![\"\"](\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/1-3.png\")
<\/p>\n\u3010\u7814\u7a76\u80cc\u666f\u3011<\/p>\n
\u9530\u9178\u9502\uff08LMO\uff09\u56e0\u5176\u4f4e\u6210\u672c\u3001\u73af\u4fdd\u548c\u8f83\u9ad8\u5de5\u4f5c\u7535\u538b\u800c\u6210\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\uff08LIB\uff09\u4e00\u79cd\u5e7f\u6cdb\u5e94\u7528\u7684\u6b63\u6781\u6750\u6599\u3002\u7136\u800c\uff0c\u5b83\u7684\u7535\u5316\u5b66\u6027\u80fd\u5728\u9ad8\u6e29\u4e0b\u4f1a\u6076\u5316\uff0c\u4e3b\u8981\u539f\u56e0\u662f\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u9000\u5316\u4ee5\u53ca\u7535\u6781\/\u7535\u89e3\u6db2\u754c\u9762\u4e0a\u4e0d\u826f\u53cd\u5e94\u7684\u589e\u5f3a\u3002\u9996\u5148\uff0cLMO \u7684\u7ed3\u6784\u5728\u4f4e\u5145\u7535\u6001\u548c\u6df1\u653e\u7535\u72b6\u6001\u4e0b\u90fd\u4e0d\u7a33\u5b9a\u3002\u5728\u4f4e\u5145\u7535\u72b6\u6001\u4e0b\uff0cMn3+ \u79bb\u5b50\u4f1a\u53d1\u751f Jahn-Teller \u7578\u53d8\uff0c\u4ece\u800c\u5bfc\u81f4\u7ed3\u6784\u53d8\u5316\uff1b\u800c\u5728\u6df1\u653e\u7535\u72b6\u6001\u4e0b\uff0cLMO \u4f1a\u63d2\u5165\u989d\u5916\u7684\u9502\uff0c\u4ece\u800c\u5f62\u6210\u4e0d\u7a33\u5b9a\u7684\u56db\u65b9\u76f8\u3002\u53e6\u4e00\u4e2a\u4e3b\u8981\u539f\u56e0\u662f\u7535\u89e3\u6db2\u4e2d\u7684 LiPF6\u5728\u9ad8\u6e29\u4e0b\u6c34\u89e3\u548c\u5206\u89e3\u4ea7\u751f HF\uff0c\u5bfc\u81f4\u7535\u6781\/\u7535\u89e3\u6db2\u754c\u9762\u8150\u8680\u5e76\u52a0\u901f\u9530\u7684\u6eb6\u89e3\uff0c\u6eb6\u89e3\u7684\u9530\u8fc1\u79fb\u5230\u8d1f\u6781\u4e0a\u6c89\u79ef\uff0c\u8fdb\u4e00\u6b65\u52a0\u5267\u4e86\u7535\u89e3\u6db2\u5206\u89e3\uff0c\u5bfc\u81f4 LIB \u5feb\u901f\u5931\u6548\u3002<\/p>\n
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<\/p>\n
\u8fd1\u65e5\uff0c\u6765\u81ea\u4e2d\u5357\u5927\u5b66\u7684\u675c\u67ef\u6559\u6388\u4e0e\u4e0a\u6d77\u71b5\u5ef6\u79d1\u6280\u6709\u9650\u516c\u53f8\u5408\u4f5c\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u6c27\u57fa\u7845\u70f7\u6dfb\u52a0\u5242TMPS\uff0c\u6765\u6539\u5584LMO\u7684\u9ad8\u6e29\u95ee\u9898\uff0c\u5373\u5229\u7528\u540c\u65f6\u5177\u6709\u9ad8HOMO\u80fd\u7ea7\u4f4eLUMO\u80fd\u7ea7\uff0c\u4ee5\u53ca\u5f3aHF\u7ed3\u5408\u80fd\u7684\u6dfb\u52a0\u5242\uff0c\u6d88\u9664\u9178\u6027\u7269\u8d28\uff0c\u91cd\u6784\u7535\u6781\/\u7535\u89e3\u6db2\u754c\u9762\uff0c\u51cf\u5c11\u7535\u6781\u4e0a\u8fc7\u6e21\u91d1\u5c5e\u7684\u6eb6\u51fa\uff0c\u63d0\u9ad8\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u7535\u6c60\u6027\u80fd\u3002\u901a\u8fc7\u4f7f\u7528\u542b 1 wt.% TMPS \u7684\u7535\u89e3\u6db2\uff0cLMO\/\/Li\u7535\u6c60\u5728 25 \u00b0C \u548c 60 \u00b0C \u4e0b\u5faa\u73af 500 \u6b21\u540e\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u5206\u522b\u4e3a95.5% \u548c 83.7%\u3002\u540c\u65f6\uff0c\u4f7f\u7528\u8fd9\u79cd\u7535\u89e3\u6db2\u7684 18650 \u578b\u5706\u67f1\u5f62\u7535\u6c60\u572860 \u00b0C\u9ad8\u6e29\u4e0b\u5faa\u73af100\u6b21\u4ecd\u5177\u670978.01%\u7684\u5bb9\u91cf\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cEnhanced elevated-temperature performance of LiMn2O4 cathodes in lithium-ion batteries via a multifunctional electrolyte additive\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aChemical Engineering Journal\u4e0a\u3002<\/p>\n
\n \u3010\u672c\u6587\u8981\u70b9\u3011<\/p>\n
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![\"\"](\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/2-3.png\")
\n \u56fe1. TMPS\u7684\u5206\u5b50\u7ed3\u6784\u4ee5\u53ca\u5bf9\u7535\u89e3\u6db2\u7684\u76f8\u5173\u5f71\u54cd<\/p>\n
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\n \u56fe2. LMO\/\/Li\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n
![\"\"](\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/4-3.png\")
<\/p>\n
\u56fe3. \u4e0d\u540c\u7535\u89e3\u6db2\u4e2dNyquist\u56fe\u53ca\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf<\/p>\n
\u8981\u70b9\u4e09\uff1a\u5faa\u73af\u540e\u7ed3\u6784\u548cCEI\u7684\u6539\u5584<\/p>\n
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![\"\"](\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/12\/7.png\")
<\/p>\n
\u56fe6. TMPS\u529f\u80fd\u793a\u610f\u56fe<\/p>\n
\u3010\u6587\u7ae0\u94fe\u63a5\u3011<\/p>\n
Enhanced elevated-temperature performance of LiMn2O4 cathodes in lithium-ion batteries via a multifunctional electrolyte additive<\/p>\n
https:\/\/doi.org\/10.1016\/j.cej.2024.158219.<\/p>\n
\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/p>\n
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