{"id":261117,"date":"2024-06-28T08:16:56","date_gmt":"2024-06-28T00:16:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=261117"},"modified":"2024-06-28T08:16:56","modified_gmt":"2024-06-28T00:16:56","slug":"0-2a%ef%bc%8c%e8%b6%85%e4%bd%8e%e5%88%86%e8%be%a8%e7%8e%87%e6%b0%94%e4%bd%93%e5%88%86%e5%ad%90%e8%af%86%e5%88%ab%e7%99%bb%e4%b8%8ascience%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=261117","title":{"rendered":"0.2\u00c5\uff0c\u8d85\u4f4e\u5206\u8fa8\u7387\u6c14\u4f53\u5206\u5b50\u8bc6\u522b\u767b\u4e0aScience\uff01"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><\/p>\n<p>\u6c14\u4f53\u5206\u79bb\u901a\u5e38\u4f7f\u7528\u56fa\u4f53\u819c\u8fdb\u884c\uff0c\u56e0\u4e3a\u5f88\u96be\u5236\u9020\u51fa\u5b54\u9699\u5c0f\u5230\u8db3\u4ee5\u5728\u5177\u6709\u76f8\u4f3c\u539f\u5b50\u5927\u5c0f\u7684\u6c14\u4f53\u4e4b\u95f4\u5206\u79bb\u7684\u591a\u5b54\u819c\u3002\u5fae\u5b54\u6676\u4f53\u6750\u6599\uff0c\u5982\u91d1\u5c5e\u548c\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08\u5206\u522b\u4e3aMOFs\u548cCOFs\uff09\u4ee5\u53ca\u6cb8\u77f3\uff0c\u5728\u4f20\u611f\u3001\u50ac\u5316\u548c\u5206\u5b50\u5206\u79bb\u7b49\u65b9\u9762\u6709\u5e7f\u6cdb\u5e94\u7528\u3002\u4f20\u7edf\u7684\u7f51\u72b6\u5316\u5b66\u548c\u5408\u6210\u540e\u4fee\u9970\u53ef\u4ee5\u83b7\u5f97\u6ee1\u8db3\u76ee\u6807\u5e94\u7528\u8981\u6c42\u7684\u7279\u5b9a\u5b54\u5f84\u3002\u5076\u5c14\u4e00\u4e9b\u6750\u6599\u4e5f\u4f1a\u8868\u73b0\u51fa\u67d4\u6027\uff0c\u5177\u6709\u523a\u6fc0\u8bf1\u5bfc\u7684\u5b54\u5f62\u72b6\u548c\u5c3a\u5bf8\u53ef\u8c03\u6027\uff0c\u4f7f\u5f97\u80fd\u591f\u5728\u5355\u4e2a\u6750\u6599\u5185\u8c03\u8282\u5b54\u4ee5\u9002\u5e94\u76ee\u6807\u5e94\u7528\u3002\u8fd9\u79cd\u6750\u6599\u7684\u67d4\u6027\u901a\u5e38\u6e90\u4e8e\u5f31\u952e\u54cd\u5e94\u5916\u90e8\u523a\u6fc0\u7684\u5b9e\u8d28\u6027\u8fd0\u52a8\uff0c\u4f8b\u5982\u5206\u5b50\u7684\u5438\u9644\u54cd\u5e94\u6e29\u5ea6\u6216\u538b\u529b\u7684\u53d8\u5316\u3002\u8fd9\u901a\u5e38\u4f1a\u5f15\u53d1\u76f8\u5bf9\u8f83\u5927\u7684\u5b54\u5f84\u53d8\u5316\uff083\u81f35\u00c5\uff09\uff0c\u5927\u4e8e\u9009\u62e9\u6027\u8bc6\u522b\u5c0f\u5206\u5b50\u6240\u9700\u7684\u4e9a\u57c3\u5c3a\u5ea6\u3002\u4f9d\u8d56\u4e8e\u5c40\u90e8\u5206\u5b50\u8fd0\u52a8\u7684\u6750\u6599\u53ef\u4ee5\u5b9e\u73b0\u9002\u5408\u4e8e\u5206\u5b50\u5206\u79bb\u7684\u5b54\u9699\u8c03\u8282\uff0c\u4f8b\u5982\uff0c\u4ee5\u533a\u5206\u540c\u4f4d\u7d20\u6216\u5c0f\u5206\u5b50\u70c3\u7c7b\u3002\u8fd9\u4e9b\u6750\u6599\u901a\u8fc7\u6269\u6563\u901f\u7387\u5dee\u6765\u533a\u5206\u5206\u5b50\uff0c\u8fd9\u53d6\u51b3\u4e8e\u8d28\u91cf\u800c\u4e0d\u662f\u5c3a\u5bf8\u7684\u5dee\u5f02\u3002\u7136\u800c\uff0c\u4f7f\u7528\u5177\u6709\u53ef\u9006\u3001\u8fde\u7eed\u53ef\u8c03\u5b54\u9699\u7684\u6676\u4f53\u6750\u6599\uff0c\u6839\u636e\u5c0f\u5206\u5b50\u7684\u771f\u5b9e\u5f62\u72b6\u548c\u5927\u5c0f\u6765\u533a\u5206\u5b83\u4eec\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u56e0\u4e3a\u8981\u5b9e\u73b0\u6b63\u597d\u4f4d\u4e8e\u4e24\u4e2a\u5206\u5b50\u5927\u5c0f\u4e4b\u95f4\u7684\u5b54\u9699\uff0c\u9700\u8981\u8d85\u9ad8\u7cbe\u5ea6\u7684\u53ef\u8c03\u6027\uff0c\u8fd9\u5c31\u9700\u8981\u5728\u7ed3\u6784\u521a\u5ea6\u548c\u5f31\u5206\u5b50\u8fd0\u52a8\u4e4b\u95f4\u5b9e\u73b0\u5fae\u5999\u5e73\u8861\u7684\u6750\u6599\u8bbe\u8ba1\uff0c\u4ee5\u4fdd\u6301\u957f\u7a0b\u79e9\u5e8f\u548c\u5c40\u90e8\u67d4\u6027\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u4ee5\u4e0a\u96be\u9898\uff0c<strong>\u7f8e\u56fd\u79d1\u7f57\u62c9\u591a\u5927\u5b66\u535a\u5c14\u5fb7\u5206\u6821\u5f20\u4f1f\u6559\u6388\u4e0e\u7ebd\u7ea6\u5dde\u7acb\u5927\u5b66\u5e03\u6cd5\u7f57\u5206\u6821<\/strong><strong>Yu Miao<\/strong>\u5408\u4f5c\uff0c\u5728<strong><em>Science<\/em><\/strong>\u53d1\u8868\u4e86\u9898\u4e3a\u201c<strong>Molecular recognition with resolution below 0.2 angstroms through thermoregulatory oscillations in covalent organic frameworks<\/strong>\u201d\u7684\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u901a\u8fc7\u56db\u82ef\u6c27\u57fa\u787c\u9178\u916f\u952e\u8fde\u63a5\uff0c\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u79bb\u5b50\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08ICOFs\uff09\uff0c\u8be5\u952e\u4fdd\u6301\u7ed3\u6784\u521a\u6027\u548c\u5c40\u90e8\u67d4\u6027\u4e4b\u95f4\u7684\u7cbe\u7ec6\u534f\u540c\u4f5c\u7528\uff0c\u4ee5\u5b9e\u73b02.9 \u00c5\u81f34.0 \u00c5\u4e4b\u95f4\u7684\u201c\u52a8\u6001\u5b54\u9699\u201d\u7684\u8fde\u7eed\u548c\u53ef\u9006\uff08100\u4e2a\u70ed\u5faa\u73af\uff09\u8c03\u8282\uff0c\u5206\u8fa8\u7387\u4f4e\u4e8e0.2 \u00c5\u3002\u8fd9\u5f97\u76ca\u4e8e\u9ad8\u9891\u5316\u5b66\u952e\u632f\u8361\u7684\u6e29\u5ea6\u8c03\u8282\u548c\u632f\u5e45\u9010\u6e10\u53d8\u5316\u3002\u8fd9\u4e9b\u70ed\u5f39\u6027\u5b54\u9699\u53ef\u4ee5\u9009\u62e9\u6027\u5730\u963b\u6321\u4f53\u79ef\u8f83\u5927\u7684\u5206\u5b50\uff0c\u8bc1\u660e\u4e86\u57fa\u4e8e\u5c3a\u5bf8\u7684\u5206\u5b50\u8bc6\u522b\u4ee5\u53ca\u5206\u79bb\u5177\u6709\u6311\u6218\u6027\u7684\u6c14\u4f53\u6df7\u5408\u7269\uff08\u5982\u6c27\u6c14\/\u6c2e\u6c14\u548c\u6c2e\u6c14\/\u7532\u70f7\uff09\u7684\u6f5c\u529b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261118\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/0-11.png\" alt=\"\" width=\"600\" height=\"294\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/0-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/0-11-300x147.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261119\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/1-6.jpg\" alt=\"\" width=\"600\" height=\"526\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/1-6.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/1-6-300x263.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1 \u00a02D ICOFs<\/strong><strong>\u7684\u5408\u7406\u8bbe\u8ba1\u53ca\u5408\u6210<\/strong><strong> \u00a9 2024 AAAS<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261120\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/2-7.jpg\" alt=\"\" width=\"600\" height=\"454\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/2-7.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/2-7-300x227.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2 \u00a0<\/strong><strong>\u4e9a\u57c3\u7ea7<\/strong><strong>ICOFs<\/strong><strong>\u7cbe\u786e\u70ed\u8c03\u8282\u5206\u5b50\u7b5b\u5206<\/strong> <strong>\u00a9 2024 AAAS<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261121\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/3-7.jpg\" alt=\"\" width=\"600\" height=\"745\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/3-7.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/3-7-242x300.jpg 242w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3 \u00a0ICOFs<\/strong><strong>\u4e2d\u6e29\u5ea6\u76f8\u5173\u7ed3\u6784\u53d8\u5316\u7684\u8ba1\u7b97\u6a21\u578b<\/strong><strong> \u00a9 2024 AAAS<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261122\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/4-6.jpg\" alt=\"\" width=\"600\" height=\"582\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/4-6.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/4-6-300x291.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4 \u00a0<\/strong><strong>\u6e29\u5ea6\u53d8\u5316\u5bf9<\/strong><strong>ICOFs<\/strong><strong>\u5438\u9644\u884c\u4e3a\u7684\u5f71\u54cd\u53ca\u4e0e\u5df2\u6709\u7684\u5438\u9644\u5242\u7684\u5bf9\u6bd4<\/strong><strong> \u00a9 2024 AAAS<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n<p>\u672c\u7814\u7a76\u62a5\u9053\u4e86\u901a\u8fc7\u7b80\u5355\u7684\u52a8\u6001\u787c\u9178\u76d0\u5316\u5b66\uff0c\u5229\u7528\u6613\u4e8e\u83b7\u5f97\u7684\u4e8c\u5143\u9187\u6784\u5efa\u6a21\u5757\u5408\u6210\u7684ICOFs\u7684\u53ef\u9006\u3001\u8d85\u9ad8\u7cbe\u5ea6\u5b54\u9699\u53ef\u8c03\u6027\u3002\u7531\u4e8eICOFs\u4e2d\u7684\u5f3a\u5171\u4ef7\u952e\u548c\u8f83\u5f31\u7684\u79bb\u5b50\u2014\u5076\u6781\u5b50\u76f8\u4e92\u4f5c\u7528\u5177\u6709\u7ec6\u81f4\u7684\u534f\u540c\u4f5c\u7528\uff0c\u56e0\u6b64\u5f53\u6e29\u5ea6\u4ece25\u2103\u53d8\u5316\u523095\u2103\u65f6\uff0c\u57282.9\u52304.0 \u00c5\u7684\u5b54\u5f84\u8303\u56f4\u5185\uff0c\u5fae\u5b54\u8c03\u6574\u7684\u5206\u8fa8\u7387\u5c0f\u4e8e0.2 \u00c5\u3002\u8fd9\u79cd\u7cbe\u786e\u7684\u3001\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u5b54\u9699\u6536\u7f29\u662f\u7531\u5feb\u901f\u5c40\u90e8\u5316\u5b66\u952e\u632f\u8361\u63a7\u5236\u7684\uff0c\u632f\u8361\u7684\u5e45\u5ea6\u968f\u6e29\u5ea6\u53d8\u5316\u800c\u53d8\u5316\uff0c\u4ece\u800c\u8c03\u6574ICOFs\u4e2d\u7684\u5b54\u9699\u3002\u6b64\u5916\uff0cICOFs\u5728\u4fdd\u6301\u7cbe\u786e\u3001\u53ef\u9006\u7684\u5b54\u9699\u53ef\u8c03\u6027\u7684\u540c\u65f6\uff0c\u8fd8\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u7ed3\u6784\u7a33\u5065\u6027\uff08\u81f3\u5c11\u53ef\u8fbe100\u6b21\u70ed\u5faa\u73af\uff09\u3002\u5bf9\u4e8e\u96be\u4ee5\u5206\u79bb\u7684\u3001\u5de5\u4e1a\u4e0a\u91cd\u8981\u7684\u6c14\u4f53\u5bf9O<sub>2\/<\/sub>N<sub>2<\/sub>\u548cN<sub>2<\/sub>\/CH<sub>4<\/sub>\uff0c\u8868\u73b0\u51fa\u4e86\u5f88\u9ad8\u7684\u9009\u62e9\u6027\u3002\u901a\u8fc7TRMS\u5728\u4e9a\u7eb3\u7c73\u5c3a\u5ea6\u5185\u5b9e\u73b0\u8fde\u7eed\u3001\u53ef\u9006\u7684\u5b54\u53ef\u8c03\u8c10\u6027\u7684\u8fd9\u79cd\u7cbe\u5ea6\uff0c\u53ef\u80fd\u4f1a\u4f7f\u5fae\u5b54\u6676\u4f53\u6750\u6599\u5728\u4e0d\u540c\u9886\u57df\u5f97\u5230\u65b0\u7684\u3001\u66f4\u6709\u6548\u7684\u5229\u7528\u3002<\/p>\n<p>\u539f\u6587\u8be6\u60c5\uff1a<a href=\"https:\/\/www.science.org\/doi\/10.1126\/science.adj8791\" target=\"_blank\" rel=\"noopener\">Molecular recognition with resolution below 0.2 angstroms through thermoregulatory oscillations in covalent organic frameworks<\/a> (<em>Science<\/em> <strong>2024<\/strong>, 384, 1441-1447)<\/p>\n<p>\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011 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