{"id":31263,"date":"2016-08-12T14:00:26","date_gmt":"2016-08-12T06:00:26","guid":{"rendered":"\/\/m.iemloyee.com\/?p=31263"},"modified":"2016-08-12T13:05:02","modified_gmt":"2016-08-12T05:05:02","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81-amjacsangew%e7%ad%89%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6mof%e6%9d%90%e6%96%99%e6%9c%80%e6%96%b0%e7%a0%94%e7%a9%b6%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=31263","title":{"rendered":"\u9876\u520a\u52a8\u6001 | AM\/JACS\/Angew\u7b49\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOF)\u6750\u6599\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u6c47\u603b\u3010\u7b2c7\u671f\u3011"},"content":{"rendered":"<p><strong>1\u3001Adv. Mater. \u7531\u542b\u7c7b\u535f\u5549\u91d1\u5c5e\u4e2d\u5fc3\u7684MOF\u884d\u751f\u51fa\u7684\u4ecb\u5b54\u78b3\u7eb3\u7c73\u7403\u7528\u4e8e\u764c\u7ec6\u80de\u7684\u9002\u5f62\u5149\u7ebf\u8bca\u7597<\/strong><\/p>\n<p>\u5317\u4eac\u5316\u5de5\u5927\u5b66\u5218\u60e0\u7389\uff08\u901a\u8baf\u4f5c\u8005\uff09\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u751f\u6001\u73af\u5883\u7814\u7a76\u4e2d\u5fc3\u5218\u601d\u91d1\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u4e2d\u56fd\u79d1\u5b66\u9662\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u5f20\u94c1\u9510\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u9996\u6b21\u5bf9\u542b\u6709\u7c7b\u535f\u5549\u91d1\u5c5e\u4e2d\u5fc3Zn\u7c07\u7684\u54aa\u5511\u6846\u67b6ZIF-8\u524d\u4f53\u8fdb\u884c\u4ecb\u5b54SiO2\u8868\u9762\u6d82\u8986\u548c\u9ad8\u6e29\u78b3\u5316\u5904\u7406\u5f97\u5230\u5305\u542b\u7c7b\u535f\u5549\u91d1\u5c5e\u4e2d\u5fc3\u7684\u4ecb\u5b54\u78b3\u7eb3\u7c73\u7403 (PMCS)\u3002PMCS\u5728\u5149\u7ebf\u7597\u6cd5\u4e2d\u4f5c\u4e3a\u7a33\u5b9a\u7684\u654f\u5316\u548c\u5149\u70ed\u5242\uff0c\u5e76\u4e14\u5728\u6ce2\u957f808\u7eb3\u7c73\u7684\u6fc0\u5149\u8f90\u7167\u4e0b\u8868\u73b0\u51fa\u826f\u597d\u7684\u7a33\u5b9a\u6027\u548c\u9ad8\u6548\u7684\u5149\u70ed\u8f6c\u6362\u7387\uff0c\u540c\u65f6\u53ef\u4ee5\u50cfICC\uff08\u4e00\u79cd\u5e38\u89c1\u7684\u8fd1\u7ea2\u5916\u67d3\u6599\/\u5149\u654f\u5242\uff09\u4ee5\u8f83\u9ad8\u7684\u91cf\u5b50\u4ea7\u7387\u63d0\u4f9b\u7c7b\u4f3c\u7684\u5355\u7ebf\u6001\u6c27\u3002\u6025\u6027\u6bd2\u7406\u5b9e\u9a8c\u8bc1\u5b9e\uff0c\u805a\u4e59\u4e8c\u9187\u5316PMCS\u5728\u4f53\u5185\u6216\u4f53\u5916\u90fd\u5177\u6709\u826f\u597d\u7684\u751f\u7269\u76f8\u5bb9\u6027\u3002PMCS\u5f15\u8d77\u80bf\u7624\u7ec6\u80de\u5728\u8fd1\u7ea2\u5916\u6fc0\u5149\u8f90\u7167\u4e0b\u574f\u6b7b\u6216\u51cb\u4ea1\u3002\u6b64\u5916\uff0cPMCS\u5728\u79fb\u690d\u809d\u764c\u7ec6\u80de\u7684\u5c0f\u9f20\u4f53\u5185\u8868\u73b0\u51faIR\u548cPA\u4f18\u826f\u7684\u6027\u80fd\u5bf9\u6bd4\uff0c\u8fd9\u6837\u53ef\u4ee5\u5b9e\u73b0\u6cbb\u7597\u8fc7\u7a0b\u4e2d\u5b9e\u65f6\u76d1\u63a7\u5e76\u6709\u56fe\u50cf\u5f15\u5bfc\u7cbe\u786e\u9002\u5f62\u6cbb\u7597\u3002\u6700\u91cd\u8981\u7684\u662f\uff0c\u5728\u6ce2\u957f808\u7eb3\u7c73\u7684\u6fc0\u5149\u4e0b\uff0cPTT \/ PDT\u534f\u540c\u4f5c\u7528\u4e0b\u7684\u6cbb\u7597\u4f1a\u4f7f\u5f97\u79fb\u690d\u80bf\u7624\u7684\u88f8\u9f20\u4e2d\u80bf\u7624\u7ec6\u80de\u5b8c\u5168\u9000\u5316\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5305\u542b\u7c7b\u535f\u5549\u91d1\u5c5e\u4e2d\u5fc3\u7684\u4ecb\u5b54\u78b3\u7eb3\u7c73\u7403\u5728\u672a\u6765\u764c\u75c7\u6cbb\u7597\u4e2d\u53ef\u4ee5\u53d1\u6325\u91cd\u8981\u7684\u89d2\u8272\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-33152\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72471-11.png\" alt=\"\u56fe\u72471\" width=\"521\" height=\"351\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72471-11.png 521w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72471-11-300x202.png 300w\" sizes=\"(max-width: 521px) 100vw, 521px\" \/><strong><br \/>\n\u56fe1<\/strong> PMCS\u7684\u5236\u5907\u6d41\u7a0b\u548cHepG2\u7ec6\u80de\u5728\u4e0d\u540c\u6d53\u5ea6\u7684PMCS\u4e0b\u5b75\u5316\u53ca\u5728\u4e0d\u540c\u6e29\u5ea6\u3001808nm\u6fc0\u5149\u7167\u5c04\u4e0e\u5426\u7684\u73af\u5883\u4e0b\u7684\u6d3b\u6027<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.201602197\/full\" target=\"_blank\">Metal\u2013Organic-Framework-Derived Mesoporous CarbonNanospheres Containing Porphyrin-Like Metal Centers for Conformal\u00a0Phototherapy <\/a>(Adv. Mater., \u00a02016, DOI: 10.1002\/adma.20160219)<\/p>\n<p><strong>2\u3001Angew. Chem. Int. Ed. \u00a0\u6c22\u952e\u6709\u673a\u6846\u67b6(HOFs)\uff1a\u4e00\u4e2a\u65b0\u578b\u591a\u5b54\u6676\u4f53\u8d28\u5b50\u4f20\u5bfc\u6750\u6599<\/strong><\/p>\n<p>\u5370\u5ea6Sujit K. Ghosh\u7814\u7a76\u7ec4\u62a5\u9053\u4e86\u4e24\u4f8b\u57fa\u4e8e\u82b3\u70c3\u78fa\u9178\u76d0\u548c\u80cd\u76d0\u79bb\u5b50\u76842D HOF(Hydrogen-bonded Organic Frameworks)\u591a\u5b54\u6676\u4f53\u6750\u6599\u3002\u8fd9\u79cd\u6750\u6599\u5728\u8f83\u9ad8\u6e7f\u5ea6\u4e0b\u8868\u73b0\u51fa\u5f88\u9ad8\u7684\u8d28\u5b50\u4f20\u5bfc\u7387\uff1a 0.75\u00d7 10-2 Scm-1 \u548c 1.8 \u00d710-2 Scm-1 \u3002\u5e76\u4e14\u5728\u5ba4\u6e29\u4f4e\u6e7f\u5ea6\u73af\u5883\u4e0b\uff0c\u76f8\u5bf9\u4e8e\u5176\u5b83\u591a\u5b54\u6676\u578b\u6750\u6599\u8bf8\u5982MOFs\u548cCOFs\u8868\u73b0\u51fa\u975e\u5e38\u4f4e\u7684\u6d3b\u5316\u80fd\u548c\u6700\u9ad8\u7684\u8d28\u5b50\u4f20\u5bfc\u7387\u3002\u8fd9\u4e2a\u91cf\u7ea7\u4e0d\u4ec5\u582a\u6bd4\u4f20\u7edf\u7684\u8d28 \u5b50\u4ea4\u6362\u819c\u8bf8\u5982\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u5168\u6c1f\u78fa\u9178\u800c\u4e14\u4e5f\u662f\u5728\u6709\u673a\u591a\u5b54\u6846\u67b6\u4e2d\u7684\u6700\u9ad8\u503c\u3002\u8be5\u62a5\u9053\u4e3aHOF\u7528\u4e8e\u56fa\u6001\u8d28\u5b50\u4ea4\u6362\u819c\u5f00\u8f9f\u4e86\u4e00\u6761\u9053\u8def\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-33142\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72472-9.jpg\" alt=\"\u56fe\u72472\" width=\"600\" height=\"311\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72472-9.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72472-9-300x156.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n<strong>\u56fe2<\/strong> 2D\u6750\u6599 HOF-GS-10 \u548c HOF-GS-11 \u4e2d\u82b3\u70c3\u78fa\u9178\u76d0\u548c\u80cd\u76d0\u79bb\u5b50\u4e4b\u95f4\u8868\u73b0\u51fa\u5f3a\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201604534\/full\" target=\"_blank\">Hydrogen-Bonded Organic Frameworks (HOFs): A New Class of\u00a0Porous Crystalline Proton-Conducting Materials <\/a>(Angew. Chem. Int. Ed., 2016, DOI: 10.1002\/anie.201604534)<\/p>\n<p><strong>3\u3001J. Am. Chem. Soc.\u00a0MOF\u56fa\u5316\u81a6\u57fa\u91d1\u5c5e\u5316\u5408\u7269\u7528\u4e8e\u5927\u8303\u56f4\u50ac\u5316\u53cd\u5e94<\/strong><\/p>\n<p>\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658c\u7814\u7a76\u7ec4\u9996\u6b21\u62a5\u9053\u4e86\u57fa\u4e8e\u4e09\u82b3\u57fa\u81a6\u7684\u591a\u5b54Zr-MOF\u53ca\u901a\u8fc7\u540e\u5408\u6210\u4e0eRh\u548cIr\u91d1\u5c5e\u5316\u5f97\u5230\u56fa\u5316M-PR3\u7684MOF\u50ac\u5316\u5242\u3002\u8be5\u50ac\u5316\u5242\u5728\u916e\u548c\u70ef\u7684\u7845\u6c22\u5316\u53cd\u5e94\uff0c\u70ef\u70c3\u7684\u6c22\u5316\u53cd\u5e94\uff0c\u82b3\u70c3\u7684\u6d3b\u5316\u787c\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u826f\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u79cd\u53ef\u91cd\u590d\u4f7f\u7528\u7684MOF\u50ac\u5316\u5242\u4f18\u4e8e\u5bf9\u5e94\u7684\u5747\u76f8\u50ac\u5316\u524d\u4f53\uff0c\u5927\u6982\u662f\u7531\u4e8e\u5728\u50ac\u5316\u5faa\u73af\u4e2d\u56fa\u5316\u7684M-PR3 \u963b\u6b62\u4e86\u6b67\u5316\u5f15\u8d77\u7684\u50ac\u5316\u5242\u4e2d\u6bd2\u548c\u914d\u4f53\u4ea4\u6362\u3002\u8be5\u7814\u7a76\u7ec4\u76f8\u4fe1\u5728MOF\u7684\u50ac\u5316\u5faa\u73af\u4e2d\u4fdd\u6301\u81a6\u57fa\u914d\u4f4d\u80fd\u529b\u4e3a\u8bbe\u8ba1\u5176\u5b83\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u79cd\u601d\u8def\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-33144\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72473-9.jpg\" alt=\"\u56fe\u72473\" width=\"471\" height=\"140\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72473-9.jpg 471w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72473-9-300x89.jpg 300w\" sizes=\"(max-width: 471px) 100vw, 471px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u00a0\u56fe3 \u00a0\u00a0<\/strong>\u00a0H<sub>3<\/sub>L\u548c P1-MOF\u7684\u5408\u6210<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b06239\" target=\"_blank\">Metal-Organic Frameworks Stabilize Mono(phosphine)-Metal\u00a0Complexes for Broad-Scope Catalytic Reactions <\/a>(J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b06239)<\/p>\n<p><strong>4\u3001J. Am. Chem. Soc. \u673a\u68b0\u538b\u5236\u6210\u5f62\u7684\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6(COF)\u8868\u73b0\u51fa\u6676\u4f53\u6392\u5e8f\u548c\u9ad8\u6548\u7684\u9502\u79bb\u5b50\u5bfc\u7535\u7387<\/strong><\/p>\n<p>\u7f8e\u56fd\u4e2d\u4f5b\u7f57\u91cc\u8fbe\u5927\u5b66Fernando J. Uribe-Romo\u7814\u7a76\u7ec4\u5c062D COF\u7c89\u672b\u673a\u68b0\u538b\u5236\u6210\u82af\u7247\u7528\u4e8e\u56fa\u6001\u7535\u6781\u7684\u5668\u4ef6\u6784\u5efa\uff0c\u82af\u7247\u91c7\u53d6\u5404\u5411\u5f02\u6027\u5e76\u62e9\u4f18\u91c7\u53d6hk0\u548c00l\u4e4b\u95f4\u7684\u6676\u9762\u6392\u5e03\u3002\u8fd9\u79cd\u6676\u4f53\u6392\u5e8f\u9002\u7528\u4e8e\u4e0d\u540c\u529f\u80fd\u5206\u5b50\u548c\u6676\u4f53\u5b66\u5bf9\u79f0\u76842D COF\u3002\u5e76\u4e14\u8fd9\u79cd\u6676\u5e8f\u805a\u5408\u7269\u6750\u6599\u8868\u73b0\u51fa\u9ad8\u6548\u7684\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u7a33\u5b9a\u7684\u7535\u5316\u5b66\u6027\u8d28\u3002\u76ee\u524d\u8be5\u7814\u7a76\u7ec4\u5728Li+\u7684\u8fc1\u79fb\u6027\uff0c\u949d\u5316\u5c42\u7684\u5f62\u6210\u53ca\u6750\u6599\u7ec4\u88c5\u5230\u7535\u6c60\u4e2d\u7b49\u65b9\u9762\u6b63\u5728\u5f00\u5c55\u540e\u7eed\u7814\u7a76\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-33145\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72474-9.jpg\" alt=\"\u56fe\u72474\" width=\"538\" height=\"820\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72474-9.jpg 538w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72474-9-197x300.jpg 197w\" sizes=\"(max-width: 538px) 100vw, 538px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4 <\/strong>(a) COF-5 \u6676\u80de\u7684\u5806\u79ef\u56fe\u53cadhk0\u548cd00l\u6b63\u4ea4\u6676\u9762\u7684\u6cd5\u5411\u91cf(b, d)\u5e73\u884c\u5782\u76f4\u5149\u8f74\u7684COF-5\u82af\u7247 (c, e) \u5e73\u884c\u548c\u5782\u76f4\u7684\u4e0d\u540c\u8f74\u5411\u538b\u529b\u4e0bCOF-5\u7684PXRD\u56fe<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b05568\" target=\"_blank\">Mechanically Shaped Two-Dimensional Covalent Organic\u00a0Frameworks Reveal Crystallographic Alignment and Fast Li-Ion Conductivity<\/a>(J. Am. Chem. Soc. , 2016, DOI: 10.1021\/jacs.6b05568)<\/p>\n<p><strong>5\u3001J. Am. Chem. Soc. \u57fa\u4e8e\u5965\u6c99\u62c9\u55ea\u7684\u751f\u7269\u76f8\u5bb9\u6027MOF\u7528\u4e8eH2\u7684\u5438\u9644\u548c\u836f\u7269\u8f93\u9001<\/strong><\/p>\n<p>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Jeffrey R. Long\u7814\u7a76\u7ec4\u5408\u6210\u5e76\u8868\u5f81\u4e86\u4e00\u7cfb\u5217\u4ee5\u6297\u708e\u836f\u7269\u5965\u6c99\u62c9\u55ea\u9178\u505a\u4e3a\u6865\u8fde\u914d\u4f53\u7684MOF-74\u6750\u6599\uff0c\u5373M2(olz)\uff08M=Mg\uff0cFe\uff0cCo\uff0cNi\u548cZn\uff09\u3002\u8be5\u7cfb\u5217\u6750\u6599\u5177\u6709\u975e\u5e38\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u5e76\u4e14\u5b54\u5f84\u7ea6\u4e3a27\u00c5\u3002\u901a\u8fc7H2\u7684\u5438\u9644\u8bd5\u9a8c\u548c\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u8868\u5f81\u8bc1\u5b9e\u4e86\u8be5\u6846\u67b6\u542b\u6709\u5f00\u653e\u7684\u91d1\u5c5e\u4f4d\u70b9\u3002\u9664\u4e86\u5bf9H2\u7684\u663e\u8457\u7684\u5438\u9644\u80fd\u529b\u4e4b\u5916\uff0c\u5177\u5907\u751f\u7269\u6d3b\u6027\u7684Mg2(olz)\u6846\u67b6\u5728\u6a21\u62df\u751f\u7406\u6761\u4ef6\u4e0b\u53ef\u540c\u65f6\u5bf9\u5965\u6c99\u62c9\u55ea\u53ca\u5176\u5b83\u836f\u5242\uff08\u8bf8\u5982\u82ef\u4e59\u80fa\uff09\u4ee5\u4e0d\u540c\u901f\u7387\u91ca\u653e\u3002\u8fd9\u79cd\u4f4e\u6bd2\u6027\u3001\u9ad8\u6bd4\u8868\u9762\u79ef\u4e14\u5177\u6709\u914d\u4f4d\u4e0d\u9971\u548c\u7684\u91d1\u5c5e\u4e2d\u5fc3\u7684Mg2(olz)\u6750\u6599\u6709\u671b\u5728\u836f\u7269\u8f93\u9001\u548c\u80c3\u80a0\u9053\u75be\u75c5\u6cbb\u7597\u4e2d\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-33146\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72475-9.jpg\" alt=\"\u56fe\u72475\" width=\"600\" height=\"308\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72475-9.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72475-9-300x154.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5<\/strong>\u00a0 \u57fa\u4e8e\u5965\u6c99\u62c9\u55eaMOF\u7cfb\u5217\u7528\u4e8eH2\u7684\u5438\u9644\u548c\u5965\u6c99\u62c9\u55ea\u548c\u82ef\u4e59\u80fa\u7684\u8f93\u9001<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b03523\" target=\"_blank\">Olsalazine-Based Metal\u2212Organic Frameworks as Biocompatible Platforms for H2 Adsorption and Drug Delivery<\/a>(J. Am. Chem. Soc, 2016, DOI:10.1021\/jacs. 6b03523)<\/p>\n<p><strong>6\u3001J. Am. Chem. Soc. \u5c06MOF-5\u5b54\u7a74\u5206\u51fa\u6709\u9650\u7684\u758f\u6c34\u533a\u7528\u4e8e\u6f6e\u6e7f\u73af\u5883\u4e0b\u7684\u78b3\u6355\u83b7<\/strong><\/p>\n<p>MOF\u6750\u6599\u7531\u4e8e\u663e\u8457\u7684\u5438\u9644\u3001\u9009\u62e9\u3001\u53ef\u518d\u751f\u6027\u5728\u5316\u77f3\u71c3\u6599\u7684\u71c3\u70e7\u4e2d\u78b3\u6355\u83b7\u80fd\u529b\u6548\u679c\u60ca\u4eba\uff0c\u7136\u800c\u7531\u4e8e\u8be5\u7c7b\u6750\u6599\u7684\u5438\u6c34\u6027\u4f7f\u5f97\u5728\u6f6e\u6e7f\u73af\u5883\u4e0b\u5bf9\u78b3\u6355\u83b7\u7684\u80fd\u529b\u964d\u4f4e\u3002\u9274\u4e8e\u6b64\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u8bfe\u9898\u7ec4\u63d0\u51fa\u4e00\u79cd\u5728MOF\u96a7\u9053\u5185\u90e8\u539f\u4f4d\u805a\u5408\u82b3\u9999\u7094\u7684\u7b56\u7565\u5f97\u5230\u9650\u57df\u758f\u6c34\u533a\u3002\u4e0e\u539f\u59cbMOF-5\u76f8\u6bd4\uff0c\u901a\u8fc7\u81ea\u7531\u57fa\u805a\u5408\u53cd\u5e94\u5f97\u5230\u7684PN@MOF-5\u5bf9CO2\u7684\u5438\u9644\u80fd\u529b\u63d0\u5347\u4e86\u4e00\u500d\uff08\u5728 273 K \u548c 1 bar\u6761\u4ef6\u4e0b\uff0c78 vs. 38 cm3\/g \uff09\u4e14\u5bf9CO2\/N2\u7684\u9009\u62e9\u6027\u63d0\u5347\u4e8622\u500d\u3002\u5bf9CO2\u7684\u52a8\u529b\u5b66\u5438\u9644\u80fd\u529b\u5728\u5faa\u73af\u4f7f\u7528\u540e\u4ecd\u80fd\u4fdd\u630190%\u4ee5\u4e0a\uff0c\u5e76\u4e14\u8fd9\u79cd\u7b56\u7565\u53ef\u5e94\u7528\u4e8e\u5176\u5b83MOF\u6750\u6599\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-33149\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72476-6.jpg\" alt=\"\u56fe\u72476\" width=\"546\" height=\"628\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72476-6.jpg 546w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72476-6-261x300.jpg 261w\" sizes=\"(max-width: 546px) 100vw, 546px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6<\/strong> \u5728PN\u8868\u9762\u4e0aCO2\u548cH2O\u7684\u7ade\u4e89\u6027\u5438\u9644\uff1b(b) MOF\u96a7\u9053\u5185\u82b3\u9999\u7094\u7684\u81ea\u7531\u57fa\u805a\u5408<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b06051\" target=\"_blank\">Partitioning MOF-5 into confined and hydrophobic compartments for carbon capture under humid conditions<\/a>(J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b06051)<\/p>\n<p><strong>7\u3001J. Am. Chem. Soc.\u00a0\u57fa\u4e8e\u9633\u79bb\u5b50\u4ea4\u6362\u7684MOF\u53ef\u4f5c\u4e3a\u70ef\u70c3\u805a\u5408\u7684\u5355\u4e2d\u5fc3\u5f02\u76f8\u50ac\u5316\u5242<\/strong><\/p>\n<p>\u5355\u4e2d\u5fc3\u5f02\u76f8\u50ac\u5316\u5242\u7684\u53d1\u5c55\u4f7f\u5f97\u5148\u8fdb\u7684\u9ad8\u5206\u5b50\u805a\u5408\u7269\u70ef\u70c3\u7684\u5236\u5907\u6210\u4e3a\u53ef\u80fd\u3002\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u8fdb\u884c\u8bbe\u8ba1\u548c\u8c03\u63a7\u7684MOF\u4f5c\u4e3a\u5f02\u76f8\u50ac\u5316\u5242\u8868\u73b0\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002\u9ebb\u7701\u7406\u5de5\u5b66\u9662Mircea Dinc\u0103\u7814\u7a76\u7ec4\u901a\u8fc7MFU-4l [Zn5Cl4(BTDD)3]\u4e2d\u7684Zn\u79bb\u5b50\u4e0e\u6d3b\u6027\u91d1\u5c5e\u8fdb\u884c\u9633\u79bb\u5b50\u4ea4\u6362\u7528\u4e8e\u50ac\u5316\u70ef\u70c3\u805a\u5408\uff0c\u5e76\u901a\u8fc7\u626b\u63cf\u7535\u955c\u8868\u5f81\u50ac\u5316\u5f97\u5230\u7684\u805a\u4e59\u70ef\u8bf4\u660e\u9ad8\u805a\u7269\u7684\u5206\u5b50\u548c\u62d3\u6251\u7ed3\u6784\u53ef\u63a7\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-33150\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u724777-2.jpg\" alt=\"\u56fe\u724777\" width=\"600\" height=\"141\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u724777-2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u724777-2-300x71.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe7\u00a0<\/strong> \u626b\u63cf\u7535\u955c\u56fe\uff1a(A) Ti(III)-MFU-4l (B)\u7531Ti(III)-MFU-4l\u50ac\u5316\u5f97\u5230\u7684\u805a\u5408\u7269 (C) \u7531 Cr(III)-MFU-4l\u50ac\u5316\u5f97\u5230\u7684\u805a\u5408\u7269<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b05200\" target=\"_blank\">Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal Organic Framework<\/a> (J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b05200)<\/p>\n<p><strong>8\u3001J. Am. Chem. Soc. \u5177\u6709\u4e19\u70ef\u9178\u7c7b\u914d\u4f53\u7684MOFs\u8868\u73b0\u51fa\u9ad8\u6548\u7684\u7532\u70f7\u5438\u9644\u5bb9\u91cf<\/strong><\/p>\n<p>\u5728\u5929\u7136\u6c14\u4f9b\u80fd\u7684\u6c7d\u8f66\u8bbe\u8ba1\u548c\u5236\u9020\u65b9\u9762\uff0c\u7532\u70f7\u5728\u591a\u5b54\u6750\u6599\u7684\u9ad8\u6548\u50a8\u5907\u662f\u975e\u5e38\u91cd\u8981\u7684\u3002\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u7814\u7a76\u7ec4\u62a5\u9053\u4e86\u4e94\u4f8bMOFs (MOF-905\uff0cMOF-905-Me2\uff0cMOF-905-Naph\uff0cMOF-905-NO2\u548cMOF-950)\u7684\u5408\u6210\u3001\u5355\u6676\u7ed3\u6784\u548c\u7532\u70f7\u7684\u5438\u9644\u6027\u7814\u7a76\u3002\u8be5\u7cfb\u5217MOFs\u5747\u542b\u6709Zn4O(-CO2)6\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u548c\u82ef-1,3,5-\u4e09-\u03b2-\u4e19\u70ef\u9178\uff08H3BTAC\uff09\u3002\u7532\u70f7\u5438\u9644\u5b9e\u9a8c\u8868\u660eMOF-905\u572880 bar\u548c298 K\u4e0b\u5438\u9644\u91cf\u8fbe\u5230203 cm3\u00b7cm-3\uff0c\u5c45\u4e8e\u4e94\u4f8b\u6750\u6599\u5bf9\u7532\u70f7\u5438\u9644\u91cf\u7684\u9996\u4f4d\u3002\u540c\u65f6\u4e5f\u9ad8\u4e8eMOFs\u4e2d\u7532\u70f7\u5438\u9644\u7684\u57fa\u51c6\u5316\u5408\u7269HKUST-1 (200 cm3\u00b7cm-3)\u7684\u5438\u9644\u91cf\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-33151\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72478-4.jpg\" alt=\"\u56fe\u72478\" width=\"600\" height=\"212\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72478-4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/08\/\u56fe\u72478-4-300x106.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n<strong>\u56fe8<\/strong> MOF-905\u7684\u62d3\u6251\u7ed3\u6784\u53ca\u4e94\u4f8bMOFs\u5bf9\u7532\u70f7\u7684\u5438\u9644\u7b49\u6e29\u7ebf<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b05261\" target=\"_blank\">High Methane Storage Working Capacity in Metal-Organic Frameworks with Acrylate Links<\/a> (J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b05261)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u7f51\u8001\u742a\u742a\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09\uff01<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u4eba\u7f51\u5c0a\u91cd\u6240\u6709\u8fdb\u884c\u77e5\u8bc6\u4f20\u64ad\u7684\u5a92\u4f53\uff0c\u8f6c\u8f7d\u8bf7\u8054\u7cfbtougao@cailiaoren.com<\/p>\n","protected":false},"excerpt":{"rendered":"<p>1\u3001Adv. 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