{"id":266454,"date":"2025-04-25T08:40:15","date_gmt":"2025-04-25T00:40:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=266454"},"modified":"2025-04-25T08:40:15","modified_gmt":"2025-04-25T00:40:15","slug":"%e5%a4%9a%e6%a0%a1%e5%90%88%e4%bd%9c%e6%9c%80%e6%96%b0science%ef%bc%9a%e8%b6%85%e7%a8%b3mofpom%e5%82%ac%e5%8c%96%e5%89%82%ef%bc%8c%e7%aa%81%e7%a0%b4%e9%ab%98%e6%95%88%e7%94%b5%e8%a7%a3%e6%b0%b4","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=266454","title":{"rendered":"\u591a\u6821\u5408\u4f5c\u6700\u65b0Science\uff1a\u8d85\u7a33MOF@POM\u50ac\u5316\u5242\uff0c\u7a81\u7834\u9ad8\u6548\u7535\u89e3\u6c34\u5236\u6c22\u74f6\u9888"},"content":{"rendered":"

\u591a\u6821\u5408\u4f5c\u6700\u65b0<\/strong>Science<\/strong>\uff1a\u8d85\u7a33<\/strong>MOF@POM<\/strong>\u50ac\u5316\u5242\uff0c\u7a81\u7834\u9ad8\u6548\u7535\u89e3\u6c34\u5236\u6c22\u74f6\u9888<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><\/p>\n

\u78b1\u6027\u6c34\u7535\u89e3\u5236\u6c22\u662f\u5b9e\u73b0\u7eff\u8272\u6c22\u80fd\u89c4\u6a21\u5316\u5e94\u7528\u7684\u5173\u952e\u6280\u672f\uff0c\u4f46\u5176\u6838\u5fc3\u6311\u6218\u5728\u4e8e\u5f00\u53d1\u9ad8\u6548\u3001\u7a33\u5b9a\u4e14\u975e\u8d35\u91d1\u5c5e\u7684\u9633\u6781\u50ac\u5316\u5242\u3002\u5f53\u524d\u5e7f\u6cdb\u7814\u7a76\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u548c\u5c42\u72b6\u53cc\u6c22\u6c27\u5316\u7269\uff08LDH\uff09\u7b49\u6750\u6599\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u6613\u53d1\u751f\u6d3b\u6027\u4f4d\u70b9\u6eb6\u89e3\u548c\u7ed3\u6784\u574d\u584c\uff0c\u5bfc\u81f4\u6027\u80fd\u5feb\u901f\u8870\u51cf\u3002\u6b64\u5916\uff0c\u4f20\u7edf\u50ac\u5316\u5242\u7535\u5b50\u4f20\u8f93\u6548\u7387\u4f4e\u3001\u8fc7\u7535\u4f4d\u9ad8\uff0c\u96be\u4ee5\u6ee1\u8db3\u5de5\u4e1a\u7535\u89e3\u69fd\u5bf9\u4f4e\u80fd\u8017\u4e0e\u957f\u5bff\u547d\u7684\u4e25\u82db\u9700\u6c42\u3002\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\uff08POM\uff09\u56e0\u5176\u72ec\u7279\u7684\u7535\u5b50\u4f20\u9012\u80fd\u529b\u88ab\u89c6\u4e3a\u6f5c\u5728\u6539\u6027\u6750\u6599\uff0c\u4f46\u5176\u4e0eMOF\u7684\u534f\u540c\u4f5c\u7528\u673a\u5236\u53ca\u7a33\u5b9a\u6027\u63d0\u5347\u7b56\u7565\u5c1a\u4e0d\u660e\u786e\u3002\u672c\u6587\u9488\u5bf9\u4e0a\u8ff0\u95ee\u9898\uff0c\u63d0\u51fa\u901a\u8fc7\u81ea\u7ec4\u88c5\u7b56\u7565\u5c06POM\u4e0eCoFe-MOF\u590d\u5408\uff0c\u6784\u5efa\u5177\u6709\u7a33\u5b9a\u8d85\u7ed3\u6784\u7684MOF@POM\u50ac\u5316\u5242\uff0c\u65e8\u5728\u89e3\u51b3\u6d3b\u6027\u4f4d\u70b9\u6eb6\u89e3\u4e0e\u7535\u5b50\u4f20\u8f93\u74f6\u9888\uff0c\u63a8\u52a8\u78b1\u6027\u6c34\u7535\u89e3\u6280\u672f\u7684\u5b9e\u7528\u5316\u8fdb\u7a0b<\/strong>\u3002<\/p>\n

\u00a0<\/strong><\/p>\n

\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n

\u4eca\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u7845\u9178\u76d0\u7814\u7a76\u6240\u4e25\u96c5\u3001\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u590f\u5b9d\u7389\u3001\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u9ec4\u5bcc\u5f3a\u3001\u65b0\u897f\u5170\u5965\u514b\u5170\u5927\u5b66\u738b\u5b50\u8fd0\u3001\u5185\u8499\u53e4\u4f4e\u78b3\u50ac\u5316\u91cd\u70b9\u5b9e\u9a8c\u5ba4Jiangwei Zhang\u8bfe\u9898\u7ec4\u5408\u4f5c\uff0c\u901a\u8fc7\u53cc\u6a21\u677f\u81ea\u7ec4\u88c5\u7b56\u7565\uff0c\u5c06\u954d\u6865\u8054\u7684\u78f7\u94a8\u9178\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\uff08PW\u2089\uff09\u4e0eCoFe-MOF\u590d\u5408\uff0c\u6210\u529f\u5236\u5907\u51faMOF@POM\u8d85\u7ed3\u6784\u50ac\u5316\u5242<\/strong>\u3002\u8be5\u6750\u6599\u5728\u7535\u5316\u5b66\u6c34\u6c27\u5316\u8fc7\u7a0b\u4e2d\u539f\u4f4d\u8f6c\u5316\u4e3a\u91d1\u5c5e\uff08\u6c27\uff09\u6c22\u6c27\u5316\u7269\u6d3b\u6027\u76f8\uff0c\u5c55\u73b0\u51fa178 mV\u7684\u4f4e\u8fc7\u7535\u4f4d\uff0810 mA cm\u207b\u00b2\uff09\u548c\u957f\u8fbe5140\u5c0f\u65f6\u7684\u8d85\u7a33\u5b9a\u8fd0\u884c\uff082 A cm\u207b\u00b2\uff09\u3002\u540c\u6b65\u8f90\u5c04PDF\u5206\u6790\u548c\u539f\u4f4d\u5149\u8c31\u8868\u5f81\u8868\u660e\uff0cPOM\u901a\u8fc7Ni-O\u6865\u4e0eMOF\u5f62\u6210\u5f3a\u8026\u5408\u754c\u9762\uff0c\u6784\u5efa\u4e86\u4eceCoFe\u6d3b\u6027\u4f4d\u70b9\u5230\u7535\u6781\u7684\u5feb\u901f\u7535\u5b50\u901a\u9053\uff0c\u540c\u65f6Ni\u5c42\u4f5c\u4e3a\u5f39\u6027\u7f13\u51b2\u5c42\u7a33\u5b9a\u6d3b\u6027\u76f8\u7ed3\u6784\u3002\u7406\u8bba\u8ba1\u7b97\u8fdb\u4e00\u6b65\u63ed\u793a\uff0cPOM\u7684\u5f15\u5165\u663e\u8457\u964d\u4f4e\u4e86CoFe\u4f4d\u70b9\u7684\u7535\u8377\u6001\uff0c\u6291\u5236\u4e86\u5176\u8fc7\u6c27\u5316\u4e0e\u6eb6\u89e3\uff0c\u4f7f\u50ac\u5316\u5242\u57281.8 V\u9ad8\u7535\u4f4d\u4e0b\u4ecd\u4fdd\u6301\u70ed\u529b\u5b66\u7a33\u5b9a\u3002\u6280\u672f\u7ecf\u6d4e\u5206\u6790\u663e\u793a\uff0cMOF@POM\u7535\u89e3\u69fd\u7684\u5236\u6c22\u5e73\u51c6\u5316\u6210\u672c\u4f4e\u81f32.324\u7f8e\u5143\/kg\uff0c\u4f18\u4e8e\u7f8e\u56fd\u80fd\u6e90\u90e82035\u5e74\u76ee\u6807\uff0c\u4e3a\u89c4\u6a21\u5316\u5e94\u7528\u5960\u5b9a\u57fa\u7840\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\u201cPolyoxometalated metal-organic framework superstructure for stable water oxidation<\/em>\u201d\u7684\u8bba\u6587\u53d1\u8868\u5728Science<\/em>\u4e0a\u3002<\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u3010\u6570\u636e\u6982\u51b5\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1. MOF@POM<\/strong>\u8d85\u7ed3\u6784\u7684\u6a21\u578b\u4e0e\u8868\u5f81\uff0c\u5c55\u793a\u5176\u82b1\u74e3\u72b6\u5f62\u8c8c\u3001\u5355\u5c42\u539a\u5ea6\u53ca\u957f\u7a0b\u6709\u5e8f\u6676\u4f53\u7ed3\u6784<\/strong>\u00a9 2025\u00a0AAAS<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2. <\/strong>\u7535\u5316\u5b66\u6027\u80fd\u66f2\u7ebf\u663e\u793a<\/strong>MOF@POM<\/strong>\u5728\u78b1\u6027\u7535\u89e3\u69fd\u4e2d\u7684\u4f4e\u7535\u538b\u9700\u6c42\u4e0e\u8d85\u957f\u7a33\u5b9a\u6027<\/strong>\u00a9 2025\u00a0AAAS<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>3. <\/strong>\u539f\u4f4d\u5149\u8c31\u4e0e\u7ed3\u6784\u6f14\u5316\u5206\u6790\u63ed\u793a\u50ac\u5316\u5242\u5728\u6c27\u5316\u8fc7\u7a0b\u4e2d\u5411\u91d1\u5c5e\uff08\u6c27\uff09\u6c22\u6c27\u5316\u7269\u7684\u76f8\u53d8\u53ca<\/strong>Ni<\/strong>\u5c42\u7684\u5f39\u6027\u7a33\u5b9a\u4f5c\u7528<\/strong>\u00a9 2025\u00a0AAAS<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4. <\/strong>\u7406\u8bba\u8ba1\u7b97\u9610\u660e<\/strong>POM<\/strong>\u6291\u5236<\/strong>CoFe<\/strong>\u6d3b\u6027\u4f4d\u70b9\u6eb6\u89e3\u7684\u673a\u5236\u53ca\u6c34\u6c27\u5316\u53cd\u5e94\u8def\u5f84\u7684\u80fd\u5792\u964d\u4f4e\u6548\u5e94<\/strong>\u00a9 2025\u00a0AAAS<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

\u00a0\u00a0<\/strong><\/p>\n

\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

MOF@POM\u8d85\u7ed3\u6784\u50ac\u5316\u5242\u901a\u8fc7\u754c\u9762\u534f\u540c\u4e0e\u7535\u5b50\u901a\u9053\u4f18\u5316\uff0c\u5b9e\u73b0\u4e86\u78b1\u6027\u6c34\u6c27\u5316\u6d3b\u6027\u4e0e\u7a33\u5b9a\u6027\u7684\u53cc\u91cd\u7a81\u7834\uff0c\u4e3a\u7eff\u8272\u6c22\u80fd\u7684\u9ad8\u6548\u5236\u5907\u63d0\u4f9b\u4e86\u65b0\u8303\u5f0f\u3002\u5176\u5de5\u4e1a\u5316\u5e94\u7528\u4ecd\u9700\u89e3\u51b3\u819c\u7535\u6781\u7ec4\u4ef6\u96c6\u6210\u3001\u5927\u89c4\u6a21\u5408\u6210\u5de5\u827a\u53ca\u6ce2\u52a8\u6027\u53ef\u518d\u751f\u80fd\u6e90\u9002\u914d\u7b49\u6311\u6218\u3002\u672a\u6765\u7814\u7a76\u53ef\u62d3\u5c55POM-MOF\u534f\u540c\u8bbe\u8ba1\u81f3\u5176\u4ed6\u7535\u50ac\u5316\u53cd\u5e94\u4f53\u7cfb\uff0c\u5e76\u63a2\u7d22\u673a\u5668\u5b66\u4e60\u52a0\u901f\u50ac\u5316\u5242\u7b5b\u9009\uff0c\u63a8\u52a8\u7535\u89e3\u6c34\u5236\u6c22\u6280\u672f\u7684\u5168\u9762\u5347\u7ea7\u3002<\/p>\n

\u00a0<\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.science.org\/doi\/10.1126\/science.ads1466<\/p>\n

\u00a0<\/strong><\/p>\n

\u672c\u6587\u7531\u6e29\u534e\u4f9b\u7a3f<\/strong><\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u591a\u6821\u5408\u4f5c\u6700\u65b0Science\uff1a\u8d85\u7a33MOF@POM\u50ac\u5316\u5242\uff0c\u7a81\u7834\u9ad8\u6548\u7535\u89e3\u6c34\u5236\u6c22\u74f6\u9888 \u00a0 \u3010\u79d1\u5b66\u80cc\u666f\u3011 \u78b1\u6027\u6c34\u7535\u89e3\u5236\u6c22\u662f\u5b9e\u73b0\u7eff\u8272\u6c22\u80fd\u89c4\u6a21\u5316\u5e94\u7528\u7684\u5173\u952e\u6280\u672f\uff0c\u4f46\u5176\u6838\u5fc3\u6311\u6218\u5728…<\/p>\n","protected":false},"author":34419,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[5153,5152,245],"class_list":["post-266454","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-5153","tag-5152","tag-mof"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/266454"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/34419"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=266454"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/266454\/revisions"}],"predecessor-version":[{"id":266461,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/266454\/revisions\/266461"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=266454"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=266454"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=266454"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}