{"id":30113,"date":"2016-08-28T18:00:47","date_gmt":"2016-08-28T10:00:47","guid":{"rendered":"\/\/m.iemloyee.com\/?p=30113"},"modified":"2016-08-28T20:08:27","modified_gmt":"2016-08-28T12:08:27","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7-%e6%89%93%e8%b5%8c%ef%bc%88bet%ef%bc%89%e8%a1%a8%e9%9d%a2%e5%88%86%e6%9e%90%ef%bc%8c%e4%bd%a0%e5%80%bc%e5%be%97%e6%8b%a5%e6%9c%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=30113","title":{"rendered":"\u5b66\u672f\u5e72\u8d27 | \u201c\u6253\u8d4c\u201d\uff08BET\uff09\u8868\u9762\u5206\u6790\uff0c\u4f60\u503c\u5f97\u62e5\u6709"},"content":{"rendered":"<p>\u6750\u6599\u8868\u9762\u901a\u5e38\u6027\u8d28\u7a81\u53d8\uff0c\u53cd\u5e94\u8fdb\u884c\u7684\u9996\u9009\u573a\u6240\uff0c\u56e0\u800c\u5728\u6750\u6599\u5b66\u7684\u7814\u7a76\u4e2d\u7edd\u5bf9\u4e0d\u5bb9\u5c0f\u89d1\u3002\u4e3a\u4e86\u8fdb\u884c\u7edf\u4e00\u6bd4\u8f83\uff0c\u901a\u5e38\u8981\u628a\u8868\u9762\u8fd9\u4e00\u5e7f\u5ea6\u91cf\u8f6c\u5316\u4e3a\u6bd4\u8868\u9762\u8fd9\u4e00\u5f3a\u5ea6\u91cf\u6765\u6bd4\u8f83\u3002\u7eb3\u7c73\u6750\u6599\u7092\u4e86\u5982\u6b64\u591a\u5e74\u4ecd\u7136\u662f\u5b66\u754c\u5ba0\u513f\uff0c\u5176\u533a\u522b\u4e0e\u5b8f\u89c2\u6750\u6599\u6700\u5927\u7684\u7279\u70b9\u4fbf\u662f\u5de8\u5927\u7684\u8868\u9762\u79ef\uff0c\u4e5f\u6b63\u662f\u8fd9\u4e00\u7279\u70b9\u4f7f\u5176\u53ef\u4ee5\u5728\u50ac\u5316\uff0c\u5438\u9644\uff0c\u5b58\u50a8\uff0c\u53cd\u5e94\u7b49\u5404\u5927\u7814\u7a76\u9886\u57df\u5927\u5c55\u62f3\u811a\u3002<\/p>\n<p>\u8c08\u5230\u79d1\u7814\u4fbf\u79bb\u4e0d\u5f00\u6d4b\u8bd5\uff0c\u4e0d\u5c11\u540c\u5b66\u4f1a\u9047\u5230\u6bd4\u8868\u9762\u79ef\u6d4b\u8bd5\u548c\u8868\u8ff0\u65b9\u9762\u7684\u95ee\u9898\uff0c\u5c24\u5176\u662f\u5728\u5199\u82f1\u6587\u8bba\u6587\u7684\u65f6\u5019\u3002\u4e3a\u6b64\uff0c\u6211\u4eec\u7279\u610f\u4e3a\u5927\u5bb6\u5f00\u4e00\u5242\u5927\u8865\u836f\u2014\u2014\u8bb2\u8bb2\u9876\u7ea7\u671f\u520a\u4e2dBET\u6bd4\u8868\u9762\u79ef\u5206\u6790\u6d4b\u8bd5\u6cd5\u7684\u63cf\u8ff0\u548c\u5e94\u7528\u3002<\/p>\n<p>I \u201cbet\u201d thses knowledge about BET is meaningful for you<\/p>\n<p><strong>1.\u4ec0\u4e48\u662f\u6bd4\u8868\u9762\u79ef\u6d4b\u8bd5\uff1f2.\u7ed3\u5408\u5438\u9644\u7b49\u6e29\u7ebf\u7684BET\u5206\u6790\uff1f3.\u6b6a\u679c\u4ec1\u7684BET\u4e16\u754c\u4f60\u8981\u61c2\u3002<\/strong><\/p>\n<p><strong>1.\u6bd4\u8868\u9762\u79ef\u6d4b\u8bd5\uff08BET\uff09<\/strong><\/p>\n<p>BET\u6d4b\u8bd5\u7406\u8bba\u662f\u6839\u636e\u5e0c\u6717\u8bfa\u5c14\u3001\u57c3\u7c73\u7279\u548c\u6cf0\u52d2\u4e09\u4eba\u63d0\u51fa\u7684\u591a\u5206\u5b50\u5c42\u5438\u9644\u6a21\u578b\uff0c\u5e76\u63a8\u5bfc\u51fa\u5355\u5c42\u5438\u9644\u91cfVm\u4e0e\u591a\u5c42\u5438\u9644\u91cfV\u95f4\u7684\u5173\u7cfb\u65b9\u7a0b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30115\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/1-32.png\" alt=\"1\" width=\"217\" height=\"73\" \/><\/p>\n<p>P: \u6c2e\u6c14\u5206\u538b<br \/>\nP0: \u5438\u9644\u6e29\u5ea6\u4e0b\uff0c\u6c2e\u6c14\u7684\u9971\u548c\u84b8\u6c7d\u538b<br \/>\nV: \u6837\u54c1\u8868\u9762\u6c2e\u6c14\u7684\u5b9e\u9645\u5438\u9644\u91cf<br \/>\nVm: \u6c2e\u6c14\u5355\u5c42\u9971\u548c\u5438\u9644\u91cf<br \/>\nC : \u4e0e\u6837\u54c1\u5438\u9644\u80fd\u529b\u76f8\u5173\u7684\u5e38\u6570<\/p>\n<p>\u64cd\u4f5c\u8fc7\u7a0b\u662f\u901a\u8fc7\u5b9e\u6d4b3-5\u7ec4\u88ab\u6d4b\u6837\u54c1\u5728\u4e0d\u540c\u6c2e\u6c14\u5206\u538b\u4e0b\u591a\u5c42\u5438\u9644\u91cf\uff0c\u4ee5P\/P0\u4e3aX\u8f74\uff0cP\/V\uff08P0-P\uff09\u4e3aY\u8f74\uff0c\u7531BET\u65b9\u7a0b\u505a\u56fe\u8fdb\u884c\u7ebf\u6027\u62df\u5408\uff0c\u5f97\u5230\u76f4\u7ebf\u7684\u659c\u7387\u548c\u622a\u8ddd\uff0c\u4ece\u800c\u6c42\u5f97Vm\u503c\u8ba1\u7b97\u51fa\u88ab\u6d4b\u6837\u54c1\u6bd4\u8868\u9762\u79ef\u3002<br \/>\n<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30116\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/QQ\u622a\u56fe20160731111953.png\" alt=\"QQ\u622a\u56fe20160731111953\" width=\"147\" height=\"54\" \/><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30117\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/QQ\u622a\u56fe20160731112008.png\" alt=\"QQ\u622a\u56fe20160731112008\" width=\"177\" height=\"46\" \/><\/p>\n<p><strong>2.\u7ed3\u5408\u5438\u9644\u7b49\u6e29\u7ebf\u7684BET\u5206\u6790<\/strong><\/p>\n<p>\u5982\u4e0a\u4e00\u5c0f\u8282\u4e2d\u63d0\u5230\u7684\uff0c\u505aBET\u5206\u6790\u4e4b\u524d\uff0c\u4e00\u5b9a\u8981\u5148\u505a\u6c2e\u6c14\u5438\u9644\u7b49\u6e29\u6d4b\u8bd5\uff0c\u7136\u540e\u6839\u636e\u83b7\u5f97\u7684\u538b\u5f3a\u4ee5\u53ca\u5438\u9644\u91cf\u7684\u6570\u636e\u7ed3\u5408BET\u516c\u5f0f\uff0c\u8fdb\u884c\u5206\u6790\u3002\u4e3a\u6b64\u4e86\u89e3\u57fa\u672c\u7684\u5438\u9644\u7b49\u6e29\u66f2\u7ebf\u662f\u6781\u5176\u5fc5\u8981\u7684\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30124\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/1-79.jpg\" alt=\"1\" width=\"679\" height=\"466\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/1-79.jpg 679w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/1-79-300x206.jpg 300w\" sizes=\"(max-width: 679px) 100vw, 679px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30118\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/\u8868.png\" alt=\"\u8868\" width=\"619\" height=\"405\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/\u8868.png 619w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/\u8868-300x196.png 300w\" sizes=\"(max-width: 619px) 100vw, 619px\" \/><\/p>\n<p>BET\u65b9\u6cd5\u4ec5\u9002\u7528\u4e8eP\/P0=0.05\u20140.35\u4e4b\u95f4\u7684\u4e5f\u5c31\u662f\u2161\u548c\u2163\u5438\u9644\u7b49\u6e29\u66f2\u7ebf<\/p>\n<p>3.\u6b6a\u679c\u4ec1\u7684\u4e16\u754c\u4f60\u8981\u61c2<\/p>\n<p>1. Nature Communication<\/p>\n<p>\u6b64\u6587\u63a2\u8ba8\u4e86\u4f7f\u7528\u4ecb\u5b54\u58c1\u81ea\u7ec4\u88c5\u5408\u6210\u7a7a\u5fc3\u7403\u5171\u4ef7\u6709\u673a\u6846\u67b6DhaTab\u7684\u65b9\u6cd5\u3002\u5408\u6210\u7684\u7a7a\u5fc3\u7403\u5177\u6709\u9ad8\u7684\u7a7a\u9699\u7387\uff0c\u800c\u4e14\u7531\u4e8e\u5206\u5b50\u95f4\u6c22\u952e\u7684\u4f5c\u7528\u5177\u6709\u826f\u597d\u7ed3\u6676\u7a0b\u5ea6\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u6709\u671b\u5e94\u7528\u4e8e\u751f\u7269\u5236\u836f\u7814\u7a76\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30119\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/2-27.png\" alt=\"2\" width=\"661\" height=\"261\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/2-27.png 661w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/2-27-300x118.png 300w\" sizes=\"(max-width: 661px) 100vw, 661px\" \/><br \/>\n\u56fe\uff08d\uff09\u4e3aDhaTab\u6c34\u6d17\u5904\u7406\u524d\u540e\u4ee5\u53ca\u9178\u5904\u7406\u524d\u540e\u7684N2\u5438\u9644\u7b49\u6e29\u7ebf\u5bf9\u6bd4\u56fe\u3002\u84dd\u8272\uff0c\u9999\u69df\u8272\u4ee5\u53ca\u7ea2\u8272\u5206\u522b\u4ee3\u8868\u5904\u7406\u524d\uff0c\u6c34\u6d17\u5904\u7406\u540e\u4ee5\u53ca\u9178\u5904\u7406\u540e\u7684\u6837\u54c1\u3002\uff08g\uff09\u56fe\u8bb0\u5f55\u7684\u5219\u662f\u4e0d\u540c\u5408\u6210\u65f6\u95f4\u6837\u54c1\u7684N2\u5438\u9644\u7b49\u6e29\u7ebf\u56fe\u3002<\/p>\n<p>\u6c2e\u6c14\u5438\u9644\u7b49\u6e29\u7684\u6d4b\u8bd5\u7528\u6765\u8bc4\u4f30\u6750\u6599\u7684\u5b54\u9699\u7387COF-DhaTab\u8868\u73b0\u51fa\u5178\u578b\u7684\u53ef\u9006\u5438\u9644\uff0c\u610f\u5473\u7740\u6750\u6599\u5185\u90e8\u4ee5\u4ecb\u5b54\u7ed3\u6784\u4e3a\u4e3b\u3002\u901a\u8fc7BET\u6a21\u578b\u8ba1\u7b97\u51fa\u6750\u6599\u7684\u6bd4\u8868\u9762\u79ef\u4e3a1,480m 2 g -1\uff0c\u5176\u5de8\u5927\u7684\u6bd4\u8868\u9762\u79ef\u6765\u6e90\u4e8e\u5f3a\u70c8\u7684\u5206\u5b50\u5185\u6c22\u952e\u7684\u4f5c\u7528\uff0c\u5728\u786e\u4fdd\u7ed3\u6784\u7a33\u5b9a\u7684\u540c\u65f6\u63d0\u5347\u4e862\u7ef4\u5c42\u7684\u5e73\u9762\u5316\u7a0b\u5ea6\uff0c\u8fd9\u4e9b\u90fd\u5c06\u5e2e\u52a9\u63d0\u5347COF\u7684\u7ed3\u6784\u6709\u5e8f\u6027\uff0c\u4ece\u800c\u589e\u5927\u6d3b\u6027\u8868\u9762\u79ef\u3002DhaBad\u7684\u8868\u9762\u79ef\u540c\u6837\u7531BET\u6a21\u578b\u8ba1\u7b97\u7684\u51fa\u5176\u5747\u503c\u5728447 m 2 g -1<br \/>\n<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30120\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/3-21.png\" alt=\"3\" width=\"363\" height=\"296\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/3-21.png 363w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/3-21-300x245.png 300w\" sizes=\"(max-width: 363px) 100vw, 363px\" \/><br \/>\n\u56fe\uff08d\uff09\u4e3aDhaTab\u5728\u80f0\u5c9b\u7d20\u586b\u5145\u524d\u540e\u7684N2\u5438\u9644\u7b49\u95ee\u5bf9\u6bd4\u56fe\u3002\u7ea2\u8272\u4e3a\u586b\u5145\u524d\u7684\uff0c\u84dd\u8272\u4e3a\u586b\u5145\u540e\u7684\u3002<br \/>\n\u586b\u5145\u540e\u7684\u8868\u9762\u79ef\u4e25\u91cd\u51cf\u5c11\uff08\u4ece1,480 \u5230 400m 2 g -1\uff09\u8bf4\u660e\u4e86\uff0cDhaTab\u6750\u6599\u7684\u4ecb\u5b54\u7ed3\u6784\u6709\u6548\u7684\u56fa\u5b9a\u4e86\u80f0\u5c9b\u7d20\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/www.nature.com\/ncomms\/2015\/150410\/ncomms7786\/abs\/ncomms7786.html\" target=\"_blank\">Self-templated chemically stable hollow spherical covalent organic framework<\/a><\/p>\n<p>2. JACS<\/p>\n<p>\u672c\u6587\u901a\u8fc7\u63a7\u5236\u51e0\u4f55\u6784\u9020\u65b9\u5f0f\u5408\u6210\u4e8617\u79cd\u6bd4\u8868\u9762\u79ef430\u22123624 m 2g -1\u4e0d\u7b49\u7684\u65b0\u578b\u7684\u591a\u5b54\u5171\u4ef7\u6709\u673a\u7269\u3002\u5e76\u5bf9\u5176\u8fdb\u884c\u4e86\u6bd4\u8f83\u7814\u7a76\u3002\u5e76\u521b\u65b0\u6027\u7684\u5b8c\u6210\u4e86\u4e09\u79cd\u4e0d\u540c\u5b98\u80fd\u56e2\u5728\u591a\u5b54\u5171\u4ef7\u6709\u673a\u7269\u4e2d\u7684\u6574\u5408\u3002\u5f00\u8f9f\u4e86\u50ac\u5316\u5242\u8bbe\u8ba1\uff0c\u529f\u80fd\u4f20\u611f\uff0c\u6c14\u4f53\u6536\u96c6\u7684\u65b0\u601d\u8def\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30121\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/4-18.png\" alt=\"4\" width=\"2100\" height=\"825\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/4-18.png 2100w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/4-18-300x118.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/4-18-768x302.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/4-18-1024x402.png 1024w\" sizes=\"(max-width: 2100px) 100vw, 2100px\" \/><\/p>\n<p>\u56fe\u7ec4\u4e3a298K\u4e0b\u9884\u5408\u6210\u7684\u591a\u5757COP\u7684\u6027\u8d28\u4ee5\u53ca\u5176\u6c14\u4f53\u5438\u9644\u6027\u80fd\u3002\uff08a\uff09\u4e3aCOP\u7684\u7cfb\u5217BET\u8868\u9762\u79ef\u8ba1\u7b97\u7ed3\u679c\u6bd4\u8f83\u3002\uff08b\uff09\u4e3aCOP\u7684\u7cfb\u5217\u5b54\u4f53\u79ef\u3002\uff08c\uff09\u4e3a\u5b54\u9699\u4f53\u79ef\u548c\u8868\u9762\u79ef\u6bd4\u503c\u5bf9\u6bd4\uff08d\uff09\u4e3a\u975e\u529f\u80fd\u5316\u7684COP\u7684CO2\u7684\u5438\u6536\u60c5\u51b5\u3002\uff08e\uff09\u4e3a\u529f\u80fd\u5316\u7684CO2\u7684\u5438\u6536\u60c5\u51b5\u3002\uff08f\uff09\u4e3a\u529f\u80fd\u5316COP\u7684N2\u5438\u6536\u60c5\u51b5\u3002\u5b9e\u5fc3\u4ee5\u53ca\u5f00\u653e\u6807\u5fd7\u5206\u522b\u4ee3\u8868\u5438\u8131\u9644\u7684\u91cf\u3002\uff08g\uff09BET\u8868\u9762\u79ef\u4e0e\u4e8c\u6c27\u5316\u78b3\u5b58\u50a8\u80fd\u529b\u6bd4\u503c \uff08h\uff09\u5b54\u9699\u4f53\u79ef\u548cCO2\u5b58\u50a8\u80fd\u529b\u6bd4\u503c\u3002\u9a8c\u8bc1\u5b98\u80fd\u56e2\u662f\u5426\u6709\u6548\u7684\u65b9\u6cd5\u662f\u8fdb\u884cCO2\u4ee5\u53caN2\u7684\u5438\u9644\u6d4b\u8bd5\u3002\u6d4b\u8bd5\u7ed3\u679c\u5982\u56fe3f\u3002<\/p>\n<p>\u901a\u5e38\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u4ee5\u53ca\u5927\u7684\u5b54\u4f53\u79ef\u5bf9\u5e94\u9ad8\u7684\u6c14\u4f53\u5438\u6536\u91cf\uff0c\u901a\u8fc7\u63a7\u5236\u957f\u5ea6\u4ee5\u53ca\u51e0\u4f55\u6784\u9020\u65b9\u5f0f\uff0c\u5408\u6210\u4e86\u4e0d\u540c\u6bd4\u8868\u9762\u79ef\u7684\u591a\u5b54\u6750\u6599\u3002\u5176\u5206\u5e03\u503c\u5982\u56fe3a,\u5b54\u4f53\u79ef\u60c5\u51b5\u5206\u5e03\u59823b\uff0c\u5e76\u53d1\u73b0\u5176\u5b54\u4f53\u79ef\u548c\u8868\u9762\u79ef\u5b58\u5728\u7ebf\u6027\u5173\u7cfb\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/europepmc.org\/abstract\/MED\/26412410\" target=\"_blank\">Systematic Tuning and Multifunctionalization of Covalent Organic Polymers for Enhanced Carbon Capture.<\/a><\/p>\n<p>3. JACS<\/p>\n<p>\u8868\u9762\u79ef\u7684\u5927\u5c0f\u662f\u8861\u91cf\u65b0\u578b\u591a\u5b54\u6750\u6599\u7684\u91cd\u8981\u6027\u8d28\u4e4b\u4e00\u3002BET\u65b9\u6cd5\u662f\u5b66\u754c\u5e38\u7528\u7684\u8868\u9762\u79ef\u6d4b\u8bd5\u65b9\u6cd5\uff0c\u4f46\u5176\u7406\u8bba\u5047\u8bbe\u57fa\u4e8e\u5e73\u9762\u591a\u5c42\u5438\u9644\uff0c\u5728\u5d0e\u5c96\u8868\u9762\u7684\u5fae\u5b54\u6750\u6599\u8868\u9762\u53ca\u68c0\u6d4b\u4e0a\u8fd8\u6709\u5f85\u63a2\u7a76\u3002\u672c\u6587\u901a\u8fc7\u7406\u8bba\u6a21\u62df\u548c\u5b9e\u9a8c\u5bf9\u6bd4\u68c0\u9a8c\u4e86BET\u8868\u9762\u79ef\u6d4b\u8bd5\u65b9\u6cd5\u5728\u65b0\u578b\u7684\u91d1\u5c5e\u6709\u673a\u76d0\u591a\u5b54\u6750\u6599\u6d4b\u8bd5\u4e2d\u7684\u53ef\u9760\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30122\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/5-17.png\" alt=\"5\" width=\"454\" height=\"418\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/5-17.png 454w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/5-17-300x276.png 300w\" sizes=\"(max-width: 454px) 100vw, 454px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-30123\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/7-16.png\" alt=\"7\" width=\"485\" height=\"331\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/7-16.png 485w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/7-16-300x205.png 300w\" sizes=\"(max-width: 485px) 100vw, 485px\" \/><\/p>\n<p>\u4e0a\u56fe\u4e3a\u4e09\u79cd\u91d1\u5c5e\u6709\u673a\u76d0\u6750\u6599\u7684\u6a21\u62df\u6c2e\u6c14\u5438\u9644\u7b49\u6e29\u56fe<\/p>\n<p>\u968f\u7740\u94fe\u8282\u957f\u5ea6\u7684\u589e\u52a0\u5355\u4f4d\u8d28\u91cf\u7684\u7a7a\u9699\u7387\u4e5f\u66f4\u9ad8\u3002\u4e0e\u6b64\u540c\u65f6\u6750\u6599\u7684\u9971\u548c\u5438\u9644\u80fd\u529b\u4e5f\u6709\u6240\u63d0\u5347\u3002\u591a\u6570\u5b9e\u9a8c\u5173\u6ce8\u9971\u548c\u533a\u7684\u5438\u9644\u60c5\u51b5\u4f7f\u5176\u5f88\u96be\u9884\u8a00\u5438\u9644\u7684\u8fdb\u7a0b\uff0c\u4f4e\u538b\u533a\u7684\u5438\u9644\u5b9e\u9a8c\u5c06\u6210\u4e3a\u672a\u6765\u7814\u7a76\u7684\u91cd\u70b9\u3002<\/p>\n<p>\u8fd9\u662f\u4e00\u7bc7\u6bd4\u8f83\u65e9\u7684\u6587\u7ae0\uff0c\u7cfb\u7edf\u6027\u7684\u53d9\u8ff0\u4e86BET\u6d4b\u8bd5\u6cd5\u5728MOF\u4e2d\u7684\u5e94\u7528\uff0c\u5168\u7bc7\u90fd\u8d2f\u7a7f\u4e86\u5bf9BET\u65b9\u6cd5\u7684\u7406\u8bba\u5047\u8bbe\u5206\u6790\u4ee5\u53ca\u5404\u79cd\u76f8\u5173\u5b9e\u9a8c\u7ed3\u8bba\u3002\u5f3a\u70c8\u63a8\u8350\u4e13\u95e8\u505a\u8868\u9762\u79ef\u5206\u6790\u5c24\u5176\u662fMOF\u7684\u540c\u5b66\u4f5c\u4e3a\u524d\u671f\u7684\u7efc\u8ff0\u4f5c\u4e3a\u9605\u8bfb\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/www.ncbi.nlm.nih.gov\/pubmed\/17580944\" target=\"_blank\">Applicability of the BET method for determining surface areas of microporous metal-organic frameworks<\/a><\/p>\n<p><strong>\u6750\u6599\u4eba\u82f1\u6587\u8bfe\u5802\u5f00\u73ed\u5566\uff01<\/strong><\/p>\n<p>\u52a0\u7c97\u90e8\u5206\u53ef\u66ff\u6362\uff0c\u6709\u5f88\u591a\u53e5\u5b50\u53ef\u4ee5\u76f4\u63a5\u4f7f\u7528\u3002\u53e5\u578b\u7ed3\u6784\u5728\u62ec\u53f7\u91cc\u7ed9\u4e88\u4e86\u8bf4\u660e\u3002<\/p>\n<p>\u4f8b\u53e51\uff1a<br \/>\nGas adsorption. \uff08\u4e00\u822cBET\u7684\u8868\u8ff0\u4f1a\u88ab\u653e\u5728\u6c14\u4f53\u5438\u9644\u8bd5\u9a8c\u4e2d\u8fdb\u884c\u8ba8\u8bba\uff09<br \/>\nThe N2 adsorption was carried out for the activated<strong> COF-DhaTab sample<\/strong> in order to evaluate the permanent porosity. COF-DhaTab exhibits reversible<strong> type IV isotherm<\/strong> (\u6307\u660e\u5438\u9644\u7b49\u6e29\u7ebf\u7684\u5c5e\u6027),which is one of the main characteristics of mesoporous materials\uff08\u4f7f\u7528\u975e\u9650\u5236\u6027\u5b9a\u8bed\u4ece\u53e5\uff0c\u5c06\u6d4b\u8bd5\u66f2\u7ebf\u5c5e\u6027\u548c\u6750\u6599\u7ed3\u6784\u6027\u8d28\u8fdb\u884c\u5173\u8054\uff09. The surface area of COF-DhaTab was calculated to be 1480 m 2 g -1 using\uff08\u975e\u8c13\u8bed\u8fdb\u884c\u8868\u9762\u79ef\u6d4b\u7b97\u7684\u63cf\u8ff0\uff09 the Brunauer\u2013Emmett\u2013Teller (BET) model<\/p>\n<p>carry out:\u5b9e\u65bd\uff08\u5b9e\u9a8c\uff09<br \/>\nevaluate\uff1a\u6d4b\u7b97\uff0c\u6d4b\u5b9a\uff0c\u8bc4\u4ef7\uff0c\u540e\u9762\u52a0\u5e7f\u5ea6\u7269\u7406\u91cf\u548c\u5f3a\u5ea6\u7269\u7406\u91cf\u90fd\u53ef\u4ee5\uff0c\u6b64\u5904\u662f\u6d4b\u5b54\u9699\u7387\uff0c\u7b97\u662fBET\u65b9\u6cd5\u7684\u901a\u7528\u3002<br \/>\nexhibit:\u8868\u73b0\uff0c\u5c55\u73b0\uff0c\u4e00\u822c\u5728\u63cf\u8ff0\u6750\u6599\u6027\u8d28\u65f6\u5e38\u7528\uff0c\u53ef\u4ee5\u66ff\u6362show, represent, address,deliver\u7b49\u8bcd\u6c47<\/p>\n<p>\u4f8b\u53e52: An instructive first check to gain insights on the suitability of<strong> these functionalized multiblock COPs<\/strong> for their application in<strong> carbon capture<\/strong> is to estimate their CO 2 \/N 2 selectivities. For this reason, we also measured the N 2 adsorption isotherms at 298 K (Figure 3f). Likewise, N 2 adsorption capacity largely<br \/>\ncorrelates with surface area and pore volume.<\/p>\n<p>gain insight on:\u5bf9\u67d0\u4e8b\u6709\u6240\u4e86\u89e3\uff0c\u76f8\u5f53\u4e8eknow, learn\u4f46\u662f\u66f4\u5730\u9053\u66f4\u9ad8\u7ea7<br \/>\nestimate\uff1a\u6d4b\u7b97\uff0c\u4e0e\u524d\u9762\u7684evaluate\u7528\u6cd5\u76f8\u540c<br \/>\ncorrelates with\uff1a\u4e0e\u4ec0\u4e48\u76f8\u5173\uff0c\u76f8\u5f53\u4e8erelated to\/with\uff0ccorrespond to<br \/>\nlikewise:\u6b63\u5982\u9884\u671f\u7684\u4e00\u6837\uff0c\u5f15\u51fa\u4e0e\u5b9e\u9a8c\u7ed3\u8bba\u76f8\u7b26\u5408\u7684\u7406\u8bba\u57fa\u7840\u3002\u4e5f\u53ef\u4ee5\u5355\u72ec\u4f5c\u4e3a\u63d2\u5165\u8bed\u4f7f\u7528\u3002<\/p>\n<p>\u4f8b\u53e53\uff1aIncreasing linker lengths correspond to more open structures with larger pore volumes per mass, and Figure 2a shows that, as expected,(\u63d2\u5165\u8bed\u90e8\u5206\uff0c\u4e0e\u5df2\u6709\u7ed3\u8bba\u76f8\u4e00\u81f4\u65f6\u53ef\u4ee5\u52a0\u5165) the adsorption saturation capacities increase with increasing \uff08\u5e38\u7528\u63cf\u8ff0\u53d8\u5316\u8d8b\u52bf\u7684\u8868\u8fbe\uff09pore volume. The most striking feature of these isotherms is an unusual step, which can be seen more clearly in Figure 2b.Eddaoudi et al. 26 have reported experimental isotherms fornitrogen in IRMOF-12 and IRMOF-14 that show a similar step,but they do not comment on it\uff08\u5b9a\u4ece\u5bf9\u5b9e\u9a8c\u7ed3\u8bba\u8fdb\u884c\u63cf\u8ff0\uff09\uff08\u6574\u4e2a\u662f\u4e00\u4e2a\u975e\u9650\u5236\u6027\u5b9a\u8bed\u4ece\u53e5\u63cf\u8ff0\u7684\u662f\u4e00\u4e2a\u975e\u5e38\u8f6c\u6298\uff09.<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u00a0<a href=\"\/\/m.iemloyee.com\/wp-admin\/edit.php?post_type=post&amp;author=287\">vivianren<\/a>\u00a0\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6b22\u8fce\u4f18\u79c0\u7855\u3001\u535a\u58eb\u751f\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u5c0f\u7ec4\uff0c\u4e00\u8d77\u4f20\u64ad\u5b66\u672f\u77e5\u8bc6\uff0c\u5c55\u73b0\u4f60\u7684\u624d\u534e\uff0c\u52a9\u529b\u6750\u6599\u79d1\u7814\uff0c\u4f18\u79c0\u7a3f\u4ef6\u4e00\u7ecf\u5f55\u7528\uff0c\u6211\u4eec\u4f1a\u5949\u4e0a\u7a3f\u916c\uff0c\u8d76\u5feb\u79c1\u4fe1\u7ba1\u7406\u5458\u8d1f\u8d23\u4eba\u201c\u6de1\u5e74\u534e\uff08QQ:601416321\uff09\u201d\u62a5\u540d\u5427\uff01<\/p>\n<p>\u6b22\u8fce\u5404\u5927\u8bfe\u9898\u7ec4\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1<a href=\"mailto:tougao@cailiaoren.com\" target=\"_blank\">tougao@cailiaoren.com<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6750\u6599\u8868\u9762\u901a\u5e38\u6027\u8d28\u7a81\u53d8\uff0c\u53cd\u5e94\u8fdb\u884c\u7684\u9996\u9009\u573a\u6240\uff0c\u56e0\u800c\u5728\u6750\u6599\u5b66\u7684\u7814\u7a76\u4e2d\u7edd\u5bf9\u4e0d\u5bb9\u5c0f\u89d1\u3002\u4e3a\u4e86\u8fdb\u884c\u7edf\u4e00\u6bd4\u8f83\uff0c\u901a\u5e38\u8981\u628a\u8868\u9762\u8fd9\u4e00\u5e7f\u5ea6\u91cf\u8f6c\u5316\u4e3a\u6bd4\u8868\u9762\u8fd9\u4e00\u5f3a\u5ea6\u91cf\u6765\u6bd4\u8f83\u3002\u7eb3\u7c73\u6750\u6599\u7092\u4e86\u5982&#8230;<\/p>\n","protected":false},"author":287,"featured_media":32519,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-30113","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-ganhuo"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/30113"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/287"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=30113"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/30113\/revisions"}],"predecessor-version":[{"id":37012,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/30113\/revisions\/37012"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/32519"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=30113"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=30113"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=30113"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}