{"id":32297,"date":"2016-08-10T08:10:22","date_gmt":"2016-08-10T00:10:22","guid":{"rendered":"\/\/m.iemloyee.com\/?p=32297"},"modified":"2016-08-10T12:25:11","modified_gmt":"2016-08-10T04:25:11","slug":"nat-mater-%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e7%94%b5%e5%8c%96%e5%ad%a6%e5%88%9a%e5%ba%a6%e7%9a%84%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=32297","title":{"rendered":"Nat. Mater. \u9502\u79bb\u5b50\u7535\u6c60\u7535\u5316\u5b66\u521a\u5ea6\u7684\u7814\u7a76"},"content":{"rendered":"<p>\u3010\u5f15\u8bed\u3011\u9502\u79bb\u5b50\u7535\u6c60\u662f\u4e00\u79cd\u9502\u79bb\u5b50\u5faa\u73af\u4e8e\u4e24\u7535\u6781\u4e4b\u95f4\u7684\u7535\u5316\u5b66\u80fd\u91cf\u5b58\u50a8\u8bbe\u5907\u3002\u5176\u4e2d\uff0c\u9502\u79bb\u5b50\u4ece\u7535\u6781\u8131\u5d4c\u8fc7\u7a0b\u4e2d\u4f1a\u9020\u6210\u7535\u6781\u53d1\u751f\u663e\u8457\u7684\u673a\u68b0\u53d8\u5316\uff0c\u4ece\u800c\u5bfc\u81f4\u7535\u6781\u7684\u500d\u7387\u6027\u80fd\u90e8\u5206\u53d7\u9650\u3002\u5728\u7535\u6c60\u5145\u7535\u548c\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u9502\u79bb\u5b50\u4e0e\u7535\u6781\u6750\u6599\u7684\u76f8\u4e92\u4f5c\u7528\u4f1a\u4ea7\u751f\u7535\u6781\u7ed3\u6784\u5185\u90e8\u538b\u529b\uff08\u5e94\u529b\uff09\u3002\u7535\u5316\u5b66\u7cfb\u7edf\u4e2d\u7684\u5e94\u529b\u6d4b\u91cf\u901a\u5e38\u662f\u7814\u7a76\u53d1\u751f\u5728\u7535\u6781\u6750\u6599\u7684\u4e9a\u5355\u5c42\u4e0b\u76f8\u4e92\u4f5c\u7528\u3002\u5728\u7535\u6c60\u7535\u6781\u4e2d\uff0c\u9502\u79bb\u5b50\u5d4c\u5165\u6548\u5e94\u662f\u5f71\u54cd\u7cfb\u7edf\u7684\u5e94\u529b\u54cd\u5e94\u7684\u4e3b\u8981\u56e0\u7d20\u3002\u7535\u6781\u6750\u6599\u5728\u9502\u5316\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u538b\u5e94\u529b\uff0c\u5728\u8131\u9502\u8fc7\u7a0b\u4e2d\u538b\u5e94\u529b\u91ca\u653e\uff0c\u5176\u4e2d\u9502\u79bb\u5b50\u4ea4\u6362\u673a\u5236\uff08\u4f8b\u5982\uff0c\u77f3\u58a8\u7535\u6781\u4e2d\u7684\u63d2\u5c42\u3001\u7845\u7535\u6781\u4e2d\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u6216\u9521\u57fa\u7535\u6781\u4e2d\u5408\u91d1\u7684\u5f62\u6210\uff09\u63a7\u5236\u5e94\u529b\u91ca\u653e\u54cd\u5e94\u3002\u9664\u4e86\u5e94\u529b\u4ea7\u751f\uff0c\u9502\u79bb\u5b50\u4e0e\u7535\u6781\u7684\u76f8\u4e92\u4f5c\u7528\u8fd8\u4f1a\u5f15\u8d77\u7535\u6781\u7684\u4f53\u79ef\u53d8\u5316\u4ee5\u53ca\u6d3b\u6027\u7269\u8d28\u7684\u4f4d\u79fb\uff08\u5e94\u53d8\uff09\u3002\u7535\u6781\u6750\u6599\u5728\u9502\u5316\u7684\u8fc7\u7a0b\u4e2d\u81a8\u80c0\uff0c\u800c\u5728\u8131\u9502\u540e\u6536\u7f29\u3002<\/p>\n<p>\u7535\u5316\u5b66\u884c\u4e3a\u4f1a\u5f71\u54cd\u7535\u6c60\u7535\u6781\u5728\u9ad8\u500d\u7387\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u5e94\u529b\u548c\u5e94\u53d8\u7684\u4ea7\u751f\u3002\u590d\u5408\u7535\u6781\u6750\u6599\u7684\u5e94\u53d8\u5206\u6790\u8868\u660e\uff0c\u8131\u5d4c\u9502\u53d1\u751f\u5728\u6d3b\u6027\u6750\u6599\u7684\u5355\u4e2a\u9897\u7c92\u6216\u6574\u4e2a\u590d\u5408\u7535\u6781\u7684\u5f02\u8d28\u7ed3\u6784\u4e2d\u3002\u5728\u9502\u79bb\u5b50\u5728\u9ad8\u500d\u7387\u4e0b\u8131\u5d4c\u7684\u8fc7\u7a0b\u4e2d\uff0c\u8fd9\u79cd\u5f02\u8d28\u6027\u66f4\u662f\u4f1a\u9020\u6210\u5f3a\u70c8\u7684\u5e94\u529b\u548c\u5e94\u53d8\u68af\u5ea6\uff0c\u6700\u7ec8\u5bfc\u81f4\u7535\u6781\u7684\u5316\u5b66\u548c\u7269\u7406\u6027\u80fd\u7684\u9000\u5316\u3002\u867d\u7136\u9502\u5728\u77f3\u58a8\u8d1f\u6781\u7684\u6269\u6563\u52a8\u529b\u5b66\u5df2\u7ecf\u88ab\u5982\u963b\u6297\u8c31\u7684\u7535\u5316\u5b66\u65b9\u6cd5\u6240\u7814\u7a76\uff0c\u4f46\u52a8\u529b\u5b66\u6548\u5e94\u5bf9\u5e94\u529b\u548c\u5e94\u53d8\u53d1\u5c55\u7684\u5f71\u54cd\u4efb\u7136\u662f\u4e0d\u786e\u5b9a\u3002<\/p>\n<p>\u867d\u7136\u9502\u79bb\u5b50\u7535\u6c60\u5df2\u7ecf\u5e7f\u6cdb\u4e0e\u7528\u4e8e\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u4e4b\u4e2d\uff0c\u4f46\u5bf9\u4e8e\u7535\u52a8\u6c7d\u8f66\u8fd9\u7c7b\u8fd0\u7528\u6765\u8bf4\u5c31\u8981\u6c42\u7535\u6c60\u80fd\u6ee1\u8db3\u5177\u6709\u66f4\u9ad8\u7684\u5145\u7535\u500d\u7387\u548c\u653e\u7535\u529f\u7387\u7684\u6807\u51c6\u3002\u800c\u6ee1\u8db3\u66f4\u529f\u7387\u548c\u5feb\u901f\u5145\u7535\u7684\u9502\u79bb\u5b50\u5728\u9ad8\u500d\u7387\u8f6c\u5316\u7684\u8fc7\u7a0b\u4e2d\uff0c\u4f1a\u5728\u7535\u6781\u4e2d\u4ea7\u751f\u663e\u8457\u7684\u5e94\u529b\u548c\u5e94\u53d8\uff0c\u6700\u7ec8\u5bfc\u81f4\u6027\u80fd\u7684\u9000\u5316\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u5728\u7535\u6c60\u7684\u7535\u6781\u4e2d\u5bf9\u4e8e\u7535\u5316\u5b66\u8bf1\u5bfc\u5e94\u529b\u548c\u5e94\u53d8\u53ea\u8fdb\u884c\u4e86\u4e2a\u522b\u7814\u7a76\u3002\u8fd1\u65e5\uff0c\u7f8e\u56fd\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66\u5384\u5df4\u7eb3-\u9999\u69df\u5206\u6821\u7684<span style=\"color: #ff0000;\"><strong>Andrew A. Gewirth<\/strong><\/span>\u6559\u6388\u548c<span style=\"color: #ff0000;\"><strong>Nancy R. Sottos<\/strong><\/span>\u6559\u6388\u7b49\u4eba\u8054\u5408\u5728Nat. Mater.\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\u201c<span style=\"color: #ff0000;\"><strong>Electrochemical sti_ness in lithium-ion batteries<\/strong><\/span>\u201d\u3002<\/p>\n<p><strong>\u8fd9\u9879\u5de5\u4f5c\u7684<span style=\"color: #ff0000;\">\u4e3b\u8981\u5185\u5bb9<\/span>\u4e3a<\/strong>\uff1a\u7814\u7a76\u5c0f\u7ec4\u901a\u8fc7\u7ed3\u5408\u77f3\u58a8\u590d\u5408\u7535\u6781\u5728\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u539f\u4f4d\u5e94\u529b\u548c\u5e94\u53d8\u6d4b\u91cf\u8ba1\u7b97\u51fa\u7535\u6781\u7684\u7535\u5316\u5b66\u521a\u5ea6\u3002\u5176\u4e2d\uff0c\u7535\u5316\u5b66\u521a\u5ea6\u662f\u901a\u8fc7\u6d4b\u91cf\u7535\u6781\u7535\u4f4d\u548c\u5bb9\u91cf\u4e0e\u5e94\u529b\u548c\u5e94\u53d8\u54cd\u5e94\u7684\u4f9d\u8d56\u5173\u7cfb\u5f97\u5230\u7684\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u4e3a\u4e2a\u522b\u76f8\u53d8\u5bf9\u7535\u6781\u7684\u673a\u68b0\u54cd\u5e94\u7684\u5f71\u54cd\u4ee5\u53ca\u5bf9\u9502\u4ece\u5bbf\u4e3b\u6750\u6599\u8131\u5d4c\u7684\u52a8\u529b\u5b66\u9650\u5236\u63d0\u4f9b\u4e86\u65b0\u7684\u89c1\u89e3\u3002\u8fd9\u79cd\u65b9\u6cd5\u4e5f\u4e3a\u5ba1\u67e5\u65b0\u578b\u7535\u6c60\u6750\u6599\u63d0\u4f9b\u4e86\u6709\u529b\u5206\u6790\u5de5\u5177\uff0c\u5e76\u6709\u5229\u4e8e\u5927\u529f\u7387\u548c\u9ad8\u500d\u7387\u7535\u6c60\u6750\u6599\u7684\u8bbe\u8ba1\u3002<\/p>\n<p><strong><span style=\"color: #ff0000;\">\u56fe\u6587\u5bfc\u8bfb\uff1a<\/span><\/strong><\/p>\n<p><span style=\"color: #333333;\"><strong>\u56fe1\uff1a\u7535\u5316\u5b66\u521a\u5ea6\u8ba1\u7b97\u65b9\u6cd5\u3002<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32298 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98981-1.jpg\" alt=\"\u65e0\u6807\u98981\" width=\"277\" height=\"251\" \/><\/p>\n<p>\uff08a\uff09\u539f\u4f4d\u5e94\u529b\u6d4b\u91cf\u793a\u610f\u56fe\u3002\u5e94\u529b\u72b6\u6001\u672a\u77e5\u7684\u7535\u6781\u9644\u5728\u886c\u5e95\u4e0a\u3002\u7b2ca1\u6b65\uff0c\u5728\u9502\u5316\u8fc7\u7a0b\u4e2d\u886c\u5e95\u9650\u5236\u4e86\u7535\u6781\u7684\u81ea\u7531\u81a8\u80c0\uff0c\u56e0\u6b64\u5728\u7535\u6781\u4e2d\u51fa\u73b0\u4e00\u4e2a\u5e94\u529b\u53d8\u5316\uff08\u8bb0\u4e3a\u25b3\u03c3\uff09\uff0c\u5bfc\u81f4\u886c\u5e95\u51fa\u73b0\u66f2\u7387C\u3002\u7b2ca2\u6b65\uff0c\u5047\u8bbe\u4e00\u4e2a\u5916\u529bf\u538b\u7f29\u7535\u6781\u4f7f\u5f97\u5f2f\u66f2\u88ab\u6d88\u9664\u3002<br \/>\n\uff08b\uff09\u539f\u4f4d\u5e94\u53d8\u6d4b\u91cf\u793a\u610f\u56fe\u3002\u7b2cb1\u6b65\uff0c\u4e00\u4e2a\u65e0\u7ea6\u675f\u7684\u3001\u5927\u5c0f\u4e3aL\u7684\u7535\u6781\u5728\u7406\u5316\u8fc7\u7a0b\u4e2d\u81ea\u7531\u81a8\u80c0\uff0c\u4ea7\u751f\u5e94\u53d8\u03b5\u3002\u7b2cb2\u6b65\uff0c\u5047\u8bbe\u540c\u6837\u7684\u5916\u529bf\u6765\u538b\u7f29\u7535\u6781\u4f7f\u5176\u53d8\u56de\u539f\u59cb\u5927\u5c0f\u3002<br \/>\n\uff08c\uff09\u6b65\u9aa4a2\u548cb2\u5904\u7406\u540e\u7684\u7535\u6781\u5177\u6709\u76f8\u540c\u7684\u5927\u5c0f\u548c\u5e94\u529b\u72b6\u6001\uff0c\u5728\u521a\u5ea6\u8ba1\u7b97\u4e2d\u88ab\u89c6\u4e3a\u76f8\u540c\u7684\u7535\u6781\u3002<\/p>\n<p><span style=\"color: #333333;\"><strong>\u56fe2: \u5faa\u73af\u4f0f\u5b89\u6cd5\u4e2d\u7535\u4f4d\u4f9d\u8d56\u6027\u7535\u6781\u54cd\u5e94\u3002<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32299 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98982-1.jpg\" alt=\"\u65e0\u6807\u98982\" width=\"361\" height=\"580\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98982-1.jpg 361w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98982-1-187x300.jpg 187w\" sizes=\"(max-width: 361px) 100vw, 361px\" \/><\/p>\n<p>(a-c)\u5206\u522b\u4e3a\u77f3\u58a8\u8d1f\u6781\u7684\u7b2c\u4e09\u6b21\u5faa\u73af\u4f0f\u5b89\u7279\u6027\u66f2\u7ebf\u3001\u5faa\u73af\u8fc7\u7a0b\u4e2d\u76f8\u5e94\u7684\u5e94\u529b\u3001\u5e94\u53d8\u3002\uff08\u6d4b\u8bd5\u901f\u7387\u4e3a25\u03bcVs<sup>-1<\/sup>\uff09<\/p>\n<p>\u5f69\u8272\u533a\u57df\u4ee3\u8868\u5bf9\u5e94\u7684\u77f3\u58a8-\u9502\u63d2\u5c42\u5316\u5408\u7269\u5728\u6b63\u6781\u626b\u63cf\u8fc7\u7a0b\u4e2d\u7684\u76f8\u53d8\uff1a1\uff0c\u5f62\u6210\u7a00\u91ca\u9636\u6bb5I\uff1b2\uff0c\u7a00\u91ca\u9636\u6bb5I\u5230\u9636\u6bb5IV\uff1b3\uff0c\u9636\u6bb5IV\u5230\u9636\u6bb5III\u518d\u5230\u7a00\u9636\u6bb5II\uff1b4\uff0c\u9636\u6bb5II\u5230\u9636\u6bb5II\uff1b5\uff0c\u9636\u6bb5II\u5230\u9636\u6bb5I\u3002<\/p>\n<p><strong><span style=\"color: #ff0000;\">\u5206\u6790\uff1a<\/span><\/strong><\/p>\n<p>\u7531\u4e8e\u5728\u4e24\u4e2a\u5468\u671f\u4e2d\u4ea7\u751f\u7684\u4e0d\u53ef\u6062\u590d\u5e94\u529b\u548c\u5e94\u53d8\uff0c\u5728\u5faa\u73af\u5f00\u59cb\u65f6\uff081.0V\uff09\u5c31\u6709\u7ea6-9.5MPa\u7684\u538b\u5e94\u529b\u548c\u7ea60.41%\u7684\u81a8\u80c0\u5e94\u53d8\u3002\u4e0d\u53ef\u9006\u7535\u6781\u54cd\u5e94\u7684\u4ea7\u751f\u4e3b\u8981\u5f52\u56e0\u4e8e\u5728\u56fa\u4f53\u7535\u89e3\u8d28\u8584\u819c\u4ea7\u751f\u65f6\u53d1\u751f\u7684\u4e0d\u53ef\u9006\u7535\u5316\u5b66\u53cd\u5e94\u3002\u5728\u6b63\u67811.0V\u52300.3V\u626b\u63cf\u8fc7\u7a0b\u4e2d\uff0c\u7535\u6d41\u4e0e\u65e0\u5e8f\u70ad\u9ed1\u7684\u9502\u5316\u548c\u77f3\u58a8\u65e9\u671f\u9502\u5316\u4ee5\u53ca\u6301\u7eed\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u5f62\u6210\u7684\u9502\u5316\u6709\u5173\u3002\u5728\u8fd9\u4e2a\u7535\u538b\u8303\u56f4\u5185\uff0c\u5728\u7ea6\u675f\u7684\u7535\u6781\u4e2d\u4ea7\u751f\u4e00\u4e2a\u5c0f\u7684\u538b\u5e94\u529b\uff0c\u800c\u65e0\u7ea6\u675f\u7684\u7535\u6781\u7a0d\u5fae\u6269\u5927\u3002\u5728\u66f4\u8d1f\u7684\u7535\u4f4d\u8303\u56f4\u4e2d\uff08\u7ea60.3v-0.01 V\uff09\uff0c\u4f0f\u5b89\u6cd5\u663e\u793a\u51fa\u5bf9\u5e94\u4e8e\u4e0d\u540c\u7684\u77f3\u58a8\u5d4c\u9502\u5316\u5408\u7269\u4e4b\u95f4\u7684\u76f8\u53d8\u3002\u5728\u6b64\u4f4e\u7535\u538b\u8303\u56f4\u4e2d\u7684\u63d2\u9502\u5316\u5408\u7269\u7684\u5f62\u6210\u5bfc\u81f4\u7684\u5e94\u529b\u4e0e\u5e94\u53d8\u6bd4\u4f8b\u7684\u5feb\u901f\u5730\u53d8\u5316\u3002\u800c\u5728\u8d1f\u6781\u626b\u63cf\u8fc7\u7a0b\u4e2d\uff0c\u538b\u5e94\u529b\u89e3\u9664\uff0c\u7535\u6781\u6536\u7f29\u3002<\/p>\n<p><span style=\"color: #333333;\"><strong>\u56fe3\uff1a\u5e94\u529b\u3001\u5e94\u53d8\u7684\u6d4b\u91cf\u53ca\u7535\u5316\u5b66\u521a\u5ea6\u7684\u8ba1\u7b97\u3002<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32300 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98983-1.jpg\" alt=\"\u65e0\u6807\u98983\" width=\"628\" height=\"274\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98983-1.jpg 628w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98983-1-300x131.jpg 300w\" sizes=\"(max-width: 628px) 100vw, 628px\" \/><\/p>\n<p>\uff08a\uff09\u5faa\u73af\u8fc7\u7a0b\u4e2d\u76f8\u5e94\u7684\u5e94\u529b\u3001\u5e94\u53d8\u76f8\u5e94\u53d6\u81ea\u77f3\u58a8\u8d1f\u6781\u7684\u7b2c\u4e09\u6b21\u5faa\u73af\u4f0f\u5b89\u7279\u6027\u66f2\u7ebf\u4e2d\u5bf9\u5e94\u7684\u6bcf\u4e00\u4e2a\u7535\u4f4d\u503c\uff08\u6d4b\u8bd5\u901f\u7387\u4e3a25\u03bcVs<sup>-1<\/sup>\uff09\u3002\u865a\u7ebf\u4ee3\u8868\u589e\u91cf0.05\/Li<sup>+\/0<\/sup>\u7535\u538b\u7b49\u503c\u7ebf\u3002\u77f3\u58a8\u7535\u6781\u8131\u5d4c\u9502\u8fc7\u7a0b\u4e2d\uff0c\u4e0d\u540c\u7684\u63d2\u5c42\u5316\u5408\u7269\u7684\u5f62\u6210\u5bfc\u81f4\u4e0d\u540c\u7684\u5e94\u529b\u4e0e\u5e94\u53d8\u659c\u7387\u7684\u53d8\u5316\u3002<br \/>\n\uff08b\uff09\u5faa\u73af\u4f0f\u5b89\u6cd5\u6b63\u6781\u626b\u63cf\u8fc7\u7a0b\u4e2d\u7535\u6781\u7535\u4f4d\u4f9d\u8d56\u6027\u521a\u5ea6\u53d8\u5316\u7684\u7814\u7a76\u3002\u5728\u5468\u671f\u5f00\u59cb\u65f6\uff0cY\u8f74\u662f\u5bf9\u521a\u5ea6\u503c\u8fdb\u884c\u5f52\u4e00\u5316\u540e\u7684\u503c\u3002\u5f69\u8272\u533a\u57df\u4ee3\u8868\u5bf9\u5e94\u7684\u77f3\u58a8-\u9502\u63d2\u5c42\u5316\u5408\u7269\u5728\u6b63\u6781\u626b\u63cf\u8fc7\u7a0b\u4e2d\u7684\u76f8\u53d8\uff1a1\uff0c\u5f62\u6210\u7a00\u91ca\u9636\u6bb5I\uff1b2\uff0c\u7a00\u91ca\u9636\u6bb5I\u5230\u9636\u6bb5IV\uff1b3\uff0c\u9636\u6bb5IV\u5230\u9636\u6bb5III\u518d\u5230\u9636\u6bb5II\uff1b4\uff0c\u9636\u6bb5II\u5230\u9636\u6bb5II\uff1b5\uff0c\u9636\u6bb5II\u5230\u9636\u6bb5I\u3002<\/p>\n<p><strong><span style=\"color: #ff0000;\">\u5206\u6790\uff1a<\/span><\/strong>\u5728\u6b63\u6781\u626b\u63cf\u7684\u5f00\u59cb\u9636\u6bb5\uff0c\u7531\u4e8e\u5c11\u91cf\u7684\u9502\u79bb\u5b50\u5d4c\u5165\u5230\u77f3\u58a8\u4ece\u800c\u7acb\u5373\u5f62\u6210\u5e94\u529b\u548c\u6700\u5c0f\u7684\u5e94\u53d8\u91cf\uff0c\u7535\u6781\u4e5f\u56e0\u6b64\u8868\u73b0\u51fa\u6700\u521d\u7684\u54cd\u5e94\u3002\u5728\u7a00\u9636\u6bb5I\u7684\u77f3\u58a8\u5d4c\u9502\u5316\u5408\u7269\u7684\u5f62\u6210\u8fc7\u7a0b\uff08\u7ea60.3V\uff09\u4e2d\uff0c\u4e00\u65e6\u6709\u8db3\u591f\u7684\u79bb\u5b50\u63d2\u5165\u77f3\u58a8\u5c42\u4e2d\uff0c\u5c42\u95f4\u8ddd\u5c31\u4f1a\u660e\u663e\u5730\u589e\u52a0\uff0c\u5e94\u53d8\u7684\u53d8\u5316\u901f\u7387\u5c06\u8fbe\u5230\u4e00\u4e2a\u66f4\u5feb\u7684\u503c\u3002\u800c\u5728\u6b64\u4e4b\u540e\uff0c\u5e94\u53d8\u7684\u589e\u52a0\u5c06\u5bfc\u81f4\u7684\u7535\u6781\u7684\u521a\u5ea6\u76f8\u5e94\u7684\u51cf\u5c11\u3002<\/p>\n<p><span style=\"color: #333333;\"><strong>\u56fe4\uff1a\u5e94\u529b\u548c\u5e94\u53d8\u7684\u5f02\u6b65\u53d8\u5316<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32301 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98984.jpg\" alt=\"\u65e0\u6807\u98984\" width=\"627\" height=\"598\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98984.jpg 627w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98984-300x286.jpg 300w\" sizes=\"(max-width: 627px) 100vw, 627px\" \/><\/p>\n<p>\uff08a\uff09\u6b63\u6781\u626b\u63cf\u8fc7\u7a0b\u4e2d\uff0c\u77f3\u58a8\u8d1f\u6781\u7684\u7b2c\u4e09\u6b21\u5faa\u73af\u4f0f\u5b89\u7279\u6027\u66f2\u7ebf\uff08\u6d4b\u8bd5\u901f\u7387\u4e3a25\u03bcVs<sup>-1<\/sup>\uff09\u5bf9\u5e94\u7684\u7535\u6d41\u54cd\u5e94\u3002<br \/>\n\uff08b\uff09\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u7535\u6d41\u54cd\u5e94\u5bf9\u5e94\u7684\u5e94\u529b\u79ef\u7d2f\u901f\u7387\u3002<br \/>\n\uff08c\uff09\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u7535\u6d41\u54cd\u5e94\u5bf9\u5e94\u7684\u5e94\u53d8\u79ef\u7d2f\u901f\u7387\u3002\u5f69\u8272\u533a\u57df\u4ee3\u8868\u5bf9\u5e94\u7684\u77f3\u58a8-\u9502\u63d2\u5c42\u5316\u5408\u7269\u5728\u6b63\u6781\u626b\u63cf\u8fc7\u7a0b\u4e2d\u7684\u76f8\u53d8\uff1a1\uff0c\u5f62\u6210\u7a00\u91ca\u9636\u6bb5I\uff1b2\uff0c\u9636\u6bb5I\u5230\u9636\u6bb5IV\uff1b3\uff0c\u9636\u6bb5IV\u5230\u9636\u6bb5III\u518d\u5230\u9636\u6bb5II\uff1b4\uff0c\u7a00\u9636\u6bb5II\u5230\u9636\u6bb5II\uff1b5\uff0c\u9636\u6bb5II\u5230\u9636\u6bb5I\u3002<br \/>\n\uff08d\uff09\u9636\u6bb5I\uff08b\u56fe\u4e2d\u7684\u865a\u7ebf\u5708\uff09\u5f62\u6210\u540e\u4e3b\u5bfc\u5e94\u529b\u53d8\u5316\u7684\u793a\u610f\u56fe\u3002<br \/>\n\uff08e\uff09\u5e94\u53d8\u53d8\u5316\u7684\u540c\u65f6\uff0c\u9636\u6bb5IV\u5f62\u6210\uff08c\u56fe\u4e2d\u7684\u865a\u7ebf\u5708\uff09\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><strong><span style=\"color: #ff0000;\">\u5206\u6790\uff1a<\/span><\/strong>\u5728\u56fe4\u4e2d\u6240\u89c2\u5bdf\u5230\u7684\u5e94\u529b\u548c\u5e94\u53d8\u7684\u5f02\u6b65\u53d8\u5316\u9996\u6b21\u8868\u660e\u4e86\uff1a\u5728\u77f3\u58a8\u7535\u6781\u4e2d\u5e94\u529b\u548c\u5e94\u53d8\u7684\u54cd\u5e94\u662f\u4e0d\u540c\u7684\u76f8\u5173\u65f6\u95f4\uff08\u52a8\u529b\u5b66\uff09\u4f9d\u8d56\u6027\u4ee5\u53ca\u7535\u4f4d\uff08\u70ed\u529b\u5b66\uff09\u4f9d\u8d56\u6027\u73b0\u8c61\u7684\u7ed3\u679c\u3002<\/p>\n<p><span style=\"color: #333333;\"><strong>\u56fe5\uff1a\u7535\u4f4d\u626b\u63cf\u901f\u5ea6\u5bf9\u77f3\u58a8\u7535\u6781\u5e94\u529b\u548c\u5e94\u53d8\u53d8\u5316\u7684\u5f71\u54cd\u3002<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32302 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98985.jpg\" alt=\"\u65e0\u6807\u98985\" width=\"504\" height=\"539\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98985.jpg 504w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u65e0\u6807\u98985-281x300.jpg 281w\" sizes=\"(max-width: 504px) 100vw, 504px\" \/><\/p>\n<p>\uff08a-d\uff09\u5206\u522b\u4e3a\u77f3\u58a8\u8d1f\u6781\u7684\u7b2c\u4e09\u6b21\u5faa\u73af\u4f0f\u5b89\u7279\u6027\u66f2\u7ebf\uff08\u6d4b\u8bd5\u901f\u7387\u4e3a10\u03bcVs<sup>-1<\/sup>\u300125\u03bcVs<sup>-1<\/sup>\u3001100\u03bcVs<sup>-1<\/sup>\uff09\u4e2d\u5bf9\u5e94\u7684\u7535\u6d41\u3001\u6bd4\u5bb9\u91cf\u3001\u5e94\u529b\u539a\u5ea6\uff08stress-thickness\uff09\u3001\u5e94\u53d8\u54cd\u5e94\u503c\u3002<\/p>\n<p>\u4e3a\u4e86\u66f4\u597d\u7684\u6bd4\u8f83\uff0c\u4e0d\u540c\u7684\u626b\u63cf\u901f\u7387\u7684\u5e94\u529b\u548c\u5e94\u53d8\u503c\u88ab\u8f6c\u6362\u4e3a\u4ece\u96f6\u5f00\u59cb\u3002\u4e0b\u964d\u7bad\u5934\u4ee3\u8868\u6b63\u6781\u626b\u63cf\uff08\u5d4c\u9502\uff09\u968f\u7535\u538b\u7684\u53d8\u5316\uff0c\u4e0a\u5347\u7bad\u5934\u4ee3\u8868\u8d1f\u6781\u626b\u63cf\uff08\u8131\u9502\uff09\u968f\u7535\u538b\u7684\u53d8\u5316\u3002<\/p>\n<p><span style=\"color: #ff0000;\"><strong>\u5206\u6790\uff1a<\/strong><\/span>\u8f83\u6162\u7684\u626b\u63cf\u901f\u7387\u4f0f\u5b89\u8868\u73b0\u51fa\u5bf9\u5e94\u7684\u5d4c\u9502\u8fc7\u7a0b\u66f4\u52a0\u6e05\u6670\uff0c\u8d8a\u6162\u7684\u9502\u5316\u901f\u7387\u4ea7\u751f\u7684\u7535\u6d41\u5927\u5c0f\u8d8a\u5c0f<span style=\"color: #ff6600;\">\uff08\u56fe5a\uff09<\/span>\uff0c\u6bd4\u5bb9\u91cf\u8d8a\u9ad8\uff0c\u5373\u603b\u9502\u542b\u91cf\u8d8a\u9ad8<span style=\"color: #ff6600;\">\uff08\u56fe5b\uff09<\/span>\u3002\u6709\u8da3\u7684\u662f\uff0c\u5e94\u529b\u7684\u5927\u5c0f<span style=\"color: #ff6600;\">\uff08\u56fe5c\uff09<\/span>\u4e0e\u9502\u5316\u901f\u7387\u76f8\u5173\uff0c\u5e94\u529b\u503c\u548c\u7535\u6d41\u503c\u5747\u968f\u7740\u7535\u4f4d\u626b\u63cf\u901f\u7387\u7684\u964d\u4f4e\u800c\u964d\u4f4e\u3002\u76f8\u53cd\uff0c\u5e94\u53d8\u7684\u53d8\u5316<span style=\"color: #ff6600;\">\uff08\u56fe5d\uff09<\/span>\u4e0e\u603b\u9502\u542b\u91cf\u76f8\u5173\uff0c\u5e94\u53d8\u503c\u548c\u5bb9\u91cf\u503c\u5747\u968f\u7740\u7535\u4f4d\u626b\u63cf\u901f\u7387\u7684\u964d\u4f4e\u800c\u589e\u52a0\u3002\u6700\u91cd\u8981\u7684\u662f\uff0c\u5e94\u529b\u548c\u5e94\u53d8\u7684\u5927\u5c0f\u4e0e\u5faa\u73af\u500d\u7387\u6210\u53cd\u6bd4\uff0c\u4e0e\u500d\u7387\u76f8\u5173\u7684\u73b0\u8c61\uff08\u5982\u9502\u79bb\u5b50\u7684\u6269\u6563\uff09\u5bf9\u5e94\u529b\u548c\u5e94\u53d8\u7684\u5f71\u54cd\u4e0d\u540c\u3002<\/p>\n<p><span style=\"color: #ff0000;\">\u3010\u603b\u7ed3\u3011<\/span>\u8fd9\u9879\u7814\u7a76\u901a\u8fc7\u5bf9\u7535\u5316\u5b66\u539f\u4f4d\u5e94\u529b\u548c\u5e94\u53d8\u7684\u6d4b\u91cf\u6765\u8ba1\u7b97\u7535\u5316\u5b66\u521a\u5ea6\uff0c\u4ee5\u63a2\u6d4b\u7535\u6781\u7684\u673a\u68b0\u5316\u5b66\u53cd\u5e94\u3002\u7814\u7a76\u53d1\u73b0\uff1a\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u4e0d\u540c\u7684\u77f3\u58a8-\u9502\u63d2\u5c42\u5316\u5408\u7269\u7684\u5f62\u6210\u662f\u7535\u5316\u5b66\u521a\u5ea6\u53d1\u751f\u5267\u70c8\u53d8\u5316\u7684\u539f\u56e0\u3002\u5206\u6790\u7ed3\u679c\u8868\u660e\u5e94\u529b\u5927\u5c0f\u4e0e\u8131\u5d4c\u9502\u901f\u7387\u6210\u6b63\u6bd4\uff0c\u5e94\u53d8\u5927\u5c0f\u4e0e\u5bb9\u91cf\u6210\u6b63\u6bd4\uff08\u4e0e\u500d\u7387\u6210\u53cd\u6bd4\uff09\u3002\u7535\u5316\u5b66\u521a\u5ea6\u7684\u6d4b\u91cf\u4e3a\u4e0e\u500d\u7387\u76f8\u5173\u7684\u673a\u68b0\u5316\u5b66\u8870\u9000\u7684\u8d77\u6e90\u4ee5\u53ca\u5bf9\u5148\u8fdb\u7684\u7535\u6c60\u7535\u6781\u7684\u8bc4\u4ef7\u63d0\u4f9b\u4e86\u65b0\u7684\u89c1\u89e3\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/www.nature.com\/nmat\/journal\/vaop\/ncurrent\/full\/nmat4708.html\" target=\"_blank\">Electrochemical stiffness in lithium-ion batteries<\/a>\uff08Nat. Mater., 2016, DOI:\u00a010.1038\/nmat4708\uff09<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u8fd9\u662f\u9996\u6b21\u5173\u4e8e\u7535\u6c60\u521a\u5ea6\u7684\u7814\u7a76\u3002<\/p>\n","protected":false},"author":272,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[18,129],"class_list":["post-32297","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-xinnengyuan","tag-battery"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/32297"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/272"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=32297"}],"version-history":[{"count":12,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/32297\/revisions"}],"predecessor-version":[{"id":32759,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/32297\/revisions\/32759"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=32297"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=32297"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=32297"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}