{"id":266628,"date":"2025-05-03T06:37:16","date_gmt":"2025-05-02T22:37:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=266628"},"modified":"2025-05-02T21:37:37","modified_gmt":"2025-05-02T13:37:37","slug":"%e5%8d%97%e7%a7%91%e5%a4%a7%e6%9c%80%e6%96%b0nature","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=266628","title":{"rendered":"\u5357\u79d1\u5927\u6700\u65b0Nature!!!"},"content":{"rendered":"<p class=\"\" data-compareid=\"0\">\u4e8c\u8302\u94c1\u7684\u53d1\u73b0\u9884\u793a\u4e86\u73b0\u4ee3\u6709\u673a\u91d1\u5c5e\u5316\u5b66\u7684\u8bde\u751f\u3002\u4e8c\u8302\u94c1\u53ca\u5176\u7c7b\u4f3c\u7269\u4ee5\u4e00\u4e2a\u6216\u4e24\u4e2a\u5e73\u9762\u73af\u70ef\u9634\u79bb\u5b50\u4e0e\u91d1\u5c5e\u03c0\u914d\u4f4d\u4e3a\u7279\u5f81\uff0c\u662f\u5e73\u9762\u5916\u73af\u70ef\u91d1\u5c5e\u914d\u5408\u7269\u7684\u5178\u578b\u4ee3\u8868\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u7531\u4e8e\u5408\u6210\u96be\u5ea6\u5927\u4ee5\u53ca\u5177\u6709\u9002\u5f53\u5185\u90e8\u5c3a\u5bf8\u7684\u73af\u70ef\u975e\u5e73\u9762\u6027\uff0c\u4ee5\u53ca\u5d4c\u5165\u91d1\u5c5e\u7684\u56f0\u96be\uff0c\u5c06\u91d1\u5c5e\u6574\u5408\u5230\u73af\u70ef\u6838\u5fc3\u4e2d\u5f62\u6210\u5e73\u9762\u5185\u73af\u70ef\u91d1\u5c5e\u914d\u5408\u7269\u53d7\u5230\u4e86\u963b\u788d\u3002\u8fd9\u4e9b\u6311\u6218\u963b\u6b62\u4e86\u6b64\u7c7b\u5e73\u9762\u5185\u73af\u70ef\u91d1\u5c5e\u914d\u5408\u7269\u7684\u5206\u79bb\u3002\u5357\u65b9\u79d1\u6280\u5927\u5b66\u5316\u5b66\u7cfb\u8bb2\u5e2d\u6559\u6388\u3001\u6df1\u5733\u683c\u62c9\u5e03\u65af\u7814\u7a76\u9662\u6267\u884c\u9662\u957f\u590f\u6d77\u5e73\u56e2\u961f\u901a\u8fc7\u539f\u521b\u7684\u5408\u6210\u7b56\u7565\uff0c\u9996\u6b21\u5b9e\u73b0\u91d1\u5c5e\u4e2d\u5fc3\u5e73\u9762\u8f6e\u70ef\u7684\u6784\u7b51\uff0c\u63ed\u793a\u4e86\u91d1\u5c5e-\u78b3\u5171\u8f6d\u7684\u65b0\u673a\u5236\uff0c\u62d3\u5c55\u4e86\u82b3\u9999\u5316\u5b66\u3001\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u7684\u8fb9\u754c\uff0c\u5e76\u4e3a\u8de8\u5b66\u79d1\u7814\u7a76\u63d0\u4f9b\u4e86\u5168\u65b0\u5206\u5b50\u5e73\u53f0\u3002\u5176\u9ad8\u7a33\u5b9a\u6027\u548c\u529f\u80fd\u5316\u6f5c\u529b\uff0c\u9884\u793a\u4e86\u5728\u50ac\u5316\u3001\u5149\u7535\u5b50\u5668\u4ef6\u7b49\u9886\u57df\u7684\u5e94\u7528\u524d\u666f\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u57284\u670830\u65e5\u4ee5\u201cMetal-centered planar [15]annulenes\u201d\u4e3a\u9898\u53d1\u8868\u4e8eNature\u3002<\/p>\n<p data-compareid=\"0\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-266629\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u5fae\u4fe1\u622a\u56fe_20250502212903.jpg\" alt=\"\" width=\"799\" height=\"319\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u5fae\u4fe1\u622a\u56fe_20250502212903.jpg 799w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u5fae\u4fe1\u622a\u56fe_20250502212903-300x120.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/05\/\u5fae\u4fe1\u622a\u56fe_20250502212903-768x307.jpg 768w\" sizes=\"(max-width: 799px) 100vw, 799px\" \/><strong>1. \u9996\u6b21\u5b9e\u73b0\u91d1\u5c5e\u4e2d\u5fc3\u5e73\u9762\u8f6e\u70ef\u7684\u5408\u6210<\/strong><\/p>\n<p data-compareid=\"0\"><strong>\u7a81\u7834\u6027\u7ed3\u6784\u8bbe\u8ba1<\/strong>\uff1a\u6210\u529f\u5c06\u91d1\u5c5e\uff08\u5982\u948c\u3001\u94fc\u7b49\uff09\u5d4c\u5165\u5e73\u9762\u8f6e\u70ef\u7684\u6838\u5fc3\u4f4d\u7f6e\uff0c\u5f62\u6210\u5177\u6709<strong>D\u2085\u2095\u5bf9\u79f0\u6027<\/strong>\u7684\u5206\u5b50\u6846\u67b6\u3002\u8fd9\u662f\u9996\u6b21\u5728\u8f6e\u70ef\u5e73\u9762\u5185\u6574\u5408\u91d1\u5c5e\uff0c\u89e3\u51b3\u4e8670\u5e74\u6765\u91d1\u5c5e\u65e0\u6cd5\u5d4c\u5165\u5e73\u9762\u8f6e\u70ef\u7684\u96be\u9898\u3002<strong>\u586b\u8865\u9886\u57df\u7a7a\u767d<\/strong>\uff1a\u4f20\u7edf\u91d1\u5c5e\u8f6e\u70ef\uff08\u5982\u4e8c\u8302\u94c1\uff09\u4e3a\u5e73\u9762\u5916\u914d\u4f4d\u7ed3\u6784\uff0c\u800c\u672c\u5de5\u4f5c\u5b9e\u73b0\u4e86\u91d1\u5c5e\u4e0e\u8f6e\u70ef\u73af\u7684<strong>\u03c3\u952e\u7ed3\u5408<\/strong>\uff0c\u5f00\u8f9f\u4e86\u5168\u65b0\u7684\u201c\u5e73\u9762\u91d1\u5c5e\u8f6e\u70ef\u201d\u7814\u7a76\u65b9\u5411\u3002<\/p>\n<p data-compareid=\"0\"><strong>2. \u521b\u65b0\u7684\u5408\u6210\u7b56\u7565\uff1a\u78b3\u9f99\u5316\u5b66\u8d4b\u80fd<\/strong><\/p>\n<p data-compareid=\"0\"><strong>\u6838\u5fc3\u53cd\u5e94<\/strong>\uff1a\u5229\u7528\u56e2\u961f\u539f\u521b\u7684\u201c\u78b3\u9f99\u914d\u5408\u7269\u201d\uff08Carbolong Complexes\uff09\u4e0e\u7094\u70c3\u7684<strong>\u73af\u52a0\u6210\u53cd\u5e94<\/strong>\uff0c\u9ad8\u6548\u6784\u7b51\u5e73\u9762\u91d1\u5c5e\u8f6e\u70ef\u3002<\/p>\n<p data-compareid=\"0\"><strong>\u514b\u670d\u4f20\u7edf\u969c\u788d<\/strong>\uff1a\u901a\u8fc7\u7cbe\u786e\u8c03\u63a7\u8f6e\u70ef\u5c3a\u5bf8\uff0815\u5143\u73af\uff09\u548c\u5e73\u9762\u6027\uff0c\u7a81\u7834\u5c0f\u73af\u8f6e\u70ef\uff08\u5982\u82ef\uff09\u5c3a\u5bf8\u4e0d\u8db3\u3001\u4e2d\u5927\u73af\u8f6e\u70ef\u975e\u5e73\u9762\u7684\u7ed3\u6784\u56f0\u5883\uff0c\u540c\u65f6\u89e3\u51b3\u8f6e\u70ef\u7f3a\u4e4f\u5bfc\u5411\u57fa\u56e2\u7684\u91d1\u5c5e\u6d3b\u5316\u96be\u9898\u3002<\/p>\n<p data-compareid=\"0\"><strong>3. \u91d1\u5c5e-\u78b3\u5171\u8f6d\u4e0e\u5f3a\u82b3\u9999\u6027<\/strong><\/p>\n<p data-compareid=\"0\"><strong>\u7535\u5b50\u7ed3\u6784\u521b\u65b0<\/strong>\uff1a\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u91d1\u5c5e\u7684<strong>d\u8f68\u9053<\/strong>\u4e0e\u4e94\u4e2a\u4e94\u5143\u73af\u53d1\u751f\u5171\u8f6d\uff0c\u8d4b\u4e88\u6574\u4e2a\u4f53\u7cfb\u5f3a\u82b3\u9999\u6027\u3002<\/p>\n<p data-compareid=\"0\"><strong>\u82b3\u9999\u6027\u6307\u6807\u8d85\u8d8a\u82ef<\/strong>\uff1a<strong>\u6838\u78c1\u5171\u632f\uff08\u00b9H NMR\uff09<\/strong>\uff1a\u8f6e\u70ef\u73af\u4e0a10\u4e2a\u6c22\u7684\u5316\u5b66\u4f4d\u79fb\u4e3a9.43 ppm\uff08\u82ef\u4e3a7.36 ppm\uff09\uff0c\u8868\u660e\u66f4\u5f3a\u7684\u73af\u7535\u6d41\u6548\u5e94\u3002<strong>\u6838\u72ec\u7acb\u5316\u5b66\u4f4d\u79fb\uff08NICS(1)zz\uff09<\/strong>\uff1a-41.9 ppm\uff08\u82ef\u4e3a-29.3 ppm\uff09\u3002<strong>\u82b3\u9999\u7a33\u5b9a\u5316\u80fd\uff08ASE\uff09<\/strong>\uff1a93.3 kcal\/mol\uff08\u82ef\u4e3a33.1 kcal\/mol\uff09\u3002<\/p>\n<p data-compareid=\"0\"><strong>4. \u67b6\u8d77\u8f6e\u70ef\u5316\u5b66\u4e0e\u535f\u5549\u5316\u5b66\u7684\u6865\u6881<\/strong><\/p>\n<p data-compareid=\"0\"><strong>\u7ed3\u6784\u7c7b\u6bd4\u91d1\u5c5e\u535f\u5549<\/strong>\uff1a\u5e73\u9762\u91d1\u5c5e\u8f6e\u70ef\u53ef\u89c6\u4e3a\u201c\u8131\u6c2e\u5168\u78b3\u535f\u5549\u201d\uff0c\u586b\u8865\u4e86\u201c\u5168\u78b3\u535f\u5549\u201d\u96be\u4ee5\u5408\u6210\u7684\u7a7a\u767d\u3002<\/p>\n<p data-compareid=\"0\"><strong>\u8de8\u5b66\u79d1\u878d\u5408<\/strong>\uff1a\u5c06\u8f6e\u70ef\u7684\u7eaf\u78b3\u9aa8\u67b6\u4e0e\u535f\u5549\u7684\u591a\u914d\u4f4d\u7279\u6027\u7ed3\u5408\uff0c\u4e3a\u65e0\u673a-\u6709\u673a\u6742\u5316\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n<p data-compareid=\"0\"><strong>5. \u4f18\u5f02\u7684\u7406\u5316\u6027\u80fd\u4e0e\u5e94\u7528\u6f5c\u529b<\/strong><\/p>\n<p data-compareid=\"0\"><strong>\u9ad8\u7a33\u5b9a\u6027<\/strong>\uff1a\u56fa\u4f53\u5728\u7a7a\u6c14\u4e2d240\u2103\u4e0b\u7a33\u5b9a\uff0c\u7535\u5316\u5b66\u53ef\u9006\u6027\u5ab2\u7f8e\u4e8c\u8302\u94c1\u3002<\/p>\n<p data-compareid=\"0\"><strong>\u72ec\u7279\u5149\u54cd\u5e94<\/strong>\uff1a\u5177\u6709<strong>\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\uff08AIE\uff09<\/strong>\u6548\u5e94\uff0c\u7d2b\u5916\u5149\u4e0b\u53d1\u51fa\u7ea2\u5149\uff0c\u53ef\u80fd\u7528\u4e8e\u5149\u7535\u6750\u6599\u3002<\/p>\n<p data-compareid=\"0\"><strong>\u6613\u529f\u80fd\u5316<\/strong>\uff1a\u53ef\u8fdb\u884c\u785d\u5316\u3001\u7898\u4ee3\u3001\u5168\u6c2f\u4ee3\u7b49\u82b3\u70c3\u53cd\u5e94\uff0c\u8f74\u5411\u914d\u4f53\u53ef\u66ff\u6362\uff0c\u9002\u5408\u4f5c\u4e3a\u4e8c\u7ef4\/\u4e09\u7ef4\u6750\u6599\u7684\u6784\u7b51\u57fa\u5143\u3002<\/p>\n<p><img decoding=\"async\" title=\"291745916779284470.jpg\" src=\"https:\/\/newshub.sustech.edu.cn\/uploads\/full\/2025\/04\/291745916779284470.jpg\" alt=\"4.jpg\" \/><\/p>\n<p>\u56fe\u00a0 \u5e73\u9762\u91d1\u5c5e[15]\u8f6e\u70ef\u7684\u884d\u751f\u5316\u53cd\u5e94<\/p>\n<p data-compareid=\"0\">\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u5176\u72ec\u7279\u7684\u79d1\u5b66\u4ef7\u503c\uff0c\u5411\u9996\u4e2a\u8f6e\u70ef\u5206\u5b50\u2014\u2014\u82ef\u7684\u53d1\u73b0200\u5468\u5e74\u732e\u4e0a\u4e86\u4e00\u4efd\u5b8c\u7f8e\u7684\u5b66\u672f\u8d3a\u793c\u3002\u590f\u6d77\u5e73\u56e2\u961f\u5efa\u8bae\u5c06\u5176\u547d\u540d\u4e3a\u201cCarborin\u201d\uff0c\u8fd9\u4e00\u547d\u540d\u65e2\u5de7\u5999\u878d\u5408\u4e86\u78b3\uff08<em>Carbon<\/em>\uff09\u3001\u535f\u5549\uff08Porphy<em>rin<\/em>\uff09\u3001\u73af\u72b6\u7ed3\u6784\uff08<em>Ring<\/em>\uff09\u4e09\u91cd\u6838\u5fc3\u79d1\u5b66\u5185\u6db5\uff0c\u53c8\u4f53\u73b0\u4e86\u5176\u5206\u5b50\u7ed3\u6784\u7684\u72ec\u7279\u9b45\u529b\u3002<\/p>\n<p data-compareid=\"0\">\u8bba\u6587\u5730\u5740\uff1ahttps:\/\/www.nature.com\/articles\/s41586-025-08841-2<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e8c\u8302\u94c1\u7684\u53d1\u73b0\u9884\u793a\u4e86\u73b0\u4ee3\u6709\u673a\u91d1\u5c5e\u5316\u5b66\u7684\u8bde\u751f\u3002\u4e8c\u8302\u94c1\u53ca\u5176\u7c7b\u4f3c\u7269\u4ee5\u4e00\u4e2a\u6216\u4e24\u4e2a\u5e73\u9762\u73af\u70ef\u9634\u79bb\u5b50\u4e0e\u91d1\u5c5e\u03c0\u914d\u4f4d\u4e3a\u7279\u5f81\uff0c\u662f\u5e73\u9762\u5916\u73af\u70ef\u91d1\u5c5e\u914d\u5408\u7269\u7684\u5178\u578b\u4ee3\u8868\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u7531\u4e8e\u5408\u6210\u96be\u5ea6&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-266628","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/266628"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=266628"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/266628\/revisions"}],"predecessor-version":[{"id":266630,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/266628\/revisions\/266630"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=266628"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=266628"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=266628"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}