{"id":267769,"date":"2025-08-04T10:34:23","date_gmt":"2025-08-04T02:34:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=267769"},"modified":"2025-08-04T10:34:24","modified_gmt":"2025-08-04T02:34:24","slug":"%e7%a6%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6%e9%83%91%e4%ba%91%e6%95%99%e6%8e%88-%e5%bc%a0%e4%b9%85%e4%bf%8a%e9%99%a2%e5%a3%ab%ef%bc%9a%e5%be%ae%e7%8e%af%e5%a2%83%e8%b0%83%e6%8e%a7%e7%ad%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=267769","title":{"rendered":"\u798f\u5dde\u5927\u5b66\u90d1\u4e91\u6559\u6388\/\u5f20\u4e45\u4fca\u9662\u58eb\uff1a\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7b56\u7565\u52a0\u901fLi+\u4f20\u5bfc\uff01"},"content":{"rendered":"\n<p><strong>\u4e00\u3001\u5168\u6587\u901f\u89c8\uff1a<\/strong><strong><\/strong><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"553\" height=\"186\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image-5.jpg\" alt=\"\" class=\"wp-image-267771\"\/><\/figure>\n\n\n\n<p>\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u56e0\u5176\u8d85\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u672c\u8d28\u5b89\u5168\u6027\u7684\u4f18\u52bf\uff0c\u5df2\u6210\u4e3a\u50a8\u80fd\u9886\u57df\u7684\u7814\u7a76\u524d\u6cbf\uff08Yun Zheng*, et al., <em>Adv. Funct. Mater.<\/em>, 2025, e11011.; Yun Zheng*, et al., <em>Adv. Mater<\/em>. 2024, 36, 2314120, ESI 1%, \u9ad8\u88ab\u5f15\u8bba\u6587; Yun Zheng*, et al., <em>Adv. Funct. Mater.<\/em>, 2024, 34, 2404427\uff09\u3002\u5728\u4f17\u591a\u7814\u7a76\u4e2d\uff0c\u805a\u919a\u7c7b\u7535\u89e3\u8d28\uff08PEs\uff09\u56e0\u5176\u4f18\u5f02\u7684\u9502\u76d0\u89e3\u79bb\u80fd\u529b\u548c\u4e0e\u9502\u91d1\u5c5e\u7684\u826f\u597d\u754c\u9762\u517c\u5bb9\u6027\uff0c\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\uff08Yun Zheng*, et al., <em>Angew. <\/em><em>Chem. Int. Ed.<\/em>, 2025, e202508857; Yun Zheng*, et al., <em>Angew. Chem. Int. Ed.<\/em>, 2025, e202502728\uff09\u3002\u7136\u800c\uff0c\u4f20\u7edfPEs\u7684\u5173\u952e\u74f6\u9888\u5728\u4e8e\u5176\u56fa\u6709\u7684\u4f4e\u9502\u79bb\u5b50\uff08Li<sup>+<\/sup>\uff09\u7535\u5bfc\u7387\uff0c\u8fd9\u4e3b\u8981\u53d7\u9650\u4e8e\u4ee5\u4e0b\u4e24\u4e2a\u5173\u952e\u56e0\u7d20\uff1a\uff081\uff09Li<sup>+<\/sup>\u4e0e\u9634\u79bb\u5b50\u7684\u5f3a\u7ed3\u5408\u4f5c\u7528\uff0c\u663e\u8457\u964d\u4f4e\u81ea\u7531Li<sup>+<\/sup>\u6d53\u5ea6\uff1b\uff082\uff09Li<sup>+<\/sup>\u4e0e\u805a\u5408\u7269\u94fe\u4e2d\u919a\u6c27\u57fa\u56e2\uff08EO\uff09\u7684\u5f3a\u914d\u4f4d\u4f5c\u7528\uff0c\u963b\u788dLi<sup>+<\/sup>\u7684\u9ad8\u6548\u8fc1\u79fb\u3002<\/p>\n\n\n\n<p>\u8fd1\u65e5\uff0c\u798f\u5dde\u5927\u5b66<strong><u>\u90d1\u4e91\u6559\u6388\u3001\u5f20\u4e45\u4fca\u9662\u58eb<\/u><\/strong>\u56e2\u961f\u63d0\u51fa\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7b56\u7565\uff0c\u901a\u8fc7\u5728PEs\u4e2d\u5f15\u5165\u5f31\u8def\u6613\u65af\u9178\u6027\u7684\u9517\u79bb\u5b50\uff08Ge<sup>4+<\/sup>\uff09\u4f4d\u70b9\uff0c\u6210\u529f\u6784\u5efa\u4e86\u9ad8\u6027\u80fd\u5fae\u73af\u5883\u8c03\u63a7\u805a\u919a\u7c7b\u805a\u5408\u7269\u7535\u89e3\u8d28\u3002\u8be5\u7b56\u7565\u5229\u7528Ge<sup>4+<\/sup>\u7684\u53cc\u91cd\u4f5c\u7528\uff1a\uff081\uff09<a>\u901a\u8fc7\u5bf9<\/a>EO\u7684\u5438\u7535\u5b50\u6548\u5e94\uff0c\u524a\u5f31Li\u207a\u2212\u805a\u5408\u7269\u76f8\u4e92\u4f5c\u7528\uff1b\uff082\uff09\u951a\u5b9a\u9634\u79bb\u5b50\uff08TFSI\u207b\uff09\u4ee5\u91ca\u653e\u66f4\u591a\u6e38\u79bbLi<sup>+<\/sup>\u3002\u6b64\u5916\uff0cGe<sup>4+<\/sup>\u57fa\u6750\u6599\uff08Li<sub>10<\/sub>GeP<sub>2<\/sub>S<sub>12<\/sub>\uff09\u7684\u81ea\u8eab\u79bb\u5b50\u901a\u9053\u989d\u5916\u63d0\u4f9b\u4e86Li<sup>+<\/sup>\u4f20\u8f93\u8def\u5f84\u3002\u5bf9\u5e94\u9502\u91d1\u5c5e\u7535\u6c60\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5feb\u5145\u6027\u80fd\u548c\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u5177\u4f53\u770b\u6765\uff0c\u6240\u88c5\u914d\u7684Li||Li\u5bf9\u79f0\u7535\u6c60\u5c55\u73b0\u51fa\u8d85\u8fc72000\u5c0f\u65f6\u7684\u8d85\u957f\u7a33\u5b9a\u5faa\u73af\uff1bLi||LiFePO<sub>4<\/sub>\u5168\u7535\u6c60\u57285C\u9ad8\u500d\u7387\u4e0b\u5faa\u73af2190\u6b21\u540e\u4ecd\u4fdd\u630192.1%\u7684\u5bb9\u91cf\u4e0e\u8fd1100%\u7684\u5e93\u4f26\u6548\u7387\u3002\u8fd9\u9879\u5de5\u4f5c\u901a\u8fc7\u5fae\u73af\u5883\u8c03\u63a7\u673a\u5236\u4e3a\u9ad8\u6027\u80fd\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u805a\u5408\u7269\u7535\u89e3\u8d28\u8bbe\u8ba1\u5f00\u8f9f\u4e86\u65b0\u7684\u601d\u8def\u4e0e\u65b9\u5411\u3002<\/p>\n\n\n\n<p><strong>\u4e8c\u3001\u6838\u5fc3\u5185\u5bb9\u8868\u8ff0\u90e8\u5206<\/strong><\/p>\n\n\n\n<p><strong><u>\uff08<\/u><\/strong><strong><u>1<\/u><\/strong><strong><u>\uff09\u65b0\u578b<\/u><\/strong><strong><u>\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d<\/u><\/strong><strong><u>\u7535\u89e3\u8d28\u8bbe\u8ba1<\/u><\/strong>\uff1a\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u533a\u522b\u4e8e\u4f20\u7edf\u805a\u5408\u7269\u7ed3\u6784\u6539\u6027\u7684\u65b0\u578b\u7b56\u7565\u2014\u2014\u901a\u8fc7\u5728\u805a\u919a\u7535\u89e3\u8d28\u4e2d\u5f15\u5165Ge<sup>4+<\/sup>\u4f4d\u70b9\uff0c\u8c03\u63a7\u805a\u5408\u7269\u4e3b\u94fe\u5468\u56f4\u7684\u5c40\u90e8\u5fae\u73af\u5883\u3002\u8be5\u65b9\u6cd5\u4e0d\u4f9d\u8d56\u590d\u6742\u7684\u805a\u5408\u7269\u5206\u5b50\u7ed3\u6784\u8bbe\u8ba1\uff0c\u5177\u5907\u5de5\u827a\u7b80\u4fbf\u3001\u9002\u5e94\u6027\u5f3a\u7b49\u4f18\u52bf\uff0c\u4e3a\u7a81\u7834\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\u4e2dLi\u207a\u8fc1\u79fb\u80fd\u5792\u95ee\u9898\u63d0\u4f9b\u4e86\u65b0\u7684\u89e3\u51b3\u8def\u5f84\u3002<\/p>\n\n\n\n<p><strong><u>\uff08<\/u><\/strong><strong><u>2<\/u><\/strong><strong><u>\uff09\u65b0\u578b<\/u><\/strong><strong><u>Li<sup>+<\/sup><\/u><\/strong><strong><u>\u4f20\u8f93\u673a\u5236\u7684\u534f\u540c\u589e\u5f3a\u6548\u5e94<\/u><\/strong>\uff1a\u901a\u8fc7\u7ed3\u5408\u591a\u79cd\u8868\u5f81\u6280\u672f\u4e0e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u6a21\u62df\u8ba1\u7b97\u7b49\u7814\u7a76\u624b\u6bb5\uff0c\u7cfb\u7edf\u63ed\u793a\u4e86\u5fae\u73af\u5883\u8c03\u63a7\u7684\u63d0\u5347\u4e09\u91cd\u534f\u540c\u673a\u5236\uff1a\u4e00\u65b9\u9762\uff0c\u5b83\u524a\u5f31Li\u207a\u4e0e\u919a\u6c27\u4e4b\u95f4\u7684\u914d\u4f4d\u4f5c\u7528\uff0c\u964d\u4f4e\u8fc1\u79fb\u52bf\u5792\uff1b\u53e6\u4e00\u65b9\u9762\uff0c<a>\u951a\u5b9a<\/a>TFSI\u207b\u9634\u79bb\u5b50\uff0c\u63d0\u9ad8\u81ea\u7531Li\u207a\u6d53\u5ea6\uff1b\u6b64\u5916\uff0c\u5f15\u5165Ge<sup>4+<\/sup>\u57fa\u6750\u6599\u7684\u81ea\u8eab\u79bb\u5b50\u901a\u9053\uff0c\u4e3aLi<sup>+<\/sup>\u8fc1\u79fb\u63d0\u4f9b\u989d\u5916\u8def\u5f84\u3002\u8fd9\u4e00\u534f\u540c\u673a\u5236\u4e0d\u4ec5\u63d0\u5347\u4e86\u805a\u5408\u7269\u4f53\u7cfb\u5728\u5ba4\u6e29\u4e0b\u7684\u79bb\u5b50\u5bfc\u7535\u7387\uff081.83 mS cm<sup>\u22121<\/sup>\uff09\u4e0e\u9ad8Li<sup>+<\/sup>\u8fc1\u79fb\u6570\uff080.8\uff09\uff0c\u540c\u65f6\u5b9e\u73b0\u4e86\u5bf9\u754c\u9762\u7a33\u5b9a\u6027\u548c\u7535\u6c60\u957f\u671f\u5faa\u73af\u6027\u80fd\u7684\u6709\u6548\u4f18\u5316\u3002<\/p>\n\n\n\n<p><strong><u>\uff08<\/u><\/strong><strong><u>3<\/u><\/strong><strong><u>\uff09\u957f\u5bff\u547d\u3001\u9ad8\u500d\u7387\u56fa\u6001\u7535\u6c60\u6027\u80fd<\/u><\/strong>\uff1a\u6240\u5f00\u53d1\u7684\u5fae\u73af\u5883\u8c03\u63a7\u805a\u919a\u7535\u89e3\u8d28\uff08MPPE\uff09\u5728Li||Li\u5bf9\u79f0\u7535\u6c60\u4e2d\u5c55\u73b0\u51fa\u8d85\u8fc72000\u5c0f\u65f6\u7684\u7a33\u5b9a\u5faa\u73af\uff1b\u5728Li||LiFePO<sub>4<\/sub>\u5168\u7535\u6c60\u4e2d\uff0c5C\u9ad8\u500d\u7387\u4e0b\u5faa\u73af2190\u6b21\u540e\u4ecd\u4fdd\u630192.1%\u7684\u5bb9\u91cf\u4e0e\u8fd1100%\u7684\u5e93\u4f26\u6548\u7387\u3002\u8be5\u6210\u679c\u9a8c\u8bc1\u4e86\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7b56\u7565\u5728\u5b9e\u73b0\u805a\u5408\u7269\u7535\u89e3\u8d28\u5feb\u79bb\u5b50\u4f20\u8f93\u4e0e\u754c\u9762\u7a33\u5b9a\u6027\u65b9\u9762\u7684\u663e\u8457\u6548\u679c\uff0c\u4e3a\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u9ad8\u500d\u7387\u4e14\u957f\u5bff\u547d\u7684\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u53d1\u5c55\u63d0\u4f9b\u4e86\u65b0\u65b9\u5411\u3002<\/p>\n\n\n\n<p><strong>\u4e09\uff0e\u4e3b\u8981\u5185\u5bb9<\/strong>\uff1a<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"486\" height=\"359\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image-4.gif\" alt=\"\" class=\"wp-image-267775\"\/><\/figure>\n\n\n\n<p><strong>\u56fe<\/strong><strong>1. <\/strong><strong>\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7b56\u7565\u7684\u8bbe\u8ba1\u539f\u5219\u548c\u9502\u79bb\u5b50\u4f20\u8f93\u673a\u5236<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u4f5c\u8005\u5de7\u5999\u5f15\u5165\u5177\u6709\u5f31\u8def\u6613\u65af\u9178\u6027\u7684Ge<sup>4+<\/sup>\u4f4d\u70b9\uff0c\u4ee5\u8c03\u63a7PDOL\uff08\u805a1,3-\u4e8c\u6c27\u620a\u73af\uff09\u4e3b\u94fe\u5468\u56f4\u7684\u5c40\u90e8\u5fae\u73af\u5883\u3002\u5177\u4f53\u800c\u8a00\uff0cGe<sup>4+<\/sup>\u4e00\u65b9\u9762\u901a\u8fc7\u5438\u7535\u5b50\u4f5c\u7528\u524a\u5f31Li\u207a\u4e0eEO\u4e4b\u95f4\u7684\u914d\u4f4d\uff0c\u53e6\u4e00\u65b9\u9762\u53ef\u951a\u5b9aTFSI\u207b\u9634\u79bb\u5b50\uff0c\u91ca\u653e\u66f4\u591a\u6e38\u79bbLi\u207a\uff1b\u540c\u65f6\uff0c\u5176\u81ea\u8eab\u79bb\u5b50\u901a\u9053\u4e3aLi\u207a\u8fc1\u79fb\u63d0\u4f9b\u989d\u5916\u8def\u5f84\u3002\u4e0a\u8ff0\u4e09\u91cd\u534f\u540c\u6548\u5e94\u663e\u8457\u63d0\u5347\u4e86\u805a\u919a\u7535\u89e3\u8d28\u4e2d\u7684Li<sup>+<\/sup>\u5bfc\u7535\u6027\uff0c\u6700\u7ec8\u5b9e\u73b0\u4e86\u517c\u5177\u957f\u5bff\u547d\u4e0e\u9ad8\u500d\u7387\u6027\u80fd\u7684\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"518\" height=\"567\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image.gif\" alt=\"\" class=\"wp-image-267770\"\/><\/figure>\n\n\n\n<p><strong>\u56fe<\/strong><strong>2. <\/strong><strong>\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7684\u805a\u919a\u7c7b\u7535\u89e3\u8d28\u5316\u5b66\u73af\u5883\u8868\u5f81\u548c\u6a21\u62df<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u4f5c\u8005\u901a\u8fc7\u8868\u9762\u9759\u7535\u52bf\u6a21\u62df\u8868\u660e\uff0c\u5728PDOL\u57fa\u7535\u89e3\u8d28\u4e2d\u5f15\u5165Ge<sup>4+<\/sup>\u57fa\u6750\u6599\u53ef\u6709\u6548\u524a\u5f31EO\u7684\u7535\u5b50\u4e91\u5bc6\u5ea6\u3002\u8fdb\u4e00\u6b65\u7ed3\u5408\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff08FT-IR\uff09\u3001\u62c9\u66fc\u5149\u8c31\uff08Raman\uff09\u53ca\u540c\u6b65\u8f90\u5c04\u6280\u672f\u5bf9MPPE\u8fdb\u884c\u6df1\u5165\u8868\u5f81\uff0c\u8bc1\u5b9e\u4e86Ge<sup>4+<\/sup>\u4e0ePDOL\u4e2dEO\u4e4b\u95f4\u5b58\u5728\u5438\u7535\u5b50\u6548\u5e94\u3002\u5177\u4f53\u800c\u8a00\uff0cGe<sup>4+<\/sup>\u4f4d\u70b9\u4e00\u65b9\u9762\u524a\u5f31\u4e86Li\u207a\u4e0e\u919a\u6c27\u4e4b\u95f4\u7684\u5f3a\u914d\u4f4d\uff0c\u53e6\u4e00\u65b9\u9762\u4e0eEO\u5f62\u6210\u4e86\u5f31\u914d\u4f4d\u7ed3\u6784\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u5c40\u90e8\u5fae\u73af\u5883\u7684\u6709\u6548\u8c03\u63a7\u3002\u8be5\u7814\u7a76\u4ece\u5206\u5b50\u6a21\u62df\u4e0e\u5b9e\u9a8c\u8868\u5f81\u4e24\u65b9\u9762\uff0c\u4e3a\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7b56\u7565\u63d0\u4f9b\u4e86\u575a\u5b9e\u7684\u7406\u8bba\u4e0e\u5b9e\u9a8c\u8bc1\u636e\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"554\" height=\"553\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image-1.gif\" alt=\"\" class=\"wp-image-267772\"\/><\/figure>\n\n\n\n<p><strong>\u56fe<\/strong><strong>3. <\/strong><strong>\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7b56\u7565\u7684<\/strong><strong>MPPE<\/strong><strong>\u7684\u57fa\u672c\u7535\u5316\u5b66\u6027\u80fd\u4ee5\u53ca\u7406\u8bba\u8ba1\u7b97<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u4f5c\u8005\u8fdb\u4e00\u6b65\u5bf9MPPE\u8fdb\u884c\u4e86\u57fa\u672c\u7684\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u3002\u62c9\u66fc\u7ed3\u679c\u8868\u660e\uff0c\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7b56\u7565\u8bbe\u8ba1\u5f31\u8def\u6613\u65af\u9178\u6027\u7684Ge<sup>4+<\/sup>\u4f4d\u70b9\u4fc3\u8fdb\u4e86TFSI\u207b\u9634\u79bb\u5b50\u89e3\u79bb\uff0c\u63d0\u9ad8\u81ea\u7531Li\u207a\u6d53\u5ea6\uff0c\u4ece\u800c\u4f7fMPPE\u5c55\u73b0\u51fa\u4f18\u5f02\u7684Li<sup>+<\/sup>\u5bfc\u7535\u6027\uff0c\u5ba4\u6e29\u4e0b\u79bb\u5b50\u5bfc\u7535\u7387\u8fbe\u52301.83 mS cm<sup>\u22121<\/sup>\uff0cLi<sup>+<\/sup>\u8fc1\u79fb\u6570\u9ad8\u8fbe0.8\u3002DFT\u8ba1\u7b97\u4e86MPPE\u4e2dLi<sup>+<\/sup>\u5728\u76f8\u90bbEO\u4e4b\u95f4\u7684\u8fc1\u79fb\u80fd\u4e5f\u66f4\u4f4e\uff08\u76f8\u8f83\u4e8e\u5bf9\u6bd4\u6837PPE\uff09\uff0c\u8be5\u7814\u7a76\u4ece\u52a8\u529b\u5b66\u6a21\u62df\u7684\u89d2\u5ea6\u4e3aLi<sup>+<\/sup>\u4f20\u8f93\u7684\u5b9e\u9a8c\u89c2\u5bdf\u7ed3\u679c\u63d0\u4f9b\u4e86\u7406\u8bba\u4f9d\u636e\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"575\" height=\"548\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image-2.gif\" alt=\"\" class=\"wp-image-267773\"\/><\/figure>\n\n\n\n<p>\u56fe4. Li|MPPE|Li\u5bf9\u79f0\u7535\u6c60\u548cLi|MPPE|Cu\u534a\u7535\u6c60\u572825 \u2103\u4e0b\u7684\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u3002<\/p>\n\n\n\n<p>\u4e3a\u4e86\u8bc4\u4f30\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7684MPPE\u4e0e\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u754c\u9762\u7a33\u5b9a\u6027\uff0c\u4f5c\u8005\u7ec4\u88c5\u4e86Li|MPPE|Li\u5bf9\u79f0\u7535\u6c60\uff0c\u57280.2 mA cm<sup>\u22122<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5b9e\u73b0\u8d852000\u5c0f\u65f6\u7a33\u5b9a\u5faa\u73af\uff0c\u8fdb\u4e00\u6b65\uff0cLi|MPPE|Cu\u534a\u7535\u6c60\u5faa\u73af150\u6b21\u540e\u5e73\u5747\u5e93\u4f26\u6548\u7387\u8fbe97.8%\u3002\u8fd9\u5f97\u76ca\u4e8eMPPE\u901a\u8fc7\u4f18\u5316\u5c40\u90e8\u914d\u4f4d\uff0c\u5b9e\u73b0\u5747\u5300\u79bb\u5b50\u901a\u91cf\uff0c\u6709\u6548\u7f13\u89e3\u6d53\u5dee\u6781\u5316\uff0c\u4ece\u800c\u6709\u6548\u63d0\u5347\u4e86\u9502\u6c89\u79ef\/\u5265\u79bb\u8fc7\u7a0b\u4e2d\u7684\u53ef\u9006\u6027\u4e0e\u754c\u9762\u7a33\u5b9a\u6027\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"554\" height=\"511\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image-3.gif\" alt=\"\" class=\"wp-image-267774\"\/><\/figure>\n\n\n\n<p><strong>\u56fe<\/strong><strong>5. <\/strong><strong>\u56fa\u6001\u7535\u89e3\u8d28<\/strong><strong>\/<\/strong><strong>\u9502\u91d1\u5c5e\u754c\u9762\u9502\u679d\u6676\u884c\u4e3a\u53ca\u5f62\u6210\u673a\u5236\u5206\u6790<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u4e3a\u4e86\u63a2\u7a76\u4e86\u9884\u9502\u5316\u8bbe\u8ba1\u5728\u56fa\u6001\u7535\u6c60\u4e2d\u7684\u4f5c\u7528\uff0c\u4ee5\u4e86\u89e3\u9502\u679d\u6676\u751f\u957f\u7684\u60c5\u51b5\uff0c\u5e76\u9610\u660e\u957f\u671f\u7a33\u5b9a\u6027\u7684\u6f5c\u5728\u673a\u5236\u3002\u4f5c\u8005\u5bf9\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5f62\u6001\u7279\u5f81\u548c\u7ed3\u6784\u6f14\u53d8\u8fdb\u884c\u4e86\u8be6\u7ec6\u7814\u7a76\u3002\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u548c\u539f\u4f4d\u5149\u5b66\u663e\u5fae\u955c\u89c2\u5bdf\u8bc1\u5b9e\uff0cMPPE\u80fd\u5f15\u5bfc\u9502\u91d1\u5c5e\u5f62\u6210\u81f4\u5bc6\u3001\u65e0\u679d\u6676\u6c89\u79ef\u5f62\u8c8c\u3002COMSOL\u591a\u7269\u7406\u573a\u6a21\u62df\u8fdb\u4e00\u6b65\u63ed\u793a\uff0cMPPE\u53ef\u663e\u8457\u6291\u5236\u5c40\u90e8\u7535\u6d41\u805a\u96c6\uff0c\u5b9e\u73b0\u5747\u5300\u7684\u9502\u6c89\u79ef\/\u5265\u79bb\u8fc7\u7a0b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"546\" height=\"491\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image-5.gif\" alt=\"\" class=\"wp-image-267776\"\/><\/figure>\n\n\n\n<p><strong>\u56fe<\/strong><strong>6. <\/strong><strong>\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7684<\/strong><strong>MPPE<\/strong><strong>\u5728<\/strong><strong>Li||LFP<\/strong><strong>\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u500d\u7387\u4e0e\u5faa\u73af\u6027\u80fd<\/strong><strong><\/strong><\/p>\n\n\n\n<p>MPPE\u5728Li||LFP\u5168\u7535\u6c60\u4e2d\u5c55\u73b0\u51fa\u5353\u8d8a\u7684\u500d\u7387\u6027\u80fd\uff0c\u57281C\u30012C\u548c5C\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5747\u80fd\u4fdd\u6301\u7a33\u5b9a\u7684\u9ad8\u6bd4\u5bb9\u91cf\u3002\u7279\u522b\u662f\u57285C\u9ad8\u500d\u7387\u4e0b\u5faa\u73af2190\u6b21\u540e\u4ecd\u4fdd\u630192.1%\u7684\u5bb9\u91cf\u4e0e\u8fd1100%\u7684\u5e93\u4f26\u6548\u7387\u3002\u4e3a\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u9ad8\u500d\u7387\u4e14\u957f\u5bff\u547d\u7684\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u53d1\u5c55\u63d0\u4f9b\u4e86\u65b0\u65b9\u5411\u3002<\/p>\n\n\n\n<p><strong>\u56db\u3001\u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/p>\n\n\n\n<p>\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u201c\u5fae\u73af\u5883\u8c03\u63a7\u201d\u7b56\u7565\uff0c\u901a\u8fc7\u5f15\u5165\u9517\u79bb\u5b50\uff08Ge<sup>4+<\/sup>\uff09\u4f4d\u70b9\uff0c\u8c03\u63a7\u805a\u919a\u7c7b\u7535\u89e3\u8d28\uff08PEs\uff09\u4e2d\u7684\u5c40\u90e8\u5fae\u73af\u5883\uff0c\u4ece\u800c\u6709\u6548\u63d0\u5347Li<sup>+<\/sup>\u5bfc\u7535\u6027\u3002\u8be5\u7b56\u7565\u901a\u8fc7\u524a\u5f31Li\u207a\u4e0e\u919a\u6c27\u4e4b\u95f4\u7684\u5f3a\u914d\u4f4d\u4f5c\u7528\uff0c\u589e\u5f3a\u9502\u76d0\u89e3\u79bb\u5e76\u91ca\u653e\u66f4\u591a\u81ea\u7531Li\u207a\uff0c\u5b9e\u73b0\u4e86\u663e\u8457\u63d0\u5347\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff081.83 mS cm<sup>\u22121<\/sup>\uff09\u4e0e\u9ad8Li<sup>+<\/sup>\u8fc1\u79fb\u6570\uff080.8\uff09\u3002\u6240\u5f00\u53d1\u7684MPPE\u5c55\u73b0\u4e86\u5353\u8d8a\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5c24\u5176\u662f\u5728Li||Li\u5bf9\u79f0\u7535\u6c60\u548cLi||LiFePO<sub>4<\/sub>\u5168\u7535\u6c60\u4e2d\u7684\u5e94\u7528\uff0c\u57285C\u500d\u7387\u4e0b\uff0cLi||LiFePO<sub>4<\/sub>\u5168\u7535\u6c60\u5faa\u73af2190\u6b21\u540e\uff0c\u4ecd\u4fdd\u630192.1%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u53ca\u63a5\u8fd1100%\u7684\u5e93\u4f26\u6548\u7387\u3002\u8be5\u7814\u7a76\u4e3a\u9ad8\u6027\u80fd\u805a\u5408\u7269\u7535\u89e3\u8d28\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\uff0c\u5bf9\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u957f\u671f\u7a33\u5b9a\u6027\u4e0e\u9ad8\u500d\u7387\u6027\u80fd\u7684\u63d0\u5347\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n\n\n\n<p><strong>\u4e94\u3001\u6587\u732e\u8be6\u60c5<\/strong><strong><\/strong><\/p>\n\n\n\n<p><strong>\u6587\u7ae0\u4fe1\u606f\uff1a<\/strong><a>H. Wang, L. Qian<\/a>, Y. Zheng*, S. Duan, B. Qin, Z. Liu, Z. Li, Q. Ma, Y. Jiang, W. Yan*, J. Zhang*. \u201cMicroenvironment Regulation Unlocks High Li<sup>+<\/sup> Conduction in Polyether Electrolytes for High-Performance Quasi-Solid-State Batteries\u201d, <strong><em>Adv. <\/em><\/strong><strong><em>Mater.<\/em><\/strong>, 2025, e10197.<\/p>\n\n\n\n<p><strong>\u6587\u7ae0\u94fe\u63a5<\/strong><strong>\uff1a<\/strong>https:\/\/doi.org\/10.1002\/adma.202510197<\/p>\n\n\n\n<p><strong>\u516d\u3001\u4f5c\u8005\u7b80\u4ecb<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u7b2c\u4e00\u4f5c\u8005\uff1a<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"113\" height=\"163\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image-6.gif\" alt=\"\" class=\"wp-image-267777\"\/><\/figure>\n\n\n\n<p>\u6c6a\u9e3f\u9065\uff0c\u798f\u5dde\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\/\u65b0\u80fd\u6e90\u6750\u6599\u4e0e\u5de5\u7a0b\u7814\u7a76\u96622022\u7ea7\u7855\u58eb\u751f\uff0c\u5e08\u4ece\u5f20\u4e45\u4fca\u9662\u58eb\u548c\u90d1\u4e91\u6559\u6388\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u56fa\u6001\/\u51c6\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\uff0c\u5171\u53d1\u8868SCI\u8bba\u65875\u7bc7\uff0c\u5176\u4e2d\u4ee5\u7b2c\u4e00\u4f5c\u8005\u5728<em>Adv. Mater.<\/em>\u3001<em>eTransportation<\/em>\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u65872\u7bc7\u3002<\/p>\n\n\n\n<p>\u901a\u8baf\u4f5c\u8005\uff1a<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"127\" height=\"163\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image-1.jpeg\" alt=\"\" class=\"wp-image-267779\"\/><\/figure>\n\n\n\n<p>\u90d1\u4e91\u6559\u6388\u7b80\u4ecb\uff1a\u90d1\u4e91\uff0c\u798f\u5dde\u5927\u5b66\u6559\u6388\u3001\u535a\u5bfc\uff0c\u5165\u9009\u56fd\u5bb6\u6559\u80b2\u90e8\u6d77\u5916\u5f15\u624d\u4e13\u9879\uff0c\u798f\u5efa\u7701\u5f15\u624d\u201c\u767e\u4eba\u8ba1\u5212\u201d\u3001\u798f\u5efa\u7701\u201c\u95fd\u6c5f\u5b66\u8005\u201d\u7279\u8058\u6559\u6388\uff0c2024\u5a01\u7acb\u4e2d\u56fd\u5f00\u653e\u79d1\u5b66\u9ad8\u8d21\u732e\u4f5c\u8005\uff08Wiley\uff09\uff0c2024\u5168\u7403\u524d2%\u9876\u5c16\u79d1\u5b66\u5bb6\uff08Elsevier\/Stanford\uff09\uff0c2024\u5e74\u5ea6\u798f\u5dde\u5927\u5b66\u9752\u5e74\u4e94\u56db\u5956\u7ae0\uff08\u4e2a\u4eba\uff09\u3002\u6e05\u534e\u5927\u5b66\u535a\u58eb\uff08\u5bfc\u5e08\uff1a\u5f20\u4e45\u4fca \u9662\u58eb\uff09\uff0c\u6ed1\u94c1\u5362\u5927\u5b66\u535a\u540e\uff08\u5bfc\u5e08\uff1a\u9648\u5fe0\u4f1f \u9662\u58eb\uff09\u3002\u73b0\u5c31\u804c\u4e8e\u798f\u5dde\u5927\u5b66\u6750\u6599\u5b66\u9662\uff0c\u62c5\u4efb\u65b0\u80fd\u6e90\u6750\u6599\u4e0e\u5de5\u7a0b\u7814\u7a76\u9662\uff08\u5f20\u4e45\u4fca\u9662\u58eb\u56e2\u961f\uff09\u515a\u652f\u90e8\u4e66\u8bb0\u3002\u957f\u671f\u4ece\u4e8b\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\uff08\u65b0\u578b\u67d4\u6027\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\uff09\u7814\u7a76\uff0c\u5171\u53d1\u8868SCI\u8bba\u6587100\u591a\u7bc7\uff0c\u5176\u4e2d\u4ee5\u7b2c\u4e00\u4f5c\u8005\u6216\u901a\u8baf\u4f5c\u8005\u5728CSR (2\u7bc7)\u3001EER\u3001PMS\u3001PNAS\u3001Joule\u3001Angew. (2\u7bc7)\u3001AM (5\u7bc7)\u3001AEM (3\u7bc7)\u3001AFM (2\u7bc7)\u3001ACB\u3001CCR\u7b49\u671f\u520a\u4e0a\u53d1\u8868\u79d1\u7814\u8bba\u658750\u4f59\u7bc7\uff0c\u5305\u62ec10\u4f59\u7bc7ESI\u9ad8\u88ab\u5f15\u8bba\u6587\u3001\u70ed\u70b9\u6587\u7ae0\u548c\u5c01\u9762\u6587\u7ae0\u3002\u7533\u8bf7\/\u6388\u6743\u53d1\u660e\u4e13\u522920\u4f59\u9879\uff0c\u4ee5\u7b2c\u4e00\u4f5c\u8005\u53d1\u8868\u5168\u82f1\u6587\u5b66\u672f\u4e13\u84571\u672c\uff08CRC Press\uff0c2019\uff09\u3001\u4e2d\u6587\u5b66\u672f\u4e13\u84571\u672c\uff08\u6e05\u534e\u5927\u5b66\u51fa\u7248\u793e\uff0c2024\uff09\uff0c\u4e3b\u6301\/\u53c2\u4e0e\u56fd\u5bb6\u7ea7\u548c\u7701\u7ea7\u79d1\u7814\u9879\u76ee20\u4f59\u9879\u3002\u53d7\u9080\u62c5\u4efb\u56fd\u9645\u7535\u5316\u5b66\u80fd\u6e90\u79d1\u5b66\u9662\uff08IAOEES\uff09\u7406\u4e8b\uff0cRenewables\u3001Advanced Powder Materials\u3001Carbon Neutrality\u3001Frontiers in Energy\u7b49\u9886\u57df\u77e5\u540d\u671f\u520a\u9752\u5e74\u7f16\u59d4\u6216\u5ba2\u5ea7\u7f16\u8f91\u3002\u4e2a\u4eba\u90ae\u7bb1\uff1a<a href=\"mailto:yunzheng@fzu.edu.cn\">yunzheng@fzu.edu.cn<\/a><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"113\" height=\"146\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/08\/image.jpeg\" alt=\"\" class=\"wp-image-267778\"\/><\/figure>\n\n\n\n<p>\u5f20\u4e45\u4fca\u6559\u6388\u7b80\u4ecb\uff1a\u4e2d\u56fd\u5de5\u7a0b\u9662\u5916\u7c4d\u9662\u58eb\u3001\u52a0\u62ff\u5927\u7687\u5bb6\u79d1\u5b66\u9662\u9662\u58eb\u3001\u52a0\u62ff\u5927\u5de5\u7a0b\u9662\u9662\u58eb\u3001\u52a0\u62ff\u5927\u5de5\u7a0b\u7814\u7a76\u9662\u9662\u58eb\u3001\u4e2d\u56fd\u5316\u5b66\u4f1a\u4f1a\u58eb\u3001\u56fd\u9645\u7535\u5316\u5b66\u5b66\u4f1a\u4f1a\u58eb\u3001\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u58eb\u3001\u56fd\u9645\u5148\u8fdb\u6750\u6599\u534f\u4f1a\u4f1a\u58eb\u3001\u56fd\u9645\u7535\u5316\u5b66\u80fd\u6e90\u79d1\u5b66\u9662\uff08IAOEES\uff09\u4e3b\u5e2d\u3001\u4e2d\u56fd\u5185\u71c3\u673a\u5b66\u4f1a\u5e38\u52a1\u7406\u4e8b\u517c\u71c3\u6599\u7535\u6c60\u53d1\u52a8\u673a\u5206\u4f1a\u4e3b\u4efb\u59d4\u5458\uff0c\u73b0\u4efb\u798f\u5dde\u5927\u5b66\u6559\u6388\u3001\u535a\u5bfc\uff0c\u798f\u5dde\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u9662\u957f\u3001\u798f\u5dde\u5927\u5b66\u65b0\u80fd\u6e90\u6750\u6599\u4e0e\u5de5\u7a0b\u7814\u7a76\u9662\u9662\u957f\u3002\u5f20\u6559\u6388\u957f\u671f\u4ece\u4e8b\u7535\u5316\u5b66\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u6362\u53ca\u5176\u6750\u6599\u7684\u7814\u7a76\u548c\u4ea7\u4e1a\u5316\u5e94\u7528\u5f00\u53d1\uff0c\u5305\u62ec\u71c3\u6599\u7535\u6c60\u3001\u9ad8\u6bd4\u80fd\u4e8c\u6b21\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001CO<sub>2<\/sub>\u7535\u5316\u5b66\u8fd8\u539f\u548c\u6c34\u7535\u89e3\u7b49\u3002\u81f3\u4eca\u5df2\u53d1\u8868\u8bba\u6587\u53ca\u79d1\u6280\u62a5\u544a850\u4f59\u7bc7\uff0c\u7f16\u8457\u4e6630\u672c\uff0c\u4e66\u7ae0\u828251\u7bc7\uff0c\u88ab\u5f15\u752894000\u591a\u6b21\uff08H-Index\u4e3a136\uff09\u3002\u76ee\u524d\u662fSpringer-nature\u300aElectrochemical Energy Reviews\u300bSCI\u671f\u520a\u4e3b\u7f16\u3001CRC Press\u300aElectrochemical Energy Storage and Conversion\u300b\u4e1b\u4e66\u4e3b\u7f16\u3001KeAi Publishing\u300aGreen Energy &amp; Environment\u300bSCI\u671f\u520a\u526f\u4e3b\u7f16\u3001\u4e2d\u56fd\u5de5\u7a0b\u9662\u9662\u520a\u80fd\u6e90\u5206\u520a\u300aFrontiers In Energy\u300b\u671f\u520a\u526f\u4e3b\u7f16\u3001\u4e2d\u56fd\u5316\u5b66\u5316\u5de5\u51fa\u7248\u793e\u5927\u578b\u4e1b\u4e66\u300a\u7535\u5316\u5b66\u80fd\u6e90\u50a8\u5b58\u548c\u8f6c\u6362\u300b\u53ca\u300a\u6c22\u80fd\u6280\u672f\u300b\u4e3b\u7f16\u53ca\u591a\u4e2a\u56fd\u9645\u671f\u520a\u7684\u7f16\u59d4\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u5168\u6587\u901f\u89c8\uff1a \u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u56e0\u5176\u8d85\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u672c\u8d28\u5b89\u5168\u6027\u7684\u4f18\u52bf\uff0c\u5df2\u6210\u4e3a\u50a8\u80fd\u9886\u57df\u7684\u7814\u7a76\u524d\u6cbf\uff08Yun Zheng*, et al., Adv. Funct. Ma&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-267769","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/267769"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=267769"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/267769\/revisions"}],"predecessor-version":[{"id":267780,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/267769\/revisions\/267780"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=267769"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=267769"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=267769"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}