{"id":260159,"date":"2024-05-12T07:45:25","date_gmt":"2024-05-11T23:45:25","guid":{"rendered":"\/\/m.iemloyee.com\/?p=260159"},"modified":"2024-05-11T21:56:36","modified_gmt":"2024-05-11T13:56:36","slug":"%e4%b8%ad%e5%8d%97%e5%a4%a7%e5%ad%a6%e6%9d%8e%e7%bb%b4%e6%9d%b0%e6%95%99%e6%8e%88angew-chem-%ef%bc%9a%e5%8a%9f%e8%83%bd%e5%9f%ba%e5%9b%a2%e7%bb%84%e8%a3%85%e7%ad%96%e7%95%a5%e8%ae%be%e8%ae%a1","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=260159","title":{"rendered":"\u4e2d\u5357\u5927\u5b66\u674e\u7ef4\u6770\u6559\u6388Angew. Chem.\uff1a\u529f\u80fd\u57fa\u56e2\u7ec4\u88c5\u7b56\u7565\u8bbe\u8ba1\u53cc\u7535\u5c42\u8c03\u63a7\u6dfb\u52a0\u5242\u7528\u4e8e\u63d0\u9ad8\u6c34\u7cfb\u950c\u91d1\u5c5e\u7535\u6c60\u4f7f\u7528\u5bff\u547d"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-260160\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-11.png\" alt=\"\" width=\"1504\" height=\"704\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-11.png 1504w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-11-300x140.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-11-768x359.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72471-11-1024x479.png 1024w\" sizes=\"(max-width: 1504px) 100vw, 1504px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u3010\u6587\u7ae0\u4fe1\u606f\u3011<\/b><\/strong><\/p>\n<p>\u529f\u80fd\u57fa\u56e2\u7ec4\u88c5\u7b56\u7565\u8bbe\u8ba1\u53cc\u7535\u5c42\u8c03\u63a7\u6dfb\u52a0\u5242\u7528\u4e8e\u63d0\u9ad8\u6c34\u7cfb\u950c\u91d1\u5c5e\u7535\u6c60\u4f7f\u7528\u5bff\u547d<\/p>\n<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u5218\u674e\u9633<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u674e\u7ef4\u6770*<\/p>\n<p>\u5355\u4f4d\uff1a\u4e2d\u5357\u5927\u5b66<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u3010\u7814\u7a76\u80cc\u666f\u3011<\/b><\/strong><\/p>\n<p>\u7531\u4e8e\u6c34\u7cfb\u950c\u91d1\u5c5e\u7535\u6c60\u5177\u6709\u9ad8\u5b89\u5168\u6027\uff0c\u4f4e\u6210\u672c\uff0c\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\uff0c\u5b83\u88ab\u89c6\u4e3a\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u4e2d\u9502\u79bb\u5b50\u7535\u6c60\u7684\u6709\u529b\u66ff\u4ee3\u8005\u3002\u7136\u800c\uff0c\u7531\u4e8e\u950c\u91d1\u5c5e\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u70ed\u529b\u5b66\u4e0d\u7a33\u5b9a\uff0c\u6613\u4e0e\u6c34\u53d1\u751f\u8150\u8680\u53cd\u5e94\uff0c\u8fdb\u800c\u5f15\u53d1\u4e00\u7cfb\u5217\u754c\u9762\u95ee\u9898\uff08\u5982\u60f0\u6027\u526f\u4ea7\u7269\u751f\u6210\uff0c\u679d\u6676\u751f\u957f\u7b49\uff09\u3002\u8fd9\u4e9b\u95ee\u9898\u4f7f\u5f97\u950c\u91d1\u5c5e\u8d1f\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u65e0\u6cd5\u6ee1\u8db3\u5b9e\u9645\u5e94\u7528\u9700\u6c42\uff0c\u4e25\u91cd\u963b\u788d\u4e86\u5176\u4ea7\u4e1a\u5316\u53d1\u5c55\u8fdb\u7a0b\u3002\u4f7f\u7528\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u8c03\u63a7\u950c\u91d1\u5c5e\u8d1f\u6781\u53cc\u7535\u5c42\u7ed3\u6784\u662f\u6291\u5236\u754c\u9762\u526f\u53cd\u5e94\u548c\u4fc3\u8fdb\u950c\u5747\u5300\u6c89\u79ef\u7684\u4e00\u79cd\u6709\u6548\u7b56\u7565\u3002\u7136\u800c\uff0c\u76ee\u524d\u5bf9\u4e8e\u53cc\u7535\u5c42\u8c03\u63a7\u6dfb\u52a0\u5242\u7684\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728\u63a2\u7a76\u5176\u5bf9\u950c\u91d1\u5c5e\u8d1f\u6781\u7a33\u5b9a\u6027\u7684\u6539\u5584\u673a\u5236\u4e0a\uff0c\u5c1a\u672a\u6709\u5173\u4e8e\u5982\u4f55\u5bf9\u8fd9\u7c7b\u6dfb\u52a0\u5242\u8fdb\u884c\u7ed3\u6784\u8bbe\u8ba1\u4ee5\u6709\u9488\u5bf9\u6027\u7684\u8c03\u63a7\u53cc\u7535\u5c42\uff0c\u4ece\u800c\u6539\u5584\u950c\u91d1\u5c5e\u8d1f\u6781\u7535\u5316\u5b66\u6027\u80fd\u7684\u62a5\u9053\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u3010\u6587\u7ae0\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u4e2d\u5357\u5927\u5b66\u674e\u7ef4\u6770\u6559\u6388\uff0c\u5728\u56fd\u9645\u77e5\u540d\u671f\u520a<strong><em>Angewandte Chemie International Edition<\/em><\/strong>\u4e0a\u53d1\u8868\u9898\u4e3a\u201cElectric Double Layer Regulator Design through a Functional Group Assembly Strategy towards Long-lasting Zinc Metal Batteries\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u8bba\u6587\u63d0\u51fa\u4e86\u4e00\u79cd\u529f\u80fd\u57fa\u56e2\u7ec4\u88c5\u7b56\u7565\uff0c\u65e8\u5728\u8bbe\u8ba1\u53cc\u7535\u5c42\u8c03\u63a7\u6dfb\u52a0\u5242\u7684\u7ed3\u6784\uff0c\u4ee5\u5b9e\u73b0\u5bf9\u950c\u91d1\u5c5e\u8d1f\u6781\u8868\u9762\u53cc\u7535\u5c42\u7684\u5b9a\u5411\u8c03\u63a7\uff0c\u4ece\u800c\u5ef6\u957f\u950c\u91d1\u5c5e\u7535\u6c60\u7684\u4f7f\u7528\u5bff\u547d\u3002\u5177\u4f53\u800c\u8a00\uff0c\u4f5c\u8005\u901a\u8fc7\u7b5b\u9009\u5341\u79cd\u5e38\u89c1\u7684\u529f\u80fd\u57fa\u56e2\uff0c\u5c06\u4e0e\u950c\u91d1\u5c5e\u6709\u8f83\u5f3a\u5438\u9644\u80fd\u529b\u7684\u54aa\u5511\u57fa\u56e2\u4e0e\u5bf9\u950c\u79bb\u5b50\u6709\u8f83\u5f3a\u7ed3\u5408\u80fd\u529b\u7684\u781c\u57fa\u8fdb\u884c\u7ec4\u88c5\uff0c\u5f97\u5230\u4e86N\uff0cN-\u4e8c\u7532\u57fa-1H-\u54aa\u5511-1-\u78fa\u9170\u80fa\uff08IS\uff09\u3002\u7531\u4e8e\u54aa\u5511\u57fa\u56e2\u7684\u5438\u9644\u529f\u80fd\uff0cIS\u5206\u5b50\u5728\u5185\u4ea5\u59c6\u970d\u5179\u5c42\u4e2d\u66ff\u4ee3\u4e86\u6c34\u5206\u5b50\u7684\u4f4d\u7f6e\uff0c\u5f62\u6210\u4e86\u4e00\u5c42\u5206\u5b50\u4fdd\u62a4\u5c42\uff0c\u4ece\u800c\u6709\u6548\u6291\u5236\u4e86\u7531\u6c34\u5f15\u53d1\u7684\u526f\u53cd\u5e94\u3002\u540c\u65f6\uff0cIS\u4e2d\u7684\u781c\u57fa\u5145\u5f53\u4e86\u950c\u79bb\u5b50\u7684\u7ed3\u5408\u4f4d\u70b9\uff0c\u5728\u950c\u6c89\u79ef\u8fc7\u7a0b\u4e2d\u4fc3\u8fdb\u950c\u79bb\u5b50\u7684\u53bb\u6eb6\u5242\u5316\uff0c\u4ece\u800c\u6709\u52a9\u4e8e\u5b9e\u73b0\u950c\u7684\u81f4\u5bc6\u6c89\u79ef\u3002\u57fa\u4e8e\u6b64\uff0c\u7535\u6c60\u4e2d\u7684\u6790\u6c22\u53cd\u5e94\u4e0e\u679d\u6676\u751f\u957f\u5f97\u5230\u4e86\u6709\u6548\u6291\u5236\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u4e86\u950c\u5bf9\u79f0\u7535\u6c60\u548c\u5168\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u8be5\u5de5\u4f5c\u4e3a\u53cc\u7535\u5c42\u8c03\u63a7\u6dfb\u52a0\u5242\u7684\u5b9a\u5411\u7ed3\u6784\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7b56\u7565\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-260161 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-12.png\" alt=\"\" width=\"3896\" height=\"2040\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-12.png 3896w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-12-300x157.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-12-768x402.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72472-12-1024x536.png 1024w\" sizes=\"(max-width: 3896px) 100vw, 3896px\" \/><\/p>\n<p>\u793a\u610f\u56fe1. \u53cc\u7535\u5c42\u8c03\u63a7\u6dfb\u52a0\u5242\u7684\u8bbe\u8ba1\u7b56\u7565\u793a\u610f\u56fe\u548cIS\u7a33\u5b9a\u950c\u91d1\u5c5e\u8d1f\u6781\u7684\u5de5\u4f5c\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u3010\u672c\u6587\u8981\u70b9\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u8981\u70b9\u4e00\uff1a\u53cc\u7535\u5c42\u8c03\u63a7\u6dfb\u52a0\u5242\u7684\u7ed3\u6784\u8bbe\u8ba1<\/b><\/strong><\/p>\n<p>\u4f5c\u8005\u901a\u8fc7\u8ba1\u7b97\u5341\u79cd\u5e38\u89c1\u529f\u80fd\u57fa\u56e2\u7684HOMO\u80fd\u7ea7\u6765\u8bc4\u4f30\u5404\u529f\u80fd\u57fa\u56e2\u5bf9\u950c\u91d1\u5c5e\u8d1f\u6781\u7684\u5438\u9644\u80fd\u529b\uff0c\u7ed3\u679c\u8868\u660e\u54aa\u5511\u57fa\u56e2\u7684HOMO\u6700\u9ad8\uff0c\u5177\u6709\u6700\u9ad8\u7684\u7ed9\u7535\u5b50\u80fd\u529b\uff0c\u66f4\u5bb9\u6613\u5438\u9644\u5728\u950c\u91d1\u5c5e\u8868\u9762\u3002\u56e0\u6b64\uff0c\u54aa\u5511\u57fa\u56e2\u88ab\u9009\u5b9a\u4e3a\u672c\u5de5\u4f5c\u4e2d\u6240\u8bbe\u8ba1\u6dfb\u52a0\u5242\u7684\u4e00\u90e8\u5206\u3002\u4e3a\u4e86\u7b5b\u9009\u4e00\u4e2a\u53ef\u4ee5\u6709\u6548\u4fc3\u8fdb\u950c\u79bb\u5b50\u53bb\u6eb6\u5242\u5316\u7684\u57fa\u56e2\uff0c\u4f5c\u8005\u8ba1\u7b97\u4e86\u4e0a\u8ff0\u529f\u80fd\u57fa\u56e2\u4e0e\u950c\u79bb\u5b50\u7684\u7ed3\u5408\u80fd\u3002\u867d\u7136\u54aa\u5511\u57fa\u56e2\u4e0e\u950c\u79bb\u5b50\u7684\u7ed3\u5408\u80fd\u529b\u6700\u5f3a\uff0c\u4f46\u662f\u54aa\u5511\u57fa\u56e2\u88ab\u8ba4\u4e3a\u662f\u4e00\u4e2a\u5438\u9644\u57fa\u56e2\uff0c\u5176\u6d3b\u6027\u4f4d\u70b9\u53ef\u80fd\u4e0e\u950c\u91d1\u5c5e\u53d1\u751f\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u4e0d\u80fd\u540c\u65f6\u4fc3\u8fdb\u950c\u79bb\u5b50\u7684\u53bb\u6eb6\u5242\u5316\u3002\u56e0\u6b64\uff0c\u5177\u6709\u4e0e\u950c\u79bb\u5b50\u7b2c\u4e8c\u9ad8\u7ed3\u5408\u80fd\u529b\uff0c\u5e76\u5bf9\u950c\u91d1\u5c5e\u6709\u8f83\u5f31\u5438\u9644\u80fd\u529b\u7684\u781c\u57fa\u88ab\u9009\u5b9a\u4e3a\u672c\u5de5\u4f5c\u4e2d\u6240\u8bbe\u8ba1\u6dfb\u52a0\u5242\u7684\u53e6\u4e00\u90e8\u5206\u3002\u901a\u8fc7\u641c\u7d22\u542b\u6709\u54aa\u5511\u548c\u781c\u57fa\u7684\u73b0\u6709\u5316\u5408\u7269\uff0c\u4f5c\u8005\u5f97\u5230\u4e861,1&#8242;-\u786b\u9170\u4e8c\u54aa\u5511\uff08DIS\uff09\u548cIS\u3002\u7136\u800c\u4e0d\u5e78\u7684\u662f\uff0cDIS\u5728\u7535\u89e3\u6db2\u4e2d\u4e0d\u6eb6\u89e3\u3002\u56e0\u6b64\uff0cIS\u88ab\u9009\u5b9a\u4e3a\u672c\u5de5\u4f5c\u4e2d\u8c03\u63a7\u950c\u91d1\u5c5e\u8868\u9762\u53cc\u7535\u5c42\u7684\u6dfb\u52a0\u5242\u3002\u968f\u540e\uff0c\u4f5c\u8005\u901a\u8fc7DFT\u8ba1\u7b97\u548c\u754c\u9762\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\uff0c\u8bc1\u660e\u4e86\uff0cIS\u4e2d\u54aa\u5511\u57fa\u56e2\u4f18\u5148\u5438\u9644\u5728\u950c\u8d1f\u6781\u8868\u9762\uff0c\u781c\u57fa\u53ef\u4ee5\u4fc3\u8fdb\u950c\u79bb\u5b50\u5728\u53cc\u7535\u5c42\u4e2d\u7684\u53bb\u6eb6\u5242\u5316\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-260162 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-9.png\" alt=\"\" width=\"2007\" height=\"2452\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-9.png 2007w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-9-246x300.png 246w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-9-768x938.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72473-9-838x1024.png 838w\" sizes=\"(max-width: 2007px) 100vw, 2007px\" \/><\/p>\n<p>\u56fe1.\u00a0(a) \u5177\u6709\u4e0d\u540c\u529f\u80fd\u57fa\u56e2\u7684\u6709\u673a\u5206\u5b50\u7684HOMO\u80fd\u7ea7\u3002(b) \u950c\u79bb\u5b50\u4e0e\u4e0d\u540c\u529f\u80fd\u57fa\u56e2\u4e4b\u95f4\u7684\u7ed3\u5408\u80fd\u3002(c) H2O\u3001IS-V \u548c IS-H \u5728\u950c (101) \u6676\u9762\u4e0a\u7684\u5438\u9644\u80fd\u3002(d) IS-V\u5728\u950c (101) \u6676\u9762\u4e0a\u5438\u9644\u7684\u7535\u8377\u5dee\u5206\u5bc6\u5ea6\u56fe\u3002(e) \u5728\u950c\u8d1f\u6781\u5e26\u8d1f\u7535\u72b6\u6001\u4e0b\uff0c\u950c\u8d1f\u6781\u8868\u9762\u533a\u57df\u7684\u7535\u89e3\u6db2\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u4fa7\u89c6\u56fe\u3002(f) \u5728\u950c\u8d1f\u6781\u5e26\u8d1f\u7535\u72b6\u6001\u4e0b\uff0c\u950c\u8d1f\u6781\u8868\u9762\u533a\u57df\u7684 O\uff08IS\uff09\u548c N1\uff08IS\uff09\u7684\u6d53\u5ea6\u5206\u5e03\u56fe\u3002(g) \u5728\u950c\u8d1f\u6781\u5e26\u8d1f\u7535\u72b6\u6001\u4e0b\uff0c\u754c\u9762\u548c\u4f53\u76f8\u7535\u89e3\u6db2\u4e2d Zn<sup>2+<\/sup>-O\uff08IS\uff09\u7684\u5f84\u5411\u5206\u5e03\u51fd\u6570\u56fe\u3002<\/p>\n<p><strong><b>\u8981\u70b9\u4e8c\uff1a\u901a\u8fc7\u8c03\u63a7\u53cc\u7535\u5c42\u7ed3\u6784\u6291\u5236\u526f\u53cd\u5e94<\/b><\/strong><\/p>\n<p>\u4f5c\u8005\u901a\u8fc7\u6d4b\u8bd5\u950c\u91d1\u5c5e\u5728IS0\u548cIS4\u4e2d\u7684\u53cc\u7535\u5c42\u7535\u5bb9\uff0czeta\u7535\u52bf\uff0c\u63a5\u89e6\u89d2\uff0c\u539f\u4f4d\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u4ee5\u53ca\u7535\u5316\u5b66\u963b\u6297\u8c31\u9a8c\u8bc1\u4e86IS\u7684\u5f15\u5165\u53ef\u4ee5\u6709\u6548\u7684\u6539\u53d8\u950c\u91d1\u5c5e\u8d1f\u6781\u8868\u9762\u7684\u53cc\u7535\u5c42\u7ed3\u6784\u3002\u968f\u540e\uff0c\u4f5c\u8005\u5bf9\u6539\u6027\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u53ca\u5176\u5bf9\u950c\u91d1\u5c5e\u8d1f\u6781\u7684\u8150\u8680\u6027\u8fdb\u884c\u4e86\u6d4b\u8bd5\uff0c\u7ed3\u679c\u8868\u660e\uff0c\u53cc\u7535\u5c42\u7ed3\u6784\u7684\u6539\u53d8\u63d0\u9ad8\u4e86\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u964d\u4f4e\u4e86\u7535\u89e3\u6db2\u5bf9\u950c\u91d1\u5c5e\u7684\u8150\u8680\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-260163 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-8.png\" alt=\"\" width=\"1270\" height=\"1050\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-8.png 1270w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-8-300x248.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-8-768x635.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72474-8-1024x847.png 1024w\" sizes=\"(max-width: 1270px) 100vw, 1270px\" \/><\/p>\n<p>\u56fe2. (a) \u5728IS0\u548cIS4\u4e2d\u950c\u8d1f\u6781\u7684\u53cc\u7535\u5c42\u7535\u5bb9\u3002(b) \u5728IS0\u548cIS4\u4e2d\u950c\u6c89\u79ef\u7269\u7684Zeta\u7535\u4f4d\u3002(c) IS0\u548cIS4\u5728\u950c\u8d1f\u6781\u8868\u9762\u7684\u63a5\u89e6\u89d2\u3002(d) \u950c\u8d1f\u6781\u5728IS4\u4e2d\u6c89\u79ef\u5265\u79bb\u65f6\u7684\u539f\u4f4d\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u8c31\u56fe\u3002(e) \u5faa\u73af\u524dZn\/\/ISx\/\/Zn\uff08x = 0\u62164\uff09\u7535\u6c60\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\u3002(f) Ti\/\/ISx\/\/Zn\uff08x = 0\u548c4\uff09\u7535\u6c60\u7684\u7ebf\u6027\u626b\u63cf\u66f2\u7ebf\u3002(g) \u950c\u8d1f\u6781\u5728IS0\u548cIS4\u4e2d\u7684\u5854\u83f2\u5c14\u66f2\u7ebf\u3002<\/p>\n<p><strong><b>\u8981\u70b9\u4e09\uff1a\u901a\u8fc7\u8c03\u63a7\u53cc\u7535\u5c42\u7ed3\u6784\u4fc3\u8fdb\u950c\u5747\u5300\u6c89\u79ef<\/b><\/strong><\/p>\n<p>\u4f5c\u8005\u5bf9\u6c89\u79ef20h\u540e\u7684\u950c\u91d1\u5c5e\u8d1f\u6781\u8fdb\u884c\u4e86\u8868\u9762\u7c97\u7cd9\u5ea6\uff0cSEM\uff0cXRD\u4ee5\u53caXPS\u7684\u8868\u5f81\uff0c\u5e76\u539f\u4f4d\u89c2\u6d4b\u4e86\u950c\u5728IS0\u4e0eIS4\u4e2d\u7684\u6c89\u79ef\u8fc7\u7a0b\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5f53\u4f7f\u7528IS\u8c03\u63a7\u950c\u91d1\u5c5e\u8d1f\u6781\u8868\u9762\u53cc\u7535\u5c42\u540e\uff0c\u950c\u91d1\u5c5e\u7684\u6c89\u79ef\u66f4\u52a0\u5747\u5300\u81f4\u5bc6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-260164 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-8.png\" alt=\"\" width=\"1270\" height=\"1392\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-8.png 1270w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-8-274x300.png 274w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-8-768x842.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72475-8-934x1024.png 934w\" sizes=\"(max-width: 1270px) 100vw, 1270px\" \/><\/p>\n<p>\u56fe3. (a) Zn\/\/ISx\/\/Zn\uff08x = 0\u548c4\uff09\u5145\u75355\u300110\u548c20\u5c0f\u65f6\u540e\uff0c\u950c\u8d1f\u6781\u7684\u7167\u7247\u3002Zn\/\/ISx\/\/Zn\uff08x = 0\u548c4\uff09\u5145\u753520\u5c0f\u65f6\u540e\u950c\u8d1f\u6781\u7684\u00a0(b) \u5149\u5b66\u8868\u9762\u8f6e\u5ed3\u6d4b\u91cf\u56fe\uff0c(c) \u8868\u9762\u9ad8\u5ea6\u5206\u5e03\u76f4\u65b9\u56fe\uff0c(d) SEM\u56fe\uff0c(e) XRD\u56fe\uff0c\u4ee5\u53ca\u00a0(f) XPS\u8c31\u56fe\uff08N 1s\uff09\u3002(g) \u5728\u539f\u4f4d\u5149\u5b66\u663e\u5fae\u955c\u4e0b\uff0c\u950c\u8d1f\u6781\u5728ISx\uff08x = 0\u548c4\uff09\u4e2d\u7684\u9540\u950c\u884c\u4e3a\u3002\u950c\u8d1f\u6781\u5728\uff08h\uff09IS0\u548c\uff08i\uff09IS4\u4e2d\u8fdb\u884c\u9540\u950c\u540e\u7684\u5149\u5b66\u663e\u5fae\u955c\u56fe\u7247\u3002(j)\u00a0\u5728IS0\u548cIS4\u4e2d\u6d4b\u5f97\u7684\u950c\u8d1f\u6781\u7684CA\u66f2\u7ebf\u3002<\/p>\n<p><strong><b>\u8981\u70b9\u56db\uff1a\u950c\u5bf9\u79f0\u7535\u6c60\u4e0e\u5168\u7535\u6c60\u6027\u80fd\u8bc4\u4f30<\/b><\/strong><\/p>\n<p>\u4e3a\u4e86\u9a8c\u8bc1IS4\u5728\u950c\u5bf9\u79f0\u7535\u6c60\u4ee5\u53ca\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u6709\u6548\u6027\uff0c\u4f5c\u8005\u6d4b\u8bd5\u4e86Zn\/\/ISx\/\/Zn\u548cZn\/\/ISx\/\/NaV<sub>3<\/sub>O<sub>8<\/sub>\u00b71.5H<sub>2<\/sub>O (NaV<sub>3<\/sub>O<sub>8<\/sub>\u00b71.5H<sub>2<\/sub>O = NVO) (x<em><i>\u00a0<\/i><\/em>= 0 and 4)\u7684\u957f\u5faa\u73af\u6027\u80fd\u548c\u500d\u7387\u6027\u80fd\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0cIS4\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u950c\u5bf9\u79f0\u7535\u6c60\u548c\u5168\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-260165 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72476-7.png\" alt=\"\" width=\"1270\" height=\"1324\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72476-7.png 1270w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72476-7-288x300.png 288w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72476-7-768x801.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72476-7-982x1024.png 982w\" sizes=\"(max-width: 1270px) 100vw, 1270px\" \/><\/p>\n<p>\u56fe4. Zn\/\/ISx\/\/Zn (x = 0 \u548c 4) \u5728 (a) 1 mA cm<sup>-2<\/sup>, 1 mAh cm<sup>-2<\/sup>, (b) 2.95 mA cm<sup>-2<\/sup>, 2.95 mAh cm<sup>-2<\/sup>\u548c (c) \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u548c\u9762\u5bb9\u91cf\u4e0b\u7684\u7535\u538b-\u65f6\u95f4\u66f2\u7ebf\u3002(d) Zn\/\/IS4\/\/Zn\u7535\u6c60\u4e0e\u5176\u4ed6\u4f7f\u7528\u6539\u6027\u7535\u89e3\u6db2\u7684\u950c\u5bf9\u79f0\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u5bf9\u6bd4\u3002(e) Zn\/\/IS0\/\/Zn \u548c (f) Zn\/\/IS4\/\/Zn \u5faa\u73af20\u5708\u540e\uff0c\u950c\u8d1f\u6781\u7684 SEM \u56fe\u3002(g) Zn\/\/ISx\/\/Cu (x = 0 \u548c 4) \u7535\u6c60\u7684\u5e93\u4ed1\u6548\u7387\u66f2\u7ebf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-260166 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72477-5.png\" alt=\"\" width=\"1272\" height=\"1063\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72477-5.png 1272w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72477-5-300x251.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72477-5-768x642.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/05\/\u56fe\u72477-5-1024x856.png 1024w\" sizes=\"(max-width: 1272px) 100vw, 1272px\" \/><\/p>\n<p>\u56fe5. (a) Zn\/\/IS4\/\/NVO\u5168\u7535\u6c60\u7684\u793a\u610f\u56fe\u3002Zn\/\/ISx\/\/NVO (x = 0 \u548c 4)\u7684\u00a0(b) CV\u66f2\u7ebf\u548c (c) \u957f\u5faa\u73af\u6d4b\u8bd5\u66f2\u7ebf\u3002Zn\/\/IS4\/\/NVO \u7684 (d) \u500d\u7387\u66f2\u7ebf\u548c (e) \u76f8\u5e94\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n<p><strong><b>\u8981\u70b9\u4e94\uff1a\u7ed3\u8bba<\/b><\/strong><\/p>\n<p>\u672c\u6587\u63d0\u51fa\u4e86\u4e00\u79cd\u529f\u80fd\u57fa\u56e2\u7ec4\u88c5\u7b56\u7565\uff0c\u7528\u4e8e\u8bbe\u8ba1\u53cc\u7535\u5c42\u8c03\u63a7\u6dfb\u52a0\u5242\u7684\u7ed3\u6784\uff0c\u4ece\u800c\u5b9a\u5411\u8c03\u63a7\u950c\u91d1\u5c5e\u8d1f\u6781\u8868\u9762\u7684\u53cc\u7535\u5c42\uff0c\u5b9e\u73b0\u4e86\u950c\u91d1\u5c5e\u7535\u6c60\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u63d0\u9ad8\u3002\u5728\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u901a\u8fc7\u7b5b\u9009\u5341\u79cd\u5e38\u89c1\u7684\u529f\u80fd\u57fa\u56e2\uff0c\u5c06\u5177\u6709\u5bf9\u950c\u91d1\u5c5e\u8d1f\u6781\u6709\u8f83\u5f3a\u5438\u9644\u80fd\u529b\u7684\u54aa\u5511\u57fa\u56e2\u4e0e\u5bf9\u950c\u79bb\u5b50\u6709\u8f83\u7ed3\u5408\u80fd\u529b\u7684\u781c\u57fa\u8fdb\u884c\u7ec4\u88c5\uff0c\u8bbe\u8ba1\u5f97\u5230IS\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cIS\u5206\u5b50\u4e2d\u7684\u54aa\u5511\u57fa\u56e2\u8d77\u5230\u4e86\u5438\u9644\u4f5c\u7528\uff0c\u5c06\u6574\u4e2aIS\u5206\u5b50\u5438\u9644\u5728\u950c\u8d1f\u6781\u8868\u9762\uff0c\u66ff\u4ee3\u4e86\u5185\u4ea5\u59c6\u970d\u5179\u5c42\u4e2d\u7684\u6c34\u5206\u5b50\uff0c\u6240\u5f62\u6210\u7684IS\u5206\u5b50\u4fdd\u62a4\u5c42\u6291\u5236\u4e86\u7531\u6c34\u5f15\u8d77\u7684\u526f\u53cd\u5e94\u3002\u4e0e\u6b64\u540c\u65f6\uff0cIS\u4e2d\u7684\u781c\u57fa\u53ef\u4ee5\u4fc3\u8fdb\u950c\u79bb\u5b50\u7684\u53bb\u6eb6\u5242\u5316\uff0c\u6709\u52a9\u4e8e\u950c\u91d1\u5c5e\u7684\u81f4\u5bc6\u6c89\u79ef\u3002\u6b64\u5916\uff0cIS\u5206\u5b50\u8fd8\u6539\u53d8\u4e86\u6c34\u7684\u6c22\u952e\u7f51\u7edc\u7ed3\u6784\uff0c\u6709\u6548\u964d\u4f4e\u4e86\u81ea\u7531\u6c34\u7684\u6d3b\u6027\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u6291\u5236\u4e86\u6790\u6c22\u53cd\u5e94\u3002\u56e0\u6b64\uff0cZn\/\/IS4\/\/Zn\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\u5f97\u5230\u4e86\u663e\u8457\u63d0\u5347\uff0c\u57281mA cm<sup>-2<\/sup>\u548c1mAh cm<sup>-2<\/sup>\u7684\u60c5\u51b5\u4e0b\u53ef\u7a33\u5b9a\u5de5\u4f5c1800\u5c0f\u65f6\u3002\u6b64\u5916\uff0cZn\/\/IS4\/\/NaVO\u5168\u7535\u6c60\u5faa\u73af1200\u5708\u540e\uff0c\u4ecd\u7136\u5177\u670991.2%\u7684\u5bb9\u91cf\u4fdd\u7559\u7387\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u3010\u6587\u7ae0\u94fe\u63a5\u3011<\/b><\/strong><\/p>\n<p>Electric Double Layer Regulator Design through a Functional Group Assembly Strategy towards Long-lasting Zinc Metal Batteries<\/p>\n<p><a href=\"https:\/\/doi.org\/10.1002\/anie.202405209\"><u>https:\/\/doi.org\/10.1002\/anie.202405209<\/u><\/a><\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u674e\u7ef4\u6770\u00a0<\/b><\/strong>\u6559\u6388\u7b80\u4ecb\uff1a\u674e\u7ef4\u6770\uff0c\u535a\u58eb\uff0c\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30022016\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u6fb3\u5927\u5229\u4e9a\u4f0d\u4f26\u8d21\u5927\u5b66\uff0c\u968f\u540e\u5728\u4f0d\u4f26\u8d21\u5927\u5b66\u505a\u535a\u58eb\u540e\u548cDECRA\u7814\u7a76\u5458\u30022022\u5e74\u4ee5\u7279\u8058\u6559\u6388\u8eab\u4efd\u5165\u804c\u4e2d\u5357\u5927\u5b66\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u65b0\u80fd\u6e90\u6750\u6599\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u3001\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7b49\u5e94\u7528\uff1b\u4e8c\u6b21\u7535\u6c60\u4f53\u7cfb\u4e2d\u56fa\u6001\u7535\u89e3\u8d28\u53ca\u7535\u89e3\u8d28\u754c\u9762\u819c\u7684\u7814\u7a76\uff1b\u4ee5\u53ca\u65b0\u578b\u6750\u6599\u5728\u80fd\u6e90\u9886\u57df\u7684\u5e94\u7528\u548c\u673a\u7406\u63a2\u7d22\u7814\u7a76\u3002\u4ee5\u7b2c\u4e00\u4f5c\u8005\u6216\u901a\u8baf\u4f5c\u8005\u5728<em><i>Adv. Mater.\u3001Angew. Chem. Int. Ed.<\/i><\/em>\u3001<em><i>ACS Nano\u3001Nano Lett.\u3001Adv. Funct. Mater.\u3001Adv. Energy Mater.\u3001Sci. Adv.<\/i><\/em>\u7b49\u56fd\u9645\u8457\u540d\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u658730\u4f59\u7bc7\uff0c\u4ee5\u5408\u4f5c\u8005\u8eab\u4efd\u5728<em><i>Angew. Chem. Int. Ed.\u3001Nature Comm.\u3001Energy Environ. Sci.<\/i><\/em>\u7b49\u56fd\u9645\u77e5\u540d\u671f\u520a\u53d1\u8868\u8bba\u658750\u4f59\u7bc7\uff0cGoogle \u5f15\u75286200\u6b21\uff0cH\u56e0\u5b5039\uff0c7\u7bc7\u8bba\u6587\u4e3aESI\u8fd1\u5341\u5e74\u9ad8\u88ab\u5f15\u8bba\u6587\u3002\u66fe\u83b7\u6fb3\u5927\u5229\u4e9a\u63a2\u7d22\u9879\u76ee\u9752\u5e74\u5b66\u8005\uff08DECRA fellow\uff09\uff0c\u6fb3\u5927\u5229\u4e9a\u4f18\u79c0\u9752\u5e74\u5b66\u8005\u6e38\u5b66\u5956\uff0c\u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\uff08JSPS\uff09fellow\u3002<\/p>\n<p><strong><b>\u3010\u8bfe\u9898\u7ec4\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n<p>\u76ee\u524d\uff0c\u674e\u7ef4\u6770\u8001\u5e08\u8bfe\u9898\u7ec4\u5df2\u5b8c\u6210\u5b9e\u9a8c\u5ba4\u7684\u5efa\u8bbe\uff0c\u62e5\u6709\u6750\u6599\u5236\u5907\u3001\u7535\u5316\u5b66\u68c0\u6d4b\u7b49\u4eea\u5668\u8bbe\u5907\uff0c\u5e76\u4e14\uff0c\u6240\u5728\u7cfb\u6240\u62e5\u6709\u4e00\u7cfb\u5217\u7535\u5316\u5b66\u76f8\u5173\u7684\u9ad8\u7aef\u68c0\u6d4b\u8bbe\u5907\uff0c\u6bd4\u5982\u539f\u4f4dXRD\uff0cDEMS, TOF-SIMS\uff0cSEM-FIB\u7b49\uff0c\u5177\u6709\u5b8c\u5584\u7684\u7535\u6c60\u7535\u6781\u6750\u6599\u5236\u5907\u548c\u6d4b\u8bd5\u6761\u4ef6\u3002\u8bfe\u9898\u7ec4\u4e3b\u8981\u4ece\u4e8b\u9ad8\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u3001\u950c\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\u7814\u53d1\u3001\u65b0\u80fd\u6e90\u50a8\u80fd\u5668\u4ef6\u7b49\u9886\u57df\u7684\u7814\u7a76\u3002<\/p>\n<p><strong><b>\u3010\u8bfe\u9898\u7ec4\u62db\u8058\u3011<\/b><\/strong><\/p>\n<p>\u6b22\u8fce\u6709\u5174\u8da3\u7684\u540c\u5b66\u52a0\u5165\u6211\u4eec\u8bfe\u9898\u7ec4\uff0c\u8bfe\u9898\u7ec4\u62db\u6536\u7855\u58eb\u3001\u535a\u58eb\u548c\u535a\u540e\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; \u3010\u6587\u7ae0\u4fe1\u606f\u3011 \u529f\u80fd\u57fa\u56e2\u7ec4\u88c5\u7b56\u7565\u8bbe\u8ba1\u53cc\u7535\u5c42\u8c03\u63a7\u6dfb\u52a0\u5242\u7528\u4e8e\u63d0\u9ad8\u6c34\u7cfb\u950c\u91d1\u5c5e\u7535\u6c60\u4f7f\u7528\u5bff\u547d \u7b2c\u4e00\u4f5c\u8005\uff1a\u5218\u674e\u9633 \u901a\u8baf\u4f5c\u8005\uff1a\u674e\u7ef4\u6770* \u5355\u4f4d\uff1a\u4e2d\u5357\u5927\u5b66 &#038;nbsp&#8230;<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-260159","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/260159"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=260159"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/260159\/revisions"}],"predecessor-version":[{"id":260170,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/260159\/revisions\/260170"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=260159"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=260159"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=260159"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}