{"id":26775,"date":"2016-07-16T08:10:41","date_gmt":"2016-07-16T00:10:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=26775"},"modified":"2016-07-15T00:36:39","modified_gmt":"2016-07-14T16:36:39","slug":"adv-mater-%e7%83%ad%e5%a1%91%e6%80%a7%e5%bc%b9%e6%80%a7%e4%bd%93%e6%99%ba%e8%83%bd%e6%b8%a9%e6%95%8f%e7%94%b5%e8%a7%a3%e8%b4%a8-%e5%8a%a9%e5%8a%9b%e7%94%b5%e5%8c%96%e5%ad%a6%e5%82%a8%e8%83%bd","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=26775","title":{"rendered":"Adv. Mater. \u70ed\u5851\u6027\u5f39\u6027\u4f53\u667a\u80fd\u6e29\u654f\u7535\u89e3\u8d28 \u52a9\u529b\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u8fc7\u70ed\u4fdd\u62a4"},"content":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb\u3011
\n\u9502\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7b49\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u7684\u80fd\u91cf\u5bc6\u5ea6\u3001\u529f\u7387\u5bc6\u5ea6\u548c\u5faa\u73af\u5bff\u547d\u8fd120\u5e74\u6765\u5df2\u7ecf\u83b7\u5f97\u663e\u8457\u63d0\u9ad8\uff0c\u4f46\u662f\uff0c\u5176\u5b89\u5168\u6027\u95ee\u9898\u5c1a\u672a\u5f97\u5230\u6709\u6548\u89e3\u51b3\u3002\u5728\u5feb\u901f\u5145\u653e\u7535\u548c\u77ed\u8def\u3001\u8fc7\u5145\u7b49\u4e0d\u5f53\u4f7f\u7528\u7684\u60c5\u51b5\u4e0b\uff0c\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u7531\u4e8e\u529f\u7387\u548c\u7535\u6d41\u5bc6\u5ea6\u9ad8\uff0c\u8fc5\u901f\u4ea7\u751f\u5927\u91cf\u7684\u70ed\uff0c\u5668\u4ef6\u5185\u90e8\u6e29\u5ea6\u548c\u538b\u5f3a\u5feb\u901f\u5347\u9ad8\uff0c\u5b58\u5728\u7740\u706b\u751a\u81f3\u7206\u70b8\u7684\u5371\u9669\u3002\u5b89\u5168\u6027\u95ee\u9898\u5df2\u6210\u4e3a\u5236\u7ea6\u5927\u5bb9\u91cf\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u5728\u7535\u52a8\u6c7d\u8f66\u3001\u50a8\u80fd\u7535\u7ad9\u7b49\u65b0\u80fd\u6e90\u6280\u672f\u9886\u57df\u5546\u4e1a\u5316\u5e94\u7528\u7684\u4e00\u5927\u969c\u788d\u3002<\/p>\n

\u70ed\u5931\u63a7\u662f\u5bfc\u81f4\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u4e0d\u5b89\u5168\u884c\u4e3a\u7684\u6839\u672c\u539f\u56e0\uff0c\u56e0\u6b64\uff0c\u5efa\u7acb\u8fc7\u70ed\u4fdd\u62a4\u673a\u5236\uff0c\u9632\u6b62\u70ed\u5931\u63a7\uff0c\u662f\u4e00\u7cfb\u5217\u9ad8\u65b0\u6280\u672f\u9886\u57df\u8feb\u5207\u7684\u5e94\u7528\u9700\u8981\u3002\u5728\u7535\u6c60\u81ea\u6fc0\u53d1\u70ed\u4fdd\u62a4\u6280\u672f\u65b9\u9762\uff0c\u76ee\u524d\u5e38\u7528\u7684\u7b56\u7565\u662f\u91c7\u7528\u6b63\u6e29\u5ea6\u7cfb\u6570\u7535\u6781\u6750\u6599\u6216\u963b\u71c3\u6027\u7535\u89e3\u6db2\u3002\u524d\u8005\u7684\u5ba4\u6e29\u7535\u5bfc\u7387\u4f4e\u3001\u6f0f\u7535\u6d41\u5927\uff0c\u5e94\u7528\u53d7\u5230\u9650\u5236\uff1b\u540e\u8005\u7531\u4e8e\u963b\u71c3\u5242\u7684\u5927\u91cf\u6dfb\u52a0\uff0c\u7535\u89e3\u6db2\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4f4e\uff0c\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u5dee\u3002<\/p>\n

\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u4f59\u6842\u534e\u6559\u6388\u8bfe\u9898\u7ec4\uff0c\u5c06\u4e00\u79cd\u5177\u6709\u53ef\u9006\u6eb6\u80f6-\u51dd\u80f6\u8f6c\u53d8\u7684\u70ed\u5851\u6027\u5f39\u6027\u4f53\u5f15\u5165\u7535\u89e3\u6db2\u4e2d\uff0c\u8fdb\u800c\u7814\u53d1\u51fa\u80fd\u591f\u5b9e\u73b0\u7535\u6c60\u81ea\u6fc0\u53d1\u70ed\u4fdd\u62a4\u7684\u667a\u80fd\u6e29\u654f\u7535\u89e3\u8d28\u3002\u5b9e\u9a8c\u4e2d\u91c7\u7528\u6eb6\u89e3\u6709H+\u6216\u8005Li+\u7684\u666e\u6717\u5c3c\u514b\uff08Pluronic\uff09\u6c34\u6eb6\u6db2\u4f5c\u7535\u89e3\u8d28\uff0c\u4f4e\u6e29\u4e0b\uff0c\u8be5\u7535\u89e3\u8d28\u4fdd\u6301\u6eb6\u80f6\u6001\uff0c\u79bb\u5b50\u80fd\u5728\u7535\u6781\u95f4\u81ea\u7531\u79fb\u52a8\uff1b\u5f53\u6e29\u5ea6\u5347\u9ad8\u65f6\uff0c\u8be5\u7535\u89e3\u8d28\u53d8\u4e3a\u51dd\u80f6\u6001\uff0c\u963b\u788d\u79bb\u5b50\u7684\u79fb\u52a8\uff0c\u8fdb\u800c\u4e2d\u65ad\u50a8\u80fd\u5668\u4ef6\u7684\u7535\u5316\u5b66\u8fc7\u7a0b\uff0c\u5b9e\u73b0\u5bf9\u5668\u4ef6\u7684\u6709\u6548\u8fc7\u70ed\u4fdd\u62a4\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011
\n\u56fe\u4e00 \u57fa\u4e8e\u5177\u6709\u53ef\u9006\u6eb6\u80f6-\u51dd\u80f6\u8f6c\u53d8\u7684\u70ed\u5851\u6027\u5f39\u6027\u4f53\u7684\u7535\u89e3\u8d28<\/strong><\/p>\n

\"\u56fe\u72471\"
\n\u56fe(a) \u57fa\u4e8e\u6e29\u654f\u51dd\u80f6\u4f53\u7cfb\u7684\u7535\u89e3\u8d28\u793a\u610f\u56fe\uff1b
\n\u56fe(b) 30wt%\u7684Pluronic\u6eb6\u6db2\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u6d41\u53d8\u884c\u4e3a\uff0c\u56fe\u4e2dG\u2019\u8868\u793a\u50a8\u80fd\u6a21\u91cf\uff0cG\u2019\u2019\u8868\u793a\u635f\u8017\u6a21\u91cf\uff1b
\n\u56fe(c) \u6eb6\u80f6\u6001\u548c\u51dd\u80f6\u6001\u7684Pluronic\u6eb6\u6db2\u5b9e\u7269\u56fe\u3002<\/p>\n

\u56fe\u4e8c \u4ee5P5800\u4f5c\u7535\u89e3\u8d28\u7684\u8d85\u7ea7\u7535\u5bb9\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\u56fe\u72472\"
\n\u56fe(a) \u4e0d\u540c\u6d53\u5ea6\u7684\u5206\u5b50\u91cf\u4e3a5800\u9053\u5c14\u987f\u7684Pluronic\u6eb6\u6db2(P5800)\uff0c\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684G\u2019\u503c\uff1b
\n\u56fe(b) 20wt%\u7684P5800\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684G\u2019\u503c\u3001G\u2019\u2019\u503c\uff1b
\n\u56fe(c)-\u56fe(f)\u5c55\u793a\u4e8620wt%\u7684P5800\u548cH2SO4\u6eb6\u6db2\u4f5c\u7535\u89e3\u8d28\u7684\u6263\u5f0f\u8d85\u7ea7\u7535\u5bb9\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1a\u5176\u4e2d\u56fe(c)\u662f20\u2103\u4e0b\u7684CV\u66f2\u7ebf\uff0c\u56fe(d)\u662f70\u2103\u4e0b\u7684CV\u66f2\u7ebf\uff0c\u56fe(e)\u5c55\u793a\u4e86\u5728\u5ba4\u6e29\uff08RT\uff0c20\u2103\uff09\u548c\u9ad8\u6e29\uff08HT\uff0c70\u2103\uff09\u72b6\u6001\u4e0b\u7684\u5145\u653e\u7535\u6d4b\u8bd5\u7ed3\u679c\uff0c\u56fe(f)\u5219\u662f\u5728\u5ba4\u6e29\u548c\u9ad8\u6e29\u4e0b\u7684\u963b\u6297\u8c31\u3002<\/p>\n

\u56fe\u4e09 \u4ee5\u4e0d\u540c\u5206\u5b50\u91cf\u7684Pluronic\u6eb6\u6db2\u4f5c\u7535\u89e3\u8d28\u7684\u8d85\u7ea7\u7535\u5bb9\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\u56fe\u72473\"
\n\u56fe(a) \u4e0d\u540c\u5206\u5b50\u91cf\u7684Pluronic\u6eb6\u6db2\u7684\u6eb6\u80f6-\u51dd\u80f6\u8f6c\u53d8\u6e29\u5ea6\uff0c\u6eb6\u6db2\u6d53\u5ea6\u5747\u4e3a30wt%\uff1b
\n\u56fe(b) \u4e0d\u540c\u6e29\u5ea6\u4e0bP4400\u7684\u6d41\u53d8\u8bd5\u9a8c\u7ed3\u679c\uff1b
\n\u56fe(c)(d)\u5c55\u793a\u4ee5P2800\u4e3a\u7535\u89e3\u8d28\u7684\u8d85\u7ea7\u7535\u5bb9\u5728\u4e0d\u540c\u626b\u901f\u4e0b\u7684CV\u6d4b\u8bd5\u7ed3\u679c\uff0c\u5176\u4e2d\u56fe(c)\u7684\u6d4b\u8bd5\u6e29\u5ea6\u4e3a20\u2103\uff0c\u56fe(d)\u7684\u6d4b\u8bd5\u6e29\u5ea6\u4e3a70\u2103\uff1b
\n\u56fe(e)(f)\u5c55\u793a\u4ee5P4400\u4e3a\u7535\u89e3\u8d28\u7684\u8d85\u7ea7\u7535\u5bb9\u5728\u4e0d\u540c\u626b\u901f\u4e0b\u7684CV\u6d4b\u8bd5\u7ed3\u679c\uff0c\u5176\u4e2d\u56fe(e)\u7684\u6d4b\u8bd5\u6e29\u5ea6\u4e3a20\u2103\uff0c\u56fe(f)\u7684\u6d4b\u8bd5\u6e29\u5ea6\u4e3a60\u2103\u3002<\/p>\n

\u56fe\u56db \u4ee5Pluronic\u6eb6\u6db2\u4f5c\u7535\u89e3\u8d28\u7684\u8d85\u7ea7\u7535\u5bb9\u7684\u6bd4\u5bb9\u91cf\u548c\u8fc7\u70ed\u4fdd\u62a4\u673a\u5236<\/strong><\/p>\n

\"\u56fe\u72474\"
\n\u56fe(a)(b)\u5c55\u793a\u4e86\u4ee5Pluronic\u6eb6\u6db2\u4f5c\u7535\u89e3\u8d28\u7684\u8d85\u7ea7\u7535\u5bb9\uff0c\u91c7\u7528\u4e0d\u540c\u7535\u6781\u6750\u6599\u548c\u5bfc\u7535\u79bb\u5b50\uff0c\u5728\u6eb6\u80f6\u6001\u548c\u51dd\u80f6\u6001\u4e0b\u7684\u6bd4\u5bb9\u91cf\uff0c\u5176\u4e2d\u56fe(a)\u7684\u7535\u89e3\u6db2\u91c7\u7528P2800\uff0c\u56fe(b)\u7684\u7535\u89e3\u6db2\u91c7\u7528P4400\uff1b
\n\u56fe(c)(d)\u5c55\u793a\u4e86\u4ee5Pluronic\u6eb6\u6db2\u4f5c\u7535\u89e3\u8d28\u7684\u8d85\u7ea7\u7535\u5bb9\u7684\u8fc7\u70ed\u4fdd\u62a4\u673a\u5236\uff1a\u52a0\u70ed\u523070\u2103\u65f6\uff0cLED\u706f\u7684\u4eae\u5ea6\u663e\u8457\u964d\u4f4e\uff0c\u8db3\u4ee5\u8bf4\u660e\u9ad8\u6e29\u4e0b\u7535\u5316\u5b66\u8fc7\u7a0b\u57fa\u672c\u88ab\u4e2d\u65ad\u3002<\/p>\n

\u56fe\u4e94 Pluronic\u6eb6\u6db2\u7684\u6d41\u53d8\u6027\u80fd\u548c\u7535\u5316\u5b66\u53c2\u6570<\/strong><\/p>\n

\"\u56fe\u72475\"
\n\u56fe(a) \u6d53\u5ea6\u4e3a30wt%\u7684P2800\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u6d41\u53d8\u6027\u8bd5\u9a8c\uff1b
\n\u56fe(b) \u4ee530wt%\u7684P2800\u4f5c\u7535\u89e3\u6db2\u7684\u8d85\u7ea7\u7535\u5bb9\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684CV\u66f2\u7ebf\uff1b
\n\u56fe(c)(d)\u5c55\u793a\u4e86\u4ee530wt%\u7684P2800\u4f5c\u7535\u89e3\u6db2\u7684\u8d85\u7ea7\u7535\u5bb9\u7684\u5faa\u73af\u6d4b\u8bd5\u7ed3\u679c\uff0c\u5176\u4e2d\u56fe(c)\u91c7\u7528\u805a\u5421\u54af\uff08PPy\uff09\u4f5c\u7535\u6781\u6750\u6599\uff0c\u56fe(d)\u91c7\u7528\u6d3b\u6027\u70ad\uff08AC\uff09\u4f5c\u7535\u6781\u6750\u6599\uff1b
\n\u56fe(e)\u663e\u793a\u7684\u662f\u91c7\u7528\u4e0d\u540c\u5e73\u5747\u5206\u5b50\u91cf\u7684\u805a\u5408\u7269\u548c\u4e0d\u540c\u5bfc\u7535\u79bb\u5b50\u7684Pluronic\u7535\u89e3\u6db2\uff0c\u5728\u6eb6\u80f6\u72b6\u6001\u548c\u51dd\u80f6\u72b6\u6001\u4e0b\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011
\n\u4f59\u6842\u534e\u8bfe\u9898\u7ec4\u7814\u53d1\u51fa\u4e00\u79cd\u667a\u80fd\u6e29\u654f\u7535\u89e3\u8d28\u4f53\u7cfb\uff0c\u80fd\u591f\u5b9e\u73b0\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u7684\u81ea\u6fc0\u53d1\u70ed\u4fdd\u62a4\u3002\u4ed6\u4eec\u91c7\u7528\u4e86\u52a0\u70ed\u65f6\u4f1a\u8fc5\u901f\u53d1\u751f\u6eb6\u80f6-\u51dd\u80f6\u8f6c\u53d8\u7684\u70ed\u5851\u6027\u5f39\u6027\u4f53\uff0c\u5373\u5546\u4e1a\u5316\u7684Pluronic\u3002\u9ad8\u6e29\u4e0b\uff0cPluronic\u7535\u89e3\u8d28\u7684\u51dd\u80f6\u5316\uff0c\u4e25\u91cd\u963b\u788d\u79bb\u5b50\u8fc1\u79fb\uff0c\u8fdb\u800c\u4e2d\u65ad\u7535\u5316\u5b66\u8fc7\u7a0b\uff0c\u5b9e\u73b0\u4e86\u5bf9\u50a8\u80fd\u5668\u4ef6\u7684\u6709\u6548\u8fc7\u70ed\u4fdd\u62a4\u3002\u8fd9\u4e00\u8bbe\u8ba1\u5177\u6709\u54cd\u5e94\u5feb\u901f\u3001\u6548\u679c\u663e\u8457\u3001\u53ef\u9006\u7a0b\u5ea6\u9ad8\u3001\u6e29\u5ea6\u9608\u503c\u53ef\u8c03\u6574\u3001\u6210\u672c\u4f4e\u5ec9\u7b49\u4f18\u70b9\uff0c\u53ef\u4ee5\u76f4\u63a5\u5e94\u7528\u4e8e\u6c34\u6eb6\u6db2\u7535\u89e3\u8d28\u7684\u7535\u6c60\u6216\u8005\u8d85\u7ea7\u7535\u5bb9\u5668\u3002<\/p>\n

\u70b9\u6211\u67e5\u770b\u6b64\u524d\u4e00\u4e2a\u5173\u4e8e\u4f59\u6842\u534e\u6559\u6388\u7684\u8bbf\u8c08<\/a><\/p>\n

\u6587\u732e\u94fe\u63a5: Thermoplastic Elastomer-Enabled Smart Electrolyte for Thermoresponsive Self-Protection of Electrochemical Energy Storage Devices<\/a><\/p>\n

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