{"id":32071,"date":"2016-08-10T08:00:02","date_gmt":"2016-08-10T00:00:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=32071"},"modified":"2016-08-09T23:47:52","modified_gmt":"2016-08-09T15:47:52","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81-jacs%ef%bc%8fangew%ef%bc%8facs-nano%e7%ad%89%e9%ab%98%e5%88%86%e5%ad%90%e6%9d%90%e6%96%99%e5%ad%a6%e6%9c%af%e8%bf%9b%e5%b1%95%e6%b1%87%e6%80%bb%e3%80%90%e7%ac%ac","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=32071","title":{"rendered":"\u9876\u520a\u52a8\u6001 | JACS\uff0fAngew\uff0fACS Nano\u7b49\u9ad8\u5206\u5b50\u6750\u6599\u5b66\u672f\u8fdb\u5c55\u6c47\u603b\u3010\u7b2c14\u671f\u3011"},"content":{"rendered":"

\u672c\u671f\u5bfc\u8bfb<\/strong>\uff1a\u4eca\u5929\u9ad8\u5206\u5b50\u6750\u6599\u5468\u62a5\u7ec4\u9080\u60a8\u4e00\u8d77\u6765\u770b\u770bACS Nano \uff0fJournal of the American Chemical Society \uff0fAngewandte Chemie International Edition\u7b49\u671f\u520a\u9ad8\u5206\u5b50\u6750\u6599\u9886\u57df\u6700\u65b0\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u672c\u671f\u5185\u5bb9\u9884\u89c8\uff1a1\u3001 ACS Nano\uff1a\u529f\u80fd\u4e09\u7ef4\u77f3\u58a8\u70ef\/\u805a\u5408\u7269\u590d\u5408\u6750\u6599\uff1b2\u3001JACS\uff1a\u5728\u5408\u6210\u7684\u50ac\u5316\u5242\u2212\u53cc\u5206\u5b50\u819c\u7cfb\u7edf\u4e2d\u5b9e\u73b0\u805a\u5408\u7269\u81ea\u7ec4\u88c5\u7684\u7eb3\u7c73\u7ea7\u63a7\u5236\uff1b3\u3001JACS\uff1a\u6709\u673a\u91d1\u5c5e\u548c\u8d85\u5206\u5b50\u53cc\u50ac\u5316\u7684\u534f\u540c\u6548\u5e94\u8303\u56f4\u548c\u673a\u7406\u7814\u7a76\uff1b4\u3001 JACS:\u624b\u6027\u82ef\u4e59\u7094\u7684\u7ed3\u6784\uff1b5\u3001 JACS\uff1a\u805a\uff08\u82ef\u7532\u9178\uff09\uff08\u73af\u6c27\u4e59\u70f7\uff09\u4f5c\u4e3a\u91d1\u5c5e\u6709\u673a\u591a\u9762\u4f53\u5206\u5b50\u8c03\u8282\u5242\uff1b6\u3001 JACS\uff1a\u5bf9\u975e\u9633\u79bb\u5b50\u805a\u4e59\u4e8c\u9187\u5237\u8fdb\u884c\u6709\u6548\u5730\u53cd\u6548\u57fa\u56e0\u63a7\u5236\uff1b7\u3001 JACS\uff1a\u9009\u62e9\u6027\u6709\u89c4\u914d\u4f4d\u805a\u5408\u6cd5\u5236\u5907\u4e59\u70ef\u57fa\u529f\u80fd\u5316\u7684\u5185\u5305C60<\/sub>\u9ad8\u5ea6\u4ea4\u8054\u590d\u5408\u7269\uff1b8\u3001Angew\uff1a\u91c7\u7528\u84b8\u53d1\u5149\u523b\u63a7\u5236\u6db2\u6ef4\u5728\u805a\u5408\u7269\u57fa\u8d28\u4e2d\u7684\u5b9a\u4f4d\u3002<\/p>\n

1\u3001 ACS Nano\uff1a\u529f\u80fd\u4e09\u7ef4\u77f3\u58a8\u70ef\/\u805a\u5408\u7269\u590d\u5408\u6750\u6599<\/strong><\/p>\n

\"1\"<\/p>\n

\u56fe1 <\/strong>3DGPCs\u7684\u591a\u79cd\u5e94\u7528\u9886\u57df<\/p>\n

\u5728\u8fc7\u53bb\u7684\u51e0\u5e74\u91cc\uff0c\u77f3\u58a8\u70ef\u4e0e\u805a\u5408\u7269\u590d\u5408\u6784\u5efa\u4e09\u7ef4\u591a\u5b54\u77f3\u58a8\u70ef\/\u805a\u5408\u7269\u590d\u5408\u6750\u6599\uff083DGPCs\uff09\u4f5c\u4e3a\u57fa\u7840\u7814\u7a76\u548c\u591a\u79cd\u6280\u672f\u5e94\u7528\u5df2\u7ecf\u5438\u5f15\u4e86\u76f8\u5f53\u591a\u7684\u5173\u6ce8\u3002\u968f\u7740\u77f3\u58a8\u70ef\u548c\u805a\u5408\u7269\u5206\u5b50\u7ed3\u6784\u7684\u591a\u6837\u5316\uff0c\u7814\u7a76\u4eba\u5458\u5df2\u7814\u5236\u51fa\u4e00\u4e9b\u5177\u5907\u7279\u6b8a\u7ed3\u6784\u3001\u7535\u5b66\u6027\u80fd\u548c\u673a\u68b0\u6027\u80fd\u76843DGPCs\uff0c\u5176\u6240\u5177\u5907\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u53ca\u591a\u79cd\u4f18\u5f02\u7684\u529f\u80fd\u6781\u5927\u5730\u62d3\u5bbd\u4e86\u77f3\u58a8\u70ef\u57fa\u590d\u5408\u6750\u6599\u7684\u7814\u7a76\u8303\u56f4\u3002\u800c\u4e14\uff0c\u80fd\u591f\u901a\u8fc7\u7cbe\u786e\u5730\u63a7\u5236\u4e09\u7ef4\u77f3\u58a8\u70ef\u7684\u5206\u5c42\u5b54\u9699\u5ea6\u4ee5\u53ca\u77f3\u58a8\u70ef\u4e0e\u805a\u5408\u7269\u4e4b\u95f4\u590d\u6742\u7684\u534f\u540c\u4f5c\u7528\u6765\u6539\u53d83DGPCs\u7684\u6027\u80fd\u3002<\/p>\n

\u6765\u81ea\u590d\u65e6\u5927\u5b66\u7684\u5f90\u5b87\u66e6\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821\u7684\u6bb5\u9576\u950b\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u603b\u7ed3\u4e863DGPCs\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u5305\u62ec\u5408\u6210\u65b9\u6cd5\u4ee5\u53ca\u5176\u5728\u73af\u5883\u4fdd\u62a4\u3001\u80fd\u91cf\u50a8\u5b58\u3001\u4f20\u611f\u5668\u3001\u5bfc\u7535\u590d\u5408\u6750\u6599\u7b49\u65b9\u9762\u7684\u5e94\u7528\u3002\u7814\u7a76\u4eba\u5458\u8ba4\u4e3a\uff0c\u4e0d\u4e45\u5c06\u8fce\u67653DGPCs\u5728\u4e0d\u540c\u9886\u57df\u7684\u5feb\u901f\u53d1\u5c55\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Functional Three-Dimensional Graphene\/Polymer Composites<\/a>\uff08ACS Nano, 2016, DOI: 10.1021\/acsnano.6b03349\uff09<\/p>\n

2\u3001JACS\uff1a\u5728\u5408\u6210\u7684\u50ac\u5316\u5242\u2212\u53cc\u5206\u5b50\u819c\u7cfb\u7edf\u4e2d\u5b9e\u73b0\u805a\u5408\u7269\u81ea\u7ec4\u88c5\u7684\u7eb3\u7c73\u7ea7\u63a7\u5236<\/strong><\/p>\n

\"2\"<\/p>\n

\u56fe2 <\/strong>\u7528\u4e8e\u805a\u5408\u7269\u751f\u957f\u7684\u50ac\u5316\u5242-\u53cc\u5206\u5b50\u819c\u7cfb\u7edf\u793a\u610f\u56fe<\/p>\n

\u5c06\u81ea\u7ec4\u88c5\u819c\u7684\u5185\u90e8\u4f5c\u4e3a\u805a\u5408\u7269\u5408\u6210\u548c\u7ec4\u88c5\u7684\u6a21\u677f\uff0c\u957f\u671f\u4ee5\u6765\u5438\u5f15\u4e86\u8bb8\u591a\u5316\u5b66\u5bb6\u7684\u7814\u7a76\u5174\u8da3\u3002\u7136\u800c\uff0c\u5f88\u96be\u5229\u7528\u8102\u8d28\u819c\u4f5c\u4e3a\u5316\u5b66\u53cd\u5e94\u5668\uff0c\u7528\u4e8e\u805a\u5408\u7269\u7684\u53ef\u63a7\u7ec4\u88c5\uff0c\u56e0\u4e3a\u8102\u8d28\u819c\u7684\u7a33\u5b9a\u6027\u5f88\u5bb9\u6613\u56e0\u5916\u6765\u5206\u5b50\u7684\u8d1f\u8f7d\u800c\u906d\u5230\u7834\u574f\u3002<\/p>\n

\u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u5316\u5b66\u7cfb\u7684Koji Harano\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548cEiichi Nakamura\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5408\u6210\u4e86\u4e00\u79cd\u50ac\u5316\u5242-\u53cc\u5206\u5b50\u819c\u7cfb\u7edf\uff0c\u53ef\u5b9e\u73b0\u805a\u5408\u7269\u7684\u53ef\u63a7\u81ea\u7ec4\u88c5\u3002\u4ed6\u4eec\u53d1\u73b0\u5728\u6709\u673a\u5bcc\u52d2\u70ef\u4e24\u4eb2\u7269\u81ea\u7ec4\u88c5\u800c\u6210\u7684\u51e0\u4e2a\u7eb3\u7c73\u539a\u5ea6\u7684\u53cc\u5c42\u56ca\u6ce1\u4e2d\u63ba\u6742\u590d\u5206\u89e3\u50ac\u5316\u5242\uff0c\u53ef\u4f5c\u4e3a\u6c34\u4e2d\u7684\u7eb3\u7c73\u5316\u5b66\u53cd\u5e94\u5668\uff0c\u5176\u4e2d\u805a\u5408\u7269\u7684\u5408\u6210\u548c\u7ec4\u88c5\u53d6\u51b3\u4e8e\u751f\u957f\u7684\u805a\u5408\u7269\u548c\u4e24\u4eb2\u7269\u6709\u673a\u57fa\u56e2\u4e4b\u95f4\u7684\u4eb2\u548c\u529b\u3002\u8fd9\u79cd\u50ac\u5316\u5242-\u53cc\u5206\u5b50\u819c\u7cfb\u7edf\u53ef\u4ee5\u63a7\u5236\u916f\u5b98\u80fd\u5316\u805a\u5408\u7269\u8d85\u5206\u5b50\u81ea\u7ec4\u88c5\u6210\u4e0d\u540c\u7684\u7eb3\u7c73\u7ed3\u6784\uff1a\u7531\u5355\u4e00\u7684\u9ad8\u5206\u5b50\u94fe\u6784\u6210\u7684\u7eb3\u7c73\u9897\u7c92\u548c\u7531\u51e0\u5341\u6761\u9ad8\u5206\u5b50\u94fe\u6784\u6210\u7684\u7eb3\u7c73\u80f6\u56ca\u3002\u8be5\u6210\u679c\u4e0d\u4ec5\u63d0\u4f9b\u4e86\u4e00\u79cd\u7528\u8102\u8d28\u56ca\u6ce1\u63a7\u5236\u805a\u5408\u7269\u7ec4\u88c5\u7684\u65b9\u6cd5\uff0c\u800c\u4e14\u63d0\u4f9b\u4e86\u4e00\u4e2a\u80fd\u540c\u65f6\u5b9e\u73b0\u5316\u5b66\u53cd\u5e94\u4e0e\u4ea7\u7269\u7684\u81ea\u7ec4\u88c5\u7ed3\u6784\u63a7\u5236\u7684\u819c\u57fa\u5408\u6210\u88c5\u7f6e\u7684\u5b9e\u4f8b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Nanoscale Control of Polymer Assembly on a Synthetic Catalyst\u2013Bilayer System<\/a>\uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b05414\uff09<\/p>\n

3\u3001JACS\uff1a\u6709\u673a\u91d1\u5c5e\u548c\u8d85\u5206\u5b50\u53cc\u50ac\u5316\u7684\u534f\u540c\u6548\u5e94\u8303\u56f4\u548c\u673a\u7406\u7814\u7a76<\/strong><\/p>\n

\"31\"<\/p>\n

\"3\"<\/p>\n

\u56fe3 <\/strong>\u4e00\u79cd\u53ef\u7528\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u4ea4\u53c9\u8026\u5408\u53cd\u5e94\u7684\u8d85\u5206\u5b50\u65b9\u6cd5<\/p>\n

\u5bf9\u914d\u4f53\u7ed3\u6784\u5728\u51b3\u5b9a\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4e2d\u6240\u8d77\u7684\u4f5c\u7528\u7684\u8ba4\u8bc6\u5e26\u6765\u4e86\u8fc7\u6e21\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u7684\u53d8\u9769\uff0c\u5e76\u4f7f\u8bb8\u591a\u4ee5\u524d\u65e0\u6cd5\u8fdb\u884c\u7684\u50ac\u5316\u8fc7\u7a0b\u5f97\u4ee5\u5b9e\u73b0\uff0c\u50ac\u751f\u4e86\u8bb8\u591a\u5177\u6709\u663e\u8457\u6d3b\u6027\u3001\u9009\u62e9\u6027\u548c\u9ad8\u6548\u7387\u7684\u65b9\u6cd5\u3002\u8fd9\u4e00\u8fdb\u6b65\u7684\u5173\u952e\u5728\u4e8e\u80fd\u591f\u8c03\u8282\u50ac\u5316\u5242\u7684\u5c40\u90e8\u5fae\u73af\u5883\uff0c\u5305\u62ec\u7a7a\u95f4\u4f4d\u963b\u548c\u7535\u5b50\uff0c\u4ece\u800c\u5f71\u54cd\u5355\u4e2a\u57fa\u5143\u53cd\u5e94\u7684\u901f\u7387\u3001\u63a7\u5236\u50ac\u5316\u5242\u7684\u5f62\u6001\u53ca\u907f\u514d\u5931\u6d3b\u8def\u5f84\u3002<\/p>\n

\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u7684Robert G. Bergman\u3001Kenneth N. Raymond\u548cF. Dean Toste\uff08\u5171\u540c\u901a\u8baf\uff09\u7b49\u63a2\u8ba8\u4e86\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269[Au(III)\uff0cPt(IV)]\u7684\u5fae\u73af\u5883\u50ac\u5316C(sp3)\u2212C(sp3)\u8fd8\u539f\u6d88\u9664\u53cd\u5e94\u7684\u8303\u56f4\u548c\u673a\u7406\u3002\u5b9e\u9a8c\u8be6\u7ec6\u9610\u660e\u4e86\u53cc\u50ac\u5316\u5bf9\u4e2d\u6027\u548c\u9634\u79bb\u5b50\u89c2\u4f17\u914d\u4f53\uff08spectator ligands\uff09\u3001\u53cd\u5e94\u6027\u70f7\u57fa\u914d\u4f53\u3001\u6eb6\u5242\u548c\u50ac\u5316\u5242\u7684\u7ed3\u6784\u6270\u52a8\u7684\u5f71\u54cd\u3002\u5b9e\u9a8c\u4e2d\u89c2\u5bdf\u5230\u51e0\u79cd\u975e\u6d3b\u6027\u7684\u542b\u914d\u4f53\u7684\u914d\u5408\u7269\uff0c\u5305\u62ec\u6676\u6001\u56ca\u72b6Au(III)\u9633\u79bb\u5b50\uff0c\u8fd9\u95f4\u63a5\u8bc1\u660e\u4e86\u914d\u4f4d\u4e0d\u9971\u548c\u9633\u79bb\u5b50\u4e2d\u95f4\u4f53\u7684\u5b58\u5728\u3002\u6700\u540e\uff0c\u57fa\u4e8e\u76f8\u5173\u50ac\u5316\u6761\u4ef6\u4e0b\u7684\u5b9a\u91cf\u5b9e\u9a8c\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u8d85\u5206\u5b50\u548c\u94c2\u53cc\u50ac\u5316\u7684\u7532\u57fa\u7898\u548c\u56db\u7532\u57fa\u9521\u95f4\u7684C-C\u8026\u5408\u7684\u8be6\u7ec6\u673a\u7406\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis<\/a>\uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b05442\uff09<\/p>\n

4\u3001 JACS:\u624b\u6027\u82ef\u4e59\u7094\u7684\u7ed3\u6784<\/strong><\/p>\n

\"4\"<\/p>\n

\u56fe4 <\/strong>\u90bb\u3001\u95f4\u3001\u5bf9\u53d6\u4ee3\u7684PPA\u7684\u4e09\u7ef4\u87ba\u65cb\u7ed3\u6784\uff08\u968f\u7740\u87ba\u65cb\u8ddd\u79bb\u7684\u589e\u52a0\uff0c\u5176\u52a8\u6001\u6d3b\u6027\u589e\u52a0\uff09<\/p>\n

\u751f\u7269\u805a\u5408\u7269\u5982\u591a\u80bd\u3001\u591a\u7cd6\u4ee5\u53caDNA\u00a0\u90fd\u91c7\u7528\u4e86\u4e0e\u5b83\u4eec\u529f\u80fd\u76f4\u63a5\u76f8\u5173\u7684\u87ba\u65cb\u7ed3\u6784\u3002\u8be5\u79cd\u7ed3\u6784\u65e8\u5728\u5728\u7279\u5b9a\u7684\u8ddd\u79bb\u548c\u87ba\u65cb\u65b9\u5411\u5ef6\u957f\u7ebf\u4e0a\u5bf9\u5176\u6b8b\u57fa\u548c\u5b98\u80fd\u56e2\u8fdb\u884c\u5b9a\u4f4d\u3002\u7531\u87ba\u65cb\u7ed3\u6784\u6240\u51b3\u5b9a\u7684\u7a7a\u95f4\u5206\u5e03\u5728\u5206\u5b50\u8bc6\u522b\u548c\u50ac\u5316\u5242\u9886\u57df\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u57fa\u4e8e\u6b64\u57fa\u7840\u4e0a\u7ed3\u6784\u4e0e\u529f\u80fd\u7684\u5173\u7cfb\uff0c\u8bb8\u591a\u5177\u6709\u87ba\u65cb\u7ed3\u6784\u7684\u5408\u6210\u805a\u5408\u7269\uff08\u4f8b\u5982\uff0c\u805a\u82ef\u4e59\u7094\uff08PPA\uff09\u3001\u805a\u5f02\u6c30\u9178\u916f\u3001\u805a\u7845\u70f7\u7b49\uff09\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u91cc\u5df2\u88ab\u7814\u7a76\u548c\u5f00\u53d1\u3002<\/p>\n

\u6765\u81ea\u897f\u73ed\u7259\u5723\u5730\u4e9a\u54e5\u00b7\u5fb7\u00b7\u5b54\u6ce2\u65af\u7279\u62c9\u5927\u5b66\u7684Ricaedo Riguera\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548cF\u00e9lix Freire\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5bf9\u8fde\u63a5\u4fa7\u57fa\uff08\u5373\uff0c\u82ef\u80fa\u3001\u82ef\u7532\u9170\u80fa\uff09\u6216\u662f\u65b9\u5411\u53d6\u4ee3\uff08\u4e34\u3001\u95f4\u3001\u5bf9\uff09\u7684\u6bcd\u4f53PPA\u7684\u6539\u6027\u8fdb\u884c\u4e86\u6df1\u5165\u7684\u7814\u7a76\uff0c\u53d1\u73b0\u5bf9\u5176\u4f38\u957f\u7387\u3001\u52a8\u6001\u7279\u6027\u3001\u5bf9\u5916\u754c\u523a\u6fc0\uff08\u6eb6\u5242\u6548\u5e94\u3001\u91d1\u5c5e\u9633\u79bb\u5b50\uff09\u7684\u54cd\u5e94\u4ee5\u53ca\u87ba\u65cb\u5f62PPA\u7684\u805a\u96c6\u60c5\u51b5\u4ea7\u751f\u4e86\u663e\u8457\u7684\u5f71\u54cd\u3002\u95f4\u4f4d\u548c\u90bb\u4f4d\u53d6\u4ee3\u7684\u87ba\u65cb\u7ed3\u6784\u4e2d\u7684\u4fa7\u94fe\u7684\u5f71\u54cd\u4f7f\u5f97\u8fd9\u4e9b\u7ed3\u6784\u7684\u5408\u7406\u53d8\u5316\uff08\u4f38\u957f\uff0f\u52a8\u6001\u884c\u4e3a\uff09\u66f4\u52a0\u56f0\u96be\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Architecture of Chiral Poly(phenylacetylene)s: From Compressed\/Highly Dynamic to Stretched\/Quasi-Static Helices<\/a>\uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b04834 \uff09<\/p>\n

5\u3001 JACS\uff1a\u805a\uff08\u82ef\u7532\u9178\uff09\uff08\u73af\u6c27\u4e59\u70f7\uff09\u4f5c\u4e3a\u91d1\u5c5e\u6709\u673a\u591a\u9762\u4f53\u5206\u5b50\u8c03\u8282\u5242<\/strong><\/p>\n

\"5\"<\/p>\n

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\u57fa\u4e8e\u91d1\u5c5e\u79bb\u5b50\u548c\u6709\u673a\u9aa8\u67b6\u7684\u81ea\u7ec4\u88c5\u7684\u8d85\u5206\u5b50\u7ed3\u6784\u7684\u8bbe\u8ba1\u4e0e\u5e94\u7528\u5df2\u7ecf\u5f15\u8d77\u4e86\u7814\u7a76\u4eba\u5458\u7684\u9ad8\u5ea6\u5173\u6ce8\u3002\u8d85\u5206\u5b50\u7eb3\u7c73\u7b3c\u5728\u8bf8\u5982\u6c14\u4f53\u50a8\u5b58\u3001\u50ac\u5316\u5242\u3001\u836f\u7269\u8f93\u9001\u548c\u4f20\u611f\u5668\u7b49\u4e00\u7cfb\u5217\u5e94\u7528\u4e2d\u5177\u6709\u975e\u5e38\u5927\u7684\u6f5c\u529b\u3002\u91d1\u5c5e\uff0d\u6709\u673a\u591a\u9762\u4f53\uff08MOPs\uff09\u662f\u79bb\u6563\u7684\u91d1\u5c5e\u6709\u673a\u5206\u5b50\u7ec4\u88c5\uff0c\u5176\u5177\u6709\u53ef\u88c1\u526a\u7684\u5185\u90e8\u7a7a\u8154\uff0c\u521a\u6027\u7684\u5206\u5b50\u7ed3\u6784\u4e14\u4e30\u5bcc\u7684\u5316\u5b66\u529f\u80fd\u3002\u96f6\u7ef4MOPs\u53ef\u4ee5\u901a\u8fc7\u5171\u4ef7\u914d\u4f53\u4e0e\u914d\u4f53\u4e4b\u95f4\u7684\u4ea4\u8054\u4ee5\u53ca\u4e0e\u6eb6\u5242\u7684\u534f\u8c03\u4f5c\u7528\u4e0b\u7ec4\u88c5\u800c\u6210\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u5723\u5730\u4e9a\u54e5\u5206\u6821\u7684Seth M. Cohen\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u7814\u53d1\u51fa\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\u2014\u2014\u5229\u7528\u805a\u5408\u7269\u914d\u4f53\uff0d\u805a\uff08\u82ef\u7532\u9178\uff09\uff08\u73af\u6c27\u4e59\u70f7\uff09\u6765\u8c03\u8282MOP\u6676\u4f53\u7684\u751f\u957f\u3002\u8be5\u79cd\u9ad8\u5206\u5b50\u8c03\u8282\u5242\u53ef\u4ee5\u6709\u6548\u5730\u63a7\u5236\u8bb8\u591a\u4e0d\u540c\u7684Cu24<\/sub>L24<\/sub>\uff08L =\u95f4\u82ef\u4e8c\u7532\u9178\u884d\u751f\u7269\uff09MOPs\u3002\u8be5\u805a\u5408\u7269\u8fd8\u80fd\u5728\u53cd\u5e94\u6761\u4ef6\uff08\u5728\u6ca1\u6709\u8c03\u8282\u5242\u7684\u60c5\u51b5\u4e0b\u53ea\u80fd\u5f62\u6210\u91d1\u5c5e\uff0d\u6709\u673a\u9aa8\u67b6\uff09\u4e0b\u5bf9MOP\u7ed3\u6784\u7684\u5f62\u6210\u8fdb\u884c\u6307\u5bfc\u3002\u6b64\u5916\uff0c\u8be5\u805a\u5408\u7269\u80fd\u591f\u4f7fMOP\u6676\u4f53\u5728\u73bb\u7483\u8868\u9762\u6c89\u79ef\u3002\u8be5\u9879\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\u6765\u63a7\u5236MOPs\u7684\u5f62\u6001\u548c\u7ec4\u88c5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Poly(isophthalic acid)(ethylene oxide) as a MacromolecularModulator for Metal\u2013Organic Polyhedra<\/a>\uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b04971\uff09<\/p>\n

6\u3001 JACS\uff1a\u5bf9\u975e\u9633\u79bb\u5b50\u805a\u4e59\u4e8c\u9187\u5237\u8fdb\u884c\u6709\u6548\u5730\u53cd\u6548\u57fa\u56e0\u63a7\u5236<\/strong><\/p>\n

\"6\"<\/p>\n

\u56fe6 <\/strong>Y\u5f62PEG\u548c\u5237\u578bPEG\u7684\u7ed3\u6784<\/p>\n

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\u8fd1\u65e5\uff0c\u6765\u81ea\u7f8e\u56fd\u4e1c\u5317\u5927\u5b66\u7684Ke Zhang\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5bf9\u5c06\u6838\u9178\u8f6c\u5316\u6210\u836f\u7269\u53c8\u505a\u51fa\u4e86\u8fdb\u4e00\u6b65\u7684\u52aa\u529b\u3002\u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff1a\u7531\u4e8e\u5e26\u8d1f\u7535\u8377\u7684\u6838\u9178\u5e38\u4e0e\u805a\u9633\u79bb\u5b50\u8f6c\u67d3\u5242\u590d\u5408\u3002\u56e0\u6b64\uff0c\u5229\u7528\u975e\u9633\u79bb\u5b50\u578b\u5e76\u5177\u6709\u751f\u7269\u76f8\u5bb9\u6027\u7684\u805a\u4e59\u4e8c\u9187\uff08PEG\uff09\u80fd\u591f\u5f62\u6210DNA\u5171\u8f6d\u805a\u5408\u7269\u5237\uff0c\u4ee5\u4f5c\u4e3a\u8f6c\u67d3\u8f7d\u4f53\u3002\u8be5\u5237\u7684\u7ed3\u6784\u80fd\u589e\u5f3a\u6838\u9178\u9176\u7684\u7a33\u5b9a\u6027\u548c\u63d0\u9ad8\u7ec6\u80de\u6444\u53d6\u836f\u7269\u7684\u6982\u7387\u3002\u7531\u4e8e\u8be5\u805a\u5408\u7269\u7684\u751f\u7269\u76f8\u5bb9\u6027\u4e14\u65e0\u7ec6\u80de\u6bd2\u6027\u3002\u8fd9\u79cd\u65b9\u6cd5\u6709\u53ef\u80fd\u89e3\u51b3\u957f\u671f\u4ee5\u6765\u5be1\u6838\u82f7\u9178\u7597\u6cd5\u6240\u5b58\u5728\u7684\u6311\u6218\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Effective Antisense Gene Regulation via Noncationic, Polyethylene Glycol Brushes<\/a>\uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b05787\uff09<\/p>\n

7\u3001 JACS\uff1a\u9009\u62e9\u6027\u6709\u89c4\u914d\u4f4d\u805a\u5408\u6cd5\u5236\u5907\u4e59\u70ef\u57fa\u529f\u80fd\u5316\u7684\u5185\u5305C60<\/sub>\u9ad8\u5ea6\u4ea4\u8054\u590d\u5408\u7269<\/strong><\/p>\n

\"7\"<\/p>\n

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\u7531\u4e8e\u5176\u7279\u6b8a\u7684\u6027\u80fd\uff0c\u4efb\u4f55\u88ab\u675f\u7f1a\u7684\u5355\u4f53\u5fc5\u987b\u5728\u50ac\u5316\u70b9\u63a5\u53d7\u914d\u5408\u3002\u53ef\u901a\u8fc7\u8c03\u6574\u7535\u5b50\u3001\u7a7a\u95f4\u548c\u8f85\u52a9\u914d\u4f53\u7684\u5bf9\u79f0\u6027\u8d28\uff0c\u91d1\u5c5e\u914d\u4f4d\u805a\u5408\u5df2\u6f14\u53d8\u6210\u4e86\u76ee\u524d\u7cbe\u786e\u63a7\u5236\u7acb\u4f53\u805a\u5408\u5316\u5b66\u53cd\u5e94\u6700\u4e3a\u5f3a\u5927\u7684\u6280\u672f\u3002<\/p>\n

\u6765\u81ea\u6c99\u7279\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66\u7684Luigi Cavallo\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u7f8e\u56fd\u79d1\u7f57\u62c9\u591a\u5dde\u7acb\u5927\u5b66\u7684Eugene Y.-X. Chen\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5229\u7528\u5177\u6709\u5b8c\u7f8e\u9009\u62e9\u6027\u548c\u9ad8\u89c4\u5ea6\u7684\u4e8c\u4e59\u70ef\u57fa\u6781\u6027\u5355\u4f53\uff0c\u6210\u529f\u5408\u6210\u4e86\u6bcf\u4e2a\u91cd\u590d\u5355\u5143\u4e2d\u90fd\u5e26\u6709\u6d3b\u6027\u4fa7\u4e59\u70ef\u57fa\u7684\u9ad8\u95f4\u540c\u6781\u6027\u4e59\u70ef\u57fa\u805a\u5408\u7269\u3002\u4e09\u79cd\u5229\u7528\u91d1\u5c5e\u4ecb\u5bfc\u7684\u914d\u4f4d\u805a\u5408\u7684\u4ee3\u8868\u6027\u6781\u6027\u4e59\u70ef\u5355\u4f53\u5305\u62ec\uff1a\u5305\u62ec\u7532\u57fa\u4e19\u70ef\u9178\u4e59\u70ef\u916f\uff08VMA\uff09\uff0c\u7532\u57fa\u4e19\u70ef\u9178\u70ef\u4e19\u916f\uff08AMA\uff09\uff0c\u548cN\uff0cN-\u4e8c\u70ef\u4e19\u57fa\u4e19\u70ef\u9170\u80fa\uff08DAA\uff09\uff0c\u5728\u6709\u50ac\u5316\u5242\u7684\u5ba4\u6e29\u6761\u4ef6\u4e0b\u5177\u6709\u5b8c\u7f8e\u7684\u5316\u5b66\u9009\u62e9\u6027\u4ee5\u53ca\u7acb\u4f53\u9009\u62e9\u6027\u9ad8\u7684\u7279\u70b9\u3002\u8be5\u6210\u679c\u5df2\u4f7f\u5f97\u5236\u5907\u9ad8\u5ea6\u4ea4\u8054\u7684\u5185\u5305C60<\/sub>\u8d85\u5206\u5b50\u7acb\u4f53\u590d\u5408\u7269\u6210\u4e3a\u53ef\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Robust Cross-Linked Stereocomplexes and C60<\/sub> Inclusion Complexes of Vinyl-Functionalized Stereoregular Polymers Derived from Chemo\/Stereoselective Coordination Polymerization<\/a>\uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b04064\uff09<\/p>\n

8\u3001Angew\uff1a\u91c7\u7528\u84b8\u53d1\u5149\u523b\u63a7\u5236\u6db2\u6ef4\u5728\u805a\u5408\u7269\u57fa\u8d28\u4e2d\u7684\u5b9a\u4f4d<\/strong><\/p>\n

\"8\"<\/p>\n

\u56fe8 <\/strong>\u91c7\u7528\u84b8\u53d1\u5149\u523b\u6280\u672f\u5b9e\u73b0\u6db2\u6ef4\u5728\u805a\u5408\u7269\u57fa\u8d28\u4e2d\u7684\u53ef\u63a7\u5206\u5e03\u7684\u793a\u610f\u56fe<\/p>\n

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\u8fd1\u65e5\uff0c\u7535\u5b50\u79d1\u6280\u5927\u5b66\u7684\u9093\u65ed\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u5d14\u5bb6\u559c\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u91c7\u7528\u84b8\u53d1\u5149\u523b\u6280\u672f\uff0c\u5b9e\u73b0\u4e86\u4ece\u6eb6\u6db2\u4e2d\u76f4\u63a5\u83b7\u5f97\u6db2\u6ef4\u5e76\u9009\u62e9\u6027\u56fa\u5b9a\u5728\u8d85\u5206\u5b50\u51dd\u80f6\u4e2d\u3002\u5728\u81ea\u7531\u84b8\u53d1\u533a\u57df\uff0c\u975e\u6325\u53d1\u6027\u6db2\u4f53\u88ab\u6d53\u7f29\u5e76\u7ecf\u5386\u76f8\u5206\u79bb\u8fc7\u7a0b\uff0c\u5728\u53d1\u751f\u51dd\u80f6\u5316\u4e4b\u524d\u5f62\u6210\u6db2\u6ef4\uff0c\u4e4b\u540e\u53d1\u751f\u5d4c\u5165\uff0c\u800c\u5728\u53d7\u963b\u84b8\u53d1\u533a\u57df\u4e2d\u5f62\u6210\u5747\u5300\u7684\u51dd\u80f6\u57fa\u8d28\u3002\u56fe\u6848\u5316\u6db2\u6ef4\u6d82\u5c42\u7684\u4e0d\u540c\u533a\u57df\u5177\u6709\u4e0d\u540c\u7684\u6db2\u6ef4\u5206\u6ccc\u80fd\u529b\uff0c\u4ece\u800c\u5b9e\u73b0\u6db2\u6ef4\u7684\u5b9a\u5411\u79fb\u52a8\u63a7\u5236\u3002\u51dd\u80f6\u5316\u540e\uff0c\u542b\u6db2\u6ef4\u548c\u4e0d\u542b\u6db2\u6ef4\u7684\u533a\u57df\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u6027\u8d28\u3002\u8be5\u6280\u672f\u53ef\u5e94\u7528\u4e8e\u4e0d\u540c\u7684\u6750\u6599\u7cfb\u7edf\u4e2d\uff0c\u7cbe\u786e\u5b9e\u73b0\u6750\u6599\u7684\u5149\u6ed1\u3001\u81ea\u6108\u3001\u6297\u6c61\u7b49\u529f\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Controlling the Localization of Liquid Droplets in Polymer Matrices by Evaporative Lithography<\/a> (Angew. Chem. Int. Ed. , 2016, DOI: 10.1002\/anie.201604868)<\/p>\n

\u672c\u671f\u6587\u732e\u6c47\u603b\u7531\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u6750\u6599\u5b66\u4e60\u5c0f\u7ec4\u6210\u5458Sea\u3001xiiluu\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u5982\u679c\u4f60\u5bf9\u9ad8\u5206\u5b50\u6750\u6599\u611f\u5174\u8da3\u5e76\u4e14\u613f\u610f\u4e0e\u9ad8\u5206\u5b50\u884c\u4e1a\u4eba\u4ea4\u6d41\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\uff1b\u5982\u679c\u4f60\u60f3\u53ca\u65f6\u638c\u63e1\u9ad8\u5206\u5b50\u5b66\u672f\u52a8\u6001\u5e76\u6df1\u5165\u5256\u6790\u9ad8\u5206\u5b50\u79d1\u7814\u53ca\u884c\u4e1a\u73b0\u72b6\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u5b66\u4e60\u5c0f\u7ec4\uff08\u62a5\u540d\u8bf7\u6233\u6211<\/a>\uff09\u3002<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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