{"id":260974,"date":"2024-06-24T06:09:29","date_gmt":"2024-06-23T22:09:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=260974"},"modified":"2024-06-23T21:09:42","modified_gmt":"2024-06-23T13:09:42","slug":"%e8%af%ba%e5%a5%96%e5%be%97%e4%b8%bb%ef%bc%8c%e5%86%8d%e5%8f%91nature%ef%bc%9a%e9%87%91%e5%b1%9e%e5%85%89%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%ce%b1-%e6%b6%88%e5%8e%bb%e6%b3%95%e8%a7%a3%e9%94%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=260974","title":{"rendered":"\u8bfa\u5956\u5f97\u4e3b\uff0c\u518d\u53d1Nature\uff1a\u91d1\u5c5e\u5149\u6c27\u5316\u8fd8\u539f\u03b1-\u6d88\u53bb\u6cd5\u89e3\u9501\u5361\u5bbe\u7684\u53cd\u5e94\u6027"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>\u8bfa\u5956\u5f97\u4e3b\uff0c\u518d\u53d1<\/strong><strong><em>Nature<\/em><\/strong><strong>\uff1a\u91d1\u5c5e\u5149\u6c27\u5316\u8fd8\u539f\u03b1<\/strong><strong>&#8211;<\/strong><strong>\u6d88\u53bb\u6cd5\u89e3\u9501\u5361\u5bbe\u7684\u53cd\u5e94\u6027<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><\/p>\n<p>\u63a7\u5236\u9ad8\u80fd\u5316\u5b66\u4e2d\u95f4\u4f53\uff0c\u5982\uff1a\u5361\u5bbe\u3001\u7c7b\u5361\u5bbe\u3001\u78b3\u8d1f\u79bb\u5b50\u3001\u78b3\u6b63\u79bb\u5b50\u3001\u81ea\u7531\u57fa\u7b49\uff0c\u5728\u6709\u673a\u5408\u6210\u9886\u57df\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c\u83b7\u5f97\u8fd9\u4e9b\u4e2d\u95f4\u4f53\u9700\u8981\u591a\u79cd\u5177\u6709\u9ad8\u80fd\u57fa\u6001\u7684\u6d3b\u6027\u8d77\u59cb\u6750\u6599\uff0c\u8fd9\u9650\u5236\u4e86\u5b98\u80fd\u56e2\u7684\u76f8\u5bb9\u6027\uff0c\u7279\u522b\u662f\u5728\u590d\u6742\u7684\u5408\u6210\u76ee\u6807\u80cc\u666f\u4e0b\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5229\u7528\u53ef\u89c1\u5149\u8fdb\u884c\u53cd\u5e94\u6027\u8f6c\u6362\uff0c\u5c06\u7a33\u5b9a\u7684\u8d77\u59cb\u7269\u8d28\u8f6c\u5316\u4e3a\u6d3b\u6027\u81ea\u7531\u57fa\u3002\u91d1\u5c5e\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u53ef\u4ee5\u901a\u8fc7\u8fc7\u6e21\u91d1\u5c5e\u4ea4\u53c9\u5076\u8054\u4e0e\u8fd9\u4e9b\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53\u7ed3\u5408\u5728\u4e00\u8d77\uff0c\u4e3a\u6709\u673a\u50ac\u5316\u7684\u8fdb\u4e00\u6b65\u7814\u7a76\u63d0\u4f9b\u4e86\u5de8\u5927\u7684\u53ef\u80fd\u6027\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5c3d\u7ba1\u5361\u5bbe\u548c\u7c7b\u5361\u5bbe\u5728\u5316\u5b66\u952e\u5f62\u6210\u4e2d\u5177\u6709\u7c7b\u4f3c\u7684\u80fd\u529b\uff0c\u4f46\u7531\u4e8e\u8bd5\u5242\u5b89\u5168\u95ee\u9898\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u5f80\u5f80\u4ee4\u4eba\u671b\u800c\u5374\u6b65\uff0c\u9650\u5236\u4e86\u5b83\u4eec\u5728\u5408\u6210\u4e2d\u7684\u5e7f\u6cdb\u5e94\u7528\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u4e0a\u8ff0\u6311\u6218\uff0c\u8fd1\u671f\u7f8e\u56fd\u666e\u6797\u65af\u987f\u5927\u5b66David W. C. MacMillan\u6559\u6388\u56e2\u961f\u7814\u7a76\u4e86\u57fa\u4e8e\u53ef\u89c1\u5149\u4ecb\u5bfc\u7684\u7b56\u7565\uff0c\u5229\u7528\u94c1-\u5361\u5bbe\u53cd\u5e94\u6027\uff0c\u4f7f\u7528\u73b0\u6210\u7684\u5316\u5b66\u539f\u6599\u4f5c\u4e3a\u81ea\u7531\u57fa\u6765\u6e90\uff0c\u5e76\u4ece\u516d\u7c7b\u5148\u524d\u672a\u5145\u5206\u5f00\u53d1\u7684\u79bb\u53bb\u57fa\u56e2\u4e2d\u6d88\u9664\u03c3\u952e\uff0c\u4ece\u800c\u4e3a\u5e94\u5bf9\u5361\u5bbe\u4ecb\u5bfc\u7684\u5316\u5b66\u591a\u6837\u5316\u7684\u6311\u6218\u63d0\u4f9b\u4e86\u4e00\u4e2a\u901a\u7528\u7684\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n<p>\u5177\u4f53\u6765\u8bb2\uff0c\u7814\u7a76\u4eba\u5458\u9009\u62e9\u03b1-\u4e59\u9170\u6c27\u57fa\u7fa7\u9178\uff0c\u56e0\u4e3a\u7fa7\u9178\u5bb9\u6613\u5f62\u6210\u81ea\u7531\u57fa\u3002\u7814\u7a76\u4eba\u5458\u9009\u62e9\u94c1\u535f\u5549\u4f5c\u4e3a\u91d1\u5c5e\u652f\u67b6\u6765\u8bc4\u4f30\u81ea\u7531\u57fa\u7ed3\u5408\u548c\u03b1-\u6d88\u9664\u6027\u3002\u94c1\u8868\u73b0\u51fa\u4e0e\u70f7\u57fa\u81ea\u7531\u57fa\u7684\u91d1\u5c5e\u5316\u53cd\u5e94\u6027\uff0c\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u4fc3\u8fdb\u03b1-\u7684\u6d88\u9664\uff0c\u8fd9\u79cd\u72b6\u6001\u53ef\u4ee5\u7528\u5149\u50ac\u5316\u5242\u6765\u63a7\u5236\uff0c\u8be5\u8fc7\u7a0b\u4e2d\uff0c\u73af\u4e19\u70f7\u5316\u88ab\u9009\u4e3a\u6a21\u578b\u53cd\u5e94\uff0c\u4ee5\u83b7\u53d6\u5047\u5b9a\u7684\u5361\u5bbe\u4e2d\u95f4\u4f53\u7684\u8bc1\u636e\uff0c\u5177\u4f53\u7684\u53cd\u5e94\u8fc7\u7a0b\u4ee5\u53ca\u539f\u6599\u89c1\u56fe1\u3002\u8fdb\u4e00\u6b65\u5bf9\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u4f18\u5316\u540e\uff0c\u7814\u7a76\u4eba\u5458\u9274\u5b9a\u51fa\u516d\u79cd\u4e0d\u540c\u7684\u80fd\u591f\u4f5c\u4e3a\u5361\u5bbe\u524d\u4f53\u7684\u79bb\u53bb\u57fa\u7684\u5b58\u5728\uff0c\u8fd9\u8bc1\u660e\u4e86\u94c1\u535f\u5549\u03b1-\u6d88\u9664\u5bf9\u5e7f\u6cdb\u7684\u79bb\u53bb\u57fa\u80fd\u529b\u7684\u8010\u53d7\u6027\uff0c\u5e76\u63d0\u4f9b\u4e86\u4e00\u79cd\u83b7\u53d6\u5361\u5bbe\u4e2d\u95f4\u4f53\u7684\u6a21\u5757\u5316\u7b56\u7565\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260975\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72471-12.png\" alt=\"\" width=\"697\" height=\"527\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72471-12.png 697w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72471-12-300x227.png 300w\" sizes=\"(max-width: 697px) 100vw, 697px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>1<\/strong> <strong>\u91d1\u5c5e\u5361\u5bbe\u5f62\u6210\u793a\u610f\u56fe\uff1b<\/strong><strong>\u00a9 Springer Nature Limited 2024<\/strong><\/p>\n<p>\u968f\u540e\uff0c\u7814\u7a76\u4eba\u5458\u5728\u4f18\u5316\u73af\u4e19\u70f7\u5316\u6761\u4ef6\u540e\uff0c\u7ee7\u7eed\u63a2\u7d22\u4e86\u7fa7\u9178\u548c\u70ef\u70c3\u7684\u8303\u56f4\u3002\u7ed3\u679c\u8868\u660e\uff0c\u7531\u03b1-\u4e59\u9170\u6c27\u57fa\u7fa7\u9178\u751f\u6210\u7684\u82ef\u57fa\u548c\u70f7\u57fa\u78b3\u70ef\u90fd\u662f\u6709\u6548\u7684\u7814\u7a76\u5bf9\u8c61\uff0c\u591a\u79cd\u6c28\u57fa\u9178\u4ee5\u53ca\u884d\u751f\u7269\u4ea6\u662f\u53ef\u884c\u7684\u5361\u5bbe\u524d\u4f53\u3002\u7814\u7a76\u4eba\u5458\u5f88\u9ad8\u5174\u5730\u53d1\u73b0\uff0c\u53ef\u4ee5\u4f7f\u7528\u81ea\u7531\u57fa\u524d\u4f53\u548c\u70ef\u70c3\u5076\u8054\u5bf9\u8c61\u7684\u591a\u79cd\u53d8\u4f53\u6765\u83b7\u5f97\u591a\u79cd\u73af\u4e19\u70f7\u5316\u652f\u67b6\u3002\u968f\u540e\uff0c\u7814\u7a76\u4eba\u5458\u8fdb\u4e00\u6b65\u63a2\u7d22\u4e86\u4e0a\u8ff0\u6a21\u5f0f\u662f\u5426\u53ef\u4ee5\u6269\u5c55\u5230\u7fa7\u9178\u884d\u751f\u7684\u5176\u4ed6\u81ea\u7531\u57fa\u524d\u4f53\uff0c\u5e76\u53d6\u5f97\u4e86\u826f\u597d\u7684\u7814\u7a76\u6548\u679c\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260976\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72472-11.png\" alt=\"\" width=\"501\" height=\"638\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72472-11.png 501w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72472-11-236x300.png 236w\" sizes=\"(max-width: 501px) 100vw, 501px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>2 <\/strong><strong>\u6761\u4ef6\u4f18\u5316\u53ca\u53cd\u5e94\u9002\u7528\u6027\uff1b<\/strong><strong>\u00a9 Springer Nature Limited 2024<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260977\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72473-10.png\" alt=\"\" width=\"519\" height=\"565\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72473-10.png 519w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72473-10-276x300.png 276w\" sizes=\"(max-width: 519px) 100vw, 519px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>3 <\/strong><strong>\u53cd\u5e94\u6a21\u578b\u7684\u9002\u7528\u6027\uff1b<\/strong> <strong>\u00a9 Springer Nature Limited 2024<\/strong><\/p>\n<p>\u8be5\u7814\u7a76\u5c55\u793a\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u91d1\u5c5e\u5149\u6c27\u5316\u8fd8\u539f\u7b56\u7565\uff0c\u7528\u4e8e\u5f62\u6210\u5361\u5bbe\u4e2d\u95f4\u4f53\uff0c\u8be5\u7b56\u7565\u6253\u7834\u4e86\u4f20\u7edf\u7814\u7a76\u7684\u5c40\u9650\u6027\uff0c\u76f8\u5173\u7814\u7a76\u4ee5\u201c<strong>Unlocking carbene reactivity by metallaphotoredox \u03b1-elimination<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a<strong>Nature<\/strong>\u4e0a\uff0c\u5f15\u8d77\u4e86\u76f8\u5173\u9886\u57df\u7814\u7a76\u4eba\u5458\u70ed\u8bae\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260978\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72474-10.png\" alt=\"\" width=\"692\" height=\"340\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72474-10.png 692w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/06\/\u56fe\u72474-10-300x147.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u516c\u5f00\u4e86\u4e00\u4e2a\u6982\u5ff5\u6027\u7684\u65b0\u5e73\u53f0\uff0c\u901a\u8fc7\u94c1\u50ac\u5316\u548c\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u7684\u5408\u5e76\u6709\u6548\u5730\u83b7\u5f97\u5361\u5bbe\u4e2d\u95f4\u4f53\u3002\u8be5\u65b9\u6cd5\u514b\u670d\u4e86\u4f7f\u7528\u4f20\u7edf\u65b9\u6cd5\u83b7\u53d6\u5361\u5bbe\u4e2d\u95f4\u4f53\u7684\u56fa\u6709\u5c40\u9650\u6027\uff0c\u901a\u8fc7\u73af\u4e19\u70f7\u548c\u03c3\u952e\u63d2\u5165\u53ef\u83b7\u5f97\u591a\u79cd\u652f\u67b6\uff0c\u8bc1\u660e\u4e86\u8be5\u65b9\u6cd5\u7684\u5b9e\u7528\u6027\u3002\u8be5\u7814\u7a76\u63d0\u51fa\u7684\u7b56\u7565\u9884\u8ba1\u5c06\u5438\u5f15\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u754c\u7684\u5b9e\u8df5\u8005\uff0c\u56e0\u4e3a\u5b83\u662f\u4e00\u79cd\u65b0\u7684\u5361\u5bbe\u751f\u6210\u673a\u5236\uff0c\u4e5f\u662f\u4e00\u79cd\u5229\u7528\u5361\u5bbe\u53cd\u5e94\u6027\u6765\u63d0\u9ad8\u5206\u5b50\u590d\u6742\u6027\u7684\u5f3a\u5927\u5408\u6210\u5de5\u5177\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><strong>Unlocking carbene reactivity by metallaphotoredox \u03b1-elimination<\/strong><strong>\uff0c<\/strong><strong>2024<\/strong><strong>\uff0c<\/strong><strong>https:\/\/doi.org\/10.1038\/s41586-024-07628-1<\/strong><strong>\uff09<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7531LWB\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u8bfa\u5956\u5f97\u4e3b\uff0c\u518d\u53d1Nature\uff1a\u91d1\u5c5e\u5149\u6c27\u5316\u8fd8\u539f\u03b1&#8211;\u6d88\u53bb\u6cd5\u89e3\u9501\u5361\u5bbe\u7684\u53cd\u5e94\u6027 \u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011 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