![\"\"](\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471.jpg\")
<\/p>\n
\u56fe1 | \u591a\u7ef4PbI\u2082@MOF\u8d85\u6676\u683c\u7684\u7ed3\u6784\u8868\u5f81\uff1a\u00a9 2024 Nature<\/p>\n
a, c, e, g: MOF\u548cPbI\u2082@MOF\u8d85\u6676\u683c\u7684\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\uff08PXRD\uff09\u56fe\u8c31\u548c\u7167\u7247\uff1aNU-1000\u548c0D PbI\u2082@NU-1000\uff08a\uff09\uff0cPCN-700\u548c1D PbI\u2082@PCN-700\uff08c\uff09\uff0cPCN-609\u548c\u534a\u586b\u51452D PbI\u2082@PCN-609\uff08e\uff09\u4ee5\u53caPCN-606\u548c\u5168\u586b\u51452D PbI\u2082@PCN-606\uff08g\uff09\u3002\u6807\u5c3a\u4e3a0.2 mm\u3002b, d, f, h: 0D PbI\u2082@NU-1000\uff08b\uff09\uff0c1D PbI\u2082@PCN-700\uff08d\uff09\uff0c\u534a\u586b\u51452D PbI\u2082@PCN-609\uff08f\uff09\u548c\u5168\u586b\u51452D PbI\u2082@PCN-606\uff08h\uff09\u7684\u5355\u6676\u7ed3\u6784\u3002\u653e\u5927\u533a\u57df\u7684PbI\u2082\u5355\u5143\u7684\u8be6\u7ec6\u7ed3\u6784\u7528\u865a\u7ebf<\/p>\n
![\"\"](\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476.jpg\")
<\/p>\n
\u56fe2 | \u76d1\u6d4b\u9010\u6b65\u751f\u957f\u8fc7\u7a0b\u4e2d\u7684\u4e2d\u95f4\u4f53a: \u5236\u59072D PbI\u2082@MOF\u8d85\u6676\u683c\u7684\u793a\u610f\u56fe\u3002\u00a9 2024 Nature<\/p>\n
b: \u4e2d\u95f4\u4f53I-V\u7684PXRD\u56fe\u8c31\uff0c\u663e\u793a\u4ecePCN-606\u5230PbI\u2082@PCN-606\u8d85\u6676\u683c\u7684\u8f6c\u53d8\u8fc7\u7a0b\u3002
\n c: \u4e2d\u95f4\u4f53I-V\u7684\u5355\u6676\u7ed3\u6784\u3002\u9ec4\u8272\u3001\u7eff\u8272\u3001\u7d2b\u8272\u3001\u7070\u8272\u548c\u7ea2\u8272\u7403\u5206\u522b\u4ee3\u8868Zr\u3001Pb\u3001I\u3001C\u548cO\u539f\u5b50\uff0c\u6c22\u539f\u5b50\u4e3a\u6e05\u6670\u8d77\u89c1\u7701\u7565\u3002<\/p>\n
![\"\"](\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473.jpg\")
<\/p>\n
\u56fe3 | \u4f4e\u5242\u91cf\u51b7\u51bb\u9ad8\u5206\u8fa8\u7387\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08HR-TEM\uff09\u56fe\u50cf\u00a9 2024 Nature<\/p>\n
a, b: \u6cbf[001]\u65b9\u5411\u7684PbI\u2082@PCN-700\uff08a\uff09\u548c\u6cbf[100]\u65b9\u5411\u7684PbI\u2082@PCN-606\uff08b\uff09\u7684\u5bf9\u6bd4\u5ea6\u6821\u6b63HR-TEM\u56fe\u50cf\u3002\u63d2\u56fe\uff1a\u5feb\u901f\u5085\u91cc\u53f6\u53d8\u6362\u56fe\u6848\u3002
\n c, e: a\u548cb\u7684\u653e\u5927\u5047\u5f69\u8272\u56fe\u50cf\u3002
\n d, f: PbI\u2082@PCN-700\uff08d\uff09\u548cPbI\u2082@PCN-606\uff08f\uff09\u8d85\u6676\u683c\u7684\u6a21\u62df\u6295\u5f71\u52bf\u3002\u63d2\u56fe\uff1a\u57fa\u4e8eSC-XRD\u6676\u4f53\u5b66\u7684\u7406\u60f3\u8d85\u6676\u683c\u7684\u6295\u5f71\u7ed3\u6784\u6a21\u578b\u3002\u865a\u7ebf\u5706\u5708\u8868\u793a\u4e0e\u76f8\u90bbZr\u8282\u70b9\u7ed3\u5408\u5e76\u5d4c\u5165MOF\u6846\u67b6\u7a7a\u8154\u4e2d\u7684\u6295\u5f71PbI\u2082\u7c07\u7684\u5178\u578b\u5bf9\u6bd4\u5ea6\u3002\u6807\u5c3a\u4e3a2 nm\u3002<\/p>\n
![\"\"](\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474.jpg\")
<\/p>\n
\u56fe4 | \u80fa\u4fee\u9970\u7684PbI\u2082@MOF\u8d85\u6676\u683c\u7684\u5236\u5907\u53ca\u5149\u5b66\u8868\u5f81\u00a9 2024 Nature<\/p>\n
a: \u5236\u5907PbI\u2082@MOF\u57fa\u53d1\u5149\u4f53\u7684\u793a\u610f\u56fe\u3002AH\uff0c\u6c28\u6c34\uff1bPA\uff0c\u4e19\u80fa\uff1bPDA\uff0c1,3-\u4e19\u4e8c\u80fa\uff1bPEA\uff0c\u82ef\u4e59\u80fa\u3002
\n b: \u4e0d\u540c\u80fa\u4fee\u9970\u7684PbI\u2082@PCN-606\u8d85\u6676\u683c\u7684\u65f6\u95f4\u4f9d\u8d56\u6027\u8367\u5149\u3002
\n c: \u4eceSC-XRD\u6570\u636e\u6a21\u62df\u7684PbI\u2082@PCN-606\u8d85\u6676\u683c\u7684PXRD\u56fe\u8c31\uff0c\u4ee5\u53ca\u5b9e\u9a8c\u7684PbI\u2082@PCN-606\u548cS-MBA\/PbI\u2082@PCN-606\u8d85\u6676\u683c\u3002\u63d2\u56fe\uff1aPbI\u2082@PCN-606\uff08\u5de6\uff09\u3001S-MBA\/PbI\u2082@PCN-606\uff08\u4e2d\uff09\u548cS-MBA\/PbI\u2082@PCN-606\u5728\u7d2b\u5916\u5149\u4e0b\u7684\u7167\u7247\u3002\u6807\u5c3a\u4e3a0.2 mm\u3002
\n d, e: PCN-606\u3001PbI\u2082@PCN-606\u548cS-MBA\/PbI\u2082@PCN-606\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\uff08d\uff09\u548c\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff08e\uff09\u3002\u63d2\u56fe\uff1ad\u4e2d\u7684\u7ebf\u6027\u62df\u5408\u7528\u4e8e\u76f4\u63a5\u5e26\u9699\u3002A\u662f\u5438\u6536\u7cfb\u6570\uff0ch\u03bd\u662f\u5149\u5b50\u80fd\u91cf\u3002
\n f: \u572878 K\u4e0b\u6d4b\u91cf\u7684S-MBA\/PbI\u2082@MOFs\u7684\u7a33\u6001\u5149\u81f4\u53d1\u5149\u5149\u8c31\u3002\u63d2\u56fe\uff1a\u5bf9\u5e94\u7684\u8367\u5149\u7167\u7247\u3002
\n g: R-\u548cS-MBA\u4ee5\u53caR-\u548cS-MBA\/PbI\u2082@PCN-606\u7684\u5706\u4e8c\u8272\u5149\u8c31\u3002
\n h: S-MBA\/PbI\u2082@PCN-606\u548cR-MBA\/PbI\u2082@PCN-606\u572878 K\u4e0b\u7531405 nm\u7ebf\u504f\u632f\u6fc0\u5149\u6fc0\u53d1\u7684\u5706\u504f\u632f\u53d1\u5149\u5149\u8c31\u548c\u5706\u504f\u632f\u53d1\u5149\u5ea6\uff08P\uff09\u3002<\/p>\n
\u3010\u4e09\u3011\u3001\u4e3b\u8981\u521b\u65b0\u70b9<\/p>\n
\uff08<\/strong>1\uff09\u4e00\u9505\u6cd5\u5408\u6210\u591a\u7ef4\u5355\u6676\u8d85\u6676\u683c<\/p>\n \u901a\u8fc7\u5229\u7528\u9506\uff08IV\uff09\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u4f5c\u4e3a\u5bbf\u4e3b\u6a21\u677f\uff0c\u5b9e\u73b0\u4e86\u91d1\u5c5e\u5364\u5316\u7269\uff08\u5982PbI\u2082\u3001PbBr\u2082\u7b49\uff09\u5728MOFs\u5b54\u9053\u4e2d\u7684\u5b9a\u5411\u6210\u6838\u548c\u7cbe\u786e\u751f\u957f\uff0c\u6210\u529f\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u591a\u7ef4\u5355\u6676\u8d85\u6676\u683c\uff0c\u7a81\u7834\u4e86\u4f20\u7edf\u8d85\u6676\u683c\u6750\u6599\u5728\u754c\u9762\u5904\u7ed3\u6784\u65e0\u5e8f\u7684\u9650\u5236\u3002<\/p>\n \uff082\uff09\u539f\u5b50\u7cbe\u5ea6\u7684\u7ed3\u6784\u8c03\u63a7\u4e0e\u529f\u80fd\u5b9a\u5236<\/p>\n \u7cbe\u786e\u63a7\u5236MOFs\u7684\u5b54\u73af\u5883\uff08\u5982\u7a7a\u8154\u5927\u5c0f\u3001\u5f62\u72b6\u548c\u76f8\u90bb\u951a\u5b9a\u4f4d\u7684\u65b9\u5411\uff09\uff0c\u5b9e\u73b0\u4e86\u5bf9\u8d85\u6676\u683c\u6784\u5efa\u5355\u5143\u7684\u7ef4\u5ea6\u548c\u7ed3\u6784\u7684\u5b9a\u5236\u3002<\/p>\n \uff083\uff09\u591a\u5b54\u6846\u67b6\u4e2d\u7684\u529f\u80fd\u5316\u5d4c\u5165\u4e0e\u6027\u80fd\u63d0\u5347<\/p>\n \u901a\u8fc7\u5728\u591a\u5b54\u6846\u67b6\u4e2d\u5d4c\u5165\u529f\u80fd\u6027\u6750\u6599\uff08\u5982\u91d1\u5c5e\u5364\u5316\u7269\uff09\uff0c\u53ef\u4ee5\u5b9e\u73b0\u6750\u6599\u6027\u80fd\u7684\u663e\u8457\u63d0\u5347\u548c\u591a\u6837\u5316\u3002\u8fd9\u79cd\u7b56\u7565\u4e0d\u4ec5\u4fdd\u7559\u4e86MOFs\u7684\u591a\u5b54\u7279\u6027\uff0c\u8fd8\u901a\u8fc7\u529f\u80fd\u5316\u5d4c\u5165\u5b9e\u73b0\u4e86\u5149\u81f4\u53d1\u5149\u3001\u7535\u8377\u5206\u79bb\u548c\u624b\u6027\u5149\u5b66\u7b49\u6027\u80fd\u7684\u5b9a\u5236\uff0c\u4e3a\u5f00\u53d1\u65b0\u578b\u5149\u7535\u5b50\u6750\u6599\u548c\u91cf\u5b50\u5668\u4ef6\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u7406\u8bba\u548c\u5b9e\u9a8c\u57fa\u7840\u3002<\/p>\n \u3010\u56db\u3011\u3001\u79d1\u5b66\u542f\u793a<\/p>\n \u672c\u6587\u901a\u8fc7\u521b\u65b0\u7684\u5408\u6210\u7b56\u7565\u548c\u7cbe\u786e\u7684\u7ed3\u6784\u8c03\u63a7\uff0c\u5c55\u793a\u4e86\u8d85\u6676\u683c\u6750\u6599\u5728\u7535\u5b50\u3001\u5149\u5b66\u548c\u91cf\u5b50\u6027\u8d28\u65b9\u9762\u7684\u5de8\u5927\u6f5c\u529b\u3002\u8fd9\u4e9b\u7814\u7a76\u6210\u679c\u4e0d\u4ec5\u4e3a\u6750\u6599\u79d1\u5b66\u9886\u57df\u63d0\u4f9b\u4e86\u65b0\u7684\u7406\u8bba\u548c\u5b9e\u9a8c\u65b9\u6cd5\uff0c\u8fd8\u4e3a\u5f00\u53d1\u9ad8\u6027\u80fd\u529f\u80fd\u6750\u6599\u548c\u5668\u4ef6\u5f00\u8f9f\u4e86\u65b0\u7684\u9014\u5f84\u3002\u540c\u65f6\uff0c\u672c\u6587\u8fd8\u63a8\u52a8\u4e86\u6750\u6599\u79d1\u5b66\u3001\u5316\u5b66\u3001\u7269\u7406\u5b66\u548c\u7535\u5b50\u663e\u5fae\u5b66\u7b49\u591a\u4e2a\u5b66\u79d1\u9886\u57df\u7684\u76f8\u4e92\u4ea4\u53c9\u3002<\/p>\n \u8bba\u6587\u8be6\u60c5\uff1ahttps:\/\/www.nature.com\/articles\/s41586-024-08447-0<\/p>\n","protected":false},"excerpt":{"rendered":" \u3010\u4e00\u3011\u3001\u79d1\u5b66\u80cc\u666f \u8d85\u6676\u683c\u6750\u6599\u662f\u4e00\u79cd\u901a\u8fc7\u4eba\u5de5\u8bbe\u8ba1\u548c\u6784\u5efa\u7684\u5468\u671f\u6027\u7ed3\u6784\u6750\u6599\uff0c\u5176\u5316\u5b66\u7ec4\u6210\u5728\u7a7a\u95f4\u4e0a\u5448\u73b0\u5468\u671f\u6027\u8c03\u5236\u3002\u8fd9\u79cd\u8c03\u5236\u53ef\u4ee5\u4ea7\u751f\u53ef\u8c03\u63a7\u7684\u5468\u671f\u6027\u52bf\u80fd\u666f\u89c2\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u6750\u6599\u7535…<\/p>\n","protected":false},"author":34569,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-264852","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/264852"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/34569"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=264852"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/264852\/revisions"}],"predecessor-version":[{"id":264857,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/264852\/revisions\/264857"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=264852"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=264852"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=264852"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}