{"id":31523,"date":"2016-08-06T16:00:43","date_gmt":"2016-08-06T08:00:43","guid":{"rendered":"\/\/m.iemloyee.com\/?p=31523"},"modified":"2016-08-09T11:02:29","modified_gmt":"2016-08-09T03:02:29","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81%ef%bd%9cjacs%ef%bc%9a7%e6%9c%88%e5%89%8d%e6%b2%bf%e5%8d%81%e5%a4%a7%e7%b2%be%e9%80%89%e7%a7%91%e7%a0%94%e6%88%90%e6%9e%9c%ef%bc%88%e5%9b%bd%e5%86%85%ef%bc%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=31523","title":{"rendered":"\u9876\u520a\u52a8\u6001\uff5cJACS\uff1a7\u6708\u6750\u6599\u524d\u6cbf\u79d1\u7814\u6210\u679c\u5341\u5927\u7cbe\u9009\uff08\u56fd\u5185\uff09"},"content":{"rendered":"
<\/p>\n
\u4eca\u5929\u6750\u6599\u725b\u9080\u60a8\u4e00\u8d77\u6765\u770b\u770b\u56fd\u9645\u8457\u540d\u671f\u520aJACS 2016\u5e747\u6708\u6750\u6599\u524d\u6cbf\u79d1\u7814\u6210\u679c\u5341\u5927\u7cbe\u9009\uff08\u56fd\u5185\uff09\uff1a\u590d\u65e6\u5927\u5b66<\/strong>\u2014\u2014\u4f7f\u7528CH3<\/sub>NH3<\/sub>PbBr0.9<\/sub>I2.1<\/sub>\u91cf\u5b50\u70b9\u901a\u8fc7\u754c\u9762\u5de5\u7a0b\u6210\u529f\u5b9e\u73b0\u4e86\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u7684\u5927\u5e45\u63d0\u9ad8\uff1b\u56fd\u7acb\u53f0\u6e7e\u5927\u5b66\u7b49<\/strong>\u2014\u2014Li2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub>\uff08M<\/em> = Li\u3001Ni\u3001Co\u3001Mn\uff09\u5fae\u7403\u6b63\u6781\u5bb9\u91cf\u51cf\u5f31\u7684\u539f\u7531\u8c03\u67e5\uff1a\u4e2d\u5b50\u884d\u5c04\u548c\u900f\u5c04X\u5c04\u7ebf\u663e\u5fae\u955c\u7814\u7a76\uff1b\u6e05\u534e\u5927\u5b66<\/strong>\u2014\u2014\u5229\u7528Biginelli\u53cd\u5e94\u5b9e\u73b0\u591a\u5143\u805a\u5408\uff1b\u7535\u5b50\u79d1\u6280\u5927\u5b66<\/strong>\u2014\u2014\u901a\u8fc7FeN3<\/sub>\u5d4c\u5165\u7684\u77f3\u58a8\u70ef\u50ac\u5316\u56db\u6c27\u5316\u4e8c\u6c2e\u5236\u6c28\uff1b\u53f0\u6e7e\u4e2d\u592e\u5927\u5b66\u7b49<\/strong>\u2014\u2014\u5177\u6709\u5f3a\u76f8\u4f4d\u5339\u914d\u6027\u7684\u949b\u7845\u9178\u76d0\u7684\u4e8c\u6b21\u8c10\u6ce2\u54cd\u5e94\u7814\u7a76\uff1b\u53a6\u95e8\u5927\u5b66<\/strong>\u2014\u2014\u94c2\u8868\u9762\u7684\u6c27\u5438\u9644\u6001\u7684\u6d41\u52a8\u6027\u548c\u53cd\u5e94\u6d3b\u6027\u7814\u7a76\uff1b\u4e2d\u79d1\u9662\u5c71\u897f\u7164\u5316\u6240\u7b49<\/strong>\u2014\u2014\u53ef\u89c1\u5149\u9a71\u52a8\u7684Au\/SiC\u50ac\u5316\u5242\u8868\u9762\u5149\u50ac\u5316\u8089\u6842\u919b\u9009\u62e9\u6027\u52a0\u6c22\uff1b\u4e2d\u79d1\u9662\u798f\u5efa\u7269\u6784\u6240<\/strong>\u2014\u2014BiFSeO3<\/sub>\uff1a\u4e00\u79cd\u5229\u7528\u5355\u4e00\u66ff\u4ee3\u65b9\u5f0f\u8bbe\u8ba1\u7684\u4f18\u5f02\u7684\u500d\u9891\u6750\u6599\uff1b\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u7b49<\/strong>\u2014\u2014\u5229\u7528\u94c1\/\u94b4\u56db\u8054\u5421\u5576\u914d\u5408\u7269\u5b9e\u73b0CO2<\/sub>\u7684\u9ad8\u6548\u4e14\u9ad8\u9009\u62e9\u6027\u5149\u50ac\u5316\u8fd8\u539f\uff1b\u5357\u4eac\u90ae\u7535\u5927\u5b66\u7b49<\/strong>\u2014\u2014\u901a\u8fc7\u5171\u632f\u5de5\u7a0b\u5b9e\u73b0\u6709\u673a\u534a\u5bfc\u4f53\u52a8\u6001\u8c03\u8c10\u7684\u6700\u4f73\u81ea\u9002\u5e94\u6027\u7814\u7a76\u3002<\/p>\n 1\u3001\u590d\u65e6\u5927\u5b66\uff1a<\/strong>\u4f7f\u7528CH3<\/sub>NH3<\/sub>PbBr0.9<\/sub>I2.1<\/sub><\/strong>\u91cf\u5b50\u70b9\u901a\u8fc7\u754c\u9762\u5de5\u7a0b\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd<\/strong><\/span><\/p>\n \u56fe1 \u754c\u9762\u5de5\u7a0b\u6cd5\u539f\u7406\u793a\u610f\u56fe<\/strong><\/p>\n \u4e3a\u4e86\u63d0\u9ad8\u9499\u949b\u77ff\u578b\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\uff0c\u63d0\u9ad8\u754c\u9762\u7535\u8377\u8f6c\u79fb\u901f\u7387\u81f3\u5173\u91cd\u8981\uff0c\u6240\u4ee5\uff0c\u5e94\u5408\u7406\u8bbe\u8ba1\u8bbe\u5907\u7684\u754c\u9762\u5de5\u7a0b\u3002<\/p>\n \u8fd1\u65e5\uff0c\u6211\u56fd\u590d\u65e6\u5927\u5b66\u7684\u738b\u5fe0\u80dc\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u90d1\u803f\u5cf0\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u754c\u9762\u5de5\u7a0b\u65b9\u6cd5\uff0c\u5373\u901a\u8fc7\u534f\u8c03MAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u4e0e\u7a7a\u7a74\u8f6c\u79fb\u6750\u6599\uff08HTM\uff09\u5c42\u95f4\u7684MAPbBr3\u2013x<\/sub>Ix<\/sub>\uff08MA = CH3<\/sub>NH3<\/sub>\uff09\u91cf\u5b50\u70b9\u6765\u8c03\u8282\u5e73\u9762\u5f02\u8d28\u7ed3\u9499\u949b\u77ff\u578b\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u4f0f\u6027\u80fd\u3002\u901a\u8fc7\u8c03\u8282Br\uff1aI\u7684\u8ba1\u91cf\u6bd4\uff0c\u5f97\u5230\u7684MAPbBr3-x<\/sub>Ix<\/sub>\u91cf\u5b50\u70b9\u8868\u73b0\u51fa\u53ef\u8c03\u8c10\u7684\u8367\u5149\u6027\u5e76\u4f4d\u4e8e\u80fd\u5e26\u8fb9\u7f18\u4f4d\u7f6e\u3002\u5f53MAPbBr3-x<\/sub>Ix<\/sub>\u7684\u4ef7\u5e26\uff08VB\uff09\u8fb9\u7f18\u4f4d\u4e8eMAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u4ee5\u4e0b\u65f6\uff0c\u7a7a\u7a74\u4eceMAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u5230HTM\u5c42\u7684\u4f20\u8f93\u4f1a\u53d7\u963b\u3002\u56e0\u6b64\uff0c\u529f\u7387\u8f6c\u6362\u6548\u7387\u964d\u4f4e\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u5f53MAPbBr3-x<\/sub>Ix<\/sub>\u91cf\u5b50\u70b9\u7684\u4ef7\u5e26\u8fb9\u7f18\u4f4d\u4e8eMAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u4ef7\u5e26\u8fb9\u7f18\u548cHTM\u5c42\u7684\u6700\u9ad8\u5360\u636e\u5206\u5b50\u8f68\u9053\u4e4b\u95f4\u65f6\uff0c\u7a7a\u7a74\u4eceMAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u5230HTM\u5c42\u7684\u4f20\u8f93\u4f1a\u66f4\u597d\uff0c\u4ece\u800c\u5bfc\u81f4\u586b\u5145\u56e0\u5b50\u3001\u77ed\u8def\u7535\u6d41\u4ee5\u53ca\u529f\u7387\u8f6c\u6362\u6548\u7387\u7684\u663e\u8457\u6539\u5584\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Enhancing Perovskite Solar Cell Performance by Interface Engineering Using CH3<\/sub>NH3<\/sub>PbBr0.9<\/sub>I2.1<\/sub> Quantum Dots<\/a> \uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b04519\uff09<\/p>\n 2\u3001\u56fd\u7acb\u53f0\u6e7e\u5927\u5b66\u7b49\uff1aLi2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub>\uff08M<\/em> = Li\u3001Ni\u3001Co\u3001Mn\uff09\u5fae\u7403\u6b63\u6781\u5bb9\u91cf\u51cf\u5f31\u7684\u539f\u7531\u8c03\u67e5\uff1a\u4e2d\u5b50\u884d\u5c04\u548c\u900f\u5c04X\u5c04\u7ebf\u663e\u5fae\u955c\u7814\u7a76<\/span><\/strong><\/p>\n \u56fe2 \u4e0d\u540c\u5145\u7535\u7a0b\u5ea6\u4e0b\uff0cLi2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub><\/strong>\uff08M = Li<\/strong>\u3001Ni<\/strong>\u3001Co<\/strong>\u3001Mn<\/strong>\uff09\u5fae\u7403\u6b63\u6781\u9897\u7c92\u7684\u76f8\u56fe<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u56fd\u7acb\u53f0\u6e7e\u5927\u5b66\u3001\u56fd\u7acb\u53f0\u5317\u79d1\u6280\u5927\u5b66\u7684\u5218\u5982\u71b9\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u6fb3\u5927\u5229\u4e9a\u6838\u79d1\u5b66\u6280\u672f\u7ec4\u7ec7\u7684Vanessa K. Peterson\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8fdb\u884c\u56e2\u961f\u5408\u4f5c\uff0c\u4f7f\u7528\u4e2d\u5b50\u884d\u5c04\u548c\u900f\u5c04X\u5c04\u7ebf\u663e\u5fae\u955c\u7ed3\u5408\u7684\u65b9\u5f0f\u5bf9\u5728\u5168\u7535\u6c60\u4e2dLi2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub>\uff08M = Li\u3001Ni\u3001Co\u3001Mn\uff09\u5fae\u7403\u6b63\u6781\u590d\u5408\u6750\u6599\u5bb9\u91cf\u51cf\u5f31\u7684\u673a\u7406\u8fdb\u884c\u4e86\u8c03\u67e5\uff0c\u4f7f\u5f97\u5176\u5728\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\u6750\u6599\u7684\u76f8\uff0c\u7ed3\u6676\u6001\u4ee5\u53ca\u5f62\u6001\u7684\u6f14\u53d8\u8fc7\u7a0b\u88ab\u4eba\u4eec\u6240\u7406\u89e3\u3002<\/p>\n \u8be5\u7535\u6781\u6750\u6599\u539f\u59cb\u7ec4\u6210\u4e3a73\uff081\uff09wt% \u70b9\u7fa4\u4e3aR3m\u7684LiM<\/em>O2<\/sub>\u548c27\uff081\uff09wt%\u70b9\u7fa4\u4e3aC2\/m\u7684Li2<\/sub>MnO3<\/sub>\u3002\u5728\u663e\u5fae\u955c\u7684\u89c2\u5bdf\u4e0bLi2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub>\u7535\u6781\u88ab\u63ed\u793a\u7531\u5145\u7535\u52304.55V\uff08vs\u00a0Li+<\/sup>\/Li\uff09\u7684LiM<\/em>O2<\/sub>\u76f8\u7684\u56fa\u6eb6\u53cd\u5e94\u6240\u542f\u52a8\uff0c\u5e76\u5728LiM<\/em>O2<\/sub>\u76f8\u7684\u4e24\u76f8\u53cd\u5e94\u4ee5\u53caLi2<\/sub>MnO3<\/sub>\u6790\u6c27\u8fdb\u4e00\u6b65\u5145\u7535\u52304.7V\uff08vs\u00a0Li+<\/sup>\/Li\uff09\u65f6\u52a0\u5f3a\uff0c\u6d89\u53ca\u4e86\u65e0\u8bba\u4f55\u79cd\u76f8\u7684\u6700\u5927\u6676\u683c\u53d8\u5316\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728\u968f\u540e\u7684\u9502\u5316\u8fc7\u7a0b\u4e2d\u53d1\u751f\u653e\u7535\u6240\u4ea7\u751f\u88c2\u7f1d\u7684Li2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub>\u7535\u6781\u9897\u7c92\u660e\u663e\u6062\u590d\uff0c\u800c\u8fd9\u4e3b\u8981\u4e0e\u91cd\u65b0\u6062\u590d\u7684LiMO2<\/sub>\u76f8\u56fa\u6eb6\u53cd\u5e94\u6709\u5173\u3002\u8fd9\u9879\u5de5\u4f5c\u8868\u660e\uff0c\u5145\u7535\u65f6Li2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub>\u7535\u6781\u6676\u683c\u5c3a\u5bf8\u51cf\u5c11\uff0c\u624d\u5bfc\u81f4\u4e86Li2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub>\u7535\u6781\u7684\u5206\u88c2\uff0c\u5e76\u4e14Li2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub>\u7535\u6781\u6676\u683c\u5c3a\u5bf8\u7684\u53d8\u5316\u53c8\u4e0e\u88c2\u7eb9\u53d8\u5316\u7a0b\u5ea6\u76f8\u5173\uff0c\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u53d1\u751f\u53cd\u5411\u56fa\u6eb6\u53cd\u5e94\uff0c\u53c8\u4f7f\u5f97\u88c2\u7eb9\u6709\u53ef\u80fd\u6108\u5408\u3002\u91cd\u8981\u7684\u662f\uff0c\u6b63\u662f\u56e0\u4e3aLiM<\/em>O2<\/sub>\u76f8\u53d1\u751f\u4e86\u76f8\u5206\u79bb\u7684\u4e24\u76f8\u53cd\u5e94\uff0c\u624d\u963b\u6b62\u4e86\u7535\u6781\u9897\u7c92\u7684\u5b8c\u5168\u6108\u5408\uff0c\u5bfc\u81f4\u5176\u5728\u540e\u7eed\u5faa\u73af\u4e2d\u88ab\u7c89\u788e\u3002\u8fd9\u9879\u5de5\u4f5c\u6307\u51fa\u4e86\u5bfc\u81f4\u76f8\u5206\u79bb\u7684\u6700\u5c0f\u5f71\u54cd\u56e0\u7d20\uff0c\u4f8b\u5982\uff0c\u4e24\u76f8\u53cd\u5e94\u8fc7\u7a0b\u548c\u6790\u6c27\u8fc7\u7a0b\u4f5c\u4e3a\u5176\u4e2d\u7684\u6838\u5fc3\u56e0\u7d20\u963b\u6b62\u4e86\u7535\u6781\u5bb9\u91cf\u7684\u51cf\u5f31\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>The Origin of Capacity Fade in the Li2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub> (M = Li, Ni, Co, Mn) Microsphere Positive Electrode: An Operando Neutron Diffraction and Transmission X-ray Microscopy Study<\/a> \uff08J. Am. Chem. Soc., 2016,\u00a0<\/strong>DOI: 10.1021\/jacs.6b03932\uff09<\/p>\n 3\u3001\u6e05\u534e\u5927\u5b66\uff1a<\/strong>\u5229\u7528Biginelli<\/strong>\u53cd\u5e94\u5b9e\u73b0\u591a\u5143\u805a\u5408<\/strong><\/span><\/p>\n \u00a0 \u56fe3 \u591a\u5143\u805a\u5408\u65b9\u6cd5\u539f\u7406\u793a\u610f\u56fe<\/strong><\/p>\n \u591a\u5143\u805a\u5408\u65b9\u6cd5\u5df2\u7ecf\u88ab\u89c6\u4e3a\u7ec4\u5408\u5316\u5b66\uff0c\u9ad8\u5206\u5b50\u5316\u5b66\u4ee5\u53ca\u6709\u673a\u5316\u5b66\u4e4b\u95f4\u65b0\u7684\u4ea4\u53c9\u70b9\u3002\u800c\u5176\u4e2d\uff0c\u4e09\u5206\u91cf\u7684Biginelli\u53cd\u5e94\u5df2\u7ecf\u4f5c\u4e3a\u591a\u7ec4\u5206\u53cd\u5e94\u7684\u6a21\u578b\uff08MCR\uff09\uff0c\u7528\u4e8e\u6709\u6548\u5730\u5236\u5907\u53c2\u6570\u8fde\u7eed\u53d8\u5316\u7684\u7ed3\u6784\u4f46\u4e0d\u540c\u7269\u7406\u6027\u8d28\u7684\u94fe\u7684\u6570\u636e\u5e93\u3002\u540c\u65f6\uff0c\u81ea\u7136\u589e\u52a0\u7684\u53cd\u5e94\u6a21\u5757\uff08\u5355\u4f53\uff09\u76f4\u63a5\u589e\u52a0\u4e86\u5728\u5e93\u805a\u5408\u7269\u7684\u6570\u91cf\uff0c\u8fdb\u4e00\u6b65\u5730\u6709\u6548\u63d0\u9ad8\u4e86\u805a\u5408\u7269\u5236\u5907\u4e2d\u7684\u6548\u7387\u3002<\/p>\n \u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u5316\u5b66\u7cfb\u7684\u9676\u78ca\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u62a5\u9053\uff0c\u4e0a\u8ff0\u76f8\u5e94\u805a\u5408\u7269\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff08Tg<\/sub><\/em>\uff09\u5df2\u7ecf\u88ab\u6574\u7406\u51fa\u6765\uff0c\u5e76\u9996\u6b21\u7528\u4e8e\u9884\u6d4b\u76f8\u5e94\u805a\u5408\u7269\u7684\u672a\u88ab\u53d1\u73b0\u7684\u540c\u7cfb\u7269\u7684Tg<\/sub><\/em>\u3002\u540c\u65f6\uff0c\u8fd9\u9879Tg<\/sub>\u6570\u636e\u5e93\u5df2\u7ecf\u7528\u4e8e\u89e3\u91ca\u76f8\u5e94\u805a\u5408\u7269\u7ed3\u6784\u56e0\u7d20\uff08\u5982\u8fde\u63a5\u7ec4\u3001\u5355\u4f53\u94fe\u957f\u7b49\uff09\u5f15\u8d77\u7684Tg<\/sub><\/em>\u7684\u5e38\u89c4\u53d8\u5316\uff0c\u4ece\u800c\u521d\u6b65\u63d0\u51fa\u4e86\u591a\u7ec4\u5206\u7ec4\u5408\u805a\u5408\u7cfb\u7edf\u7684\u5b66\u672f\u610f\u4e49\u3002\u4ed6\u4eec\u76f8\u4fe1\uff0c\u5f53\u524d\u7684\u7814\u7a76\u5960\u5b9a\u4e86\u901a\u8fc7MCR\u5408\u6210\u65b0\u805a\u5408\u7269\u7684\u6570\u636e\u5e93\uff0c\u5e76\u4e14\u53ef\u80fd\u5bf9\u5728\u8de8\u5b66\u79d1\u9886\u57df\u5177\u6709\u66f4\u5e7f\u6cdb\u7684\u7814\u7a76\u601d\u8def\u6709\u6240\u542f\u793a\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Multicomponent Combinatorial Polymerization via the Biginelli Reaction<\/a> \uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b04425\uff09<\/p>\n 4\u3001\u7535\u5b50\u79d1\u6280\u5927\u5b66\uff1a<\/strong>\u901a\u8fc7<\/strong>FeN3<\/sub><\/strong>\u5d4c\u5165\u7684\u77f3\u58a8\u70ef\u50ac\u5316\u56db\u6c27\u5316\u4e8c\u6c2e\u5236\u6c28<\/strong><\/span><\/p>\n \u00a0 \u56fe4 \u77f3\u58a8\u70ef\u4e2d\u5d4c\u5165<\/strong>FeN3<\/sub><\/strong>\u7684\u50ac\u5316\u5242\u7684\u7ed3\u6784\u539f\u7406\u793a\u610f\u56fe<\/strong><\/p>\n \u5927\u6c14\u4e2d\u7684N2<\/sub>\u975e\u5e38\u4e30\u5bcc\uff0c\u4f46\u5728\u4e00\u4e9b\u6709\u673a\u7269\u4e2d\u5f88\u96be\u5b58\u5728\uff0c\u9664\u975e\u5c06\u4e4b\u5148\u8f6c\u5316\u6210\u6c28\uff08NH3<\/sub>\uff09\u3002\u6c2e\u7684\u56fa\u5b9a\uff0c\u662f\u751f\u7269\u5316\u5b66\u4e2d\u6700\u70ed\u95e8\u7684\u8f6c\u5316\u5de5\u827a\u4e4b\u4e00\u3002<\/p>\n \u8fd1\u65e5\uff0c\u7535\u5b50\u79d1\u6280\u5927\u5b66\u5149\u7535\u4fe1\u606f\u5b66\u9662\u7684\u674e\u5c0f\u98de\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u6839\u636e\u7b2c\u4e00\u6027\u539f\u7406\u8bbe\u8ba1\u4e86\u4e00\u79cd\u77f3\u58a8\u70ef\u4e2d\u5d4c\u5165FeN3<\/sub>\u7684\u56fa\u6c2e\u50ac\u5316\u5242\u3002\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0cFeN3<\/sub>\u4e2d\u5fc3\u662f\u9ad8\u5ea6\u81ea\u65cb\u6781\u5316\u7684\uff0c\u4f7f\u5f97\u5176\u5177\u6709\u4e00\u4e2a\u5c40\u57df\u78c1\u77e9\uff0c\u8fd9\u5c31\u76f8\u5f53\u4e8e\u80fd\u591f\u4fc3\u8fdb\u5bf9N2<\/sub>\u7684\u5438\u6536\uff0c\u5e76\u4e14\u6d3b\u5316\u5176\u4e2d\u7684N-N\u4e09\u952e\u3002\u77f3\u58a8\u70ef\u4e0eFeN3<\/sub>\u95f4\u7684\u534f\u540c\u4f5c\u7528\u4f7f\u5f97\u5176\u80fd\u591f\u901a\u8fc7\u4e00\u79cd\u516d\u8d28\u5b50\u516d\u7535\u5b50\u8fc7\u7a0b\uff0c\u4ee5\u5ba4\u6e29\u4e0b\u4e09\u79cd\u53ef\u80fd\u7684\u65b9\u5f0f\u5c06N2<\/sub>\u9ad8\u6548\u5730\u8f6c\u5316\u4e3aNH3<\/sub>\u3002\u8be5\u6210\u679c\u63d0\u4f9b\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u56fa\u6c2e\u50ac\u5316\u6a21\u5f0f\uff0c\u5728\u5408\u6210\u6c28\u5de5\u4e1a\u4e2d\u5e94\u7528\u6f5c\u529b\u5de8\u5927\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Conversion of dinitrogen to ammonia by FeN3-embedded graphene<\/a> \uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b04778\uff09<\/p>\n 5\u3001\u53f0\u6e7e\u4e2d\u592e\u5927\u5b66\u7b49\uff1a<\/strong>\u5177\u6709\u5f3a\u76f8\u4f4d\u5339\u914d\u6027\u7684\u949b\u7845\u9178\u76d0\u7684\u4e8c\u6b21\u8c10\u6ce2\u54cd\u5e94\u7814\u7a76<\/strong><\/span><\/p>\n \u56fe5\u00a0Li2<\/sub>K4<\/sub>[(TiO)Si4<\/sub>O12<\/sub>]\u7684\u4e09\u7ef4\u6846\u67b6\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n \u7531\u4e8e\u5728\u6fc0\u5149\u5e94\u7528\u4e2d\u5177\u6709\u91cd\u8981\u7684\u6280\u672f\u6027\uff0c\u5bfb\u627e\u65b0\u800c\u9ad8\u6548\u7684\u975e\u7ebf\u6027\u5149\u5b66\uff08NLO\uff09\u6750\u6599\u4e00\u76f4\u662f\u4e00\u4e2a\u6d3b\u8dc3\u7684\u7814\u7a76\u8bfe\u9898\u3002\u867d\u7136\u5df2\u7ecf\u6709\u5927\u91cf\u7684\u500d\u9891\u6c27\u5316\u7269\u3001\u78f7\u9178\u76d0\u3001\u787c\u9178\u76d0\u3001\u548c\u542b\u6c1f\u787c\u9178\u76d0\u88ab\u53d1\u73b0\uff0c\u4f46\u662f\u8fd8\u6ca1\u6709\u5177\u6709NLO\u6027\u80fd\u7684\u8fc7\u6e21\u91d1\u5c5e\u7845\u9178\u76d0\u88ab\u62a5\u9053\u53d1\u73b0\u3002<\/p>\n \u8fd1\u65e5\uff0c\u6211\u56fd\u53f0\u6e7e\u4e2d\u592e\u5927\u5b66\u5316\u5b66\u7cfb\u3001\u4e2d\u592e\u7814\u7a76\u9662\u5316\u5b66\u7814\u7a76\u6240\u7684\u674e\u5149\u534e\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u53f0\u6e7e\u4e2d\u592e\u5927\u5b66\u5316\u5b66\u7cfb\u7684\u5f20\u4f2f\u741b\uff08\u901a\u8baf\u4f5c\u8005\uff09\u5e26\u9886\u56e2\u961f\u901a\u8fc7\u4f7f\u7528\u901a\u91cf\u548c\u8d85\u4e34\u754c\u6c34\u70ed\u6cd5\u5408\u6210\u4e86\u4e24\u79cd\u949b\u7684\u7845\u9178\u76d0\u6676\u4f53\uff0cLi2<\/sub>K4<\/sub>[(TiO)Si4<\/sub>O12<\/sub>]\u548cLi2<\/sub>Rb4<\/sub>[(TiO)Si4<\/sub>O12<\/sub>]\u3002\u5176\u72ec\u7279\u7684\u4e09\u7ef4\u6846\u67b6\u7ed3\u6784\u5305\u542b\u7740\u9ad8\u5ea6\u538b\u7f29\u7684TiO5<\/sub>\u56db\u65b9\u9525\uff0c\u800c\u5176\u4e2d\u56db\u65b9\u9525\u4e4b\u95f4\u53c8\u5f7c\u6b64\u76f8\u8fde\u5f62\u6210Ti-O\u952e\u957f\u53ef\u8c03\u7684\u00b7\u00b7\u00b7Ti\u2013O\u00b7\u00b7\u00b7Ti\u2013O\u76f4\u94fe\u3002\u8fd9\u4e24\u79cd\u6750\u6599\u6ee1\u8db3\u4e86\u9ad8\u6548\u4e8c\u6b21\u8c10\u6ce2\u4ea7\u751f\u7684\u8981\u6c42\uff0c\u5305\u62ec\u7f3a\u4e2d\u5fc3\u7684\u53cd\u5bf9\u79f0\u6027\uff0c\u5927\u78c1\u5316\u7387\uff0c\u76f8\u4f4d\u5339\u914d\u6027\uff0c\u8ff7\u4eba\u7684\u4f20\u8f93\u6ce2\u957f\uff0c\u8010\u6fc0\u5149\u635f\u4f24\u6027\u4ee5\u53ca\u70ed\u7a33\u5b9a\u6027\u3002\u8fd9\u4e9b\u5c5e\u6027\u4f7f\u5f97\u5b83\u4eec\u6210\u4e3a\u4e86\u975e\u5e38\u6709\u5438\u5f15\u529b\u7684\u500d\u9891\u6750\u6599\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Titanosilicates with Strong Phase-Matched Second Harmonic Generation Responses<\/a>\uff08J. Am. Chem. Soc., 2016,\u00a0DOI: 10.1021\/jacs.6b05327\uff09<\/p>\n 6\u3001\u53a6\u95e8\u5927\u5b66\uff1a\u94c2\u8868\u9762\u7684\u6c27\u5438\u9644\u6001\u7684\u6d41\u52a8\u6027\u548c\u53cd\u5e94\u6d3b\u6027\u7814\u7a76<\/span><\/strong><\/p>\n \u56fe6\u00a0Pt\u7535\u6781\u50ac\u5316\u6c27\u5316\u8fc7\u7a0b\u539f\u7406\u793a\u610f\u56fe<\/strong><\/p>\n \u94c2\u8868\u9762\u6c27\u7684\u5438\u9644\u6001\u7684\u6d41\u52a8\u6027\u548c\u5438\u9644\u6027\u5bf9\u4e8e\u8868\u9762\u5438\u9644CO\u53d1\u751f\u6c27\u5316\u53cd\u5e94\u81f3\u5173\u91cd\u8981\uff0c\u8fd9\u53ef\u4ee5\u5bfc\u81f4Pt\u50ac\u5316\u5242\u7684\u5931\u6d3b\u3002<\/p>\n \u8fd1\u65e5\uff0c\u53a6\u95e8\u5927\u5b66\u7684\u8a79\u4e1c\u5e73\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u901a\u8fc7\u4f7f\u7528\u7eb3\u7c73\u7535\u6781\u548c\u8d85\u5fae\u7535\u6781\u6280\u672f\uff0c\u4ed6\u4eec\u6210\u529f\u89c2\u5bdf\u5230\u4e86\u7531H2<\/sub>O\u4ee5\u53ca\u6c27\u5438\u9644\u6001\u548cPt\u8868\u9762CO\u95f4\u53d1\u751f\u7684\u754c\u9762\u53cd\u5e94\u7684\u89e3\u79bb\u5438\u9644\u6240\u4ea7\u751f\u7684\u6c27\u5438\u9644\u6001\u7684\u8868\u9762\u6d41\u52a8\u6027\u3002\u5728Pt\u7eb3\u7c73\u7535\u6781\u4e0a\u7684\u89e3\u5438\u7535\u8377\u91cf\u88ab\u53d1\u73b0\u4e0e\u626b\u63cf\u901f\u7387\u7684\u5e73\u65b9\u6839\u7684\u5012\u6570\u6210\u6b63\u6bd4\u3002\u5229\u7528\u8be5\u4fe1\u606f\uff0c\u6c27\u5438\u9644\u6001\u7684\u8868\u89c2\u8868\u9762\u6269\u6563\u7cfb\u6570\u572825\u2103\u4e0b\u662f\uff085.61 \u00b1 0.84\uff09\u00d710\u201310<\/sup> cm2<\/sup>\/s\u3002\u5bf9\u4e8eCO\u5728\u8868\u9762\u7684\u6c27\u5316\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u89c2\u5bdf\u5230\u6709\u4e24\u4e2a\u7535\u6d41\u5cf0\uff0c\u8fd9\u4f7f\u5f97CO\u7684\u6c27\u5316\u8fc7\u7a0b\u80fd\u591f\u5728Pt\u7535\u6781\/\u7535\u89e3\u6db2\u7684\u754c\u9762\u4e2d\u53d1\u751f\uff0c\u540c\u65f6\u90bb\u8fd1Pt\u7535\u6781\u8868\u9762\u6c27\u5316\u6001\u5177\u6709\u6d41\u52a8\u6027\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u6c27\u5316\u6001\u7684\u8868\u9762\u6d41\u52a8\u6027\u5728\u9632\u6b62Pt\u50ac\u5316\u5242\u4e2d\u6bd2\u4ee5\u53caPt\u50ac\u5316\u5242\u53cd\u5e94\u4e2d\u975e\u5e38\u91cd\u8981\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Mobility and Reactivity of Oxygen Adspecies on Platinum Surface<\/a> \uff08J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b05259\uff09<\/p>\n 7\u3001\u4e2d\u79d1\u9662\u5c71\u897f\u7164\u5316\u6240\u7b49<\/strong>\uff1a<\/strong>\u53ef\u89c1\u5149\u9a71\u52a8\u7684Au\/SiC<\/strong>\u50ac\u5316\u5242\u8868\u9762\u5149\u50ac\u5316\u8089\u6842\u919b\u9009\u62e9\u6027\u52a0\u6c22<\/strong><\/span><\/p>\n \u56fe7\u00a0Au\/SiC\u50ac\u5316\u5242\u50ac\u5316\u52a0\u6c22\u8089\u6842\u919b\u4e3a\u8089\u6842\u9187\u7684\u539f\u7406\u793a\u610f\u56fe<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5c71\u897f\u7164\u5316\u6240\u7684\u90ed\u5411\u4e91\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u90ed\u6653\u5b81\uff08\u901a\u8baf\u4f5c\u8005\uff09\u4ee5\u53ca\u7f8e\u56fd\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66\u9999\u69df\u5206\u6821\u7684\u6768\u5b8f\uff08\u901a\u8baf\u4f5c\u8005\uff09\u5408\u4f5c\uff0c\u5229\u7528Au\/SiC\u590d\u5408\u7c92\u5b50\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\u6210\u529f\u5b9e\u73b0\u4e86\u8089\u6842\u919b\u9009\u62e9\u6027\u52a0\u6c22\u5408\u6210\u8089\u6842\u9187\u3002\u572820\u2103\u548c\u53ef\u89c1\u5149\u4e0b\uff0c\u5b9e\u73b0\u4e86\u52a0\u6c22\u6548\u7387\u9ad8\u8fbe487 h-1<\/sup>\u4ee5\u53ca100%\u5408\u6210\u9187\u7684\u53ef\u9009\u62e9\u6027\u3002\u8fd9\u79cd\u9ad8\u6027\u80fd\u5f97\u76ca\u4e8e\u8868\u9762\u5c40\u57df\u7b49\u79bb\u5b50\u4f53\u5171\u632f\u7684Au\u7eb3\u7c73\u9897\u7c92\u7684\u534f\u540c\u6548\u5e94\u4ee5\u53ca\u7535\u8377\u5728SiC\/Au\u754c\u9762\u95f4\u7684\u4f20\u8f93\u3002\u867d\u7136\u7535\u5b50\u548c\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\u6709\u5229\u4e8e\u03b1\u3001\u03b2-\u4e0d\u9971\u548c\u919b\u7684\u672b\u7aef\u5438\u9644\u4ece\u800c\u9009\u62e9\u6027\u5730\u8f6c\u5316\u4e3a\u4e0d\u9971\u548c\u9187\uff0c\u4f46\u5728\u5e26\u7535\u91d1\u5c5e\u8868\u9762\u5f02\u4e19\u9187\u5f88\u5bb9\u6613\u88ab\u6c27\u5316\u6210\u4e19\u916e\u3002\u4ed6\u4eec\u56e2\u961f\u5c55\u793a\u4e86Au\/SiC\u5149\u50ac\u5316\u5242\u591f\u9ad8\u5ea6\u9009\u62e9\u6027\u5730\u50ac\u5316\u5404\u79cd\u03b1\u3001\u03b2-\u4e0d\u9971\u548c\u919b\u4e3a\u76f8\u5e94\u7684\u4e0d\u9971\u548c\u9187\u3002<\/p>\n<\/p>\n
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