{"id":263842,"date":"2024-12-14T07:40:42","date_gmt":"2024-12-13T23:40:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=263842"},"modified":"2024-12-13T22:42:08","modified_gmt":"2024-12-13T14:42:08","slug":"%e4%b8%ad%e5%9b%bd%e7%a7%91%e5%ad%a6%e9%99%a2%e9%9d%92%e5%b2%9b%e7%94%9f%e7%89%a9%e8%83%bd%e6%ba%90%e4%b8%8e%e8%bf%87%e7%a8%8b%e7%a0%94%e7%a9%b6%e6%89%80valentin-valtchev%e7%a0%94%e7%a9%b6%e5%91%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=263842","title":{"rendered":"\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u5c9b\u751f\u7269\u80fd\u6e90\u4e0e\u8fc7\u7a0b\u7814\u7a76\u6240Valentin Valtchev\u7814\u7a76\u5458\u548c\u5362\u9e4f\u526f\u7814\u7a76\u5458\u56e2\u961fNature\uff1a\u9996\u4f8b\u7ed3\u6784\u7a33\u5b9a\u7684\u672c\u5f81\u4ecb\u5b54\u6cb8\u77f3\u5206\u5b50\u7b5b"},"content":{"rendered":"

\u00a0<\/b><\/strong><\/p>\n

\u6cb8\u77f3\u5206\u5b50\u7b5b\u662f\u4e00\u79cd\u5fae\u5b54\u7ed3\u6676\u6750\u6599\uff0c\u5728\u5de5\u4e1a\u9886\u57df\u53ef\u7528\u4f5c\u79bb\u5b50\u4ea4\u6362\u5242\u3001\u5438\u9644\u5242\u548c\u975e\u5747\u76f8\u50ac\u5316\u5242\u3002\u7136\u800c\uff0c\u5206\u5b50\u7b5b\u4e2d\u7684\u672c\u5f81\u5fae\u5b54\u5c3a\u5bf8\u901a\u5e38\u5c0f\u4e8e1\u7eb3\u7c73\uff0c\u8fd9\u963b\u788d\u4e86\u5176\u5728\u6d89\u53ca\u5927\u5206\u5b50\u5904\u7406\u8fc7\u7a0b\u4e2d\u7684\u5e94\u7528\u3002\u5728\u5206\u5b50\u7b5b\u4e2d\u5f15\u5165\u975e\u672c\u5f81\u4ecb\u5b54\uff08\u6676\u95f4\/\u6676\u5185\u4ecb\u5b54\uff09\u662f\u514b\u670d\u6269\u6563\u9650\u5236\u7684\u6709\u6548\u65b9\u6cd5\uff0c\u4f46\u5f15\u5165\u7684\u975e\u672c\u5f81\u4ecb\u5b54\u901a\u5e38\u7f3a\u5c11\u957f\u7a0b\u6709\u5e8f\u6027\uff0c\u968f\u4e4b\u800c\u6765\u7684\u95ee\u9898\u662f\u5b54\u5f84\u4e0d\u5747\u4e00\u3001\u8868\u9762\u9178\u6027\u53d7\u635f\u3001\u7ed3\u6676\u5ea6\u4e0b\u964d\u3002\u56e0\u6b64\uff0c\u7814\u7a76\u8005\u671f\u671b\u5f00\u53d1\u51fa\u5177\u6709\u5747\u4e00\u5b54\u9053\u4e14\u6c34\u70ed\u7a33\u5b9a\u6027\u9ad8\u7684\u3001\u672c\u5f81\u4ecb\u5b54\u4e0e\u5fae\u5b54\u4ee5\u539f\u5b50\u5f62\u5f0f\u76f8\u8fde\u63a5\u7684\u5206\u5b50\u7b5b\uff0c\u8fd9\u91cc\u79f0\u4e3a\u7ed3\u6676\u672c\u5f81\u4ecb\u5b54\u5206\u5b50\u7b5b\u3002<\/p>\n

Green Carbon\u4e3b\u7f16\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u5c9b\u751f\u7269\u80fd\u6e90\u4e0e\u8fc7\u7a0b\u7814\u7a76\u6240Valentin Valtchev\u7814\u7a76\u5458\u548c\u5362\u9e4f\u526f\u7814\u7a76\u5458<\/b><\/strong>\u56e2\u961f\u8fd1\u671f\u5728Nature<\/i><\/em>\u671f\u520a\u53d1\u8868\u9898\u4e3a\u201cA stable zeolite with atomically ordered and interconnected mesopore channel\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u7814\u7a76\u6210\u529f\u5408\u6210\u4e86\u4e16\u754c\u9996\u4f8b\u65b0\u578b\u4ecb\u5b54\u6cb8\u77f3\u5206\u5b50\u7b5b\u6750\u6599-\u201c\u9752\u5c9b\u80fd\u6e90\u6240\u5206\u5b50\u7b5b\u6750\u65991\u53f7\u201d\uff08ZMQ-1\uff09\uff0c\u5e76\u5b9a\u4e49\u4e3a\u672c\u5f81\u4ecb\u5b54\u6cb8\u77f3\u5206\u5b50\u7b5b\u3002\u8be5\u65b0\u578b\u6cb8\u77f3\u5206\u5b50\u7b5b\u542b\u670928\u00d710\u00d710\u5143\u73af\u7ec4\u6210\u7684\u4e09\u7ef4\u5b54\u9053\u7cfb\u7edf\uff0c\u5176\u4e2d28\u5143\u73af\u6700\u5927\u5c3a\u5bf8\u4e3a2.28\u7eb3\u7c73\uff0c\u8fbe\u5230\u4ecb\u5b54\u5c3a\u5bf8\u8303\u7574\u3002\u5b83\u4e0d\u4ec5\u62e5\u6709\u5747\u4e00\u7684\u5b54\u9053\u7ed3\u6784\uff0c\u66f4\u5177\u6709\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u6c34\u70ed\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u5176\u7ed3\u6784\u4e2d\u7684\u94dd\u539f\u5b50\u4e5f\u4e3a\u50ac\u5316\u53cd\u5e94\u63d0\u4f9b\u4e86\u5f3a\u5927\u7684\u52a8\u529b\u3002\u5c06\u8be5\u65b0\u578b\u6cb8\u77f3\u5206\u5b50\u7b5b\u5e94\u7528\u4e8e\u91cd\u6cb9\u50ac\u5316\u88c2\u5316\u53cd\u5e94\uff0c\u4e0e\u73b0\u6709\u5546\u4e1a\u5316\u6cb8\u77f3\u5206\u5b50\u7b5b\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u5b9e\u73b0\u4e86\u66f4\u9ad8\u7684\u8f7b\u8d28\u6cb9\u54c1\u9009\u62e9\u6027\uff0c\u4e14\u79ef\u78b3\u66f4\u4f4e\u3002<\/p>\n

\u7814\u7a76\u5185\u5bb9<\/b><\/strong><\/p>\n

ZMQ-1\u5206\u5b50\u7b5b\u7684\u5408\u6210\u548c\u62d3\u6251\u7ed3\u6784<\/b><\/strong><\/p>\n

\u79d1\u7814\u56e2\u961f\u521b\u9020\u6027\u7684\u5c06\u53cc\u5b63\u78f7\u9633\u79bb\u5b50\uff08bis-1,8(tricyclohexyl phosphonium) octamethylene\uff0cTri-Cy-dC8\uff09\u4f5c\u4e3a\u6709\u673a\u7ed3\u6784\u5bfc\u5411\u5242\u548c\u6a21\u677f\u5242\uff0c\u5229\u7528\u7ed3\u6784\u5bfc\u5411\u4f5c\u7528\u548c\u7a7a\u95f4\u586b\u5145\u53cc\u91cd\u4f5c\u7528\uff0c\u9996\u6b21\u5b9e\u73b0\u4e86\u672c\u5f81\u4ecb\u5b54\u4e0e\u5fae\u5b54\u5728\u539f\u5b50\u5c42\u9762\u7684\u5b8c\u7f8e\u8fde\u63a5\uff0c\u5408\u6210\u4e86\u7ed3\u6784\u7a33\u5b9a\u7684\u672c\u5f81\u4ecb\u5b54\u6cb8\u77f3\u5206\u5b50\u7b5b\u3002ZMQ-1\u5206\u5b50\u7b5b\u6700\u521d\u662f\u5728\u78b1\u4f53\u7cfb\u4e2d\uff0c180 \u2103\u4e0b\u6210\u529f\u5408\u6210\u5f97\u5230\uff0c\u5728190 \u2103\u52a0\u901f\u4e86ZMQ-1\u5206\u5b50\u7b5b\u7684\u6676\u5316\uff1b\u5176\u9aa8\u67b6\u7845\/\u94dd\u6469\u5c14\u6bd4\u53ef\u5728\u8f83\u5bbd\u7684\u8303\u56f4\u5185\u8fdb\u884c\u8c03\u8282\uff08\u7ea615-70\uff09\uff1b\u5728\u4e0d\u540c\u7845\u6e90\u3001\u94dd\u6e90\u53ca\u51dd\u80f6\u914d\u6bd4\u4e0b\u5747\u53ef\u5408\u6210\uff0c\u8bc1\u660e\u672c\u5de5\u4f5c\u5f00\u53d1\u7684\u5408\u6210\u65b9\u6cd5\u5177\u6709\u9ad8\u7684\u53ef\u91cd\u590d\u6027\uff0c\u8fd9\u4e3a\u540e\u7eed\u7684\u5de5\u4e1a\u5316\u653e\u5927\u751f\u4ea7\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002\u6c1f\u4f53\u7cfb\u4e0b\u5408\u6210\u9700\u66f4\u957f\u7684\u6676\u5316\u65f6\u95f4\uff0c\u78b1\u4f53\u7cfb\u548c\u6c1f\u4f53\u7cfb\u4e2d\u5408\u6210\u7684\u6676\u4f53\u5f62\u8c8c\u5206\u522b\u4e3a\u72ec\u7acb\u548c\u805a\u96c6\u7684\u56db\u68f1\u67f1\uff0c\u6700\u5927\u5c3a\u5bf8\u7ea62 \u03bcm\uff08\u56fe1\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1 ZMQ-1\u5206\u5b50\u7b5b\u7684\u5f62\u8c8c<\/p>\n

 <\/p>\n

\u9274\u4e8e\u8be5\u5206\u5b50\u7b5b\u6676\u4f53\u5c3a\u5bf8\u5747\u4e3a\u7eb3\u7c73\u5c3a\u5ea6\uff0c\u65e0\u6cd5\u901a\u8fc7\u5e38\u89c4\u7684\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u65b9\u6cd5\u8fdb\u884c\u6676\u4f53\u7ed3\u6784\u89e3\u6790\u3002\u4f5c\u8005\u91c7\u7528\u65f6\u4e0b\u6700\u4e3a\u5148\u8fdb\u7684\u4e09\u7ef4\u65cb\u8f6c\u7535\u5b50\u884d\u5c04\uff08cRED\uff09\u6280\u672f\uff0c\u6536\u96c6\u4e86\u7119\u70e7\u540e\u7684ZMQ-1\u6837\u54c1\u884d\u5c04\u6570\u636e\uff0c\u5e76\u5bf9\u5176\u7ed3\u6784\u8fdb\u884c\u4e86\u89e3\u6790\uff08\u4e0e\u745e\u5178\u65af\u5fb7\u54e5\u5c14\u6469\u5927\u5b66\u90b9\u6653\u51ac\u6559\u6388\u56e2\u961f\u5408\u4f5c\uff09\u3002\u7119\u70e7\u540e\u7684ZMQ-1\u5206\u5b50\u7b5b\u6676\u4f53\u7ed3\u6784\u4e3a\u6b63\u4ea4\u6676\u7cfb\uff0c\u7a7a\u95f4\u7fa4\u4e3aCmmm<\/i><\/em>\uff08No.65\uff09\uff0c\u6676\u80de\u53c2\u6570\u4e3a\uff1aa = 18.83(10) \u00c5\uff0cb = 54.9(2) \u00c5\u548cc = 20.36(5) \u00c5\u3002ZMQ-1\u5206\u5b50\u7b5b\u5177\u6709\u4e09\u7ef428\u00d710\u00d710\u5143\u73af\uff08MR\uff09\u5b54\u9053\u7cfb\u7edf\uff08\u56fe2\uff09\uff0c28MR\u5b54\u5f84\u4e3a22.76 \u00c5\u00d711.83 \u00c5\uff0c\u5b58\u5728\u4e09\u79cd\u4e0d\u540c\u768410MR\u5b54\u9053\uff0c\u5176\u5c3a\u5bf8\u5206\u522b\u4e3a5.91 \u00c5\u00d75.32 \u00c5\u00a0(\u9752\u8272), 5.56 \u00c5\u00d75.58 \u00c5\u00a0(\u7eff\u8272), 5.11 \u00c5\u00d75.90 \u00c5\uff08\u84dd\u8272\uff09\uff08\u56fe2b\uff09\uff0c\u662f\u73b0\u6709\u7ed3\u6784\u7a33\u5b9a\u5206\u5b50\u7b5b\u4e2d\u5b54\u5f84\u6700\u5927\u3001\u9aa8\u67b6\u5bc6\u5ea6\u6700\u4f4e\u7684\u7845\u94dd\u5206\u5b50\u7b5b\u3002ZMQ-1\u5206\u5b50\u7b5b\u4e2d\u768428MR\u5b54\u9053\u8fdb\u4e00\u6b65\u901a\u8fc7\u79ef\u5206\u5dee\u5206\u76f8\u4f4d\u886c\u5ea6\u9ad8\u5206\u8fa8\u7535\u955c\u6280\u672f\uff08iDPC-STEM\uff09\u5f97\u5230\u4f50\u8bc1\uff08\u56fe2c\uff09\u3002ZMQ-1\u5206\u5b50\u7b5b\u5177\u6709\u524d\u6240\u672a\u6709\u7684\u8d85\u5927\u5b54\u5c3a\u5bf8\uff0c\u4f46\u5176\u7ed3\u6784\u7279\u5f81\u4e0e\u5e38\u89c1\u7684\u5206\u5b50\u7b5b\u7ed3\u6784\u6709\u76f8\u4f3c\u4e4b\u5904\u3002\u8be5\u7ed3\u6784\u7531\u5782\u76f4\u4e8eb\u8f74\uff08\u7eff\u8272\uff09\u7684\u6ce2\u6d6a\u5c42\u6784\u6210\uff0c\u8fd9\u4e9b\u5c42\u7531\u6cbfc\u8f74\uff08\u7d2b\u8272\uff09\u5ef6\u4f38\u7684\u6241\u5e73\u6761\u5e26\u8fde\u63a5\uff0c\u5982\u56fe2a-c\u6240\u793a\u3002\u8be5\u6761\u5e26\u5305\u542b\u7531\u53cc\u8776\u5f62\u5355\u5143\u6784\u6210\u768410MR\uff08\u56fe2c\uff09\u3002ZMQ-1\u7684\u4e00\u4e2a\u72ec\u7279\u4e4b\u5904\u5728\u4e8e\u8776\u5f62\u7f51\u4e2d\u7684\u6240\u6709TO4<\/sub>\u56db\u9762\u4f53\u90fd\u6307\u5411\u540c\u4e00\u65b9\u5411\uff0c\u5e76\u4e0e\u53e6\u4e00\u4e2a\u8776\u5f62\u7f51\u76f8\u8fde\uff0c\u5f62\u6210\u53cc\u6761\u5e26\uff08\u56fe2a-b\uff09\u3002\u8fd9\u4e0e\u7531\u8776\u5f62\u5355\u5143\u6784\u5efa\u7684\u5176\u5b83\u5206\u5b50\u7b5b\u4e0d\u540c\uff0c\u8fd9\u4e9b\u5206\u5b50\u7b5b\u4e2d\u8776\u5f62\u7f51\u4e2d\u4e0d\u540c\u7684TO4<\/sub>\u56db\u9762\u4f53\u6307\u5411\u4e0d\u540c\u7684\u65b9\u5411\u3002ZMQ-1\u7684\u7ed3\u6784\u4e2d\u5305\u542b\u4e86\u5206\u5b50\u7b5b\u4e2d\u5e38\u89c1\u7684\u590d\u5408\u6784\u7b51\u5355\u5143\uff08CBU\uff09\uff0c\u5982d5r<\/i><\/em>\u3001d6r<\/i><\/em>\u00a0\u548cnon<\/i><\/em>\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2 \u7119\u70e7\u540e\u548c\u65b0\u9c9c\u5408\u6210\u7684ZMQ-1\u7684\u7ed3\u6784\u548ciDPC-STEM\u56fe\u50cf<\/p>\n

\"\"<\/p>\n

\u56fe3 ZMQ-1\u5206\u5b50\u7b5b\u7684\u7ec4\u6210\u7ed3\u6784\u5355\u5143\u53ca\u7119\u70e7\u524d\u540e\u7684\u7ed3\u6784\u53d8\u5316<\/p>\n

 <\/p>\n

\u4e3a\u4e86\u6df1\u5165\u63a2\u7a76OSDA\u5728\u5bfc\u5411\u751f\u6210ZMQ-1\u5206\u5b50\u7b5b\u7ed3\u6784\u4e2d\u7684\u4f5c\u7528\uff0c\u5bf9OSDA\u5728\u5206\u5b50\u7b5b\u4e2d\u6240\u5904\u4f4d\u7f6e\u7684\u786e\u5b9a\u81f3\u5173\u91cd\u8981\u3002\u4f5c\u8005\u9996\u5148\u91c7\u7528\u4e0a\u8ff0\u76f8\u540c\u7684cRED\u6280\u672f\u5bf9\u65b0\u9c9c\u5408\u6210\u7684ZMQ-1\u8fdb\u884c\u4e86\u7ed3\u6784\u89e3\u6790\uff0c\u5f97\u5230\u5176\u6676\u80de\u53c2\u6570\u4e3a\uff1aa = 18.94(3) \u00c5, b = 20.21(4) \u00c5, c = 27.51(7) \u00c5,\u03b2\u00a0= 103.56(19)\u02da\u3002\u65b0\u9c9c\u6837\u54c1\u540c\u6837\u5177\u670928MR*10MR\u5b54\u9053\u7ed3\u6784\uff0c\u4f46\u517628MR\u5448\u73b0\u626d\u66f2\u7684\u53cc\u53f6\u578b\u7ed3\u6784\uff08\u56fe2e-f\uff09\u3002\u7119\u70e7\u9664\u53bbOSDA\u6709\u673a\u7ec4\u5206\u540e\uff0c\u53d8\u4e3a\u89c4\u6574\u7684\u692d\u5706\u5f62\u5b54\u9053\u7ed3\u6784\uff08\u56fe2d\uff0c\u56fe3e\uff09\u3002\u4f5c\u8005\u8fdb\u4e00\u6b65\u91c7\u7528\u4f4e\u5242\u91cf\u51b7\u51bb-cRED\u6280\u672f\u786e\u5b9a\u4e86\u65b0\u9c9c\u5408\u6210ZMQ-1\u4e2dOSDA\u7684\u786e\u5207\u7684\u4f4d\u7f6e\u548c\u6570\u76ee\uff0c\u53d1\u73b0OSDA\u7684\u7aef\u57fa\u4e09\u73af\u5df1\u57fa\u78f7\u9633\u79bb\u5b50\u57fa\u56e2\u4f4d\u4e8e28MR\u5927\u7684\u5b54\u9053\u4e2d\uff0c\u8d77\u5230\u4e86\u586b\u5145\u6216\u6a21\u677f\u4f5c\u7528\uff0c\u800c\u7ebf\u6027\u7684\u4e9a\u7532\u57fa\u94fe\u88ab10MR\u201c\u7a97\u53e3\u201d\u9501\u4f4f\u3002\u57fa\u4e8e\u6b64\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86ZMQ-1\u5206\u5b50\u7b5b\u7684\u5f62\u6210\u673a\u7406\uff1a\u5927\u5c3a\u5bf8\u517c\u5177\u521a\u6027\u7684\u4e09\u73af\u5df1\u57fa\u78f7\u57fa\u56e2\u63d0\u4f9b\u4e86\u5927\u5c3a\u5bf8\u7a7a\u95f4\u5360\u4f4d\u4f5c\u7528\uff0c\u800c\u5177\u6709\u7075\u6d3b\u6027\u7684\u4e9a\u7532\u57fa\u94fe\u4e3a\u5206\u5b50\u7b5b\u7ed3\u6784\u7684\u751f\u957f\u63d0\u4f9b\u4e86\u53ef\u80fd\uff0c\u6700\u7ec8\u5f97\u5230\u4ecb\u5b54ZMQ-1\u5206\u5b50\u7b5b\u7ed3\u6784\u3002<\/p>\n

 <\/p>\n

ZMQ-1\u5206\u5b50\u7b5b\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28<\/b><\/strong><\/p>\n

\u65b0\u9c9c\u5408\u6210\u7684ZMQ-1\u5728\u4e00\u6b21\u7119\u70e7\u540e\uff0cOSDA\u7684\u6709\u673a\u7ec4\u5206\u88ab\u5b8c\u5168\u79fb\u9664\uff0c\u4f46\u78f7\u7269\u79cd\u4f1a\u6b8b\u7559\u5728\u5206\u5b50\u7b5b\u5b54\u9053\u5185\u90e8\uff0c\u8fd9\u4e9b\u78f7\u7269\u79cd\u901a\u8fc7\u6c2f\u5316\u94f5\u6eb6\u6db2\u6d17\u6da4\u548c\u4ea4\u6362\uff0c\u53ef\u4ee5\u88ab\u5b8c\u5168\u795b\u9664\uff0c\u5f97\u5230\u5b8c\u5168\u5f00\u653e\u7684ZMQ-1\u9aa8\u67b6\u7ed3\u6784\u3002\u7119\u70e7\u9664\u78f7\u540e\u7684ZMQ-1\u5206\u5b50\u7b5b\u6c29\u6c14\u7269\u7406\u5438\u9644\u8868\u73b0\u4e3aI\uff08b\uff09\u578b\u7b49\u6e29\u7ebf\uff08\u56fe4b\uff09\uff0c\u8fd9\u8868\u660e\u5176\u5b58\u5728\u8d85\u5927\u5fae\u5b54\u6216\u72ed\u7a84\u7684\u4ecb\u5b54\uff08\u5c0f\u4e8e2.5\u7eb3\u7c73\uff09\u3002\u91c7\u7528NLDFT\u6a21\u578b\u5f97\u5230\u4e86\u7d2f\u8ba1\u5b54\u5bb9\u548c\u5b54\u5206\u5e03\u6570\u636e\uff0c\u53d1\u73b0\u4e24\u79cd\u4e3b\u8981\u7684\u4f53\u79ef\u5438\u6536\uff0c\u5206\u522b\u5bf9\u5e94\u4e8e\u4e24\u79cd\u4e0d\u540c\u7684\u5b54\u5f84\u5206\u5e03\uff08\u56fe4c\uff09\uff0c\u537310MR\u548c28MR\u3002ZMQ-1\u5177\u6709\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff081447m\u00b2\/g\uff09\u4ee5\u53ca\u7834\u7eaa\u5f55\u7684\u5fae\u5b54\u5b54\u5bb9\uff080.47cm\u00b3\/g\uff09\u3002\u9274\u4e8eZMQ-1\u72ec\u7279\u7684\u4ecb\u5b54\u7ed3\u6784\uff0c\u4f5c\u8005\u5728\u8fd9\u91cc\u63d0\u51fa\u4e86\u4e00\u4e2a\u65b0\u7684\u672f\u8bed\u201c\u5206\u5b50\u7b5b\u5b54\u4f53\u79ef\u201d\uff0c\u662f\u5bf9\u7ecf\u5178\u201c\u5fae\u5b54\u4f53\u79ef\u201d\u5b9a\u4e49\u7684\u8865\u5145\uff0c\u56e0\u4e3aZMQ-1\u7684\u5b54\u5f84\u5206\u5e03\u6b63\u597d\u5904\u4e8eIUPAC\u6240\u5b9a\u4e49\u7684\u5fae\u5b54\u548c\u4ecb\u5b54\u7684\u4ea4\u53c9\u5730\u5e26\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 ZMQ-1\u7684\u5b54\u5f84\u5206\u6790<\/p>\n

\u5206\u5b50\u7b5b\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\u81f3\u5173\u91cd\u8981\uff0c\u56e0\u4e3a\u50ac\u5316\u53cd\u5e94\u7b49\u8fc7\u7a0b\u901a\u5e38\u6d89\u53ca\u9ad8\u6e29\u9ad8\u538b\u548c\u6c34\u6c7d\u3002\u65b0\u9c9c\u5408\u6210\u548c\u7119\u70e7\u540e\u7684ZMQ-1\u8868\u73b0\u51fa\u53ef\u8010\u53d7\u81f3800\u2103\u7684\u9ad8\u70ed\u7a33\u5b9a\u6027\u548c\u6c34\u70ed\u7a33\u5b9a\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u94f5\u4ea4\u6362\u540e\u7684\u65e0\u78f7ZMQ-1\u751a\u81f3\u57281000\u2103\u4e0b\u4e5f\u80fd\u4fdd\u6301\u7ed3\u6784\u7684\u70ed\u548c\u6c34\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n

\u4e3a\u4e86\u7814\u7a76\u65b0\u9c9c\u5408\u6210\u5206\u5b50\u7b5b\u7119\u70e7\u79fb\u9664OSDA\u5f62\u6210\u5b8c\u5168\u8fde\u63a5\u7684\u5f00\u653eZMQ-1\u9aa8\u67b6\u7684\u8fc7\u7a0b\uff0c\u4f5c\u8005\u91c7\u7528\u771f\u7a7a\u539f\u4f4d\u5347\u6e29\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\uff08in situ<\/i><\/em>\u00a0FTIR\uff09\u5bf9\u8fc7\u7a0b\u8fdb\u884c\u4e86\u8ffd\u8e2a\u3002\u4ee5\u65b0\u9c9c\u5408\u6210ZMQ-1\u4e3a\u8d77\u59cb\u6837\u54c1\uff0c\u968f\u7740\u6e29\u5ea6\u7531\u5ba4\u6e29\u5347\u81f3150\u2103\u5904\u740675min\uff0c\u5bf9\u5e94\u7684\u6c34\u5438\u9644\u5cf0\u6d88\u5931\uff08\u56fe5a\uff09\u3002\u968f\u7740\u6e29\u5ea6\u7ee7\u7eed\u5347\u9ad8\u76f4\u81f3450\u2103\uff0c\u5438\u6536\u5cf0\u51fa\u73b0\u4e86\u660e\u663e\u7684\u53d8\u5316\u3002\u5bf9\u5e94\u4e8e\u5b64\u7acb\u7845\u7f9f\u57fa\u548c\u5f31\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u7684\u7845\u7f9f\u57fa\u7684\u5438\u6536\u5cf0\u968f\u7740\u6e29\u5ea6\u5347\u9ad8\u9010\u6e10\u84dd\u79fb\uff0c\u968f\u540e\u878d\u5408\u4e3a\u4e00\u4e2a\u5438\u6536\u5cf0\uff0c\u8fdb\u800c\u6f14\u5316\u4e3a\u4e00\u4e2a\u5c16\u9510\u5f3a\u5438\u6536\u5cf0\uff083745 cm-1<\/sup>\uff09\uff0c\u5176\u5bf9\u5e94\u4e8e\u5b8c\u5168\u5b64\u7acb\u7684\u7845\u7f9f\u57fa\uff08\u56fe5b\uff09\u3002\u8fd9\u8868\u660e\uff0c\u65b0\u9c9c\u5408\u6210\u7684ZMQ-1\u5728\u5347\u6e29\u7119\u70e7\u8fc7\u7a0b\u4e2d\uff0c28MR\u5904\u7684\u7845\u7f9f\u57fa\u7f3a\u9677\u4f4d\u70b9\u5728400\u2103\u7684\u70ed\u5904\u7406\u5f00\u59cb\u65f6\u4f1a\u8fdb\u884c\u7f29\u805a\u5e76\u6700\u7ec8\u53d8\u4e3a\u5b8c\u5168\u8fde\u63a5\u3002450\u2103\u5904\u74064h\u540e\uff0c\u57283600-3500 cm-1<\/sup>\u8303\u56f4\u5185\u51fa\u73b0\u65b0\u7684\u5f3a\u5438\u6536\u591a\u5cf0\uff0c\u8fd9\u5bf9\u5e94\u4e8e\u7845\u6c27\u94dd\u6865\u7f9f\u57fa\u7684Br\u00f8nsted\u9178\u6027\u4f4d\u70b9\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 \u65b0\u9c9c\u5408\u6210ZMQ-1\u7684\u771f\u7a7a\u539f\u4f4d\u5347\u6e29FTIR\u6f14\u53d8<\/p>\n

 <\/p>\n

ZMQ-1\u5206\u5b50\u7b5b\u662f\u9996\u4e2a\u901a\u8fc7\u76f4\u63a5\u5408\u6210\u65b9\u6cd5\u5f97\u5230\u7684\u5177\u6709\u672c\u5f81\u4ecb-\u5fae\u5b54\u7ed3\u6784\u7684\u5206\u5b50\u7b5b\u6750\u6599\uff0c\u5176\u9aa8\u67b6Si\/Al\u539f\u5b50\u6bd4\u4e3a20\u5de6\u53f3\uff0c\u975e\u5e38\u9002\u5408\u7528\u4e8e\u56fa\u4f53\u9178\u50ac\u5316\u53cd\u5e94\u4e2d\u3002\u77f3\u6cb9\u70bc\u5236\u8fc7\u7a0b\uff0c\u7279\u522b\u662f\u50ac\u5316\u88c2\u5316\u8fc7\u7a0b\uff0c\u4e00\u76f4\u81f4\u529b\u4e8e\u5bfb\u627e\u66f4\u5927\u5b54\u5f84\u7684\u5206\u5b50\u7b5b\u7528\u4f5c\u9178\u50ac\u5316\u5242\u3002\u4f5c\u8005\u5c06\u8be5\u65b0\u578b\u5206\u5b50\u7b5b\u5e94\u7528\u4e8e\u91cd\u6cb9\u50ac\u5316\u88c2\u5316\u53cd\u5e94\uff0c\u4e0e\u73b0\u6709\u5546\u4e1a\u5316\u6cb8\u77f3\u5206\u5b50\u7b5b\u50ac\u5316\u5242\u8fdb\u884c\u5bf9\u6bd4\u3002\u4ea7\u7269\u5206\u6790\u7ed3\u679c\u663e\u793a\uff08\u56fe6\uff09\uff0c\u542b\u78f7\u7684ZMQ-1\u5b9e\u73b0\u4e86\u66f4\u9ad8\u7684\u8f7b\u8d28\u6cb9\u54c1\u9009\u62e9\u6027\uff08\u6c7d\u6cb9\u548c\u67f4\u6cb9\u603b\u9009\u62e9\u6027\u63a5\u8fd180%\uff09\uff0c\u4e14\u79ef\u78b3\u66f4\u4f4e\uff08\u22645%\uff09\uff0c\u540c\u65f6\u80fd\u591f\u4fdd\u6301\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u4e9b\u521d\u6b65\u7684\u53cd\u5e94\u7ed3\u679c\u8868\u660e\uff0cZMQ-1\u65b0\u578b\u5206\u5b50\u7b5b\u6709\u5229\u4e8e\u4f18\u5316\u50ac\u5316\u88c2\u5316\u4ea7\u7269\u7684\u5206\u5e03\uff0c\u63d0\u9ad8\u4ea7\u54c1\u7684\u8d28\u91cf\u548c\u7ecf\u6d4e\u4ef7\u503c\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6 \u5206\u5b50\u7b5b\u7684\u50ac\u5316\u6027\u80fd\u8bc4\u4ef7<\/p>\n

 <\/p>\n

\u672c\u5f81\u4ecb\u5b54\u6cb8\u77f3\u5206\u5b50\u7b5bZMQ-1\u7684\u6210\u529f\u5408\u6210\uff0c\u4e3a\u6cb8\u77f3\u5206\u5b50\u7b5b\u6750\u6599\u9886\u57df\u7684\u53d1\u5c55\u63d0\u4f9b\u65b0\u7684\u601d\u8def\u548c\u65b9\u5411\uff0c\u4e5f\u5728\u7cbe\u7ec6\u5316\u5b66\u54c1\u5408\u6210\u3001\u73af\u5883\u6cbb\u7406\u3001\u80fd\u6e90\u8f6c\u5316\u7b49\u9886\u57df\u5c55\u793a\u51fa\u66f4\u4e3a\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u672a\u6765\uff0c\u53ef\u901a\u8fc7\u8de8\u5b66\u79d1\u5408\u4f5c\uff0c\u52a0\u5f3a\u4ea7\u5b66\u7814\u7ed3\u5408\uff0c\u63a8\u52a8\u5176\u4ece\u5b9e\u9a8c\u5ba4\u8d70\u5411\u5546\u4e1a\u5316\u5e94\u7528\u3002<\/p>\n

 <\/p>\n

 <\/p>\n

 <\/p>\n

\u901a\u8baf\u4f5c\u8005\u4ecb\u7ecd<\/p>\n

\"\"<\/p>\n

Valentin Valtchev\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u5c9b\u751f\u7269\u80fd\u6e90\u4e0e\u8fc7\u7a0b\u7814\u7a76\u6240\u5206\u5b50\u7b5b\u6750\u6599\u7814\u7a76\u7ec4\u8d1f\u8d23\u4eba\uff0c\u6cd5\u56fd\u56fd\u5bb6\u79d1\u5b66\u7814\u7a76\u4e2d\u5fc3\u50ac\u5316\u4e0e\u5149\u8c31\u5316\u5b66\u5b9e\u9a8c\u5ba4\uff08\u5361\u6602\uff09\u4e3b\u4efb\uff0cDR1\u7814\u7a76\u5458\uff0cGreen Carbon<\/i><\/em>\u4e3b\u7f16\u3002\u56fd\u9645\u5206\u5b50\u7b5b\u5b66\u4f1a\u4e3b\u5e2d\uff082016-2019\uff09\uff0c\u56fd\u9645\u5206\u5b50\u7b5b\u5b66\u4f1a\u5927\u4f7f\uff082022-2024\uff09\uff0c\u56fd\u9645\u5206\u5b50\u7b5b\u5b66\u4f1aBreck\u5956\u3001\u56fd\u9645\u5206\u5b50\u7b5b\u5b66\u4f1a\u5956\u3001\u6b27\u6d32\u5206\u5b50\u7b5b\u8054\u76dfKronstedt\u5956\u83b7\u5f97\u8005\u3002\u4e13\u4e1a\u9886\u57df\u662f\u5206\u5b50\u7b5b\u6676\u4f53\u5de5\u7a0b\u5b66\uff0c\u662f\u7eb3\u7c73\u5206\u5b50\u7b5b\u5b66\u79d1\u7684\u5f00\u521b\u8005\u3002\u5728Science<\/i><\/em>\u7b49\u671f\u520a\u53d1\u8868\u5b66\u672f\u8bba\u6587\u8fd1300\u7bc7\uff0c\u5f15\u7528\u903e15000\u6b21\u3002<\/p>\n

\"\"<\/p>\n

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\"\"<\/p>\n

\u626b\u7801\u53ef\u9605\u8bfb\u539f\u6587<\/p>\n

Peng Lu, Jiaoyan Xu, Yiqing Sun, R\u00e9my Guillet-Nicolas, Tom Willhammar, Mohammad Fahda, Eddy Dib, Bo Wang, Zhengxing Qin, Hongyi Xu, Jung Cho, Zhaopeng Liu, Haijun Yu, Xiaobo Yang, Qiaolin Lang, Svetlana Mintova, Xiaodong Zou & Valentin Valtchev, A stable zeolite with atomically ordered and interconnected mesopore channel, Nature 636 (2024) 368-373.<\/p>\n

https:\/\/doi.org\/10.1038\/s41586-024-08206-1<\/p>\n","protected":false},"excerpt":{"rendered":"

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