{"id":266888,"date":"2025-05-18T06:58:21","date_gmt":"2025-05-17T22:58:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=266888"},"modified":"2025-05-17T22:03:46","modified_gmt":"2025-05-17T14:03:46","slug":"%e5%8d%97%e6%98%8c%e5%a4%a7%e5%ad%a6%e9%99%88%e4%b9%89%e6%97%ba%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9fnat-commun-%e8%b4%ab%e6%b0%b4%e5%8f%8c%e7%94%b5%e5%b1%82%e5%8d%8f%e5%90%8c%e7%a8%b3%e5%ae%9a","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=266888","title":{"rendered":"\u5357\u660c\u5927\u5b66\u9648\u4e49\u65fa\u6559\u6388\u56e2\u961fNat. Commun. \u8d2b\u6c34\u53cc\u7535\u5c42\u534f\u540c\u7a33\u5b9a\u754c\u9762\u5de5\u7a0b\u5b9e\u73b0\u957f\u6548\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60"},"content":{"rendered":"<p><strong>\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/p>\n<p>\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff08ZIBs\uff09\u51ed\u501f\u950c\u91d1\u5c5e\u7535\u6781\u9ad8\u7406\u8bba\u5bb9\u91cf\u3001\u4f4e\u7535\u5316\u5b66\u7535\u4f4d\u3001\u8d44\u6e90\u4e30\u5bcc\u53ca\u4f4e\u6210\u672c\u7b49\u4f18\u52bf\uff0c\u6210\u4e3a\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u6781\u5177\u7ade\u4e89\u529b\u7684\u6280\u672f\u65b9\u6848\u3002\u7136\u800c\uff0c\u5176\u5546\u4e1a\u5316\u8fdb\u7a0b\u53d7\u9650\u4e8e\u754c\u9762\u95ee\u9898\uff1a\u950c\u679d\u6676\u4e0d\u53ef\u63a7\u751f\u957f\u3001\u5316\u5b66\u8150\u8680\u3001\u6790\u6c22\u53cd\u5e94\u53ca\u4f4e\u950c\u5229\u7528\u7387\uff0c\u5bfc\u81f4\u5e93\u4ed1\u6548\u7387\u548c\u5faa\u73af\u5bff\u547d\u96be\u4ee5\u8fbe\u5230\u5de5\u4e1a\u57fa\u51c6\u3002\u5176\u6838\u5fc3\u77db\u76fe\u6e90\u4e8e\u950c\u9633\u6781\u754c\u9762\u5bcc\u6c34\u7684\u53cc\u7535\u5c42\uff08EDL\uff09\u548c\u6c34\u5206\u89e3\u4e3b\u5bfc\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u5171\u540c\u5f15\u53d1\u7684\u4e0d\u53ef\u9006\u53cd\u5e94\u3002\u5bcc\u6c34\u7684EDL\u7ed3\u6784\u4fc3\u4f7f\u6c34\u5206\u5b50\u4e0e\u950c\u8868\u9762\u76f4\u63a5\u63a5\u89e6\uff0c\u52a0\u5267\u526f\u53cd\u5e94\u52a8\u529b\u5b66\uff1b\u800c\u4f20\u7edf\u7535\u89e3\u8d28\u4f53\u7cfb\u56e0\u7f3a\u4e4f\u6709\u6548\u949d\u5316\u7ec4\u5206\uff0c\u96be\u4ee5\u6784\u5efa\u7a33\u5b9a\u7684SEI\u3002\u4e3a\u5f25\u8865\u4e0d\u53ef\u9006\u950c\u635f\u8017\uff0c\u5e38\u9700\u5927\u5e45\u589e\u52a0\u950c\u7b94\u7528\u91cf\uff0c\u76f4\u63a5\u524a\u5f31\u7cfb\u7edf\u80fd\u91cf\u5bc6\u5ea6\u4e0e\u7ecf\u6d4e\u6027\u3002\u8fd1\u671f\u7814\u7a76\u63ed\u793aEDL\u7279\u6027\u53ef\u901a\u8fc7\u8c03\u63a7\u754c\u9762\u6c34\u6d3b\u6027\u548cZn\u00b2\u207a\u8131\u6eb6\u5242\u5316\u8fc7\u7a0b\u5f71\u54cdSEI\u5f62\u6210\uff0c\u4f46\u5982\u4f55\u901a\u8fc7EDL\u5de5\u7a0b\u6784\u5efa\u957f\u6548\u6c34\u5c4f\u853d\u5c42\u53ca\u7a33\u5b9aSEI\u4ecd\u662f\u5173\u952e\u79d1\u5b66\u96be\u9898\u3002<\/p>\n<p><strong>\u9488\u5bf9\u4e0a\u8ff0\u6311\u6218\uff0c\u5357\u660c\u5927\u5b66\u5f6d\u949f\u6709\u535a\u58eb<\/strong><strong>\/<\/strong><strong>\u8c08\u5229\u627f\u6559\u6388<\/strong><strong>\/<\/strong><strong>\u9648\u4e49\u65fa\u6559\u6388\u56e2\u961f\u521b\u65b0\u6027\u5f15\u5165\u5fae\u91cf\u975e\u79bb\u5b50\u4e24\u4eb2\u6027\u805a\u5c71\u68a8\u916f\uff08<\/strong><strong>PS<\/strong><strong>\uff09\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\uff0c\u901a\u8fc7\u534f\u540c\u8c03\u63a7<\/strong><strong>EDL<\/strong><strong>\u4e0e<\/strong><strong>SEI<\/strong><strong>\u63d0\u5347<\/strong><strong>ZIBs<\/strong><strong>\u754c\u9762\u7a33\u5b9a\u6027\u3002\u7814\u7a76\u8868\u660e\uff0c<\/strong><strong>PS<\/strong><strong>\u5206\u5b50\u51ed\u501f\u5316\u5b66\u5438\u9644\u4f5c\u7528\u5f62\u6210\u5b9a\u5411\u6392\u5e03\u754c\u9762\u5c42\uff1a\u5176\u758f\u6c34\u957f\u94fe\u5411\u5916\u6784\u7b51\u7269\u7406\u5c4f\u969c\uff0c\u6709\u6548\u7834\u574f\u754c\u9762\u6c22\u952e\u7f51\u7edc\u5e76\u6291\u5236\u6c34\u5206\u5b50\u6d3b\u6027\uff1b\u4eb2\u950c\u57fa\u56e2\u5219\u901a\u8fc7\u914d\u4f4d\u951a\u5b9a<\/strong><strong>Zn\u00b2\u207a<\/strong><strong>\u8fc1\u79fb\u901a\u9053\uff0c\u7ef4\u6301\u9ad8\u6548\u79bb\u5b50\u4f20\u8f93\u3002\u8be5\u6dfb\u52a0\u5242\u540c\u65f6\u8bf1\u5bfc\u6784\u5efa\u6709\u673a<\/strong><strong>&#8211;<\/strong><strong>\u65e0\u673a\u6742\u5316<\/strong><strong>SEI<\/strong><strong>\uff0c\u4fc3\u8fdb\u754c\u9762\u7535\u573a\u5747\u8d28\u5316\u5206\u5e03\u4e0e\u950c\u5747\u5300\u6210\u6838\uff0c\u5b9e\u73b0\u950c\uff08<\/strong><strong>002<\/strong><strong>\uff09\u6676\u9762\u62e9\u4f18\u53d6\u5411\u6c89\u79ef\u53ca\u526f\u53cd\u5e94\u6291\u5236\u3002\u57fa\u4e8e\u542b<\/strong><strong>PS<\/strong><strong>\u7535\u89e3\u6db2\u7684<\/strong><strong>Zn||Zn<\/strong><strong>\u5bf9\u79f0\u7535\u6c60\u5728<\/strong><strong>1 mA cm\u207b\u00b2\/1 mAh cm\u207b\u00b2<\/strong><strong>\u6761\u4ef6\u4e0b\u5b9e\u73b0<\/strong><strong>8060<\/strong><strong>\u5c0f\u65f6\uff08<\/strong><strong>~336<\/strong><strong>\u5929\uff09\u8d85\u957f\u5faa\u73af\uff0c\u5e76\u5728<\/strong><strong>40 mA cm\u207b\u00b2\/40 mAh cm\u207b\u00b2<\/strong><strong>\u9ad8\u5de5\u51b5\u4e0b\u7a33\u5b9a\u8fd0\u884c<\/strong><strong>450<\/strong><strong>\u5c0f\u65f6\uff0c\u6027\u80fd\u663e\u8457\u4f18\u4e8e\u4f20\u7edf\u4f53\u7cfb\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u4e3a\u950c\u7535\u6781\u754c\u9762\u5316\u5b66\u8c03\u63a7\u63d0\u4f9b\u65b0\u601d\u8def\uff0c\u66f4\u6df1\u5316\u4e86\u5bf9\u6c34\u7cfb<\/strong><strong>ZIBs<\/strong><strong>\u4e2d<\/strong><strong>EDL<\/strong><strong>\u4e0e<\/strong><strong>SEI<\/strong><strong>\u534f\u540c\u4f5c\u7528\u673a\u5236\u7684\u7406\u89e3\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-266890\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72471-13.png\" alt=\"\" width=\"548\" height=\"469\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72471-13.png 548w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72471-13-300x257.png 300w\" sizes=\"(max-width: 548px) 100vw, 548px\" \/><\/strong><\/p>\n<p><strong>\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<\/strong><strong>Water-shielding electric double layer and stable interphase engineering for durable aqueous zinc-ion batteries<\/strong><strong>\u201d\u4e3a\u9898\u53d1\u8868\u4e8e\u56fd\u9645\u6743\u5a01\u671f\u520a\u300a<\/strong><strong><em>Nature Communications<\/em><\/strong><strong>\u300b\uff0c\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5357\u660c\u5927\u5b66\u5f6d\u949f\u6709\u52a9\u7406\u7814\u7a76\u5458\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u5357\u660c\u5927\u5b66<\/strong><strong>\/<\/strong><strong>\u6c5f\u897f\u5e08\u8303\u5927\u5b66\u9648\u4e49\u65fa\u6559\u6388\u4e0e\u5357\u660c\u5927\u5b66\u8c08\u5229\u627f\u6559\u6388\u3002<\/strong><\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-266891\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72472-13.png\" alt=\"\" width=\"500\" height=\"441\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72472-13.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72472-13-300x265.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\u56fe1 \u7535\u89e3\u6db2\u7684\u8868\u5f81\u4e0e\u6a21\u62df\u3002a 1 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u5bf9\u7535\u89e3\u6db2\u4e0e\u950c\u7535\u6781\u754c\u9762\u5316\u5b66\u5f71\u54cd\u7684\u793a\u610f\u56fe\u3002b \u2076\u2077Zn\u6838\u78c1\u5171\u632f\u8c31\uff0cc \u00b9\u2077O\u6838\u78c1\u5171\u632f\u8c31\uff0cd \u542b\u4e0d\u540cPS\u6d53\u5ea6\u7535\u89e3\u6db2\u7684FTIR\u5149\u8c31\uff0c\u4ee5\u53ca\uff08e\uff09\u542b\u4e0d\u540cPS\u6d53\u5ea6\u7535\u89e3\u6db2\u7684\u62c9\u66fc\u5149\u8c31\u3002f \u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2MD\u6a21\u62df\u3002g \u4eceMD\u6a21\u62df\u83b7\u53d6\u7684Zn\u00b2\u207a-O\u7684\u5f84\u5411\u5206\u5e03\u51fd\u6570\u548c\u914d\u4f4d\u6570\u3002h \u7ecf\u5f52\u4e00\u5316\u5904\u7406\u7684Zn K XANES\u5149\u8c31\u3002i EXAFS\u66f2\u7ebf\uff0c\u4ee5\u53ca\uff08j\uff091 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u7684Zn K\u8fb9XANES\u7684\u5c0f\u6ce2\u53d8\u6362\u7ed3\u679c\u3002k 1 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2Zeta\u7535\u4f4d\u3002l 1 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u5728\u88f8\u950c\u7b94\u4e0a\u7684\u63a5\u89e6\u89d2\uff08I\uff09\u3001\u9884\u6d78\u6ce1\u57281 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u7684\u950c\u7b94\u4e0a\u7684\u63a5\u89e6\u89d2\uff08III\uff09\uff0c\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u5728\u88f8\u950c\u7b94\u4e0a\u7684\u63a5\u89e6\u89d2\uff08II\uff09\u3001\u9884\u6d78\u6ce1\u5728\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u950c\u7b94\u4e0a\u7684\u63a5\u89e6\u89d2\uff08IV\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-266892\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72473-12.png\" alt=\"\" width=\"500\" height=\"359\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72473-12.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72473-12-300x215.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\u56fe2 PS\u5bf9Zn<sup>2+<\/sup>\u6c89\u79ef\/\u5265\u79bb\u884c\u4e3a\u7684\u5f71\u54cd\u7814\u7a76\u3002a \u94dc\u7535\u6781\u4ee5\u53ca\uff08b\uff09\u950c\u7535\u6781\u57281 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u5faa\u73af50\u6b21\u7684SEM\u56fe\u50cf\u3002\u57281 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u5faa\u73af50\u6b21\u7684\u950c\u7535\u6781\u7684\uff08c\uff09AFM\u56fe\u4ee5\u53ca\uff08d\uff09KPFM\u56fe\u3002e\u950c\u7535\u6781\u57281 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u5faa\u73af50\u6b21\u76842D GIWAXS\uff0c\u4ee5\u53ca\uff08f\uff09\uff08002\uff09\u6781\u56fe\u3002\u950c\u7535\u6781\u5728\uff08g\uff091 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\uff08h\uff09\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u5faa\u73af50\u6b21\u7684SECM\u56fe\u50cf\u3002i \u57281 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u4e2dEQCM\u7ed3\u679c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-266895\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72474-14.png\" alt=\"\" width=\"500\" height=\"373\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72474-14.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72474-14-300x224.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\u56fe3 \u542b\u6216\u4e0d\u542b\u6709PS\u7535\u89e3\u6db2\u4e2d\u950c\u7535\u6781\u7684\u7a33\u5b9a\u6027\u53ca\u4f5c\u7528\u673a\u7406\u7814\u7a76\u3002a H\u2082O\u5206\u5b50\u548cPS\u5206\u5b50\u5728\u4e0d\u540c\u950c\u6676\u9762\u4e0a\u7684\u5438\u9644\u80fd\u6bd4\u8f83\u3002b H\u2082O\u5206\u5b50\u548cPS\u5206\u5b50\u5728\u950c\uff08101\uff09\u6676\u9762\u7684\u7535\u8377\u5bc6\u5ea6\u5dee\u3002c \u57281 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u4e2d\u950c\u7535\u6781\u53cc\u7535\u5c42\u7535\u5bb9\u3002d \u963f\u4f26\u5c3c\u4e4c\u65af\u66f2\u7ebf\u4ee5\u53ca\u6d3b\u5316\u80fd\u7684\u6bd4\u8f83\u3002e \u950c\u7535\u6781\u7684\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\u3002f Zn<sup>2+<\/sup>\u6c89\u79ef\/\u5265\u79bb\u8fc7\u7a0b\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u3002g, h Zn<sup>2+<\/sup>\u6c89\u79ef\/\u5265\u79bb\u8fc7\u7a0b\u7684\u539f\u4f4dFTIR\u5149\u8c31\uff0ci Zn<sup>2+<\/sup>\u6c89\u79ef\u8fc7\u7a0b\u7684\u539f\u4f4d\u5149\u5b66\u663e\u5fae\u955c\u56fe\u50cf\u3002Zn||Zn\u5bf9\u79f0\u7535\u6c60\u5728\uff08j\uff091 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\uff08k\uff09\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u539f\u4f4dEIS\u3002l \u57285 mA\/cm\u00b2\u7535\u6d41\u5bc6\u5ea6\u4e0b\u950c\u7535\u6781\u8868\u9762\u5b9e\u65f6pH\u503c\u53d8\u5316\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-266896\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72475-12.png\" alt=\"\" width=\"500\" height=\"356\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72475-12.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72475-12-300x214.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\u56fe4 \u7a33\u5b9a\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u7684\u7ed3\u6784\u8868\u5f81\u53ca\u5f62\u6210\u673a\u7406\u7814\u7a76\u3002\u950c\u7535\u6781\u5728\u542b\u67091 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u4e2d\u5faa\u73af50\u6b21\u540e\u7684a C 1<em>s<\/em>\uff0cb F 1<em>s<\/em>\uff0cc S 2<em>p<\/em>\u548cd O 1<em>s<\/em>\u7684XPS\u3002e 1 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\uff08f\uff09\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u4e2d\u5faa\u73af50\u6b21\u540e\u950c\u7535\u6781\u7684ToF-SIMS\u3002g \u5728\u542b\u67091 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u4e2d\u5faa\u73af50\u6b21\u950c\u7535\u6781\u7684HRTEM\u56fe\u50cf\u3002h H<sub>2<\/sub>O\u5206\u5b50\u548cPS\u5206\u5b50\u7684LUMO\u53caHOMO\u7b49\u503c\u9762\u3002i 1 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u548c\uff08j\uff09\u542b\u67091 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u4e2d\uff0c\u950c\u7535\u6781\u950c\u6c89\u79ef\u8fc7\u7a0b\u6a21\u62df\u7535\u573a\u5206\u5e03\u60c5\u51b5\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-266898\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72476-9.png\" alt=\"\" width=\"500\" height=\"382\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72476-9.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72476-9-300x229.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\u56fe5 \u9ad8\u7a33\u5b9a\u53ca\u9ad8\u5229\u7528\u7387\u7684\u950c\u91d1\u5c5e\u7535\u6781\u3002a Zn||Zn\u5bf9\u79f0\u7535\u6c60\u57281 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u6c89\u79ef\/\u5265\u79bb\u7535\u5316\u5b66\u6027\u80fd\u3002b, c Zn||Zn\u5bf9\u79f0\u7535\u6c60\u57281 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u6c89\u79ef\/\u5265\u79bb\u7684\u500d\u7387\u6027\u80fd\u3002d Zn||Cu\u7535\u6c60\u57281 M Zn(OTf)<sub>2<\/sub>\u7535\u89e3\u6db2\u4ee5\u53ca\u542b1 <em>wt<\/em>% PS\u7684\u7535\u89e3\u6db2\u7684\u5e93\u4ed1\u6548\u7387\uff0c\u4ee5\u53ca\uff08e\uff09\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u4e0b\u76f8\u5e94\u7684\u7535\u538b\u66f2\u7ebf\u3002f Zn||Zn\u5bf9\u79f0\u7535\u6c60\u5728\u542b\u6709PS\u6dfb\u52a0\u5242\u7684\u4e0d\u540c\u950c\u76d0\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u7535\u5316\u5b66\u6027\u80fd\u3002g, h\u672c\u7814\u7a76\u4e0e\u8fd1\u671f\u6587\u732e\u4e2d\u7535\u89e3\u6db2\u6539\u6027\u7b56\u7565\u518d\u5faa\u73af\u53ef\u9006\u6027\u65b9\u9762\u5bf9\u6bd4\u5206\u6790\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-266899\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72477-9.png\" alt=\"\" width=\"500\" height=\"394\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72477-9.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72477-9-300x236.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\u56fe6 \u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002a \u4e0d\u540c\u7535\u89e3\u6db2\u7684\u6761\u4ef6\u4e0bZn||V\u2082O\u2085\/rGO\u5168\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u3002b \u4e0d\u540c\u7535\u89e3\u6db2\u7684\u6761\u4ef6\u4e0bZn||V\u2082O\u2085\/rGO\u5168\u7535\u6c60\u6052\u6d41\u5145\u653e\u7535\u5faa\u73af\u6027\u80fd\u3002c \u672c\u7814\u7a76\u5236\u5907\u7684\u7535\u6c60\u4e0e\u5df2\u62a5\u9053\u7684\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u5bf9\u6bd4\u3002d, e \u5728\u4e0d\u540c\u7535\u89e3\u6db2\u6761\u4ef6Zn||V\u2082O\u2085\/rGO\u5168\u7535\u6c60\u57285 A\/g\u7535\u6d41\u5bc6\u5ea6\u5faa\u73af1000\u6b21\u950c\u7535\u6781\u7684SEM\u56fe\u3002f \u5728\u4e0d\u540c\u7535\u89e3\u6db2\u6761\u4ef6\u5168\u7535\u6c60Zn\u00b2\u207a\u6269\u6563\u7cfb\u6570\u3002g \u4e0d\u540c\u7535\u89e3\u6db2\u7684\u6761\u4ef6\u4e0b\u5168\u7535\u6c60\u81ea\u653e\u7535\u884c\u4e3a\u3002h \u4e0d\u540c\u7535\u89e3\u6db2\u7684\u6761\u4ef6\u4e0bZn||V\u2082O\u2085\/rGO\u8f6f\u5305\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><strong>\u3010\u6587\u732e\u4fe1\u606f\u3011<\/strong><\/p>\n<p>Zhongyou Peng, Shulong Li, Ling Tang, Jinyang Zheng, Licheng Tan*, Yiwang Chen*, Water-shielding electric double layer and stable interphase engineering for durable aqueous zinc-ion batteries, <em>Nat Commun<\/em> 16, 4490 (2025). https:\/\/doi.org\/10.1038\/s41467-025-59830-y<\/p>\n<p><strong>\u3010\u76f8\u5173\u5de5\u4f5c\u5c55\u793a\u3011<\/strong><\/p>\n<p>1.Zhongyou Peng, Ling Tang, Shulong Li, Licheng Tan*, Yiwang Chen*, Strong Replaces Weak: Hydrogen Bond-Anchored Electrolyte Enabling Ultra-Stable and Wide-Temperature Aqueous Zinc-Ion Capacitors. <em> Chem. Int. Ed.<\/em> 64 (4), e202418242 (1-11) (2025). Hot Paper.<\/p>\n<p>2.Zhongyou Peng, Yuting Huang, Alexander G. Bannov, Shulong Li, Ling Tang, Licheng Tan*, Yiwang Chen*, Regulating oxygen vacancy and coordination environment of manganese dioxides for enhanced high-mass-loading energy storage. <em>Energy Environ. Sci.<\/em> 17 (10), 3384-3395 (2024). ESI Highly Cited Paper.<\/p>\n<p>3.Zhongyou Peng, Alexander G. Bannov, Shulong Li, Yuting Huang, Ling Tang, Licheng Tan*, Yiwang Chen*, Coupling Uniform Pore Size and Multi\u2011Chemisorption Sites: Hierarchically Ordered Porous Carbon for Ultra-fast and Large Zinc Ion Storage. <em> Funct. Mater.<\/em> 33 (40) 2303205 (1-11) (2023).<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u7814\u7a76\u80cc\u666f\u3011 \u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff08ZIBs\uff09\u51ed\u501f\u950c\u91d1\u5c5e\u7535\u6781\u9ad8\u7406\u8bba\u5bb9\u91cf\u3001\u4f4e\u7535\u5316\u5b66\u7535\u4f4d\u3001\u8d44\u6e90\u4e30\u5bcc\u53ca\u4f4e\u6210\u672c\u7b49\u4f18\u52bf\uff0c\u6210\u4e3a\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u6781\u5177\u7ade\u4e89\u529b\u7684\u6280\u672f\u65b9\u6848\u3002\u7136\u800c\uff0c\u5176\u5546\u4e1a\u5316\u8fdb&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-266888","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/266888"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=266888"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/266888\/revisions"}],"predecessor-version":[{"id":266900,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/266888\/revisions\/266900"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=266888"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=266888"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=266888"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}