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loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266682\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72475-4.png\" alt=\"\" width=\"1269\" height=\"756\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72475-4.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72475-4-300x179.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72475-4-768x458.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72475-4-1024x610.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/strong><\/p>\n<p>\u56fe3\u3001Hollandite\u7535\u6781\u6750\u6599\u7684\u50a8\u94a0\u53cd\u5e94\u673a\u5236<\/p>\n<p>&nbsp;<\/p>\n<p>\u79bb\u5b50\u5d4c\u5165\u4f4d\u70b9\u53ca\u5176\u7ed3\u6784\u6548\u5e94<\/p>\n<p>\u57282\u00d72\u96a7\u9053\u7ed3\u6784\u7684\u5047\u6c27\u8154\u5185\uff0c\u5b58\u57285\u4e2a\u4e0d\u540c\u5bf9\u79f0\u6027\u7684\u7ed3\u5408\u4f4d\u70b9\uff082a\u30012b\u30014e\u30018h\u30018h&#8217;\uff09\uff0c\u7528\u4e8e\u5bb9\u7eb3\u8f7d\u6d41\u5b50\u3002\u5c0f\u9633\u79bb\u5b50\uff08\u5982Li\u207a\u3001Na\u207a\uff09\u901a\u5e38\u503e\u5411\u4e8e\u5360\u636e8h\u62168h&#8217;\u4f4d\u70b9\uff0c\u800c\u4e0d\u662f\u4e2d\u5fc3\u4f4d\u70b9\u3002\u968f\u7740\u9633\u79bb\u5b50\u6d53\u5ea6\u7684\u589e\u52a0\uff0c\u4f4d\u70b9\u504f\u597d\u4f1a\u53d1\u751f\u53d8\u5316\uff0c\u540c\u65f6\u6676\u4f53\u7ed3\u6784\u4e5f\u4f1a\u53d1\u751f\u53d8\u5f62\u3002\u968f\u7740\u9633\u79bb\u5b50\u6d53\u5ea6\u7684\u5347\u9ad8\uff0c\u6676\u683c\u4f1a\u53d1\u751f\u81a8\u80c0\uff0c\u5bfc\u81f4\u6676\u80de\u4f53\u79ef\u589e\u5927\uff0c\u5e76\u4e14\u8fd9\u79cd\u81a8\u80c0\u8868\u73b0\u51fa\u5404\u5411\u5f02\u6027\u3002\u4e3a\u4e86\u7ef4\u6301\u7535\u8377\u4e2d\u6027\uff0c\u516b\u9762\u4f53\u9633\u79bb\u5b50\u53ef\u80fd\u4f1a\u53d1\u751f\u8fd8\u539f\u53cd\u5e94\uff0c\u8fd9\u53ef\u80fd\u4f1a\u5f15\u53d1Jahn-Teller\u7578\u53d8\uff0c\u4ece\u800c\u5bfc\u81f4\u7ed3\u6784\u5931\u6548\u3002\u56e0\u6b64\uff0c\u7814\u7a76\u79bb\u5b50\u5360\u636e\u60c5\u51b5\uff0c\u6709\u52a9\u4e8e\u7406\u89e3\u79bb\u5b50\u4f20\u8f93\u673a\u5236\uff0c\u9610\u91ca\u7ed3\u6784-\u6027\u80fd\u5173\u7cfb\uff0c\u6307\u5bfc\u7535\u6781\u6750\u6599\u8bbe\u8ba1\uff0c\u63d0\u5347\u79bb\u5b50\u4f20\u8f93\u548c\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266683\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72476-3.png\" alt=\"\" width=\"1267\" height=\"755\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72476-3.png 1267w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72476-3-300x179.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72476-3-768x458.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72476-3-1024x610.png 1024w\" sizes=\"(max-width: 1267px) 100vw, 1267px\" \/><\/strong><\/p>\n<p>\u56fe4\u3001Hollandite\u7535\u6781\u6750\u6599\u5728\u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u79bb\u5b50\u5d4c\u5165\u4f4d\u70b9\u53ca\u5176\u7ed3\u6784\u6548\u5e94\u7814\u7a76<\/p>\n<p>&nbsp;<\/p>\n<p>\uff08\u4e09\uff09\u8d85\u7ea7\u7535\u5bb9<\/p>\n<p>\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u9886\u57df\uff0cHollandite\u6750\u6599\u51ed\u501f\u5176\u4e00\u7ef4\u5b54\u7ed3\u6784\u548c\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u6846\u67b6\u4e0a\u7684\u53ef\u53d8\u4ef7\u79bb\u5b50\u7684\u8868\u9762\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u5c55\u73b0\u51fa\u8d5d\u7535\u5bb9\u7279\u6027\u3002\u8fd9\u79cd\u7279\u6027\u4f7f\u5f97Hollandite\u7535\u6781\u6750\u6599\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u5176\u51fa\u8272\u7684\u7535\u5316\u5b66\u6027\u80fd\u5f97\u76ca\u4e8e\u4e24\u79cd\u673a\u5236\u7684\u534f\u540c\u4f5c\u7528\uff1a\u4e00\u662f\u4e3a\u5ba2\u4f53\u79bb\u5b50\uff08\u5982K<sup>+<\/sup>\u3001Na<sup>+<\/sup>\uff09\u63d0\u4f9b\u5feb\u901f\u8f93\u9001\u8def\u5f84\uff0c\u589e\u5f3a\u7ed3\u6784\u7a33\u5b9a\u6027\uff1b\u4e8c\u662f\u8bf1\u53d1\u8868\u9762\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u8d21\u732e\u8d5d\u7535\u5bb9\u7279\u6027\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266684\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72477-3.png\" alt=\"\" width=\"1267\" height=\"752\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72477-3.png 1267w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72477-3-300x178.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72477-3-768x456.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72477-3-1024x608.png 1024w\" sizes=\"(max-width: 1267px) 100vw, 1267px\" \/><\/strong><\/p>\n<p>\u56fe5\u3001Hollandite\u7535\u6781\u6750\u6599\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u53cd\u5e94\u673a\u5236<\/p>\n<p>\uff08\u56db\uff09\u6c34\u7cfb\u950c\u7535<\/p>\n<p>\u5728\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u03b1-MnO<sub>2<\/sub>\u4f5c\u4e3a\u6b63\u6781\u6750\u6599\u5c55\u73b0\u51fa\u590d\u6742\u7684\u7535\u5316\u5b66\u884c\u4e3a\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u03b1-MnO<sub>2<\/sub>\u4e2dZn<sup>2+<\/sup>\u7684\u5d4c\u5165\/\u8131\u51fa\u3001H<sup>+<\/sup>\u7684\u5d4c\u5165\u673a\u5236\u3001Zn<sup>2+<\/sup>\u548cH<sup>+<\/sup>\u5171\u5d4c\u5165\u673a\u5236\u4ee5\u53ca\u6eb6\u89e3-\u6c89\u79ef\u673a\u5236\u5171\u540c\u4f5c\u7528\uff0c\u5f71\u54cd\u7535\u6c60\u7684\u6027\u80fd\u3002\u4e0e\u975e\u6c34\u7cfb\u7535\u6c60\u76f8\u6bd4\uff0c\u6c34\u7cfb\u7535\u89e3\u6db2\u7cfb\u7edf\u4e2d\u590d\u6742\u7684\u5bb9\u91cf\u9a71\u52a8\u673a\u5236\u548c\u4e0d\u53ef\u907f\u514d\u7684\u526f\u53cd\u5e94\u4f7f\u5f97\u7535\u5316\u5b66\u8fc7\u7a0b\u66f4\u52a0\u590d\u6742\uff0c\u5bfc\u81f4\u5173\u4e8e\u03b1-MnO<sub>2<\/sub>\u5728\u5f31\u9178\u6027ZnSO<sub>4<\/sub>\u7535\u89e3\u6db2\u6eb6\u6db2\u4e2d\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u548c\u5bb9\u91cf\u8870\u51cf\u80cc\u540e\u7684\u7535\u8377\u5b58\u50a8\u673a\u5236\u4ecd\u5b58\u5728\u4e89\u8bae\u548c\u6311\u6218\u3002\u76ee\u524d\uff0c\u5173\u4e8e\u03b1-MnO<sub>2<\/sub>\u5728\u6c34\u7cfbZIBs\u4e2d\u7684\u7535\u8377\u5b58\u50a8\u673a\u5236\u4e3b\u8981\u6709\u4ee5\u4e0b\u51e0\u79cd\u89c2\u70b9\uff1a<\/p>\n<p>1.Zn<sup>2+<\/sup>\u7684\u5d4c\u5165\u673a\u5236\uff1a<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266685\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72478-2.png\" alt=\"\" width=\"1267\" height=\"967\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72478-2.png 1267w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72478-2-300x229.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72478-2-768x586.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72478-2-1024x782.png 1024w\" sizes=\"(max-width: 1267px) 100vw, 1267px\" \/><\/strong><\/p>\n<p>\u56fe6\u3001\u03b1-MnO<sub>2<\/sub>\u4e2dZn<sup>2+<\/sup>\u7684\u5d4c\u5165\u673a\u5236<\/p>\n<p>&nbsp;<\/p>\n<p>2.Zn<sup>2+<\/sup>\u548cH<sup>+<\/sup>\u7684\u5171\u5d4c\u5165\u673a\u5236\u548cH<sup>+<\/sup>\u5d4c\u5165\u673a\u5236\uff1a<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266686\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72479-1.png\" alt=\"\" width=\"1269\" height=\"1288\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72479-1.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72479-1-296x300.png 296w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72479-1-768x779.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u72479-1-1009x1024.png 1009w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/strong><\/p>\n<p>\u56fe7\u3001\u03b1-MnO<sub>2<\/sub>\u4e2dZn<sup>2+<\/sup>\u548cH<sup>+<\/sup>\u7684\u5171\u5d4c\u5165\u673a\u5236\u548cH<sup>+<\/sup>\u5d4c\u5165\u673a\u5236\uff1aH<sup>+<\/sup>\u548cZHS\u5b58\u5728\u7684\u8bc1\u636e<\/p>\n<p>&nbsp;<\/p>\n<p>3.\u6eb6\u89e3-\u6c89\u79ef\u673a\u5236\uff1a<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266687\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u724710.png\" alt=\"\" width=\"1269\" height=\"854\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u724710.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u724710-300x202.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u724710-768x517.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u56fe\u724710-1024x689.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/strong><\/p>\n<p>\u56fe8\u3001\u03b1-MnO<sub>2<\/sub>\u7684\u6eb6\u89e3-\u6c89\u79ef\u673a\u5236\u548cTOC-Al\u7684\u754c\u9762\u5b58\u50a8\u673a\u5236<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong><b>\u5c55\u671b<\/b><\/strong><\/p>\n<p>\u5c3d\u7ba1Hollandite\u6750\u6599\u5728\u80fd\u6e90\u5b58\u50a8\u9886\u57df\u5177\u6709\u5de8\u5927\u6f5c\u529b\uff0c\u4f46\u4ecd\u9762\u4e34\u8bf8\u591a\u6311\u6218\uff0c\u5982 J-T \u6548\u5e94\u5bfc\u81f4\u7684\u7ed3\u6784\u5931\u6548\u3001\u7535\u8377\u5b58\u50a8\u673a\u5236\u590d\u6742\u7b49\u3002\u672a\u6765\u7814\u7a76\u65b9\u5411\u5305\u62ec\u901a\u8fc7\u5ba2\u4f53\u79bb\u5b50\u8c03\u8282\u5b9e\u73b0\u96a7\u9053\u5de5\u7a0b\u3001\u7ed3\u6784\u8c03\u5236\u4e0e\u4f18\u5316\uff08\u5982\u79bb\u5b50\u63ba\u6742\u3001\u590d\u5408\u6750\u6599\u5236\u5907\u3001\u7ed3\u6784\u7eb3\u7c73\u5316\uff09\u3001\u5b9a\u91cf\u5206\u6790J-T\u6548\u5e94\u52a8\u6001\u3001\u7406\u8bba\u8ba1\u7b97\u6a21\u62df\u4ee5\u53ca\u5f00\u53d1\u5148\u8fdb\u8868\u5f81\u5de5\u5177\u7b49\uff0c\u65e8\u5728\u4f18\u5316\u6750\u6599\u6027\u80fd\uff0c\u63a8\u52a8\u5176\u5728\u80fd\u6e90\u5b58\u50a8\u6280\u672f\u4e2d\u7684\u5e94\u7528\u3002\u6587\u7ae0\u6700\u540e\u5f3a\u8c03\uff0c\u901a\u8fc7\u6df1\u5165\u7406\u89e3Hollandite\u6750\u6599\u7684\u7ed3\u6784-\u6027\u80fd\u5173\u7cfb\uff0c\u7ed3\u5408\u7ed3\u6784\/\u6210\u5206\u5de5\u7a0b\u7b56\u7565\uff0c\u6709\u671b\u4f7f\u5176\u5728\u80fd\u6e90\u5b58\u50a8\u9886\u57df\u53d1\u6325\u66f4\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1a<\/p>\n<p>&nbsp;<\/p>\n<p>The Role of Tunnel-Structured Hollandite Material Family for Advancing Energy Storage,\u00a0Xuemei Zeng, Kun He, Xiaomei Li, Yanshuai Li*, Yifei Yuan *,\u00a0<em><i>Adv. Funct. 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