{"id":263023,"date":"2024-10-11T06:56:12","date_gmt":"2024-10-10T22:56:12","guid":{"rendered":"\/\/m.iemloyee.com\/?p=263023"},"modified":"2024-10-10T16:10:46","modified_gmt":"2024-10-10T08:10:46","slug":"%e6%89%8b%e6%80%a7%e9%98%b3%e7%a6%bb%e5%ad%90%e7%ad%96%e7%95%a5%e8%b0%83%e6%8e%a7ptii%e6%b0%af%e5%8c%96%e7%89%a9%e7%9a%84%e5%9c%86%e5%81%8f%e6%8c%af%e7%a3%b7%e5%85%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=263023","title":{"rendered":"\u624b\u6027\u9633\u79bb\u5b50\u7b56\u7565\u8c03\u63a7Pt(II)\u6c2f\u5316\u7269\u7684\u5706\u504f\u632f\u78f7\u5149"},"content":{"rendered":"

\u5706\u504f\u632f\u78f7\u5149\uff08CPP\uff09\u5982\u624b\u6027Pt(II)\u914d\u5408\u7269\uff08Angew. Chem. Int. Ed.<\/em> 2010<\/strong>, 49<\/em>, 99)\u3001Ir(III)\u914d\u5408\u7269\uff08Adv. Funct. Mater.<\/em> 2024<\/strong>, 34<\/em>, 2402906\uff09\u3001Au(I)\u914d\u5408\u7269\uff08Angew. Chem. Int. Ed.<\/em> 2023<\/strong>, 62<\/em>, e202311572\uff09\u517c\u5177\u5706\u504f\u632f\u53d1\u5149\uff08CPL\uff09\u548c\u78f7\u5149\u7684\u4f18\u52bf\uff0c\u5728\u4fe1\u606f\u52a0\u5bc6\uff08J. Am. Chem. Soc. <\/em>2021<\/strong>, 143<\/em>, 18527\uff09\u548c\u4fe1\u606f\u5b58\u50a8\uff08Adv. Mater.<\/em> 2023<\/strong>, 35<\/em>, 2304405\uff09\u7b49\u9886\u57df\u663e\u793a\u51fa\u4e86\u5e7f\u9614\u7684\u5e94\u7528\u6f5c\u529b\u3002\u5728\u8fd9\u4e9bCPP\u8fc7\u6e21\u91d1\u5c5e\u6750\u6599\u4e2d\uff0c\u5176\u4e2d\u5177\u6709\u4e0d\u540c\u914d\u4f4d\u7ed3\u6784\u548c\u4f18\u826f\u5149\u5b66\u6027\u80fd\u7684Pt(II)\u914d\u5408\u7269\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u901a\u5e38\uff0c\u5706\u504f\u632f\u78f7\u5149Pt(II)\u914d\u5408\u7269\u662f\u901a\u8fc7\u5f15\u5165\u624b\u6027\u914d\u4f53\u5b9e\u73b0\u624b\u6027\u5149\u5b66\u6027\u8d28\uff0c\u4f46\u8fd9\u4e9b\u65b9\u6cd5\u901a\u5e38\u9762\u4e34\u7740\u590d\u6742\u7684\u5408\u6210\u6b65\u9aa4\u548c\u5bf9\u6620\u4f53\u5206\u79bb\u56f0\u96be\u7684\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u83b7\u5f97\u5408\u6210\u7b80\u5355\u3001\u6210\u672c\u4f4e\u3001\u4ea7\u7387\u9ad8\u3001\u6027\u80fd\u4f18\u5f02\u7684CPP\u6750\u6599\u4ecd\u7136\u662f\u4e00\u4e2a\u91cd\u8981\u7684\u6311\u6218\u3002<\/p>\n

\u672c\u6587\u91c7\u7528\u4e86\u624b\u6027\u9633\u79bb\u5b50\u8c03\u63a7\u7684\u7b56\u7565\uff0c\u901a\u8fc7\u7b80\u5355\u7684\u4e00\u6b65\u53cd\u5e94\u5236\u5907\u5f97\u5230\u9634\u79bb\u5b50\u578bPt(II)\u6c2f\u5316\u7269\u7684\u624b\u6027\u5bf9\u6620\u4f53R\/S<\/em>-ABA\u00b7[Pt(ppy)Cl2<\/sub>]\u548cR\/S<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\uff08ppy = 2-\u82ef\u57fa\u5421\u5576\uff0cABA = 3-\u6c28\u57fa\u4e01\u9178\uff0c\u56fe1\uff09\uff0c\u4ea7\u7387\u63a5\u8fd1100%\u3002\u8fd9\u4e9b\u624b\u6027Pt(II)\u6c2f\u5316\u7269\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u4e0e\u7a7a\u6c14\u7a33\u5b9a\u6027\uff0c\u5728\u624b\u6027\u9633\u79bb\u5b50\u7684\u8bf1\u5bfc\u4e0b\uff0c\u539f\u672c\u5e73\u9762\u7684[Pt(ppy)Cl2<\/sub>]–<\/sup>\u5448\u73b0\u660e\u663e\u7684\u624b\u6027\u7ed3\u6784\u7578\u53d8\uff0c\u5176\u5355\u6676\u7ed3\u6784\u663e\u793a\u4e3a\u624b\u6027\u7a7a\u95f4\u7fa4\uff08R\/S<\/em>-ABA\u00b7[Pt(ppy)Cl2<\/sub>]\u548cR\/S<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\u7684\u7a7a\u95f4\u7fa4\u5206\u522b\u4e3aP<\/em>21<\/sub>\u548cP<\/em>21<\/sub>21<\/sub>21<\/sub>\uff09\u3002<\/p>\n

\u56fe<\/strong>1.<\/strong> \u672c\u6587\u7684\u7814\u7a76\u601d\u8def\u4ee5\u53caR\/S<\/em>-ABA\u00b7[Pt(ppy)Cl2<\/sub>]\u548cR\/S<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\u7684\u5316\u5b66\u7ed3\u6784\u3002<\/p>\n

\u5bf9\u624b\u6027Pt(II)\u6c2f\u5316\u7269\u7684\u5706\u4e8c\u8272\uff08CD\uff09\u548c\u5706\u504f\u632f\u53d1\u5149\u5149\u8c31\uff08\u56fe2-3\uff09\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u5b9e\u9a8c\u548c\u7406\u8bba\u7814\u7a76\uff0c\u8bc1\u5b9e\u4e86\u624b\u6027\u4ece\u9633\u79bb\u5b50\u6210\u529f\u8f6c\u79fb\u5230\u53d1\u5149\u4e2d\u5fc3[Pt(ppy)Cl2]–<\/sup>\u3002R\/S<\/em>-ABA\u00b7[Pt(ppy)Cl2<\/sub>]\u548cR\/S<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\u7684\u53d1\u5149\u4e0d\u5bf9\u79f0\u56e0\u5b50\uff08g<\/em>lum<\/sub>\uff09\u5206\u522b\u4e3a+1.4\/-1.8\u00d710-3<\/sup>\u548c+4.4\/-2.8\u00d710-3<\/sup>\u3002R\/S<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\u8f83\u9ad8\u7684g<\/em>lum<\/sub>\u662f\u5f52\u56e0\u4e8e\u5728MBA+<\/sup>\u8f83\u5f3a\u7684\u56fa\u6709\u624b\u6027\u8bf1\u5bfc\u4e0b\uff0cR\/S<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\u8868\u73b0\u51fa\u66f4\u660e\u663e\u7684\u624b\u6027\u7578\u53d8\uff0c\u5728\u78f7\u5149\u7535\u5b50\u8dc3\u8fc1\u4e2d\u6709\u66f4\u6709\u5229\u7684\u78c1\u8dc3\u8fc1\u5076\u6781\u77e9\u548c\u7535\u8dc3\u8fc1\u5076\u6781\u77e9\u3002\u7efc\u4e0a\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u624b\u6027\u9633\u79bb\u5b50\u7b56\u7565\uff0c\u6210\u529f\u6784\u5efa\u4e86\u5177\u6709\u4f18\u5f02\u624b\u6027\u5149\u5b66\u6027\u8d28\u548c\u9ad8\u53d1\u5149\u6548\u7387\u7684Pt(II)\u6c2f\u5316\u7269\u3002\u8fd9\u4e00\u7b56\u7565\u4e0d\u4ec5\u7b80\u5316\u4e86\u5236\u5907\u8fc7\u7a0b\uff0c\u8fd8\u663e\u8457\u63d0\u5347\u4e86\u6750\u6599\u7684\u6027\u80fd\uff0c\u4e3a\u6784\u7b51\u9ad8\u6027\u80fd\u5706\u504f\u632f\u78f7\u5149\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong>. R\/S<\/em>-ABA\u00b7[Pt(ppy)Cl2<\/sub>]\uff08a\uff09\u548cR\/S<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\uff08c\uff09\u7684CD\u5149\u8c31\uff08\u5b9e\u7ebf\u4e3a\u5b9e\u9a8c\u7ed3\u679c\uff0c\u865a\u7ebf\u4e3a\u7406\u8bba\u6a21\u62df\u7ed3\u679c\uff1bR\/S<\/em>-ABA\u00b7[Pt(ppy)Cl2<\/sub>]\uff08b\uff09\u548cR\/S<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\uff08d\uff09\u7684\u5438\u6536\u4e0d\u5bf9\u79f0\u56e0\u5b50\uff08g<\/em>CD<\/sub>\uff09\uff1bR<\/em>-ABA\u00b7[Pt(ppy)Cl2<\/sub>]\uff08e\uff09\u548cR<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\uff08f\uff09\u4e3b\u8981CD\u5cf0\u7684\u7535\u8dc3\u8fc1\u5076\u6781\u77e9\u548c\u78c1\u8dc3\u8fc1\u5076\u6781\u77e9\u77e2\u91cf\u5206\u6790<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3<\/strong>. R\/S<\/em>-ABA\u00b7[Pt(ppy)Cl2<\/sub>]\u7684CPL\u5149\u8c31\uff08a\uff09\u548cg<\/em>lum<\/sub>\uff08b\uff09\uff1bR\/S<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\u7684CPL\u5149\u8c31\uff08c\uff09\u548cg<\/em>lum<\/sub>\uff08d\uff09\uff1b\u5e73\u9762\u7684[Pt(ppy)Cl2<\/sub>]–<\/sup>\u7684\u624b\u6027\u8bf1\u5bfc\u7ed3\u6784\u7578\u53d8\u793a\u610f\u56fe\uff08e\uff09\uff1bR<\/em>-ABA\u00b7[Pt(ppy)Cl2<\/sub>]\uff08f\uff09\u548cR<\/em>-MBA\u00b7[Pt(ppy)Cl2<\/sub>]\uff08g\uff09\u5728\u4f18\u5316\u7684T1<\/sub>\u6001\u7684\u624b\u6027\u7578\u53d8\u4e8c\u9762\u89d2\uff08ppy\u914d\u4f53\u793a\u610f\u4e3a\u84dd\u8272\u5e73\u9762\uff0cPt\u548c\u4e24\u4e2aCl\u539f\u5b50\u786e\u5b9a\u7684\u5e73\u9762\u793a\u610f\u4e3a\u7c89\u8272\uff09\u3002<\/p>\n

Tuning the Circularly Polarized Phosphorescence of Platinum(II) Complexes through Chiral Cation Strategy. Jiajia Ren#, Tengfei He#, Haolin Lu, Hebin Wang, Tianyin Shao, Zhaoyu Wang, Yunxin Zhang, Sehrish Gull, Yun Chi, Yu-Wu Zhong, Yongsheng Chen, Guankui Long*<\/p>\n

\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5357\u5f00\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u7684\u7855\u58eb\u7814\u7a76\u751f\u4efb\u4f73\u4f73\u548c\u535a\u58eb\u540e\u4f55\u817e\u98de\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u5357\u5f00\u5927\u5b66\u9f99\u5b98\u594e\u7814\u7a76\u5458\uff0c\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u5b63\u6600\u6559\u6388\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u949f\u7fbd\u6b66\u7814\u7a76\u5458\u548c\u5357\u5f00\u5927\u5b66\u9648\u6c38\u80dc\u6559\u6388\u7684\u6307\u5bfc\u3002<\/p>\n

Materials Horizons <\/em>2024<\/strong>, DOI: 10.1039\/D4MH01105H.<\/p>\n

https:\/\/doi.org\/10.1039\/D4MH01105H<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5706\u504f\u632f\u78f7\u5149\uff08CPP\uff09\u5982\u624b\u6027Pt(II)\u914d\u5408\u7269\uff08Angew. Chem. Int. Ed. 2010, 49, 99)\u3001Ir(III)\u914d\u5408\u7269\uff08Adv. Funct…<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-263023","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/263023"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=263023"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/263023\/revisions"}],"predecessor-version":[{"id":263029,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/263023\/revisions\/263029"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=263023"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=263023"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=263023"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}