{"id":265601,"date":"2025-03-19T07:53:42","date_gmt":"2025-03-18T23:53:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=265601"},"modified":"2025-03-19T01:00:19","modified_gmt":"2025-03-18T17:00:19","slug":"%e5%90%8c%e6%b5%8e%e5%a4%a7%e5%ad%a6%e5%bc%a0%e6%b8%85%e7%84%b6%e3%80%81%e6%b2%b3%e5%8d%97%e5%a4%a7%e5%ad%a6%e7%94%b0%e5%bf%97%e7%ba%a2%ef%bc%9a%e6%96%b0%e5%85%b4%e7%83%ad%e8%81%9a%e5%90%88%e4%ba%8c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=265601","title":{"rendered":"\u540c\u6d4e\u5927\u5b66\u5f20\u6e05\u7136\u3001\u6cb3\u5357\u5927\u5b66\u7530\u5fd7\u7ea2\uff1a\u65b0\u5174\u70ed\u805a\u5408\u4e8c\u7ef4\u78b3\u6750\u6599\u5728\u7535\u50ac\u5316\u80fd\u6e90\u8f6c\u6362\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011 \u00a0<\/strong><\/p>\n \u968f\u7740\u6c14\u5019\u53d8\u5316\u3001\u80fd\u6e90\u5371\u673a\u548c\u73af\u5883\u6076\u5316\u7684\u65e5\u76ca\u4e25\u91cd\uff0c\u5bfb\u627e\u6e05\u6d01\u548c\u53ef\u518d\u751f\u80fd\u6e90\u5df2\u6210\u4e3a\u5b9e\u73b0\u53ef\u6301\u7eed\u7ecf\u6d4e\u7684\u57fa\u7840\u3002\u5728\u8fd9\u4e00\u8f6c\u578b\u8fc7\u7a0b\u4e2d\uff0c\u5148\u8fdb\u7684\u80fd\u6e90\u8f6c\u6362\u7cfb\u7edf\uff08\u5982\u6c34\/CO\u2082\u7535\u89e3\u3001\u71c3\u6599\u7535\u6c60\u3001\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u7b49\uff09\u81f3\u5173\u91cd\u8981\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u6280\u672f\u7684\u53d1\u5c55\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4f9d\u8d56\u4e8e\u9ad8\u6027\u80fd\u7535\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\uff0c\u8fd9\u4e9b\u50ac\u5316\u5242\u9700\u8981\u5177\u5907\u9ad8\u6d3b\u6027\u3001\u9ad8\u9009\u62e9\u6027\u3001\u826f\u597d\u7684\u5bfc\u7535\u6027\u3001\u957f\u671f\u7a33\u5b9a\u6027\u3001\u5927\u8868\u9762\u79ef\u548c\u4f4e\u6210\u672c\u7b49\u7279\u70b9\u3002\u8fd1\u5e74\u6765\uff0c\u4e8c\u7ef4\uff082D\uff09\u78b3\u6750\u6599\u56e0\u5176\u72ec\u7279\u7684\u7ed3\u6784\u7279\u5f81\u548c\u7535\u5b50\u7279\u6027\uff0c\u5728\u7535\u50ac\u5316\u9886\u57df\u5c55\u73b0\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002\u672c\u6587\u7efc\u8ff0\u4e86\u901a\u8fc7\u9ad8\u6e29\u5316\u5b66\u65b9\u6cd5\u8bbe\u8ba1\u548c\u5236\u5907\u7684\u4e8c\u7ef4\u78b3\u6750\u6599\u5728\u7535\u50ac\u5316\u80fd\u6e90\u8f6c\u6362\u4e2d\u7684\u5e94\u7528\uff0c\u91cd\u70b9\u4ecb\u7ecd\u4e86\u901a\u8fc7\u70ed\u805a\u5408\u65b9\u6cd5\u7cbe\u7ec6\u8c03\u63a7\u6d3b\u6027\u7ed3\u6784\u7684\u8bbe\u8ba1\u3001\u5236\u5907\u548c\u673a\u7406\u7814\u7a76\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u70ed\u805a\u5408\u662f\u78b3\u7eb3\u7c73\u6750\u6599\u5408\u6210\u7684\u5173\u952e\u8fc7\u7a0b\u3002\u901a\u8fc7\u9009\u62e9\u5408\u9002\u7684\u6709\u673a\u524d\u4f53\uff0c\u70ed\u805a\u5408\u4e0d\u4ec5\u53ef\u4ee5\u8c03\u63a7\u50ac\u5316\u5242\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u8fd8\u53ef\u4ee5\u901a\u8fc7\u7a0b\u5e8f\u5316\u7684\u6742\u539f\u5b50\u63ba\u6742\u6216\u7f3a\u9677\u5de5\u7a0b\u521b\u5efa\u7406\u60f3\u7684\u6d3b\u6027\u7ed3\u6784\u3002\u4f8b\u5982\uff0c\u4ee5\u4e8c\u6c30\u4e8c\u80fa\uff08DCDA\uff09\u4e3a\u524d\u4f53\uff0c\u5728\u60f0\u6027\u6c14\u6c1b\u4e2d\u70ed\u89e3\u53ef\u4ee5\u751f\u6210\u77f3\u58a8\u76f8\u6c2e\u5316\u78b3\uff08g-C\u2083N\u2084\uff09\u4f5c\u4e3a\u6a21\u677f\uff0c\u8fdb\u4e00\u6b65\u5347\u9ad8\u6e29\u5ea6\u53ef\u4ee5\u53bb\u9664\u6c2e\u5316\u78b3\u6846\u67b6\uff0c\u7559\u4e0b\u6709\u5e8f\u7684\u4e8c\u7ef4\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u7247\u3002\u901a\u8fc7\u8c03\u63a7\u70ed\u805a\u5408\u6761\u4ef6\uff08\u65f6\u95f4\/\u6e29\u5ea6\uff09\u548c\u53cd\u5e94\u5316\u5b66\u8ba1\u91cf\u6bd4\uff0c\u53ef\u4ee5\u7cbe\u786e\u8c03\u63a7\u6c2e\u63ba\u6742\u7684\u7c7b\u578b\u548c\u6570\u91cf\u3001\u539a\u5ea6\u548c\u957f\u7a0b\u6709\u5e8f\u5f62\u6001\u3002<\/p>\n \u4e8c\u7ef4\u78b3\u6750\u6599\u901a\u5e38\u5177\u6709\u539f\u5b50\u7ea7\u539a\u5ea6\uff08\u5355\u5c42\u6216\u591a\u5c42\uff09\uff0c\u5e76\u5177\u6709\u6781\u9ad8\u7684\u6a2a\u5411\u9762\u79ef\u4e0e\u539a\u5ea6\u6bd4\u3002\u5c3d\u7ba1\u539f\u59cb\u78b3\u5728\u7535\u50ac\u5316\u4e2d\u76f8\u5bf9\u4e0d\u6d3b\u8dc3\uff0c\u4f46\u5176\u4e8c\u7ef4\u884d\u751f\u7269\uff08\u5982\u77f3\u58a8\u70ef\uff09\u901a\u5e38\u8868\u73b0\u51fa\u72ec\u7279\u7684\u7ed3\u6784\u7279\u5f81\u3001\u4e30\u5bcc\u7684\u8868\u9762\u6216\u8fb9\u7f18\u5316\u5b66\u6027\u8d28\u4ee5\u53ca\u53ef\u8c03\u7684\u7535\u5b50\u7279\u6027\uff0c\u8fd9\u4e9b\u90fd\u6709\u5229\u4e8e\u50ac\u5316\u6d3b\u6027\u7ed3\u6784\u7684\u5f62\u6210\u3002\u9996\u5148\uff0c\u4e8c\u7ef4\u78b3\u7535\u50ac\u5316\u5242\u901a\u5e38\u5177\u6709\u975e\u5e38\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u5176\u4e2d\u5927\u90e8\u5206\u539f\u5b50\u5904\u4e8e\u9ad8\u80fd\u6001\uff08\u6216\u9ad8\u53cd\u5e94\u6027\uff09\u3002\u5176\u6b21\uff0c\u901a\u8fc7\u5f62\u6210\u4e8c\u7ef4\u5c42\u72b6\u7ed3\u6784\uff0c\u8868\u9762\u7535\u5b50\u6027\u8d28\uff08\u5982\u8d39\u7c73\u80fd\u7ea7\u9644\u8fd1\u7684\u7535\u5b50\u5bc6\u5ea6\u6216\u72b6\u6001\uff09\u548c\u7269\u7406\u5316\u5b66\u7279\u6027\uff08\u5982\u7535\u8377\u8fc1\u79fb\u7387\uff09\u53d1\u751f\u663e\u8457\u53d8\u5316\uff0c\u4ece\u800c\u6539\u53d8\u4e86\u7535\u5bfc\u7387\u548c\u7535\u5b50\u4eb2\u548c\u529b\uff0c\u5b9e\u73b0\u4e86\u53ef\u8c03\u7684\u50ac\u5316\u8fc7\u7a0b\u3002\u6b64\u5916\uff0c\u4e8c\u7ef4\u78b3\u50ac\u5316\u5242\u7684\u826f\u597d\u5bfc\u7535\u6027\u548c\u5927\u8868\u9762\u79ef\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u4e86\u7535\u5316\u5b66\u8868\u9762\u79ef\u7684\u589e\u52a0\uff0c\u52a0\u901f\u4e86\u7535\u8377\u8f6c\u79fb\u3002\u6b64\u5916\uff0c\u66b4\u9732\u7684\u4e8c\u7ef4\u8868\u9762\u8d4b\u4e88\u5c42\u72b6\u78b3\u50ac\u5316\u5242\u4e30\u5bcc\u7684\u4e0d\u9971\u548c\u914d\u4f4d\u4f4d\u70b9\uff0c\u8fd9\u4e9b\u4f4d\u70b9\u4f4d\u4e8e\u7ed3\u6784\u7f3a\u9677\u548c\u8fb9\u7f18\uff0c\u80fd\u591f\u4e0e\u53cd\u5e94\u7269\u548c\u4e2d\u95f4\u4f53\u53d1\u751f\u5f3a\u5316\u5b66\u76f8\u4e92\u4f5c\u7528\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u951a\u5b9a\u66f4\u5177\u50ac\u5316\u6d3b\u6027\u7684\u7ec4\u5206\uff08\u5982\u5355\u539f\u5b50\u6216\u5408\u91d1\uff09\uff0c\u8fd9\u4e9b\u672a\u9971\u548c\u7684\u8868\u9762\u6216\u8fb9\u7f18\u4f4d\u70b9\u4e5f\u53ef\u4ee5\u7528\u4e8e\u5f62\u6210\u4e0d\u540c\u7684\u6df7\u5408\u7535\u50ac\u5316\u5242\uff0c\u4ee5\u63d0\u9ad8\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n \u57fa\u4e8e\u4e0a\u8ff0\u539f\u56e0\uff0c\u5927\u91cf\u7814\u7a76\u81f4\u529b\u4e8e\u8bbe\u8ba1\u548c\u5f00\u53d1\u4e8c\u7ef4\u78b3\u57fa\u6750\u6599\uff08CMs\uff09\u7528\u4e8e\u9ad8\u6548\u7535\u50ac\u5316\u3002\u7136\u800c\uff0c\u5c3d\u7ba1\u53d6\u5f97\u4e86\u4e00\u4e9b\u8fdb\u5c55\uff0c\u4f46\u7531\u4e8e\u5bf9\u50ac\u5316\u673a\u7406\uff08\u7279\u522b\u662f\u7ed3\u6784\/\u6d3b\u6027\u5173\u7cfb\uff09\u7684\u7406\u89e3\u4e0d\u8db3\uff0c\u4e8c\u7ef4\u78b3\u6750\u6599\u7684\u4f4e\u6d3b\u6027\u3001\u9009\u62e9\u6027\u3001\u7a33\u5b9a\u6027\u548c\u7535\u6d41\u6548\u7387\u4ecd\u7136\u963b\u788d\u4e86\u5176\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u8fd1\u5e74\u6765\u5728\u6750\u6599\u8bbe\u8ba1\u3001\u8868\u5f81\u65b9\u6cd5\u548c\u673a\u7406\u7814\u7a76\u65b9\u9762\u7684\u7a81\u7834\u6781\u5927\u5730\u63a8\u52a8\u4e86\u4e8c\u7ef4\u5171\u4ef7\u7535\u50ac\u5316\u5242\u7684\u53d1\u5c55\uff0c\u63ed\u793a\u4e86\u591a\u79cd\u5177\u6709\u9ad8\u50ac\u5316\u6027\u80fd\u7684\u4e8c\u7ef4\u6750\u6599\uff0c\u5176\u6027\u80fd\u751a\u81f3\u4f18\u4e8e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u3002\u57fa\u4e8e\u6d3b\u6027\u4f4d\u70b9\u7684\u7c7b\u578b\u53ca\u5176\u901a\u8fc7\u70ed\u89e3\u7cbe\u7ec6\u8c03\u63a7\u7684\u7b56\u7565\uff0c\u4ee5\u4e0b\u90e8\u5206\u5c06\u4ecb\u7ecd\u8fd9\u4e9b\u9ad8\u6027\u80fd\u7684\u4e8c\u7ef4\u78b3\u6750\u6599\u5728\u7535\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n 4.1 \u65e0\u91d1\u5c5e\u6742\u539f\u5b50\u63ba\u6742<\/p>\n \u65e0\u91d1\u5c5e\u4e8c\u7ef4\u78b3\u6750\u6599\u5177\u6709\u8bb8\u591a\u4f18\u52bf\uff0c\u5982\u4f4e\u6210\u672c\u3001\u9ad8\u7a33\u5b9a\u6027\u3001\u5316\u5b66\u8010\u53d7\u6027\u3001\u826f\u597d\u7684\u5bfc\u7535\u6027\u548c\u53ef\u8c03\u7684\u7535\u5b50\u7279\u6027\u3002\u7136\u800c\uff0c\u539f\u59cb\u77f3\u58a8\u70ef\u7247\u7684\u7535\u50ac\u5316\u6027\u80fd\u8f83\u5dee\uff0c\u4e3b\u8981\u662f\u7531\u4e8e\u7f3a\u4e4f\u80fd\u591f\u7279\u5f02\u6027\u7ed3\u5408\u53cd\u5e94\u7269\u5206\u5b50\uff08\u5982\u6c34\u3001O\u2082\u3001N\u2082\u548cCO\u2082\uff09\u7684\u6d3b\u6027\u7269\u79cd\u3002\u56e0\u6b64\uff0c\u6750\u6599\u5316\u5b66\u7684\u591a\u79cd\u5de5\u5177\u88ab\u5e94\u7528\u4e8e\u8bbe\u8ba1\u7406\u60f3\u7684\u7ed3\u5408\u4f4d\u70b9\uff0c\u901a\u8fc7\u5f15\u5165\u6742\u539f\u5b50\u6216\u751f\u6210\u7ed3\u6784\u7f3a\u9677\u6765\u6270\u52a8sp\u00b2\u6742\u5316\u78b3\u57fa\u5e95\u7684\u7535\u5b50\u5bf9\u79f0\u6027\uff0c\u4ece\u800c\u8c03\u8282\u7ed3\u5408\u548c\u8fde\u7eed\u7684\u7535\u50ac\u5316\u8fc7\u7a0b\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u7531\u4e8e\u63ba\u6742\u539f\u5b50\u4e0e\u5bbf\u4e3b\u78b3\u9aa8\u67b6\u4e4b\u95f4\u7684\u7535\u8d1f\u6027\u4e0d\u540c\uff0c\u7535\u8377\u53d8\u5316\u4ee5\u53ca\u9178\u78b1\u76f8\u4e92\u4f5c\u7528\u88ab\u5f15\u5165\uff0c\u4ee5\u5728\u4e8c\u7ef4\u7535\u50ac\u5316\u5242\u4e2d\u5f62\u6210\u7406\u60f3\u7684\u6742\u539f\u5b50\u6d3b\u6027\u57fa\u56e2\u3002\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u6216\u5176\u4ed6\u8ba1\u7b97\u5efa\u6a21\u65b9\u6cd5\uff0c\u53ef\u4ee5\u6e05\u6670\u5730\u9610\u660e\u7ed3\u6784-\u6d3b\u6027\/\u9009\u62e9\u6027\u5173\u7cfb\uff0c\u4e3a\u672a\u6765\u5f00\u53d1\u9ad8\u6548\u7684\u4e8c\u7ef4\u78b3\u50ac\u5316\u5242\u63d0\u4f9b\u63cf\u8ff0\u5de5\u5177\u3002\u4e3a\u6b64\uff0c\u901a\u8fc7\u70ed\u805a\u5408\u65b9\u6cd5\u7cbe\u786e\u8bbe\u8ba1\u4e86\u5177\u6709\u4e0d\u540c\u6742\u539f\u5b50\uff08\u5982N\u3001O\u548cB\uff09\u7684\u4e8c\u7ef4\u78b3\u6750\u6599\uff0c\u4ee5\u5b9e\u73b0\u9ad8\u6548\u7684\u50ac\u5316\u8fc7\u7a0b\u3002<\/p>\n 4.2 \u7f3a\u9677\u5de5\u7a0b<\/p>\n \u539f\u59cbsp\u00b2\u6742\u5316\u77f3\u58a8\u70ef\u7f51\u7edc\u7684\u62d3\u6251\u504f\u5dee\u901a\u5e38\u4f1a\u5728\u78b3\u57fa\u8d28\u7684\u8fb9\u7f18\u6216\u6676\u754c\u6216\u5355\u7a7a\u4f4d\u5904\u4ea7\u751f\u7f3a\u9677\uff0c\u5982\u4e94\u8fb9\u5f62\u3001\u4e03\u8fb9\u5f62\u6216Thrower-Stone-Wales\u7f3a\u9677\uff0c\u8fd9\u4e9b\u7f3a\u9677\u5bf9\u7535\u5316\u5b66\u53cd\u5e94\uff08\u5982CO\u2082\u8fd8\u539f\u548cORR\uff09\u8868\u73b0\u51fa\u9ad8\u6d3b\u6027\/\u9009\u62e9\u6027\u3002\u901a\u8fc7DFT\u6a21\u578b\uff0c\u5df2\u7ecf\u9610\u660e\u96c6\u4f53\u78b3\u7535\u5b50\u4e91\u4e0a\u7684\u8f68\u9053\u53ef\u4ee5\u901a\u8fc7\u5305\u542b\u7684\u78b3\u7f3a\u9677\u8f7b\u677e\u8c03\u8282\uff0c\u4ece\u800c\u8d4b\u4e88\u5b83\u4eec\u5bf9\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u6539\u8fdb\u4eb2\u548c\u529b\uff0c\u5e76\u52a0\u901fORR\u8fc7\u7a0b\u4e2d\u7684\u7f13\u6162\u52a8\u529b\u5b66\u3002\u6b64\u5916\uff0c\u7ed3\u6784\u7f3a\u9677\u7684\u5f62\u6210\u901a\u5e38\u4f1a\u6539\u53d8\u5b54\u9699\u7387\uff08\u5982\u5fae\u5b54\u3001\u4e2d\u5b54\u751a\u81f3\u5927\u5b54\uff09\u548c\u5806\u79ef\u884c\u4e3a\uff0c\u4ece\u800c\u5f71\u54cd\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u8d28\u91cf\u4f20\u9012\u548c\u53cd\u5e94\u9009\u62e9\u6027\u3002\u56e0\u6b64\uff0c\u5408\u7406\u8bbe\u8ba1\u4e8c\u7ef4\u78b3\u6750\u6599\u4e2d\u7684\u7ed3\u6784\u7f3a\u9677\u4ee3\u8868\u4e86\u4e00\u79cd\u63d0\u9ad8\u60f0\u6027\u78b3\u9aa8\u67b6\u7535\u50ac\u5316\u6027\u80fd\u7684\u53ef\u884c\u89e3\u51b3\u65b9\u6848\u3002\u5b9e\u9a8c\u4e0a\uff0cTao\u7b49\u4eba\u901a\u8fc7\u7b49\u79bb\u5b50\u4f53\u8f85\u52a9\u8680\u523b\u5de5\u827a\u5f00\u53d1\u4e86\u5bcc\u542b\u8fb9\u7f18\u548c\u65e0\u63ba\u6742\u5242\u7684\u77f3\u58a8\u70ef\u4f5c\u4e3aORR\u7535\u50ac\u5316\u5242\u3002\u7531\u4e8e\u5f62\u6210\u4e86\u4e30\u5bcc\u7684\u8fb9\u7f18\u548c\u7f3a\u9677\u4f4d\u70b9\uff0c\u8be5\u50ac\u5316\u5242\u8868\u73b0\u51fa\u9ad8ORR\u6d3b\u6027\uff0c\u5177\u6709\u4f18\u5f02\u7684\u71c3\u6599\u9009\u62e9\u6027\u548c\u957f\u671f\u7a33\u5b9a\u6027\uff0c\u751a\u81f3\u4f18\u4e8e\u5546\u4e1aPt\/C\u7535\u6781\uff0c\u8bc1\u660e\u4e86\u5728\u4e8c\u7ef4\u77f3\u58a8\u70ef\u6750\u6599\u4e2d\u521b\u5efa\u7ed3\u6784\u7f3a\u9677\u5bf9\u7535\u50ac\u5316\u7684\u6709\u6548\u6027\u3002\u901a\u8fc7\u7406\u8bba\u6a21\u62df\uff0cZhao\u7b49\u4eba\u63cf\u8ff0\u4e86\u62d3\u6251\u7f3a\u9677\u4f9d\u8d56\u7684ORR\u6d3b\u6027\uff0c\u5176\u4e2d\u5305\u542b\u4e24\u4e2a\u4e94\u8fb9\u5f62\u548c\u4e00\u4e2a\u516b\u8fb9\u5f62\u7684\u6a21\u578b\u7f3a\u9677\u8bf1\u5bfc\u4e86\u5c40\u90e8\u7535\u5b50\u6001\u7684\u663e\u8457\u53d8\u5316\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86ORR\u8fc7\u7a0b\u4e2d\u7684\u901f\u7387\u51b3\u5b9a\u6b65\u9aa4\u3002\u6b64\u5916\uff0cDFT\u6a21\u578b\u8868\u660e\uff0c\u77f3\u58a8\u70ef\u8fb9\u7f18\u7684\u62d3\u6251\u7f3a\u9677\u5bf9ORR\u6027\u80fd\u7684\u5f71\u54cd\u5927\u4e8e\u63ba\u6742\u548c\u666e\u901a\u8fb9\u7f18\u7ec8\u6b62\u3002\u7136\u800c\uff0c\u5b9e\u9a8c\u9a8c\u8bc1\u8fd9\u4e9b\u9884\u6d4b\u9700\u8981\u7cbe\u786e\u8bbe\u8ba1\u78b3\u7f3a\u9677\/\u7a7a\u4f4d\uff0c\u8fd9\u4ecd\u7136\u8d85\u51fa\u4e86\u7b80\u5355\u70ed\u805a\u5408\u7684\u8303\u56f4\u3002\u4e3a\u4e86\u901a\u8fc7\u521b\u5efa\u7279\u5b9a\u7f3a\u9677\u5b9e\u73b0\u9ad8\u6548\u7684\u50ac\u5316\u8fc7\u7a0b\uff0cJia\u7b49\u4eba\u4ece\u6c2e\u63ba\u6742\u524d\u4f53\u4e2d\u53bb\u9664\u6742\u539f\u5b50\uff0c\u5f00\u53d1\u4e86\u5177\u6709\u5404\u79cd\u62d3\u6251\u7f3a\u9677\u7684\u4e8c\u7ef4\u77f3\u58a8\u70ef\u6750\u6599\u3002\u4f7f\u7528\u9ad8\u5206\u8fa8\u7387\u50cf\u5dee\u6821\u6b63TEM\uff0c\u5728\u77f3\u58a8\u70ef\u57fa\u5e95\u7684\u8fb9\u7f18\u63ed\u793a\u4e86\u4e0d\u540c\u7c7b\u578b\u7684\u78b3\u7f3a\u9677\uff08\u4e94\u8fb9\u5f62\u3001\u4e03\u8fb9\u5f62\u548c\u516b\u8fb9\u5f62\uff09\uff0c\u63d0\u4f9b\u4e86\u5173\u4e8e\u63ba\u6742\u4e8c\u7ef4\u78b3\u50ac\u5316\u5242\u4e2d\u62d3\u6251\u7f3a\u9677\u7684\u6e05\u6670\u5b9e\u9a8c\u8bc1\u636e\u3002\u53d7\u76ca\u4e8e\u8fd9\u79cd\u9ad8\u5ea6\u7f3a\u9677\u7684\u7ed3\u6784\uff0cJia\u7b49\u4eba\u5f00\u53d1\u7684\u4e8c\u7ef4\u77f3\u58a8\u70ef\u6750\u6599\u8fd8\u8868\u73b0\u51fa\u6539\u8fdb\u7684\u7269\u7406\u5316\u5b66\u8868\u9762\u6027\u8d28\uff0c\u5bfc\u81f4\u4e0d\u540c\u7684\u50ac\u5316\u5242\u8868\u9762\u79ef\u548c\u758f\u6c34\u6027\u3002\u6b63\u5982\u9884\u671f\u7684\u90a3\u6837\uff0c\u7f3a\u9677\u77f3\u58a8\u70ef\u50ac\u5316\u5242\u663e\u793a\u51fa\u6bd4\u539f\u59cb\u548c\u63ba\u6742\u77f3\u58a8\u70ef\u6837\u54c1\u66f4\u9ad8\u7684ORR\u6d3b\u6027\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u5728\u8fd9\u79cd\u4e8c\u7ef4\u78b3\u6750\u6599\u4e2d\u5305\u542b\u4e0d\u540c\u7c7b\u578b\u7684\u7ed3\u6784\u7f3a\u9677\uff0c\u7f3a\u9677\u77f3\u58a8\u70ef\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u8fd8\u8868\u73b0\u51fa\u826f\u597d\u7684OER\u548cHER\u6d3b\u6027\uff0c\u4f5c\u4e3aORR\u3001OER\u548cHER\u7684\u4e09\u529f\u80fd\u7535\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u7b80\u5355\u5730\u8bbe\u8ba1\u78b3\u7f3a\u9677\u5b9e\u73b0\u4e86\u9ad8\u6548\u7684\u7535\u50ac\u5316\u8f6c\u5316\u3002\u8fd9\u4e00\u6982\u5ff5\u5f97\u5230\u4e86\u53e6\u4e00\u9879\u5de5\u4f5c\u7684\u652f\u6301\uff0c\u8be5\u5de5\u4f5c\u4e13\u6ce8\u4e8e\u4f7f\u7528\u4ece\u7c7b\u4f3c\u7684\u6c2e\u53bb\u9664\u7b56\u7565\u884d\u751f\u7684\u7f3a\u9677\u4ecb\u5b54\u78b3\/\u77f3\u58a8\u70ef\u8fdb\u884cCO\u2082\u7535\u8fd8\u539f\u4e3aCO\uff0c\u5176\u4e2d\u78b3\u7f3a\u9677\u5728\u67d0\u4e9b\u50ac\u5316\u4f5c\u7528\u4e2d\u53ef\u4ee5\u8d85\u8d8a\u6742\u539f\u5b50\u63ba\u6742\u5242\u7684\u529f\u80fd\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728\u6700\u8fd1\u7684\u51e0\u9879\u7814\u7a76\u4e2d\uff0c\u77f3\u58a8\u70ef\u57fa\u5e95\u4e2d\u8fd9\u4e9b\u7ed3\u6784\u7f3a\u9677\u7684\u50ac\u5316\u6d3b\u6027\u4e5f\u88ab\u8bc1\u660e\u5728\u52a0\u901f2e-ORR\u8fc7\u7a0b\u4e2d\u6709\u6548\uff0c\u5728\u5177\u6709\u9762\u5185\u6216\u9762\u5916\u7f3a\u9677\u7684\u8fb9\u7f18\u5bcc\u77f3\u58a8\u70ef\u4e0a\u8868\u73b0\u51fa\u9ad8H\u2082O\u2082\u9009\u62e9\u6027\u3002\u7136\u800c\uff0c\u5c3d\u7ba1\u6709\u76f8\u5f53\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4f46\u7531\u4e8e\u5176\u5c40\u90e8\u5316\u5b66\u73af\u5883\u7684\u590d\u6742\u6027\uff0c\u5173\u4e8e\u4e8c\u7ef4\u78b3\u6750\u6599\u4e2d\u771f\u6b63\u6d3b\u6027\u7ed3\u6784\uff08\u5982sp\u00b2\u6216sp\u00b3\u7f3a\u9677\u3001\u62d3\u6251\u7a7a\u4f4d\u7c7b\u578b\uff09\u7684\u4e89\u8bba\u4ecd\u5728\u7ee7\u7eed\u3002\u5df2\u77e5\u7528\u4e8e\u521b\u5efa\u8fd9\u4e9b\u62d3\u6251\u7f3a\u9677\u7684\u9ad8\u6e29\u4e5f\u53ef\u80fd\u4fc3\u8fdb\u4e8c\u7ef4\u78b3\u4e2d\u77f3\u58a8\u9aa8\u67b6\u7684\u6062\u590d\uff08\u90e8\u5206\u7531\u4e8e\u78b3\u539f\u5b50\u7684\u5f3a\u70c8\u70ed\u8fd0\u52a8\uff09\uff0c\u8fd9\u53ef\u80fd\u4f1a\u9650\u5236\u6700\u7ec8\u7684\u7f3a\u9677\u542b\u91cf\u3002\u6b64\u5916\uff0c\u5c3d\u7ba1\u901a\u8fc7\u53bb\u9664\u77f3\u58a8\u70ef\u4e2d\u7684\u5916\u6765\u6742\u539f\u5b50\uff08\u5982N\uff09\u66f4\u5bb9\u6613\u83b7\u5f97\u7a7a\u4f4d\uff0c\u4f46\u53bb\u9664\u8fc7\u7a0b\u901a\u5e38\u662f\u4e0d\u5b8c\u5168\u7684\uff0c\u4e0d\u53ef\u907f\u514d\u5730\u4f1a\u5728\u6700\u7ec8\u4ea7\u54c1\u4e2d\u7559\u4e0b\u4e00\u5b9a\u91cf\u7684N\u6b8b\u7559\u3002\u56e0\u6b64\uff0c\u7cbe\u786e\u63a7\u5236\u4e8c\u7ef4\u78b3\u7535\u50ac\u5316\u5242\u4e2d\u7684\u7279\u5b9a\u78b3\u7f3a\u9677\u7ed3\u6784\u662f\u672a\u6765\u673a\u7406\u7814\u7a76\u7684\u70ed\u95e8\u8bdd\u9898\u3002\u4e3a\u6b64\uff0cChen\u7b49\u4eba\u5c55\u793a\u4e86\u4e00\u79cd\u6c28\u8f85\u52a9\u70ed\u5904\u7406\u65b9\u6cd5\uff0c\u7528\u4e8e\u5f7b\u5e95\u53bb\u9664\u5bcc\u6c2e\u591a\u5b54\u78b3\u4e2d\u7684\u6742\u539f\u5b50\uff0c\u65e8\u5728\u521b\u5efa\u5927\u91cf\u5177\u6709\u53ef\u533a\u5206\u78b3\u7ed3\u6784\u7684\u7f3a\u9677\u3002\u7ed3\u679c\uff0c\u5408\u6210\u7684\u78b3\u6750\u6599\u8868\u73b0\u51fa\u9ad8\u5bc6\u5ea6\u7684\u62d3\u6251\u7f3a\u9677\uff0c\u8fd9\u4e9b\u7f3a\u9677\u4e0e\u7535\u50ac\u5316CO\u2082-to-CO\u6027\u80fd\u5448\u6b63\u76f8\u5173\u3002\u7ed3\u5408\u6750\u6599\u8868\u5f81\u548cDFT\u8ba1\u7b97\uff0c\u6240\u6709\u7ed3\u679c\u90fd\u8bc1\u5b9e\u4e865\u5143\u73afC\u7f3a\u9677\u8fb9\u7f18\u4f4d\u70b9\u5728\u4fc3\u8fdbCO\u2082RR\u884c\u4e3a\u4e2d\u7684\u4e0d\u53ef\u6216\u7f3a\u7684\u4f5c\u7528\uff0c\u8bc1\u660e\u4e86\u62d3\u6251\u7a7a\u4f4d\u5bf9CO\u2082RR\u7684\u50ac\u5316\u6709\u6548\u6027\u3002\u9664\u4e86\u8fd9\u4e9b\u78b3\u7a7a\u4f4d\u4e4b\u5916\uff0c\u5728\u8fd9\u79cd\u7f3a\u9677\u78b3\u4e2d\uff0c\u6c27\u529f\u80fd\u57fa\u56e2\u7684\u6f5c\u5728\u5f71\u54cd\u4e5f\u4e0d\u5e94\u88ab\u5b8c\u5168\u5ffd\u89c6\uff0c\u56e0\u4e3a\u50ac\u5316\u6d3b\u6027\u6c27\u7269\u79cd\u503e\u5411\u4e8e\u4e0e\u78b3\u7a7a\u4f4d\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u53ef\u80fd\u5f71\u54cd\u53cd\u5e94\u8def\u5f84\u3002<\/p>\n \u00a0\u00a0 Figure 1. Schematic illustration of bottom-up synthesis of 2D carbonaceous electrocatalysts through the thermal pyrolysis method.<\/p>\n Figure 2. Scanning electron microscopy (SEM) images of 2D carbons made of glucose in eutectic, noninnocent salt melts: (a) N-doped carbon sheets, N-CS; (b) S-doped carbon sheets, S-CS. (c) The nitrogen sorption isotherms, indicating that the sheets have a high outer surface area, but also inner microporosity.<\/p>\n Figure 3. TEM micrographs of (a) BMP-800 and (b) meso-BMP-800. (c) Electrochemical ORR performance of the meso-BMP-800 catalyst compared with the commercial Vulcan XC 72R carbon in 0.1 M HClO4<\/sub>. The inset shows the cyclic voltammogram of meso-BMP-800 and Vulcan XC 72R measured without rotation in deaerated 0.1 M HClO4<\/sub>. (d) Schematic illustration of the N-FLG preparation procedure. (e) TEM image of N-FLG. (f) ORR polarization curves of N-FLG-8, N-FLG-12, and N-FLG-16, showing the ORR current density on the disk (jdisk) and the detected H2<\/sub>O2<\/sub>\u00a0currents on the ring electrode (Iring). (g) The calculated H2<\/sub>O2<\/sub>\u00a0selectivity and corresponding electron transfer number.<\/p>\n Figure 4. (a) Schematic of N-doped topological defects catalyst (S-1-900) synthesis. (b) Low-resolution and (c) the aberration-corrected TEM images of S-1-900. Inset images in Figure 4c are enlarged images from the red dash squares from areas 1 and 2 in (c). (d) ORR activity of S-1-900, commercial Pt\/C and N-doped carbon in 0.1 M HClO4<\/sub>.<\/p>\n Figure 5. (a) TEM and (b) corresponding EDS mappings of BG-1 for B, C, and O. (c) The NH3<\/sub>\u00a0production rates (left y axis) and Faradaic efficiency for NH3<\/sub>\u00a0(right y axis) of BG-1. The error bars represent the average of three independent measurements. (d) Typical AFM image and (e) low-resolution TEM image of BG. (f) ORR activity of graphene\/GCE, BG\/GCE and bulk Pt disk electrode in an O2<\/sub>-saturated 0.1 M KOH solution.<\/p>\n Figure 6. (a) Electrochemical ORR behavior of the as-prepared F-mrGO, A-mrGO, and XC72-based electrodes. (b) Idealized schemes of proposed low-overpotential active sites on F-mrGO and F-mrGO (600). (c) Different oxygen functional group type configurations examined in this study. The carbon atoms denoted by a blue circle are the active sites under investigation (M = H and Na). (d) Calculated two-electron (solid black) ORR-related volcano plot for the ORR to H2<\/sub>O2<\/sub>\u00a0displayed with the limiting potential plotted as a function of \u0394GOOH*.<\/p>\n Figure 7. (a) ORR curves of BCN graphene with different compositions in 0.1 M KOH. (b) Polarization curves of B-doped graphene, N doped graphene, h-BN-dominated graphene, and h-BN-free graphene electrocatalysts in 0.1 M KOH and (c) their corresponding HO2<\/sub>\u2212selectivity and electron transfer number. (d) STEM image of BNG sample and EDS elemental maps for B, C, N, and O. (e) ORR activity of BNG samples.<\/p>\n Figure 8. (a) Schematic of synthesis procedure of CNB-ZIL catalysts. (b) TEM image and (c) corresponding elemental maps for B, N, and C on CNB-ZIL 8. (d) B K-edge near edge X-ray absorption fine structure (NEXAFS) spectra of the CNB-ZIL catalysts and a boron nitride sample for comparison. (e) 2e\u2212 ORR performance of CNB-ZIL catalysts and (f) their HO2<\/sub>\u00a0\u2212 selectivity in 0.1 M KOH.<\/p>\n Figure 9. (a) The schematic of the formation mechanism of defective graphene. (b) HAADF image of defective graphene. Hexagons, pentagons, heptagons, and octagons were labeled in orange, green, blue, and red, respectively. (c) ORR, (d) OER, and (e) HER activity of defective graphene (DG), N-doped graphene (NG), graphene (G), and commercial Pt\/C and Ir\/C.<\/p>\n \u00a0\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n \u540c\u6d4e\u5927\u5b66\u5f20\u6e05\u7136\u8054\u5408\u6cb3\u5357\u5927\u5b66\u7530\u5fd7\u7ea2\u4ece\u591a\u4e2a\u89d2\u5ea6\u7cfb\u7edf\u56de\u987e\u4e86\u4e8c\u7ef4\u78b3\u8d28\u6750\u6599\u5728\u7535\u50ac\u5316\u9886\u57df\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u53ca\u5176\u5728\u53ef\u63a7\u50ac\u5316\u7684\u7535\u5316\u5b66\u80fd\u91cf\u8f6c\u6362\u4e0e\u5b58\u50a8\u6280\u672f\u4e2d\u7684\u5e94\u7528\u3002\u603b\u7ed3\u4e86\u4e8c\u7ef4\u78b3\u8d28\u6750\u6599\u5728\u5b9e\u9645\u7535\u50ac\u5316\u5e94\u7528\u4e2d\u7684\u4e3b\u8981\u6311\u6218\u4e0e\u673a\u9047\uff0c\u5305\u62ec\u5408\u6210\u65b9\u6cd5\u7684\u53ef\u91cd\u590d\u6027\u4e0e\u89c4\u6a21\u5316\u3001\u6d3b\u6027\u57fa\u5e8f\u7684\u7cbe\u786e\u63a7\u5236\u4ee5\u53ca\u539f\u4f4d\u8868\u5f81\u6280\u672f\u7684\u5f00\u53d1\u7b49\u3002\u540c\u65f6\uff0c\u4e3a\u4e8c\u7ef4\u78b3\u8d28\u6750\u6599\u5728\u7535\u50ac\u5316\u9886\u57df\u7684\u672a\u6765\u53d1\u5c55\u63d0\u4f9b\u4e86\u7cfb\u7edf\u7684\u7406\u8bba\u6307\u5bfc\u548c\u5b9e\u8df5\u65b9\u5411\uff0c\u4e3a\u63a8\u52a8\u53ef\u6301\u7eed\u80fd\u6e90\u6280\u672f\u7684\u8fdb\u6b65\u5960\u5b9a\u4e86\u91cd\u8981\u57fa\u7840\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cEmerging two-dimensional carbonaceous materials for electrocatalytic energy conversions: rational design of active structures through high-temperature chemistry\u201d\u4e3a\u9898\u53d1\u8868\u4e8eACS Nano. \uff08DOI: 10.1021\/acsnano.3c12198\uff09<\/p>\n \u3010\u7ed3\u8bba\u3011<\/strong><\/p>\n \u7535\u5316\u5b66\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u6280\u672f\u662f\u672a\u6765\u6700\u5177\u524d\u666f\u7684\u80fd\u6e90\u89e3\u51b3\u65b9\u6848\u4e4b\u4e00\uff0c\u5176\u6838\u5fc3\u5728\u4e8e\u5f00\u53d1\u9ad8\u6548\u7535\u50ac\u5316\u5242\uff0c\u800c\u4e8c\u7ef4\u78b3\u6750\u6599\u51ed\u501f\u4e30\u5bcc\u7684\u8fb9\u7f18\u4f4d\u70b9\u3001\u5927\u8868\u9762\u79ef\u3001\u9ad8\u5bfc\u7535\u6027\u53ca\u53ef\u8c03\u7535\u8377\/\u81ea\u65cb\u5bc6\u5ea6\uff0c\u5728\u7535\u50ac\u5316\u9886\u57df\u5c55\u73b0\u51fa\u5353\u8d8a\u6027\u80fd\uff0c\u751a\u81f3\u5728\u67d0\u4e9b\u5e94\u7528\u4e2d\u8d85\u8d8a\u4e86\u8d35\u91d1\u5c5e\u57fa\u51c6\uff08\u5982Pt\u3001RuO\u2082\u6216IrO\u2082\uff09\u3002\u901a\u8fc7\u9ad8\u6e29\u70ed\u805a\u5408\/\u9000\u706b\u65b9\u6cd5\uff0c\u524d\u4f53\u5206\u5b50\u548c\u9000\u706b\u6e29\u5ea6\u53ef\u7cbe\u7ec6\u8c03\u63a7\u63ba\u6742\u539f\u5b50\u3001\u8fb9\u7f18\u7ec8\u6b62\u548c\u7f3a\u9677\uff0c\u663e\u8457\u63d0\u5347\u4e86\u65e0\u91d1\u5c5e\u4e8c\u7ef4\u78b3\u50ac\u5316\u5242\u5728ORR\u548cCO\u2082RR\u7b49\u53cd\u5e94\u4e2d\u7684\u6027\u80fd\uff0c\u5176\u4e2dB\/N\u5171\u63ba\u6742\u6750\u6599\u7684\u534f\u540c\u6548\u5e94\u53ca\u754c\u9762B-N-C\u57fa\u5e8f\u88ab\u8bc1\u5b9e\u4e3a\u5173\u952e\u6d3b\u6027\u4f4d\u70b9\uff0c\u800c\u8868\u9762\u6c27\u529f\u80fd\u5316\u548c\u7f3a\u9677\u4fee\u9970\uff08\u5982C-O-C\u57fa\u5e8f\uff09\u8fdb\u4e00\u6b65\u62d3\u5bbd\u4e86\u50ac\u5316\u8def\u5f84\u7684\u53ef\u8c03\u6027\u3002\u7136\u800c\uff0c\u4e8c\u7ef4\u78b3\u50ac\u5316\u5242\u7684\u672a\u6765\u53d1\u5c55\u4ecd\u9762\u4e34\u5408\u6210\u65b9\u6cd5\u89c4\u6a21\u5316\u3001\u6d3b\u6027\u57fa\u5e8f\u7cbe\u786e\u63a7\u5236\u53ca\u539f\u4f4d\u8868\u5f81\u6280\u672f\u5f00\u53d1\u7b49\u6311\u6218\uff0c\u9700\u8fdb\u4e00\u6b65\u4f18\u5316\u8bbe\u8ba1\u4ee5\u6ee1\u8db3\u7eff\u8272\u7535\u529b\u548c\u6c22\u7ecf\u6d4e\u7684\u5b9e\u9645\u9700\u6c42\uff0c\u63a8\u52a8\u53ef\u6301\u7eed\u80fd\u6e90\u6280\u672f\u7684\u8fdb\u6b65\u3002<\/p>\n \u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n \u5f20\u6e05\u7136\u535a\u58eb\u4e8e2022\u5e74\u52a0\u5165\u540c\u6d4e\u5927\u5b66\uff0c\u73b0\u62c5\u4efb\u73af\u5883\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u957f\u8058\u526f\u6559\u6388\u517c\u7279\u8058\u7814\u7a76\u5458\uff0c\u9ad8\u7b49\u7814\u7a76\u9662\u9752\u5e74\u767e\u4eba\uff08A\u5c97\uff09\uff0c\u535a\u58eb\u751f\u3001\u7855\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u9ad8\u5c42\u6b21\u9752\u5e74\u4eba\u624d\u8ba1\u5212\u5165\u9009\u8005\uff0c\u83b7\u4e0a\u6d77\u5e02\u9ad8\u5c42\u6b21\u4eba\u624d\uff08\u9886\u519b\u4eba\u624d\uff09\u79f0\u53f7\u7b49\u8363\u8a89\u3002\u535a\u58eb\u6bd5\u4e1a\u4e8e\u6fb3\u5927\u5229\u4e9a\u65b0\u5357\u5a01\u5c14\u58eb\u5927\u5b66\uff0c\u5e08\u4ece\u5973\u738b\u751f\u65e5\u52cb\u7ae0\u83b7\u5f97\u8005\uff0c\u6fb3\u5927\u5229\u4e9a\u4e09\u9662\u9662\u58ebRose Amal\u6559\u6388\u3002\u8fd1\u5e74\u6765\u5148\u540e\u5728 Science Advances\uff0cNature Communications, Advanced Energy Materials, Energy and Environmental Science, Angewandte\uff0cACS nano\uff0cWater Research \u7b49\u56fd\u9645\u4e00\u6d41\u671f\u520a\u4e0a\u53d1\u8868\u9ad8\u6c34\u5e73\u5b66\u672f\u8bba\u658730\u4f59\u7bc7\u3002<\/p>\n \u539f\u6587\u8be6\u60c5<\/strong>\uff1a<\/p>\n \u672c\u6587\u7531XXX\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":" \u3010\u5f15\u8a00\u3011 \u00a0 \u968f\u7740\u6c14\u5019\u53d8\u5316\u3001\u80fd\u6e90\u5371\u673a\u548c\u73af\u5883\u6076\u5316\u7684\u65e5\u76ca\u4e25\u91cd\uff0c\u5bfb\u627e\u6e05\u6d01\u548c\u53ef\u518d\u751f\u80fd\u6e90\u5df2\u6210\u4e3a\u5b9e\u73b0\u53ef\u6301\u7eed\u7ecf\u6d4e\u7684\u57fa\u7840\u3002\u5728\u8fd9\u4e00\u8f6c\u578b\u8fc7\u7a0b\u4e2d\uff0c\u5148\u8fdb\u7684\u80fd\u6e90\u8f6c\u6362\u7cfb\u7edf\uff08\u5982\u6c34\/CO\u2082\u7535\u89e3…<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-265601","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265601"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=265601"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265601\/revisions"}],"predecessor-version":[{"id":265611,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265601\/revisions\/265611"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=265601"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=265601"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=265601"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\n
\n
\n
\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n