{"id":261687,"date":"2024-08-11T06:10:55","date_gmt":"2024-08-10T22:10:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=261687"},"modified":"2024-08-10T19:11:03","modified_gmt":"2024-08-10T11:11:03","slug":"%e6%b5%99%e6%b1%9f%e5%a4%a7%e5%ad%a6nat-chem-%ef%bc%9a%e7%bc%96%e7%bb%87%e7%ba%af%e6%9c%89%e6%9c%ba%e8%81%9a%e5%90%88%e7%89%a9%e7%bd%91%e7%bb%9c%e5%8d%95%e6%99%b6%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=261687","title":{"rendered":"\u6d59\u6c5f\u5927\u5b66Nat. Chem.\uff1a\u7f16\u7ec7\u7eaf\u6709\u673a\u805a\u5408\u7269\u7f51\u7edc\u5355\u6676\uff01"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><\/p>\n<p>\u7f16\u7ec7\u662f\u4eba\u7c7b\u6700\u53e4\u8001\u7684\u4f20\u7edf\u6280\u827a\u4e4b\u4e00\uff0c\u81ea\u77f3\u5668\u65f6\u4ee3\u8d77\uff0c\u8fd9\u4e00\u6280\u827a\u5728\u65e5\u5e38\u751f\u6d3b\u548c\u751f\u4ea7\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\u548c\u63a8\u5d07\u3002\u6570\u5343\u5e74\u6765\u7684\u5b9e\u8df5\u8bc1\u660e\uff0c\u5728\u5b8f\u89c2\u548c\u5fae\u89c2\u5c42\u9762\u4e0a\uff0c\u7f16\u7ec7\u662f\u4e00\u79cd\u7ecf\u4e45\u4e0d\u8870\u7684\u5f3a\u5927\u5de5\u5177\uff0c\u53ef\u4ee5\u7528\u76f8\u5bf9\u7b80\u5355\u76841D\u80a1\u7ebf\u7f16\u7ec7\u51fa\u529f\u80fd\u6027\u76842D\u548c3D\u7ec7\u7269\u3002\u5206\u5b50\u7f16\u7ec7\u7684\u65b9\u5f0f\u8ba9\u79d1\u5b66\u5bb6\u8054\u60f3\u5230\u5b8f\u89c2\u7ec7\u7269\u7684\u5236\u4f5c\uff0c\u5b83\u5c55\u793a\u4e86\u81ea\u4e0b\u800c\u4e0a\u8c03\u8282\u6750\u6599\u7279\u6027\u7684\u53ef\u80fd\u6027\uff0c\u8fd9\u662f\u62d3\u6251\u7ed3\u6784\u4ece\u5206\u5b50\u7ebf\u5f00\u59cb\u7684\u7ed3\u679c\u3002\u7f16\u7ec7\u6280\u672f\u7684\u7eb3\u7c73\u7ea7\u5e94\u7528\u88ab\u8ba4\u4e3a\u662f\u6784\u5efa\u591a\u529f\u80fd\u65b0\u6750\u6599\u7684\u6709\u524d\u9014\u7684\u7b56\u7565\u3002\u5c06\u7eaf\u6709\u673a\u5206\u5b50\u7ebf\u7f16\u7ec7\u6210\u5b8c\u7f8e\u65e0\u7455\u7684\u4e8c\u7ef4\u56fe\u6848\u4ecd\u7136\u662f\u4e00\u4e2a\u8270\u5de8\u7684\u6311\u6218\uff0c\u7eaf\u6709\u673a\u3001\u72ec\u7acb\u4e8c\u7ef4\u7f16\u7ec7\u805a\u5408\u7269\u7f51\u7edc\uff082D WPNs\uff09\u7684\u5355\u6676\u5c1a\u672a\u5f97\u5230\u5168\u9762\u7814\u7a76\u3002\u56e0\u6b64\uff0c\u5728\u8ba8\u8bba\u4e8c\u7ef4\u7f16\u7ec7\u6750\u6599\u7684\u5f62\u6210\u673a\u7406\u548c\u7ed3\u6784\u2014\u6027\u80fd\u5173\u7cfb\u65f6\uff0c\u5f88\u96be\u83b7\u5f97\u7cbe\u786e\u7684\u7ed3\u6784\u4fe1\u606f\uff0c\u5982\u805a\u5408\u7269\u7f51\u7edc\u4e2d\u539f\u5b50\u7684\u952e\u957f\u3001\u952e\u89d2\u548c\u7a7a\u95f4\u4f4d\u7f6e\u3002\u6b64\u5916\uff0c\u4ece\u5c42\u72b6\u6750\u6599\u4e2d\u5265\u79bb\u51fa\u6765\u7684\u72ec\u7acb\u4e8c\u7ef4\u5355\u5c42\u7f16\u7ec7\u7247\u4e5f\u975e\u5e38\u7a00\u5c11\uff0c\u8fd9\u5bf9\u6709\u6548\u63a2\u7d22\u5176\u591a\u6837\u5316\u7684\u8868\u9762\u548c\u7ed3\u6784\u7279\u5f81\u6784\u6210\u4e86\u969c\u788d\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u4ee5\u4e0a\u96be\u9898\uff0c<strong>\u6d59\u6c5f\u5927\u5b66\u9ec4\u98de\u9e64\u6559\u6388\u3001\u674e\u5149\u950b\u7814\u7a76\u5458\u3001\u7f8e\u56fd\u897f\u5317\u5927\u5b66<\/strong><strong>J. Fraser Stoddart<\/strong><strong>\u6559\u6388\u548c\u6d59\u6c5f\u5de5\u4e1a\u5927\u5b66\u6731\u827a\u6db5\u6559\u6388<\/strong>\u7b49\u4eba\u5408\u4f5c\uff0c\u5728<strong><em>Nature Chemistry<\/em><\/strong>\u53d1\u8868\u4e86\u9898\u4e3a\u201c<strong>Single crystals of purely organic free-standing two-dimensional woven polymer networks<\/strong>\u201d\u7684\u8bba\u6587\uff0c\u4ecb\u7ecd\u4e86\u4e00\u79cd\u7531\u53cc\u5411 B-N \u952e\u9a71\u52a8\u7684\u65e0\u7f3a\u9677\u3001\u7eaf\u6709\u673a\u3001\u72ec\u7acb\u7684\u4e8c\u7ef4\u7f16\u7ec7\u805a\u5408\u7269\u7f51\u7edc\u7684\u5408\u6210\u3002\u7814\u7a76\u4eba\u5458\u83b7\u5f97\u4e86\u8fd9\u79cd\u7f16\u7ec7\u805a\u5408\u7269\u7f51\u7edc\u7684\u5355\u6676\uff0c\u901a\u8fc7 XRD\u5206\u6790\u63ed\u793a\u4e86\u5176\u6e05\u6670\u7684\u7f16\u7ec7\u62d3\u6251\u7ed3\u6784\uff0c\u5e76\u901a\u8fc7\u673a\u68b0\u5265\u79bb\u5f97\u5230\u4e86\u539a\u5ea6\u4e3a1.3 nm\u7684\u5355\u5c42\u5206\u5b50\u7f16\u7ec7\u805a\u5408\u7269\u7eb3\u7c73\u7247\u3002\u968f\u540e\u901a\u8fc7\u7efc\u5408\u4f4e\u5242\u91cf\u548c\u4f4e\u6e29\u7535\u5b50\u663e\u5fae\u955c\u6210\u50cf\u6280\u672f\u7814\u7a76\u4e86\u7eb3\u7c73\u7247\u7684\u8868\u9762\u7279\u5f81\u3002\u8fd9\u4e9b\u7814\u7a76\u7ed3\u679c\u8868\u660e\u4e86\u7eaf\u6709\u673a\u7f16\u7ec7\u805a\u5408\u7269\u7f51\u7edc\u7684\u7cbe\u786e\u6784\u9020\uff0c\u5e76\u5f3a\u8c03\u4e86\u5728\u4e8c\u7ef4\u6709\u673a\u6750\u6599\u4e2d\u5e94\u7528\u7f16\u7ec7\u62d3\u6251\u7ed3\u6784\u7684\u72ec\u7279\u673a\u9047\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261688\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/0-12.png\" alt=\"\" width=\"600\" height=\"297\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/0-12.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/0-12-300x149.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u7814\u7a76\u4eba\u5458\u4f7f\u7528\u4e24\u4e2a\u7b80\u5355\u7684\u914d\u4f531,4-\u82ef\u4e8c\u787c\u9178\u90bb\u4e8c\u82ef\u915a\u916f\u4e0e1,2-\u4e8c(4-\u5421\u5576\u57fa)\u4e59\u70ef\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5408\u6210\u4e86\u5927\u5c3a\u5bf8\u7684\u7247\u72b6\u5206\u5b50\u7f16\u7ec7\u805a\u5408\u7269\u5355\u66762DWPN-1\uff0c\u5e76\u901a\u8fc7XRD\u5bf9\u5176\u7ed3\u6784\u8fdb\u884c\u5206\u6790\u3002\u5149\u5b66\u663e\u5fae\u56fe\u50cf\u663e\u793a\uff0c2DWPN-1\u7684\u5398\u7c73\u7ea7\u9ec4\u8272\u5355\u6676\u5177\u6709\u88c2\u9699\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261689\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/1-25.png\" alt=\"\" width=\"600\" height=\"651\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/1-25.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/1-25-276x300.png 276w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1 \u00a0<\/strong><strong>\u4e8c\u7ef4\u5206\u5b50\u7f16\u7ec7\u805a\u5408\u7269\u7684\u5236\u5907\u53ca\u5176\u7ed3\u6784\u8868\u5f81<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p>\u901a\u8fc7\u5bf9\u7167\u5b9e\u9a8c\uff0c\u7814\u7a76\u4eba\u5458\u8bc1\u5b9e\u4e86\u6eb6\u5242\u5206\u5b50\u5728\u7f16\u7ec7\u62d3\u6251\u5f62\u6210\u7684\u8fc7\u7a0b\u4e2d\u8d77\u5230\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261690\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/2-25.png\" alt=\"\" width=\"600\" height=\"738\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/2-25.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/2-25-244x300.png 244w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2 \u00a0<\/strong><strong>\u6eb6\u5242\u5bf9\u7f16\u7ec7\u62d3\u6251\u5f62\u6210\u7684\u5f71\u54cd<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p>\u53d7\u77f3\u58a8\u70ef\u5265\u79bb\u5236\u5907\u7684\u542f\u53d1\uff0c\u7814\u7a76\u4eba\u5458\u5c1d\u8bd5\u4e86\u91c7\u7528\u673a\u68b0\u5265\u79bb\u7684\u65b9\u6cd5\u5bf9\u5927\u5757\u7684\u6676\u4f53\u8fdb\u884c\u5265\u79bb\uff0c\u6700\u7ec8\u6210\u529f\u5f97\u5230\u4e86\u4e0d\u540c\u5c42\u6570\u7684\u8584\u5c42\u5206\u5b50\u7f16\u7ec7\u805a\u5408\u7269\u7eb3\u7c73\u7247\uff0c\u5355\u5c42\u539a\u5ea6\u4ec5\u4e3a1.3 nm\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261691\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/3-24.png\" alt=\"\" width=\"600\" height=\"770\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/3-24.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/3-24-234x300.png 234w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3 \u00a0<\/strong><strong>\u5206\u5b50\u7f16\u7ec7\u805a\u5408\u7269\u7684\u5265\u79bb\u53ca\u5176\u8584\u5c42\u7ed3\u6784\u8868\u5f81<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261692\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/4-22.png\" alt=\"\" width=\"600\" height=\"383\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/4-22.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/4-22-300x192.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4 \u00a0<\/strong><strong>\u4e8c\u7ef4\u5206\u5b50\u7f16\u7ec7\u805a\u5408\u7269\u7684\u9ad8\u500d\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261693\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/5-12.png\" alt=\"\" width=\"600\" height=\"535\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/5-12.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/07\/5-12-300x268.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5 \u00a0<\/strong><strong>\u4e8c\u7ef4\u5206\u5b50\u7f16\u7ec7\u805a\u5408\u7269\u7684\u673a\u68b0\u6027\u80fd<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u5e76\u6784\u5efa\u4e86\u4e00\u7c7b\u57fa\u4e8e\u914d\u4f4dB-N\u952e\u9a71\u52a8\u7684\u7eaf\u6709\u673a\u4e8c\u7ef4\u7f16\u7ec7\u805a\u5408\u7269\u7f51\u7edc\u3002\u901a\u8fc7X\u5c04\u7ebf\u5355\u6676\u5206\u6790\u548c\u5bf9\u6bd4\u5b9e\u9a8c\u9a8c\u8bc1\u4e86\u6eb6\u5242\u5206\u5b50\u5728\u7f16\u7ec7\u62d3\u6251\u7ed3\u6784\u5f62\u6210\u8fc7\u7a0b\u4e2d\u7684\u5173\u952e\u4f5c\u7528\u3002\u6b64\u5916\uff0c\u5229\u7528\u5fae\u673a\u68b0\u5265\u79bb\u6cd5\u6210\u529f\u5730\u5236\u5907\u51fa\u4e86\u539a\u5ea6\u4e3a1.3 nm\u7684\u4e8c\u7ef4\u5206\u5b50\u7f16\u7ec7\u805a\u5408\u7269\u7eb3\u7c73\u7247\uff0c\u83b7\u5f97\u4e86\u5168\u65b0\u7684\u4e8c\u7ef4\u805a\u5408\u7269\u6750\u6599\u3002\u968f\u540e\uff0c\u901a\u8fc7\u4f4e\u5242\u91cf\u51b7\u51bb\u7535\u955c\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u76f4\u63a5\u3001\u6e05\u6670\u548c\u51c6\u786e\u5730\u5c55\u793a\u4e86\u5206\u5b50\u7f16\u7ec7\u805a\u5408\u7269\u7ed3\u6784\u7279\u5f81\u3002\u6b64\u5916\uff0c\u7f16\u7ec7\u62d3\u6251\u7ed3\u6784\u63d0\u4f9b\u4e86\u4e00\u79cd\u72ec\u7279\u800c\u6709\u6548\u7684\u5e94\u529b\u5206\u6563\u9014\u5f84\uff0c\u5e76\u63d0\u9ad8\u4e86\u521a\u6027\u6676\u4f53\u7684\u67d4\u97e7\u6027\u3002\u8fd9\u9879\u7814\u7a76\u4e0d\u4ec5\u63d0\u51fa\u4e86\u4e00\u79cd\u5c06\u7eaf\u6709\u673a\u7f16\u7ec7\u805a\u5408\u7269\u7f51\u7edc\u4f5c\u4e3a\u7ed3\u6784\u5947\u89c2\u7684\u6709\u6548\u65b9\u6cd5\uff0c\u800c\u4e14\u8fd8\u63ed\u793a\u4e86\u5b83\u4eec\u7684\u5f62\u6210\u673a\u5236\uff0c\u4ee5\u53ca\u7f16\u7ec7\u805a\u5408\u7269\u7f51\u7edc\u7684\u4e8c\u7ef4\u7279\u5f81\u548c\u673a\u68b0\u6027\u80fd\uff0c\u4e3a\u7531\u7eaf\u6709\u673a\u72ec\u7acb\u5f0f2D WPNs\u6784\u5efa\u7684\u529f\u80fd\u6750\u6599\u6253\u5f00\u4e86\u5927\u95e8\u3002<\/p>\n<p>\u539f\u6587\u8be6\u60c5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41557-024-01580-3\" target=\"_blank\" rel=\"noopener\">Single crystals of purely organic free-standing two-dimensional woven polymer networks<\/a> (<em>Nat. Chem.<\/em> <strong>2024<\/strong>, DOI: 10.1038\/s41557-024-01580-3)<\/p>\n<p>\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011 \u7f16\u7ec7\u662f\u4eba\u7c7b\u6700\u53e4\u8001\u7684\u4f20\u7edf\u6280\u827a\u4e4b\u4e00\uff0c\u81ea\u77f3\u5668\u65f6\u4ee3\u8d77\uff0c\u8fd9\u4e00\u6280\u827a\u5728\u65e5\u5e38\u751f\u6d3b\u548c\u751f\u4ea7\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\u548c\u63a8\u5d07\u3002\u6570\u5343\u5e74\u6765\u7684\u5b9e\u8df5\u8bc1\u660e\uff0c\u5728\u5b8f\u89c2\u548c\u5fae\u89c2\u5c42\u9762\u4e0a\uff0c\u7f16\u7ec7\u662f\u4e00&#8230;<\/p>\n","protected":false},"author":36791,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-261687","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/261687"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/36791"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=261687"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/261687\/revisions"}],"predecessor-version":[{"id":261694,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/261687\/revisions\/261694"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=261687"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=261687"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=261687"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}