316\u8f6c\u79fb\u7531Ba-MOF\u4ee5\u5355\u6676\u5230\u5355\u6676(SC-SC)\u7684\u5f62\u5f0f\u8f6c\u5316\u4e3a\u65b0\u578b\u7684Tb-MOF\u3002\u8fd9\u4f7f\u5f97\u5b54\u7a74\u4e2d\u542b\u9633\u79bb\u5b50\u7684\u9634\u79bb\u5b50\u6846\u67b6\u8f6c\u53d8\u4e3a\u4e2d\u6027\u6846\u67b6\u3002\u8f6c\u5316\u673a\u5236\u7814\u7a76\u8868\u660e\u901a\u8fc7\u91d1\u5c5e-\u914d\u4f53\u7684\u952e\u88c2\u5b9e\u73b0\u4e86\u6838-\u58f3\u5f0f\u91d1\u5c5e\u4ea4\u6362\u3002Tb-MOF\u8868\u73b0\u4e3a\u66f4\u9ad8\u7684\u8367\u5149\u6027\uff0c\u5e76\u4e14\u5728\u6eb6\u6db2\u4e2d\u9009\u62e9\u6027\u8bc6\u522b\u78f7\u9178\u76d0\u3002\u8be5\u9879\u5de5\u4f5c\u4e0d\u4ec5\u4e3a\u5408\u6210\u5728\u4f20\u611f\u65b9\u9762\u6709\u6f5c\u5728\u5e94\u7528\u7684\u529f\u80fdMOF\u63d0\u4f9b\u4e00\u79cd\u65b0\u65b9\u6cd5\uff0c\u540c\u65f6\u4e5f\u9610\u660e\u4e86\u8f6c\u5316\u673a\u5236\u3002<\/p>\n

\"\u56fe\u724777\"
\n\u56fe7<\/strong> \u5728\u91d1\u5c5e\u4ea4\u6362\u8fc7\u7a0b\u4e2dBa-MOF\u53d1\u751f\u7684\u5355\u6676\u5230\u5355\u6676\u8f6c\u53d8\u5b9e\u65f6\u76d1\u6d4b<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Complete Transmetalation in a Metal\u2013Organic Framework by Metal Ion Metathesis in a Single Crystal for Selective Sensing of Phosphate Ions in Aqueous Media<\/a>\u00a0(Angew. Chem. IntEd.\uff0c2016\uff0cDOI:10.1002\/ange.201606185)<\/p>\n

8\u3001Angew. Chem. Int. Ed. MOF\u7528\u4e8eCO2\u548c\u6c34\u7684\u4e73\u5316<\/strong><\/p>\n

CO2\u548c\u6c34\u5f62\u6210\u4e73\u5242\u53ef\u4ee5\u6269\u5c55CO2\u7684\u5e94\u7528\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u80f6\u4f53\u3001\u754c\u9762\u4e0e\u5316\u5b66\u70ed\u529b\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u97e9\u5e03\u5174\u8bfe\u9898\u7ec4\u9996\u6b21\u5229\u7528MOF\u6765\u4e73\u5316CO2\u548c\u6c34\u3002MOF\u5f88\u5bb9\u6613\u5728CO2\/H2O\u8868\u9762\u7ec4\u88c5\uff0c\u5e76\u5728\u5206\u6563\u6db2\u6ef4\u5468\u56f4\u5f62\u6210\u4fdd\u62a4\u5c42\u3002\u7531MOF\u7a33\u5b9a\u7684 CO2 \u548c\u6c34\u7684\u4e73\u5242\u76f8\u5bf9\u4e8e\u90a3\u4e9b\u7531\u8868\u9762\u6d3b\u6027\u5242\u548c\u5176\u5b83\u56fa\u4f53\u7a33\u5b9a\u7684\u4e73\u5242\u6765\u8bf4\u5177\u6709\u8d85\u5e38\u7684\u7a33\u5b9a\u6027\u3002\u8fd9\u79cd\u7531CO2\uff0c\u6c34\uff0cMOF\u5f62\u6210\u7684\u4e73\u5316\u5242\u4e3a\u6784\u5efa\u591a\u79cd\u529f\u80fd\u7684MOF\u8d85\u5206\u5b50\u7ed3\u6784\u63d0\u4f9b\u7b80\u5355\u8def\u7ebf\u3002\u4e0d\u540c\u79cd\u7684MOF\u5927\u5b54\u7f51\u683c\u548c\u4e2d\u7a7a\u80f6\u56ca\u79bb\u4e0d\u5f00CO2 \u548c\u6c34\u7684\u4e73\u5242\u3002<\/p>\n

\"\u56fe\u724788\"
\n\u56fe8<\/strong> CO2\u548c\u6c34\u7684\u4e73\u5242\u4e2d\u6784\u5efaMOF\u5927\u5b54\u7f51\u683c\u548c\u4e2d\u7a7a\u80f6\u56ca\u793a\u610f\u56fe<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Metal\u2013Organic Framework for Emulsifying Carbon Dioxide and Water<\/a> (Angew. Chem. Int. Ed.\uff0c2016\uff0cDOI: 10.1002\/ange.201602150)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8MOF\u7ec4\u7f51\u8001\u742a\u742a\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u4e0eMOF\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3MOF\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

1\u3001Adv. Mater. MOF\u884d\u751f\u7684\u4e0d\u542b\u8d35\u91d1\u5c5e\u7684\u8702\u7a9d\u72b6\u50ac\u5316\u5242\u7528\u4e8e\u6c27\u7684\u9ad8\u6548\u7535\u8fd8\u539f \u6c27\u7535\u89e3\u8fd8\u539f\uff08ORR\uff09\u5728\u9ad8\u5206\u5b50\u7535\u89e3\u8d28\u71c3\u6599\u7535\u6c60\u7684\u9634\u6781\u4e0a\u662f\u975e\u5e38\u91cd\u8981\u7684\u8fc7\u7a0b\u3002\u9ad8\u6548\u7684\u6c27…<\/p>\n","protected":false},"author":1123,"featured_media":35255,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[67],"tags":[245],"class_list":["post-35237","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhoubao","tag-mof"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/35237"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1123"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=35237"}],"version-history":[{"count":14,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/35237\/revisions"}],"predecessor-version":[{"id":35671,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/35237\/revisions\/35671"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/35255"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=35237"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=35237"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=35237"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}