{"id":264075,"date":"2024-12-23T08:14:37","date_gmt":"2024-12-23T00:14:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=264075"},"modified":"2024-12-22T22:19:28","modified_gmt":"2024-12-22T14:19:28","slug":"%e8%bd%ac%e5%8c%96%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e5%b1%82%e7%8a%b6%e6%b0%a7%e5%8c%96%e7%89%a9%e6%ae%8b%e7%a2%b1%e4%b8%ba%e8%a1%a5%e9%92%a0%e5%89%82%e5%90%8c%e6%97%b6%e7%a8%b3%e5%ae%9a","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=264075","title":{"rendered":"\u8f6c\u5316\u94a0\u79bb\u5b50\u7535\u6c60\u5c42\u72b6\u6c27\u5316\u7269\u6b8b\u78b1\u4e3a\u8865\u94a0\u5242\u540c\u65f6\u7a33\u5b9a\u5176\u6676\u683c\u7684\u5bcc\u94a0\u6d46\u6599\u6dfb\u52a0\u5242"},"content":{"rendered":"<p>\u65e0\u9700\u9884\u5904\u7406\uff0c\u6d46\u6599\u4e2d\u539f\u4f4d\u8f6c\u5316\u8868\u9762\u6b8b\u78b1\u4e3a\u8865\u94a0\u6dfb\u52a0\u5242<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-264077\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72471-21.png\" alt=\"\" width=\"670\" height=\"261\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72471-21.png 670w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72471-21-300x117.png 300w\" sizes=\"(max-width: 670px) 100vw, 670px\" \/>\u00a0\u00a0\u00a0<\/p>\n<p><strong><b>\u3010\u6587\u7ae0\u4fe1\u606f\u3011<\/b><\/strong><\/p>\n<p>\u8f6c\u5316\u94a0\u79bb\u5b50\u7535\u6c60\u5c42\u72b6\u6c27\u5316\u7269\u6b8b\u78b1\u4e3a\u8865\u94a0\u5242\u540c\u65f6\u7a33\u5b9a\u5176\u6676\u683c\u7684\u5bcc\u94a0\u6d46\u6599\u6dfb\u52a0\u5242<\/p>\n<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u8d75\u5f66\u7855<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u5218\u7426<\/p>\n<p>\u5355\u4f4d\uff1a\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6750\u6599\u5b66\u9662<\/p>\n<p><strong><b>\u3010\u7814\u7a76\u80cc\u666f\u3011<\/b><\/strong><\/p>\n<p>\u94a0\u79bb\u5b50\u7535\u6c60\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u548c\u4f4e\u901f\u7535\u52a8\u6c7d\u8f66\u9886\u57df\u5177\u6709\u5de8\u5927\u7684\u53d1\u5c55\u6f5c\u529b\u548c\u5e7f\u9614\u7684\u5e02\u573a\u524d\u666f\u3002O3\u578b\u5c42\u72b6\u6c27\u5316\u7269\u9634\u6781\u548c\u786c\u78b3\uff08HC\uff09\u9633\u6781\u662f\u6700\u6709\u5e0c\u671b\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u5019\u9009\u6750\u6599\uff0c\u800c\u6c27\u5316\u7269\u9634\u6781\u7684\u8868\u9762\u7ed3\u6784\u7a33\u5b9a\u6027\u5dee\u3001\u78b1\u6027\u5f3a\uff0c\u4ee5\u53caHC\u9633\u6781\u7684\u521d\u59cb\u5e93\u4ed1\u6548\u7387\u8f83\u4f4e\uff0c\u963b\u788d\u4e86\u5176\u5927\u89c4\u6a21\u5e94\u7528\u3002\u8be5\u6587\u7ae0\u805a\u7126\u94a0\u79bb\u5b50\u7535\u6c60\u5c42\u72b6\u6c27\u5316\u7269\u7684\u7a7a\u6c14\u7a33\u5b9a\u6027\uff0c\u6307\u51fa\u79d1\u5b66\u7814\u7a76\u4e2d\u5c06\u6750\u6599\u5b58\u4e8e\u624b\u5957\u7bb1\u4e2d\u7684\u7f3a\u70b9\u4ee5\u53ca\u5e38\u7528\u591a\u6b65\u6539\u8fdb\u65b9\u6cd5\u7684\u5f0a\u7aef\uff0c\u521b\u65b0\u6027\u63d0\u51fa\u4e00\u79cd\u6d46\u6599\u6dfb\u52a0\u5242\u3002\u8be5\u6587\u4e3a\u5c42\u72b6\u6c27\u5316\u7269\u7684\u8868\u9762\u78b1\u6027\u7269\u8d28\u5904\u7406\uff0c\u5168\u7535\u6c60\u7684\u8865\u94a0\u624b\u6bb5\uff0c\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u5355\u3001\u9ad8\u6548\u7684\u7b56\u7565\uff0c\u6709\u52a9\u4e8e\u52a0\u901f\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u7814\u7a76\u548c\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n<p><strong><b>\u3010\u6587\u7ae0\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6750\u6599\u5b66\u9662\u5434\u950b\u9662\u58eb\u56e2\u961f\u5218\u7426\u526f\u6559\u6388\u8bfe\u9898\u7ec4\uff0c\u5728Journal of Power Source\u4e0a\u53d1\u8868\u9898\u4e3a\u201cNa-rich Additive Converting Residual Alkali into Sodium Compensation and Stabilizing Lattice of O3-type Layered Oxides Cathode for Sodium-ion Full Cells\u201d\u7684\u7814\u7a76\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u9634\u6781\u6d46\u6599\u6dfb\u52a0\u5242\uff0c\u8be5\u6dfb\u52a0\u5242\u53ef\u5728\u6d46\u6599\u5236\u5907\u4e2d\u5c06 NaNi<sub>1\/3<\/sub>Fe<sub>1\/3<\/sub>Mn<sub>1\/3<\/sub>O<sub>2<\/sub>\uff08NFM\uff09 \u9634\u6781\u4e0a\u7684\u78b1\u6027\u7269\u8d28\u539f\u4f4d\u4e00\u6b65\u8f6c\u5316\u4e3a\u7535\u5316\u5b66\u6d3b\u6027\u7684\u542b Na<sup>+<\/sup>\u00a0\u5316\u5408\u7269\uff0c\u7528\u4e8e\u94a0\u7f3a\u4e4f\u7684\u786c\u78b3\u9633\u6781\uff0c\u540c\u65f6\u91cd\u6784\u7a33\u5b9a\u7684 NFM \u8868\u9762\u6676\u683c\uff0c\u5b9e\u73b0\u4e86\u9ad8\u80fd\u91cf\u5bc6\u5ea6 NFM || HC \u5168\u7535\u6c60\u7684\u957f\u671f\u7a33\u5b9a\u5faa\u73af\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-264078\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72472-20.png\" alt=\"\" width=\"1269\" height=\"714\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72472-20.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72472-20-300x169.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72472-20-768x432.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72472-20-1024x576.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p><strong><b>\u3010\u672c\u6587\u8981\u70b9\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u8981\u70b9\u4e00\uff1a<\/b><\/strong>\u00a0\u6291\u5236\u51dd\u80f6\u5316-\u6d46\u6599\u6dfb\u52a0\u5242\u5bf9\u6d46\u6599\u7684\u7a33\u5b9a\u4f5c\u7528<\/p>\n<p>\u5f53 NFM \u76f4\u63a5\u4e0e PVDF \u7c98\u5408\u5242\u3001\u51dd\u80f6\u548c N \u7532\u57fa\u5421\u54af\u70f7\u916e\uff08NMP\uff09\u6df7\u5408\u5f62\u6210\u6d46\u6599\u65f6\uff0c\u5f80\u5f80\u4f1a\u53d1\u751f\u6d46\u6599\u51dd\u80f6\u5316\uff0c\u5982\u56fe 1g\uff081 \u548c 2\uff09\u6240\u793a\u3002\u800c\u5728\u6d46\u6599\u4e2d\u53ea\u6dfb\u52a0 0.5% \u7684\u6d46\u6599\u6dfb\u52a0\u5242-\u8349\u9178\u6c22\u94a0\uff08NHC\uff09\u5c31\u80fd\u5f97\u5230\u7a33\u5b9a\u7684\u9634\u6781\u677f\uff08\u56fe 1g\u30013 \u548c 4\uff09\u3002\u56e0\u6b64\uff0c\u5728\u6d46\u6599\u4e2d\u52a0\u5165 0.5% \u7684 NHC \u53ef\u9632\u6b62\u7c98\u5408\u5242 PVDF \u7684\u8131\u6c22\u6c1f\u5316\uff0c\u8fd9\u8868\u660e\u6d46\u6599\u7684\u6574\u4f53\u78b1\u5ea6\u56e0\u8def\u6613\u65af\u9178\u78b1\u4e2d\u548c\u800c\u964d\u4f4e\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-264079\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72473-20.png\" alt=\"\" width=\"1236\" height=\"693\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72473-20.png 1236w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72473-20-300x168.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72473-20-768x431.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72473-20-1024x574.png 1024w\" sizes=\"(max-width: 1236px) 100vw, 1236px\" \/><\/p>\n<p><strong><b>\u8981\u70b9\u4e8c\uff1a<\/b><\/strong>\u00a0\u727a\u7272\u578b\u8865\u94a0\u5242-\u5bf9\u786c\u78b3\u8d1f\u6781\u7684\u8865\u94a0\u4f5c\u7528<\/p>\n<p>HC \u7535\u6781\u7684\u521d\u59cb\u653e\u7535\u5bb9\u91cf\u4e3a 422.8 mAh\/g\uff0c\u968f\u540e\u5728 0.01 \u81f3 3.0 V \u4e4b\u95f4\u7684\u5145\u7535\u5bb9\u91cf\u4e3a 307.3 mAh\/g\uff0c\u76f8\u5f53\u4e8e 72.7 % \u7684 ICE\u3002\u8fd9\u610f\u5473\u7740\u5728\u78b3\u6c22\u5316\u5408\u7269\u9633\u6781\u4e0a\u5f62\u6210\u7684 SEI \u5c06\u4e0d\u53ef\u9006\u8f6c\u5730\u6d88\u8017 27.3% \u7684 Na+ \u4f5c\u4e3a\u9634\u6781\uff0c\u4ece\u800c\u5bfc\u81f4\u80fd\u91cf\u5bc6\u5ea6\u4e0b\u964d\uff0c\u5168\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u6076\u5316\u3002\u4e3a\u907f\u514d\u8fd9\u4e00\u95ee\u9898\uff0c\u5728 NFM \u9634\u6781\u4e2d\u6dfb\u52a0 5% \u7684 NHC\uff0c\u4ee5\u8865\u5145 HC \u9633\u6781\u5168\u7535\u6c60\u4e0d\u53ef\u9006\u7684\u94a0\u6d88\u8017\u3002\u5982\u56fe 2f \u6240\u793a\uff0c\u6dfb\u52a0 5% NHC \u7684\u5168\u7535\u6c60\u5bb9\u91cf\u660e\u663e\u589e\u52a0\uff0c\u5faa\u73af\u7a33\u5b9a\u6027\u4e0e\u6dfb\u52a0 0.5% NHC \u7684\u5168\u7535\u6c60\u76f8\u4f3c\u3002\u800c\u4e14\uff0c\u4ece\u56fe 2g \u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u5168\u7535\u6c60\u5728 10 C \u65f6\u4ecd\u7136\u6709\u66f4\u597d\u7684\u5bb9\u91cf\u53d1\u6325\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-264080\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72474-20.png\" alt=\"\" width=\"1149\" height=\"951\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72474-20.png 1149w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72474-20-300x248.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72474-20-768x636.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72474-20-1024x848.png 1024w\" sizes=\"(max-width: 1149px) 100vw, 1149px\" \/><\/p>\n<p><strong><b>\u8981\u70b9\u4e09\uff1a<\/b><\/strong>\u00a0\u9634\u6781\u8868\u9762\u4fdd\u62a4\u5c42-\u6291\u5236\u8868\u9762\u6676\u683c\u52a3\u5316\uff0c\u4fdd\u6301\u5feb\u901f\u79bb\u5b50\u8131\u5d4c<\/p>\n<p>\u53ef\u4ee5\u6e05\u695a\u5730\u770b\u5230\uff0c\u6750\u6599\u7684\u4f53\u76f8\u90e8\u5206\u90fd\u662f\u5178\u578b\u7684 O3 \u578b\u5c42\u72b6\u7ed3\u6784\uff0c\u7ecf FFT \u6a21\u5f0f\u6821\u51c6\u7684\u884d\u5c04\u56fe\u6837\u7684\u6676\u4f53\u5b66\u95f4\u8ddd\u5206\u522b\u5bf9\u5e94\u4e8e (012)\/(104) \u548c (012)\/(006) \uff0c\u4f46\u6750\u6599\u8868\u9762\u7684\u60c5\u51b5\u5e76\u975e\u5982\u6b64\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u5f53 NHC \u7684\u6dfb\u52a0\u91cf\u4e3a 0.5%\u65f6\uff0c\u8868\u9762\u7531\u8f83\u8584\u7684\u65e0\u5b9a\u5f62\u533a\u57df\uff08\u9ec4\u9ed1\u865a\u7ebf\u4e4b\u95f4\uff09\u548c\u6676\u683c\u7578\u53d8\u533a\u57df\uff08II\uff09\u7ec4\u6210\u3002\u7531\u4e8e\u6781\u5c11\u91cf\u7684 NHC \u4ec5\u80fd\u786e\u4fdd\u9634\u6781\u6d46\u6db2\u4e0d\u4f1a\u51dd\u80f6\uff0c\u56e0\u6b64\u8fd9\u79cd\u8f83\u8584\u7684\u65e0\u5b9a\u5f62\u533a\u57df\u88ab\u89c6\u4e3a\u9634\u6781\u7535\u89e3\u8d28\u754c\u9762\uff08CEI\uff09\u3002\u800c\u6676\u683c\u7578\u53d8\u533a\u57df\u7684\u5fae\u5f31\u5feb\u901f\u5085\u7acb\u53f6\u53d8\u6362\uff08FFT\uff09\u6591\u70b9\u6e05\u695a\u5730\u8868\u660e\uff0c\u5c42\u72b6\u7ed3\u6784\u5728\u9760\u8fd1\u6750\u6599\u8fb9\u7f18\u6216\u8868\u9762\u7684\u533a\u57df\u53d1\u751f\u4e86\u574d\u584c\u6216\u53d8\u5316\u3002\u6dfb\u52a0\u4e86 5% NHC \u7684\u8868\u9762\u5177\u6709\u5e73\u5747\u539a\u5ea6\u7ea6\u4e3a 6 nm \u7684\u65e0\u5b9a\u5f62\u533a\u57df\uff0c\u8fd9\u4e9b\u533a\u57df\u7d27\u90bb\u6676\u683c\u5b8c\u6574\u7684\u5c42\u72b6\u7ed3\u6784\uff0c\u8868\u660e NHC \u5728\u53bb\u9664\u8868\u9762\u6b8b\u78b1\u5e76\u5b9e\u73b0\u94a0\u8865\u5145\u540e\u4ea7\u751f\u4e86\u4fdd\u62a4\u5c42\u3002\u8be5\u65e0\u5b9a\u5f62\u5c42\u539a\u5ea6\u9002\u4e2d\uff0c\u53ef\u6291\u5236\u8868\u9762\u6676\u683c\u91cd\u5851\uff0c\u4ece\u800c\u5728\u6750\u6599\u8868\u9762\u5f62\u6210\u5feb\u901f\u7684\u94a0\u79bb\u5b50\u52a8\u529b\u5b66<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-264081\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72475-18.png\" alt=\"\" width=\"1006\" height=\"497\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72475-18.png 1006w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72475-18-300x148.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/\u56fe\u72475-18-768x379.png 768w\" sizes=\"(max-width: 1006px) 100vw, 1006px\" \/><\/p>\n<p><strong><b>\u3010\u6587\u7ae0\u94fe\u63a5\u3011<\/b><\/strong><\/p>\n<p>\u201cNa-rich Additive Converting Residual Alkali into Sodium Compensation and Stabilizing Lattice of O3-type Layered Oxides Cathode for Sodium-ion Full 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