{"id":264733,"date":"2025-01-28T07:20:42","date_gmt":"2025-01-27T23:20:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=264733"},"modified":"2025-01-28T19:52:43","modified_gmt":"2025-01-28T11:52:43","slug":"%e6%b1%9f%e8%a5%bf%e5%b8%88%e8%8c%83%e5%a4%a7%e5%ad%a6%e8%a2%81%e5%bd%a9%e9%9b%b7%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9facs-energy-letters%ef%bc%9a%e6%8f%ad%e7%a4%ba%e4%ba%8c%e7%bb%b4fe7s8%e8%a1%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=264733","title":{"rendered":"\u6c5f\u897f\u5e08\u8303\u5927\u5b66\u8881\u5f69\u96f7\u6559\u6388\u56e2\u961fACS Energy Letters\uff1a\u63ed\u793a\u4e8c\u7ef4Fe7S8\u8868\u9762\u81ea\u65cb\u6784\u578b\u5bf9\u6790\u6c27\u53cd\u5e94\u6548\u7387\u63d0\u5347\u7684\u4f5c\u7528"},"content":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u50ac\u5316\u5242\u7684\u8868\u9762\u81ea\u65cb\u6784\u578b\u5728\u81ea\u65cb\u4f9d\u8d56\u50ac\u5316\u9886\u57df\u4e2d\u81f3\u5173\u91cd\u8981\uff0c\u56e0\u4e3a\u7535\u5316\u5b66\u53cd\u5e94\u4e3b\u8981\u53d1\u751f\u5728\u50ac\u5316\u5242\u4e0e\u7535\u89e3\u6db2\u63a5\u89e6\u7684\u56fa\u6db2\u754c\u9762\u3002\u8868\u9762\u81ea\u65cb\u6784\u578b\u901a\u8fc7\u8c03\u8282\u50ac\u5316\u53cd\u5e94\u4e2d\u4e2d\u95f4\u4f53\u7684\u81ea\u65cb\u72b6\u6001\uff0c\u80fd\u591f\u663e\u8457\u5f71\u54cd\u6700\u7ec8\u4ea7\u7269\u7684\u751f\u6210\u53ca\u53cd\u5e94\u6548\u7387\u3002\u8fd1\u5e74\u6765\uff0c\u56fd\u5185\u5916\u7684\u7814\u7a76\u63a2\u7d22\u4e86\u78c1\u6027\u6750\u6599\u81ea\u65cb\u6784\u578b\u4e0e\u5176\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u5e76\u63d0\u51fa\u901a\u8fc7\u65bd\u52a0\u5916\u90e8\u78c1\u573a\u6539\u53d8\u6750\u6599\u7684\u81ea\u65cb\u6784\u578b\u4ee5\u63d0\u9ad8\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u6d3b\u6027\u7684\u7b56\u7565\u3002\u7136\u800c\uff0c\u76ee\u524d\u5927\u90e8\u5206\u7814\u7a76\u6240\u7528\u7684\u50ac\u5316\u5242\u4e3a\u7c89\u672b\u6216\u7eb3\u7c73\u9897\u7c92\uff0c\u800c\u5e38\u7528\u7684\u78c1\u6027\u8868\u5f81\u6280\u672f\u4ec5\u80fd\u8bc4\u4f30\u8fd9\u4e9b\u6750\u6599\u7684\u5185\u90e8\u81ea\u65cb\u6784\u578b\u3002\u6b64\u5916\uff0c\u8fd9\u4e9b\u6750\u6599\u5f80\u5f80\u5448\u73b0\u4e0d\u89c4\u5219\u7684\u5f62\u6001\u3001\u8868\u9762\u7f3a\u9677\u53ca\u65ad\u88c2\u952e\uff0c\u4ece\u800c\u5bfc\u81f4\u8868\u9762\u81ea\u65cb\u6784\u578b\u4e0e\u5185\u90e8\u81ea\u65cb\u6784\u578b\u4e4b\u95f4\u5b58\u5728\u5dee\u5f02\u3002\u9274\u4e8e\u7535\u5316\u5b66\u53cd\u5e94\u4e3b\u8981\u53d1\u751f\u5728\u50ac\u5316\u5242\u8868\u9762\uff0c\u8fd9\u4e9b\u9650\u5236\u4f7f\u6211\u4eec\u5bf9\u81ea\u65cb\u4f9d\u8d56\u50ac\u5316\u673a\u5236\u7684\u7406\u89e3\u5b58\u5728\u663e\u8457\u4e0d\u8db3\u3002\u56e0\u6b64\uff0c\u51c6\u786e\u8bc6\u522b\u8868\u9762\u81ea\u65cb\u6784\u578b\u5bf9\u4e8e\u6df1\u5165\u7406\u89e3\u5176\u5728\u81ea\u65cb\u4f9d\u8d56\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u6838\u5fc3\u4f5c\u7528\u81f3\u5173\u91cd\u8981\uff0c\u5e76\u4e3a\u50ac\u5316\u5242\u8868\u9762\u81ea\u65cb\u6784\u578b\u7684\u8bbe\u8ba1\u548c\u8c03\u63a7\u63d0\u4f9b\u4e86\u5b9d\u8d35\u7684\u89c1\u89e3\u3002\u503c\u5f97\u5f3a\u8c03\u7684\u662f\uff0c\u94c1\u78c1\u6027\u4e8c\u7ef4\u6750\u6599\u5c55\u73b0\u51fa\u5353\u8d8a\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u50ac\u5316\u53cd\u5e94\u4e3b\u8981\u53d1\u751f\u5728\u5176\u8868\u9762\uff0c\u4e14\u5176\u8868\u9762\u81ea\u65cb\u6784\u578b\u6613\u4e8e\u89c2\u5bdf\u3002\u6b64\u5916\uff0c\u67d0\u4e9b\u94c1\u78c1\u6027\u4e8c\u7ef4\u6750\u6599\u7684\u78c1\u7ed3\u6784\u5bf9\u539a\u5ea6\u548c\u5916\u90e8\u78c1\u573a\u7684\u53d8\u5316\u9ad8\u5ea6\u654f\u611f\u3002\u8fd9\u4e9b\u7279\u6027\u8868\u660e\uff0c\u8868\u9762\u81ea\u65cb\u6784\u578b\u53ef\u4ee5\u901a\u8fc7\u8c03\u63a7\u6750\u6599\u7684\u539a\u5ea6\u4ee5\u53ca\u65bd\u52a0\u5916\u90e8\u78c1\u573a\u8fdb\u884c\u7cbe\u786e\u64cd\u63a7\u3002\u4f5c\u4e3a\u4e00\u79cd\u5ba4\u6e29\u94c1\u78c1\u6027\u4e8c\u7ef4\u6750\u6599\uff0cFe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u5728OER\u4e2d\u5c55\u73b0\u4e86\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u3002\u56e0\u6b64\uff0c\u4e8c\u7ef4Fe<sub>7<\/sub>S<sub>8<\/sub>\u6750\u6599\uff0c\u51ed\u501f\u5176\u4f18\u826f\u7684OER\u6027\u80fd\u548c\u6f5c\u5728\u53ef\u8c03\u63a7\u7684\u8868\u9762\u81ea\u65cb\u6784\u578b\uff0c\u4e3a\u63a2\u7d22\u8868\u9762\u81ea\u65cb\u6784\u578b\u4e0eOER\u6d3b\u6027\u4e4b\u95f4\u7684\u5173\u7cfb\u63d0\u4f9b\u4e86\u7406\u60f3\u7684\u5e73\u53f0\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p>\u8fd1\u671f\uff0c\u6c5f\u897f\u5e08\u8303\u5927\u5b66\u8881\u5f69\u96f7\u6559\u6388\u56e2\u961f\u901a\u8fc7\u63a7\u5236CVD\u751f\u957f\u6e29\u5ea6\uff0c\u6210\u529f\u5236\u5907\u4e86\u4e0d\u540c\u539a\u5ea6\u7684Fe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u3002\u78c1\u529b\u663e\u5fae\u955c\uff08MFM\uff09\u89c2\u6d4b\u7ed3\u679c\u8868\u660e\uff0c\u4e0d\u540c\u539a\u5ea6\u7684\u7eb3\u7c73\u7247\u5177\u6709\u4e0d\u540c\u7684\u8868\u9762\u81ea\u65cb\u6784\u578b\uff08\u7ea648 nm\u65f6\u4e3a\u591a\u7574\u6784\u578b\uff0c9 nm\u65f6\u4e3a\u5355\u7574\u6784\u578b\uff09\u3002\u901a\u8fc7\u6bd4\u8f83\u591a\u7574\u548c\u5355\u7574\u6837\u54c1\u5728\u5916\u52a0\u78c1\u573a\u4f5c\u7528\u524d\u540e\u7684\u8868\u9762\u81ea\u65cb\u6784\u578b\u53caOER\u6027\u80fd\uff0c\u7814\u7a76\u56e2\u961f\u6210\u529f\u63ed\u793a\u4e86\u78c1\u7574\u58c1\u4e2d\u7684\u81ea\u65cb\u65e0\u5e8f\u5bf9OER\u81ea\u65cb\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002\u8fd9\u4e00\u7814\u7a76\u6210\u679c\u5df2\u53d1\u8868\u4e8e\u300aACS Energy Letters\u300b\uff0c\u9898\u4e3a\u300aRealizing Surface Spin Configurations of Two-Dimensional Fe<sub>7<\/sub>S<sub>8<\/sub>\u00a0for Oxygen Evolution Reaction\u300b\u3002\u6c5f\u897f\u5e08\u8303\u5927\u5b66\u8881\u5f69\u96f7\u6559\u6388\u4e3a\u901a\u8baf\u4f5c\u8005\uff0c\u7855\u58eb\u7814\u7a76\u751f\u674e\u5ef7\u5cf0\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u5468\u6587\u8fbe\u535a\u58eb\u548c\u7855\u58eb\u7814\u7a76\u751f\u949f\u8d85\u4e3a\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-264734\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72471-25.png\" alt=\"\" width=\"800\" height=\"681\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72471-25.png 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72471-25-300x255.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72471-25-768x654.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/> \u00a0\u00a0\u00a0<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/b><\/strong><\/p>\n<p>1\u3001\u672c\u7814\u7a76\u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u6e29\u5ea6\u6765\u63a7\u5236Fe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u7684\u539a\u5ea6\uff0c\u5e76\u6210\u529f\u91c7\u7528\u5e38\u538b\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\uff08APCVD\uff09\u65b9\u6cd5\u8bbe\u8ba1\u51fa\u5177\u6709\u4e0d\u540c\u8868\u9762\u78c1\u7ed3\u6784\uff08\u8868\u9762\u81ea\u65cb\u6784\u578b\uff09\u7684Fe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u3002\u8fd9\u4e9b\u7eb3\u7c73\u7247\u5728\u7ea648 nm\u539a\u5ea6\u65f6\u5c55\u73b0\u51fa\u591a\u7574\u6784\u578b\uff0c\u800c\u5728\u7ea69 nm\u539a\u5ea6\u65f6\u5219\u8868\u73b0\u4e3a\u5355\u7574\u6784\u578b\u3002<\/p>\n<p>2\u3001\u78c1\u529b\u663e\u5fae\u955c\uff08MFM\uff09\u89c2\u6d4b\u7ed3\u679c\u8868\u660e\uff0c\u5f53\u65bd\u52a0200 mT\u5916\u90e8\u78c1\u573a\u65f6\uff0c\u591a\u7574\u6837\u54c1\u7684\u8868\u9762\u81ea\u65cb\u6784\u578b\u8f6c\u53d8\u4e3a\u5355\u7574\u6784\u578b\uff0c\u78c1\u7574\u58c1\u5b8c\u5168\u6d88\u5931\uff0c\u800c\u5355\u7574\u6837\u54c1\u5219\u4fdd\u6301\u5176\u539f\u6709\u7684\u8868\u9762\u81ea\u65cb\u6784\u578b\u3002\u56e0\u6b64\uff0c\u5177\u6709\u6613\u4e8e\u8bc6\u522b\u548c\u53ef\u63a7\u8868\u9762\u81ea\u65cb\u6784\u578b\u7684Fe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u4e3a\u7814\u7a76\u81ea\u65cb\u6784\u578b\u5bf9OER\u6027\u80fd\u7684\u5f71\u54cd\u63d0\u4f9b\u4e86\u7406\u60f3\u7684\u5b9e\u9a8c\u5e73\u53f0\u3002<\/p>\n<p>3\u3001\u7535\u5316\u5b66\u6d4b\u8bd5\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u8868\u660e\uff0c\u78c1\u7574\u58c1\u533a\u57df\u81ea\u65cb\u65e0\u5e8f\u5230\u81ea\u65cb\u6709\u5e8f\u7684\u8f6c\u53d8\uff0c\u663e\u8457\u5f71\u54cd\u4e86OER\u81ea\u65cb\u9009\u62e9\u6027\uff0c\u5e76\u6709\u6548\u964d\u4f4e\u4e86\u53cd\u5e94\u80fd\u5792\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-264735\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72472-23.png\" alt=\"\" width=\"800\" height=\"655\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72472-23.png 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72472-23-300x246.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72472-23-768x629.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p><strong>\u56fe1.<\/strong>\u00a0\u7406\u8bba\u8ba1\u7b97\u3002\uff08a\uff09Fe<sub>7<\/sub>S<sub>8<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\uff1b\uff08b\uff09Fe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u7684\u6001\u5bc6\u5ea6\uff1b\uff08c\uff09Fe<sub>7<\/sub>S<sub>8<\/sub>\u7684OER\u673a\u5236\u7684\u793a\u610f\u56fe\uff1b<em>\u03b7<\/em>\u8868\u793a\u901f\u7387\u51b3\u5b9a\u6b65\u9aa4\u7684\u7406\u8bba\u8fc7\u7535\u4f4d\uff1b\uff08d\uff09Fe<sub>7<\/sub>S<sub>8<\/sub>\u57280 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k\uff09\uff08i\uff09\u7684Fe\u548cS\u5143\u7d20\u7684\u76f8\u5e94EDS\u6620\u5c04\u56fe\u50cf;\uff08n, o\uff09\uff08m\uff09\u7684Fe\u548cS\u5143\u7d20\u7684\u76f8\u5e94EDS\u6620\u5c04\u56fe\u50cf;\uff08l\uff09\uff08i\uff09\u7684\u76f8\u5e94\u80fd\u8c31\u5143\u7d20\u5206\u6790\u56fe\u8c31;\uff08p\uff09\uff08m\uff09\u7684\u76f8\u5e94\u80fd\u8c31\u5143\u7d20\u5206\u6790\u56fe\u8c31\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-264737\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72474-17.png\" alt=\"\" width=\"800\" height=\"753\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72474-17.png 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72474-17-300x282.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72474-17-768x723.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p><strong>\u56fe3<\/strong>. CVD\u5408\u6210\u7684\u4e8c\u7ef4Fe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u7684\u78c1\u6027\u7279\u6027\u3002\u56fe\uff08a\uff09\u548c\uff08b\uff09\u5206\u522b\u5c55\u793a\u4e86\u5728300 K\u4e0b\uff0c\u78c1\u573a\u5782\u76f4\u4e8eFe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u57fa\u5e95\u5e73\u9762\u65f6\uff0c\u751f\u957f\u6e29\u5ea6\u4e3a650 \u2103\u548c600 \u2103\u7684\u78c1\u6ede\u56de\u7ebf\uff1b\uff08c\uff09 \u5728650 \u2103\u751f\u957f\u6e29\u5ea6\u4e0bFe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u7684\u539f\u5b50\u529b\u663e\u5fae\u955c\u56fe\u50cf\u53ca\u76f8\u5e94\u7684\u9ad8\u5ea6\u5256\u9762\uff1b\uff08d, e\uff09 \u5206\u522b\u662f\u5728\u6ca1\u6709200 mT\u78c1\u573a\u548c\u6709200 mT\u78c1\u573a\u4e0b\u7684\u76f8\u5e94MFM\u56fe\u50cf\uff1b\uff08f\uff09\u5728600 \u2103\u751f\u957f\u6e29\u5ea6\u4e0bFe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u7684\u539f\u5b50\u529b\u663e\u5fae\u955c\u56fe\u50cf\u53ca\u76f8\u5e94\u7684\u9ad8\u5ea6\u5256\u9762\uff1b\uff08g, h\uff09\u5206\u522b\u662f\u5728\u6ca1\u6709200 mT\u78c1\u573a\u548c\u6709200 mT\u78c1\u573a\u4e0b\u7684\u76f8\u5e94MFM\u56fe\u50cf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-264738\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72475-15.png\" alt=\"\" width=\"800\" height=\"974\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72475-15.png 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72475-15-246x300.png 246w, \/\/m.iemloyee.com\/wp-content\/uploads\/2025\/01\/\u56fe\u72475-15-768x935.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p><strong>\u56fe4<\/strong>. \u591a\u7574\uff08MD\uff09\u548c\u5355\u7574\uff08SD\uff09\u6837\u54c1\u5728\u5b58\u5728\u548c\u4e0d\u5b58\u5728200 mT\u78c1\u573a\u4e0b\u7684\u7535\u5316\u5b66\u6d3b\u6027\u3002\uff08a\uff09\u7535\u5316\u5b66\u5fae\u7535\u6c60\u8bbe\u7f6e\u7684\u793a\u610f\u56fe\u3002HOPG\uff08\u9ad8\u5ea6\u5b9a\u5411\u70ed\u89e3\u77f3\u58a8\uff09\u4f5c\u4e3a\u6837\u54c1\u7684\u57fa\u5e95\uff1b\uff08b\uff09\u5728\u5b58\u5728\u548c\u4e0d\u5b58\u5728200 mT\u78c1\u573a\u4e0b\uff0c\u591a\u7574\uff08MD\uff09\u548c\u5355\u7574\uff08SD\uff09\u6837\u54c1\u53caIrO<sub>2<\/sub>\u7684iR\u6821\u51c6\u540e\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u66f2\u7ebf\uff1b\uff08c\uff09\u5728\u5b58\u5728\u548c\u4e0d\u5b58\u5728200 mT\u78c1\u573a\u4e0b\uff0c\u591a\u7574\uff08MD\uff09\u548c\u5355\u7574\uff08SD\uff09\u6837\u54c1\u53caIrO<sub>2<\/sub>\u7684\u76f8\u5e94Tafel\u56fe\uff1b\uff08d\uff09\u5728\u5b58\u5728\u548c\u4e0d\u5b58\u5728200 mT\u78c1\u573a\u4e0b\uff0c\u591a\u7574\uff08MD\uff09\u548c\u5355\u7574\uff08SD\uff09\u6837\u54c1\u7684Nyquist\u56fe\uff1b\uff08e\uff09\u5728\u5b58\u5728\u548c\u4e0d\u5b58\u5728200 mT\u78c1\u573a\u4e0b\uff0c\u591a\u7574\uff08MD\uff09\u548c\u5355\u7574\uff08SD\uff09\u6837\u54c1\u7684<em>C<\/em><sub>dl<\/sub>\uff1b\uff08f\uff09200 mT\u5916\u90e8\u78c1\u573a\u4e0b\u591a\u7574\uff08MD\uff09\u6837\u54c1\u548c\u5355\u7574\uff08SD\uff09\u6837\u54c1\u7684\u78c1\u7ed3\u6784\u548c\u81ea\u65cb\u72b6\u6001\u5206\u5e03\u6f14\u53d8\u793a\u610f\u56fe\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/b><\/strong><\/p>\n<p>\u672c\u7814\u7a76\u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u6e29\u5ea6\u6765\u63a7\u5236Fe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u7684\u539a\u5ea6\uff0c\u6210\u529f\u8bbe\u8ba1\u4e86\u5177\u6709\u4e0d\u540c\u8868\u9762\u81ea\u65cb\u6784\u578b\u7684Fe<sub>7<\/sub>S<sub>8<\/sub>\u7eb3\u7c73\u7247\u3002MFM\u89c2\u5bdf\u7ed3\u679c\u8868\u660e\uff0c\u5728200 mT\u5916\u90e8\u78c1\u573a\u4e0b\uff0c\u591a\u7574\u6837\u54c1\u7684\u8868\u9762\u81ea\u65cb\u6784\u578b\u8f6c\u53d8\u4e3a\u5355\u7574\u7ed3\u6784\uff0c\u800c\u5355\u7574\u6837\u54c1\u7684\u81ea\u65cb\u6784\u578b\u5219\u4fdd\u6301\u4e0d\u53d8\u3002\u572810 mA\u00b7cm\u207b\u00b2\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cOER\u6d4b\u8bd5\u663e\u793a\uff0c\u591a\u7574\u6837\u54c1\u7684\u521d\u59cb\u8fc7\u7535\u4f4d\u4e3a306 mV\uff0c\u5728200 mT\u78c1\u573a\u4e0b\u964d\u81f3240 mV\uff0c\u589e\u52a0\u573a\u5f3a\u81f3300 mT\u540e\u6027\u80fd\u672a\u8fdb\u4e00\u6b65\u63d0\u5347\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5355\u7574\u6837\u54c1\u5728\u65e0\u5916\u90e8\u78c1\u573a\u65f6\u7684\u8fc7\u7535\u4f4d\u4e3a257 mV\uff0c\u65bd\u52a0\u78c1\u573a\u540e\u5176OER\u6027\u80fd\u51e0\u4e4e\u6ca1\u6709\u6539\u5584\u3002\u6b64\u5916\uff0cDFT\u8ba1\u7b97\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e86\u591a\u7574\u6837\u54c1\u5728\u78c1\u573a\u4e0b\u50ac\u5316\u6d3b\u6027\u7684\u63d0\u5347\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u78c1\u7574\u58c1\u7684\u81ea\u65cb\u65e0\u5e8f\u662f\u5f71\u54cdOER\u8fc7\u7a0b\u4e2d\u81ea\u65cb\u9009\u62e9\u6027\u7684\u5173\u952e\u56e0\u7d20\u3002\u56e0\u6b64\uff0c\u5236\u5907\u5355\u7574\u6837\u54c1\uff0c\u6216\u5c06\u591a\u7574\u6837\u54c1\u7684\u7574\u58c1\u533a\u57df\u4ece\u65e0\u5e8f\u81ea\u65cb\u72b6\u6001\u8c03\u63a7\u4e3a\u6709\u5e8f\u81ea\u65cb\u72b6\u6001\uff0c\u662f\u63d0\u5347OER\u6027\u80fd\u7684\u6709\u6548\u7b56\u7565\u3002\u8fd9\u4e3a\u63a8\u52a8\u65b0\u578b\u81ea\u65cb\u9009\u62e9\u6027\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u4e0e\u5f00\u53d1\uff0c\u5c24\u5176\u662f\u5728\u53ef\u6301\u7eed\u80fd\u6e90\u6280\u672f\u4e2d\u7684\u5e94\u7528\uff0c\u63d0\u4f9b\u4e86\u65b0\u7684\u7814\u7a76\u65b9\u5411\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>Realizing Surface Spin Configurations of Two-Dimensional Fe<sub>7<\/sub>S<sub>8<\/sub>\u00a0for Oxygen Evolution Reaction<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/acsenergylett.5c00059<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 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