{"id":265204,"date":"2025-02-27T07:25:23","date_gmt":"2025-02-26T23:25:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=265204"},"modified":"2025-02-26T22:33:28","modified_gmt":"2025-02-26T14:33:28","slug":"%e6%b9%96%e5%8d%97%e5%a4%a7%e5%ad%a6%e4%bd%95%e6%b8%85-%e5%bd%ad%e6%a1%91%e7%8f%8a%e8%af%be%e9%a2%98%e7%bb%84adv-energy-mater-%ef%bc%9a-%e8%b6%85%e5%88%86%e5%ad%90%e7%9b%b8%e4%ba%92%e4%bd%9c%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=265204","title":{"rendered":"\u6e56\u5357\u5927\u5b66\u4f55\u6e05\/\u5f6d\u6851\u73ca\u8bfe\u9898\u7ec4Adv. Energy Mater.\uff1a \u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u9a71\u52a8\u805a\u82b3\u57fa\u54cc\u5576\u819c\u975e\u6676\u5316\u4ee5\u589e\u5f3a\u8d28\u5b50\u4f20\u5bfc"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265205\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-29.png\" alt=\"\" width=\"980\" height=\"331\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-29.png 980w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-29-300x101.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-29-768x259.png 768w\" sizes=\"(max-width: 980px) 100vw, 980px\" \/>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>\u975e\u6c1f\u5316\u805a\u5408\u7269\u819c\u4e3a\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60(RFB)\u63d0\u4f9b\u4e86\u5546\u4e1a\u4e0a\u53ef\u884c\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u4f46\u5176\u5b9e\u9645\u5e94\u7528\u53d7\u5230\u56fa\u6709\u6311\u6218\u7684\u963b\u788d\uff0c\u5982\u5316\u5b66\u4e0d\u7a33\u5b9a\u6027\u548c\u4f4e\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u5728\u8fd9\u9879\u7814\u7a76\u4e2d\uff0c\u5f00\u53d1\u4e86\u4e00\u7cfb\u5217\u65e0\u919a\u952e\u7684\u805a(\u82b3\u57fa\u54cc\u5576)\u819c\uff0c\u901a\u8fc7\u4e0e\u6709\u673a\u9178\u7684\u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u7834\u574f\u65e0\u919a\u805a(\u82b3\u57fa\u54cc\u5576)\u819c\u4e2d\u7684\u94fe\u5806\u79ef\u6765\u89e3\u51b3\u8fd9\u4e9b\u9650\u5236\u3002\u8fd9\u79cd\u8bbe\u8ba1\u901a\u8fc7\u6d88\u9664\u5316\u5b66\u4e0d\u7a33\u5b9a\u7684\u82b3\u57fa\u919a\u952e\u548c\u907f\u514d\u989d\u5916\u7684\u5316\u5b66\u4fee\u9970\uff0c\u4f7f\u5f97\u819c\u8868\u73b0\u51fa\u663e\u8457\u7684\u957f\u671f\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u540c\u65f6\uff0c\u6709\u673a\u9178\u7684\u76f8\u4e92\u4f5c\u7528\u6709\u6548\u5730\u7834\u574f\u4e86\u5bc6\u96c6\u7684\u805a\u5408\u7269\u94fe\uff0c\u5c06\u8d28\u5b50\u4e0d\u53ef\u8fdb\u5165\u7684\u7ed3\u6676\u533a\u57df\u8f6c\u5316\u4e3a\u53ef\u8fdb\u5165\u7684\u65e0\u5b9a\u5f62\u533a\u57df\uff0c\u5229\u7528\u805a\u5408\u7269\u57fa\u8d28\u5185\u7684\u94fe\u95f4\u95f4\u9699\u8fdb\u884c\u5feb\u901f\u548c\u9009\u62e9\u6027\u7684\u8d28\u5b50\u4f20\u8f93(\u56fe1a)\u3002\u5b9e\u9a8c\u6570\u636e\u548c\u7406\u8bba\u6a21\u578b\u8868\u660e\uff0c\u8be5\u819c\u7684\u4f18\u5f02\u6027\u80fd\u6e90\u4e8e\u76f8\u4e92\u8fde\u63a5\u4e14\u5e7f\u6cdb\u5206\u5e03\u7684\u94fe\u95f4\u95f4\u9699\uff0c\u5176\u5b54\u8154\u6781\u9650\u76f4\u5f84\u7ea6\u4e3a8 \u00c5\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u65b0\u8bbe\u8ba1\u5177\u6709\u4ee5\u4e0b\u7684\u4f18\u52bf:1)\u7406\u8bba\u4e0a\uff0c\u819c\u57fa\u8d28\u4e2d\u7684\u94fe\u95f4\u95f4\u9699\u6bd4\u4eb2\u6c34\u7eb3\u7c73\u76f8\u66f4\u4e30\u5bcc\u4e14\u5206\u5e03\u66f4\u5e7f\uff0c\u6709\u52a9\u4e8e\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u7a81\u7834\u30022)\u8fd9\u4e9b\u95f4\u9699\u9884\u8ba1\u6bd4\u7eb3\u7c73\u7ea7\u4eb2\u6c34\u57df\u5c0f\u5f97\u591a\uff0c\u589e\u5f3a\u4e86\u5bf9\u6d3b\u6027\u7269\u8d28\u7684\u963b\u9694\u6027\u80fd\u30023)\u4f7f\u7528\u65e0\u919a\u805a\u5408\u7269\u4f5c\u4e3a\u819c\u6750\u6599\u6d88\u9664\u4e86\u4e0e\u5316\u5b66\u4e0d\u7a33\u5b9a\u7684\u82b3\u57fa\u919a\u952e\u76f8\u5173\u7684\u4e3b\u94fe\u964d\u89e3\u95ee\u9898\u30024)\u8fd9\u79cd\u8bbe\u8ba1\u7ee7\u627f\u4e86\u4f2a\u7eb3\u7c73\u76f8\u5206\u79bb\u7b56\u7565\u7684\u4f18\u70b9\uff0c\u4f8b\u5982\u6d88\u9664\u5316\u5b66\u4fee\u9970\u548c\u7b80\u5316\u819c\u5236\u5907\u8fc7\u7a0b\u3002\u5229\u7528\u5177\u6709\u589e\u5f3a\u7684\u94fe\u5806\u79ef\u65e0\u5e8f\u7684\u805a(\u82b3\u57fa\u54cc\u5576)\u819c\uff0c\u5176\u9492RFB\u5728280 mA cm<sup>-2<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5b9e\u73b0\u4e8680%\u7684\u80fd\u91cf\u6548\u7387\uff0c\u5e76\u5728\u8d85\u8fc71000\u6b21\u5145\u7535\/\u653e\u7535\u5faa\u73af\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u548c\u5bb9\u91cf\u4fdd\u6301\u7387\u3002<\/p>\n<p>\u5982\u56fe1b\u6240\u793a\uff0c\u7528\u67e0\u6aac\u9178(CA)\u548c\u4e19\u4e09\u9178(TA)\u5bf9PTP\u6eb6\u6db2\u8fdb\u884c<sup>1<\/sup>H NMR\u6ef4\u5b9a\u3002\u968f\u7740\u9178\u6d53\u5ea6\u7684\u589e\u52a0\uff0c\u4e0eN\u8fde\u63a5\u7684\u7532\u57fa\u6c22(H<sub>g<\/sub>)\u76f8\u5bf9\u5e94\u7684\u7279\u5f81\u5cf0\u9010\u6e10\u5411\u4f4e\u573a\u79fb\u52a8\uff0c\u8fd9\u8868\u660e\u5728PTP\u548c\u9178\u4e4b\u95f4\u5b58\u5728\u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u3002H<sub>g<\/sub>\u5728PTP\/CA\u4f53\u7cfb\u4e2d\u7684\u79fb\u52a8\u6bd4\u5728PTP\/TA\u4f53\u7cfb\u4e2d\u7684\u79fb\u52a8\u66f4\u660e\u663e\uff0c\u8fd9\u53ef\u80fd\u662f\u56e0\u4e3aCA\u5177\u6709\u989d\u5916\u7684-OH\u8d28\u5b50\u4f9b\u4f53\uff0cCA\u4e0ePTP\u53d1\u751f\u4e86\u66f4\u5f3a\u548c\u66f4\u5e7f\u6cdb\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u4e3a\u4e86\u9a8c\u8bc1\u8fd9\u4e00\u5047\u8bbe\uff0c\u672c\u6587\u8fdb\u884c\u4e86\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u3002\u5982\u56fe1c\u3001d\u6240\u793a\uff0c\u5728\u5f84\u5411\u5206\u5e03\u51fd\u6570(RDF)\u66f2\u7ebf\u4e0a\u89c2\u5bdf\u5230\u5c0f\u4e8e3 \u00c5\u7684\u5cf0\u662fPTP\u548c\u9178\u4e4b\u95f4\u7684\u6c22\u952e\u3002\u5177\u4f53\u6765\u8bf4\uff0cTA\u901a\u8fc7-COOH\u57fa\u56e2\u4ee52.15 \u00c5\u7684\u952e\u957f\u4e0ePTP\u5f62\u6210\u6c22\u952e\uff0c\u800cCA\u4e0d\u4ec5\u901a\u8fc7-COOH\u57fa\u56e2\u4e0ePTP\u5f62\u6210\u6c22\u952e\uff0c\u8fd8\u901a\u8fc7-OH\u57fa\u56e2\u4ee52.35 \u00c5\u7684\u952e\u957f\u76f8\u4e92\u4f5c\u7528(\u56fe1e)\u3002\u56e0\u6b64\uff0c\u5728PTP\/CA\u4f53\u7cfb\u4e2d\u6709\u66f4\u591a\u7684\u6c22\u952e\u6570\u76ee\u548c\u66f4\u5f3a\u7684\u76f8\u4e92\u4f5c\u7528(\u56fe1f\uff0cg)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265206\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-30.png\" alt=\"\" width=\"980\" height=\"831\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-30.png 980w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-30-300x254.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-30-768x651.png 768w\" sizes=\"(max-width: 980px) 100vw, 980px\" \/><\/p>\n<p>\u56fe1 a)\u901a\u8fc7\u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u7834\u574f\u805a\u5408\u7269\u94fe\u7684\u5bc6\u96c6\u5806\u79ef\u4ee5\u4fc3\u8fdb\u5feb\u901f\u548c\u9009\u62e9\u6027\u8d28\u5b50\u4f20\u8f93\u7684\u793a\u610f\u56fe\u3002(PTP:\u805a(\u5bf9-\u4e09\u8054\u82ef-N-\u7532\u57fa\u54cc\u5576)\uff0cTA:\u4e19\u4e09\u9178\uff0cCA:\u67e0\u6aac\u9178\uff0cDA:\u4e8c\u6c1f\u4e59\u9178\uff0cTCA:\u56db\u6c22\u544b\u5583-2\uff0c3\uff0c4\uff0c5\u56db\u7fa7\u9178\uff0cHHA: 1\uff0c2\uff0c3\uff0c4\uff0c5\uff0c6-\u73af\u5df1\u70f7\u516d\u7fa7\u9178)\u3002b)\u4f7f\u7528DMSO-d<sub>6<\/sub>\u4f5c\u4e3a\u6eb6\u5242\uff0c\u901a\u8fc7\u5411PTP\u6eb6\u6db2\u4e2d\u9010\u6e10\u52a0\u5165\u4e0d\u540c\u5f53\u91cf\u7684CA(\u5de6)\u6216TA(\u53f3)\u8fdb\u884c<sup>1<\/sup>H NMR\u6ef4\u5b9a\u3002c)PTP\/CA\u4f53\u7cfb\u4e2dN<sub>PTP<\/sub>-H<sub>CA-OH<\/sub>\u548cN<sub>PTP<\/sub>-H<sub>CA-COOH<\/sub>\u7684\u5f84\u5411\u5206\u5e03\u51fd\u6570(RDF)\u66f2\u7ebf\u3002d)PTP\/TA\u4f53\u7cfb\u4e2dN<sub>PTP<\/sub>-H<sub>TA-COOH<\/sub>\u7684RDF\u66f2\u7ebf\u3002e)\u4eceRDF\u66f2\u7ebf\u63a8\u5bfc\u51fa\u7684PTP\u548cCA(\u5de6)\u4ee5\u53caPTP\u548cTA(\u53f3)\u4e4b\u95f4\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u3002f,g)PTP\/CA\u4f53\u7cfb\u4e2dPTP\u4e0eCA\u4e4b\u95f4\u4ee5\u53caPTP\/TA\u4f53\u7cfb\u4e2dPTP\u4e0eTA\u4e4b\u95f4\u7684\u6c22\u952e\u6570\u548c(f)\u76f8\u4e92\u4f5c\u7528\u80fd(g)\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u901a\u8fc7\u6eb6\u6db2\u6d47\u94f8\u5236\u5907\u57fa\u4e8ePTP\u7684\u819c\uff0c\u5c06\u7279\u5b9a\u91cf\u7684CA\u6216TA\u7ed3\u5408\u5230\u6d47\u94f8\u6eb6\u6db2\u4e2d\u3002\u6240\u5f97\u819c\u547d\u540d\u4e3aPTP\/C-x\u548cPTP\/T-x\uff0c\u5176\u4e2dx = 1\u30012\u62163\u4ee3\u8868\u9178\u5206\u5b50\u4e2dPTP\u91cd\u590d\u5355\u5143\u4e0e\u7fa7\u57fa\u7684\u6469\u5c14\u6bd4(\u5206\u522b\u4e3a1\u22361\u30011\u22363\u548c1\u22365)\u3002\u968f\u540e\uff0c\u7528\u6c34\u548c\u786b\u9178\u6eb6\u6db2\u5bf9\u819c\u8fdb\u884c\u5f7b\u5e95\u6e05\u6d17\u4ee5\u9664\u53bb\u6709\u673a\u9178\uff0c\u5e76\u5c06\u5176\u6d78\u51653 M \u786b\u9178\u6eb6\u6db2\u4e2d\u5907\u7528\u3002\u8fd9\u4e9b\u5904\u7406\u8fc7\u7684\u819c\u5206\u522b\u6807\u8bb0\u4e3aPTP-Cx\u548cPTP-Tx\uff0c\u4e0d\u542bCA\u6216TA\u5236\u5907\u7684\u5bf9\u7167\u819c\u88ab\u8bb0\u4e3aPTP\u3002\u5982\u56fe2a\u6240\u793a\uff0c\u5728PTP-C2\u548cPTP-T2\u819c\u7684FTIR\u5149\u8c31\u4e2d\uff0cPTP\/C-2\u548cPTP\/T-2\u819c\u4e2d\u5b58\u5728\u76841730 cm<sup>-1<\/sup>\u5904\u7684C\u2550O\u62c9\u4f38\u5cf0\u6d88\u5931\u3002PTP-C2\u548cPTP-T2\u819c\u7684FTIR\u5149\u8c31\u4e0e\u539f\u59cb\u7684PTP\u76f8\u540c\uff0c\u8fd9\u8868\u660e\u6709\u673a\u9178\u88ab\u5b8c\u5168\u53bb\u9664\u3002\u5982\u56fe2b\u6240\u793a\uff0c\u539f\u59cbPTP\u819c\u7684\u5e7f\u89d2X\u5c04\u7ebf\u884d\u5c04(WAXD)\u56fe\u572818\u00b0\u548c22\u00b0\u663e\u793a\u51fa\u7a84\u7684\u884d\u5c04\u5cf0\u3002PTP-Cx\u548cPTP-Tx\u819c\u7684\u8fd9\u4e9b\u5cf0\u7684\u4f4d\u7f6e\u76f8\u5bf9\u4fdd\u6301\u4e0d\u53d8\uff0c\u4f46\u6709\u673a\u9178\u7684\u8c03\u8282\u5bfc\u81f4\u5cf0\u5f3a\u5ea6\u663e\u8457\u964d\u4f4e\uff0c\u7ed3\u6676\u5ea6\u964d\u4f4e\uff0c\u5e76\u4e14CA\u5728\u964d\u4f4e\u7ed3\u6676\u5ea6\u65b9\u9762\u6bd4TA\u8868\u73b0\u51fa\u66f4\u663e\u8457\u7684\u6548\u679c\uff0c\u8fd9\u662f\u7531\u4e8eCA\u548cPTP\u4e4b\u95f4\u66f4\u5f3a\u7684\u6c22\u952e\u3002\u4e3a\u4e86\u8bc4\u4f30\u7834\u574f\u94fe\u5806\u79ef\u5bf9\u819c\u5185\u8d28\u5b50\u53ef\u53ca\u7a7a\u9699\u7684\u5f71\u54cd\uff0c\u6784\u5efa\u4e09\u4e2a\u6a21\u62df\u7bb1\u8fdb\u884c\u4e86\u5b54\u9699\u5206\u6790\u3002\u5982\u56fe2d\u3001f\u6240\u793a\uff0c PTP\u7cfb\u7edf\u4e2d\u7684\u7a7a\u9699\u7a7a\u95f4\u51e0\u4e4e\u5b8c\u5168\u65ad\u5f00\u3002\u5728CA\u548cTA\u7684\u4f5c\u7528\u4e0b\uff0cPTP-C2\u548cPTP-T2\u5177\u6709\u66f4\u591a\u7684\u8d28\u5b50\u53ef\u53ca\u7a7a\u9699\u3002\u8fd9\u8868\u660e\u7834\u574f\u6676\u7574\u4ea7\u751f\u4e86\u989d\u5916\u7684\u7a7a\u9699\uff0c\u589e\u5f3a\u4e86\u819c\u5185\u7684\u4e92\u8fde\u5e76\u5f62\u6210\u4e86\u8fde\u7eed\u7684\u901a\u9053\u3002\u5982\u56fe2c\u6240\u793a\uff0cPTP-C2\u548cPTP-T2\u7cfb\u7edf\u7684\u5b54\u5f84\u90fd\u5c0f\u4e8e2 nm\u3002\u5982\u56fe2g\u3001h\u6240\u793a\uff0cPTP-C2\u7684\u6700\u5927\u7a7a\u8154\u76f4\u5f84(LCD)\u4e3a14.0 \u00c5\uff0c\u5b54\u9699\u6781\u9650\u76f4\u5f84(PLD)\u4e3a8.7\u00a0\u00c5\uff0c\u800cPTP-T2\u7684LCD\u4e3a17.4\u00a0\u00c5\uff0cPLD\u4e3a7.4\u00a0\u00c5\u3002\u5982\u56fe2i\u6240\u793a\uff0c\u4e0e\u6c34\u5408\u9492\u79bb\u5b50\u7684\u5c3a\u5bf8\u76f8\u6bd4\uff0c\u4e24\u4e2a\u7cfb\u7edf\u4e2d\u5b54\u9699\u7ed3\u6784\u80fd\u5bf9\u9492\u79bb\u5b50\u8d77\u5230\u8f83\u597d\u7684\u963b\u9694\u4f5c\u7528\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265207\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-28.png\" alt=\"\" width=\"980\" height=\"830\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-28.png 980w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-28-300x254.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-28-768x650.png 768w\" sizes=\"(max-width: 980px) 100vw, 980px\" \/><\/p>\n<p>\u56fe2 a)\u53bb\u9664\u6709\u673a\u9178\u4e4b\u524d(PTP\/C-2\u548cPTP\/T-2)\u548c\u4e4b\u540e(PTP-C2\u548cPTP-T2)\u7684PTP\u819c\u7684\u5085\u7acb\u53f6\u53d8\u6362\u7ea2\u5916(FTIR)\u5149\u8c31\u3002b)PTP\u3001PTP-C2\u548cPTP-T2\u819c\u7684\u5e7f\u89d2X\u5c04\u7ebf\u884d\u5c04(WAXD)\u56fe\u3002c)PTP-C2\u548cPTP-T2\u819c\u4e2d\u7684\u901a\u9053\u5c3a\u5bf8\u5206\u5e03\u3002d-f) PTP\u3001PTP-C2\u548cPTP-T2\u7cfb\u7edf\u6a21\u62df\u76d2\u5b50\u7684\u4e09\u7ef4\u53ef\u89c6\u5316(\u76d2\u5b50\u5c3a\u5bf8:5 \u00d7 5 \u00d7 5 nm)\u3002\u6709\u673a\u9178\u5728\u540e\u4e24\u4e2a\u7cfb\u7edf\u4e2d\u88ab\u53bb\u9664\u7528\u4e8e\u5b54\u9699\u5206\u6790\uff0c\u5176\u4e2d\u7ea2\u8272\u9634\u5f71\u8868\u793a\u5b64\u7acb\u7684\u5b54\u9699\uff0c\u7eff\u8272\u9634\u5f71\u8868\u793a\u76f8\u4e92\u8fde\u63a5\u7684\u5b54\u9699\u3002g\uff0ch) PTP-C2\u548cPTP-T2\u819c\u4e2d\u7684\u5b54\u6781\u9650\u76f4\u5f84(PLD)\u548c\u6700\u5927\u7a7a\u8154\u76f4\u5f84(LCD)\u3002i)\u7528\u4e8e\u5bf9\u6bd4\u5206\u6790\u7684\u6c34\u5408\u9492\u79bb\u5b50\u5c3a\u5bf8\u793a\u610f\u56fe\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u7ed3\u6676\u5ea6\u7684\u964d\u4f4e\u5bfc\u81f4PTP\u57fa\u819c\u7684\u9178\u548c\u6c34\u5438\u6536\u589e\u5f3a\u3002\u5982\u56fe3a\u6240\u793a\uff0c\u539f\u59cbPTP\u819c(&gt; 7.5 M)\u5185\u7684\u9178\u6d53\u5ea6\u9ad8\u4e8e\u73af\u5883\u9178\u6eb6\u6db2(3.0 M)\uff0c\u8fd9\u662f\u56e0\u4e3aPTP\u7ed3\u6784\u4e2d\u7684\u54cc\u5576\u57fa\u56e2\u4fc3\u8fdb\u4e86\u786b\u9178\u5bcc\u96c6\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cPTP-Cx\u548cPTP-Tx\u7cfb\u5217\u819c\u663e\u793a\u51fa\u6bd4\u539f\u59cbPTP\u819c\u66f4\u4f4e\u7684\u819c\u5185\u9178\u6d53\u5ea6\uff0c\u53ef\u80fd\u662f\u7531\u4e8e\u819c\u5185\u90e8\u548c\u5916\u90e8\u9178\u6027\u6eb6\u6db2\u4e4b\u95f4\u7684\u6e17\u900f\u538b\u68af\u5ea6\uff0c\u8fd9\u6709\u5229\u4e8e\u6c34\u7684\u5438\u6536\u800c\u4e0d\u662f\u9178\u3002\u5982\u56fe3b\u6240\u793a\uff0cPTP\u57fa\u819c\u7684\u9762\u7535\u963b\u968f\u7740\u6709\u673a\u9178\u7684\u589e\u52a0\u800c\u663e\u8457\u964d\u4f4e\u3002\u6839\u636e\u9762\u7535\u963b\u8ba1\u7b97\u7684\u8d28\u5b50\u4f20\u5bfc\u7387\u6d88\u9664\u4e86\u539a\u5ea6\u53d8\u5316\u7684\u5f71\u54cd\uff0cPTP-C2\/T2\u548cPTP-C3\/T3\u819c\u7684\u8d28\u5b50\u4f20\u5bfc\u7387\u662f\u539f\u59cbPTP\u819c\u768413.3-31.2\u500d\uff0c\u662fNafion 115\u76842.4-5.6\u500d(\u56fe3c)\u3002\u8d28\u5b50\u4f20\u8f93\u4e3b\u8981\u7531Grotthuss\u673a\u5236\u9a71\u52a8\uff0c\u6d3b\u5316\u80fd\u4f4e\u4e8e0.4 eV\u8bc1\u660e\u4e86\u8fd9\u4e00\u70b9(\u56fe3d)\u3002\u5982\u56fe3e\u6240\u793a\uff0c\u57fa\u4e8ePTP\u7684\u819c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u963b\u9492\u6027\u80fd\uff0c\u6bd4Nafion 115\u4f4e\u4e00\u5230\u4e24\u4e2a\u6570\u91cf\u7ea7\u3002\u603b\u7684\u6765\u8bf4\uff0cPTP-Cx\u548cPTP-Tx\u819c\u5b9e\u73b0\u4e86\u4f4e\u9762\u7535\u963b\u548c\u6700\u5c0f\u9492\u6e17\u900f\u4e4b\u95f4\u7684\u6709\u6548\u5e73\u8861\uff0c\u5728\u964d\u4f4e\u9762\u7535\u963b\u548c\u63d0\u9ad8\u8d28\u5b50\u7535\u5bfc\u7387\u65b9\u9762\u53d6\u5f97\u4e86\u663e\u8457\u8fdb\u6b65\uff0c\u8d85\u8fc7\u4e86\u6700\u8fd1\u62a5\u9053\u7684\u5176\u4ed6\u6587\u732e(\u56fe3f)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265208\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-28.png\" alt=\"\" width=\"980\" height=\"554\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-28.png 980w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-28-300x170.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-28-768x434.png 768w\" sizes=\"(max-width: 980px) 100vw, 980px\" \/><\/p>\n<p>\u56fe3 a)PTP\u57fa\u819c\u4e2d\u7684\u9178\u6d53\u5ea6(\u7531\u9178\u63ba\u6742\u6c34\u5e73\u548c\u819c\u7684\u5438\u6c34\u6c34\u5e73\u4f30\u8ba1)\u3002b)\u5ba4\u6e29\u4e0b\uff0c\u57283 M H<sub>2<\/sub>SO<sub>4<\/sub>\u6eb6\u6db2\u4e2d\u6d4b\u91cf\u7684PTP\u57fa\u819c\u548cNafion 115\u7684\u9762\u7535\u963b\u3002c)\u4ece\u9762\u7535\u963b\u5f97\u5230\u7684\u8de8\u5e73\u9762\u8d28\u5b50\u4f20\u5bfc\u7387\u3002d)\u963f\u4f26\u5c3c\u4e4c\u65af\u56fe\uff0c\u663e\u793a\u4e86\u5728293\u81f3333 K\u7684\u6e29\u5ea6\u8303\u56f4\u548c98%\u7684\u76f8\u5bf9\u6e7f\u5ea6\u4e0b\u5404\u79cd\u819c\u7684\u8d28\u5b50\u4f20\u8f93\u6d3b\u5316\u80fd(Ea)\u3002e)PTP\u57fa\u819c\u548cNafion 115\u7684\u9492\u6e17\u900f\u6027\u3002f)\u5728\u672c\u7814\u7a76\u548c\u6700\u8fd1\u7684\u6587\u732e\u4e2d\uff0c\u805a(\u82b3\u57fa\u54cc\u5576)\u548c\u5176\u4ed6\u57fa\u4e8e\u805a\u5408\u7269\u7684\u9492RFB\u819c\u7684\u9492\u6e17\u900f\u6027\u548c\u9762\u7535\u963b\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u5982\u56fe4a\u6240\u793a\uff0cPTP-Cx\u548cPTP-Tx\u819c\u5177\u670998.4%\u81f399.7%\u7684\u9ad8\u5e93\u4ed1\u6548\u7387(CE)\uff0c\u4e0e\u539f\u59cb\u7684PTP\u819c\u76f8\u5f53\uff0c\u5e76\u4e14\u663e\u8457\u9ad8\u4e8e\u5546\u4e1aNafion 115\u3002\u5982\u56fe4b\u6240\u793a\uff0cPTP-Cx\u548cPTP-Tx\u819c\u7684\u7535\u538b\u6548\u7387(VE)\u8d85\u8fc7\u4e86PTP\u819c\u3002\u5982\u56fe4c\u6240\u793a\uff0c\u4e0e\u539f\u59cb\u7684PTP\u819c\u548cNafion 115\u76f8\u6bd4\uff0cPTP-Cx\u548cPTP-Tx\u819c\u8868\u73b0\u51fa\u663e\u8457\u589e\u5f3a\u7684\u80fd\u91cf\u6548\u7387(EE)\u3002\u5982\u56fe4d\u6240\u793a\uff0c\u8fd9\u9879\u5de5\u4f5c\u4e2d\u5b9e\u73b0\u7684\u6027\u80fd\u8d85\u8fc7\u4e86\u6240\u6709\u5148\u524d\u62a5\u9053\u7684\u57fa\u4e8e\u805a(\u82b3\u57fa\u54cc\u5576)\u7684\u819c\uff0c\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea6\u64cd\u4f5c\u4e2d\u5448\u73b0\u51fa\u5b9e\u8d28\u6027\u7a81\u7834\u3002\u540c\u65f6\uff0c\u5176\u4ed6\u6709\u673a\u9178(\u5305\u62ecDA\u3001TCA\u548cHHA)\u7684\u6709\u6548\u6027\u4e5f\u5f97\u5230\u4e86\u7c7b\u4f3c\u7684\u8bc1\u5b9e(\u56fe4e\uff0cf)\u3002\u5982\u56fe4g\u6240\u793a\uff0c\u5728240 mA cm<sup>-2<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7528PTP-C2\u548cPTP-T2\u819c\u7ec4\u88c5\u7684\u7535\u6c60\u4fdd\u6301\u4e86\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u57281000\u6b21\u5145\u7535\/\u653e\u7535\u5faa\u73af\u540e\u90fd\u8868\u73b0\u51fa\u7a33\u5b9a\u7684\u6548\u7387\u3002\u5982\u56fe4h\u6240\u793a\uff0cPTP-C2\u548cPTP-T2\u819c\u7684\u964d\u89e3\u901f\u7387\u660e\u663e\u4f4e\u4e8e\u5148\u524d\u62a5\u9053\u7684\u57fa\u4e8e\u805a(\u82b3\u57fa\u54cc\u5576)\u7684\u819c\u3002\u603b\u7684\u6765\u8bf4\uff0c\u8fd9\u4e9b\u7ed3\u679c\u8bc1\u5b9e\u4e86\u7834\u574f\u805a(\u82b3\u57fa\u54cc\u5576)\u57fa\u819c\u4e2d\u7684\u94fe\u5806\u79ef\u6709\u5229\u4e8e\u5f00\u53d1\u5177\u6709\u8d85\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u7684\u975e\u6c1f\u5316\u819c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265209\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-24.png\" alt=\"\" width=\"980\" height=\"842\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-24.png 980w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-24-300x258.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-24-768x660.png 768w\" sizes=\"(max-width: 980px) 100vw, 980px\" \/><\/p>\n<p>\u56fe4 a-c)\u7531PTP\u3001PTP-C2\u3001PTP-T2\u548cNafion 115\u819c\u7ec4\u88c5\u7684\u9492RFB\u5728100-300 mA cm<sup>-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u8303\u56f4\u5185\u7684\u5e93\u4ed1\u6548\u7387(CE)\u3001\u7535\u538b\u6548\u7387(VE)\u548c\u80fd\u91cf\u6548\u7387(EE)\u3002d)\u5c06PTP-C2\/T2\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\u83b7\u5f97\u7684EEs\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u57fa\u4e8e\u805a(\u82b3\u57fa\u54cc\u5576)\u7684\u819c\u7684EEs\u8fdb\u884c\u6bd4\u8f83\u3002e\u3001f)\u5728100-300 mA cm<sup>-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u8303\u56f4\u5185\uff0cPTP\u3001PTP-DA\u3001PTP-TCA\u548cPTP-HHA\u819c\u7ec4\u88c5\u7684\u9492RFB\u7684CE\u548cEE\u3002g)\u5728240 mA cm<sup>-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7ec4\u88c5\u6709PTP-C2\u3001PTP-T2\u548cNafion 115\u819c\u7684\u9492RFB\u7684\u5faa\u73af\u6027\u80fd\u3002\u5f53\u5bb9\u91cf\u8870\u51cf\u5230\u5176\u521d\u59cb\u503c\u768470%\u65f6\uff0c\u7535\u89e3\u8d28\u88ab\u66f4\u6362\u3002h)\u672c\u7814\u7a76\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u57fa\u4e8e\u805a(\u82b3\u57fa\u54cc\u5576)\u7684\u9492RFB\u819c\u7684\u7279\u5b9a\u5faa\u73af\u7684\u5bb9\u91cf\u8870\u51cf\u7387\u6570\u636e\u5bf9\u6bd4\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u589e\u5f3a\u94fe\u5806\u79ef\u65e0\u5e8f\u6027\u7684\u65e0\u919a\u805a(\u82b3\u57fa\u54cc\u5576)\u819c\uff0c\u4ee5\u5b9e\u73b0\u9ad8\u6027\u80fd\u9492\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60(RFBs)\u3002\u5728\u819c\u5185\u5f15\u5165\u6709\u673a\u9178\u80fd\u591f\u6709\u6548\u5730\u7834\u574f\u5bc6\u96c6\u7684\u805a\u5408\u7269\u94fe\uff0c\u5c06\u8d28\u5b50\u4e0d\u53ef\u8fdb\u5165\u7684\u7ed3\u6676\u533a\u57df\u8f6c\u5316\u4e3a\u8d28\u5b50\u53ef\u8fdb\u5165\u7684\u65e0\u5b9a\u5f62\u533a\u57df\uff0c\u8fd9\u6709\u52a9\u4e8e\u5feb\u901f\u8d28\u5b50\u4f20\u8f93\u3002\u540c\u65f6\uff0c\u5176\u5b54\u8154\u6781\u9650\u76f4\u5f84\u7ea6\u4e3a8 \u00c5\uff0c\u4e3a\u9492\u79bb\u5b50\u4ea4\u53c9\u63d0\u4f9b\u4e86\u826f\u597d\u7684\u5c4f\u969c\u3002\u56e0\u6b64\uff0c\u8fd9\u4e9b\u9694\u819c\u5b9e\u73b0\u4e86\u4f4e\u9762\u7535\u963b\u548c\u8d85\u4f4e\u9492\u79bb\u5b50\u6e17\u900f\u7387\uff0c\u5e76\u4e14\u5728280 mA cm<sup>-2<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u80fd\u91cf\u6548\u7387\u7ea6\u4e3a80%\u3002\u540c\u65f6\uff0c\u65e0\u5316\u5b66\u4e0d\u7a33\u5b9a\u7684\u82b3\u57fa\u919a\u952e\u548c\u5316\u5b66\u6539\u6027\u4f7f\u819c\u5177\u6709\u8d85\u8fc71000\u6b21\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>Title: Supramolecular Interaction-Driven Amorphization of\u00a0Poly(aryl piperidine) Membranes for Enhanced Proton\u00a0Conductivity<\/p>\n<p>Authors\uff1aQianqian Cheng, Zutao Sheng, Mingjie Li, Wenjing Ye, Sangshan Peng,* Guang Zeng,*\u00a0and Qing He*<\/p>\n<p>To be cited as\uff1a<em><i>Adv. Energy Mater. <\/i><\/em><strong><em><b><i>2025<\/i><\/b><\/em><\/strong><em><i>,<\/i><\/em>\u00a02405436.<\/p>\n<p>DOI\uff1a10.1002\/aenm.202405436<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265210\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-17.png\" alt=\"\" width=\"176\" height=\"221\" \/><\/p>\n<p>\u5f6d\u6851\u73ca\uff0c\u6e56\u5357\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u526f\u6559\u6388\uff0c\u7814\u7a76\u751f\u5bfc\u5e08\u30022009\u81f32019\u5e74\uff0c\u5148\u540e\u5728\u5927\u8fde\u7406\u5de5\u5927\u5b66\u83b7\u5f97\u5b66\u58eb\u5b66\u4f4d\u548c\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u8d3a\u9ad8\u7ea2\u6559\u6388\uff1b2017\u5e749\u6708-2018\u5e749\u6708\u5728\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u8fdb\u884c\u535a\u58eb\u8054\u5408\u57f9\u517b\uff0c\u5e08\u4ece\u4f59\u6842\u534e\u6559\u6388\u30022019\u5e747\u6708\u52a0\u5165\u6e56\u5357\u5927\u5b66\uff0c\u73b0\u4e3a\u5316\u5b66\u5316\u5de5\u5b66\u9662\u526f\u6559\u6388\u3002\u957f\u671f\u4ece\u4e8b\u79bb\u5b50\u4f20\u5bfc\u819c\u7684\u8bbe\u8ba1\u7814\u53d1\uff0c\u5e76\u7528\u4e8e\u6db2\u6d41\u7535\u6c60\u7b49\u7535\u5316\u5b66\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u6362\u5668\u4ef6\uff0c\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\u7b49\u8bfe\u9898\u3002\u57fa\u4e8e\u6db2\u6d41\u7535\u6c60\u79bb\u5b50\u4f20\u5bfc\u819c\u7684\u7814\u7a76\uff0c\u4ee5\u7b2c\u4e00\u6216\u901a\u8baf\u4f5c\u8005\u5728<em>Chem\u3001Chemical Society Review\u3001Angewandte Chemie International Edition\u3001Advanced Energy Materials (3)\u3001Energy Storage Materials (2)\u3001Journal of Membrane Science (2)\u3001Journal of Materials Chemistry A<\/em>\u7b49\u6743\u5a01\u671f\u520a\u53d1\u8868\u8bba\u6587\u5341\u4f59\u7bc7\uff0c\u4ee5\u7b2c\u4e00\u53d1\u660e\u4eba\u7533\u8bf7\/\u6388\u6743\u4e13\u52294\u9879\uff0c\u76ee\u524d\u62c5\u4efb\u300a\u7535\u5316\u5b66(\u4e2d\u82f1\u6587)\u300b\uff08Journal of Electrochemistry\uff09\u9752\u5e74\u7f16\u59d4\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265211\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-5.png\" alt=\"\" width=\"267\" height=\"366\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-5.png 267w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-5-219x300.png 219w\" sizes=\"(max-width: 267px) 100vw, 267px\" \/><\/p>\n<p>\u66fe\u5149\uff0c\u7537\uff0c1986\u5e74\u51fa\u751f\uff0c\u4e2d\u5171\u515a\u5458\uff0c\u535a\u58eb\uff0c\u526f\u6559\u6388\uff0c\u7855\u58eb\u751f\u5bfc\u5e08\uff0c\u957f\u6c99\u7406\u5de5\u5927\u5b66\u201c\u6e56\u6e58\u5b66\u8005\u201d\u30022013\u5e746\u6708\u6bd5\u4e1a\u4e8e\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u5b66\uff0c\u83b7\u7269\u7406\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\u30022015\u5e746\u6708\u81f32020\u5e742\u6708\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5e76\u7559\u6240\u5de5\u4f5c\u30022020\u5e743\u6708\u52a0\u5165\u957f\u6c99\u7406\u5de5\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\uff1a\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u6750\u6599\u3001\u78b3\u6750\u6599\u3001\u91d1\u5c5e\u53ca\u5176\u5316\u5408\u7269\u7b49\u591a\u5b54\u6750\u6599\u548c\u4f4e\u7ef4\u7eb3\u7c73\u6750\u6599\u5728\u7535\u5316\u5b66\u50a8\u80fd\uff08\u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\u7b49\uff09\u548c\u7535\u5316\u5b66\u50ac\u5316\uff08\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u7b49\uff09\u7b49\u80fd\u6e90\u9886\u57df\u7684\u5e94\u7528\u7814\u7a76\u3002\u76ee\u524d\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9752\u5e74\u9879\u76ee\uff0821905278\uff09\u4e00\u9879\uff0c\u6e56\u5357\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\uff082023JJ30015\uff09\u4e00\u9879\uff0c\u798f\u5efa\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9752\u5e74\u9879\u76ee\uff082019J05158\uff09\u4e00\u9879\u3002\u53c2\u4e0e\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u548c\u798f\u5efa\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u591a\u9879\u3002\u5df2\u5728<em>Advanced Functional Materials<\/em><em>\u3001<\/em><em>Nano Energy<\/em><em>\u3001<\/em><em>Nano Research<\/em><em>\u3001<\/em><em>Nanoscale<\/em>\u7b49\u56fd\u9645\u6743\u5a01\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587\u8fd120\u7bc7\uff0c\u8bba\u6587\u4ed6\u5f151400\u4f59\u6b21\uff0ch-index\u6307\u657014\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265212\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72478-3.png\" alt=\"\" width=\"233\" height=\"303\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72478-3.png 233w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72478-3-231x300.png 231w\" sizes=\"(max-width: 233px) 100vw, 233px\" \/><\/p>\n<p>\u4f55\u6e05\uff0c\u6e56\u5357\u5927\u5b66\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u3001\u56fd\u5bb6\u6d77\u5916\u9ad8\u5c42\u6b21\u9752\u5e74\u4eba\u624d\u3001\u6e56\u6e58\u9ad8\u5c42\u6b21\u4eba\u624d\u805a\u96c6\u5de5\u7a0b\u2013\u521b\u65b0\u4eba\u624d\u30022010\u5e747\u6708\u4e8e\u6e56\u5357\u5e08\u8303\u5927\u5b66\u5236\u836f\u5de5\u7a0b\u7cfb\u83b7\u5b66\u58eb\u5b66\u4f4d\uff1b2015\u5e747\u6708\u4e8e\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u83b7\u5f97\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\uff1b2015\u5e747\u6708\u20132019\u5e743\u6708\u5728\uff08\u7f8e\u56fd\uff09\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u5316\u5b66\u7cfb\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff08\u5408\u4f5c\u5bfc\u5e08\u4e3aJonathan L. Sessler\u6559\u6388\uff09\uff1b2019\u5e74\u5165\u9009\u56fd\u5bb6\u6d77\u5916\u9ad8\u5c42\u6b21\u4eba\u624d\u9752\u5e74\u9879\u76ee\u56de\u56fd\u5de5\u4f5c\uff0c\u4efb\u6e56\u5357\u5927\u5b66\u5316\u5b66\u7cfb\u6559\u6388\u3002\u4e3b\u6301\/\u627f\u62c5\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\u3001\u9752\u5e74\u9879\u76ee\u53ca\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u5b50\u8bfe\u9898\u7b49\u591a\u9879\u8bfe\u9898\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u8d85\u5206\u5b50\u5316\u5b66\u548c\u65b0\u578b\u529f\u80fd\u6750\u6599\uff0c\u5305\u62ec\u5206\u5b50\u7b3c\u5316\u5b66\uff08\u8d85\u8543\u5316\u5b66\u4e0e\u5854\u7b3c\u5316\u5b66\uff09\u3001\u65b0\u578b\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u529b\u3001\u5148\u8fdb\u8d85\u5206\u5b50\u6750\u6599\uff08\u975e\u591a\u5b54\u975e\u6676\u6001\u8d85\u5438\u9644\u6750\u6599\u3001\u8d85\u5206\u5b50\u79bb\u5b50\u4f20\u5bfc\u819c\uff09\u548c\u8d85\u5206\u5b50\u5206\u79bb\u6280\u672f\u3002\u5728<em>S<\/em><em>ci. Adv.<\/em>\u3001<em><i>Nat<\/i><\/em><em><i>.<\/i><\/em><em><i>\u00a0Commun<\/i><\/em><em><i>.<\/i><\/em>\u3001<em><i>Chem<\/i><\/em>\u3001<em><i>J. Am. Chem. Soc.<\/i><\/em>\u3001<em><i>Angew. Chem. Int. Ed.<\/i><\/em>\u3001<em><i>Adv<\/i><\/em><em><i>.<\/i><\/em><em><i>\u00a0Energy Mater.<\/i><\/em>\u3001<em><i>Chem. Rev.<\/i><\/em>\u3001<em><i>Chem. Soc. Rev.<\/i><\/em>\u3001<em><i>Acc. Chem. Res.<\/i><\/em>\u3001<em><i>Coordin. Chem. Rev.\u3001CCS Chem.<\/i><\/em>\u7b49\u671f\u520a\u4e0a\u53d1\u8868\u5b66\u672f\u8bba\u658760\u4f59\u7bc7\uff0c\u7533\u8bf7\/\u6388\u6743\u4e13\u52298\u9879\u3002\u76ee\u524d\u62c5\u4efb\u300a\u56db\u9762\u4f53\u300b\uff08Tetrahedron\uff09\u548c\u300a\u56db\u9762\u4f53\u5feb\u62a5\u300b\uff08Tetrahedron Letters\uff09\u9752\u5e74\u7f16\u59d4\u3001\u300aTetrahedron Chem\u300b\u5ba2\u5ea7\u7f16\u8f91\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 &nbsp; &nbsp; \u975e\u6c1f\u5316\u805a\u5408\u7269\u819c\u4e3a\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60(RFB)\u63d0\u4f9b\u4e86\u5546\u4e1a\u4e0a\u53ef\u884c\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u4f46\u5176\u5b9e\u9645\u5e94\u7528\u53d7\u5230\u56fa\u6709\u6311\u6218\u7684\u963b\u788d\uff0c\u5982\u5316\u5b66\u4e0d\u7a33\u5b9a\u6027\u548c&#8230;<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-265204","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265204"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=265204"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265204\/revisions"}],"predecessor-version":[{"id":265213,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265204\/revisions\/265213"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=265204"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=265204"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=265204"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}