{"id":261060,"date":"2024-06-27T07:51:39","date_gmt":"2024-06-26T23:51:39","guid":{"rendered":"\/\/m.iemloyee.com\/?p=261060"},"modified":"2024-06-26T22:28:14","modified_gmt":"2024-06-26T14:28:14","slug":"%e9%a6%99%e6%b8%af%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6%e4%ba%8e%e6%b6%b5%e3%80%81%e9%a2%9c%e6%b2%b3%e3%80%8aees%e3%80%8b%ef%bc%9a%e7%83%b7%e6%b0%a7%e5%9f%ba%e5%8f%96%e4%bb%a3%e8%81%9a%e5%90%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=261060","title":{"rendered":"\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u4e8e\u6db5\u3001\u989c\u6cb3\u300aEES\u300b\uff1a\u70f7\u6c27\u57fa\u53d6\u4ee3\u805a\u5408\u7269\u53d7\u4f53\u6709\u6548\u964d\u4f4e\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u80fd\u91cf\u635f\u5931\uff0c\u5b9e\u73b0\u9ad8\u6548\u5ba4\u5916\/\u5ba4\u5185\u5149\u4f0f\u591a\u529f\u80fd\u5e94\u7528"},"content":{"rendered":"<p>\u76f8\u6bd4\u4e8e\u65e0\u673a\u534a\u5bfc\u4f53\uff0c\u6709\u673a\u534a\u5bfc\u4f53\u6750\u6599\u6700\u5927\u7684\u4f18\u52bf\u5c31\u5728\u4e8e\u53ef\u4ee5\u901a\u8fc7\u5408\u7406\u7684\u5316\u5b66\u4fee\u9970\u6765\u8c03\u8282\u5206\u5b50\u5185\u7684\u7535\u8377\u8f6c\u79fb(intramolecular charge transfer, ICT)\u6548\u5e94\uff0c\u4ece\u800c\u8c03\u8282\u5206\u5b50\u7684\u672c\u5f81\u5149\u8c31\u5438\u6536\u4ee5\u53ca\u5806\u79ef\u6027\u8d28\u3002\u9274\u4e8e\u76ee\u524d\u6700\u4e3a\u4e3b\u6d41\u7684Y-\u7cfb\u5217\u5c0f\u5206\u5b50\u53d7\u4f53\uff0c\u6211\u4eec\u5728\u4e4b\u524d\u7684\u5de5\u4f5c\u4e2d\u5df2\u7ecf\u6210\u529f\u5f00\u53d1\u51fa\u03b2-\u567b\u5429\u70f7\u6c27\u57fa\u53d6\u4ee3\u7b56\u7565\uff0c\u524a\u5f31ICT\u6548\u5e94\u4ece\u800c\u5c06\u5149\u8c31\u5438\u6536\u5cf0\u84dd\u79fb\u81f3750 nm\u5de6\u53f3(Adv. Energy Mater., 2021, 11, 2003141; Adv. Mater. 2024, 2405404)\uff0c\u4e0e\u5ba4\u5185LED\u706f\u7684\u53d1\u5c04\u5149\u8c31\u9ad8\u5ea6\u91cd\u53e0\uff0c\u6ee1\u8db3\u5ba4\u5185\u5149\u4f0f\u5668\u4ef6\u8981\u6c42\u3002\u4e0e\u6b64\u540c\u65f6\uff0c<strong><b>\u9999\u6e2f\u79d1\u6280<\/b><\/strong><strong><b>\u5927\u5b66\u4e8e\u6db5\u3001\u989c\u6cb3<\/b><\/strong>\u7814\u7a76\u56e2\u961f\u5728\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u8fd1\u4e9b\u5e74\u79ef\u7d2f\u4e86\u4e30\u539a\u7684\u5206\u5b50\u8bbe\u8ba1\u4e0e\u5668\u4ef6\u6027\u80fd\u7684\u7814\u7a76\u6210\u679c\uff08<strong><b>\u7aef\u57fa\u6c1f\u5316\u7b56\u7565<\/b><\/strong>\uff1aAdv. Energy Mater. 2021, 11, 2003171; Angew. Chem. 2021, 133, 10225-10234; Joule, 2021, 5, 1548-1565; Adv. Funct. Mater. 2021, 31, 2100791; Adv. Funct. Mater. 2023, 33, 2300712; Adv. Funct. Mater., 2024, 34, 2400131;<strong><b>\u4e59\u70ef\u57fa-\u521a\u6027\u6784\u8c61\u7b56\u7565<\/b><\/strong>\uff1aAdv. Mater. 2022, 34, 2200361; Adv. Sci., 2022, 9, 220222; Adv. Energy Mater., 2022, 12, 2202729; Nat. Commun., 2023, 14, 2323\uff09\u3002\u57fa\u4e8e\u4ee5\u4e0a\u7814\u7a76\u57fa\u7840\uff0c\u534f\u540c\u7684\u5206\u5b50\u8bbe\u8ba1\u7b56\u7565\u6709\u671b\u5b9e\u73b0\u9ad8\u6548\u3001\u7a33\u5b9a\u7684\u5168\u805a\u5408\u7269\u5149\u4f0f\u5668\u4ef6\u7528\u4e8e\u5ba4\u5916\u3001\u5ba4\u5185\u591a\u529f\u80fd\u5e94\u7528\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u8fd1\u671f\uff0c<strong><b>\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u989c\u6cb3\u3001\u4e8e\u6db5\u8bfe\u9898\u7ec4<\/b><\/strong>\u5408\u6210\u5e76\u7cfb\u7edf\u7814\u7a76\u4e86\u4e00\u79cd\u70f7\u6c27\u57fa\u53d6\u4ee3\u7684\u805a\u5408\u7269\u53d7\u4f53\uff08PYO-V\uff09\uff0c\u5176\u567b\u5429\u5206\u5b50\u4e0a\u6709\u4e00\u4e2a\u4f20\u7edf\u7684 Y \u7cfb\u5217\u4e2d\u5fc3\u6838\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u76f8\u6bd4\u4e8e\u7ecf\u5178\u7684PY-V-<em><i>\u03b3<\/i><\/em>\uff0c\u70f7\u6c27\u57fa\u53d6\u4ee3\u7684PYO-V\u5177\u6709\u84dd\u79fb\u7684\u5149\u8c31\u5438\u6536\u548c\u4e0a\u79fb\u7684LUMO\u80fd\u7ea7\uff0c\u8fd9\u5f97\u76ca\u4e8ePYO-V\u8f83\u5f31\u7684ICT\u6548\u5e94\u3002\u5f53\u5728 PM6:PY-V-<em><i>\u03b3<\/i><\/em>\u00a0\u4e3b\u4f53\u7cfb\u4e2d\u5f15\u5165PYO-V \u53ef\u5b9e\u73b0\u4e92\u8865\u7684\u5438\u6536\u5149\u8c31\uff0c\u5e76\u6709\u6548\u63a7\u5236\u80fd\u91cf\u635f\u5931\u3002\u56e0\u6b64\uff0cPM6:PY-V-<em><i>\u03b3<\/i><\/em>:PYO-V \u4e09\u5143\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60(all-PSCs)\u5668\u4ef6\u7684\u6548\u7387\u8fbe\u5230\u4e8618.5%\uff08\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u6700\u9ad8\u6548\u7387\u4e4b\u4e00\uff09\uff0c<em><i>V<\/i><\/em><sub>OC<\/sub>\u4e3a0.932 V\uff0c<em><i>J<\/i><\/em><sub>SC<\/sub>\u00a0\u4e3a25.9 mA cm<sup>-2<\/sup>\uff0c\u8fdc\u9ad8\u4e8e\u57fa\u4e8ePM6:PY-V-<em><i>\u03b3<\/i><\/em>\u7684\u5668\u4ef6\uff0817.3%\uff09\u3002\u9664\u4e86\u5ba4\u5916\u5149\u4f0f\u6280\u672f\uff0cPYO-V \u5728\u5ba4\u5185\u5149\u4f0f\u6280\u672f\u4e2d\u4e5f\u8868\u73b0\u51fa\u5176\u591a\u529f\u80fd\u5e94\u7528\u7684\u4e00\u9762\uff0c\u5176\u4e8c\u5143\u5668\u4ef6\u7684\u6548\u7387\u8fbe\u523024%\uff0c\u4e5f\u662f\u5168\u805a\u5408\u7269\u5ba4\u5185\u5149\u4f0f\u7684\u6700\u9ad8\u6548\u7387\u4e4b\u4e00\u3002\u8fd9\u9879\u5de5\u4f5c\u8868\u660e\uff0c\u70f7\u6c27\u57fa\u53d6\u4ee3\u662f\u8c03\u6574\u805a\u5408\u7269\u53d7\u4f53\u5149\u7535\u7279\u6027\u548c\u5b9e\u73b0\u9ad8\u6548\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u5e94\u7528\u7684\u6709\u6548\u7b56\u7565\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-261061 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72471-16.png\" alt=\"\" width=\"841\" height=\"464\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72471-16.png 841w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72471-16-300x166.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72471-16-768x424.png 768w\" sizes=\"(max-width: 841px) 100vw, 841px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>1<\/b><\/strong>.\u00a0\u672c\u6587\u6d89\u53ca\u7684\u805a\u5408\u7269\u53d7\u4f53\u7ed3\u6784\u3001\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\u3001\u7535\u5316\u5b66\u80fd\u7ea7\u3002<\/p>\n<p>\u5982\u56fe1\u6240\u793a\uff0cPY-V-<em><i>\u03b3<\/i><\/em>\u00a0\u548cPYO-V \u7684\u5149\u5b66\u5e26\u9699\u5206\u522b\u4e3a1.31 \u548c1.47 eV\u3002\u4e0e\u4e8c\u5143\u5171\u6df7\u7269\u76f8\u6bd4\uff0c\u5728\u4e09\u5143\u4f53\u7cfb\u4e2d\u6dfb\u52a020%wt\u7684PYO-V\u53ef\u589e\u5f3a\u5438\u6536\uff0c\u4fc3\u8fdb\u5149\u5b50\u6536\u96c6\u548c\u5149\u7535\u6d41\u751f\u6210\u3002\u4ee5\u4e0a\u7ed3\u679c\u63ed\u793a\u4e86\u70f7\u6c27\u57fa\u5bf9PYO-V\u5149\u7535\u7279\u6027\u7684\u5f71\u54cd\uff0c\u5e76\u8bc1\u660e\u4e86PYO-V\u4f5c\u4e3a\u4e09\u5143\u4f53\u7cfb\u4e2d\u7684\u5ba2\u4f53\u7ec4\u5206\u53ef\u4ee5\u5b9e\u73b0\u5149\u8c31\u4e92\u8865\u3001\u6291\u5236\u6709\u673a\u5149\u4f0f\u5668\u4ef6\u7684\u80fd\u91cf\u635f\u5931\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-261062 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72472-14.png\" alt=\"\" width=\"903\" height=\"483\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72472-14.png 903w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72472-14-300x160.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72472-14-768x411.png 768w\" sizes=\"(max-width: 903px) 100vw, 903px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>2<\/b><\/strong>.\u00a0\uff08a\uff09\u5149\u4f0f\u7279\u6027\u66f2\u7ebf\uff0c\uff08b\uff09\u5916\u91cf\u5b50\u6548\u7387\u66f2\u7ebf\uff0c\uff08c\uff09\u6697\u7535\u6d41\u62df\u5408\u7406\u60f3\u56e0\u5b50\uff08d\uff09\u65f6\u95f4\u5206\u8fa8\u5149\u81f4\u53d1\u5149\u6d4b\u8bd5\uff08TR-PL\uff09,\uff08e\uff09\u77ac\u6001\u5149\u7535\u6d41(TPC)\u548c\uff08f\uff09\u77ac\u6001\u5149\u7535\u538b(TPV)\u6d4b\u8bd5\u3002<\/p>\n<p>\u4e3a\u4e86\u8bc4\u4f30\u4e24\u79cd\u65b0\u578b\u805a\u5408\u7269\u53d7\u4f53\u5bf9\u5149\u4f0f\u6027\u80fd\u7684\u5f71\u54cd\uff0c\u4f5c\u8005\u9009\u62e9\u7ecf\u5178\u7684\u805a\u5408\u7269PM6\u4f5c\u4e3a\u7ed9\u4f53\u6765\u8fdb\u884c\u5668\u4ef6\u4f18\u5316\u3002\u521d\u6b65\u7ed3\u679c\u8868\u660e\uff0c\u867d\u7136\u57fa\u4e8ePYO-V\u7684\u4e8c\u5143\u5668\u4ef6\u8868\u73b0\u51fa\u8f83\u5f31\u7684\u5149\u4f0f\u6027\u80fd\uff0c\u4f46\u5f53\u5176\u4f5c\u4e3a\u7b2c\u4e09\u7ec4\u5206\u5f15\u5165\u5230\u4e3b\u4f53PM6:PY-V-<em><i>\u03b3<\/i><\/em>\u4e2d\u65f6\uff0c\u4e09\u5143\u5168\u805a\u5408\u7269\u4f53\u7cfb\u8868\u73b0\u51fa\u66f4\u5feb\u7684\u6fc0\u5b50\u89e3\u79bb\u6548\u7387\u3001\u8f7d\u6d41\u5b50\u626b\u9664\u6548\u7387\u4e0e\u88ab\u6291\u5236\u7684\u7535\u8377\u590d\u5408\u901f\u7387\u3002\u56e0\u6b64\uff0c\u4e09\u5143\u4f53\u7cfb\u5b9e\u73b0\u4e86\u660e\u663e\u63d0\u5347\u7684\u5149\u4f0f\u8f6c\u6362\u6548\u738718.5%.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-261063 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72473-13.png\" alt=\"\" width=\"838\" height=\"451\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72473-13.png 838w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72473-13-300x161.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72473-13-768x413.png 768w\" sizes=\"(max-width: 838px) 100vw, 838px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong>.\u00a0\u7ed3\u6676\u6027\u4e0e\u76f8\u5206\u79bb\u8868\u5f81\u7ed3\u679c\uff08GIWAXS and RSoXS\uff09\u3002<\/p>\n<p>\u7531\u4e8e\u70f7\u6c27\u4fa7\u94fe\u7684\u5f15\u5165\u4f7f\u5f97\u5206\u5b50\u7684\u6784\u8c61\u5f97\u4ee5\u9501\u5b9a\uff0c\u5206\u5b50\u94fe\u7ed3\u6676\u6027\u589e\u5f3a\u3002GIWAXS\u6d4b\u91cf\u8868\u660e\uff0c\u6dfb\u52a0PYO-V\u6539\u5584\u4e86PY-V-<em><i>\u03b3<\/i><\/em>\u00a0\u7684\u5206\u5b50\u5806\u79ef\u3002\u56e0\u6b64\uff0c\u4e09\u5143\u6df7\u5408\u8584\u819c\u5177\u6709\u66f4\u597d\u7684\u7535\u8377\u4f20\u8f93\u548c\u5668\u4ef6\u6027\u80fd\u3002RSoXS\u6d4b\u91cf\u7ed3\u679c\u8868\u660e\uff0c\u6df7\u5408\u8584\u819c\u5177\u6709\u4e0d\u540c\u7684\u76f8\u7eaf\u5ea6\u548c\u957f\u5ea6\u5c3a\u5ea6\u76f8\u5206\u79bb\u3002\u6dfb\u52a020%\u7684PYO-V\u53ef\u589e\u5f3a\u53d7\u4f53\u90e8\u5206\u76f8\u533a\u7eaf\u5ea6\uff0c\u4fdd\u6301\u4e09\u5143\u5668\u4ef6\u7684\u5f62\u8c8c\u5e76\u4fc3\u8fdb\u7535\u8377\u7684\u4f20\u8f93\u4e0e\u6536\u96c6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-261064 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72474-13.png\" alt=\"\" width=\"813\" height=\"707\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72474-13.png 813w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72474-13-300x261.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72474-13-768x668.png 768w\" sizes=\"(max-width: 813px) 100vw, 813px\" \/><\/p>\n<p><strong><b>\u56fe4<\/b><\/strong><strong><b>\u00a0<\/b><\/strong>\u77ac\u6001\u5438\u6536\u5149\u8c31\u8868\u5f81\u3002<\/p>\n<p>\u968f\u540e\uff0c\u4f5c\u8005\u5229\u7528\u77ac\u6001\u5438\u6536\u5149\u8c31\u7814\u7a76\u4e86\u539f\u59cb\u8584\u819c\u548c\u6df7\u5408\u8584\u819c\u7684\u6fc0\u5b50\u52a8\u529b\u5b66\u3002\u4e0ePY-V-<em><i>\u03b3<\/i><\/em>\u548cPY-V-<em><i>\u03b3<\/i><\/em>:PYO-V\u76f8\u6bd4\uff0cPYO-V\u7684\u6fc0\u5b50\u8870\u51cf\u65f6\u95f4\u8f83\u6162\u3002\u4e0e\u4e8c\u5143\u5171\u6df7\u7269\u76f8\u6bd4\uff0c\u4e09\u5143\u5171\u6df7\u7269\u5177\u6709\u66f4\u5feb\u7684\u7a7a\u7a74\u8f6c\u79fb\u901f\u7387\u548c\u8f83\u6162\u7684\u8870\u51cf\u901f\u7387\uff0c\u4ece\u800c\u5b9e\u73b0\u66f4\u597d\u7684\u00a0<em><i>J<\/i><\/em><sub>SC<\/sub>\u548cFF\u3002\u8fd9\u79cd\u6539\u5584\u5f52\u529f\u4e8e\u6dfb\u52a0PYO-V\u540e\u4f18\u5316\u7684\u4f9b\u4f53-\u53d7\u4f53\u754c\u9762\u5f62\u6001\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-261065 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72475-9.png\" alt=\"\" width=\"1975\" height=\"953\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72475-9.png 1975w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72475-9-300x145.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72475-9-768x371.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72475-9-1024x494.png 1024w\" sizes=\"(max-width: 1975px) 100vw, 1975px\" \/><\/p>\n<p><strong><b>\u56fe5<\/b><\/strong>\u00a0\u7535\u538b\u635f\u8017\u6d4b\u8bd5<\/p>\n<p>\u4e3a\u4e86\u91cf\u5316\u4f7f\u7528PYO-V \u53d7\u4f53\u7684\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u4e2d\u7684\u80fd\u91cf\u635f\u8017\uff0c\u6211\u4eec\u8fdb\u884c\u4e86\u5b9e\u9a8c\u7814\u7a76\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4e0ePM6:PY-V-<em><i>\u03b3<\/i><\/em>\u00a0\u548cPM6:PYO-V \u76f8\u6bd4\uff0cPM6:PY-V-\u03b3 \u6df7\u5408\u7269\u5177\u6709\u66f4\u4f4e\u7684\u975e\u8f90\u5c04\u590d\u5408\u548c\u7535\u538b\u635f\u8017\u3002\u4e09\u5143\u5668\u4ef6\u7684<em><i>E<\/i><\/em><sub>loss<\/sub>\uff080.499 eV\uff09\u662f\u76ee\u524dall-PSC\u4e2d\u6700\u5c0f\u503c\uff0c\u751a\u81f3\u8d85\u8fc7\u4e86\u67d0\u4e9b\u57fa\u4e8e\u5c0f\u5206\u5b50\u53d7\u4f53\u7684\u9ad8\u6027\u80fd\u5668\u4ef6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-261066 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72476-6.png\" alt=\"\" width=\"1768\" height=\"899\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72476-6.png 1768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72476-6-300x153.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72476-6-768x391.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72476-6-1024x521.png 1024w\" sizes=\"(max-width: 1768px) 100vw, 1768px\" \/><\/p>\n<p><strong><b>\u56fe6<\/b><\/strong>\u00a0\u5149\u7a33\u5b9a\u6027\u6d4b\u8bd5\u53ca\u5ba4\u5185\u5e94\u7528<\/p>\n<p>\u6700\u540e\uff0c\u5229\u7528\u6700\u5927\u529f\u7387\u70b9\u8ddf\u8e2a\uff08MPPT\uff09\u6280\u672f\u8bc4\u4f30\u4e86\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u7684\u8fd0\u884c\u7a33\u5b9a\u6027\u300270\u5c0f\u65f6\u540e\uff0c\u4e8c\u5143\u5668\u4ef6\u7684PCE\u4e0b\u964d\u5230\u521d\u59cbPCE\u768480%\uff0c170\u5c0f\u65f6\u5de6\u53f3\u53c8\u4e0b\u964d\u523060%\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u4e09\u5143\u5668\u4ef6\u5728170\u5c0f\u65f6\u540e\u4ecd\u80fd\u4fdd\u6301\u7ea670%\u7684\u521d\u59cb PCE\u3002\u5728 PM6:PY-V-<em><i>\u03b3<\/i><\/em>\u00a0\u7cfb\u7edf\u4e2d\u5f15\u5165PYO-V\u63d0\u9ad8\u4e86\u5668\u4ef6\u7684\u5149\u70ed\u7a33\u5b9a\u6027\u3002\u6211\u4eec\u8fd8\u4f7f\u7528\u4e0d\u540c\u7684LED\u5149\u6e90\u7814\u7a76PYO-V\u7684\u5ba4\u5185\u5149\u4f0f\u6027\u80fd\uff0c\u5176\u4e2d2600K\u662f\u6700\u4f73\u6761\u4ef6\uff0c\u56e0\u4e3a\u5b83\u7684\u53d1\u5c04\u5149\u8c31\u4e0ePYO-V\u975e\u5e38\u5339\u914d\u3002\u57282600K LED\u706f\u76842000 lux\u5149\u5f3a\u4e0b\uff0cPM6:PYO-V\u7684PCE\u8fbe\u5230\u4e8624.0%\uff0c\u8fd9\u4e5f\u662f\u8fc4\u4eca\u4e3a\u6b62\u62a5\u544a\u7684\u5ba4\u5185\u5168\u805a\u5408\u7269\u5ba4\u5185\u5149\u4f0f\u7684\u6700\u9ad8\u6027\u80fd\u4e4b\u4e00\u3002<\/p>\n<p><strong><b>\u5c0f\u7ed3<\/b><\/strong>\uff1a\u901a\u8fc7\u5728Y\u7cfb\u5217\u805a\u5408\u7269\u53d7\u4f53\u5916\u5c42\u567b\u5429\u5355\u5143\u7684<em><i>\u03b2<\/i><\/em>\u4f4d\u7f6e\u52a0\u5165\u70f7\u6c27\u57fa\u4fa7\u94fe\uff0c\u6210\u529f\u5730\u6784\u5efa\u4e86\u4e00\u79cd\u9ad8\u6027\u80fd\u805a\u5408\u7269\u53d7\u4f53PYO-V\u3002\u70f7\u6c27\u57fa\u4fa7\u94fe\u5b98\u80fd\u5316\u5bfc\u81f4\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u84dd\u79fb\u548c\u80fd\u7ea7\u4e0a\u79fb\u3002\u8fd9\u79cd\u6539\u53d8\u4f7f\u4e3b\u53cc\u5143\u4f53\u7cfb\u80fd\u591f\u5b9e\u73b0\u4e92\u8865\u5438\u6536\u5e76\u6709\u6548\u63a7\u5236\u80fd\u91cf\u635f\u5931\u3002\u7531\u6b64\u4ea7\u751f\u7684PM6:PY-V-<em><i>\u03b3<\/i><\/em>:PYO-V\u4e09\u5143\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u663e\u8457\u63d0\u9ad8\uff0c\u8fbe\u5230 18.5%, <em><i>V<\/i><\/em><sub>OC<\/sub>\u9ad8\u8fbe0.932 V\uff0c\u8fdc\u9ad8\u4e8e\u57fa\u4e8ePM6:PY-V-\u03b3\u7684\u592a\u9633\u80fd\u7535\u6c60\u768417.3%\u3002\u4e09\u5143\u5668\u4ef6\u6027\u80fd\u7684\u63d0\u9ad8\u5f97\u76ca\u4e8e\u4e92\u8865\u5149\u6536\u96c6\u5149\u8c31\u7684\u534f\u540c\u6548\u5e94\u3001\u6fc0\u5b50\u89e3\u79bb\u6548\u7387\u63d0\u9ad8\u3001\u7535\u8377\u91cd\u7ec4\u7684\u6291\u5236\u4ee5\u53ca\u80fd\u91cf\u635f\u8017\u7684\u964d\u4f4e\u3002\u6b64\u5916\uff0cPYO-V \u8fd8\u5c55\u793a\u4e86\u5176\u5728\u5ba4\u5185\u5149\u4f0f\u9886\u57df\u7684\u6f5c\u529b\uff0c\u5728\u4e8c\u5143\u5668\u4ef6\u4e2d\u5b9e\u73b0\u4e8624%\u7684\u6548\u7387\u3002\u8fd9\u4e9b\u7ed3\u679c\u51f8\u663e\u4e86\u70f7\u6c27\u57fa\u53d6\u4ee3\u4f5c\u4e3a\u5fae\u8c03\u805a\u5408\u7269\u53d7\u4f53\u5149\u7535\u7279\u6027\u7684\u4e00\u79cd\u53ef\u884c\u7b56\u7565\u7684\u6709\u6548\u6027\uff0c\u4ece\u800c\u4e3a\u591a\u529f\u80fd\u5149\u4f0f\u5e94\u7528\u5e26\u6765\u4e86\u9ad8\u6548\u7684\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u3002<\/p>\n<p>\u672c\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u79d1\u7814\u52a9\u7406\u6559\u6388\u4e8e\u6db5\u535a\u58eb\uff0c\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u535a\u58eb\u7814\u7a76\u751f\u8d75\u8d85\u8d8a\u3002\u672c\u6587\u7684\u901a\u8baf\u4f5c\u8005\u4e3a\u4e1c\u534e\u5927\u5b66\u80e1\u534e\u4f1f\u6559\u6388, \u6df1\u5733\u6280\u672f\u5927\u5b66\u5f20\u5149\u70e8\u526f\u6559\u6388\u548c\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u989c\u6cb3\u6559\u6388\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2024\/ee\/d4ee01804d<\/p>\n<p>&nbsp;<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\uff1a<\/p>\n<p>\u4e8e\u6db5\u535a\u58eb\u7b80\u4ecb\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-261067 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72477-4.png\" alt=\"\" width=\"155\" height=\"205\" \/><\/p>\n<p>2017\u5e74\u672c\u79d1\u6bd5\u4e1a\u4e8e\u5317\u4eac\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\uff08\u5bfc\u5e08\uff1a\u8d75\u8fbe\u6167\u6559\u6388\uff09\uff0c\u968f\u540e\u8fdb\u5165\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u5316\u5b66\u7cfb\u653b\u8bfb\u7814\u7a76\u751f\uff0c\u4e8e2021\u5e74\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\uff08\u5bfc\u5e08\uff1a\u989c\u6cb3\u6559\u6388\uff09\u3002\u6bd5\u4e1a\u540e\u83b7\u5f97\u9999\u6e2f\u7279\u522b\u884c\u653f\u533a\u521b\u65b0\u79d1\u6280\u7f72-\u521b\u65b0\u79d1\u6280\u57fa\u91d1\u535a\u58eb\u540e\u8d44\u52a9\u9879\u76ee\uff0c2021-2024\u5e74\u4e8e\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u7ee7\u7eed\u535a\u58eb\u540e\u7814\u7a76\uff0c2024\u8d77\u62c5\u4efb\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u5316\u5b66\u7cfb\u79d1\u7814\u52a9\u7406\u6559\u6388\u3002\u4e8e\u6db5\u535a\u58eb\u4e3b\u8981\u4ece\u4e8b\u65b0\u578b\u805a\u5408\u7269\u5149\u4f0f\u53d7\u4f53\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210\u5de5\u4f5c\uff0c\u7740\u773c\u4e8e\u63a2\u7d22\u65b0\u578b\u805a\u5408\u7269\u5149\u4f0f\u53d7\u4f53\u4e4b\u95f4\u7684\u6784\u6548\u5173\u7cfb\uff0c\u5728\u57fa\u4e8e\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u4e0e\u7a33\u5b9a\u6027\u65b9\u9762\u53d6\u5f97\u4e86\u91cd\u8981\u7684\u521b\u65b0\u6027\u7814\u7a76\u6210\u679c\uff0c\u5e76\u6570\u6b21\u521b\u9020\u5168\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u7eaa\u5f55\u3002\u4e8e\u6db5\u535a\u58eb\u5171\u53d1\u8868SCI\u5b66\u672f\u8bba\u658761\u7bc7\uff0c\u5176\u4e2d\u4ee5\u7b2c\u4e00\u4f5c\u8005\/\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\/\u901a\u8baf\u4f5c\u8005\u53d1\u8868\u5728\u300a<em>Nature Review Materials<\/em><em>\u300b<\/em>\u3001\u300a<em>Nature Communications<\/em><em>\u300b<\/em>\u3001\u300a<em>Joule<\/em>\u300b\u3001<em>\u300a<\/em><em>Energy &amp; Environmental Science<\/em><em>\u300b<\/em>\u3001\u300a<em>Advanced Materials<\/em>\u300b\u3001\u300a<em>Angewandte Chemie<\/em>\u300b\u3001\u300a<em>Advanced Energy Materials<\/em>\u300b\u3001\u300a<em>Advanced Functional Materials<\/em>\u300b\u7b49\u671f\u520a\u768429\u7bc7\u8bba\u6587\uff0c\u5f15\u7528\u6b21\u6570\u8d85\u8fc73100\u6b21\uff0cH\u56e0\u5b50: 30\u3002\u76ee\u524d\u4ecd\u4e3b\u8981\u4ece\u4e8b\u5149\u4f0f\u6750\u6599\u7684\u8bbe\u8ba1\u5f00\u53d1\uff0c\u7528\u4e8e\u9ad8\u6548\u7387\u3001\u9ad8\u7a33\u5b9a\u6027\u3001\u540c\u65f6\u6613\u4e8e\u5927\u89c4\u6a21\u52a0\u5de5\u7684\u67d4\u6027\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u5e94\u7528\u3002<\/p>\n<p>\u80e1\u534e\u4f1f\u7b80\u4ecb\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-261068 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72478-3.png\" alt=\"\" width=\"280\" height=\"280\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72478-3.png 280w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72478-3-150x150.png 150w\" sizes=\"(max-width: 280px) 100vw, 280px\" \/><\/p>\n<p>\u4e1c\u534e\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u00a0\u7ea4\u7ef4\u6750\u6599\u6539\u6027\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4 \u7814\u7a76\u5458\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u30022017\u5e74\u5728\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c2017\u5e74-2021\u5e74\u5148\u540e\u5728\u7f8e\u56fd\u5317\u5361\u7f57\u6765\u7eb3\u5dde\u7acb\u5927\u5b66\u548c\u829d\u52a0\u54e5\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u30022021\u5e74\u52a0\u5165\u4e1c\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662\uff0c\u4e3b\u8981\u4ece\u4e8b\u6709\u673a\u5149\u4f0f\u4ee5\u53ca\u67d4\u6027\u672c\u5f81\u53ef\u62c9\u4f38\u7535\u5b50\u5668\u4ef6\u7684\u7814\u7a76\uff0c\u8fc4\u4eca\u5728Nat. Mater., Nat. Electron., J. Am. Chem. Soc., Acc. Chem. Res., Angew. Chem. Int. Ed., Adv. Mater., Adv. Energy. Mater., Energy Environ. Sci. \u7b49\u56fd\u9645\u6743\u5a01\u671f\u520a\u53d1\u8868\u8bba\u658770\u4f59\u7bc7, \u5176\u4e2dESI\u9ad8\u88ab\u5f1513\u7bc7\uff0c\u6587\u7ae0\u603b\u5f15\u75289000\u4f59\u6b21\u3002<\/p>\n<p>\u5f20\u5149\u70e8\u7b80\u4ecb\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-261069 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72479-1.png\" alt=\"\" width=\"243\" height=\"326\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72479-1.png 243w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72479-1-224x300.png 224w\" sizes=\"(max-width: 243px) 100vw, 243px\" 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research-cell efficiency chart\u201d\u4e16\u754c\u7eaa\u5f55\u8868\u3002<\/p>\n<p>\u989c\u6cb3\u6559\u6388\u5efa\u7acb\u4e86\u4ee5\u9999\u6e2f\u4e3a\u4e2d\u5fc3\u7684\u56fd\u9645\u8de8\u5b66\u79d1\u7814\u7a76\u5e73\u53f0\uff0c\u540c\u65f6\u8fd8\u5177\u6709\u4e30\u5bcc\u7684\u4ea7\u4e1a\u5316\u7ecf\u9a8c\uff0c\u662f\u4e2d\u56fd\u65b0\u578b\u5149\u4f0f\u6280\u672f\u4ea7\u4e1a\u5316\u7684\u5f15\u9886\u8005\uff0c\u5e76\u4e8e2018\u5e74\u521b\u7acb\u4e86\u6df1\u5733\u6613\u67d4\u5149\u4f0f\u6709\u9650\u516c\u53f8\uff0c\u63d0\u51fa\u4e86\u6709\u673a\u5149\u4f0f\u4ea7\u4e1a\u5316\u65b0\u8def\u7ebf\uff0c\u5e76\u5e26\u9886\u516c\u53f8\u591a\u6b21\u83b7\u5f97\u521b\u4e1a\u5927\u8d5b\u5956\u9879\u30022019\u5e74\uff0c\u516c\u53f8\u8363\u83b7\u7b2c\u5341\u4e00\u5c4a\u4e2d\u56fd\u6df1\u5733\u521b\u65b0\u521b\u4e1a\u5927\u8d5b\u65b0\u80fd\u6e90\u53ca\u8282\u80fd\u73af\u4fdd\u4ea7\u4e1a\u7ec4\u51b3\u8d5b\u4e00\u7b49\u5956\u3002\u540c\u5e74\uff0c\u516c\u53f8\u4ece\u5168\u56fd7\u4e2a\u533a\u57df\u6bd4\u8d5b\u76841279\u4e2a\u9879\u76ee\u4e2d\u8131\u9896\u800c\u51fa\uff0c\u5728\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u4e0e\u8d8a\u79c0\u96c6\u56e2\u8054\u5408\u4e3e\u529e\u7684\u201c\u767e\u4e07\u521b\u4e1a\u5927\u8d5b\u201d\u4e2d\u83b7\u5f97\u51a0\u519b\u3002<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u76f8\u6bd4\u4e8e\u65e0\u673a\u534a\u5bfc\u4f53\uff0c\u6709\u673a\u534a\u5bfc\u4f53\u6750\u6599\u6700\u5927\u7684\u4f18\u52bf\u5c31\u5728\u4e8e\u53ef\u4ee5\u901a\u8fc7\u5408\u7406\u7684\u5316\u5b66\u4fee\u9970\u6765\u8c03\u8282\u5206\u5b50\u5185\u7684\u7535\u8377\u8f6c\u79fb(intramolecular 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