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\"\u66fe\u6d77\u6ce2\"<\/p>\n

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2.2.2 \u975e\u6ce8\u5c04\u6cd5<\/h3>\n

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2.3 \u6eb6\u5242\u70ed\/\u6c34\u70ed\u6cd5<\/h2>\n

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\"\u94b1\u9038\u6cf0\"<\/p>\n

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\u5f53\u628a\u6eb6\u5242\u70ed\u6cd5\u4e2d\u7684\u6eb6\u5242\u6362\u6210\u6c34\u65f6\uff0c\u5c31\u53d8\u6210\u4e86\u6c34\u70ed\u6cd5\uff0c\u5176\u5b9e\u6c34\u70ed\u6cd5\u7684\u5386\u53f2\u6bd4\u6eb6\u5242\u70ed\u6cd5\u65e9\u5f88\u591a\uff0c\u5730\u7403\u5185\u90e8\u77ff\u7269\u7684\u5f62\u6210\u5176\u5b9e\u5c31\u662f\u4e00\u79cd\u6c34\u70ed\u6cd5\u5408\u6210\u6750\u6599\u7684\u7ecf\u5178\u4f8b\u5b50(\u5176\u5b9e\u5927\u81ea\u7136\u624d\u662f\u6700\u5389\u5bb3\u7684\u201c\u5408\u6210\u4e4b\u738b\u201d\uff0c\u540e\u9762\u6709\u673a\u4f1a\u5c0f\u7f16\u53ef\u80fd\u8ddf\u5927\u5bb6\u8c08\u8c08\u4eba\u5de5\u5149\u5408\u6210\u4e4b\u7c7b\u7684\uff0c\u4e5f\u662f\u4ece\u81ea\u7136\u754c\u5b66\u4e60\u7684\u5b9e\u4f8b)\u3002\u5173\u4e8e\u6c34\u70ed\u6cd5\u5408\u6210\u6750\u6599\u7684\u5de5\u4f5c\u4e5f\u5f88\u591a\uff0c\u5728\u6b64\u4e0d\u4f5c\u8fc7\u591a\u4ecb\u7ecd\uff0c\u6709\u5174\u8da3\u7684\u8bfb\u8005\u53ef\u4ee5\u9605\u8bfb\u540e\u9762\u7684\u63a8\u8350\u6587\u732e\u3002\u524d\u9762\u53ea\u662f\u5f00\u4e2a\u5934\uff0c\u5176\u5b9e\u5c0f\u7f16\u6700\u60f3\u8ddf\u5927\u5bb6\u5206\u4eab\u7684\u662f\u63a5\u4e0b\u6765\u7684\u8fd9\u7bc7\u6587\u7ae0\u30022005\u5e74\uff0c\u674e\u4e9a\u680b\u8001\u5e08(\u5076\u50cf\u54e6)\u8bfe\u9898\u7ec4\u5728nature\u4e0a\u62a5\u9053\u4e86\u4e00\u79cd\u5408\u6210\u7eb3\u7c73\u6676\u7684\u901a\u7528\u65b9\u6cd5\u2014LSS\u6cd5[10]<\/sup>\u3002\u8bdd\u4e0d\u591a\u8bf4\uff0c\u5148\u4e0a\u56fe\uff01<\/p>\n

\"LSS1\"<\/p>\n

\u56fe7\u00a0 LSS\u6cd5\u5408\u6210\u91cf\u5b50\u70b9\u7684TEM\u56fe\u50cf[10]<\/sup><\/p>\n

\"LSS2\"<\/p>\n

\u56fe8\u00a0 LSS\u6cd5\u5408\u6210\u91cf\u5b50\u70b9\u7684\u7167\u7247[10]<\/sup><\/p>\n

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\"nature03968-f3.2\"<\/p>\n

\u56fe9\u00a0 LSS\u6cd5\u5408\u6210\u7eb3\u7c73\u6676\u7684\u673a\u740610<\/sup><\/a><\/p>\n

\u603b\u7ed3<\/h1>\n

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(1)\u4f60\u51c6\u5907\u9009\u62e9\u4ec0\u4e48\u6eb6\u5242\uff0c\u4e3a\u4ec0\u4e48(\u5982\u94b1\u9038\u6cf0\u8001\u5e08\u90a3\u7bc7science\u4e3a\u4ec0\u4e48\u9009\u62e9\u82ef\u4f5c\u4e3a\u6eb6\u5242)\uff1b(2)\u4f60\u51c6\u5907\u9009\u62e9\u4ec0\u4e48\u524d\u9a71\u4f53(\u5982\u94b1\u9038\u6cf0\u8001\u5e08\u90a3\u7bc7science\u4e3a\u4ec0\u4e48\u9009\u62e9\u90a3\u4e24\u79cd\u53cd\u5e94\u7269)\uff1b(3)\u4f60\u51c6\u5907\u9009\u7528\u4ec0\u4e48\u53cd\u5e94\u6e29\u5ea6\uff1b(4)\u9700\u4e0d\u9700\u8981\u52a0\u70b9\u5176\u4ed6\u7684\u4ec0\u4e48\u4e1c\u897f\uff0c\u5982\u8868\u9762\u6d3b\u6027\u5242\uff0c\u76ee\u7684\u662f\u4ec0\u4e48\uff0c\u4e3a\u4ec0\u4e48\uff1b(5)\u5404\u79cd\u7269\u8d28\u9700\u8981\u52a0\u591a\u5c11\uff0c\u4e3a\u4ec0\u4e48\u7b49\u7b49\u3002\u5176\u5b9e\u641e\u6e05\u695a\u8fd9\u4e9b\u95ee\u9898\u6709\u65f6\u5019\u5e76\u4e0d\u5bb9\u6613\uff0c\u4f46\u662f\u4f60\u8981\u5c3d\u91cf\u5bf9\u4f60\u7684\u5408\u6210\u4f5c\u6bd4\u8f83\u6df1\u5165\u4e86\u89e3\u7684\u601d\u8003\uff0c\u76f8\u4fe1\u6211\uff0c\u8fd9\u6837\u4f60\u4f1a\u63d0\u9ad8\u5f88\u591a\u7684\u3002<\/p>\n

\u603b\u4e4b\uff0c\u5408\u6210\u662f\u4e00\u95e8\u6280\u672f\uff0c\u6211\u4eec\u4e0d\u4ec5\u9700\u8981\u8c28\u614e\u9009\u62e9\u5408\u6210\u65b9\u6cd5\u548c\u4e00\u4e9b\u91cd\u8981\u7684\u7ec6\u8282\uff0c\u66f4\u4e3a\u91cd\u8981\u7684\u662f\u7406\u89e3\u6e05\u695a\u6bcf\u4e00\u79cd\u5408\u6210\u65b9\u6cd5\u80cc\u540e\u7684\u673a\u7406(\u5c24\u5176\u662f\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66)\uff0c\u4e3a\u4f60\u7684\u79d1\u7814\u52a9\u529b\u3002\u5173\u4e8e\u91cf\u5b50\u70b9\u6216\u8005\u5176\u4ed6\u4e00\u4e9b\u7eb3\u7c73\u6750\u6599\u7684\u5408\u6210\u8bfb\u8005\u53ef\u4ee5\u53c2\u8003\u540e\u9762\u7ed9\u51fa\u7684\u4e00\u4e9b\u4f18\u79c0\u6587\u732e[1,11]<\/sup>\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/h1>\n
    \n
  1. Kwon, S. G.; Hyeon, T., Formation Mechanisms of Uniform Nanocrystals via Hot-Injection and Heat-Up Methods. Small <\/em>2011,<\/strong> 7<\/em> (19), 2685-2702.<\/li>\n
  2. Akhavan, V. A.; Goodfellow, B. W.; Panthani, M. G.; Reid, D. K.; Hellebusch, D. J.; Adachi, T.; Korgel, B. A., Spray-deposited CuInSe2 nanocrystal photovoltaics. Energy & Environmental Science <\/em>2010,<\/strong> 3<\/em> (10), 1600-1606.<\/li>\n
  3. Colvin, V. L.; Goldstein, A. N.; Alivisatos, A. P., Semiconductor nanocrystals covalently bound to metal surfaces with self-assembled monolayers. Journal of the American Chemical Society <\/em>1992,<\/strong> 114<\/em> (13), 5221-5230.<\/li>\n
  4. Ge, J.-P.; Chen, W.; Liu, L.-P.; Li, Y.-D., Formation of Disperse Nanoparticles at the Oil\/Water Interface in Normal Microemulsions. Chemistry \u2013 A European Journal <\/em>2006,<\/strong> 12<\/em> (25), 6552-6558.<\/li>\n
  5. LaMer, V. K.; Dinegar, R. H., Theory, Production and Mechanism of Formation of Monodispersed Hydrosols. Journal of the American Chemical Society <\/em>1950,<\/strong> 72<\/em> (11), 4847-4854.<\/li>\n
  6. Murray, C. B.; Norris, D. J.; Bawendi, M. G., Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites. Journal of the American Chemical Society <\/em>1993,<\/strong> 115<\/em> (19), 8706-8715.<\/li>\n
  7. Song, J.; Li, J.; Li, X.; Xu, L.; Dong, Y.; Zeng, H., Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX3). Advanced materials <\/em>2015,<\/strong> 27<\/em> (44), 7162-7167.<\/li>\n
  8. Liu, L.; Zhuang, Z.; Xie, T.; Wang, Y.-G.; Li, J.; Peng, Q.; Li, Y., Shape Control of CdSe Nanocrystals with Zinc Blende Structure. Journal of the American Chemical Society <\/em>2009,<\/strong> 131<\/em> (45), 16423-16429.<\/li>\n
  9. Xie, Y.; Qian, Y.; Wang, W.; Zhang, S.; Zhang, Y., A Benzene-Thermal Synthetic Route to Nanocrystalline GaN. Science <\/em>1996,<\/strong> 272<\/em> (5270), 1926-1927.<\/li>\n
  10. Wang, X.; Zhuang, J.; Peng, Q.; Li, Y., A general strategy for nanocrystal synthesis. Nature <\/em>2005,<\/strong> 437<\/em> (7055), 121-124.<\/li>\n
  11. (a) Zhuang, Z.; Peng, Q.; Li, Y., Controlled synthesis of semiconductor nanostructures in the liquid phase. Chemical Society reviews <\/em>2011,<\/strong> 40<\/em> (11), 5492-5513; (b) Xia, Y.; Xiong, Y.; Lim, B.; Skrabalak, S. E., Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics? Angewandte Chemie <\/em>2009,<\/strong> 48<\/em> (1), 60-103; (c) Yin, Y.; Alivisatos, A. P., Colloidal nanocrystal synthesis and the organic-inorganic interface. Nature <\/em>2005,<\/strong> 437<\/em> (7059), 664-70; (d) Peng, X., An essay on synthetic chemistry of colloidal nanocrystals. Nano Research <\/em>2009,<\/strong> 2<\/em> (6), 425-447; (e) Park, J.; Joo, J.; Kwon, S. G.; Jang, Y.; Hyeon, T., Synthesis of Monodisperse Spherical Nanocrystals. Angewandte Chemie International Edition <\/em>2007,<\/strong> 46<\/em> (25), 4630-4660.<\/li>\n<\/ol>\n

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