{"id":265178,"date":"2025-02-25T07:50:37","date_gmt":"2025-02-24T23:50:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=265178"},"modified":"2025-02-24T21:57:13","modified_gmt":"2025-02-24T13:57:13","slug":"%e8%a5%bf%e5%ae%89%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6%e6%9d%8e%e5%96%9c%e9%a3%9e%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9fafm%ef%bc%9aca-n%e5%85%b1%e6%8e%ba%e6%9d%82%e7%ad%96%e7%95%a5%e8%b0%83%e6%8e%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=265178","title":{"rendered":"\u897f\u5b89\u7406\u5de5\u5927\u5b66\u674e\u559c\u98de\u6559\u6388\u56e2\u961fAFM\uff1aCa\/N\u5171\u63ba\u6742\u7b56\u7565\u8c03\u63a7\u5c42\u72b6MnO2\u7684d\/p\u5e26\u4e2d\u5fc3\u63a5\u8fd1\u5ea6\u589e\u5f3a\u53cc\u79bb\u5b50\u5b58\u50a8"},"content":{"rendered":"<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265179\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-28.png\" alt=\"\" width=\"703\" height=\"330\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-28.png 703w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-28-300x141.png 300w\" sizes=\"(max-width: 703px) 100vw, 703px\" \/><\/strong><\/p>\n<p><strong><b>1\u3001<\/b><\/strong><strong>\u7814\u7a76<\/strong><strong>\u80cc\u666f<\/strong><\/p>\n<p>\u76ee\u524d\uff0c\u7531\u4e8e\u950c\u91d1\u5c5e\u7684\u6210\u672c\u6548\u76ca\u3001\u5176\u9ad8\u7406\u8bba\u5bb9\u91cf\u3001\u4f4e\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u4ee5\u53ca\u7531\u4e8e\u4f7f\u7528\u542b\u6c34\u7535\u89e3\u8d28\u800c\u589e\u5f3a\u7684\u5b89\u5168\u6027\uff0c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60(AZIBs)\u6b63\u53d7\u5230\u6781\u5927\u7684\u5173\u6ce8\u3002\u6b63\u6781\u6750\u6599\u4f5c\u4e3a\u8fd9\u4e9b\u7535\u6c60\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u5bf9\u5b9e\u73b0AZIBs\u7535\u6c60\u7684\u9ad8\u6027\u80fd\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5df2\u7ecf\u62a5\u9053\u4e86\u5404\u79cd\u5177\u6709\u72ec\u7279\u4f18\u52bf\u548c\u6311\u6218\u7684\u6b63\u6781\u6750\u6599\u3002\u5176\u4e2d\uff0c\ud835\udeff-MnO<sub>2<\/sub>\u4ee5\u5176\u72ec\u7279\u7684\u4e8c\u7ef4\u5c42\u72b6\u7ed3\u6784\u4e3a\u7279\u5f81\uff0c\u662f\u4e00\u79cd\u975e\u5e38\u6709\u524d\u9014\u7684AZIBs\u5019\u9009\u6750\u6599\u3002\u7136\u800c\uff0c\ud835\udeff-MnO<sub>2<\/sub>\u7684\u5bbd\u5e26\u9699\u548c\u6d3b\u6027\u6c27\u539f\u5b50p\u5e26\u4e2d\u5fc3(\u03b5<sub>p<\/sub>)\u7684\u53d7\u9650\u8c03\u8282\u663e\u8457\u5f71\u54cd\u950c\u50a8\u5b58\u8fc7\u7a0b\u4e2d\u7684\u7535\u5b50\u4f20\u5bfc\u548c\u79bb\u5b50\u6269\u6563\u3002\u6742\u539f\u5b50\u63ba\u6742\u662f\u63d0\u9ad8\u950c\u5b58\u50a8\u6027\u80fd\u7684\u6709\u6548\u7b56\u7565\u3002O\u4f4d\u4f5c\u4e3a\u5b9e\u9645\u7684\u6d3b\u6027\u4e2d\u5fc3\uff0c\u91d1\u5c5e\u79bb\u5b50\u5728\ud835\udeff-MnO<sub>2<\/sub>\u4e2d\u7684\u63ba\u6742\u901a\u8fc7\u5f62\u6210Mn-O-M\u952e(M\u4ee3\u8868\u91d1\u5c5e\u79bb\u5b50)\u5bf9O\u7684\u03b5<sub>p<\/sub>\u8fdb\u884c\u8c03\u8282\u3002\u7136\u800c\uff0c\u8fd9\u79cd\u8c03\u8282\u4f5c\u7528\u8868\u73b0\u51fa\u5c40\u9650\u6027\u3002\u9274\u4e8eMn-O\u952e\u7684\u5171\u4ef7\u6027\u8d28\uff0c\u5efa\u7acbMn-N\u952e(\u5176\u4e2dN\u8868\u793a\u975e\u91d1\u5c5e\u79bb\u5b50)\u4ee5\u7cbe\u786e\u8c03\u8282Mn\u539f\u5b50\u7684d\u5e26\u4e2d\u5fc3(\u03b5<sub>d<\/sub>)\uff0c\u4ece\u800c\u8c03\u8282O\u7684\u03b5<sub>p<\/sub>\u3002<\/p>\n<p><strong><b>2\u3001\u7814\u7a76\u5185\u5bb9<\/b><\/strong><\/p>\n<p>\u57fa\u4e8e\u6b64\uff0c<strong>\u897f\u5b89\u7406\u5de5\u5927\u5b66\u674e\u559c\u98de\u6559\u6388\u56e2\u961f<\/strong>\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aAdvanced Functional Materials\u4e0a\u53d1\u8868\u9898\u4e3a\u201cEfficient Modulation d\/p-Band Center Proximity in Birnessite-Type MnO<sub>2<\/sub>\u00a0by Cation\/Anion Co-Doping for Enhanced Dual-Ion Storage\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u9633\u79bb\u5b50\/\u9634\u79bb\u5b50\u5171\u63ba\u6742\u7b56\u7565\uff0c\u901a\u8fc7\u5728Ca\/N\u5171\u63ba\u6742\u03b4-MnO<sub>2<\/sub>\u00a0(Ca\/N-MnO<sub>2<\/sub>)\u4e2d\u5efa\u7acbMn\u2013O\u2013Ca\u548cMn\u2500N\u952e\u6765\u540c\u65f6\u8c03\u8282O\u7684p\u5e26\u4e2d\u5fc3(\u03b5<sub>p<\/sub>)\u548cMn\u7684d\u5e26\u4e2d\u5fc3(\u03b5<sub>d<\/sub>)\u3002\u8fd9\u79cd\u5171\u63ba\u6742\u6548\u5e94\u5bfc\u81f4[MnO<sub>6<\/sub>]\u516b\u9762\u4f53\u4e2dMn\u2500O\u952e\u7684\u4e3b\u8981\u62c9\u4f38\u632f\u52a8\u6a21\u5f0f\u53d1\u751f\u8f6c\u53d8\uff0c\u5bfc\u81f4d\/p\u5e26\u4e2d\u5fc3\u63a5\u8fd1\u5ea6(\u0394\u03b5<sub>d-p<\/sub>)\u964d\u4f4e\u4e3a1.688 ev (\u03b4-MnO<sub>2<\/sub>\u4e3a1.750 eV)\u3002\u56e0\u6b64\uff0cZn<sup>2+<\/sup>\/H<sup>+<\/sup>\u79bb\u5b50\u7684\u5438\u9644\u5bb9\u91cf\u548c\u5438\u9644\/\u89e3\u5438\u901f\u7387\u90fd\u63d0\u9ad8\u4e86\u3002\u7406\u8bba\u8ba1\u7b97\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86\u5171\u63ba\u6742\u663e\u8457\u5730\u89e6\u53d1\u4e86\u5e26\u9699\u3001\u8fc1\u79fb\u80fd\u5792\u548c\u5438\u9644\u80fd\u7684\u4f18\u5316\u3002\u56e0\u6b64\uff0cCa\/N-MnO<sub>2<\/sub>\u57281.0 A g<sup>-1<\/sup>\u4e0b\u7ecf\u8fc7200\u6b21\u5faa\u73af\u540e\u83b7\u5f97\u4e86192.7 mAh g<sup>-1<\/sup>\u7684\u4f18\u5f02\u53ef\u9006\u5bb9\u91cf\u548c\u51fa\u8272\u7684\u500d\u7387\u6027\u80fd\u3002\u6b64\u5916\uff0c\u50a8\u950c\u673a\u5236\u4e5f\u88ab\u5168\u9762\u9610\u660e\u3002\u8fd9\u79cd\u534f\u540cd\/p\u5e26\u4e2d\u5fc3\u8c03\u8282\u7b56\u7565\u4e3a\u9ad8\u6548\u50a8\u80fd\u5e94\u7528\u63d0\u4f9b\u4e86\u5de8\u5927\u6f5c\u529b\u3002<\/p>\n<p><strong><b>3<\/b><\/strong><strong><b>\u3001\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265180\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-29.png\" alt=\"\" width=\"1040\" height=\"1156\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-29.png 1040w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-29-270x300.png 270w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-29-768x854.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-29-921x1024.png 921w\" sizes=\"(max-width: 1040px) 100vw, 1040px\" \/><\/strong><\/p>\n<p>\u56fe1. a,e) \ud835\udeff-MnO<sub>2<\/sub>,\u00a0b,f)\u00a0Ca-MnO<sub>2<\/sub>,\u00a0c,g) N-MnO<sub>2<\/sub>\u548cd,h) Ca\/N-MnO<sub>2<\/sub>\u7684TEM\u548cHRTEM\u56fe;\u00a0i) XRD\u56fe;\u00a0j)\u62c9\u66fc\u5149\u8c31;\u00a0k)\u00a0Ca\/N-MnO<sub>2<\/sub>\u7684\u539f\u5b50HAADF-STEM\u56fe\u50cf\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265181\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-27.png\" alt=\"\" width=\"1038\" height=\"842\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-27.png 1038w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-27-300x243.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-27-768x623.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-27-1024x831.png 1024w\" sizes=\"(max-width: 1038px) 100vw, 1038px\" \/><\/strong><\/p>\n<p>\u56fe2.\u00a0a) \ud835\udeff-MnO<sub>2<\/sub>\uff0cCa-MnO<sub>2<\/sub>\uff0cN-MnO<sub>2<\/sub>\u548cCa\/N-MnO<sub>2<\/sub>\u4e2dMn 3s\u7684\u9ad8\u5206\u8fa8\u7387XPS\u5149\u8c31;\u00a0b\uff09Ca\/N-MnO<sub>2<\/sub>\u548c\u6807\u51c6CaO\u7684Ca K-Edge XANES\u66f2\u7ebf;\u00a0c,d) \ud835\udeff-MnO<sub>2<\/sub>\u548cCa\/N-MnO<sub>2<\/sub>\u7684Mn K\u8fb9XANES\u66f2\u7ebf;\u00a0e)\u00a0\u5728R\u7a7a\u95f4\u5904\u7684FT-EXAFS\u5149\u8c31;\u00a0f) \ud835\udeff-MnO<sub>2<\/sub>\u548cCa\/N-MnO<sub>2<\/sub>\u7684\u5c0f\u6ce2\u53d8\u6362\u56fe;\u00a0g)\u00a0\u5171\u63ba\u6742\u65f6[MnO<sub>6<\/sub>]\u516b\u9762\u4f53\u5185\u7535\u5b50\u5bc6\u5ea6\u548c\u952e\u957f\u7684\u6539\u53d8\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265182\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-27.png\" alt=\"\" width=\"1041\" height=\"858\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-27.png 1041w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-27-300x247.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-27-768x633.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-27-1024x844.png 1024w\" sizes=\"(max-width: 1041px) 100vw, 1041px\" \/><\/strong><\/p>\n<p>\u56fe3. a)\u00a0\u57280.1 mV s<sup>-1<\/sup>\u4e0b\u56db\u4e2a\u6b63\u6781\u6750\u6599\u7684CV\u66f2\u7ebf;\u00a0b),\u00a0Ca\/N-MnO<sub>2<\/sub>\u521d\u59cb5\u4e2a\u5faa\u73af\u7684CV\u66f2\u7ebf\uff1a\u00a0c)\u00a00.3 A g<sup>-1<\/sup>\u4e0b\u7684GCD\u66f2\u7ebf;\u00a0d)\u00a0\u500d\u7387\u6027\u80fd;\u00a0e) \ud835\udeff-MnO<sub>2<\/sub>\u548cCa\/N-MnO<sub>2<\/sub>\u7684GCD\u66f2\u7ebf;\u00a0f)\u00a0Ca\/N-MnO<sub>2<\/sub>\u7684\u500d\u7387\u6027\u80fd\u4e0e\u5df2\u62a5\u9053\u7684AZIBs\u7684\u6b63\u6781\u6750\u6599\u7684\u6bd4\u8f83;\u00a0g)\u00a01.0 A g<sup>-1<\/sup>\u548ch)\u00a03.0 A g<sup>-1<\/sup>\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265183\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-23.png\" alt=\"\" width=\"1116\" height=\"839\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-23.png 1116w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-23-300x226.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-23-768x577.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-23-1024x770.png 1024w\" sizes=\"(max-width: 1116px) 100vw, 1116px\" \/><\/strong><\/p>\n<p>\u56fe4. a) \ud835\udeff-MnO<sub>2<\/sub>\u548cd)\u00a0Ca\/N-MnO<sub>2<\/sub>\u6b63\u6781\u7684EQCM\u9891\u7387\u54cd\u5e94;\u00a0b) \ud835\udeff-MnO<sub>2<\/sub>\u548ce)\u00a0Ca\/N-MnO<sub>2<\/sub>\u6b63\u6781\u7684CV\u66f2\u7ebf\u548c\u5bf9\u5e94\u7684\u8d28\u91cf\u53d8\u5316\u54cd\u5e94;\u00a0c) \ud835\udeff-MnO<sub>2<\/sub>\u548cf)\u00a0Ca\/N-MnO<sub>2<\/sub>\u7684\u8d28\u91cf\u53d8\u5316\u66f2\u7ebf;\u00a0\u56db\u4e2a\u6837\u54c1\u4e2dg)\u00a0O\u7684p\u5e26\u4e2d\u5fc3\u503c,\u00a0h)\u00a0Mn\u7684d\u5e26\u4e2d\u5fc3\u503c\u548ci)\u00a0d\u2013p\u5e26\u4e2d\u5fc3\u5dee\u503c\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265184\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-16.png\" alt=\"\" width=\"1089\" height=\"651\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-16.png 1089w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-16-300x179.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-16-768x459.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-16-1024x612.png 1024w\" sizes=\"(max-width: 1089px) 100vw, 1089px\" \/><\/strong><\/p>\n<p>\u56fe5. a) \ud835\udeff-MnO<sub>2<\/sub>\u548cb)\u00a0Ca\/N-MnO<sub>2<\/sub>\u7684\u4f18\u5316Zn<sup>2+<\/sup>\u548cH<sup>+<\/sup>\u79bb\u5b50\u5438\u9644\u6a21\u578b\u4ee5\u53ca\u76f8\u5e94\u7684\u5438\u9644\u80fd;\u00a0c) \ud835\udeff-MnO<sub>2<\/sub>\uff0cCa-MnO<sub>2<\/sub>\uff0cN-MnO<sub>2<\/sub>\u548cCa\/N-MnO<sub>2<\/sub>\u7684DOS\u3002<\/p>\n<p><b><\/b><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265185\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-4.png\" alt=\"\" width=\"1038\" height=\"864\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-4.png 1038w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-4-300x250.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-4-768x639.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-4-1024x852.png 1024w\" sizes=\"(max-width: 1038px) 100vw, 1038px\" \/><\/b><\/strong><\/p>\n<p>\u56fe6. a) \ud835\udeff-MnO<sub>2<\/sub>\u548cb) Ca\/N-MnO<sub>2<\/sub>\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf;\u00a0c) \ud835\udeff-MnO<sub>2<\/sub>\u548cd) Ca\/N-MnO<sub>2<\/sub>\u7684i<sub>p<\/sub>\u5bf9v<sup>1\/2<\/sup>\u56fe\u7684\u7ebf\u6027\u62df\u5408\u7ed3\u679c;\u00a0e) \ud835\udeff-MnO<sub>2<\/sub>\u548cCa\/N-MnO<sub>2<\/sub>\u7684\u8fc1\u79fb\u8def\u5f84\u548cZn<sup>2+<\/sup>\u6269\u6563\u80fd\u5792;\u00a0f, g)\u5948\u594e\u65af\u7279\u56fe; h)\u5faa\u73af\u524d\u540e\u56db\u4e2a\u6b63\u6781\u7684Rct\u503c\u6bd4\u8f83\u3002<\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265186\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72478-2.png\" alt=\"\" width=\"1038\" height=\"878\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72478-2.png 1038w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72478-2-300x254.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72478-2-768x650.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72478-2-1024x866.png 1024w\" sizes=\"(max-width: 1038px) 100vw, 1038px\" \/><\/b><\/strong><\/p>\n<p>\u56fe7. a) \u6052\u7535\u6d41\u7535\u538b\u66f2\u7ebf\u548c\u76f8\u5e94\u7684\u975e\u539f\u4f4dXRD\u66f2\u7ebf;\u00a0\u539f\u59cb\u548c\u5b8c\u5168\u653e\u7535\/\u5145\u7535\u72b6\u6001\u4e0bb) Zn 2p\u548cc) Mn 2p\u7684\u975e\u539f\u4f4d\u9ad8\u5206\u8fa8\u7387XPS\u5149\u8c31;\u00a0d)\u4e0d\u540c\u5145\u7535\/\u653e\u7535\u72b6\u6001\u4e0bCa\/N-MnO<sub>2<\/sub>\u7535\u6781\u7684\u975e\u539f\u4f4dXANES\u548ce) EXAFS\u5149\u8c31;\u00a0f)ICP\u5206\u6790;\u00a0g)\u5728\u7b2c\u4e8c\u5faa\u73af\u671f\u95f4Ca\/N-MnO<sub>2<\/sub>\u6b63\u6781\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u548ch) \u76f8\u5e94\u7684\u5c40\u90e8\u653e\u5927\u5149\u8c31;\u00a0i)\u5904\u4e8e\u5b8c\u5168\u653e\u7535\u72b6\u6001\u7684Ca\/N-MnO<sub>2<\/sub>\u7684STEM-EDS\u56fe\u3002<\/p>\n<p><strong><b>4\u3001\u7ed3\u8bba<\/b><\/strong><\/p>\n<p>\u603b\u4e4b\uff0c\u9633\u79bb\u5b50\u548c\u9634\u79bb\u5b50\u5171\u63ba\u6742\u7684Ca\/N-MnO<sub>2<\/sub>\u6b63\u6781\u91c7\u7528\u6c34\u70ed\u6cd5\u5408\u6210\uff0c\u968f\u540e\u8fdb\u884c\u9000\u706b\u5904\u7406\u3002Ca\u548cN\u7684\u5171\u63ba\u6742\u8bf1\u5bfc\ud835\udeff-MnO<sub>2<\/sub>\u6676\u4f53\u7ed3\u6784\u4ece\u5355\u659c\u5411\u516d\u65b9\u5c42\u5bf9\u79f0\u8f6c\u53d8\uff0c\u8fd9\u8c03\u8282\u4e86d-p\u5e26\u4e2d\u5fc3\u7684\u63a5\u8fd1\u5ea6\u5e76\u4f18\u5316\u4e86Zn<sup>2+<\/sup>\/H<sup>+<\/sup>\u79bb\u5b50\u7684\u5438\u9644\u548c\u89e3\u5438\u884c\u4e3a\u3002\u8fd9\u79cd\u7ed3\u6784\u4fee\u9970\u589e\u5f3a\u4e86\u5438\u9644\u5bb9\u91cf\uff0c\u5bfc\u81f4\u53ef\u9006\u5bb9\u91cf\u663e\u8457\u589e\u52a0\u3002\u6b64\u5916\uff0c\u5171\u63ba\u6742\u884c\u4e3a\u4ea7\u751f\u4e30\u5bcc\u7684\u7a7a\u4f4d\uff0c\u6709\u6548\u5730\u964d\u4f4e\u4e86\u5e26\u9699\u548c\u6269\u6563\u52bf\u5792\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86Ca\/N-MnO<sub>2<\/sub>\u6b63\u6781\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u56e0\u6b64\uff0cCa\/N-MnO<sub>2<\/sub>\u8868\u73b0\u51fa\u663e\u8457\u589e\u5f3a\u7684\u5bb9\u91cf\u548c\u4f18\u5f02\u7684\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u901a\u8fc7\u7cfb\u7edf\u7684\u539f\u4f4d\u548c\u975e\u539f\u4f4d\u5206\u6790\uff0c\u6df1\u5165\u7814\u7a76\u4e86Ca\/N-MnO<sub>2<\/sub>\u7684\u50a8\u80fd\u673a\u7406\u3002\u8be5\u7814\u7a76\u4e3a\ud835\udeff-MnO<sub>2<\/sub>\u6b63\u6781\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u89c6\u89d2\uff0c\u5e76\u9610\u660e\u4e86\u5176\u50a8\u80fd\u673a\u5236\uff0c\u6709\u52a9\u4e8eAZIBs\u7684\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u6587\u732e<\/b><\/strong><strong><b>\u4fe1\u606f\uff1a<\/b><\/strong><\/p>\n<p>Yuhui Xu, Gaini Zhang*, Xiaoxue Wang, Jianhua Zhang, Haocheng Wen, Dongniu Wang*, Yitong Yuan, Qinting Jiang, Huaming Qian, Yukun Xi, Jiaxuan Zuo, Ming Li, Jihu Liu, Huijuan Yang, Yangyang Luo, Jingjing Wang, Wenbin Li, Xifei Li*, Efficient Modulation d\/p-Band Center Proximity in Birnessite-Type MnO<sub>2<\/sub>\u00a0by Cation\/Anion Co-Doping for Enhanced Dual-Ion Storage, Advanced Functional Materials, 2025, DOI: 10.1002\/adfm.202500137.<\/p>\n<p>https:\/\/doi.org\/10.1002\/adfm.202500137<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/b><\/strong><\/p>\n<p><strong><b>\u674e\u559c\u98de<\/b><\/strong>\uff0c\u897f\u5b89\u7406\u5de5\u5927\u5b66\u6559\u6388\uff0c\u535a\u5bfc\uff0c\u5165\u9009\u56fd\u5bb6\u7ea7\u4eba\u624d\uff0c\u4eab\u53d7\u56fd\u52a1\u9662\u653f\u5e9c\u7279\u6b8a\u6d25\u8d34\uff0c\u79d1\u777f\u552f\u5b89\u201c\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u201d\uff082018-2023\uff09\u3001\u7231\u601d\u552f\u5c14\u4e2d\u56fd\u9ad8\u88ab\u5f15\u5b66\u8005\u548c\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u58eb\u7b49\uff0c\u88ab\u6388\u4e88\u56fd\u5bb6\u6709\u7a81\u51fa\u8d21\u732e\u4e2d\u9752\u5e74\u4e13\u5bb6\u3001\u5168\u56fd\u77f3\u6cb9\u548c\u5316\u5de5\u4f18\u79c0\u79d1\u6280\u5de5\u4f5c\u8005\u7b49\uff0c\u83b7\u9655\u897f\u7701\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\u3001\u4e2d\u56fd\u77f3\u5316\u8054\u5408\u4f1a\u79d1\u5b66\u6280\u672f\u4e8c\u7b49\u5956\u7b49\u3002\u62c5\u4efb\u56fd\u9645\u7535\u5316\u5b66\u80fd\u6e90\u79d1\u5b66\u9662\u526f\u4e3b\u5e2d\uff08IAOEES\uff09\u3001\u4e2d\u56fd\u5185\u71c3\u673a\u5b66\u4f1a\u71c3\u6599\u7535\u6c60\u53d1\u52a8\u673a\u5206\u4f1a\u526f\u4e3b\u4efb\u3001\u4e2d\u56fd\u77f3\u6cb9\u4e0e\u5316\u5de5\u8054\u5408\u4f1a\u5316\u5de5\u65b0\u6750\u6599\u4e13\u59d4\u4f1a\u526f\u4e3b\u4efb\u3001Electrochemical Energy Reviews\uff08IF\uff1a28.4\uff09\u6267\u884c\u4e3b\u7f16\u548c\u4e2d\u56fd\u5316\u5b66\u4f1a\u7535\u5316\u5b66\u59d4\u5458\u4f1a\u59d4\u5458\u7b49\u3002\u5df2\u5728Sci. Adv.\u3001Nat. Commun.\u3001Angew.\u3001Adv. Mater.\u3001Joule\u3001Energy Environ. Sci.\u7b49\u56fd\u9645\u671f\u520a\u53d1\u8868450\u4f59\u7bc7\u5b66\u672f\u8bba\u6587\uff08\u5305\u62ecESI\u9ad8\u88ab\u5f15\u8bba\u658770\u4f59\u7bc7\uff09\uff0c\u5f15\u7528\u6b21\u657030000\u6b21\uff0cH\u56e0\u5b5093\u3002\u4e3b\u6301\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u5b50\u8bfe\u9898\u3001\u56fd\u5bb6\u81ea\u7136\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\u7b4930\u4f59\u9879\u79d1\u7814\u9879\u76ee\uff0c\u88ab\u8058\u4e3a\u897f\u5b89\u745f\u798f\u80fd\u6e90\u79d1\u6280\u6709\u9650\u516c\u53f8\u9996\u5e2d\u6280\u672f\u987e\u95ee\u3001\u683c\u6797\u7f8e\uff08\u6df1\u5733\uff09\u8d85\u7ea7\u7eff\u8272\u6280\u672f\u7814\u7a76\u9662\u9996\u5e2d\u79d1\u5b66\u5bb6\u7b49\u3002\u6210\u679c\u66fe\u88ab\u9655\u897f\u7535\u89c6\u53f0\u3001\u5929\u6d25\u536b\u89c6\u3001\u9655\u897f\u65e5\u62a5\u7b49\u5a92\u4f53\u591a\u6b21\u62a5\u9053\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u00a0 1\u3001\u7814\u7a76\u80cc\u666f \u76ee\u524d\uff0c\u7531\u4e8e\u950c\u91d1\u5c5e\u7684\u6210\u672c\u6548\u76ca\u3001\u5176\u9ad8\u7406\u8bba\u5bb9\u91cf\u3001\u4f4e\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u4ee5\u53ca\u7531\u4e8e\u4f7f\u7528\u542b\u6c34\u7535\u89e3\u8d28\u800c\u589e\u5f3a\u7684\u5b89\u5168\u6027\uff0c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60(AZIBs)\u6b63\u53d7\u5230\u6781\u5927\u7684\u5173\u6ce8\u3002\u6b63&#8230;<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-265178","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265178"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=265178"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265178\/revisions"}],"predecessor-version":[{"id":265187,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/265178\/revisions\/265187"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=265178"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=265178"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=265178"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}