{"id":268663,"date":"2025-09-27T07:22:00","date_gmt":"2025-09-26T23:22:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=268663"},"modified":"2025-09-26T21:55:57","modified_gmt":"2025-09-26T13:55:57","slug":"%e5%88%86%e5%ad%90%e9%97%b4%e6%b0%a2%e9%94%ae%e8%b0%83%e6%8e%a7%e6%ba%b6%e5%89%82%e7%bb%93%e6%9e%84%ef%bc%9a%e4%b8%ba%e4%bd%8e%e6%b8%a9%e3%80%81%e9%95%bf%e5%af%bf%e5%91%bd%e9%94%82%e7%94%b5%e6%89%93","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=268663","title":{"rendered":"\u5206\u5b50\u95f4\u6c22\u952e\u8c03\u63a7\u6eb6\u5242\u7ed3\u6784\uff1a\u4e3a\u4f4e\u6e29\u3001\u957f\u5bff\u547d\u9502\u7535\u6253\u5f00\u65b0\u5c40\u9762"},"content":{"rendered":"\n<p><strong>\u5bfc\u8bed<\/strong><\/p>\n\n\n\n<p>\u5728\u6781\u5bd2\u73af\u5883\u4e2d\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u5f80\u5f80\u56e0\u4e3a\u7535\u89e3\u8d28\u4e2d\u6eb6\u5242\u2014\u9502\u79bb\u5b50\u76f8\u4e92\u4f5c\u7528\u589e\u5f3a\u3001\u79bb\u5b50\u8fc1\u79fb\u56f0\u96be\u3001\u754c\u9762\u963b\u6297\u5347\u9ad8\u7b49\u95ee\u9898\u800c\u6027\u80fd\u6025\u5267\u4e0b\u964d\u3002<\/p>\n\n\n\n<p>\u6700\u8fd1\uff0c\u4e00\u9879\u53d1\u8868\u4e8e Advanced Functional Materials \u7684\u7814\u7a76\u6307\u51fa\uff1a\u201c\u5206\u5b50\u95f4\u6c22\u952e\u8c03\u63a7\u6eb6\u5242\u7ed3\u6784\u201d\u53ef\u4ee5\u663e\u8457\u6291\u5236\u4f4e\u6e29\u4e0b\u6eb6\u5242\u56f4\u7ed5\u9502\u79bb\u5b50\u7684\u8fc7\u5ea6\u805a\u96c6\uff0c\u4ece\u800c\u5b9e\u73b0 \u4f4e\u6e29\u5faa\u73af\u7a33\u5b9a\u6027\u63d0\u5347\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"720\" height=\"304\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/09\/\u5fae\u4fe1\u622a\u56fe_20250926215507.jpg\" alt=\"\" class=\"wp-image-268673\"\/><\/figure>\n\n\n\n<p><strong>\u6838\u5fc3\u5185\u5bb9\u89e3\u8bfb<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u9762\u4e34\u5bb9\u91cf\u8870\u51cf\u5feb\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\u7b49\u95ee\u9898\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u6311\u6218\uff0c\u7814\u7a76\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u7535\u89e3\u6db2\u4f53\u7cfb\uff0c\u65e8\u5728\u5b9e\u73b0 <strong>LFP\/\u77f3\u58a8\u7535\u6c60\u5728\u4f4e\u6e29\u4e0b\u7684\u7a33\u5b9a\u5faa\u73af<\/strong>\u3002\u7535\u89e3\u6db2\u9700\u8981\u6ee1\u8db3\u5bbd\u6db2\u6001\u533a\u95f4\u3001\u4f4e\u9ecf\u5ea6\u548c\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7b49\u8981\u6c42\u3002\u7814\u7a76\u8005\u5728\u7b5b\u9009\u6eb6\u5242\u65f6\u53d1\u73b0\uff0c\u76f4\u94fe\u8148\u7c7b\uff08\u5982 AN\u3001PN\u3001BN\u3001VN\uff09\u867d\u7136\u5177\u6709\u4f4e\u6e29\u7279\u6027\uff0c\u4f46\u5b58\u5728\u77f3\u58a8\u5171\u5d4c\u5165\u7684\u98ce\u9669\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u652f\u94fe\u8148\u7c7b\uff08\u5982 IBN\u3001MBAN\u3001TMAN\uff09\u7ed3\u6784\u66f4\u4e3a\u6709\u5229\uff0c\u5176\u4e2d <strong>IBN \u8868\u73b0\u6700\u4f73<\/strong>\uff0c\u4f46\u4ecd\u9700\u8fdb\u4e00\u6b65\u4f18\u5316\u4ee5\u907f\u514d Li\u207a \u5171\u5d4c\u5165\u73b0\u8c61\u3002<\/p>\n\n\n\n<p>\u4e3a\u6b64\uff0c\u7814\u7a76\u56e2\u961f\u5f15\u5165\u4e86 <strong>\u5171\u6eb6\u5242\u7b56\u7565<\/strong>\u3002FEC \u4f5c\u4e3a\u5e38\u89c1\u7684\u6210\u819c\u6eb6\u5242\uff0c\u80fd\u591f\u6709\u6548\u6291\u5236\u5171\u5d4c\u5165\uff0c\u4f46\u9ecf\u5ea6\u8fc7\u9ad8\uff1bFDMA \u5177\u6709\u4f4e\u9ecf\u5ea6\u3001\u4f4e\u7194\u70b9\uff0c\u540c\u65f6\u5176\u6700\u4f4e LUMO \u80fd\u7ea7\u4f7f\u5176\u5728\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\u4f18\u5148\u5f62\u6210 SEI\u3002\u6700\u7ec8\uff0c\u56e2\u961f\u4f18\u5316\u51fa <strong>IBN\/FDMA\/FEC = 8:1:1\uff0c1 M LiTFSI<\/strong>&nbsp;\u7684\u7535\u89e3\u6db2\u914d\u6bd4\u3002<\/p>\n\n\n\n<p>\u5728\u4f20\u8f93\u4e0e\u6eb6\u5242\u5316\u7279\u6027\u65b9\u9762\uff0c\u4f18\u5316\u7535\u89e3\u6db2\u5c55\u73b0\u51fa\u4f18\u5f02\u8868\u73b0\u3002IBN \u57fa\u7535\u89e3\u6db2\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u9ad8\u8fbe <strong>12.11 mS\/cm<\/strong>\uff0c\u660e\u663e\u4f18\u4e8e\u4f20\u7edf EC\/DEC \u7535\u89e3\u6db2\uff0c\u5e76\u4e14\u5728 \u221260 \u00b0C \u4ecd\u80fd\u4fdd\u6301 <strong>3.15 mS\/cm<\/strong>\u3002\u5176\u6d3b\u5316\u80fd\u4ec5\u4e3a <strong>0.077 eV<\/strong>\uff0c\u8fdc\u4f4e\u4e8e EC\/DEC \u4f53\u7cfb\u3002\u5206\u5b50\u52a8\u529b\u5b66\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u663e\u793a\uff0cIBN \u662f Li\u207a \u7684\u4e3b\u8981\u914d\u4f4d\u6eb6\u5242\uff0c\u800c FDMA \u4e0e IBN \u4e4b\u95f4\u901a\u8fc7 <strong>\u6c22\u952e\u4f5c\u7528<\/strong>&nbsp;\u8c03\u8282\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u5f62\u6210\u66f4\u5927\u89c4\u6a21\u7684\u6eb6\u5242\u5316\u7c07\uff0c\u4ece\u800c\u6291\u5236\u77f3\u58a8\u5171\u5d4c\u5165\u5e76\u63d0\u5347\u4f53\u7cfb\u7a33\u5b9a\u6027\u3002<\/p>\n\n\n\n<p>\u754c\u9762\u5206\u6790\u7ed3\u679c\u663e\u793a\uff0cIBN\/FDMA\/FEC \u7535\u89e3\u6db2\u80fd\u591f\u5f62\u6210\u4e00\u5c42 <strong>\u8584\u800c\u7a33\u5b9a\u7684 SEI<\/strong>\u3002Cryo-TEM \u8868\u660e\uff0c\u8be5 SEI \u539a\u5ea6\u4ec5\u7ea6 5 nm\uff0c\u660e\u663e\u5c0f\u4e8e EC\/DEC \u4f53\u7cfb\u7684 ~28 nm\u3002\u8fdb\u4e00\u6b65\u7684 TOF-SIMS \u4e0e XPS \u5206\u6790\u786e\u8ba4\uff0c\u8fd9\u4e00 SEI \u5bcc\u542b <strong>LiF\u3001Li\u2082O\u3001Li\u2082CO\u2083<\/strong>&nbsp;\u7b49\u65e0\u673a\u6210\u5206\uff0c\u754c\u9762\u66f4\u52a0\u7a33\u5b9a\u3002\u800c\u4f20\u7edf EC\/DEC \u7535\u89e3\u6db2\u5f62\u6210\u7684 SEI \u539a\u4e14\u4e0d\u5747\u5300\uff0c\u5bfc\u81f4\u66f4\u591a\u9502\u679d\u6676\u6c89\u79ef\u3002<\/p>\n\n\n\n<p>\u5728\u7535\u5316\u5b66\u6027\u80fd\u65b9\u9762\uff0c\u8fd9\u4e00\u65b0\u578b\u7535\u89e3\u6db2\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u9002\u5e94\u6027\u3002\u5e38\u6e29\u4e0b\u7535\u6c60\u5177\u6709\u7a33\u5b9a\u7684\u957f\u5faa\u73af\u6027\u80fd\u548c\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\uff1b\u5728 <strong>\u4f4e\u6e29\uff08\u221220 \u81f3 \u221250 \u00b0C\uff09<\/strong>&nbsp;\u6761\u4ef6\u4e0b\uff0c\u221220 \u00b0C \u65f6\u7535\u6c60\u5728\u5faa\u73af <strong>800 \u5708\u540e\u4ecd\u4fdd\u6301 99.9% \u5bb9\u91cf<\/strong>\uff0c\u5728 \u221240 \u00b0C \u65f6\u5bb9\u91cf\u53ef\u8fbe 759 mAh\uff0c\u662f EC\/DEC \u4f53\u7cfb\u7684\u4e09\u500d\uff1b\u5728 <strong>\u9ad8\u6e29\uff0860 \u00b0C\uff09<\/strong>&nbsp;\u4e0b\u540c\u6837\u4fdd\u6301\u7a33\u5b9a\uff0c\u6781\u5316\u8f83\u5c0f\u3002\u6574\u4f53\u6027\u80fd\u663e\u8457\u4f18\u4e8e\u4ee5\u5f80\u62a5\u9053\u7684 LFP\/\u77f3\u58a8\u4f53\u7cfb\u7535\u89e3\u6db2\u3002<\/p>\n\n\n\n<p>\u603b\u7ed3\u6765\u770b\uff0c\u8be5\u7814\u7a76\u7684\u6838\u5fc3\u5728\u4e8e <strong>\u6c22\u952e\u8c03\u63a7\u7684\u6eb6\u5242\u5316\u7ed3\u6784<\/strong>\u3002\u4f18\u5316\u7535\u89e3\u6db2\u5728\u4f4e\u6e29\u4e0b\u6709\u6548\u6291\u5236\u6eb6\u5242\u5206\u5b50\u7684\u8fc7\u5ea6\u914d\u4f4d\uff0c\u4fdd\u8bc1\u9634\u79bb\u5b50\u80fd\u591f\u53c2\u4e0e\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u5f62\u6210\u7a33\u5b9a\u7684\u754c\u9762\u819c\uff0c\u540c\u65f6\u4fdd\u6301\u9ad8\u7535\u5bfc\u7387\u3002\u6700\u7ec8\uff0c\u8fd9\u4e00\u4f53\u7cfb\u5728 <strong>\u221280 \u81f3 +80 \u00b0C \u7684\u5bbd\u6e29\u533a\u95f4<\/strong>&nbsp;\u5185\u5747\u80fd\u5b9e\u73b0\u7a33\u5b9a\u8fd0\u884c\uff0c\u4ee3\u8868\u4e86\u5bd2\u51b7\u6c14\u5019\u4e0b\u9502\u79bb\u5b50\u7535\u6c60\u7535\u89e3\u6db2\u8bbe\u8ba1\u7684\u4e00\u9879\u91cd\u5927\u7a81\u7834\u3002<\/p>\n\n\n\n<p>\u8bba\u6587\u5730\u5740\uff1a<a href=\"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adfm.202519001\">Intermolecular Hydrogen Bonding Tailors Solvation Structures for Low\u2010Temperature and Long\u2010Cycling Lithium\u2010Ion Batteries &#8211; Wu &#8211; Advanced Functional Materials &#8211; Wiley Online Library<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5bfc\u8bed \u5728\u6781\u5bd2\u73af\u5883\u4e2d\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u5f80\u5f80\u56e0\u4e3a\u7535\u89e3\u8d28\u4e2d\u6eb6\u5242\u2014\u9502\u79bb\u5b50\u76f8\u4e92\u4f5c\u7528\u589e\u5f3a\u3001\u79bb\u5b50\u8fc1\u79fb\u56f0\u96be\u3001\u754c\u9762\u963b\u6297\u5347\u9ad8\u7b49\u95ee\u9898\u800c\u6027\u80fd\u6025\u5267\u4e0b\u964d\u3002 \u6700\u8fd1\uff0c\u4e00\u9879\u53d1\u8868\u4e8e Advanced F&#8230;<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-268663","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/268663"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=268663"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/268663\/revisions"}],"predecessor-version":[{"id":268674,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/268663\/revisions\/268674"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=268663"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=268663"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=268663"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}