{"id":33534,"date":"2016-08-30T10:56:56","date_gmt":"2016-08-30T02:56:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=33534"},"modified":"2016-09-10T09:23:49","modified_gmt":"2016-09-10T01:23:49","slug":"%e5%b8%a6%e4%bd%a0%e9%a2%86%e7%95%a5%e5%a4%9a%e6%a0%b7%e7%9a%84%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e7%94%b5%e6%9e%81%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=33534","title":{"rendered":"\u5e26\u4f60\u9886\u7565\u591a\u6837\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599"},"content":{"rendered":"

\u3010\u524d\u8a00<\/strong>\u3011
\n\u5316\u77f3\u71c3\u6599\u50a8\u91cf\u7684\u65e5\u76ca\u51cf\u5c11\u53ca\u5176\u4f7f\u7528\u5e26\u6765\u7684\u73af\u5883\u95ee\u9898\u6210\u4e3a\u4e86\u793e\u4f1a\u53d1\u5c55\u8fc7\u7a0b\u4e2d\u9762\u4e34\u7684\u68d8\u624b\u96be\u9898\u3002\u56e0\u6b64\uff0c\u5bf9\u4e8e\u53ef\u518d\u751f\u8d44\u6e90\u7684\u5229\u7528\uff0c\u6210\u4e3a\u4e86\u51cf\u7f13\u8fd9\u4e00\u96be\u9898\u7684\u4e00\u4e2a\u6709\u6548\u624b\u6bb5\u3002\u4e8c\u6b21\u7535\u6c60\u50a8\u80fd\u7cfb\u7edf\u6210\u4e3a\u4e86\u5f88\u597d\u7684\u53ef\u518d\u751f\u8d44\u6e90\u5b58\u50a8\u65b9\u5f0f\u3002\u5176\u4e2d\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u53d1\u5c55\u6700\u4e3a\u8fc5\u901f\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u5177\u6709\u5faa\u73af\u6027\u80fd\u597d\u3001\u6bd4\u5bb9\u91cf\u5927\u3001\u53ef\u5feb\u901f\u5145\u653e\u7535\u3001\u4f53\u79ef\u5c0f\u7b49\u4e00\u7cfb\u5217\u663e\u8457\u4f18\u70b9\uff0c\u5e7f\u6cdb\u5730\u5e94\u7528\u4e8e\u624b\u673a\u3001\u7b14\u8bb0\u672c\u7535\u8111\u7b49\u7535\u5b50\u8bbe\u5907\u3002\u968f\u7740\u7535\u8f66\u3001\u667a\u80fd\u7535\u7f51\u7b49\u5927\u578b\u50a8\u80fd\u7cfb\u7edf\u7684\u53d1\u5c55\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u7684\u52a3\u52bf\u9010\u6e10\u660e\u663e\u3002\u9502\u8d44\u6e90\u50a8\u91cf\u6709\u9650\u4f7f\u5176\u6210\u672c\u8f83\u9ad8\uff0c\u9650\u5236\u4e86\u5176\u5728\u5927\u578b\u50a8\u80fd\u7cfb\u7edf\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n

\u94a0\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5177\u6709\u6210\u672c\u4f4e\u3001\u50a8\u91cf\u4e30\u5bcc\u3001\u5206\u5e03\u5e7f\u6cdb\u7684\u7279\u70b9\uff0c\u5c06\u6210\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7406\u60f3\u66ff\u4ee3\u8005\u3002\u94a0\u79bb\u5b50\u7535\u6c60\u4e3b\u8981\u7531\u6b63\u6781\u6750\u6599\u3001\u8d1f\u6781\u6750\u6599\u3001\u9694\u819c\u3001\u7535\u89e3\u6db2\u7b49\u7ec4\u6210\uff0c\u5176\u4e2d\u7535\u6781\u6750\u6599\u7684\u6027\u80fd\u76f4\u63a5\u51b3\u5b9a\u4e86\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u5bf9\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\u7684\u7814\u7a76\u6210\u4e3a\u4e86\u5f53\u524d\u7814\u7a76\u7684\u91cd\u70b9\u3002<\/p>\n

1. \u6b63\u6781\u6750\u6599<\/strong>
\n 1.1 \u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269<\/strong>
\n\u6839\u636e\u94a0\u79bb\u5b50\u5c42\u72b6\u6c27\u5316\u7269\u548c\u4e00\u822c\u6c27\u5316\u5c42\u5bc6\u5806\u79ef\u65b9\u5f0f\u4e0d\u540c\uff0cDelmas \u5c06\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u5206\u4e3a\uff1aO3\u578b(ABCABC)\u3001P2\u578b\uff08ABBA\uff09\u548c P3\u578b\uff08ABBCCA\uff09\u4e09\u7c7b\uff0c\u4e0d\u540c\u5bc6\u5806\u79ef\u65b9\u5f0f\u4e2d\u94a0\u79bb\u5b50\u5904\u5728\u4e0d\u540c\u7684\u914d\u4f4d\u73af\u5883\uff08P=\u68f1\u5f62\u3001O=\u516b\u9762\u4f53\uff09\u3002<\/p>\n

\u9530\u57fa\u6c27\u5316\u7269\u3001\u94c1\u57fa\u6c27\u5316\u7269\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\uff0c\u4f5c\u4e3a\u5355\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u8868\u73b0\u51fa\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u4f46\u662f\uff0c\u03b1-NaFeO2\u5bf9\u6c34\u5206\u654f\u611f\uff0c\u6613\u751f\u6210FeOOH\u548cNaOH\uff0c\u5f71\u54cd\u7535\u6c60\u5bb9\u91cf\u53d1\u6325\u3002\u4e3a\u4e86\u63d0\u9ad8\u8fd9\u7c7b\u6750\u6599\u7684\u7a33\u5b9a\u6027\u548c\u5faa\u73af\u6027\u53ef\u4ee5\u5728\u5355\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u53d6\u4ee3\u6216\u63ba\u6742\u5176\u4ed6\u8fc7\u6e21\u91d1\u5c5e\uff0c\u5982Fe\u53d6\u4ee3Mn\u53ef\u4ee5\u6291\u5236NaMnO2\u6750\u6599\u94a0\u8131\u51fa\u540e\u53d1\u751f\u76f8\u53d8\uff0c\u4ece\u800c\u63d0\u9ad8\u6750\u6599\u7a33\u5b9a\u6027\u3002\u5bf9\u4e8e\u5c42\u72b6NaCrO2\u800c\u8a00\uff0c\u5f53\u7528\u4f5c\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u65f6\uff0c\u5728\u5faa\u73af50\u5468\u671f\u540e\uff0c\u5176\u653e\u7535\u5bb9\u91cf\u4e3a90\u2013120 mAh\u00a0g\u22121[1]\u3002\u7535\u6d41\u5bc6\u5ea6\u4ece\u00a025 mA\u00a0g\u22121\u5347\u81f3250 mA\u00a0g\u22121\u65f6\uff0c\u5176\u653e\u7535\u5bb9\u91cf\u589e\u52a0\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u540c\u6837\u5f97\u5230\u4e86\u63d0\u9ad8\uff0c\u7535\u5316\u5b66\u6027\u80fd\u826f\u597d\u3002<\/p>\n

\"NaCrO\"<\/p>\n

\u56fe\u4e00 Na||NaCrO2\u3001Li||LiCrO2\u7535\u6c60\u5faa\u73af\u6027\u80fd\u7684\u6bd4\u8f83<\/p>\n

\u5bf9\u4e8e\u5c42\u72b6\u94a0\u79bb\u5b50\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u800c\u8a00\uff0c\u867d\u7136\u5728\u7535\u5316\u5b66\u65b9\u9762\u8868\u73b0\u51fa\u826f\u597d\u7684\u6027\u80fd\uff0c\u4f46\u662f\u5b83\u4eec\u5236\u5907\u6bd4\u8f83\u56f0\u96be\uff0c\u5bf9\u6c34\u548cCO2\u6bd4\u8f83\u654f\u611f\uff0c\u5728\u5b9e\u9645\u6279\u91cf\u751f\u4ea7\u4e2d\u8fd8\u6709\u5f85\u8fdb\u4e00\u6b65\u6539\u8fdb\u3002<\/p>\n

1.2 \u805a\u9634\u79bb\u5b50\u5316\u5408\u7269<\/strong>
\n\u805a\u9634\u79bb\u5b50\u6750\u6599\u5177\u6709\u7ed3\u6784\u591a\u6837\u6027\u3001\u7ed3\u6784\u7a33\u5b9a\u6027\u3001\u94a0\u79bb\u5b50\u8fc1\u79fb\u80fd\u4f4e\u548c\u7535\u538b\u5e73\u53f0\u7a33\u5b9a<\/strong>\u7684\u7279\u70b9\u3002\u5176\u7a33\u5b9a\u7684\u5171\u4ef7\u7ed3\u6784\u4f7f\u5176\u5177\u6709\u8f83\u9ad8\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u4ee5\u53ca\u9ad8\u7535\u538b\u6c27\u5316\u7a33\u5b9a\u6027\u3002\u7531\u4e8e\u4ee5\u4e0a\u8bf8\u591a\u4f18\u52bf\uff0c\u805a\u9634\u79bb\u5b50\u5316\u5408\u7269\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u7814\u7a76\u4e2d\u4e5f\u5907\u53d7\u9752\u7750\u3002\u4f46\u662f\u5176\u8f83\u5927\u7684\u805a\u9634\u79bb\u5b50\u57fa\u56e2\u4f7f\u5176\u7406\u8bba\u5bb9\u91cf\u4e00\u822c\u6bd4\u8f83\u4f4e\u3002<\/p>\n

\u805a\u9634\u79bb\u5b50\u5316\u5408\u7269\u4e3b\u8981\u5305\u62ec\uff1a\u78f7\u9178\u76d0\uff0c\u6c1f\u78f7\u9178\u76d0\uff0c\u7126\u78f7\u9178\u76d0\uff0c\u786b\u9178\u76d0\u7b49<\/strong>\u3002\u6c1f\u4ee3\u805a\u9634\u79bb\u5b50\u6750\u6599\u662f\u5728\u805a\u9634\u79bb\u5b50\u7ed3\u6784\u4e2d\u5f15\u5165\u9ad8\u7535\u8d1f\u6027\u7684\u6c1f\u539f\u5b50\uff0c\u6c1f\u539f\u5b50\u7684\u5f15\u5165\u80fd\u63d0\u9ad8\u6750\u6599\u7684\u6c27\u5316\u8fd8\u539f\u5bf9\u7535\u538b\uff0c\u4ece\u800c\u63d0\u5347\u80fd\u91cf\u5bc6\u5ea6\u3002\u786b\u9178\u76d0\u4e2d\u7684\u786b\u9178\u6839\u5177\u6709\u66f4\u5f3a\u7684\u7535\u8d1f\u6027\uff0c\u4f7f\u5176\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u5177\u6709\u66f4\u9ad8\u7684\u7535\u538b\u5e73\u53f0\u3002<\/p>\n

\u78f7\u94c1\u94a0\u77ff\u76f8\u7684NaFePO4\uff0c\u5177\u6709\u7a33\u5b9a\u7684\u70ed\u529b\u5b66\u7ed3\u6784\uff0c\u4f46\u5176\u6676\u4f53\u4e2d\u6ca1\u6709\u76f8\u5e94\u7684\u94a0\u79bb\u5b50\u6269\u6563\u901a\u9053\uff0c\u4e0d\u5177\u6709\u7535\u5316\u5b66\u6d3b\u6027\u3002\u800c\u6a44\u6984\u77f3\u76f8\u7684NaFePO4\u53ef\u4ee5\u7528\u4f5c\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\uff0c\u7406\u8bba\u5bb9\u91cf\u4e3a154 mAh g-1\uff0c\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u6709\u4e24\u4e2a\u7535\u538b\u5e73\u53f0\uff0c\u7531\u4e8eFePO4\u7535\u5b50\/\u79bb\u5b50\u7535\u5bfc\u7387\u6bd4\u8f83\u5dee\uff0c\u6240\u4ee5\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f1a\u4ea7\u751f\u8f83\u5927\u7684\u6781\u5316\u3002NaFePO4\u521d\u8bd5\u5bb9\u91cf\u4e3a125 mAh g-1\uff0c50\u4e2a\u5faa\u73af\u540e\u4ecd\u53ef\u4fdd\u6301\u5728110 mAhg-1\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u8f83\u9ad8[2]\u3002<\/p>\n

\"2\"<\/p>\n

\u56fe\u4e8c Na\/\/NaFePO4\u7535\u6c60\u5faa\u73af\u6027\u80fd\u6d4b\u8bd5\u66f2\u7ebf<\/p>\n

1.3 \u666e\u9c81\u58eb\u84dd\u7c7b\u5316\u5408\u7269<\/strong>
\n\u666e\u9c81\u58eb\u84dd\u7c7b\u5316\u5408\u7269\u4e3a CN-\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u914d\u4f4d\u5f62\u6210\u7684\u914d\u5408\u7269\uff0c\u5177\u67093D\u5f00\u653e\u7ed3\u6784\uff0c\u6709\u5229\u4e8e\u94a0\u79bb\u5b50\u4f20\u8f93\u548c\u50a8\u5b58\uff0c\u4e5f\u88ab\u5e7f\u6cdb\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002\u4f5c\u4e3a\u4f20\u7edf\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u805a\u9634\u79bb\u5b50\u5316\u5408\u7269\u7684\u66ff\u4ee3\u8005\uff0c\u666e\u9c81\u58eb\u84dd\u7c7b\u5316\u5408\u7269\u8fd8\u5177\u6709\u5143\u7d20\u6210\u672c\u4f4e\u3001\u5ba4\u6e29\u6613\u5408\u6210\u7684\u7279\u70b9\u3002<\/p>\n

FeFe(CN)6\u5355\u6676\u7eb3\u7c73\u9897\u7c92\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u94a0\u5b58\u50a8\u6027\u80fd\uff0c\u53ef\u9006\u5bb9\u91cf120 mAh g\u22121\u00a0\uff0c\u5e93\u4f26\u6548\u7387\u7ea6\u4e3a100%\u300220C\u65f6\uff0c\u4ecd\u7136\u5177\u6709\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\uff0c500\u4e2a\u5468\u671f\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u8fbe87%\uff0c\u5177\u6709\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u53ef\u4ee5\u6210\u4e3a\u4e00\u79cd\u4f4e\u6210\u672c\u3001\u65e0\u6c61\u67d3\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002<\/p>\n

\"c3ta12036h-f3\"<\/p>\n

\u56fe\u4e09 FeFe(CN)6\u7535\u5316\u5b66\u6027\u80fd\u7684\u7814\u7a76<\/p>\n

1.4 \u6709\u673a\u7535\u6781\u6750\u6599<\/strong>
\n\u6709\u673a\u7535\u6781\u6750\u6599\u7531\u4e8e\u5176\u73af\u5883\u53cb\u597d\u3001\u50a8\u91cf\u4e30\u5bcc\u3001\u7ed3\u6784\u591a\u6837<\/strong>\uff0c\u5f00\u59cb\u5438\u5f15\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\uff0c\u53ef\u80fd\u4f1a\u6210\u4e3a\u4f20\u7edf\u65e0\u673a\u6750\u6599\u7684\u7406\u60f3\u66ff\u4ee3\u8005\uff0c\u5176\u4e2d\u5171\u8f6d\u7fb0\u57fa\u5316\u5408\u7269\u56e0\u5176\u5177\u6709\u8f83\u597d\u7684\u6c27\u5316\u8fd8\u539f\u53ef\u9006\u6027\u4ee5\u53ca\u7ed3\u6784\u7a33\u5b9a\u6027\uff0c\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u3002<\/p>\n

PTCDA\uff0c\u4e00\u79cd\u5177\u6709\u4e00\u4e2a\u82b3\u73af\u4e2d\u5fc3\u548c\u4e24\u4e2a\u9178\u9150\u57fa\u56e2\u7684\u6709\u673a\u67d3\u6599\uff0c\u5f53\u7528\u4f5c\u9ad8\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u65f6\u8868\u73b0\u51fa\u4e86\u8f83\u9ad8\u7684\u7535\u5316\u5b66\u53ef\u9006\u6027[1]\u3002\u57281-3V\u8fdb\u884c\u6d4b\u8bd5\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA g\u20131\u65f6 \uff0c\u5176\u5bb9\u91cf\u53ef\u8fbe140 mAh g\u20131\uff0c\uff1b\u5f53\u7535\u6d41\u5bc6\u5ea6\u4e3a1000 mA g\u20131\u65f6\uff0c\u5176\u5bb9\u91cf\u4ecd\u53ef\u8fbe91 mAh g\u20131\uff1b200\u4e2a\u5faa\u73af\uff08\u8d77\u59cb5\u4e2a\u5faa\u73af20 mA g\u20131\uff0c\u968f\u540e195\u4e2a\u5faa\u73af200 mA g\u20131\uff09\u540e\u5bb9\u91cf\u4ecd\u4fdd\u6301\u6709100 mAh g\u20131\uff0c\u5e93\u4f26\u6548\u7387\u51e0\u4e4e\u4e3a100%\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u3002\u6b64\u5916\uff0cNa2C6O6\u3001\u84bd\u918c\u7b49\u4e5f\u8fd8\u7528\u4f5c\u94a0\u79bb\u5b50\u6b63\u6781\u6750\u6599\u3002<\/p>\n

\"PTCDA\"<\/p>\n

\u56fe\u56db PTCDA\u7684\u5faa\u73af\u6027\u80fd\u7814\u7a76<\/p>\n

\u5c3d\u7ba1\u6709\u673a\u7535\u6781\u6750\u6599\u5177\u6709\u591a\u79cd\u4f18\u70b9\uff0c\u4f46\u662f\u5b83\u4e0d\u5bfc\u7535\u3001\u5bb9\u6613\u6eb6\u89e3\u5728\u7535\u89e3\u8d28\u4e2d\uff0c\u9700\u8981\u901a\u8fc7\u6dfb\u52a0\u5bfc\u7535\u5242\u589e\u52a0\u5bfc\u7535\u6027\uff0c\u901a\u8fc7\u6210\u76d0\u6216\u8005\u5f62\u6210\u805a\u5408\u7269\u964d\u4f4e\u5176\u6eb6\u89e3\u5ea6\uff0c\u4f7f\u5176\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u5faa\u73af\u6027\u80fd\u5f97\u4ee5\u63d0\u9ad8\u3002<\/p>\n

2.\u8d1f\u6781\u6750\u6599<\/strong>
\n 2.1 \u5d4c\u5165\u7c7b\u6750\u6599(\u78b3\u6750\u6599\u7b49)<\/strong>
\n\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u9502\u79bb\u5b50\u53ef\u4ee5\u5728\u77f3\u58a8\u4e2d\u53ef\u9006\u7684\u5d4c\u5165\u548c\u8131\u51fa\u4f7f\u77f3\u58a8\u5177\u6709\u8f83\u4f4e\u7684\u5de5\u4f5c\u7535\u538b\u3001\u8f83\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff0c\u6210\u4e3a\u4e86\u4e00\u79cd\u6027\u80fd\u4f18\u5f02\u7684\u8d1f\u6781\u6750\u6599\u3002\u800c\u94a0\u79bb\u5b50\u534a\u5f84\u6bd4\u8f83\u5927\uff0c\u4e0e\u77f3\u58a8\u5c42\u95f4\u4e0d\u5339\u914d\uff0c\u4e14\u94a0\u79bb\u5b50\u4e0e\u77f3\u58a8\u5c42\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u6bd4\u8f83\u5f31\uff0c\u56e0\u6b64\uff0c\u77f3\u58a8\u5e76\u4e0d\u9002\u5408\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u3002\u56e0\u6b64\uff0c\u7814\u7a76\u8005\u4eec\u5bf9\u975e\u77f3\u58a8\u8d28\u78b3\u6750\u6599\uff08\u5373\u786c\u78b3\u3001\u8f6f\u78b3\u548c\u65e0\u5b9a\u5f62\u78b3\uff09\u7b49\u8fdb\u884c\u4e86\u5e7f\u6cdb\u4e86\u7684\u7814\u7a76\u3002\u5c3d\u7ba1\u5d4c\u5165\u7c7b\u6750\u6599\u4e00\u822c\u5faa\u73af\u5bff\u547d\u8f83\u597d\uff0c\u4f46\u5176\u5bb9\u91cf\u8f83\u4f4e\u3002<\/p>\n

\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7ebf\u53ef\u7528\u4f5c\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff0c\u572850mAh g-1\uff080.2C\uff09,0.01-1.2V\u5faa\u73af400\u5468\u671f\u540e\u5176\u53ef\u9006\u5bb9\u91cf\u4e3a251 mAh g-1\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a82.2%[5]\u3002\u5728500 mA g\u20131\u00a0(2C)\u65f6\uff0c\u5176\u53ef\u9006\u5bb9\u91cf\u4ecd\u4e3a149 mAh g\u20131\uff0c\u8868\u73b0\u51fa\u8f83\u597d\u7684\u500d\u7387\u6027\u80fd\u3002<\/p>\n

\"nl-2012-016957_0006\"<\/p>\n

\u56fe\u4e94 \u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7ebf\u500d\u7387\u6027\u80fd\u7814\u7a76<\/p>\n

2.2 \u5408\u91d1\u7c7b\u6750\u6599(Sn\uff0cSb\uff0cP\u7b49)<\/strong>
\n\u4f7f\u7528Na\u2013Me\uff08Me=Si\u3001Ge\u3001Sn\u3001Pb\u3001P\u3001As\u3001Sb\u3001Bi\uff09\u5408\u91d1\u7c7b\u6750\u6599\u7528\u4f5c\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u65f6\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf\uff0c\u8f83\u4f4e\u7684\u50a8\u94a0\u7535\u4f4d\uff0c\u826f\u597d\u7684\u5bfc\u7535\u6027<\/strong>\uff0c\u6b64\u5916\u8fd8\u53ef\u4ee5\u907f\u514d\u7531\u94a0\u5355\u8d28\u4ea7\u751f\u7684\u679d\u6676\u95ee\u9898\uff0c\u4f7f\u5176\u5b89\u5168\u6027\u5f97\u4ee5\u63d0\u9ad8\u3001\u4f7f\u7528\u5bff\u547d\u589e\u957f\u3002\u7531\u4e8e\u94a0\u79bb\u5b50\u79bb\u5b50\u6bd4\u8f83\u5927\uff0c\u5408\u91d1\u7c7b\u6750\u6599\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u53ef\u4ee5\u5b58\u50a8\u591a\u4e2a\u94a0\u79bb\u5b50\uff0c\u8fd9\u4f7f\u5f97\u7535\u6781\u6750\u6599\u4f53\u79ef\u53d8\u5316\u6bd4\u8f83\u5927\uff0c\u7834\u574f\u7535\u6781\u6750\u6599\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\uff0c\u4f7f\u5faa\u73af\u7a33\u5b9a\u6027\u53d8\u5dee\u3002\u56e0\u6b64\uff0c\u5bf9\u4e8e\u5408\u91d1\u7c7b\u6750\u6599\u800c\u8a00\uff0c\u63d0\u9ad8\u5176\u5faa\u73af\u7a33\u5b9a\u6027\u662f\u7814\u7a76\u7684\u91cd\u70b9\u3002<\/p>\n

Sn \u548cNa\u53ef\u4ee5\u53d1\u751f\u5408\u91d1\u5316\u53cd\u5e94\uff0cNa-Sn\u5408\u91d1\u53ef\u7528\u4f5c\u94a0\u79bb\u5b50\u8d1f\u6781\u6750\u6599\u3002\u4e00\u4e2aSn\u539f\u5b50\u6700\u591a\u53ef\u4ee5\u548c3.75\u4e2a\u94a0\u539f\u5b50\u7ed3\u5408\uff0c\u56e0\u6b64Sn\u5728\u5d4c\u94a0\/\u8131\u94a0\u7684\u8fc7\u7a0b\u4e2d\u4f1a\u4e0d\u53ef\u907f\u514d\u5730\u4ea7\u751f\u5de8\u5927\u7684\u81a8\u80c0\/\u6536\u7f29\u3002\u8fd9\u79cd\u7531\u4e8e\u5927\u4f53\u79ef\u53d8\u5316\u5f15\u8d77\u7684\u91cd\u590d\u6027\u7684\u7ed3\u6784\u53d8\u5316\u662f\u6b64\u7c7b\u7535\u6781\u6750\u6599\u5bb9\u91cf\u8870\u51cf\u7684\u4e3b\u8981\u539f\u56e0\u3002\u5f00\u53d1\u7eb3\u7c73\u590d\u5408\u6750\u6599\u6216\u6539\u6027\u5176\u7ed3\u6784\u6210\u4e3a\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u7684\u5173\u952e\u3002Sn0.9Cu0.1\u7eb3\u7c73\u9897\u7c92\u7528\u4f5c\u94a0\u79bb\u5b50\u8d1f\u6781\u6750\u6599\u65f6\uff0c\u5728\u500d\u7387\u4e3a0.2\uff23\u7684\u6761\u4ef6\u4e0b\uff0c\u7ecf\u8fc7100\u5468\u5faa\u73af\u5145\u653e\u7535\u540e\uff0c\u7535\u6c60\u7684\u53ef\u9006\u5bb9\u91cf\u4e3a420 mAh g-1\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a97%\uff0c\u8868\u73b0\u51fa\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd[6]\u3002<\/p>\n

\"Sn\"<\/p>\n

\u56fe\u516d \u57280.2C\uff08169mA g-1\uff09\u5faa\u73af\u65f6\uff0cSn0.9Cu0.1\u7eb3\u7c73\u9897\u7c92\u3001Sn\u7eb3\u7c73\u9897\u7c92\u3001Sn\u5fae\u7c92\u7535\u6781\u7684\u653e\u7535\u5bb9\u91cf\uff08a\uff09\u548c\u5e93\u4f26\u6548\u7387\uff08b\uff09\u56fe<\/p>\n

2.3 \u8f6c\u5316\u7c7b\u6750\u6599(\u91d1\u5c5e\u6c27\u5316\u7269\/\u786b\u5316\u7269)<\/strong>
\n\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u5982\uff1aFe2O3\u3001CuO\u3001CoO\u3001MoO3\u3001NiCo2O4\u7b49\uff0c\u53ef\u7528\u4f5c\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u3002Fe3O4\uff0c\u7406\u8bba\u5bb9\u91cf\u4e3a926 mAh g-1\uff0c\u5f53\u7528\u4f5c\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff0c\u5728\u8f6c\u5316\u53cd\u5e94\u7684\u8fc7\u7a0b\u4e2d\uff0c\u94a0\u79bb\u5b50\u7684\u5d4c\u5165Fe3O4\u4f1a\u751f\u6210\u91d1\u5c5eFe\u548cNa2O[7]\u3002\u5176\u9996\u6b21\u653e\u7535\u5bb9\u91cf\u4e3a643mAh g-1\uff0c\u5145\u7535\u5bb9\u91cf\u4e3a366 mAh g-1\uff0c\u5e93\u4f26\u6548\u7387\u8f83\u9ad8\uff0c\u53ef\u8fbe\u523057%\uff0c10\u4e2a\u5faa\u73af\u540e\u5176\u5bb9\u91cf\u4ecd\u4e3a\u8d77\u59cb\u5145\u7535\u5bb9\u91cf\u768465%\u3002<\/p>\n

\"Fe\"<\/p>\n

\u56fe\u4e03 Fe3O4\u57280.04\u20133.0 V vs. Na\/Na+\uff0c\u4ee50.06C\u6052\u7535\u6d41\u5faa\u73af\u65f6\u7684\u7535\u538b\u66f2\u7ebf<\/p>\n

\u4f46\u662f\u91d1\u5c5e\u6c27\u5316\u7269\u7c7b\u8d1f\u6781\u6750\u6599\u7531\u4e8e\u5176\u81ea\u8eab\u5bfc\u7535\u6027\u8f83\u5dee\u4ee5\u53ca\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4f1a\u4ea7\u751f\u8f83\u5927\u7684\u4f53\u79ef\u81a8\u80c0\uff0c\u4f1a\u7834\u574f\u7535\u6781\u6750\u6599\u7684\u5b8c\u6574\u6027\uff0c\u5bfc\u81f4\u8f83\u5dee\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u9700\u8981\u901a\u8fc7\u8bbe\u8ba1\u4e00\u4e9b\u65b0\u578b\u7684\u5177\u5907\u5fae\u7eb3\u7ed3\u6784\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u6539\u5584\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002
\n2.4 \u6709\u673a\u7535\u6781\u6750\u6599<\/strong><\/p>\n

\"Na\"<\/p>\n

\u56fe\u516b \u672a\u5904\u7406\u7684Na2C8H4O4\u7535\u6781\u53ca\u539f\u5b50\u5c42\u6c89\u79ef\u6280\u672f\u5904\u7406\u540e\u7684Na2C8H4O4\u4e24\u7c7b\u7535\u6781\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

Na2C8H4O4\u88ab\u5f15\u5165\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u8868\u73b0\u51fa\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5728 0.29 V vs Na+\/Na\u65f6\uff0c\u5177\u6709\u8f83\u4f4e\u7684\u94a0\u5d4c\u5165\u7535\u538b[8]\u3002\u4f34\u968f\u77402\u4e2a\u7535\u8377\u7684\u8f6c\u79fb\uff0c\u5176\u53ef\u9006\u5bb9\u91cf\u4e3a250 mAh g\u22121\uff0c\u5177\u6709\u826f\u597d\u7684\u5faa\u73af\u6027\u80fd\u3002
\n\u5c3d\u7ba1\u5728\u5bb9\u91cf\u548c\u5de5\u4f5c\u7535\u538b\u65b9\u9762\u7fa7\u9178\u7c7b\u6709\u673a\u5206\u5b50\u53ef\u4ee5\u63d0\u4f9b\u76f8\u5bf9\u826f\u597d\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4f46\u662f\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u6027\u80fd\u7684\u95ee\u9898\u4ecd\u7136\u6709\u5f85\u89e3\u51b3\u3002\u901a\u8fc7\u6539\u53d8\u5206\u5b50\u7ed3\u6784\u3001\u8fdb\u884c\u8868\u9762\u6d82\u8986\u3001\u805a\u5408\u7b49\u65b9\u5f0f\uff0c\u4f7f\u5f97\u94a0\u79bb\u5b50\u7535\u6c60\u6709\u673a\u8d1f\u6781\u6750\u6599\u6027\u80fd\u6709\u6240\u63d0\u9ad8\u5c06\u6210\u4e3a\u7814\u7a76\u7684\u91cd\u70b9\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong>
\n\u94a0\u5143\u7d20\u5177\u6709\u4e0e\u9502\u76f8\u4f3c\u7684\u7535\u5316\u5b66\u6027\u8d28\uff0c\u4e14\u5176\u8d44\u6e90\u4e30\u5bcc\uff0c\u6240\u4ee5\uff0c\u5728\u672a\u6765\u7684\u53d1\u5c55\u4e2d\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\u5177\u6709\u5f88\u5e7f\u9614\u7684\u524d\u666f\u3002\u968f\u7740\u7535\u6781\u6750\u6599\u7814\u7a76\u7684\u8fdb\u884c\u548c\u53d1\u5c55\uff0c\u901a\u8fc7\u8bbe\u8ba1\u5fae\u7eb3\u7ed3\u6784\u6216\u5236\u5907\u78b3\u590d\u5408\u6750\u6599\uff0c\u4f18\u5316\u7535\u89e3\u6db2\u7b49\u5c06\u4f7f\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u5bb9\u91cf\u548c\u7535\u538b\u53ca\u5176\u7a33\u5b9a\u6027\u5f97\u5230\u8fdb\u4e00\u6b65\u7684\u63d0\u9ad8\uff0c\u5bf9\u4e8e\u7535\u8f66\uff0c\u667a\u80fd\u7535\u7f51\u7c7b\u5927\u578b\u50a8\u80fd\u7cfb\u7edf\u7684\u5e94\u7528\u4e5f\u5c06\u8d77\u5230\u4e00\u5b9a\u7684\u63a8\u52a8\u4f5c\u7528\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a
\n[1]Electrochemical intercalation activity of layered NaCrO2\u00a0vs. LiCrO2<\/a>
\n[2]Reversible NaFePO4 electrode for sodium secondary batteries<\/a>
\n[3]Single-crystal\u00a0FeFe(CN)6\u00a0nanoparticles:\u00a0a\u00a0high\u00a0capacity\u00a0and\u00a0high\u00a0rate\u00a0cathode\u00a0for\u00a0Na-ion batteries<\/a>
\n[4]An Organic Pigment as a High-Performance Cathode for Sodium-Ion Batteries<\/a>
\n[5]Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications<\/a>
\n[6]Sn\u2013Cu Nanocomposite Anodes for Rechargeable Sodium-Ion Batteries<\/a>
\n[7]A rationally designed dual role anode material for lithium-ion and sodium-ion batteries: case study of eco-friendly Fe3O4<\/a>
\n[8]Disodium Terephthalate (Na2C8H4O4) as High Performance Anode Material for Low-Cost Room-Temperature Sodium-Ion Battery<\/a><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u7ec4 NeverSayBye<\/strong> \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002
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