{"id":268518,"date":"2025-10-01T07:59:00","date_gmt":"2025-09-30T23:59:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=268518"},"modified":"2025-09-30T22:58:15","modified_gmt":"2025-09-30T14:58:15","slug":"%e6%9c%89%e6%9c%ba%e5%8c%96%e5%ad%a6%e6%96%b0%e7%aa%81%e7%a0%b4%ef%bc%9a%e8%af%a5%e7%af%87science%e5%ae%9e%e7%8e%b0z%e9%80%89%e6%8b%a9%e6%80%a7c-h%e5%ae%98%e8%83%bd%e5%9b%a2%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=268518","title":{"rendered":"\u6709\u673a\u5316\u5b66\u65b0\u7a81\u7834\uff1a\u8be5\u7bc7Science\u5b9e\u73b0Z\u9009\u62e9\u6027C-H\u5b98\u80fd\u56e2\u5316"},"content":{"rendered":"\n<p class=\"has-text-align-center\"><strong>\u6709\u673a\u5316\u5b66\u65b0\u7a81\u7834\uff1a\u8be5\u7bc7<\/strong><strong>Science<\/strong><strong>\u5b9e\u73b0Z\u9009\u62e9\u6027C-H\u5b98\u80fd\u56e2\u5316<\/strong><strong><\/strong><\/p>\n\n\n\n<p class=\"has-text-align-center\"><strong>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><strong><\/strong><\/p>\n\n\n\n<p>C-H\u952e\u7684\u8f6c\u5316\u662f\u6709\u673a\u5408\u6210\u9886\u57df\u957f\u671f\u4ee5\u6765\u7684\u76ee\u6807\u3002\u6570\u5341\u5e74\u7684\u7814\u7a76\u5df2\u5f00\u53d1\u51fa\u591a\u79cd\u673a\u7406\u5404\u5f02\u7684\u7b56\u7565\uff0c\u5c06\u8fd9\u7c7b\u4f20\u7edf\u60f0\u6027\u952e\u66ff\u6362\u4e3a\u65b0\u7684C-C\u952e\u3002\u5728\u6b64\u5e7f\u9614\u9886\u57df\u4e2d\uff0c\u63a7\u5236\u7acb\u4f53\u9009\u62e9\u6027\u7684\u7b56\u7565\u81f3\u5173\u91cd\u8981\u3002\u5c3d\u7ba1\u8fd1\u671f\u51fa\u73b0\u4e86\u4e00\u4e9bC-H\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u7684\u5b9e\u4f8b\uff0c\u4f46Z\u9009\u62e9\u6027\u70ef\u57faC-H\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u4ecd\u96be\u4ee5\u5b9e\u73b0\u3002\u4f8b\u5982\uff0c\u5c3d\u7ba1\u8bfa\u8d1d\u5c14\u5956\u83b7\u5956\u53cd\u5e94\u2014\u8d6b\u514b\u53cd\u5e94\u5df2\u5386\u7ecf\u534a\u4e2a\u591a\u4e16\u7eaa\u7684\u521b\u65b0\uff0c\u4f46\u5176Z\u9009\u62e9\u6027\u53d8\u4f53\u4ecd\u672a\u51fa\u73b0\u3002\u5c3d\u7ba1\u5df2\u77e5\u5b58\u5728\u5176\u4ed6\u5408\u6210Z-\u70ef\u70c3\u7684\u7b56\u7565\uff0c\u4f46\u6240\u6709\u9009\u62e9\u6027\u65ad\u88c2\u4eb2Z-C-H\u952e\u7684\u65b9\u6cd5\u5747\u4f9d\u8d56\u5bfc\u5411\u57fa\u5b9e\u73b0\u7acb\u4f53\u9009\u62e9\u6027\u3002\u8fd9\u79cd\u7b56\u7565\u672c\u8d28\u4e0a\u5c06Z-\u9009\u62e9\u6027C-H\u5b98\u80fd\u56e2\u5316\u5c40\u9650\u4e8e\u4e00\u5c0f\u7c7b\u5e26\u6709\u5f3a\u914d\u4f4d\u8f85\u52a9\u57fa\u7684\u521a\u6027\u70ef\u70c3\u3002\u603b\u4e4b\uff0c\u8981\u5b9e\u73b0\u975e\u5bfc\u5411\u6027Z\u9009\u62e9\u6027C-H\u5b98\u80fd\u56e2\u5316\u7684\u4e92\u8865\u65b9\u6cd5\uff0c\u5fc5\u987b\u5efa\u7acb\u65b0\u7684\u673a\u7406\u7b56\u7565\u4ee5\u514b\u670d\u963b\u788dZ\u70ef\u70c3\u5f62\u6210\u7684\u56fa\u6709\u70ed\u529b\u5b66\u969c\u788d\u3002<\/p>\n\n\n\n<p class=\"has-text-align-center\"><strong>\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n\n\n\n<p>\u57fa\u4e8e\u4e0a\u8ff0\u6311\u6218\uff0c\u8fd1\u671f\u5a01\u65af\u5eb7\u661f\u5927\u5b66\u9ea6\u8fea\u900a\u5206\u6821Zachary K. Wickens\u6559\u6388\u3001\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821Osvaldo Gutierrez\u6559\u6388\u3001Marcel 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Science<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u5728\u7814\u7a76\u567b\u84bd\uff08TT\uff09\u4e0e\u70ef\u70c3\u5f62\u6210\u7684\u53cc\u52a0\u6210\u7269\u4e0e\u5355\u52a0\u6210\u7269\u7684\u7535\u5316\u5b66\u53cd\u5e94\u6027\u65f6\uff0c\u7814\u7a76\u4eba\u5458\u89c2\u5bdf\u5230\u53cc\u52a0\u6210\u7269\u4e0e\u5355\u52a0\u6210\u7269\u7684\u6469\u5c14\u6bd4\u4e0e\u751f\u6210\u7684\u8131\u53bb\u4ea7\u7269\u4e2dZ-E\u5f02\u6784\u4f53\u6bd4\u4f8b\u5b58\u5728\u660e\u786e\u5bf9\u5e94\u5173\u7cfb\uff08\u56fe2A\uff09\u3002\u8be5\u8d8b\u52bf\u9884\u793a\u53cc\u52a0\u6210\u7269\u5c06\u9009\u62e9\u6027\u8131\u53bb\u751f\u6210Z-\u70ef\u57fa\u786b\u84bd\u9393\u4ea7\u72691\u3002\u4e3a\u9a8c\u8bc1\u6b64\u9884\u6d4b\uff0c\u7814\u7a76\u4eba\u5458\u5206\u79bb\u51fa\u7535\u89e3\u751f\u6210\u7684\u5fae\u91cf\u53cc\u52a0\u6210\u7269\uff0c\u5e76\u7528\u5f31\u78b1\u4e09\u6c1f\u4e59\u9178\u76d0\uff08\u8be5\u8bd5\u5242\u4e0d\u4f1a\u4fc3\u8fdb\u70ef\u57fa\u786b\u84bd\u9393\u5f02\u6784\u5316\uff09\u8fdb\u884c\u5904\u7406\u3002\u5b9e\u9a8c\u8bc1\u5b9e\u53cc\u52a0\u6210\u7269\u4ee5\u8fd1\u4e4e\u5b8c\u7f8e\u7684Z\u9009\u62e9\u6027\u53d1\u751f\u8131\u53bb\u53cd\u5e94\uff0c\u8be5\u53d1\u73b0\u4e3a\u5efa\u7acbZ\u9009\u62e9\u6027C-H\u5b98\u80fd\u56e2\u5316\u901a\u7528\u7b56\u7565\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n\n\n\n<p>\u968f\u540e\uff0c\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u7684\u7535\u5316\u5b66\u7cfb\u7edf\uff0c\u540c\u65f6\u6291\u5236\u4e86\u5355\u52a0\u6210\u53cd\u5e94\u5e76\u9632\u6b62\u53cc\u52a0\u6210\u5411\u5355\u52a0\u6210\u7684\u8f6c\u5316\u3002\u867d\u7136\u6700\u521d\u91c7\u7528\u5206\u9694\u7535\u89e3\u6c60\u4ee5\u7ef4\u6301\u9ad8\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c\u4f46\u7814\u7a76\u4eba\u5458\u8bbe\u60f3\u4f7f\u7528\u65e0\u5206\u9694\u7535\u89e3\u6c60\u2014\u5373\u5728\u53cd\u5e94\u5ba4\u4e2d\u5f15\u5165\u9634\u6781\uff0c\u8fd9\u53ef\u5e26\u6765\u4e24\u5927\u4f18\u52bf\uff08\u56fe2C\uff09\u3002\u9996\u5148\uff0c\u9634\u6781\u901a\u8fc7\u8fd8\u539f\u9633\u6781\u53ef\u7ef4\u6301TT\u7684\u9ad8\u7a33\u6001\u6d53\u5ea6\uff0c\u4ece\u800c\u6291\u5236\u6b67\u5316\u53cd\u5e94\uff0c\u5728\u65e0\u9700\u5927\u91cf\u8fc7\u91cfTT\u7684\u60c5\u51b5\u4e0b\u51cf\u5c11\u5355\u4f53\u751f\u6210\u3002\u5176\u6b21\uff0c\u9634\u6781\u4e0a\u4e09\u6c1f\u4e59\u9178\u7684\u6c22\u6790\u51fa\u53cd\u5e94\u5c06\u751f\u6210\u4e09\u6c1f\u4e59\u9178\u76d0\u78b1\u3002\u8fd9\u79cd\u914d\u5bf9\u7535\u89e3\u88c5\u7f6e\u786e\u4fdd\u4ec5\u5728\u5f62\u6210\u52a0\u5408\u7269\u65f6\u4ea7\u751f\u78b1\uff0c\u4ece\u800c\u7f13\u89e3\u78b1\u8bf1\u5bfc\u7684\u53cd\u5e94\u6291\u5236\u3002\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u672a\u5206\u9694\u7535\u89e3\u6c60\u98a0\u8986\u4e86\u567b\u84bd\u5316\u53cd\u5e94\u7684\u5178\u578b\u7acb\u4f53\u9009\u62e9\u6027\uff0c\u5728\u6781\u5c11\u989d\u5916\u4f18\u5316\u4e0b\u5373\u4ee5\u9ad8\u6536\u7387\u548cZ\u9009\u62e9\u6027\u83b7\u5f97\u6a21\u578b\u70ef\u57fa\u567b\u84bd\u9393\u76d01\uff08\u56fe2D\uff09\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"558\" height=\"741\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/09\/\u56fe\u72472-1.png\" alt=\"\" class=\"wp-image-268520\" style=\"width:840px;height:auto\" \/><\/figure><\/div>\n\n\n<p class=\"has-text-align-center\"><strong>\u56fe<\/strong><strong>2 <\/strong><strong>\u53cd\u5e94\u8bbe\u8ba1\uff1b<\/strong><strong>\u00a9 2025 Science<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u968f\u540e\uff0c\u7814\u7a76\u4eba\u5458\u63a2\u7a76\u4e86\u9002\u7528\u4e8e\u8be5Z\u9009\u62e9\u6027\u567b\u84bd\u5316\u53cd\u5e94\u7684\u70ef\u70c3\u8303\u56f4\uff08\u56fe3A\uff09\u3002\u5728\u6574\u4e2a\u7814\u7a76\u8fc7\u7a0b\u4e2d\uff0c\u4ed6\u4eec\u53d1\u73b0\u8be5\u8fc7\u7a0b\u7684\u56fa\u6709Z\u9009\u62e9\u6027\u59cb\u7ec8\u4fdd\u6301\u5728\u8f83\u9ad8\u6c34\u5e73\u3002\u6b64\u5916\uff0c\u8fd9\u4e9bZ-\u70ef\u57fa\u567b\u84bd\u9393\u76d0\u5177\u6709\u5353\u8d8a\u7684\u7ed3\u6676\u6027\uff0c\u901a\u8fc7\u91cd\u7ed3\u6676\u53ef\u83b7\u5f97\u8fd1\u4e4e\u5bf9\u6620\u4f53\u7eaf\u7684\u4ea7\u7269\u3002\u8fd9\u76f8\u8f83\u4e8e\u4f20\u7edf\u70ef\u70c3\u5408\u6210\u5177\u6709\u663e\u8457\u4f18\u52bf\uff0c\u5728\u672a\u5206\u9694\u7684\u53cd\u5e94\u6c60\u6761\u4ef6\u4e0b\uff0c\u901a\u8fc7\u542b\u591a\u79cd\u5e38\u89c1\u5b98\u80fd\u56e2\u7684\u672b\u7aef\u70ef\u70c3\uff0c\u53ef\u8f7b\u677e\u83b7\u5f97Z-\u70ef\u57fa\u786b\u84bd\u9393\u76d0\u3002\u5176\u4ed6\u542b\u4eb2\u6838\u6027\u5b98\u80fd\u56e2\u7684\u70ef\u70c3\u5e95\u7269\uff0c\u5982\u9170\u80fa\u3001\u7fa7\u9178\u548c\u78fa\u9170\u80fa\uff0c\u5747\u53ef\u5728\u4e0d\u7ecf\u539f\u4f4d\u8f6c\u5316\u60c5\u51b5\u4e0b\u5b9e\u73b0\u567b\u84bd\u5316\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"656\" height=\"819\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/09\/\u56fe\u72473-1.png\" alt=\"\" class=\"wp-image-268521\" style=\"width:789px;height:auto\" \/><\/figure><\/div>\n\n\n<p class=\"has-text-align-center\"><strong>\u56fe<\/strong><strong>3 <\/strong><strong>Z-\u9009\u62e9\u6027C<\/strong><strong>&#8211;<\/strong><strong>H<\/strong><strong>\u567b\u84bd<\/strong><strong>\u5316\u53cd\u5e94\uff1b &nbsp;<\/strong><strong>\u00a9 2025 Science<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u8fdb\u4e00\u6b65\u5730\uff0c\u8be5\u7814\u7a76\u56e2\u961f\u5c55\u793a\u4e86\u8be5\u7c7bZ\u578b\u70ef\u57fa\u786b\u84bd\u9393\u76d0\u5728\u591a\u79cd\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u4e2d\u7684\u9002\u7528\u6027\uff0cSonogashira\u3001Suzuki\u3001Negishi\u3001Heck\u5076\u8054\u4ee5\u53ca\u7fb0\u57fa\u5316\u53cd\u5e94\u5728\u5185\u7684\u4e00\u7cfb\u5217\u53cd\u5e94\uff0c\u5747\u80fd\u9ad8\u5ea6\u4fdd\u6301\u70ef\u70c3\u7684Z\u6784\u578b\u3002\u8fd8\u65b9\u6cd5\u8fd8\u88ab\u6210\u529f\u5e94\u7528\u4e8e\u591a\u79cd\u751f\u7269\u6d3b\u6027\u5929\u7136\u4ea7\u7269\u7684\u5408\u6210\u4e2d\uff0c\u7279\u522b\u662f\u4e00\u4e9b\u751f\u7269\u4fe1\u606f\u7d20\uff08\u56fe4\uff09\uff0c\u663e\u793a\u51fa\u5176\u5f3a\u5927\u7684\u5408\u6210\u5b9e\u7528\u6027\u548c\u6b65\u9aa4\u7ecf\u6d4e\u6027\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"704\" height=\"767\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/09\/\u56fe\u72474-1.png\" alt=\"\" class=\"wp-image-268522\" style=\"width:816px;height:auto\" \/><\/figure><\/div>\n\n\n<p class=\"has-text-align-center\"><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\u5408\u6210\u5e94\u7528<\/strong><strong>\uff1b <\/strong><strong>\u00a9 2025 Science<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u7814\u7a76\u4eba\u5458\u6700\u540e\u5bf9\u8be5\u53cd\u5e94\u7684\u673a\u7406\u8fdb\u884c\u4e86\u63a2\u7a76\uff0c\u57fa\u4e8e\u8ba1\u7b97\u5316\u5b66\u5206\u6790\uff0c\u4ed6\u4eec\u53d1\u73b0\uff0c\u867d\u7136\u4ece\u57fa\u6001\u6784\u8c61\u4e0a\u770b\uff0cE\u578b\u6d88\u9664\u8def\u5f84\u4f3c\u4e4e\u66f4\u6709\u4f18\u52bf\uff0c\u4f46\u5728\u8fc7\u6e21\u6001\u4e2d\uff0cZ\u578b\u8def\u5f84\u56e0\u4fdd\u7559\u4e86\u5173\u952e\u7684\u03c0-\u03c0\u5806\u53e0\u548cC-H\u00b7\u00b7\u00b7S\u6c22\u952e\u4f5c\u7528\u800c\u80fd\u91cf\u66f4\u4f4e\u3002\u5728\u7ef4\u6301\u5173\u952e\u7a33\u5b9a\u4f5c\u7528\u7684\u540c\u65f6\uff0c\u7acb\u4f53\u4f4d\u963b\u6700\u5c0f\u7684\u8fc7\u6e21\u6001\u6700\u7ec8\u5f62\u6210Z\u578b\u7acb\u4f53\u5f02\u6784\u4f53\uff08\u56fe5C\uff09\u3002\u7814\u7a76\u4eba\u5458\u968f\u540e\u8bbe\u8ba1\u4e86\u5c06\u786b\u539f\u5b50\u66ff\u6362\u4e3a\u6c27\u539f\u5b50\u7684\u5bf9\u7167\u5b9e\u9a8c\uff0c\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u4e86\u6c22\u952e\u4f5c\u7528\u5728\u7acb\u4f53\u63a7\u5236\u4e2d\u7684\u5173\u952e\u89d2\u8272\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"638\" height=\"735\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/09\/\u56fe\u72475-1.png\" alt=\"\" class=\"wp-image-268523\" style=\"width:777px;height:auto\" \/><\/figure><\/div>\n\n\n<p class=\"has-text-align-center\"><strong>\u56fe<\/strong><strong>5<\/strong><strong>&nbsp;Z-<\/strong><strong>\u9009\u62e9\u6027\u7684<\/strong><strong>\u673a\u7406\u7814\u7a76<\/strong><strong>\uff1b <\/strong><strong>\u00a9 2025 Science <\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u8be5\u7814\u7a76\u63ed\u793a\u4e86\u70ef\u70c3\u8f6c\u5316\u4e3a\u77ac\u60011,2-\u53cc\u567b\u84bd\u9393\u4e2d\u95f4\u4f53\u7684\u8fc7\u7a0b\uff0c\u8be5\u4e2d\u95f4\u4f53\u901a\u8fc7\u7a33\u5b9a\u4f5c\u7528\u6253\u7834\u6559\u79d1\u4e66\u5f0f\u7684E2\u7acb\u4f53\u9009\u62e9\u6027\u89c4\u5219\uff0c\u5b9e\u73b0Z\u9009\u62e9\u6027\u6d88\u9664\u53cd\u5e94\u3002\u7814\u7a76\u53d1\u73b0\u6210\u5bf9\u7535\u89e3\u65e2\u80fd\u9009\u62e9\u6027\u751f\u6210\u5fc5\u9700\u7684\u53cc\u567b\u84bd\u9393\u4e2d\u95f4\u4f53\uff0c\u53c8\u80fd\u9a71\u52a8\u5176\u539f\u4f4d\u5feb\u901f\u6d88\u9664\uff0c\u6210\u4e3a\u5b9e\u73b0\u8be5\u76ee\u6807\u7684\u5173\u952e\u7b56\u7565\u3002\u7531\u6b64\u83b7\u5f97\u7684Z\u5f0f\u951a\u5b9a\u4f53\uff0c\u901a\u8fc7\u7a33\u5065\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\uff0c\u4f7f\u5ec9\u4ef7\u539f\u6599\u5f97\u4ee5\u8f6c\u5316\u4e3a\u591a\u79cd\u76ee\u6807Z-\u70ef\u70c3\u5316\u5408\u7269\u3002\u6587\u7ae0\u4ee5\u201c<strong>Stereo-reversed E2 unlocks Z-selective C<\/strong><strong>&#8211;<\/strong><strong>H functionalization<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a<strong>Science<\/strong>\u4e0a\uff0c\u5f15\u8d77\u4e86\u76f8\u5173\u9886\u57df\u7814\u7a76\u4eba\u5458\u70ed\u8bae\u3002<strong><\/strong><\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"393\" height=\"212\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/09\/\u56fe\u72476.png\" alt=\"\" class=\"wp-image-268524\" style=\"width:845px;height:auto\" \/><\/figure><\/div>\n\n\n<p class=\"has-text-align-center\"><strong>\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u8be5\u7814\u7a76\u56e2\u961f\u5b8c\u6210\u7684\u8fd9\u9879\u7814\u7a76\u4e3a\u957f\u671f\u5b58\u5728\u7684\u96be\u9898\u63d0\u4f9b\u4e86\u89e3\u51b3\u65b9\u6848\uff1a\u5b9e\u73b0\u672a\u6d3b\u5316\u70ef\u70c3\u7684Z-\u9009\u62e9\u6027C-H\u5b98\u80fd\u56e2\u5316\u3002\u8be5\u8f6c\u5316\u901a\u8fc7\u77ac\u6001\u53cc\u567b\u84bd\u9393\u4e2d\u95f4\u4f53\u7684\u610f\u5916Z-\u9009\u62e9\u6027\u8131\u79bb\u53cd\u5e94\u5f97\u4ee5\u5b9e\u73b0\uff0c\u8be5\u4e2d\u95f4\u4f53\u901a\u8fc7\u7a33\u5b9a\u4f5c\u7528\u6253\u7834\u4e86\u6559\u79d1\u4e66\u4e2d\u5173\u4e8eE2\u53cd\u5e94\u7acb\u4f53\u9009\u62e9\u6027\u7684\u9884\u6d4b\u3002\u7814\u7a76\u4eba\u5458\u9610\u660e\u4e86\u5982\u4f55\u5c06\u7535\u5316\u5b66\u7535\u6c60\u8bbe\u8ba1\u4f5c\u4e3a\u5173\u952e\u53c2\u6570\uff0c\u65e2\u80fd\u9009\u62e9\u6027\u751f\u6210\u5fc5\u9700\u7684\u53cc\u567b\u84bd\u9393\u4e8c\u6838\u53d7\u4f53\uff0c\u53c8\u80fd\u9a71\u52a8\u5176\u539f\u4f4d\u5feb\u901f\u8131\u53bb\u4ee5\u89c4\u907f\u5176\u56fa\u6709\u4e0d\u7a33\u5b9a\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u4e3aZ-\u70ef\u70c3\u5408\u6210\u63d0\u4f9b\u4e86\u5b9e\u7528\u65b9\u6cd5\uff0c\u66f4\u63ed\u793a\u4e86\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u5982\u4f55\u5728\u8131\u53bb\u53cd\u5e94\u4e2d\u8d85\u8d8a\u56fa\u6709\u7acb\u4f53\u9009\u62e9\u6027\uff0c\u672a\u6765\u6709\u7740\u5e7f\u9614\u7684\u7814\u7a76\u7a7a\u95f4\u3002<\/p>\n\n\n\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1aStereo-reversed E2 unlocks Z-selective C-H functionalization\uff0c2<\/strong><strong>025<\/strong><strong>\uff0c<\/strong><strong>https:\/\/doi.org\/<\/strong>&nbsp;<strong>10.1126\/science.adv7630\uff09<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u672c\u6587\u7531LWB\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6709\u673a\u5316\u5b66\u65b0\u7a81\u7834\uff1a\u8be5\u7bc7Science\u5b9e\u73b0Z\u9009\u62e9\u6027C-H\u5b98\u80fd\u56e2\u5316 \u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011 C-H\u952e\u7684\u8f6c\u5316\u662f\u6709\u673a\u5408\u6210\u9886\u57df\u957f\u671f\u4ee5\u6765\u7684\u76ee\u6807\u3002\u6570\u5341\u5e74\u7684\u7814\u7a76\u5df2\u5f00\u53d1\u51fa\u591a\u79cd\u673a\u7406\u5404\u5f02\u7684\u7b56&#8230;<\/p>\n","protected":false},"author":38813,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-268518","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/268518"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/38813"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=268518"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/268518\/revisions"}],"predecessor-version":[{"id":268525,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/268518\/revisions\/268525"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=268518"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=268518"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=268518"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}