{"id":267622,"date":"2025-07-26T10:54:25","date_gmt":"2025-07-26T02:54:25","guid":{"rendered":"\/\/m.iemloyee.com\/?p=267622"},"modified":"2025-07-26T10:54:25","modified_gmt":"2025-07-26T02:54:25","slug":"%e6%96%b0%e5%8a%a0%e5%9d%a1%e5%9b%bd%e7%ab%8b%e5%a4%a7%e5%ad%a6-%e5%b1%b1%e4%b8%9c%e5%a4%a7%e5%ad%a6%e5%9b%a2%e9%98%9fjacs%ef%bc%9a%e5%bc%80%e5%8f%91%e8%81%9a%e5%90%88%e7%89%a9%e5%9b%ba%e6%80%81-2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=267622","title":{"rendered":"\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\/\u5c71\u4e1c\u5927\u5b66\u56e2\u961fJACS\uff1a\u5f00\u53d1\u805a\u5408\u7269\u56fa\u6001\u7535\u89e3\u8d28\u52a8\u6001\u79bb\u5b50\u4f20\u8f93\u901a\u9053\u4ee5\u5b9e\u73b0\u9ad8\u6027\u80fd\u9502\u91d1\u5c5e\u7535\u6c60"},"content":{"rendered":"\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"858\" height=\"226\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/07\/\u56fe\u72471-6.png\" alt=\"\" class=\"wp-image-267623\"\/><\/figure>\n\n\n\n<p>\u9502\u91d1\u5c5e\u7535\u6c60\uff08LMBs\uff09\u4ee5\u5176\u8d85\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\uff083860 mAh g<sup>-1<\/sup>\uff09\u88ab\u89c6\u4e3a\u4e0b\u4e00\u4ee3\u50a8\u80fd\u6280\u672f\u7684\u9886\u519b\u8005\uff0c\u4f46\u6db2\u6001\u7535\u89e3\u8d28\u7684\u6613\u71c3\u6027\u548c\u70ed\u5931\u63a7\u95ee\u9898\u9650\u5236\u4e86\u5176\u5546\u4e1a\u5316\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e9b\u5b89\u5168\u95ee\u9898\uff0c\u56fa\u6001\u7535\u89e3\u8d28\uff08SEs\uff09\u6210\u4e3a\u4e86\u70ed\u95e8\u66ff\u4ee3\u65b9\u6848\uff0c\u5176\u4e2d\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\uff08SPEs\uff09\u56e0\u5176\u4f18\u5f02\u7684\u819c\u52a0\u5de5\u6027\u80fd\u548c\u7075\u6d3b\u7684\u5f62\u6001\u7279\u6027\u800c\u5907\u53d7\u5173\u6ce8\u3002<\/p>\n\n\n\n<p>\u7136\u800c\uff0cSPEs\u9762\u4e34\u79bb\u5b50\u5bfc\u7535\u6027\u5dee\u548c\u754c\u9762\u7a33\u5b9a\u6027\u4e0d\u8db3\u7684\u6311\u6218\u3002\u6b64\u7814\u7a76\u63d0\u51fa\u901a\u8fc7\u5728\u805a\u4e19\u70ef\u9178\u57faSPE\u4e2d\u5f15\u5165\u5fae\u91cf\u56db\u6c22\u567b\u5429\u781c\uff08SL\uff09\uff0c\u8bbe\u8ba1\u201c\u52a8\u6001\u79bb\u5b50\u4f20\u8f93\u901a\u9053\u201d\u3002\u901a\u8fc7\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u548c\u5b9e\u9a8c\u9a8c\u8bc1\uff0c\u7cbe\u786e\u8c03\u63a7\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u63d0\u5347\u4e86\u79bb\u5b50\u5bfc\u7535\u6027\u548c\u9502\u79bb\u5b50\u8fc1\u79fb\u6570\u3002\u8fdb\u4e00\u6b65\u5206\u6790\u53d1\u73b0\uff0c<em>In situ<\/em>-SL2\u7535\u89e3\u8d28\u4fc3\u8fdb\u4e86\u7a33\u5b9a\u4e14\u5bcc\u542b\u65e0\u673a\u7269\u7684\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u5f62\u6210\uff0c\u6709\u6548\u6291\u5236\u4e86\u9502\u679d\u6676\u7684\u751f\u957f\u3002LFP|<em>In situ<\/em>-SL2|Li\u7535\u6c60\u57283C\u4e0b\u5faa\u73af2000\u6b21\u540e\u4ecd\u4fdd\u630191.7%\u7684\u5bb9\u91cf\uff0c\u5c55\u793a\u4e86\u5353\u8d8a\u7684\u6027\u80fd\u548c\u957f\u65f6\u95f4\u7a33\u5b9a\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u9ad8\u6027\u80fd\u3001\u957f\u5bff\u547d\u4e14\u5b89\u5168\u7684\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"1269\" height=\"1072\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/07\/\u56fe\u72472-6.png\" alt=\"\" class=\"wp-image-267624\"\/><\/figure>\n\n\n\n<p>\u56fe1. (a) \u805a\u5408\u540e\u7684<em>in situ<\/em>-SL2\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\u8868\u9762SEM\u56fe\u50cf\u3002(b) \u5355\u4f53\u548c\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684FT-IR\u8c31\u56fe\u3002(c) \u62c9\u4f38\u5e94\u529b\u2212\u5e94\u53d8\u66f2\u7ebf\u3002(d)<em>&nbsp;in situ<\/em>\u57fa\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u62c9\u66fc\u5149\u8c31\u3002(e) <sup>7<\/sup>Li\u6838\u78c1\u5171\u632f\uff08NMR\uff09\u8c31\u3002(f) SL\u5206\u5b50\u5728\u4e0d\u540c\u4e8c\u9762\u89d2\u53d8\u5316\u4e0b\u7684\u8868\u9762\u9759\u7535\u52bf\u5206\u5e03\u56fe\u3002(g) 720\u2212770 cm<sup>-1<\/sup>\u8303\u56f4\u5185\u7684Lorentzian\u2212Gaussian\u89e3\u5377\u79ef\u62c9\u66fc\u5149\u8c31\u3002(h) \u5f84\u5411\u5206\u5e03\u51fd\u6570\uff08g(r)\uff0c\u5b9e\u7ebf\uff09\u548c\u914d\u4f4d\u6570\uff08\u865a\u7ebf\uff09\u3002(i) <em>in situ<\/em>-SL2&nbsp;SPE\u7684MD\u5feb\u7167\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"1269\" height=\"1069\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/07\/\u56fe\u72473-6.png\" alt=\"\" class=\"wp-image-267625\"\/><\/figure>\n\n\n\n<p>\u56fe2. \u5bc6\u5ea6\u573a\u56fe\u793a\u8bf4\u660e\u9502\u79bb\u5b50\u4f20\u8f93\u901a\u9053\uff1a(a) <em>in situ<\/em>-SL1\u00a0SPE\u548c(b<em>) in situ<\/em>-SL2\u00a0SPE\u7684\u4f20\u8f93\u901a\u9053\u3002 (c)<em>\u00a0in situ<\/em>-SL1 SPE\u548c(d) <em>in situ<\/em>-SL2 SPE\u4e2d\uff0cLi<sup>+<\/sup>\u4e0e\u6eb6\u5242\u5316\u58f3\u4e2d\u4ee3\u8868\u6027\u6c27\u539f\u5b50\u4e4b\u95f4\u7684\u6838\u95f4\u8ddd\u79bb\u3002 (e) Li<sup>+<\/sup>\u7684\u5747\u65b9\u4f4d\u79fb\uff08MSD\uff09\u548c(f) <em>in situ<\/em>-SL1 SPE\uff08\u5de6\uff09\u53ca<em>in situ<\/em>-SL2 SPE\uff08\u53f3\uff09\u4e2d\u4ee3\u8868\u6027Li<sup>+<\/sup>\u79bb\u5b50\u7684\u4e09\u7ef4\u8f68\u8ff9\u3002(g)\u67d0\u4e00\u7279\u5b9a\u9502\u539f\u5b50\u5728<em>in situ<\/em>-SL1\uff08\u4e0a\uff09\u548c<em>in situ<\/em>-SL2\uff08\u4e0b\uff09SPE\u4e2d\u8fd0\u52a8\u7684\u5feb\u7167\u3002(h) <sup>7<\/sup>Li\u548c<sup>19<\/sup>F PFG-NMR\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"1269\" height=\"1065\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/07\/\u56fe\u72474-3.png\" alt=\"\" class=\"wp-image-267626\"\/><\/figure>\n\n\n\n<p>\u56fe3. (a) \u79bb\u5b50\u7535\u5bfc\u7387\u548c(b) \u5728\u5ba4\u6e29\u4e0b\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\uff08EIS\uff09\u3002 (c) \u4f7f\u7528Arrhenius\u6a21\u578b\u62df\u5408\u7684\u6d3b\u5316\u80fd\u3002(d) \u5ba4\u6e29\u4e0b\u7684LSV\u66f2\u7ebf\u3002(e) \u548c (f) \u572810 mV\u504f\u538b\u4e0b\uff0c<em>in situ<\/em>-SL2\u548c<em>in situ<\/em>-SL3 SPE\u7684\u7a33\u6001\u8ba1\u65f6\u5b89\u57f9\u6781\u5316\u66f2\u7ebf\u3002(g) \u4e0d\u540c SPE\u7684Li\u5bf9\u79f0\u7535\u6c60\u7684EIS\u8c31\u56fe\u3002(h) <em>in situ<\/em>-SL2 SPE\u4e2d\u79bb\u5b50\u4f20\u8f93\u673a\u5236\u7684\u793a\u610f\u56fe\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"1269\" height=\"1038\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/07\/\u56fe\u72475-3.png\" alt=\"\" class=\"wp-image-267627\"\/><\/figure>\n\n\n\n<p>\u56fe4. (a) <em>in situ<\/em>-SPE\u7ec4\u88c5\u7684Li\u5bf9\u79f0\u7535\u6c60\u7684Tafel\u56fe\u3002(b) \u57280.3 mA cm<sup>-2<\/sup>\u548c0.3 mAh cm<sup>-2<\/sup>\u4e0b\u7684\u6052\u7535\u6d41\u5faa\u73af\u66f2\u7ebf\u3002 (c) \u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u5b9a\u7535\u6d41\u6781\u5316\u66f2\u7ebf\u3002(d) \u5728\u9636\u68af\u5f0f\u7535\u6d41\u5bc6\u5ea6\uff080.1\u22122.0 mA cm<sup>-2<\/sup>\uff09\u4e0b\u7684\u4e34\u754c\u7535\u6d41\u5bc6\u5ea6\uff08CCD\uff09\u6d4b\u8bd5\u3002 (e) \u6587\u732e\u6027\u80fd\u6bd4\u8f83\u3002(f) <em>in situ<\/em>-SPE\u7684Cu||Li\u534a\u7535\u6c60\u57280.2 mA cm\u207b\u00b2\u548c0.6 mAh cm\u207b\u00b2\u4e0b\u7684\u6027\u80fd\u3002(g) <em>in situ<\/em>-SPE\u7684Cu||Li\u534a\u7535\u6c60\u4e2d\u9502\u7535\u9540\/\u5265\u79bb\u7684\u7535\u538b-\u5bb9\u91cf\u66f2\u7ebf\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"1269\" height=\"1048\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/07\/\u56fe\u72476-2.png\" alt=\"\" class=\"wp-image-267628\"\/><\/figure>\n\n\n\n<p>\u56fe5. (a) \u4e0d\u540c\u500d\u7387\u4e0bLFP|<em>In situ<\/em>-SL2|Li\u548cLFP|<em>In situ<\/em>-SL3|Li\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u3002(b) LFP|<em>In situ<\/em>-SL2|Li\u7535\u6c60\u5728\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002(c) LFP|<em>In situ<\/em>-SL3|Li\u7535\u6c60\u5728\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002(d) LFP||Li\u7535\u6c60\u57283C\u4e0b\u7684\u957f\u65f6\u95f4\u5faa\u73af\u6027\u80fd\u3002(e) LFP|<em>In situ<\/em>-SL2|Li\u7535\u6c60\u5faa\u73af\u540e\u9502\u91d1\u5c5e\u7684\u7c97\u7cd9\u5ea6\u53ca\u76f8\u5e94\u7684\u6768\u6c0f\u6a21\u91cf\u5206\u6790\u3002(f) LFP|<em>In situ<\/em>-SL2|Li\u7535\u6c60\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684EIS\u963b\u6297\u8c31\u56fe\u3002(g) 4.2-5.0V\u8303\u56f4\u5185\uff0cLFP|<em>In situ<\/em>-SL2|Li\u548cLFP|<em>In situ<\/em>-SL3|Li\u7535\u6c60\u7684\u7535\u5316\u5b66\u6d6e\u52a8\u5206\u6790\u3002(h) \u5728\u5f2f\u66f2\u548c\u526a\u5207\u6761\u4ef6\u4e0b\uff0c\u8f6f\u5305\u7535\u6c60\u70b9\u4eaeLED\u7684\u5b89\u5168\u6027\u6d4b\u8bd5\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"1269\" height=\"909\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/07\/\u56fe\u72477-2.png\" alt=\"\" class=\"wp-image-267629\"\/><\/figure>\n\n\n\n<p>\u56fe6. (a) \u57fa\u4e8e\u4ece\u5934\u7b97\u5206\u5b50\u52a8\u529b\u5b66\uff08AIMD\uff09\u6a21\u62df\u7684\u754c\u9762\u53cd\u5e94\u53ca\u5728\u9502\u91d1\u5c5e\u4e0a\u5f62\u6210\u7684\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u3002(b) SEI\u4e2d\u4e3b\u8981\u4ea7\u7269\u7684\u76f8\u5bf9\u542b\u91cf\u3002(c) \u5143\u7d20\u5206\u6790\u548c(d, e) \u5faa\u73af\u540eLFP|<em>In situ<\/em>-SL2|Li\u548cLFP|<em>In situ<\/em>-SL3|Li\u7535\u6c60\u9502\u8868\u9762F 1s\u7684\u6df1\u5ea6\u5206\u6790\u3002(f) \u5faa\u73af10\u6b21\u540eLFP|<em>In situ<\/em>-SL2|Li\u548cLFP<em>|In situ<\/em>-SL3|Li\u7535\u6c60\u76843D TOF-SIMS\u56fe\u3002(g) LFP|<em>In situ<\/em>-SL2|Li\u548c(h) LFP|<em>In situ<\/em>-SL3|Li\u7535\u6c60\u57fa\u4e8eCOMSOL Multiphysics\u6709\u9650\u5143\u65b9\u6cd5\uff08FEMS\uff09\u7684\u9502\u79bb\u5b50\u6d53\u5ea6\u5206\u5e03\u6a21\u62df\u3002<\/p>\n\n\n\n<p>\u6587\u7ae0\u94fe\u63a5\uff1aDeveloping Dynamic Ion Transport Channels in Polymer Solid Electrolytes for High-Performance Lithium Metal Batteries<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u9502\u91d1\u5c5e\u7535\u6c60\uff08LMBs\uff09\u4ee5\u5176\u8d85\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\uff083860 mAh g-1\uff09\u88ab\u89c6\u4e3a\u4e0b\u4e00\u4ee3\u50a8\u80fd\u6280\u672f\u7684\u9886\u519b\u8005\uff0c\u4f46\u6db2\u6001\u7535\u89e3\u8d28\u7684\u6613\u71c3\u6027\u548c\u70ed\u5931\u63a7\u95ee\u9898\u9650\u5236\u4e86\u5176\u5546\u4e1a\u5316\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e9b&#8230;<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-267622","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/267622"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=267622"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/267622\/revisions"}],"predecessor-version":[{"id":267630,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/267622\/revisions\/267630"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=267622"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=267622"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=267622"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}