{"id":31272,"date":"2016-08-05T16:00:55","date_gmt":"2016-08-05T08:00:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=31272"},"modified":"2016-08-05T13:05:22","modified_gmt":"2016-08-05T05:05:22","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81%ef%bd%9cnature-%e5%ad%90%e5%88%8aangewjacs%e7%ad%89%e7%94%b5%e5%82%ac%e5%8c%96%e6%9d%90%e6%96%99%e8%bf%9b%e5%b1%95%e6%9a%91%e6%9c%9f%e7%ac%ac%e4%ba%8c%e6%b3%a2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=31272","title":{"rendered":"\u9876\u520a\u52a8\u6001\uff5cNature \u5b50\u520a\/Angew\/JACS\u7b49\u7535\u50ac\u5316\u6750\u6599\u8fdb\u5c55\u6691\u671f\u7b2c\u4e8c\u6ce2\u3010\u65b0\u80fd\u6e90\u5468\u62a5\u7b2c14\u671f\u3011"},"content":{"rendered":"<p>\u968f\u7740\u8fd1\u5e74\u6765\u968f\u7740\u65b0\u80fd\u6e90\u884c\u4e1a\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u4f17\u591a\u79d1\u5b66\u5bb6\u90fd\u5728\u81f4\u529b\u4e8e\u5f00\u53d1\u51fa\u53ef\u4f9b\u5b9e\u7528\u7684\u65b0\u578b\u73af\u4fdd\u80fd\u6e90\u4f9b\u4eba\u4eec\u4f7f\u7528\uff0c\u5176\u4e2d\u6700\u4e3a\u6838\u5fc3\u7684\u7535\u50ac\u5316\u5242\u6750\u6599\u51b3\u5b9a\u7740\u6574\u4e2a\u884c\u4e1a\u7684\u53d1\u5c55\uff0c\u9ad8\u6d3b\u6027\u3001\u9ad8\u9009\u62e9\u6027\u3001\u4f4e\u5ec9\u7684\u4ef7\u683c\u662f\u5927\u5bb6\u4e00\u76f4\u68a6\u5bd0\u7684\u8ffd\u6c42\u3002\u63a5\u4e0b\u6765\u8ba9\u6211\u4eec\u4e00\u8d77\u6765\u89c2\u8d4f\u8fd1\u671f\u5728\u5404\u5927\u9876\u7ea7\u671f\u520a\u4e0a\u7684\u6700\u65b0\u7535\u50ac\u5316\u7814\u7a76\u8fdb\u5c55\u5427\u3002<\/p>\n<p><strong>1<\/strong><strong>.<\/strong><strong>Nature Communications<\/strong><strong>\uff1a\u94d1<\/strong><strong>\/<\/strong><strong>\u7845\u5f31\u5f31\u8054\u5408\u6210\u5171\u50ac\u5316\u5242\u5728\u6790\u6c22\u53cd\u5e94\u4e2d\u5927\u4e8e\u94c2\u57fa\u50ac\u5316\u5242<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31273 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig-1.jpg\" alt=\"fig 1\" width=\"600\" height=\"638\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig-1-282x300.jpg 282w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1. Rh\/Si<\/strong><strong>\u7eb3\u7c73\u7ebf\u4e0a<\/strong><strong>HER<\/strong><strong>\u53cd\u5e94\u6a21\u578b<\/strong><strong>. a) HER<\/strong><strong>\u53cd\u5e94\u673a\u7406\u56fe\u793a\uff1a<\/strong><strong>1) <\/strong><strong>\u6c22\u79bb\u5b50\u5728\u94d1\u8868\u9762\u7684\u5438\u9644<\/strong><strong>.2) <\/strong><strong>\u4ece\u94d1\u8868\u9762\u5230\u7845\u8868\u9762\u7684\u6c22\u539f\u5b50\u7684\u6269\u6563<\/strong><strong>. 3) <\/strong><strong>\u5728\u7845\u8868\u9762\u4e0a\u7684\u5438\u9644\u7684\u6c22\u539f\u5b50\u4e0e\u8d28\u5b50\u53d1\u751f\u53cd\u5e94\uff0c\u5f62\u6210\u6c22\u5206\u5b50<\/strong><strong>. <\/strong><strong>\u94d1\u5438\u9644\u7684\u6c22\u53ef\u4ee5\u8fc1\u79fb\u5230\u7845\u539f\u5b50\u7684\u8868\u9762\uff08\u6807\u6709\u7ea2\u8272\u5706\u5708\uff09<\/strong><strong>; b) IS<\/strong><strong>\uff0c\u59cb\u6001\uff1b<\/strong><strong>c) TS<\/strong><strong>\uff0c\u8fc7\u6e21\u6001<\/strong><strong>; d) FS, <\/strong><strong>\u7ec8\u6001<\/strong><strong>; \u00a0e) <\/strong><strong>\u6d3b\u5316\u80fd\u5230\u8fbe\u8fc7\u6e21\u6001\u9700\u8981<\/strong><strong>0.24 eV<\/strong><strong>\uff1b\u7ec8\u6001\u5438\u9644\u6c22\u7684\u80fd\u91cf\u6bd4\u8fc7\u6e21\u6001\u7684\u4f4e<\/strong><strong>0.33 eV<\/strong><strong>\uff0c\u6bd4\u59cb\u6001\u7684\u4f4e<\/strong><strong>0.09 eV.<\/strong><\/p>\n<p>\u4f17\u6240\u5468\u77e5\uff0c\u94c2\u57fa\u7535\u50ac\u5316\u5242\u662f\u76ee\u524d\u6790\u6c22\u53cd\u5e94\u7684\u4e0d\u4e8c\u9009\u62e9\u3002\u4f46\u5728\u6790\u6c22\u53cd\u5e94\u4e2d\uff0c\u50ac\u5316\u5242\u90fd\u9075\u5faaSabatier\u539f\u5219\uff0c\u5373\u6c22\u5438\u9644\u5728\u50ac\u5316\u5242\u8868\u9762\u4e0a\u5e94\u8be5\u662f\u9002\u4e2d\u7684\u91cf\uff0c\u4ece\u800c\u8fbe\u5230\u6c22\u5438\u9644\u548c\u89e3\u5438\u4e4b\u95f4\u7684\u5e73\u8861\u3002<\/p>\n<p>\u4e3a\u4e86\u66f4\u597d\u5730\u5b9e\u73b0\u50ac\u5316\u6790\u6c22\u53cd\u5e94\uff0c\u7a81\u7834\u8fd9\u4e00\u5c40\u9650\uff0c\u6700\u8fd1\uff0c\u82cf\u5dde\u5927\u5b66\u529f\u80fd\u7eb3\u7c73\u4e0e\u8f6f\u7269\u8d28\u7814\u7a76\u9662\u90b5\u540d\u671b\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u3001\u674e\u6709\u52c7\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u9009\u62e9\u94d1\/\u7845\u7eb3\u7c73\u7ebf\u534f\u540c\u7684\u50ac\u5316\u5242\uff0c\u5176\u4e2d\uff0c\u6c22\u5438\u9644\u5728\u94d1\u4e0a\uff0c\u800c\u6790\u6c22\u53cd\u5e94\u53d1\u751f\u5728\u7845\u4e0a\u3002\u8be5\u6750\u6599\u62e5\u6709\u66f4\u9ad8\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u751a\u81f3\u8d85\u8fc7\u94c2\u78b3\u50ac\u5316\u5242\u3002\u4e14\u6570\u636e\u8868\u660e\u7845\u5728\u7535\u50ac\u5316\u4e2d\u6709\u7740\u5f88\u5927\u7684\u4f5c\u7528\u3002<\/p>\n<p>\u6b64\u5de5\u4f5c\u4e3a\u5f00\u53d1\u65e0\u8d35\u91d1\u5c5e\u6216\u5c11\u8d35\u91d1\u5c5e\u7528\u91cf\u7684\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u53ef\u9760\u7684\u65b9\u5411\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/www.nature.com\/ncomms\/2016\/160721\/ncomms12272\/full\/ncomms12272.html\" target=\"_blank\">A rhodium\/silicon co-electrocatalyst design concept to surpass platinum hydrogen evolution activity at high overpotentials<\/a><\/strong><\/p>\n<p><strong style=\"line-height: 1.5;\">2.Angew. Chem. Int. Ed.: <\/strong><strong style=\"line-height: 1.5;\">\u50ac\u5316<\/strong><strong style=\"line-height: 1.5;\">CO<sub>2<\/sub><\/strong><strong style=\"line-height: 1.5;\">\u8f6c\u4e3a\u78b3\u57fa\u71c3\u6599\u6709\u671b\u4f9b\u4eba\u4eec\u4f7f\u7528<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"wp-image-31274 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig2.png\" alt=\"fig2\" width=\"600\" height=\"449\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig2-300x225.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><br \/>\n<\/strong><strong>\u56fe<\/strong><strong>2. <\/strong><strong>\u591a\u6676\u94f6\u548c\u94f6\u7684\u6c27\u5316\u884d\u751f\u7269\u7684\u7535\u50ac\u5316\u751f\u6210<\/strong><strong>CO<\/strong><strong>\u6d3b\u6027\u7684\u6bd4\u8f83<\/strong><strong>.<\/strong><\/p>\n<p>\u4e3a\u4e86\u5c06\u96c6\u4e2d\u6392\u653e\u7684CO<sub>2<\/sub>\u7528\u7535\u5316\u5b66\u65b9\u6cd5\u8f6c\u5316\u4e3a\u78b3\u57fa\u7684\u71c3\u6599\uff0c\u4f5c\u4e3a\u53ef\u518d\u751f\u7684\u7535\u529b\u8d44\u6e90\uff0c\u8fbe\u5230\u78b3\u5faa\u73af\u7684\u76ee\u7684\uff0c\u5f88\u591a\u79d1\u5b66\u5bb6\u4e00\u76f4\u5728\u81f4\u529b\u4e8e\u5bfb\u627e\u4e00\u4e2a\u5ec9\u4ef7\u3001\u7a33\u5b9a\u3001\u9ad8\u6548\u4e14\u6709\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u6765\u5b9e\u73b0\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u4ee3\u5c14\u592b\u7279\u7406\u5de5\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u7cfbWilson A. Smith\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u5728\u4e00\u4e2a\u9002\u4e2d\u7684\u8fc7\u7535\u4f4d\u4e0b\uff0c\u7528\u94f6\u7684\u6c27\u5316\u884d\u751f\u7269\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u4e3aCO,\u50ac\u5316\u9009\u62e9\u6027\u9ad8\u8fbe80%\uff0c\u76f8\u6bd4\u4e8e\u540c\u6761\u4ef6\u4e0b\u7684\u94f6\u9ad8\u5f88\u591a\u3002\u6b64\u7814\u7a76\u8868\u660e\u9ad8\u6d3b\u6027\u4e3b\u8981\u5f97\u76ca\u4e8e\u7fa7\u57fa\u81ea\u7531\u57fa\u7684\u7a33\u5b9a\uff0c\u4e14\u7531\u4e8e\u8be5\u50ac\u5316\u5242\u8868\u9762PH\u8f83\u9ad8\u6291\u5236\u4e86\u6c22\u6c14\u7684\u6790\u51fa\uff0c\u6545\u800c\u6709\u5229\u4e8e\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<p>\u867d\u7136\u8be5\u94f6\u6c27\u5316\u7269\u7684\u50ac\u5316\u80fd\u529b\u6ca1\u6709\u91d1\u7684\u6c27\u5316\u7269\u9ad8\uff0c\u4f46\u662f\u4ef7\u683c\u66f4\u4f4e\u5ec9\u7684\u94f6\u6750\u6599\u5e26\u7ed9\u4eba\u4eec\u4e00\u4e2a\u66f4\u5b9e\u9645\u7684\u9014\u5f84\u6765\u5927\u89c4\u6a21\u5730\u8fd8\u539fCO<sub>2<\/sub>\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201604654\/full\" target=\"_blank\">Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts<\/a><\/strong><\/p>\n<p><strong>3.Angew. Chem. Int. Ed.:<\/strong> <strong>\u57fa\u4e8e<\/strong><strong>MOFs<\/strong><strong>\u5f62\u6210\u591a\u5b54\u78f7\u5316\u94bc\u7684\u9ad8\u6548\u4ea7\u6c22<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31275 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig3.png\" alt=\"fig3\" width=\"600\" height=\"451\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig3-300x226.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><br \/>\n<strong>\u56fe3. a) \u516d\u79cd\u7535\u50ac\u5316\u5242\u7684\u6781\u5316\u66f2\u7ebf; b) \u7531\u6781\u5316\u66f2\u7ebf\u8ba1\u7b97\u7684\u5854\u83f2\u5c14\u56fe; \u00a0c) \u4e09\u79cd\u7535\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31; (RS\uff1a\u7535\u89e3\u8d28\uff0cRCT\uff1a\u7535\u8377\u8f6c\u79fb\u7535\u963b) d) MoP@PC\u548cMo2C@PC\u7684\u8010\u4e45\u6027\u56fe.<\/strong><\/p>\n<p>\u73b0\u4eca\uff0c\u5316\u77f3\u80fd\u6e90\u7684\u5feb\u901f\u6d88\u8d39\u5bfc\u81f4\u4e86\u5168\u7403\u53d8\u6696\u548c\u96fe\u973e\u7b49\u73af\u5883\u95ee\u9898\u3002\u5bfb\u627e\u53ef\u53d6\u4ee3\u5316\u77f3\u80fd\u6e90\u7684\u6e05\u6d01\u80fd\u6e90\u548c\u53ef\u518d\u751f\u80fd\u6e90\u662f\u5f53\u52a1\u4e4b\u6025\u3002\u7531\u7535\u89e3\u6c34\u5236\u6c22\u4ea7\u751f\u7684\u6c22\uff08H<sub>2<\/sub>\uff09\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u7684\u53ef\u518d\u751f\u80fd\u6e90\u548c\u6e05\u6d01\u80fd\u6e90\uff0c\u5177\u6709\u5f88\u5927\u7684\u4f18\u52bf\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5148\u8fdb\u7eb3\u7c73\u50ac\u5316\u5242\u4e2d\u5fc3\u7684\u5434\u5b87\u6069\u6559\u6388\u548c\u6e05\u534e\u5927\u5b66\u5316\u5b66\u7cfb\u7684\u674e\u4e9a\u680b\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09\u62a5\u9053\u4e86\u4e00\u7cfb\u5217\u591a\u5b54\u7eb3\u7c73\u7ed3\u6784\u78b3\u50ac\u5316\u5242\uff0c\u7531\u78b3\u50ac\u5316\u5242\u4e0e\u94bc\u57fa\u590d\u5408\u6750\u6599\uff08\u5982Mo<sub>2<\/sub>C\uff0cMoN\u548cMoP\uff09\u5229\u7528MOFs\u8f85\u52a9\u7b56\u7565\u5f62\u6210\u6742\u5316\u7ed3\u6784\u3002\u8fd9\u4e9b\u94bc\u57fa\u590d\u5408\u6750\u6599\u57280.5 M\u786b\u9178\u6eb6\u6db2\u4e2d\uff0cMoP@\u591a\u5b54\u78b3\uff08MoP@PC\uff09\u5bf9\u6790\u6c22\u53cd\u5e94\u5177\u6709\u975e\u5e38\u597d\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u9879\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u7cfb\u5217\u7684\u591a\u529f\u80fd\u7c92\u5b50\u50ac\u5316\u5242\uff0c\u8fd9\u79cd\u7ed3\u6784\u8ba9\u4eba\u4eec\u5bf9\u80fd\u91cf\u8f6c\u6362\u548c\u71c3\u6599\u7535\u6c60\u50ac\u5316\u6709\u66f4\u6df1\u5165\u7684\u4e86\u89e3\u3002<\/p>\n<p>\u8fd9\u9879\u7814\u7a76\u8868\u660eMOFs\u57fa\u590d\u5408\u6750\u6599\u5728\u7535\u50ac\u5316\u5e94\u7528\u65b9\u9762\u5177\u6709\u5f88\u4e50\u89c2\u7684\u53d1\u5c55\u524d\u666f\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201604315\/abstract\" target=\"_blank\">Porous Molybdenum Phosphide Nano-Octahedrons Derived from Confined Phosphorization in UIO-66 for Efficient Hydrogen Evolution<\/a><\/strong><\/p>\n<p><strong>\u00a04.<\/strong><strong style=\"line-height: 1.5;\">Angew. Chem. Int. Ed.: <\/strong><strong style=\"line-height: 1.5;\">\u94c1\u9508\u505a\u7535\u6781\u50ac\u5316\u6790\u6c22\u53cd\u5e94<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31276 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig4.png\" alt=\"fig4\" width=\"600\" height=\"392\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig4-300x196.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><br \/>\n\u56fe4. \u53d8\u5e9f\u4e3a\u5b9d\uff0c\u5728\u7535\u89e3\u6db2\u4e2d\u901a\u8fc7\u7535\u5316\u5b66\u6c27\u5316\u8fd8\u539f\u5faa\u73af\u56de\u6536\u751f\u9508\u7684\u4e0d\u9508\u94a2\u7528\u4f5c\u4f4e\u6210\u672c\u3001\u9ad8\u6548\u3001\u72ec\u7acb\u7684\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u7535\u6781\u3002<\/strong><\/p>\n<p>\u7535\u89e3\u6c34\u4f5c\u4e3a\u662f\u4e00\u79cd\u89e3\u51b3\u65e5\u76ca\u589e\u957f\u7684\u80fd\u6e90\u5371\u673a\u548c\u73af\u5883\u6c61\u67d3\u95ee\u9898\u5f88\u6709\u524d\u9014\u7684\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u5176\u6574\u4f53\u6548\u7387\u5374\u88ab\u52a8\u529b\u5b66\u4e0a\u7f13\u6162\u7684\u6790\u6c22\u53cd\u5e94\u4e25\u91cd\u963b\u788d\u3002\u76ee\u524d\uff0c\u6700\u5148\u8fdb\u7684OER\u7535\u50ac\u5316\u5242\u662fRuO<sub>2<\/sub>\u548cIrO<sub>2<\/sub>\uff0c\u4f46\u5b83\u4eec\u5f88\u7a00\u7f3a\u4e14\u6210\u672c\u5f88\u9ad8\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240\u7a00\u571f\u8d44\u6e90\u5229\u7528\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5f20\u65b0\u6ce2\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u63d0\u51fa\u7528\u751f\u9508\u7684\u4e0d\u9508\u94a2\u677f\u4f5c\u4e3aOER\u50ac\u5316\u5242\uff0c\u5229\u7528\u6c34\u70ed\u6cd5\u7ed3\u5408\u539f\u4f4d\u7535\u5316\u5b66\u6c27\u5316\u8fd8\u539f\u5faa\u73af\uff08EORC\uff09\u7684\u65b9\u6cd5\u6a21\u62df\u548c\u52a0\u901f\u8150\u8680\u8fc7\u7a0b\uff0c\u4ece\u800c\u6fc0\u6d3b\u4e0d\u9508\u94a2\u6210\u4e3aOER\u7535\u6781\u3002\u8be5\u7535\u6781\u6709\u7740\u8f83\u597d\u7684\u7684OER\u6027\u80fd\u3002\u5728\u957f\u671f\u4f7f\u7528\u540e\uff0c\u7535\u6d41\u7684\u8f7b\u5fae\u9000\u5316\u53ef\u4ee5\u901a\u8fc7\u7535\u5316\u5b66\u6c27\u5316\u8fd8\u539f\u5faa\u73af\u7acb\u5373\u539f\u4f4d\u4fee\u590d\u3002<\/p>\n<p>\u8be5\u65b9\u6cd5\u80fd\u6709\u6548\u5730\u628a\u751f\u9508\u7684\u4e0d\u9508\u94a2\u53d8\u4e3a\u7a33\u5b9a\u3001\u4f4e\u6210\u672c\u548c\u72ec\u7acb\u7684OER\u7535\u6781\u3002\u5c06\u4e3a\u56de\u6536\u751f\u9508\u7684\u4e0d\u9508\u94a2\u8f6c\u5411\u65b0\u7684\u589e\u503c\u5e94\u7528\u6253\u5f00\u5d2d\u65b0\u7684\u9014\u5f84\uff0c\u5e76\u4e14\u5bf9\u5efa\u7acb\u4e00\u4e2a\u8d44\u6e90\u53ef\u6301\u7eed\u548c\u73af\u5883\u53cb\u597d\u578b\u793e\u4f1a\u6709\u5f88\u5927\u7684\u610f\u4e49\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/ange.201604040\/full\" target=\"_blank\">In Situ Activating Ubiquitous Rust towards Low-Cost, Efficient, Free-Standing, and Recoverable Oxygen Evolution Electrodes<\/a><\/strong><\/p>\n<p><strong>\u00a05.<\/strong><strong>JACS<\/strong><strong>\uff1a\u5438\u9644\u5728\u94c2\u8868\u9762\u7684\u6c27\u5316\u7269\u7684\u8fc1\u79fb\u7387\u548c\u53cd\u5e94\u6d3b\u6027<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31278 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig6.png\" alt=\"fig6\" width=\"600\" height=\"439\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig6-300x220.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n\u56fe5. \u94c2\u8868\u9762\u7684\u8868\u9762\u5438\u9644\u3001\u8fc1\u79fb\u548c\u89e3\u5438\u793a\u610f\u56fe. a) \u5438\u9644\u7684\u6c27\u5316\u7269\u662f\u5728\u94c2\u6216\u7535\u89e3\u8d28\u7684\u754c\u9762\u5904\u7684\u6c34\u89e3\u79bb\u5438\u9644\u5e76\u6cbf\u76f8\u90bb\u94c2\u8868\u9762\u7684\u6269\u6563\u5f62\u6210\u7684. b)\u662f a)\u7684\u5c55\u5f00\u56fe\uff0c\u663e\u793a\u51fa\u8868\u9762\u6d41\u52a8\u7684\u9a71\u52a8\u529b\u5b9e\u9645\u4e0a\u662f\u8868\u9762\u5438\u9644\u6c27\u5316\u7269\u7684\u6d53\u5ea6\u68af\u5ea6.<\/strong><\/p>\n<p>\u5728\u94c2\u8868\u9762\u5438\u9644\u7684\u6c27\u5316\u7269\u5bf9\u8868\u9762\u5438\u9644CO\u7684\u6c27\u5316\u662f\u81f3\u5173\u91cd\u8981\u7684\uff0c\u8fd9\u4f1a\u4f7f\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u94c2\u50ac\u5316\u5242\u5931\u6d3b\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u53a6\u95e8\u5927\u5b66\u56fa\u4f53\u8868\u9762\u7269\u7406\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u8a79\u4e1c\u5e73\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u901a\u8fc7\u91c7\u7528\u7eb3\u7c73\u7535\u6781\u548c\u5fae\u7535\u6781\u6280\u672f\uff0c\u89c2\u5bdfPt\u8868\u9762\u7531H<sub>2<\/sub>O\u89e3\u79bb\u5438\u9644\u4ea7\u751f\u7684\u6c27\u5438\u9644\u6001\u7684\u8868\u9762\u6d41\u52a8\u548c\u5438\u9644\u7684\u6c27\u5316\u7269\u4e0e\u5438\u9644\u7684CO\u7684\u8868\u9762\u53cd\u5e94\u3002\u5728CO\u8868\u9762\u6c27\u5316\u8fc7\u7a0b\u4e2d\uff0c\u5f97\u5230\u4e24\u4e2a\u7535\u6d41\u5cf0\uff0c\u8fd9\u5206\u522b\u5f52\u56e0\u4e8ePt \/\u7535\u89e3\u8d28\u754c\u9762\u7684CO\u6c27\u5316\u548c\u76f8\u90bbPt\u8868\u9762\u4e0a\u7684\u5438\u9644\u6c27\u5316\u7269\u7684\u8868\u9762\u6d41\u52a8\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u5438\u9644\u6c27\u5316\u7269\u7684\u8868\u9762\u8fc1\u79fb\u7387\u5728Pt\u50ac\u5316\u5242\u7684\u6bd2\u5316\u548c\u518d\u751f\u4e2d\u8d77\u7740\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n<p>\u5df2\u7ecf\u8bc1\u660e\uff0c\u901a\u8fc7\u5229\u7528\u7eb3\u7c73\u7535\u6781\u6216\u8d85\u5fae\u7535\u6781\u6280\u672f\u53ef\u89c2\u6d4b\u5230Pt\u4e0a\u7684\u5438\u9644\u6c27\u5316\u7269\u4e0eCO\u7684\u8868\u9762\u53cd\u5e94\uff0c\u4e3a\u4e86\u89e3\u8868\u9762\u53cd\u5e94\u7684\u50ac\u5316\u673a\u7406\u63d0\u4f9b\u4e86\u6709\u4ef7\u503c\u7684\u4fe1\u606f\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><strong><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b05259\" target=\"_blank\">Mobility and Reactivity of Oxygen Adspecies on Platinum Surface<\/a><\/strong><\/p>\n<p><strong style=\"line-height: 1.5;\">6.JACS<\/strong><strong style=\"line-height: 1.5;\">\uff1a\u7535\u50ac\u5316\u6790\u6c22\u548c\u9ad8\u7a33\u5b9a\u6027\u5206\u5b50\u50ac\u5316\u5242\u7684\u673a\u7406\u7814\u7a76<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31277 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig5.jpeg\" alt=\"fig5\" width=\"600\" height=\"321\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig5.jpeg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig5-300x161.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6. \u6790\u6c22\u50ac\u5316\u5faa\u73af\u7684\u63d0\u51fa. \u50ac\u5316\u5faa\u73af\u4e2dE<sub>PC<\/sub>(\u4e0eFe(C<sub>5<\/sub>H<sub>5<\/sub>)<sub>2<\/sub><sup>0\/+<\/sup>\u76f8\u6bd4)\u662f\u5728\u4e59\u8148\u4e2d\u6d4b\u5f97, pKa\u662f\u5728DMSO\u4e2d\u6d4b\u5f97.<\/strong><\/p>\n<p>\u6700\u8fd1\uff0c\u7f8e\u56fd\u52a0\u5229\u798f\u5c3c\u4e9a\u5927\u5b66\u5316\u5b66\u7cfbJenny Y. Yang\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u5f00\u53d1\u51fa\u4e00\u79cd\u6c34\u6eb6\u6027\u954d\u914d\u5408\u7269 [Ni(DHMPE)<sub>2<\/sub>]<sup>2+<\/sup>\u7528\u5728pH\u503c\u4e3a1\u7684\u7535\u50ac\u5316\u6790\u6c22\u53cd\u5e94\u4e2d\uff0c\u6709\u7740\u9ad8\u8fbe10<sup>3 <\/sup>s<sup>-1<\/sup>\u7684\u6cd5\u62c9\u7b2c\u7535\u6d41\u6548\u7387\u3002\u8be5\u7814\u7a76\u63d0\u51fa\u4e86\u901a\u8fc7\u7ec4\u5408\u8fd8\u539f\u4e24\u7535\u5b50\u7684\u4e8c\u4ef7\u954d\uff0c\u8d28\u5b50\u5316\u751f\u6210[HNi(DHMPE)<sub>2<\/sub>]<sup>+<\/sup>\uff0c\u5e76\u8fdb\u4e00\u6b65\u8d28\u5b50\u5316\u53c2\u4e0e\u6c22\u952e\u7684\u5f62\u6210\u673a\u7406\u3002<\/p>\n<p>\u672c\u6587\u62a5\u9053\u7684\u9ad8\u6548\u50ac\u5316\u5242\u53ef\u7528\u4e8e\u592a\u9633\u80fd\u71c3\u6599\uff0c\u4e14\u5176\u6c22\u952e\u5f62\u6210\u673a\u7406\u7684\u7814\u7a76\u6709\u52a9\u4e8e\u8fdb\u4e00\u6b65\u8bbe\u8ba1\u51fa\u65b0\u7684\u9ad8\u6d3b\u6027\u7684\u50ac\u5316\u5242\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b05851\" target=\"_blank\">Electrocatalytic Hydrogen Evolution under Acidic Aqueous Conditions and Mechanistic Studies of a Highly Stable Molecular Catalyst<\/a><\/strong><\/p>\n<p><strong>7.Adv. Funct. Mater.<\/strong><strong>: <\/strong><strong>\u8f7d\u6709<\/strong><strong>\u786b\u5316\u94bc\u7684\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u7ba1\u4e0a\u7684\u7a33\u5b9a\u8fb9\u7f18\u6d3b\u6027\u4f4d\u70b9<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31279 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig7.png\" alt=\"fig7\" width=\"600\" height=\"468\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/fig7-300x234.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><strong><br \/>\n<\/strong><strong>\u56fe<\/strong><strong>7. a)<\/strong><strong>\u7531\u4e8e<\/strong><strong>S<\/strong><strong>\u539f\u5b50\uff08\u5708\u8d77\u6765\u7684\uff09\u7684\u5b58\u5728\uff0c<\/strong><strong>MoS<sub>2<\/sub><\/strong><strong>\u7684\u9876\u90e8\u548c\u8fb9\u7f18\u7edf\u4e00\u949d\u5316\uff1b<\/strong><strong>b<\/strong><strong>\uff09<\/strong><strong>MoS<sub>2<\/sub><\/strong><strong>\u7c07\u5782\u76f4\u5438\u9644\u5230<\/strong><strong>N-CS<\/strong><strong>\u7684\u6676\u80de\u4fef\u89c6\u56fe\uff1b<\/strong><strong>c) MoS<sub>2<\/sub><\/strong><strong>\u7c07\u5782\u76f4\u5438\u9644\u5230<\/strong><strong>N-CS<\/strong><strong>\u7684\u4fa7\u89c6\u56fe\uff0c\u7bad\u5934\u8868\u793a\u7528\u4f5c\u8ba1\u7b97\u25b3<\/strong><strong>E<sub>H.<\/sub><\/strong><strong>\u7684<\/strong><strong>H<\/strong><strong>\u5438\u9644\u70b9\uff1b<\/strong><strong>d)<\/strong><strong>\u4e0d\u540c\u50ac\u5316\u5242\u76f8\u5e94\u7684\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\u4e0e\u25b3<\/strong><strong>G<sub>H<\/sub><\/strong><strong>\u7684\u5173\u7cfb\uff0c\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\u6765\u81ea<\/strong>Norskov\u7b49.<\/p>\n<p>\u6c22\u6c14\u53ef\u7531\u6c34\u7535\u89e3\u53cd\u5e94\u4ea7\u751f\uff0c\u6c34\u7535\u89e3\u8fc7\u7a0b\u4e2d\u4f7f\u7528\u78b1\u6027\u6216\u9178\u6027\u7535\u89e3\u8d28\u4f5c\u4e3a\u5bfc\u7535\u4ecb\u8d28\u3002\u76ee\u524d\uff0c\u9178\u6027\u7535\u89e3\u8d28\u4e2d\u6700\u4f73\u7535\u50ac\u5316\u5242\u662f\u975e\u5e38\u7a00\u7f3a\u7684\u8d35\u91d1\u5c5e\u5982\u94c2\u53ca\u5176\u590d\u5408\u6750\u6599\uff0c\u5176\u8868\u73b0\u51fa\u975e\u5e38\u4f4e\u7684\u8fc7\u7535\u4f4d\u548c\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u745e\u5178\u4e8e\u9ed8\u5965\u5927\u5b66\u7269\u7406\u7cfbThomas W\u00e5gberg\u6559\u6388\u548cEduardo Gracia-Espino\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\uff09\u62a5\u9053\u4e86\u4e00\u8868\u9762\u79ef\u975e\u5e38\u5927\u7684\u6742\u5316\u50ac\u5316\u5242\uff0c\u5176\u7535\u6781\u662f\u7531\u534a\u7ed3\u6676\u7684\u786b\u5316\u94bc\u50ac\u5316\u5242\uff08MoS<sub>2+x<\/sub>\uff09\u8d1f\u8f7d\u5230\u6c2e\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u7ba1\uff08N-CNTs\uff09\u7ec4\u6210\u7684\u3002\u63ba\u6742\u6c2e\u4f7f\u5f97\u5177\u6709\u534a\u7ed3\u6676\u7ed3\u6784\u7684MoS<sub>2+x<\/sub>\u7684\u8d1f\u8f7d\u66f4\u52a0\u7262\u56fa\uff0c\u540c\u65f6\u4e5f\u80fd\u66b4\u9732\u51fa\u66f4\u591a\u53c2\u4e0eHER\u53cd\u5e94\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u4e14\u6742\u5316\u50ac\u5316\u5242\u7684\u8fde\u63a5\u6210\u5206\u53ef\u4fc3\u8fdb\u7535\u5b50\u4f20\u9012\u3002<\/p>\n<p>\u8be5\u7814\u7a76\u6210\u679c\u53d1\u73b0\u7684\u9ad8\u6027\u4ef7\u6bd4\u7535\u50ac\u5316\u5242\uff0c\u5bf9\u4e8e\u7535\u89e3\u6c34\u4ea7\u6c22\u6709\u5f88\u5927\u7684\u6307\u5bfc\u4f5c\u7528\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a 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