{"id":265824,"date":"2025-03-30T06:23:15","date_gmt":"2025-03-29T22:23:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=265824"},"modified":"2025-03-29T20:25:30","modified_gmt":"2025-03-29T12:25:30","slug":"%e6%b8%af%e5%9f%8e%e5%a4%a7%e5%90%95%e5%9d%9a%e3%80%81%e5%9c%b0%e5%a4%a7%e5%8c%97%e4%ba%ac%e9%bb%84%e6%9c%9d%e6%99%96%e3%80%81%e5%8c%97%e7%90%86%e5%b7%a5%e9%82%b5%e7%91%9e%e6%96%87%e5%9b%a2%e9%98%9fan","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=265824","title":{"rendered":"\u6e2f\u57ce\u5927\u5415\u575a\u3001\u5730\u5927\u5317\u4eac\u9ec4\u671d\u6656\u3001\u5317\u7406\u5de5\u90b5\u745e\u6587\u56e2\u961fAngew\uff1a\u201c\u5b9a\u5411\u4fee\u526a\u201d\u7b56\u7565\u4ee5\u5b9e\u73b0\u94c2\u539f\u5b50\u56e2\u7c07\u7684\u914d\u4f4d\u5de5\u7a0b\u7528\u4e8e\u9ad8\u6548\u7535\u50ac\u5316\u6790\u6c22"},"content":{"rendered":"

\u5168\u6587\u901f\u89c8
\n \u539f\u5b50\u7ea7\u56e2\u7c07\u50ac\u5316\u5242\u4e2d\u7684\u914d\u4f4d\u6570\u8d4b\u4e88\u5176\u50ac\u5316\u6027\u80fd\u7075\u6d3b\u7684\u53ef\u8c03\u6027\u3002\u7136\u800c\uff0c\u539f\u5b50\u7ea7\u56e2\u7c07\u50ac\u5316\u5242\u7684\u914d\u4f4d\u6570\u548c\u50ac\u5316\u6d3b\u6027\u4e4b\u95f4\u7684\u5b9a\u91cf\u5173\u7cfb\u4ecd\u7136\u4e0d\u660e\u786e\u3002\u5728\u6b64\uff0c\u53d7\u5230\u56ed\u4e01\u4fee\u526a\u690d\u7269\u6811\u679d\u4ee5\u83b7\u5f97\u89c2\u8d4f\u4ef7\u503c\u5f62\u72b6\u7684\u542f\u53d1\u3002\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u201c\u5b9a\u5411\u4fee\u526a\u201d\u7b56\u7565\uff0c\u4ee5\u83b7\u5f97\u4e00\u7cfb\u5217\u5177\u6709\u8f83\u5bbd\u8303\u56f4\u6c2f\u914d\u4f4d\u7684\u539f\u5b50\u7ea7\u56e2\u7c07\u50ac\u5316\u5242\uff0c\u5e76\u5efa\u7acb\u5012\u706b\u5c71\u66f2\u7ebf\u6765\u89e3\u91ca\u914d\u4f4d\u6570\u5bf9\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u5f71\u54cd\u3002\u6b64\u5916\uff0cPt\/CB-90\uff08\u6700\u4f18Cl\u914d\u4f4d\u6570\u4e3a3.7\uff09\u572810 mA cm-2\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8868\u73b022.94 mV\u7684\u6700\u4f4e\u8fc7\u7535\u4f4d\u548c\u51fa\u8272\u7684\u8d28\u91cf\u6d3b\u6027\uff08\u662f\u5546\u4e1a Pt\/C\u768425\u500d\uff09\u3002\u8be5\u5408\u6210\u7b56\u7565\u5145\u5206\u5229\u7528\u4e86\u524d\u9a71\u4f53\u539f\u5b50\uff0c\u5e94\u7528\u5e7f\u6cdb\u3002\u53cd\u5e94\u6db2\u53ef\u91cd\u590d\u4f7f\u7528\u591a\u8fbe20\u6b21\uff0c\u4ee5\u83b7\u5f971130 mg\u50ac\u5316\u5242\uff0c\u5e76\u4e14\u65e0\u9700\u5f15\u5165\u4efb\u4f55\u5176\u4ed6\u5316\u5b66\u54c1\u3002\u6b64\u5916\uff0c\u7406\u8bba\u8ba1\u7b97\u7a81\u51fa\u4e86 Pt2 \u539f\u5b50\u7ea7\u56e2\u7c07\u4e0a\u7684 HER \u7684\u9002\u91cf Cl \u914d\u4f4d\u6570\u7684\u4f18\u52bf\u3002\u8fd9\u9879\u5de5\u4f5c\u5bf9\u914d\u4f4d\u6570\u5728\u50ac\u5316\u6d3b\u6027\u4e2d\u7684\u4f5c\u7528\u7684\u57fa\u672c\u7406\u89e3\u4ee5\u53ca\u63d0\u9ad8\u5404\u79cd\u50ac\u5316\u53cd\u5e94\u7684\u6027\u80fd\u63d0\u4f9b\u4e86\u6709\u4ef7\u503c\u7684\u6307\u5bfc\u3002
\n \u80cc\u666f\u4ecb\u7ecd
\n \u5b8c\u5168\u66b4\u9732\u7684\u539f\u5b50\u7ea7\u56e2\u7c07\u50ac\u5316\u5242\u5728\u5404\u79cd\u50ac\u5316\u53cd\u5e94\u4e2d\u8d8a\u6765\u8d8a\u53d7\u5230\u5173\u6ce8\uff0c\u56e0\u4e3a\u5b83\u4eec\u63d0\u4f9b\u4e86\u4e30\u5bcc\u7684\u76f8\u90bb\u91d1\u5c5e\u539f\u5b50\u5e76\u786e\u4fdd\u539f\u5b50\u7684\u6700\u5927\u5229\u7528\u7387\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u539f\u5b50\u7ea7\u56e2\u7c07\u50ac\u5316\u5242\u7684\u914d\u4f4d\u73af\u5883\u53d6\u51b3\u4e8e\u5404\u79cd\u53c2\u6570\uff0c\u5305\u62ec\u914d\u4f4d\u7ed3\u6784\u3001\u7c07\u79cd\u7c7b\u3001\u8f7d\u4f53\u548c\u6f5c\u5728\u914d\u4f53\uff0c\u4ece\u800c\u5b9e\u73b0\u53ef\u63a7\u7684\u50ac\u5316\u7279\u6027\u3002\u8fd1\u5e74\u6765\uff0c\u6742\u539f\u5b50\u88ab\u5e7f\u6cdb\u7528\u4e8e\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u7684\u5408\u7406\u8bbe\u8ba1\uff0c\u4ee5\u5b9e\u73b0\u9ad8\u6548\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u7136\u800c\uff0c\u91d1\u5c5e\u6d3b\u6027\u4e2d\u5fc3\u7684\u6700\u4f73\u914d\u4f4d\u539f\u5b50\u6570\u5c1a\u672a\u7cfb\u7edf\u6027\u7684\u786e\u5b9a\u3002\u56e0\u6b64\uff0c\u5fc5\u987b\u91cf\u5316\u914d\u4f4d\u539f\u5b50\u6570\u4e0e\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u624d\u80fd\u4ece\u6839\u672c\u4e0a\u4e86\u89e3\u590d\u6742\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u50ac\u5316\u6d3b\u6027\u7684\u6548\u7387\u3002\u6b64\u5916\uff0c\u6742\u539f\u5b50\u4f5c\u4e3a\u914d\u4f4d\u539f\u5b50\u7684\u53c2\u4e0e\u901a\u5e38\u9700\u8981\u590d\u6742\u7684\u8f7d\u4f53\u52a0\u5de5\u6216\u91cd\u65b0\u5f15\u5165\u989d\u5916\u7684\u5316\u5b66\u54c1\uff0c\u4ece\u800c\u5bfc\u81f4\u9ad8\u751f\u4ea7\u6210\u672c\u548c\u590d\u6742\u7684\u5236\u5907\u8fc7\u7a0b\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u4f7f\u7528\u4e00\u79cd\u6781\u5176\u7b80\u5355\u7684\u65b9\u6cd5\u6210\u529f\u5730\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u4e0eCl\u914d\u4f4d\u7684 Pt\u539f\u5b50\u7ea7\u56e2\u7c07\uff0c\u65e0\u9700\u4efb\u4f55\u989d\u5916\u7684\u5316\u5b66\u54c1\uff0c\u5e76\u91cf\u5316\u4e86\u914d\u4f4d\u539f\u5b50\u7684\u6570\u91cf\u4e0e HER \u4e2d\u50ac\u5316\u6d3b\u6027\u4e4b\u95f4\u7684\u5173\u7cfb\u3002
\n \u672c\u6587\u4eae\u70b9
\n 1. \u53d7\u56ed\u4e01\u4fee\u526a\u679d\u6761\u8fc7\u7a0b\u548c\u7406\u8bba\u6307\u5bfc\u7684\u542f\u53d1\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u201c\u5b9a\u5411\u4fee\u526a\u201d\u5408\u6210\u7b56\u7565\uff0c\u4ee5\u5b9e\u73b0\u914d\u4f4d\u539f\u5b50\u6570\u7684\u7cbe\u7ec6\u4fee\u526a\u3002
\n 2. \u5bf9\u5177\u6709\u4e0d\u540cCl\u914d\u4f4d\u7684Pt\/CB\u50ac\u5316\u5242\u7684\u8fdb\u4e00\u6b65\u5206\u6790\u63ed\u793a\u4e86Cl\u7684\u914d\u4f4d\u6570\u4e0eHER\u7684\u8fc7\u7535\u4f4d\u4e4b\u95f4\u5448\u5012\u706b\u5c71\u66f2\u7ebf\u3002\u53ef\u4ee5\u83b7\u5f97\u914d\u4f4d\u539f\u5b50\u6570\u4e0e\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u91cf\u5316\u5173\u7cfb\uff0c\u4ee5\u5408\u7406\u8bbe\u8ba1\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u914d\u4f4d\u7ed3\u6784\u3002
\n 3. \u6240\u63d0\u51fa\u7684\u57fa\u4e8e\u4f4e\u6210\u672c\u201c\u5b9a\u5411\u4fee\u526a\u201d\u7684\u5408\u6210\u7b56\u7565\u786e\u4fdd\u4e86\u6240\u6709\u524d\u9a71\u4f53\u539f\u5b50\u7684\u5145\u5206\u5229\u7528\uff0c\u5e76\u5177\u6709\u666e\u904d\u9002\u7528\u6027\uff08\u6210\u529f\u5e94\u7528\u4e8e Ru\u3001Rh\u3001Ir \u548c Pd \u4f5c\u4e3a\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\uff09\uff0c\u65e0\u9700\u4efb\u4f55\u989d\u5916\u7684\u5316\u5b66\u54c1\u3002\u53cd\u5e94\u5e9f\u6db2\u6700\u591a\u53ef\u91cd\u590d\u4f7f\u7528 20 \u6b21\uff0c\u603b\u5171\u53ef\u83b7\u5f97 1130 mg \u5177\u6709\u4e00\u81f4\u50ac\u5316\u6d3b\u6027\u7684\u50ac\u5316\u5242\u3002
\n \u56fe\u6587\u89e3\u6790
\n \u5b9e\u9a8c\u8bbe\u8ba1\u7684\u7075\u611f\u6765\u81ea\u56ed\u4e01\u4fee\u526a\u6811\u679d\u7684\u8fc7\u7a0b\u3002\u5728\u5927\u591a\u6570\u60c5\u51b5\u4e0b\uff0c\u56ed\u4e01\u901a\u5e38\u4f1a\u5b9a\u5411\u4fee\u526a\u690d\u7269\u7684\u591a\u4f59\u679d\u6761\uff0c\u4ee5\u6291\u5236\u9876\u7aef\u4f18\u52bf\uff0c\u6216\u8fdb\u4e00\u6b65\u83b7\u5f97\u66f4\u5177\u89c2\u8d4f\u4ef7\u503c\u7684\u5f62\u72b6\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u50cf\u56ed\u4e01\u4e00\u6837\u5bf9\u539f\u5b50\u7ea7\u56e2\u7c07\u7684\u9884\u671f\u914d\u4f4d\u6570\u7684\u5b9a\u5411\u5de5\u7a0b\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u56e0\u6b64\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u201c\u5b9a\u5411\u4fee\u526a\u201d\u7b56\u7565\u6765\u5b9e\u73b0\u5bf9\u6700\u4f18\u914d\u4f4d\u6570\u7684\u7cbe\u786e\u8c03\u8282\uff0c\u5e76\u7ed3\u5408\u7406\u8bba\u8ba1\u7b97\u83b7\u5f97\u6709\u4ef7\u503c\u7684\u7ed3\u6784\u3002\u8fd9\u79cd\u201c\u5b9a\u5411\u4fee\u6574\u201d\u6280\u672f\u662f\u6839\u636e\u5b9e\u9645\u8981\u6c42\u8bbe\u8ba1\u50ac\u5316\u5242\u7684\u9884\u671f\u914d\u4f4d\u7ed3\u6784\u7684\u57fa\u7840\uff08\u56fe1a\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1 \u5408\u6210\u7b56\u7565\u793a\u610f\u56fe\u53ca\u7406\u8bba\u6307\u5bfc
\n \u9996\u5148\u4f5c\u8005\u4f7f\u7528\u79d1\u7434\u78b3\u548c\u6c2f\u94c2\u9178\u7684\u6c34\u6eb6\u6db2\u6df7\u5408\u6d78\u6e0d\u83b7\u5f97\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08Pt\/CB-0\uff09\uff0c\u6839\u636e\u56fe2a-d\u7684HRTEM\u3001HADDF-STEM\u4ee5\u53caEDS mapping\u53ef\u4ee5\u770b\u51fa\uff0cPt\/CB-0\u7684\u91d1\u5c5e\u4f4d\u70b9\u4ee5\u5355\u539f\u5b50\u7684\u5f62\u5f0f\u5b58\u5728\uff0c\u53e6\u5916\u5236\u5907\u8fc7\u7a0b\u4e2d\u91c7\u7528\u51b7\u51bb\u5e72\u71e5\u800c\u975e\u4f20\u7edf\u7684\u9ad8\u6e29\u70e7\u7ed3\u53ef\u4ee5\u6781\u5927\u7684\u4fdd\u7559\u524d\u9a71\u4f53\u4e2dCl\u5143\u7d20\u5e76\u4f5c\u4e3a\u4e3b\u8981\u7684\u914d\u4f4d\u539f\u5b50\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u9ad8\u9891\u6b21\u7684\u8d85\u58f0\u7b56\u7565\u88ab\u5f15\u5165\u5230\u6d78\u6e0d\u8fc7\u7a0b\u4e2d\uff0c\u901a\u8fc7\u6539\u53d8\u4e0d\u540c\u7684\u8d85\u58f0\u65f6\u95f4\u5206\u522b\u83b7\u5f97\u4e86Pt\/CB-90\u4ee5\u53caPt\/CB-300\u50ac\u5316\u5242\u3002\u533a\u522b\u4e8ePt\/CB-0\uff0cPt\/CB-90\u548cPt\/CB-300\u7684\u91d1\u5c5e\u4f4d\u70b9\u5c3a\u5bf8\u7531\u5355\u539f\u5b50\u5f62\u5f0f\u8fdb\u4e00\u6b65\u8f6c\u53d8\u4e3a\u539f\u5b50\u7ea7\u56e2\u7c07\u4e14\u5177\u6709\u76f8\u5e94\u7684Cl\u914d\u4f4d\uff08\u56fe2e-l\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2 \u5177\u6709\u4e0d\u540cCl\u914d\u4f4d\u7684Pt\/CB\u50ac\u5316\u5242\u7684\u7ed3\u6784\u8868\u5f81\u3002
\n XRD\u8fdb\u4e00\u6b65\u8bc1\u660ePt\/CB\u50ac\u5316\u5242\u7684\u539f\u5b50\u7ea7\u91d1\u5c5e\u4f4d\u70b9\uff0c\u548c\u7403\u5dee\u7b49\u6570\u636e\u8868\u73b0\u51fa\u4e00\u81f4\u7684\u7ed3\u679c\u3002\u62c9\u66fc\u5149\u8c31\u663e\u793a\u968f\u7740\u8d85\u58f0\u65f6\u95f4\u7684\u5ef6\u957f\uff0cID\/IG\u7684\u6bd4\u503c\u9010\u6e10\u7f13\u6162\u5347\u9ad8\uff0c\u8fd9\u662f\u7531\u4e8e\u8d85\u58f0\u8fc7\u7a0b\u548c\u91d1\u5c5e\u7269\u79cd\u7684\u5f15\u5165\u5bfc\u81f4\u8f7d\u4f53\u7684\u7f3a\u9677\u589e\u52a0\u3002XPS\u7684\u7ed3\u679c\u663e\u793a\uff0c\u968f\u7740\u8d85\u58f0\u65f6\u95f4\u7684\u5ef6\u957f\uff0cPt4+\/Pt2+\u7684\u6bd4\u4f8b\u8fdb\u4e00\u6b65\u51cf\u5c0f\uff0c\u8fd9\u610f\u5473\u7740Pt\u91d1\u5c5e\u7269\u79cd\u9010\u6e10\u7531\u9ad8\u4ef7\u6001\u8f6c\u53d8\u4e3a\u4f4e\u4ef7\u6001\uff0c\u8fd9\u4e3b\u8981\u662f\u56e0\u4e3a\u7531\u4e8e\u8d85\u58f0\u8fc7\u7a0b\u4e2d\u4e0d\u65ad\u4f9b\u7ed9\u7684\u80fd\u91cf\u4fc3\u4f7fPt\u91d1\u5c5e\u7269\u79cd\u7684\u914d\u4f4d\u539f\u5b50\u8fdb\u4e00\u6b65\u51cf\u5c11\u3002\u53e6\u5916XAS\u7528\u4e8e\u5206\u6790Pt\/CB\u50ac\u5316\u5242\u7684\u914d\u4f4d\u7ed3\u6784\uff0cPt\/CB\u50ac\u5316\u5242\u7684\u4e3b\u8981\u914d\u4f4d\u952e\u4e3aPt-Cl\u952e\u3002\u6839\u636eEXAFS\u62df\u5408\u7ed3\u679c\u968f\u7740\u53cd\u5e94\u65f6\u95f4\u7684\u5ef6\u957f\uff0cPt\/CB\u50ac\u5316\u5242\u7684Cl\u914d\u4f4d\u6570\u9010\u6e10\u964d\u4f4e\u8fdb\u4e00\u6b65\u8868\u660e\u8fd9\u79cd\u57fa\u4e8e\u9ad8\u9891\u6b21\u8d85\u58f0\u7684\u201c\u5b9a\u5411\u4fee\u526a\u201d\u7b56\u7565\u53ef\u4ee5\u7f13\u6162\u7684\u51cf\u5c11Pt\u91d1\u5c5e\u7269\u79cd\u7684Cl\u914d\u4f4d\u6570\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 \u5177\u6709\u4e0d\u540cCl\u914d\u4f4d\u7684Pt\/CB\u50ac\u5316\u5242\u7684XRD\u5206\u6790\u53ca\u5149\u8c31\u8868\u5f81
\n \u91c7\u75280.5 M H2SO4\u8fdb\u4e00\u6b65\u8bc4\u4f30Pt\/CB\u50ac\u5316\u5242\u7684HER\u6027\u80fd\uff0cLSV\u66f2\u7ebf\u8868\u660e\u9002\u5b9c\u6570\u91cfCl\u914d\u4f4d\u7684Pt\/CB-90\u5177\u6709\u6700\u9ad8\u7684HER\u53cd\u5e94\u6d3b\u6027\uff0c\u572810 mA cm-2\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cPt\/CB-90\u53ea\u9700\u898122.94mV\u7684\u53cd\u5e94\u8fc7\u7535\u4f4d\u3002\u53e6\u5916\u572850mV\u7684\u8fc7\u7535\u4f4d\u4e0b\uff0cPt\/CB-90\u7684\u8d28\u91cf\u6d3b\u6027\u662f\u5546\u4e1aPt\/C\u768425\u500d\u3002\u540c\u65f6\u901a\u8fc7\u6539\u53d8\u9ad8\u9891\u6b21\u8d85\u58f0\u65f6\u95f4\uff0c\u83b7\u5f97\u4e86Pt\u539f\u5b50\u7ea7\u56e2\u7c07\u7684Cl\u914d\u4f4d\u6570\u91cf\u548cHER\u8fc7\u7535\u4f4d\u4e4b\u95f4\u7684\u5012\u706b\u5c71\u5173\u7cfb\u3002\u8fd9\u8fdb\u4e00\u6b65\u8bc1\u660eCl\u914d\u4f4d\u7684\u6570\u91cf\u5b58\u5728\u4e00\u4e2a\u4e2d\u95f4\u7684\u9002\u5b9c\u503c\u4ee5\u5b9e\u73b0\u6700\u4f18\u7684HER\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 \u5177\u6709\u4e0d\u540cCl\u914d\u4f4d\u7684Pt\/CB\u50ac\u5316\u5242\u7684\u9178\u6027HER\u6027\u80fd
\n \u901a\u8fc7DFT\u8ba1\u7b97\u8fdb\u4e00\u6b65\u89e3\u91ca\u4e86\u5408\u6210\u8fc7\u7a0b\u4e2d\u7684\u673a\u5236\u4ee5\u53ca\u91d1\u5c5e\u4f4d\u70b9\u7684\u5c3a\u5ea6\u53d8\u5316\uff0c\u8fd9\u79cd\u201c\u5b9a\u5411\u4fee\u526a\u201d\u7684\u8fc7\u7a0b\u4e3b\u8981\u5206\u4e3a\u4e24\u4e2a\u9636\u6bb5\uff1a\u9996\u5148Pt\u7269\u79cd\u7531\u4e8e\u5916\u754c\u9ad8\u9891\u6b21\u8d85\u58f0\u7684\u4ecb\u5165\u7531\u5355\u539f\u5b50\u8f6c\u53d8\u4e3a\u539f\u5b50\u7ea7\u56e2\u7c07\uff0c\u63a5\u4e0b\u6301\u7eed\u4f9b\u7ed9\u7684\u80fd\u91cf\u8fdb\u4e00\u6b65\u7f29\u51cf\u91d1\u5c5e\u4f4d\u70b9\u914d\u4f4d\u539f\u5b50\u7684\u6570\u91cf\u3002DFT\u5206\u522b\u8ba1\u7b97\u4e86\u4e0d\u540cCl\u914d\u4f4d\u6570\u76ee\u7684Pt2\u6a21\u578b\u7684\u70ed\u529b\u5b66\u80fd\u91cf\u5dee\u5f02\uff0c\u7ed3\u679c\u663e\u793a\u539f\u5b50\u7ea7\u56e2\u7c07\u9700\u8981\u8fdb\u4e00\u6b65\u7684\u5916\u754c\u80fd\u91cf\u4f9b\u7ed9\u4ee5\u5b9e\u73b0\u914d\u4f4d\u6570\u7684\u9010\u6e10\u964d\u4f4e\uff0c\u8fdb\u4e00\u6b65\u901a\u8fc7\u8ba1\u7b97\u7684\u89d2\u5ea6\u8bc1\u660e\u201c\u5b9a\u5411\u4fee\u526a\u201d\u7b56\u7565\u7684\u5408\u7406\u6027\u3002\u53e6\u5916\u8fd9\u79cd\u6781\u5176\u7b80\u5355\u7684\u5408\u6210\u7b56\u7565\u65e0\u9700\u5916\u754c\u5f15\u5165\u989d\u5916\u7684\u5316\u5b66\u54c1\u4ece\u800c\u5b9e\u73b0\u53cd\u5e94\u5e9f\u6db2\u7684\u6700\u5927\u5316\u539f\u5b50\u5229\u7528\u7387\u3002\u53cd\u5e94\u5e9f\u6db2\u53ef\u53cd\u590d\u4f7f\u7528\u591a\u8fbe20\u6b21\u5e76\u83b7\u5f97\u6027\u80fd\u4e00\u81f4\u76841130 mg\u7684\u50ac\u5316\u5242\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 \u5408\u6210\u673a\u7406\u89e3\u91ca
\n \u66f4\u4e3a\u91cd\u8981\u7684\u662f\u8be5\u7b56\u7565\u53ef\u4ee5\u8fdb\u4e00\u6b65\u62d3\u5c55\u5230\u5176\u4ed6\u91d1\u5c5e\uff0c\u4f8b\u5982\uff1aRu\uff0cRh\uff0cIr\u4ee5\u53caPd\u3002\u5e76\u4e14\u83b7\u5f97\u76f8\u5e94\u7684\u5177\u6709\u4e00\u5b9aCl\u914d\u4f4d\u7684\u539f\u5b50\u7ea7\u91d1\u5c5e\u4f4d\u70b9\u7684\u50ac\u5316\u5242\u3002DFT\u8fdb\u4e00\u6b65\u89e3\u91ca\u4e86Cl\u914d\u4f4d\u7684\u5f15\u5165\u6709\u5229\u4e8e\u6d3b\u6027\u6c22H*\u7684\u5438\u8131\u9644\u8fc7\u7a0b\uff0c\u800c\u8fc7\u9ad8\u7684Cl\u914d\u4f4d\u539f\u5b50\u4f1a\u8fdb\u4e00\u6b65\u5360\u636eH*\u7684\u5438\u9644\u4f4d\u70b9\uff0c\u56e0\u6b64\u5b58\u5728\u9002\u5b9c\u914d\u4f4d\u6570\u91cf\u7684\u4e2d\u95f4\u503c\u3002
\n \"\"
\n \u56fe6\uff1a\u201c\u5b9a\u5411\u4fee\u526a\u201d\u7b56\u7565\u7684\u666e\u9002\u6027\u7814\u7a76\u53caDFT\u8ba1\u7b97\u7ed3\u679c
\n \u603b\u7ed3\u4e0e\u5c55\u671b
\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u53d7\u56ed\u4e01\u5b9a\u5411\u4fee\u526a\u690d\u7269\u679d\u6761\u7684\u542f\u53d1\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u201c\u5b9a\u5411\u4fee\u526a\u201d\u5408\u6210\u7b56\u7565\uff0c\u6210\u529f\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u4e0d\u540cCl\u914d\u4f4d\u6570\u91cf\u7684\u539f\u5b50\u7ea7\u56e2\u7c07\u50ac\u5316\u5242\uff0c\u5e76\u5728\u914d\u4f4d\u539f\u5b50\u6570\u548cHER\u50ac\u5316\u8fc7\u7535\u4f4d\u4e4b\u95f4\u5efa\u7acb\u4e86\u91cf\u5316\u7684\u5012\u706b\u5c71\u5173\u7cfb\u3002Pt\/CB-90\u5177\u6709\u4e2d\u7b49Cl\u914d\u4f4d\u6570\u91cf\uff0c\u53ea\u9700\u898122.94 mV\u7684\u8fc7\u7535\u4f4d\u5373\u53ef\u5b9e\u73b010 mA cm-2\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u5176\u8d28\u91cf\u6d3b\u6027\u662f\u5546\u4e1aPt\/C\u768425\u500d\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0c\u4e0d\u540c\u6570\u91cf\u7684\u914d\u4f4d\u539f\u5b50\u5360\u636e\u6d3b\u6027\u5438\u9644\u4f4d\u70b9\u4ee5\u8c03\u6574\u50ac\u5316\u5242\u7684 HER \u6d3b\u6027\u3002\u6240\u63d0\u51fa\u7684\u5b9a\u5411\u4fee\u6574\u7b56\u7565\u5177\u6709\u5e7f\u6cdb\u7684\u9002\u7528\u6027\uff0c\u8fd9\u5bf9\u914d\u4f4d\u539f\u5b50\u6570\u5728\u50ac\u5316\u6d3b\u6027\u4e2d\u7684\u4f5c\u7528\u7684\u57fa\u672c\u7406\u89e3\u4e3a\u901a\u8fc7\u914d\u4f4d\u7ed3\u6784\u5de5\u7a0b\u5408\u7406\u8bbe\u8ba1\u9ad8\u6548\u539f\u5b50\u7ea7\u56e2\u7c07\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u6709\u4ef7\u503c\u7684\u6307\u5bfc\u3002
\n \u6587\u732e\u4fe1\u606f\uff1a
\n https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202504828?af=R
\n \u7814\u7a76\u56e2\u961f\u4ecb\u7ecd\uff1a
\n \"\"
\n \u5415\u575a\u9662\u58eb\uff1a\u6cd5\u56fd\u56fd\u5bb6\u6280\u672f\u79d1\u5b66\u9662\uff08NATF\uff09\u9662\u58eb\u3001\u9999\u6e2f\u5de5\u7a0b\u79d1\u5b66\u9662\u9662\u58eb\u3001\u9999\u6e2f\u9ad8\u7b49\u7814\u7a76\u9662\u9ad8\u7ea7\u7814\u7a76\u5458\u3001\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u5de5\u5b66\u9662\u9662\u957f\u3001\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u673a\u68b0\u5de5\u7a0b\u7cfb\u8bb2\u5ea7\u6559\u6388\u3001\u56fd\u5bb6\u8d35\u91d1\u5c5e\u6750\u6599\u5de5\u7a0b\u7814\u7a76\u4e2d\u5fc3\u9999\u6e2f\u5206\u4e2d\u5fc3\u4e3b\u4efb\u3001\u5148\u8fdb\u7ed3\u6784\u6750\u6599\u4e2d\u5fc3\u4e3b\u4efb\u3002\u66fe\u4efb\u6cd5\u56fd\u7279\u9c81\u74e6\u6280\u672f\u5927\u5b66\u673a\u68b0\u7cfb\u7edf\u5de5\u7a0b\u7cfb\u7cfb\u4e3b\u4efb\u3001\u6cd5\u56fd\u6559\u80b2\u90e8\u4e0e\u6cd5\u56fd\u56fd\u5bb6\u79d1\u5b66\u4e2d\u5fc3\uff08CNRS\uff09\u673a\u68b0\u7cfb\u7edf\u4e0e\u5e76\u884c\u5de5\u7a0b\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\u3001\u9999\u6e2f\u7406\u5de5\u5927\u5b66\u673a\u68b0\u5de5\u7a0b\u7cfb\u7cfb\u4e3b\u4efb\u3001\u8bb2\u5ea7\u6559\u6388\u3001\u517c\u4efb\u9999\u6e2f\u7406\u5de5\u5927\u5b66\u5de5\u7a0b\u5b66\u9662\u526f\u9662\u957f\u3001\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u526f\u6821\u957f\uff08\u7814\u7a76\u53ca\u79d1\u6280\uff09\u517c\u7814\u7a76\u751f\u9662\u9662\u957f\u3002\u66fe2011\u5e74\u88ab\u6cd5\u56fd\u56fd\u5bb6\u6280\u672f\u79d1\u5b66\u9662\uff08NATF\uff09\u9009\u4e3a\u9662\u58eb\uff0c\u662f\u8be5\u9662\u8fd1300\u4f4d\u9662\u58eb\u4e2d\u9996\u4f4d\u534e\u88d4\u9662\u58eb\u30022006\u5e74\u4e0e2017\u5e74\u5206\u522b\u83b7\u6cd5\u56fd\u603b\u7edf\u4efb\u547d\u83b7\u6cd5\u56fd\u56fd\u5bb6\u8363\u8a89\u9a91\u58eb\u52cb\u7ae0\u53ca\u6cd5\u56fd\u56fd\u5bb6\u8363\u8a89\u519b\u56e2\u9a91\u58eb\u52cb\u7ae0\uff0c2018\u5e74\u83b7\u4e2d\u56fd\u5de5\u7a0b\u9662\u5149\u534e\u5de5\u7a0b\u79d1\u6280\u5956\u3002\u5df2\u53d6\u5f9783\u9879\u4e2d\u7f8e\u4e13\u5229\u6388\u6743\uff0c\u5728\u672c\u9886\u57df\u9876\u5c16\u6742\u5fd7Nature(\u5c01\u9762\u6587\u7ae0)\u3001Science\u3001Nature Materials\u3001 Nature Chemistry, Nature Water, Science Advances. Nature Communications. Materials Today. Advanced Materials. PRL\u3001JACS\u3001\u7b49\u4e13\u4e1a\u6742\u5fd7\u4e0a\u53d1\u8868\u8bba\u6587550\u4f59\u7bc7\uff0c\u5f15\u75284\u4e079\u5343\u4f59\u6b21(Google Scholar)\u3002\u4e2a\u4eba\u4e3b\u9875\uff1ahttps:\/\/www.cityu.edu.hk\/mne\/people\/academic-staff\/prof-lu-jian<\/p>\n

\"\"<\/p>\n

\u9ec4\u671d\u6656\u6559\u6388\uff1a\u4e8c\u7ea7\u6559\u6388\uff0c\u66fe\u4efb\u4e2d\u56fd\u5730\u8d28\u5927\u5b66\uff08\u5317\u4eac\uff09\u6821\u5de5\u4f1a\u517c\u804c\u526f\u4e3b\u5e2d\uff0c\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u526f\u9662\u957f\u3002\u62c5\u4efb\u4e2d\u56fd\u7845\u9178\u76d0\u5b66\u4f1a\u8010\u706b\u6750\u6599\u5206\u4f1a\u526f\u7406\u4e8b\u957f\u3001\u7279\u79cd\u9676\u74f7\u5206\u4f1a\u7406\u4e8b\uff0c\u5168\u56fd\u6750\u6599\u79d1\u5b66\u6280\u672f\u540d\u8bcd\u5ba1\u5b9a\u59d4\u5458\u4f1a\u7279\u8058\u4e13\u5bb6\uff0c\u76f8\u5173\u90e8\u59d4\u7684\u8d44\u6e90\u7efc\u5408\u5229\u7528\u3001\u8282\u80fd\u51cf\u6392\u73af\u4fdd\u7b49\u9879\u76ee\u548c\u79d1\u6280\u5956\u52b1\u8bc4\u5ba1\u4e13\u5bb6\u59d4\u5458\u3002\u66fe\u83b7\u5f97\u7701\u90e8\u79d1\u6280\u8fdb\u6b65\u4e8c\u7b49\u59564\u9879\u3002\u4e3b\u6301\u8d1f\u8d23\u201c\u5341\u4e09\u4e94\u201d\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u201c\u56fa\u5e9f\u8d44\u6e90\u5316\u201d\u4e13\u9879\u3001\u201c\u5341\u4e8c\u4e94\u201d\u79d1\u6280\u652f\u6491\u9879\u76ee\u548c\u56fd\u5bb6\u81ea\u7136\u57fa\u91d1\u91cd\u70b9\u9879\u76ee\uff0c\u53d1\u8868\u8bba\u6587300\u4f59\u7bc7\uff0c\u6388\u6743\u53d1\u660e\u4e13\u522920\u4f59\u9879\u3002\u897f\u6fb3\u5927\u5229\u4e9a\u5927\u5b66Gledden Visiting Senior Fellowship\uff0c\u4e0e\u725b\u6d25\u5927\u5b66\u3001\u54c8\u4f5b\u5927\u5b66\u533b\u5b66\u9662\u548c\u65e5\u672c\u56fd\u7acb\u6750\u6599\u7814\u7a76\u6240\u7b49\u8054\u5408\u57f9\u517b\u7ea650\u4f4d\u7855\u535a\u7814\u7a76\u751f\u3002<\/p>\n

\"\"<\/p>\n

\u90b5\u745e\u6587\u6559\u6388\uff1a\u5317\u4eac\u7406\u5de5\u5927\u5b66\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u957f\u671f\u4ece\u4e8b\u673a\u5668\u4eba\u7cfb\u7edf\u8bbe\u8ba1\u4e0e\u7eb3\u7c73\u7ea7\u9ad8\u7cbe\u5ea6\u64cd\u4f5c\u3001\u663e\u5fae\u89c6\u89c9\u3001\u5fae\u7eb3\u52a0\u5de5\u7b49\u9886\u57df\u7684\u7814\u7a76\uff0c\u81f4\u529b\u4e8e\u7ed3\u5408\u5fae\u7eb3\u64cd\u4f5c\u673a\u5668\u4eba\u7cfb\u7edf\u548c\u900f\u5c04\uff0f\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\u5bf9\u5fae\u7eb3\u5668\u4ef6\u8fdb\u884c\u539f\u578b\u521b\u6210\u53ca\u8fd0\u884c\u673a\u5236\u7684\u7814\u7a76\u3002\u81ea\u4e3b\u7814\u5236\u4e86\u7528\u4e8e\u4f4e\u7ef4\u7eb3\u7c73\u6750\u6599\u7269\u6027\u7814\u7a76\u7684\u626b\u63cf-\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u8054\u5408\u64cd\u4f5c\u6d4b\u91cf\u4eea\u5668\uff0c\u901a\u8fc7\u5fae\u7eb3\u64cd\u4f5c\u673a\u5668\u4eba\u7cfb\u7edf\u6784\u7b51\u590d\u6742\u5fae\u7eb3\u5668\u4ef6\u7ed3\u6784\uff0c\u5728\u539f\u5b50\u5c3a\u5ea6\u4e0a\u7814\u7a76\u7c7b\u8111\u82af\u7247\u3001\u4f20\u611f\u5668\u3001\u5b58\u50a8\u5668\u3001\u80fd\u6e90\u5668\u4ef6\u7b49\u5fae\u7eb3\u5668\u4ef6\u7684\u8fd0\u884c\u53ca\u5931\u6548\u673a\u5236\u3002\u4ee5\u7b2c\u4e00\u6216\u901a\u8baf\u4f5c\u8005\u5728 Nature Communications\u3001Nano Letters\u3001Advanced Energy Materials\u3001Advanced Functional Materials\u7b49\u56fd\u9645\u8457\u540d\u671f\u520a\u53d1\u8868\u8bba\u6587 40 \u4f59\u7bc7\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5168\u6587\u901f\u89c8 \u539f\u5b50\u7ea7\u56e2\u7c07\u50ac\u5316\u5242\u4e2d\u7684\u914d\u4f4d\u6570\u8d4b\u4e88\u5176\u50ac\u5316\u6027\u80fd\u7075\u6d3b\u7684\u53ef\u8c03\u6027\u3002\u7136\u800c\uff0c\u539f\u5b50\u7ea7\u56e2\u7c07\u50ac\u5316\u5242\u7684\u914d\u4f4d\u6570\u548c\u50ac\u5316\u6d3b\u6027\u4e4b\u95f4\u7684\u5b9a\u91cf\u5173\u7cfb\u4ecd\u7136\u4e0d\u660e\u786e\u3002\u5728\u6b64\uff0c\u53d7\u5230\u56ed\u4e01\u4fee\u526a\u690d\u7269\u6811\u679d\u4ee5\u83b7…<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-265824","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265824"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=265824"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265824\/revisions"}],"predecessor-version":[{"id":265836,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265824\/revisions\/265836"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=265824"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=265824"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=265824"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}