{"id":264337,"date":"2025-01-04T10:18:33","date_gmt":"2025-01-04T02:18:33","guid":{"rendered":"\/\/m.iemloyee.com\/?p=264337"},"modified":"2025-01-04T10:18:33","modified_gmt":"2025-01-04T02:18:33","slug":"adv-mater-%ef%bc%9amof%e8%a1%8d%e7%94%9f%e7%9a%84%e7%a2%b3%e5%9f%ba%e6%9d%90%e6%96%99%e5%9c%a8%e8%83%bd%e6%ba%90%e7%9b%b8%e5%85%b3%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=264337","title":{"rendered":"Adv. Mater.\uff1aMOF\u884d\u751f\u7684\u78b3\u57fa\u6750\u6599\u5728\u80fd\u6e90\u76f8\u5173\u7684\u5e94\u7528"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011
\n \u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08Metal-Organic Frameworks\uff0cMOFs\uff09\u4ee5\u5176\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u9ad8\u5b54\u9699\u7387\u3001\u4f18\u5f02\u5316\u5b66\u7269\u7406\u6027\u8d28\u548c\u70ed\u7a33\u5b9a\u6027\u5df2\u6210\u4e3a\u6784\u5efa\u65b0\u578b\u7eb3\u7c73\u6750\u6599\u7684\u70ed\u95e8\u524d\u9a71\u4f53\u3002\u9ad8\u6e29\u70ed\u89e3\u5904\u7406\u7684MOF\u884d\u751f\u7684\u78b3\u57fa\u6750\u6599\uff08Carbon-based materials\uff0cCMs\uff09\u4e0d\u4ec5\u5730\u7ee7\u627fMOF\u524d\u4f53\u7684\u591a\u5b54\u7279\u6027\uff0c\u8fd8\u5b9e\u73b0\u4e86\u6d3b\u6027\u7ec4\u5206\u7684\u7075\u6d3b\u529f\u80fd\u96c6\u6210\uff0c\u5df2\u5728\u9ad8\u6548\u80fd\u6e90\u76f8\u5173\u7684\u5e94\u7528\u4e2d\u53d6\u5f97\u4ee4\u4eba\u77a9\u76ee\u7684\u53d1\u5c55\u52bf\u5934\u3002\u57fa\u4e8e\u6b64\uff0c\u9762\u5411\u6d3b\u6027\u6210\u5206\u7684\u7cbe\u786e\u7b5b\u9009\u3001\u7ed3\u6784\u8c03\u63a7\u548c\u529f\u80fd\u5316\u7b49\u65b9\u9762\u7684MOF\u884d\u751f\u7684CMs\u8bbe\u8ba1\uff0c\u53ef\u4ee5\u5c06\u5fae\u7eb3\u7ed3\u6784\u548c\u6d3b\u6027\u6210\u5206\u7684\u534f\u540c\u4f5c\u7528\u4e0e\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u5185\u5728\u5173\u8054\u548c\u8fdb\u5316\u884c\u4e3a\u96c6\u6210\u4e00\u4f53\uff0c\u62d3\u5c55\u5176\u5e94\u7528\uff0c\u6210\u4e3a\u5316\u5b66\u548c\u6750\u6599\u79d1\u5b66\u9886\u57df\u7684\u65b0\u5174\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1. MOF\u884d\u751f\u7684\u4e0d\u540c\u7c7b\u578b\u7684CMs\u7684\u529f\u80fd\u5316\u5e94\u7528\u6982\u8ff0<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011
\n \u8fd1\u65e5\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u6f58\u519b\u9752\u6559\u6388\u548c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u5468\u7428\u6559\u6388\u7684\u56e2\u961f\u5728\u6750\u6599\u7efc\u8ff0\u7684\u9876\u520a\u300aAdvanced Materials\u300b\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cMOF-derived carbon-based materials for energy-related applications\u201d\u7684\u7efc\u8ff0\u6027\u8bba\u6587\uff08DOI: 10.1002\/adma.202413658\uff09\uff0c\u535a\u58eb\u7814\u7a76\u751f\u67f4\u8def\u8def\u4e3a\u7b2c\u4e00\u4f5c\u8005\u3002\u672c\u7efc\u8ff0\u4ece\u7ec4\u6210\u6210\u5206\u7684\u89d2\u5ea6\u53bb\u7cfb\u7edf\u603b\u7ed3\u4e86\u4e0d\u540c\u7c7b\u578bMOF\u884d\u751fCMs\u7684\u5408\u6210\u7b56\u7565\u4e0e\u7ed3\u6784\u6f14\u53d8\uff0c\u8be6\u7ec6\u9610\u8ff0\u4e86\u6210\u5206\u8bbe\u8ba1\u548c\u7ed3\u6784\u8c03\u63a7\u5bf9\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u5185\u5728\u5173\u8054\u548c\u6f14\u53d8\u89c4\u5f8b\uff0c\u5e76\u5168\u9762\u5730\u5206\u6790\u4e86MOF\u884d\u751fCMs\u5728\u6700\u65b0\u7535\u5316\u5b66\u50a8\u80fd\uff08\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u3001\u94a0\u94be\u79bb\u5b50\u7535\u6c60\u7b49\uff09\u548c\u7535\u50ac\u5316\uff08ORR\u3001OER\u3001CO2RR\u7b49\uff09\u9886\u57df\u4e2d\u7684\u4f18\u5f02\u53cd\u5e94\u6027\u80fd\uff0c\u5f3a\u8c03\u4e86\u4e0d\u540c\u6750\u6599\u5728\u5404\u79cd\u573a\u666f\u4e2d\u7684\u4f18\u52bf\uff08\u56fe1\uff09\u3002\u6700\u540e\uff0c\u603b\u7ed3\u4e86\u76ee\u524dMOF\u884d\u751fCMs\u9762\u4e34\u7684\u6311\u6218\u548c\u73b0\u72b6\uff0c\u5e76\u5bf9\u672a\u6765\u7814\u7a76\u65b9\u5411\u4e0e\u6311\u6218\u8fdb\u884c\u4e86\u6307\u5bfc\u6027\u7684\u5c55\u671b\u3002<\/p>\n

\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011
\n 1. MOF\u884d\u751fCMs\u8bbe\u8ba1\u4e2d\u7684\u5408\u6210\u7b56\u7565
\n \u4eceMOF\u524d\u9a71\u4f53\u7684\u6210\u5206\u8bbe\u8ba1\u63a7\u5236\u8003\u8651\uff0c\u5982\u91d1\u5c5e\u8282\u70b9\u548c\u6709\u673a\u914d\u4f53\u7684\u5408\u7406\u9009\u62e9\u3001\u914d\u4f4d\u65b9\u5f0f\u9009\u62e9\u4ee5\u53ca\u78b3\u5316\u6761\u4ef6\u9009\u62e9\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u5b9a\u5236\u9ad8\u6548\u7684\u591a\u529f\u80fd\u7684\u78b3\u6750\u6599\uff0c\u5728\u4e0e\u80fd\u6e90\u76f8\u5173\u7684\u9886\u57df\u4e2d\u5c55\u73b0\u51fa\u91cd\u8981\u7684\u5e94\u7528\u524d\u666f\u3002\u4ece\u4e0d\u540cMOFs\u884d\u751f\u7684CMs\u4e3b\u8981\u5206\u4e3a\u56db\u5927\u7c7b\uff1a\u65e0\u91d1\u5c5e\u7684\u7eaf\u78b3\u6750\u6599\u3001\u65e0\u91d1\u5c5e\u7684\u6742\u539f\u5b50\u63ba\u6742\u7684CMs\u3001\u91d1\u5c5e\u63ba\u6742\u7684CMs\uff08\u5982\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u548c\u5355\/\u53cc\u539f\u5b50\uff09\u4ee5\u53ca\u91d1\u5c5e\u5316\u5408\u7269\u63ba\u6742CMs\uff08\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u91d1\u5c5e\u78f7\u5316\u7269\u3001\u91d1\u5c5e\u786b\u5316\u7269\u548cLDH\u7b49\uff09\uff08\u56fe2\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2. \u7531MOF\u884d\u751f\u7684\u7684\u5404\u79cdCMs\u7684\u7ed3\u6784\u56fe\u3002
\n 1.1 \u65e0\u91d1\u5c5e\u78b3\u57fa\u6750\u6599
\n MOF\u884d\u751f\u7684\u65e0\u91d1\u5c5eCMs\u901a\u5e38\u662f\u5c06MOFs\u524d\u9a71\u4f53\u8fdb\u884c\u9ad8\u6e29\u70ed\u89e3\u3001\u539f\u4f4d\u84b8\u53d1\u6216\u6d78\u51fa\u91d1\u5c5e\u7269\u79cd\u7b49\u65b9\u6cd5\u6765\u83b7\u53d6\u3002\u5176\u4e2d\u65e0\u91d1\u5c5eCMs\u5305\u62ec\u7eaf\u78b3\u548c\u6742\u539f\u5b50\u63ba\u6742\u78b3\u6750\u6599\u3002
\n \"\"
\n \u56fe3. \u5404\u79cdMOF\u884d\u751f\u7684\u7eaf\u78b3\u6750\u6599\u7684\u5408\u6210\u7b56\u7565
\n \u5bf9\u4e8e\u7eaf\u78b3\u6750\u6599\u7684\u5236\u5907\uff0c\u5927\u591a\u90fd\u9009\u62e9\u5e38\u89c1\u7684\u7fa7\u9178\u914d\u4f53H2BDC\u548cH3BTC\u7b49\u914d\u4f53\u4e0e\u4f4e\u6cb8\u70b9\u7684\u91d1\u5c5e\u76d0\uff08Zn\uff1a907 oC\uff0cCd\uff1a767 oC\u7b49\uff09\u914d\u4f4d\u5f62\u6210\u4f4e\u6cb8\u70b9\u7684\u91d1\u5c5e\u57faMOFs\uff0c\u968f\u540eMOF\u5728\u9ad8\u7684\u78b3\u5316\u6e29\u5ea6\uff08800-1200 oC\uff09\u4e0b\u76f4\u63a5\u78b3\u5316\uff0c\u5176\u4e2d\u6709\u673a\u9aa8\u67b6\u5206\u89e3\uff0c\u91d1\u5c5e\u7269\u79cd\u88ab\u539f\u4f4d\u84b8\u53d1\u3002\u53e6\u5916\uff0c\u9ad8\u6cb8\u70b9\u7684\u91d1\u5c5e\u57faMOFs\uff0c\u4f8b\u5982Al\u3001Mg\u3001Fe\u3001Co\u3001Ni\u3001Cu\u3001In\u7b49\u5728\u78b3\u5316\u8fc7\u7a0b\u4e2d\u5bb9\u6613\u5f62\u6210\u91d1\u5c5e\u6c27\u5316\u7269\u6216\u91d1\u5c5e\u9897\u7c92\uff0c\u53ef\u4ee5\u901a\u8fc7\u9178\u6216\u78b1\u523b\u8680\u8fdb\u4e00\u6b65\u53bb\u9664\u6765\u5f97\u5230\u5177\u6709\u4e30\u5bcc\u5b54\u9699\u7ed3\u6784\u7684\u65e0\u91d1\u5c5eCMs\u3002\u6b64\u5916\uff0c\u5bf9\u83b7\u5f97\u7684\u65e0\u91d1\u5c5eCMs\u8fd8\u53ef\u4ee5\u901a\u8fc7\u5316\u5b66\u6d3b\u5316\u624b\u6bb5\u4e0eKOH\u548cKNO3\u8fdb\u884c\u989d\u5916\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u751f\u6210\u66f4\u5927\u6bd4\u8868\u9762\u79ef\u7684\u6d3b\u6027\u78b3\uff08AC\uff09\uff0c\u540c\u65f6\u91ca\u653e\u51fa\u4e00\u4e9b\u6c14\u4f53\uff08CO\u3001H2\u3001CO2\u548cH2O\u7b49\uff09\uff08\u56fe3\uff09\u3002
\n \u5bf9\u4e8e\u6742\u539f\u5b50\u63ba\u6742\u78b3\u6750\u6599\u7684\u5236\u5907\uff0c\u4e3b\u8981\u901a\u8fc7\u539f\u4f4d\u70ed\u89e3\u63ba\u6742\u548c\u53cd\u5e94\u6027\u6742\u539f\u5b50\u6e90\u8fdb\u884c\u540e\u5904\u7406\u63ba\u6742\u7684\u5408\u6210\u5de5\u827a\u6765\u83b7\u5f97\u5355\u4e00\u6216\u591a\u79cd\u6742\u539f\u5b50\u7684\u6709\u6548\u63ba\u6742\uff08\u56fe4\uff09\u3002
\n \"\"
\n \u56fe4. \u5404\u79cdMOF\u884d\u751f\u7684\u65e0\u91d1\u5c5e\u6742\u539f\u5b50\u63ba\u6742CMs\u7684\u5408\u6210\u7b56\u7565
\n 1.2 \u91d1\u5c5e\u63ba\u6742\u78b3\u57fa\u6750\u6599
\n \u901a\u8fc7\u9ad8\u6e29\u70ed\u89e3\uff0cMOFs\u4e2d\u7684\u91d1\u5c5e\u9633\u79bb\u5b50\u88ab\u8fd8\u539f\u5f62\u6210\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u6216\u5355\u539f\u5b50\u5747\u5300\u5730\u951a\u5b9a\u5728\u591a\u5b54\u78b3\u57fa\u5e95\u4e0a\u3002\u76f8\u6bd4\u4e8e\u539f\u4f4d\u70ed\u89e3\u3001\u7a7a\u95f4\u7ea6\u675f\u3001\u5438\u9644\u8fd8\u539f\u3001\u914d\u4f4d\u8bbe\u8ba1\u3001\u4e24\u6b65\u70ed\u89e3\u7b49\u591a\u79cd\u5408\u6210\u7b56\u7565
\n \u5176\u4e2d\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u56e0\u8f83\u5927\u7684\u5c3a\u5bf8\u548c\u4e30\u5bcc\u7684\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\uff0c\u663e\u8457\u5730\u63d0\u5347\u4e86\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u4f46\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u6613\u56e2\u805a\u5bfc\u81f4\u8f83\u5dee\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002\u4f20\u7edf\u7684\u91d1\u5c5eNPs\/\u5408\u91d1\u76f8\u6bd4\uff0c\u91d1\u5c5e\u5355\u539f\u5b50\uff08SAs\uff09\u6216\u53cc\u539f\u5b50\uff08DAs\uff09\u7531\u4e8e\u660e\u786e\u7684\u7535\u5b50\u7ed3\u6784\u548c\u6781\u9ad8\u7684\u539f\u5b50\u5229\u7528\u7387\uff0c\u53ef\u4ee5\u51cf\u5c11\u91d1\u5c5e\u8d44\u6e90\u7684\u4f7f\u7528\uff0c\u6709\u5229\u4e8e\u6709\u6548\u964d\u4f4e\u50ac\u5316\u5242\u6210\u672c\u3002\u76ee\u524d\u5df2\u6709\u539f\u4f4d\u70ed\u89e3\u3001\u7a7a\u95f4\u7ea6\u675f\u3001\u5438\u9644\u8fd8\u539f\u3001\u914d\u4f4d\u8bbe\u8ba1\u3001\u4e24\u6b65\u70ed\u89e3\u7b49\u591a\u79cd\u5408\u6210\u7b56\u7565\u88ab\u62a5\u9053\uff0c\u4ece\u800c\u4e3a\u50ac\u5316\u5242\u8bbe\u8ba1\u5f00\u8f9f\u4e86\u65b0\u7684\u65b9\u5411\uff0c\u4fc3\u8fdb\u4e86\u9ad8\u6548\u3001\u4f4e\u6210\u672c\u50ac\u5316\u5242\u7684\u53d1\u5c55\uff08\u56fe5\uff09\u3002
\n \"\"
\n \u56fe5. \u5404\u79cdMOF\u884d\u751f\u7684\u5355\u539f\u5b50\/\u53cc\u539f\u5b50\u8d1f\u8f7d\u7684CMs\u7684\u5408\u6210\u7b56\u7565
\n 1.3 \u91d1\u5c5e\u5316\u5408\u7269\u63ba\u6742\u78b3\u57fa\u6750\u6599
\n \u91d1\u5c5e\u5316\u5408\u7269\u5982\u91d1\u5c5e\u6c27\u5316\u7269\uff08MxOy\uff09\u3001\u91d1\u5c5e\u786b\u5316\u7269\uff08MxSy\uff09\u3001\u91d1\u5c5e\u78f7\u5316\u7269\uff08MxPy\uff09\u548cLDHs\u7b49\u4e5f\u53ef\u4ee5\u5d4c\u5165\u5728\u591a\u5b54\u78b3\u57fa\u5e95\u4e2d\uff0c\u5f62\u6210\u7a33\u5b9a\u7684\u6742\u5316\u7ed3\u6784\u3002\u8fd9\u4e9bCMs\u662fMOFs\u901a\u8fc7\u70ed\u89e3\u548c\u540e\u7eed\u5904\u7406\u5de5\u827a\u4e2d\u91d1\u5c5e\u79bb\u5b50\u4e0e\u5f15\u5165\u7684\u6c27\u3001\u786b\u3001\u78f7\u3001\u5c3f\u7d20\u7b49\u7269\u8d28\u53cd\u5e94\u751f\u6210\u76f8\u5e94\u7684\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u4ece\u800c\u8d4b\u4e88\u6750\u6599\u4f18\u5f02\u7684\u5bfc\u7535\u6027\u3001\u50ac\u5316\u6d3b\u6027\u4ee5\u53ca\u7a33\u5b9a\u6027\uff0c\u5c55\u73b0\u51fa\u5728\u80fd\u6e90\u548c\u5176\u4ed6\u9886\u57df\u7684\u5e94\u7528\u524d\u666f\uff08\u56fe6\uff09\u3002
\n \"\"
\n \u56fe6 \u5404\u79cdMOF\u884d\u751f\u7684MxPy\/CMs\u7684\u5408\u6210\u7b56\u7565
\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4e0a\u8ff0MOF\u884d\u751f\u7684CMs\u5408\u6210\u7b56\u7565\u662f\u6d89\u53caMOF\u524d\u4f53\u7684\u9009\u62e9\u6027\u5236\u5907\u548cMOF\u57fa\u524d\u4f53\/\u6a21\u677f\u7ecf\u8fc7\u4e00\u7cfb\u5217\u540e\u5904\u7406\uff08\u4f8b\u5982\u78b3\u5316\u3001\u8868\u9762\u4fee\u9970\u548c\u5316\u5b66\u6539\u6027\uff09\u7684\u8f6c\u5316\uff0c\u4ee5\u5b9e\u73b0\u9ad8\u5b54\u9699\u7387\u3001\u9ad8\u5bfc\u7535\u7f51\u7edc\u3001\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u591a\u6837\u5316\u7684\u7ed3\u6784\u7279\u5f81\u3002\u5c24\u5176\u662f\u5728\u7ec4\u5206\u8c03\u63a7\u3001\u5f62\u8c8c\u63a7\u5236\u548c\u7ed3\u6784\u5de5\u7a0b\u65b9\u9762\u7684\u4e0a\u8ff0\u5408\u6210\u7b56\u7565\u4e3a\u5148\u8fdb\u7684MOF\u884d\u751f\u7684CMs\u5728\u80fd\u6e90\u76f8\u5173\u7684\u5e94\u7528\u4e2d\u5e26\u6765\u4e86\u96be\u4ee5\u60f3\u8c61\u7684\u673a\u4f1a\u3002
\n 2. MOF\u884d\u751f\u78b3\u57fa\u6750\u6599\u5728\u80fd\u6e90\u76f8\u5173\u9886\u57df\u4e2d\u7684\u5e94\u7528
\n \u5982\u4e0a\u8ff0\u6240\u8ff0\uff0c\u901a\u8fc7\u4e0d\u540c\u5408\u6210\u7b56\u7565\u83b7\u5f97\u7684MOF\u884d\u751f\u7684CMs\u8d4b\u4e88\u9ad8\u5bfc\u7535\u6027\u3001\u826f\u597d\u7684\u6da6\u6e7f\u6027\u3001\u5145\u8db3\u7684\u6d3b\u6027\u4f4d\u70b9\u3001\u5feb\u901f\u7684\u7535\u5b50\/\u79bb\u5b50\u8f6c\u79fb\u4ee5\u53ca\u9ad8\u7684\u6574\u4f53\u7a33\u5b9a\u6027\u7684\u591a\u91cd\u4f18\u52bf\uff0c\u6210\u4e3a\u66ff\u4ee3\u5546\u4e1a\u5316\u7684\u6d3b\u6027\u78b3\u7684\u73af\u5883\u53cb\u597d\u7684\u7535\u6781\u6750\u6599\u6216\u50ac\u5316\u5242\u3002\u672c\u8282\u5c06\u8ba8\u8bba\u5229\u7528\u7eb3\u7c73\u7ed3\u6784\u7684MOF\u884d\u751f\u7684CMs\u5728\u7535\u5316\u5b66\u8f6c\u5316\u4e0e\u50a8\u5b58\u7b49\u65b9\u9762\u7684\u5e94\u7528
\n 2.1 \u7535\u5316\u5b66\u50a8\u80fd\uff08EES\uff09\u5e94\u7528
\n \u5728EES\u7cfb\u7edf\u4e2d\uff0c\u5177\u6709\u72ec\u7279\u5fae\u7ed3\u6784\u7684\u7535\u6781\u6750\u6599\u51b3\u5b9a\u4e86\u79bb\u5b50\/\u7535\u5b50\u7684\u4f20\u9012\u9014\u5f84\u3001\u6d3b\u6027\u4f4d\u70b9\u7684\u6570\u91cf\u548c\u5206\u5e03\u4ee5\u53ca\u6750\u6599\u7684\u7a33\u5b9a\u6027\uff0c\u5728\u65b0\u578b\u50a8\u80fd\u9886\u57df\u5177\u6709\u81f3\u5173\u91cd\u8981\u7684\u5730\u4f4d\u3002\u76ee\u524d\uff0c\u901a\u8fc7\u5408\u7406\u7684\u8bbe\u8ba1\u548c\u8c03\u63a7\uff0cMOFs\u884d\u751f\u7684\u78b3\u590d\u5408\u6750\u6599\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\uff08SCs\uff09\u3001\u950c\u79bb\u5b50\u7535\u6c60\uff08ZIBs\uff09\u3001\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u548c\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u7b49\u50a8\u80fd\u9886\u57df\u5177\u6709\u5f88\u5927\u7684\u5e94\u7528\u6f5c\u529b\uff08\u56fe7\u548c\u56fe8\uff09\u3002
\n \"\"
\n \u56fe7. \u5404\u79cdMOF\u884d\u751f\u7684CMs\u5728SCs\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002
\n \"\"
\n \u56fe8. \u5404\u79cdMOF\u884d\u751f\u7684CMs\u5728LSBs\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002
\n 2.2 \u7535\u5316\u5b66\u80fd\u6e90\u8f6c\u6362\uff08EEC\uff09\u5e94\u7528
\n \u9ad8\u6548\u5408\u7406\u7684\u7535\u50ac\u5316\u5242\u662f\u964d\u4f4e\u80fd\u91cf\u58c1\u5792\u548c\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u7684\u8feb\u5207\u8981\u6c42\uff0c\u5bf9EEC\u88c5\u7f6e\u7684\u5b9e\u9645\u5e94\u7528\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002MOF\u884d\u751f\u7684CMs\u5177\u6709\u4e30\u5bcc\u7684\u591a\u5b54\u7ed3\u6784\u3001\u4e30\u5bcc\u7684\u6d3b\u6027\u6210\u5206\u3001\u4f18\u5f02\u7684\u5bfc\u7535\u6027\u548c\u673a\u68b0\u5f3a\u5ea6\u7b49\u4f18\u70b9\uff0c\u5df2\u88ab\u8bc1\u660e\u662fEEC\u9886\u57df\uff08\u5982ORR\u3001OER\u3001HER\u3001CO2RR\u3001NRR\uff09\u7684\u4f18\u5f02\u6d3b\u6027\u6750\u6599\uff08\u56fe9\u548c\u56fe10\uff09\u3002
\n \"\"
\n \u56fe9. \u5404\u79cdMOF\u884d\u751f\u7684CMs\u5728ORR\/OER\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002
\n \"\"
\n \u56fe10. \u5404\u79cdMOF\u884d\u751f\u7684CMs\u5728CO2RR\u548cNRR\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002
\n 2.3 \u73af\u5883\u53ef\u6301\u7eed\u6027\u5e94\u7528
\n \u5de5\u4e1a\u5e9f\u6c34\u548c\u5316\u77f3\u71c3\u6599\u71c3\u70e7\u7b49\u5404\u79cd\u6765\u6e90\u4ea7\u751f\u7684\u6c61\u67d3\u7269\u5df2\u6210\u4e3a\u4e00\u4e2a\u7d27\u8feb\u7684\u73af\u5883\u95ee\u9898\u3002MOF\u884d\u751f\u7684CMs\u56e0\u5176\u56fa\u6709\u529f\u80fd\u5316\u7ed3\u6784\u548c\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5728\u89e3\u51b3\u65e5\u76ca\u7d27\u8feb\u7684\u73af\u5883\u5371\u673a\u4e2d\u4e5f\u5f97\u5230\u4e86\u8fc5\u901f\u53d1\u5c55\uff0c\u5c24\u5176\u662f\u5728\u901a\u8fc7\u9ad8\u6548\u5438\u9644\u548c\u50ac\u5316\u964d\u89e3\u6709\u673a\u6c61\u67d3\u7269\u548c\u91cd\u91d1\u5c5e\u7b49\u65b9\u9762\u53d1\u6325\u4e86\u4e3e\u8db3\u8f7b\u91cd\u7684\u6f5c\u529b\uff0c\u4ece\u800c\u5229\u4e8e\u5e9f\u6c34\u51c0\u5316\u548c\u73af\u5883\u4fee\u590d\uff08\u56fe11\uff09\u3002
\n \"\"
\n \u56fe11. \u5404\u79cdMOF\u884d\u751f\u7684CMs\u5728\u73af\u5883\u53ef\u6301\u7eed\u6027\u9886\u57df\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002
\n \u4ee5\u4e0a\u63d0\u53ca\u7684\u4e0d\u540c\u7ec4\u5206\u548c\u7ed3\u6784\u7684MOF\u884d\u751f\u7684CMs\u5728\u80fd\u6e90\u76f8\u5173\u7684\u5e94\u7528\u4e2d\u5747\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u5176\u4e2d\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u7b49\u7ea7\u5b54\u9053\u7ed3\u6784\u548c\u91d1\u5c5e\/\u975e\u91d1\u5c5e\u63ba\u6742\u80fd\u591f\u63d0\u4f9b\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u663e\u8457\u63d0\u5347\u7535\u8377\u4f20\u8f93\u6548\u7387\u548c\u50ac\u5316\u6d3b\u6027\uff0c\u8d4b\u4e88\u6750\u6599\u9ad8\u5bb9\u91cf\u3001\u9ad8\u500d\u7387\u6027\u80fd\u53ca\u4f18\u5f02\u7684\u50ac\u5316\u53cd\u5e94\u9009\u62e9\u6027\u3002
\n \u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011
\n \u672c\u6587\u7efc\u8ff0\u4e86\u8fd1\u4e94\u5e74\u6765MOF\u884d\u751f\u7684CMs\u5728\u80fd\u6e90\u76f8\u5173\u7684\u5e94\u7528\u4e2d\u7ed3\u6784\u529f\u80fd\u4f18\u5316\u8bbe\u8ba1\u548c\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u6211\u4eec\u8be6\u7ec6\u5730\u63cf\u8ff0\u4e86\u7531MOF\u524d\u9a71\u4f53\u901a\u8fc7\u5404\u79cd\u53ef\u63a7\u7684\u5408\u6210\u7b56\u7565\u6765\u5236\u5907\u4e0d\u540c\u529f\u80fd\u5316\u7684\u591a\u5b54CMs\u3002\u800c\u4e14\uff0c\u901a\u8fc7\u7ed3\u6784\u4e0e\u56fa\u6709\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u7ee7\u7eed\u63a2\u7d22\u4e86\u8fd9\u4e9bCMs\u5728\u80fd\u6e90\u76f8\u5173\u9886\u57df\u4e2d\u7684\u5177\u6709\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u63a8\u52a8\u4e86\u5176\u5728\u672a\u6765\u53ef\u6301\u7eed\u65b0\u80fd\u6e90\u6280\u672f\u7684\u53d1\u5c55\u548c\u521b\u65b0\u3002\u867d\u7136MOF\u884d\u751f\u7684CMs\u5728\u7535\u6c60\u548c\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u53d6\u5f97\u4e86\u91cd\u5927\u8fdb\u5c55\uff0c\u4f46\u5728\u672a\u6765\u7684\u7814\u7a76\u4e2d\u4ecd\u9700\u8981\u63a2\u7d22\u548c\u89e3\u51b3\u4e00\u4e9b\u672a\u63a2\u7d22\u7684\u673a\u9047\u548c\u6311\u6218\uff0c\u4f8b\u5982\u8bbe\u8ba1\u548c\u5f00\u53d1\u65b0\u578bMOF\u7ed3\u6784\u548c\u5176\u884d\u751f\u7684CMs\uff0c\u6df1\u5165\u7814\u7a76\u5176\u5728\u7535\u6c60\u548c\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u5e94\u7528\uff1b\u5176\u6b21\uff0c\u4f18\u5316\u7684\u5236\u5907\u7b56\u7565\u3001\u7406\u6e05\u7ed3\u6784\u53cd\u5e94\u673a\u7406\u3001\u53d1\u6325\u534f\u540c\u591a\u529f\u80fd\u6027\u80fd\u548c\u4e2d\u8bd5\u653e\u5927\u6548\u5e94\u7b49\u6311\u6218\u63a8\u52a8\u5176\u8fdb\u4e00\u6b65\u53d1\u5c55\u548c\u5728\u66f4\u591a\u9886\u57df\u7684\u5b9e\u9645\u5e94\u7528\uff08\u56fe12\uff09\u3002
\n \"\"
\n \u56fe12. MOF\u884d\u751f\u7684CMs\u5728\u672a\u6765\u9762\u4e34\u4e3b\u8981\u7684\u6311\u6218\u3002<\/p>\n

\u6587\u732e\u4fe1\u606f
\n Lulu Chai, Rui Li, Yanzhi Sun, Kun Zhou*, and Junqing Pan*, MOF-derived carbon-based materials for energy-related applications, Adv. Mater., 2025, DOI: 10.1002\/adma.202413658
\n https:\/\/doi.org\/10.1002\/adma.202413658<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08Metal-Organic Frameworks\uff0cMOFs\uff09\u4ee5\u5176\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u9ad8\u5b54\u9699\u7387\u3001\u4f18\u5f02\u5316\u5b66\u7269\u7406\u6027\u8d28\u548c\u70ed\u7a33\u5b9a\u6027\u5df2\u6210\u4e3a\u6784\u5efa\u65b0\u578b\u7eb3…<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-264337","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/264337"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=264337"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/264337\/revisions"}],"predecessor-version":[{"id":264351,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/264337\/revisions\/264351"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=264337"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=264337"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=264337"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}