{"id":260389,"date":"2024-05-24T08:10:59","date_gmt":"2024-05-24T00:10:59","guid":{"rendered":"\/\/m.iemloyee.com\/?p=260389"},"modified":"2024-05-24T08:10:59","modified_gmt":"2024-05-24T00:10:59","slug":"%e9%87%8d%e7%a3%85science-%e5%88%98%e5%90%8c%e8%b6%85%ef%bc%8c%e5%91%a8%e6%b6%9b-khalil-amine%e9%99%a2%e5%a3%ab%e6%9c%80%e6%96%b0%e9%94%82%e7%94%b5%e6%88%90%e6%9e%9c%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=260389","title":{"rendered":"\u91cd\u78c5Science!  \u5218\u540c\u8d85\uff0c\u5468\u6d9b&amp; Khalil Amine\u9662\u58eb\u6700\u65b0\u9502\u7535\u6210\u679c\uff01"},"content":{"rendered":"<p><strong>1.<\/strong><strong>\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><\/p>\n<p>\u5bcc\u954d\u5c42\u72b6\u6c27\u5316\u7269\u6b63\u6781\uff08NMC\uff09\u88ab\u8ba4\u4e3a\u662f\u53d1\u5c55\u9ad8\u7eed\u822a\u7535\u52a8\u6c7d\u8f66\u7684\u5019\u9009\u6750\u6599\uff0c\u5176\u4e2d\uff0c\u8003\u8651\u5230\u80fd\u91cf\u5bc6\u5ea6\u548c\u9502\u79bb\u5b50\uff08Li<sup>+<\/sup>\uff09\u7684\u6269\u6563\u52a8\u529b\u5b66\uff0c\u805a\u96c6\u591a\u6676\u5df2\u6210\u4e3a\u5546\u4e1a\u5316\u6b63\u6781\u6750\u6599\u7684\u4e3b\u8981\u9009\u62e9\u5f62\u6001\u3002\u7136\u800c\uff0c\u521d\u7ea7\u7c92\u5b50\u4e4b\u95f4\u7684\u4e0d\u5747\u5300\u4f53\u79ef\u53d8\u5316\u4f1a\u5bfc\u81f4\u6cbf\u6676\u754c\u7684\u7c92\u5b50\u5fae\u88c2\u7eb9\uff0c\u8bf1\u53d1\u989d\u5916\u7684\u526f\u4f5c\u7528\uff0c\u52a0\u5267\u8fc7\u6e21\u91d1\u5c5e\u7684\u6eb6\u89e3\u548c\u754c\u9762\u7ed3\u6784\u7684\u9000\u5316\u3002<strong>\u5355\u6676\u5bcc\u954d\u6b63\u6781\uff08<\/strong><strong>SC-NMC<\/strong><strong>\uff09\u6750\u6599\u907f\u514d\u4e86\u6676\u754c\uff0c\u5177\u6709\u589e\u5f3a\u7684\u529b\u5b66\u6027\u80fd\uff0c\u5f15\u8d77\u4e86\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u754c\u7684\u5de8\u5927\u5173\u6ce8\u3002<\/strong>\u7136\u800c\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u9ad8\u954d\u542b\u91cf\uff08\u226570%\uff09\u7684SC-NMC\u5c3d\u7ba1\u5177\u6709\u8f83\u9ad8\u7684\u6297\u5fae\u88c2\u7eb9\u5f62\u6210\u80fd\u529b\uff0c\u4f46\u5b9e\u9645\u5bb9\u91cf\u8f83\u4f4e\uff0c\u5bb9\u91cf\u8870\u51cf\u8fc5\u901f\u3002<strong>SC-NMC<\/strong><strong>\u5bb9\u91cf\u8870\u51cf\u7684\u539f\u56e0\uff0c\u4ee5\u53ca\u5bb9\u91cf\u8870\u51cf\u4e0e\u7ed3\u6784\u53d8\u5316\u4e4b\u95f4\u7684\u76f8\u5173\u6027\u81f3\u4eca\u4ecd\u5b58\u5728\u4e89\u8bae\uff0c\u6210\u4e3a\u53d1\u5c55\u9ad8\u7a33\u5b9a\u6027<\/strong><strong>SC-NMC<\/strong><strong>\u6b63\u6781\u7684\u5173\u952e\u79d1\u5b66\u96be\u9898\u3002<\/strong><\/p>\n<p><strong>2.<\/strong><strong>\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u4ee5\u4e0a\u7814\u7a76\u80cc\u666f\uff0c<strong>\u7f8e\u56fd\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4<\/strong><strong>Khalil Amine<\/strong><strong>\u6559\u6388\u3001\u5218\u540c\u8d85\u7814\u7a76\u5458\u3001\u5468\u6d9b\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5229\u7528\u591a\u5c3a\u5ea6\u7a7a\u95f4\u5206\u8fa8\u884d\u5c04\u548c\u6210\u50cf\u6280\u672f\uff0c\u89c2\u5bdf\u5230<\/strong><strong>SC-NMC<\/strong><strong>\u6b63\u6781\u4e2d\u5b58\u5728\u4e0d\u53ef\u9006\u7684\u6676\u683c\u65cb\u8f6c\uff0c\u5e76\u8bc1\u660e\u5176\u5728\u7ed3\u6784\u9000\u5316\u4e2d\u4ea7\u751f\u4e86\u5173\u952e\u5f71\u54cd\u3002<\/strong>\u8fd9\u4e9b\u53d1\u73b0\u4e3a\u5355\u6676\u6b63\u6781\u6027\u80fd\u5931\u6548\u548c\u5fae\u89c2\u7ed3\u6784\u89c2\u6d4b\u4e4b\u95f4\u5efa\u7acb\u8d77\u4e86\u6709\u6548\u7684\u673a\u5236\u8054\u7cfb\uff0c\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cUnrecoverable lattice rotation governs structural degradation of single-crystalline cathodes\u201d\u4e3a\u9898\u53d1\u8868\u5728\u6700\u65b0<strong><em>Science<\/em><\/strong>\u671f\u520a\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260402\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u5c01\u9762-2.png\" alt=\"\" width=\"1102\" height=\"415\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u5c01\u9762-2.png 1102w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u5c01\u9762-2-300x113.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u5c01\u9762-2-768x289.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u5c01\u9762-2-1024x386.png 1024w\" sizes=\"(max-width: 1102px) 100vw, 1102px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260390\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-17.png\" alt=\"\" width=\"1553\" height=\"1859\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-17.png 1553w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-17-251x300.png 251w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-17-768x919.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-17-855x1024.png 855w\" sizes=\"(max-width: 1553px) 100vw, 1553px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1. SC-NMC<\/strong><strong>\u6b63\u6781\u7684\u7ed3\u6784\u548c\u7535\u5316\u5b66\u6027\u8d28\u3002<\/strong>\u00a9 2024 AAAS<\/p>\n<p>\u9996\u5148\u4ee5\u5178\u578b\u7684\u5bcc\u954dLiNi<sub>0.83<\/sub>Mn<sub>0.06<\/sub>Co<sub>0.11<\/sub>O<sub>2<\/sub>\u4e3a\u6a21\u578b\u7cfb\u7edf\uff0c\u5168\u9762\u7814\u7a76\u4e86SC-NMC\u6b63\u6781\u7684\u5931\u6548\u673a\u5236\u3002\u5e38\u89c4\u5171\u6c89\u6dc0\u6cd5\u548c\u56fa\u76f8\u7145\u70e7\u6cd5\u5408\u6210\u7684SC-NMC\u6750\u6599\u663e\u793a\u51fa\u6e05\u6670\u7684\u5178\u578b\u5c42\u72b6\u7ed3\u6784\u3002\u968f\u540e\u4f7f\u7528\u534a\u7535\u6c60\u5728\u4e0d\u540c\u7684\u622a\u6b62\u7535\u538b\u4e0b\u8fdb\u884c\u4e86\u7535\u5316\u5b66\u6027\u80fd\u8bc4\u4f30\uff0c\u5728C\/10\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5f53\u622a\u65ad\u7535\u538b\u4e3a4.3\u30014.4\u30014.5 V\u65f6\uff0cSC-NMC\u7684\u521d\u59cb\u5bb9\u91cf\u5206\u522b\u4e3a192.7\u3001206.2\u3001210.4 mAh g<sup>\u22121<\/sup>\u3002\u7136\u800c\uff0cSC-NMC\u5728\u5faa\u73af\uff08\u7279\u522b\u662f\u9ad8\u7535\u538b\u5faa\u73af\uff09\u4e2d\u8868\u73b0\u51fa\u5feb\u901f\u7684\u5bb9\u91cf\u8870\u51cf\u3002X\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u7ed3\u679c\u8868\u660eSC-NMC\u7684\u7ed3\u6784\u662f\u53ef\u9006\u7684\uff0c\u4e0d\u80fd\u89e3\u91ca\u5176\u5feb\u901f\u5bb9\u91cf\u8870\u51cf\u548c\u7ed3\u6784\u9000\u5316\u3002\u63a5\u4e0b\u6765\uff0c\u5229\u7528X\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7ed3\u6784\uff08XANES\uff09\u5206\u6790\u4e86SC-NMC\u5728\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u7684\u6c27\u5316\u6001\u53d8\u5316\uff0c\u7ed3\u679c\u4e5f\u8868\u660e\u5728Li<sup>+<\/sup>\u63d2\u5c42\u5d4c\u5165\u2014\u8131\u5d4c\u7684\u8fc7\u7a0b\u4e2d\uff0c\u7ed3\u6784\u548c\u5316\u5b66\u6f14\u53d8\u662f\u53ef\u9006\u7684\u3002<strong>\u56e0\u6b64\uff0c<\/strong><strong>SC-NMC<\/strong><strong>\u6b63\u6781\u7684\u5931\u6548\u6a21\u5f0f\u5728\u5e38\u89c4\u5b8f\u89c2\u8868\u5f81\u6280\u672f\u4e2d\u65e0\u6cd5\u6709\u6548\u68c0\u6d4b\u5230\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260391\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-18.png\" alt=\"\" width=\"1199\" height=\"1731\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-18.png 1199w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-18-208x300.png 208w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-18-768x1109.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-18-709x1024.png 709w\" sizes=\"(max-width: 1199px) 100vw, 1199px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2. SC-NMC<\/strong><strong>\u5355\u4e2a\u9897\u7c92\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684<\/strong><strong>3D<\/strong><strong>\u6676\u683c\u6f14\u5316<\/strong><strong>\u3002<\/strong>\u00a9 2024 AAAS<\/p>\n<p>XRD\u548c\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c\uff08TEM\uff09\u662f\u7814\u7a76\u7535\u6c60\u6750\u6599\u7ed3\u6784\u6f14\u53d8\u6700\u5e38\u7528\u7684\u8868\u5f81\u624b\u6bb5\uff0c\u524d\u8005\u662f\u5c06\u6570\u4ee5\u5343\u8bb0\u7c92\u5b50\u7ed3\u6784\u4fe1\u606f\u8fdb\u884c\u5e73\u5747\u7684<strong>\u7edf\u8ba1<\/strong>\u6280\u672f\uff0c\u540e\u8005\u5219\u53ef\u4ee5\u5b9e\u73b0<strong>\u4e2a\u4f53<\/strong>\u5c40\u90e8\u7ed3\u6784\u7684\u9ad8\u5206\u8fa8\u7387\u56fe\u50cf\uff0c\u867d\u7136\u8fd9\u4e24\u79cd\u6280\u672f\u90fd\u63d0\u4f9b\u4e86\u6709\u4ef7\u503c\u7684\u4fe1\u606f\uff0c\u4f46\u4e24\u8005\u4e4b\u95f4\u5b58\u5728\u68c0\u6d4b\u5c3a\u5ea6\u5dee\u8ddd\uff0c\u65e0\u6cd5\u9610\u660e\u4ecb\u89c2\u7ed3\u6784\u6f14\u5316\u3002<strong>\u591a\u6676\u4f53\u6447\u6446\u66f2\u7ebf\uff08<\/strong><strong>MCRC<\/strong><strong>\uff09\u662f\u4e00\u79cd\u5177\u6709\u9ad8\u7ed3\u6784\u5206\u8fa8\u7387\u7684\u8868\u5f81\u6280\u672f\uff0c\u53ef\u7528\u4e8e\u540c\u65f6\u63d0\u4f9b\u7edf\u8ba1\u548c\u4e2a\u4f53\u7684\u6676\u683c\u7ed3\u6784\u4fe1\u606f\uff0c<\/strong>\u586b\u8865\u4e86\u7edf\u8ba1\u9ad8\u80fd\u540c\u6b65\u8f90\u5c04XRD\u548c\u9ad8\u5206\u8fa8\u7387\u6210\u50cf\u6280\u672f\u4e4b\u95f4\u7684\u77e5\u8bc6\u7a7a\u767d\u3002\u6676\u683c\u65cb\u8f6c\uff0c\u901a\u5e38\u4e0e\u7f3a\u9677\u7684\u5f62\u6210\u76f8\u5173\uff0c\u5e76\u4e14\u5728\u7535\u6c60\u6750\u6599\u4e2d\u666e\u904d\u5b58\u5728\u3002\u4f46\u4e0e\u6676\u683c\u7578\u53d8\u76f8\u6bd4\uff0c\u7531\u4e8e\u4f20\u7edf\u65b9\u6cd5\u7684\u8868\u5f81\u9650\u5236\uff0c\u6676\u683c\u65cb\u8f6c\u5bf9\u7ed3\u6784\u7834\u574f\u548c\u5bb9\u91cf\u8870\u51cf\u7684\u5f71\u54cd\u5f88\u5c11\u88ab\u4e86\u89e3\u3002\u4ee4\u4eba\u6b23\u559c\u7684\u662f\uff0c\u5229\u7528MCRC\u6280\u672f\u53ef\u4ee5\u89c2\u5bdf\u5230\uff0c\u5728\u5145\u7535\u8fc7\u7a0b\u4e2dSC-NMC\u7684\u6676\u683c\u65cb\u8f6c\u53d8\u5316\u503c\u4f1a\u589e\u52a0\uff0c\u4f46\u5728\u653e\u7535\u540e\u4e0d\u4f1a\u6062\u590d\u3002\u6676\u683c\u65cb\u8f6c\u7684\u589e\u52a0\u901a\u5e38\u4e0e\u7ed3\u6784\u7f3a\u9677\u548c\u6676\u683c\u7578\u53d8\u7684\u5f62\u6210\u6709\u5173\uff0c\u8fd9\u4e0d\u80fd\u7b80\u5355\u5730\u901a\u8fc7Li<sup>+<\/sup>\u91cd\u65b0\u63d2\u5165\u6765\u6d88\u9664\u3002\u56e0\u6b64\uff0c<strong>\u968f\u7740\u6bcf\u4e00\u4e2a\u8fde\u7eed\u7684\u5faa\u73af\uff0c\u4e0d\u53ef\u9006\u7684\u6676\u683c\u65cb\u8f6c\u4fc3\u4f7f\u5851\u6027\u53d8\u5f62\u548c\u673a\u68b0\u635f\u4f24\u4e0d\u65ad\u79ef\u7d2f\uff0c\u7834\u574f\u4e86<\/strong><strong>Li+<\/strong><strong>\u7684\u6269\u6563\u548c\u53ef\u9006\u50a8\u5b58\uff0c\u6700\u7ec8\u5bfc\u81f4<\/strong><strong>SC-NMC<\/strong><strong>\u7c92\u5b50\u4e25\u91cd\u7684\u5bb9\u91cf\u8870\u51cf\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260392\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-15.png\" alt=\"\" width=\"1551\" height=\"1301\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-15.png 1551w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-15-300x252.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-15-768x644.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-15-1024x859.png 1024w\" sizes=\"(max-width: 1551px) 100vw, 1551px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3. <\/strong><strong>\u539f\u5b50\u6c34\u5e73\u89c2\u5bdf\u5c40\u90e8\u7ed3\u6784\u548c\u673a\u68b0\u4e0d\u7a33\u5b9a\u6027\u3002<\/strong>\u00a9 2024 AAAS<\/p>\n<p><strong>\u88c5\u914d\u7535\u5b50\u80fd\u91cf\u635f\u5931\u5149\u8c31\uff08<\/strong><strong>EELS<\/strong><strong>\uff09\u7684<\/strong><strong>TEM<\/strong><strong>\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86<\/strong><strong>SC-NMC<\/strong><strong>\u6837\u54c1\u7684\u5c40\u90e8\u5f62\u6001\u548c\u7ed3\u6784\u6f14\u5316\u3002<\/strong>\u5728\u7b2c\u4e00\u4e2a\u5faa\u73af\u4e2d\u5c06SC-NMC\u5145\u7535\u52304.1 V\u65f6\uff0c\u51e0\u4f55\u76f8\u4f4d\u5206\u6790\u63ed\u793a\u4e86\u5757\u4f53\u4e2d\u5f62\u6210\u7684\u5927\u91cf\u6676\u683c\u7578\u53d8\u4ee5\u53ca\u6676\u683c\u7578\u53d8\u5468\u56f4\u7684\u4e0d\u540cNi\u6c27\u5316\u6001\u3002\u7a7a\u95f4\u4e0a\u4e0d\u540c\u6b65\u7684Li<sup>+<\/sup>\u8131\u5d4c\u663e\u8457\u4fc3\u8fdb\u4e86\u6676\u683c\u7578\u53d8\u548c\u6676\u683c\u65cb\u8f6c\u3002\u5c3d\u7ba1\u5355\u6676\u7ed3\u6784\u56fa\u6709\u7684\u529b\u5b66\u7a33\u5b9a\u6027\u5f97\u5230\u4e86\u589e\u5f3a\uff0c\u4f46\u5f53\u53d7\u5230\u6676\u683c\u65cb\u8f6c\u5f71\u54cd\u65f6\uff0c\u5b83\u4ecd\u7136\u4f1a\u4ee5\u90e8\u5206\u4e0d\u53ef\u9006\u5e73\u9762\u6ed1\u52a8\u548c\u6676\u5185\u88c2\u7eb9\u7684\u5f62\u5f0f\u53d1\u751f\u529b\u5b66\u9000\u5316\u3002\u968f\u7740\u4e0d\u53ef\u9006\u6676\u683c\u65cb\u8f6c\u5bc6\u5ea6\u7684\u589e\u52a0\uff0c\u5b83\u4eec\u7684\u573a\u53d8\u5f97\u8db3\u591f\u63a5\u8fd1\u4ece\u800c\u76f8\u4e92\u4f5c\u7528\uff0c\u6700\u7ec8\u5bfc\u81f4\u957f\u65f6\u95f4\u5faa\u73af\u540e\u5355\u6676\u6b63\u6781\u7684\u5fae\u88c2\u7eb9\u4ea7\u751f\u548c\u5bb9\u91cf\u5feb\u901f\u8870\u51cf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260393\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-14.png\" alt=\"\" width=\"1501\" height=\"1435\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-14.png 1501w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-14-300x287.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-14-768x734.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-14-1024x979.png 1024w\" sizes=\"(max-width: 1501px) 100vw, 1501px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4.<\/strong> <strong>\u901a\u8fc7<\/strong><strong>TXM<\/strong><strong>\u89c2\u5bdf\u975e\u5747\u5300\u5316\u5b66\u6c27\u5316\u6001\u5206\u5e03\u3002<\/strong>\u00a9 2024 AAAS<\/p>\n<p>\u901a\u8fc7\u4ece\u7edf\u8ba1\u5230\u5355\u4e2a\u7c92\u5b50\u548c\u539f\u5b50\u5c3a\u5ea6\u7684\u591a\u5c3a\u5ea6\u7ed3\u6784\u5206\u6790\uff0c SC-NMC\u5728\u5e26\u7535\u72b6\u6001\u4e0b\u7684\u4e0d\u5747\u5300\u7ed3\u6784\u53d8\u5316\u5f97\u5230\u4e86\u786e\u8ba4\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u4e86\u89e3\u53cd\u5e94\u7684\u4e0d\u5747\u5300\u6027\uff0c\u4f7f\u7528\u5168\u89c6\u91ce\u900f\u5c04X\u5c04\u7ebf\u663e\u5fae\u955c\uff08TXM\uff09\u7ed3\u54083D XANES\u5728\u7edf\u8ba1\u548c\u5355\u4e2a\u7c92\u5b50\u6c34\u5e73\u4e0a\u8fdb\u884c\u4e86\u5316\u5b66\u72b6\u6001\u5206\u6790\u3002\u5728\u539f\u59cb\u72b6\u6001\u4e0b\uff0c\u89c2\u5bdf\u5230\u7684\u7c92\u5b50\u4e4b\u95f4\u4ee5\u53ca\u5355\u4e2a\u7c92\u5b50\u5185\u90e8\u7684\u989c\u8272\u5206\u5e03\u76f8\u5bf9\u5747\u5300\uff0c\u5bf9\u5e94\u5747\u5300\u7684Ni\u6c27\u5316\u72b6\u6001\u3002\u5f53\u5e26\u7535\u52304.1 V\u65f6\uff0c\u89c2\u5bdf\u5230\u7684\u7c92\u5b50\u989c\u8272\u9010\u6e10\u53d8\u4e3a\u9ec4\u8272\u548c\u7ea2\u8272\uff0c\u8fd9\u8868\u660e\u968f\u7740Li\u7684\u53bb\u9664Ni\u7684\u4ef7\u6001\u9010\u6e10\u589e\u52a0\u3002\u5f53\u7535\u538b\u8fbe\u52304.3 V\u548c4.5 V\u65f6\uff0c\u7c92\u5b50\u5185\u90e8\u53ef\u89c1\u66f4\u591a\u7684\u7ea2\u8272\u533a\u57df\u548c\u66f4\u4e0d\u5747\u5300\u7684\u989c\u8272\u5206\u5e03\uff0c\u8868\u660eNi\u4ef7\u6001\u7684\u663e\u8457\u589e\u52a0\u548c\u66f4\u4e0d\u5747\u5300\u7684Li<sup>+<\/sup>\u8131\u5d4c\u52a8\u529b\u5b66\u3002\u539f\u4f4dXRD\u4e5f\u663e\u793a\uff0cSC-NMC\u5728\u9ad8\u8131\u9502\u72b6\u6001\u4e0b\u7ecf\u5386\u4e86\u660e\u663e\u5927\u7684\u6676\u683c\u53d8\u5316\u3002\u5f53\u91cd\u65b0\u653e\u7535\u81f32.8 V\u65f6\uff0c\u7c92\u5b50\u5185\u90e8\u7684\u5316\u5b66\u6c27\u5316\u4e0d\u5747\u5300\u6027\u96be\u4ee5\u6d88\u9664\u6062\u590d\u5230\u539f\u59cb\u72b6\u6001\uff0c\u8fd9\u5f52\u56e0\u4e8e<strong>\u4e0d\u53ef\u9006\u6676\u683c\u65cb\u8f6c\u89e6\u53d1\u7684\u4e0d\u53ef\u9006\u7ed3\u6784\u9000\u5316\u548c\u7535\u5316\u5b66\u6027\u80fd\u8870\u51cf\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-260394\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-14.png\" alt=\"\" width=\"1062\" height=\"1081\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-14.png 1062w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-14-295x300.png 295w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-14-768x782.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-14-1006x1024.png 1006w\" sizes=\"(max-width: 1062px) 100vw, 1062px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5. SC-NMC<\/strong><strong>\u7ed3\u6784\u9000\u5316\u793a\u610f\u56fe\u3002<\/strong>\u00a9 2024 AAAS<\/p>\n<p>\u00a0<strong>3.<\/strong><strong>\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n<p>\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u5229\u7528\u591a\u5c3a\u5ea6\u8868\u5f81\u624b\u6bb5\u89e3\u91ca\u4e86\u5355\u6676\u5bcc\u954d\u6b63\u6781SC-NMC\u6750\u6599\u7ed3\u6784\u9000\u5316\u7684\u8d77\u6e90\u3002\u5f53Li<sup>+<\/sup>\u8131\u51fa\u65f6\uff0c\u5355\u4e2aSC-NMC\u7c92\u5b50\u5185\u90e8\u4f1a\u4ea7\u751f\u6676\u683c\u7578\u53d8\u548c\u6676\u683c\u65cb\u8f6c\u3002\u5f53Li<sup>+<\/sup>\u91cd\u65b0\u63d2\u5165\u65f6\uff0c\u6676\u683c\u7578\u53d8\u5927\u90e8\u5206\u662f\u53ef\u9006\u7684\uff0c\u4f46\u5355\u7eaf\u7684Li<sup>+<\/sup>\u91cd\u65b0\u63d2\u5165\u5e76\u4e0d\u80fd\u5b8c\u5168\u6d88\u9664\u6676\u683c\u65cb\u8f6c\u3002\u4e0d\u53ef\u9006\u7684\u6676\u683c\u65cb\u8f6c\u968f\u7740\u5faa\u73af\u7684\u8fdb\u884c\u9010\u6e10\u7d2f\u79ef\uff0c\u52a0\u5267\u4e86\u5f62\u6001\u548c\u7ed3\u6784\u7684\u7834\u574f\uff0c\u5982\u4ea7\u751f\u5fae\u88c2\u7eb9\u3001\u4e0d\u53ef\u9006\u7684\u76f8\u53d8\u548c\u8868\u9762\u7ed3\u6784\u9000\u5316\uff0c\u4ece\u800c\u5bfc\u81f4\u4e25\u91cd\u7684\u7535\u5316\u5b66\u8870\u53d8\u3002\u5728\u7535\u6c60\u6750\u6599\u4e2d\uff0c\u6676\u683c\u65cb\u8f6c\u4e0e\u6676\u683c\u7578\u53d8\u4e00\u6837\u666e\u904d\u5b58\u5728\uff0c\u800c\u4e14\u7531\u4e8e\u5b83\u5bf9\u4e0d\u53ef\u9006\u53d8\u5316\u7684\u654f\u611f\u6027\u66f4\u9ad8\uff0c\u56e0\u6b64\u4e0e\u6676\u683c\u7578\u53d8\u76f8\u6bd4\uff0c\u6211\u4eec\u53ef\u4ee5\u5c1d\u8bd5\u5c06\u6676\u683c\u65cb\u8f6c\u53ef\u4ee5\u4f5c\u4e3a\u7814\u7a76\u5931\u6548\u673a\u5236\u66f4\u654f\u611f\u66f4\u597d\u7684\u8bc4\u4ef7\u6307\u6807\u3002<strong>\u53d7\u6b64\u542f\u53d1\uff0c\u4e3a\u4e86\u5f97\u5230\u66f4\u7a33\u5b9a\u7684<\/strong><strong>SC-NMC<\/strong><strong>\u6750\u6599\uff0c\u5fc5\u987b\u8003\u8651\u51cf\u5c11\u6676\u683c\u65cb\u8f6c\u548c\u63d0\u9ad8\u6676\u683c\u7ed3\u6784\u5bf9\u5355\u4e2a\u7c92\u5b50\u5185\u90e8\u6676\u683c\u7578\u53d8\u7684\u8010\u53d7\u80fd\u529b<\/strong>\u3002\u672c\u7814\u7a76\u5de5\u4f5c\u6240\u5c55\u793a\u51fa\u7684\u7535\u5316\u5b66\u2014\u529b\u5b66\u76f8\u5173\u95ee\u9898\u7684\u8ba4\u77e5\u89e3\u91ca\u3001\u7535\u6781\u6750\u6599\u7814\u7a76\u8868\u5f81\u4e2d\u201c\u795e\u5175\u5229\u5668\u201d\u7684\u5f00\u53d1\u4f7f\u7528\uff0c\u5bf9\u957f\u5faa\u73af\u5bff\u547d\u548c\u9ad8\u80fd\u5bc6\u5ea6\u7684\u65b0\u4e00\u4ee3\u7535\u6c60\u5355\u6676\u6b63\u6781\u6750\u6599\u7814\u7a76\u5177\u6709\u6df1\u523b\u7684\u6307\u5bfc\u610f\u4e49\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1aHuang, et al. Unrecoverable lattice rotation governs structural degradation of single-crystalline cathodes, Science (2024). https:\/\/www.science.org\/doi\/10.1126\/science.ado1675\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>1.\u3010\u79d1\u5b66\u80cc\u666f\u3011 \u5bcc\u954d\u5c42\u72b6\u6c27\u5316\u7269\u6b63\u6781\uff08NMC\uff09\u88ab\u8ba4\u4e3a\u662f\u53d1\u5c55\u9ad8\u7eed\u822a\u7535\u52a8\u6c7d\u8f66\u7684\u5019\u9009\u6750\u6599\uff0c\u5176\u4e2d\uff0c\u8003\u8651\u5230\u80fd\u91cf\u5bc6\u5ea6\u548c\u9502\u79bb\u5b50\uff08Li+\uff09\u7684\u6269\u6563\u52a8\u529b\u5b66\uff0c\u805a\u96c6\u591a\u6676\u5df2\u6210\u4e3a\u5546\u4e1a\u5316\u6b63\u6781&#8230;<\/p>\n","protected":false},"author":35692,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-260389","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/260389"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35692"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=260389"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/260389\/revisions"}],"predecessor-version":[{"id":260405,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/260389\/revisions\/260405"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=260389"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=260389"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=260389"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}