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Commun.<\/em> 2021<\/strong>, 57<\/em>, 4496\u20134499\uff1bTetrahedron Chem<\/em> 2022<\/strong>, 1<\/em>, 100006\uff1bCell Rep. Phys. Sci.<\/em> 2022<\/strong>, 3<\/em>, 100875. Cell Rep. Phys. Sci. <\/em>2023<\/strong>, 4<\/em>, 101295; Nat. 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NTU\uff09\uff08\u56fe4D\uff09\u3002\u800c\u6ca1\u6709\u4f7f\u7528N2<\/sub>\u6d41\u5904\u7406\u7684\u6d51\u6d4a\u6eb6\u6db2\u7684\u6d4a\u5ea6\u4fdd\u6301\u5b8c\u5168\u4e0d\u53d8\u3002\u8be5\u7ed3\u679c\u8868\u660e\u8d85\u85431<\/strong>\u53ef\u4ee5\u901a\u8fc7\u7b80\u5355\u7684N2<\/sub>\u6d41\u5904\u7406\u5728\u5ba4\u6e29\u4e0b\u518d\u751f\u3002\u4e0e\u4f20\u7edf\u5316\u5b66\u5438\u9644\u5242\u6355\u83b7\u548c\u91ca\u653eCO2<\/sub>\u7c7b\u4f3c\uff0c\u5438\u9644\u5242\u6709\u6548\u518d\u751f\u548c\u91ca\u653eCO2<\/sub>\u6240\u9700\u7684\u6c14\u4f53\u6d41 \uff08N2<\/sub>\u6216Ar\uff09\u963b\u788d\u4e86\u91ca\u653eCO2<\/sub>\u7684\u5b9e\u9645\u6d53\u5ea6\u548c\u56de\u6536\uff0c\u6240\u4ee5\u4ecd\u9700\u63a2\u7d22\u65b0\u7684CO2<\/sub>\u8131\u9644\u65b9\u6cd5\u3002<\/p>\n \u4e8e\u662f\u4f5c\u8005\u5c06\u542bCO2<\/sub>\u7684\u6df7\u6d4a\u6eb6\u6db2\u5728\u5ba4\u6e29\u4e0b\u8fdb\u884c\u78c1\u529b\u6405\u62cc\uff08\u8f6c\u901f700\u8f6c\/\u5206\uff09\uff0c\u6eb6\u6db2\u6d4a\u5ea6\u572820\u5206\u949f\u5185\u8fc5\u901f\u4ece603 NTU\u964d\u81f3~0 NTU\uff0c\u8868\u660eCO2<\/sub>\u7684\u6210\u529f\u91ca\u653e\uff08\u56fe4D\uff09\u3002\u5728\u4e0d\u4f7f\u7528\u78c1\u529b\u6405\u62cc\u7684\u60c5\u51b5\u4e0b\uff0c\u542b\u6709CO2<\/sub>\u52a0\u5408\u7269\u6d51\u6d4a\u60ac\u6d6e\u6db2\u7684\u6d4a\u5ea6\u51e0\u4e4e\u4fdd\u6301\u4e0d\u53d8\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u6405\u62cc\u901f\u5ea6\u8d8a\u9ad8\uff0cCO2<\/sub>\u7684\u91ca\u653e\u901f\u7387\u8d8a\u5feb\uff08\u56fe4E\uff09\u3002\u5728\u6405\u62cc\u901f\u5ea6\u4e3a700\u8f6c\/\u5206\u7684\u60c5\u51b5\u4e0b\uff0c\u572820\u5206\u949f\u5185\uff0c\u6240\u6709\u56db\u79cdCO2<\/sub>\u6c14\u6e90\u90fd\u5b8c\u6210\u4e86\u4e8c\u6c27\u5316\u78b3\u7684\u89e3\u5438\uff0c\u89e3\u5438\u65f6\u95f4\u8fdc\u77ed\u4e8e\u90a3\u4e9b\u80fa\u57fa\u56fa\u4f53\u8f7d\u4f53\u7cfb\u7edf\u7684\u4f4e\u6e29\u4e8c\u6c27\u5316\u78b3\u91ca\u653e\u65f6\u95f4\uff08\u56fe4F\uff09\u3002<\/p>\n \u56fe4 \u4ece\uff08A\uff09\u7eafCO2<\/sub>\u3001\uff08B\uff09\u6a21\u62df\u70df\u6c14\uff08\u7ea2\u7ebf\u548c\u6b63\u65b9\u5f62\uff09\u548c\u547c\u51fa\u7a7a\u6c14\uff08\u84dd\u7ebf\u548c\u5706\u5708\uff09\u4ee5\u53ca\uff08C\uff09\u5ba4\u6e29\u6761\u4ef6\u4e0b\u7684\u5927\u6c14\u6d41\u4e2d\u5438\u9644CO2<\/sub>\u3002\uff08D\uff09\u5206\u522b\u4ece\u542bCO2<\/sub>\u7684\u6df7\u6d4a\u6eb6\u6db2\u4e2d\u89e3\u5438CO2<\/sub>\uff08\u9ed1\u7ebf\u548c\u5706\u5708\uff09\u6216\u901a\u8fc7N2<\/sub>\u6d41\uff08\u7ea2\u7ebf\u548c\u6b63\u65b9\u5f62\uff09\u548c\u78c1\u529b\u6405\u62cc\uff08\u84dd\u7ebf\u548c\u4e09\u89d2\u5f62\uff09\u52a0\u901fCO2<\/sub>\u3002\uff08E\uff09\u5206\u522b\u4ee5\u6bcf\u5206\u949f0\uff08\u9ed1\u7ebf\u548c\u4e09\u89d2\u5f62\uff09\u3001300\uff08\u7ea2\u7ebf\u548c\u6b63\u65b9\u5f62\uff09\u3001500\uff08\u7eff\u7ebf\u548c\u4e94\u8fb9\u5f62\uff09\u548c700\uff08\u84dd\u7ebf\u548c\u534a\u5706\uff09\u8f6e\u52a0\u901f\u78c1\u6405\u62cc\u5bf9\u542bCO2<\/sub>\u6df7\u6d4a\u6eb6\u6db2\u4e2dCO2<\/sub>\u7684\u89e3\u5438\u3002\uff08F\uff09\u4e0d\u540cCO2<\/sub>\u6e90\u8bf1\u5bfc\u7684\u542bCO2<\/sub>\u6df7\u6d4a\u60ac\u6d6e\u6db2\u4e2dCO2<\/sub>\u7684\u78c1\u6405\u62cc\u89e3\u5438\uff0c\u8f6c\u901f\u4e3a\u6bcf\u5206\u949f700\u8f6c<\/p>\n \u4f5c\u8005\u5bf9\u8d85\u85431<\/strong>\u8fde\u7eed\u6355\u83b7\/\u91ca\u653eCO2<\/sub>\u7684\u5faa\u73af\u80fd\u529b\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u7ed3\u679c\u8868\u660e\u5728\u8fde\u7eed\u8fdb\u884c\u4e8620\u4e2a\u6a21\u62df\u70df\u9053\u6c14\uff0812% CO2<\/sub> + 88%\u7a7a\u6c14\uff09CO2<\/sub>\u6355\u83b7\u2013\u91ca\u653e\u5faa\u73af\uff0c\u5176CO2<\/sub>\u5438\u8131\u9644\u80fd\u529b\u6ca1\u6709\u660e\u663e\u4e0b\u964d\uff08\u56fe5A\uff09\u3002\u4f7f\u7528\u4eba\u4f53\u547c\u6c14\u65f6\uff0c\u5728\u8fde\u7eed10\u4e2aCO2<\/sub>\u6355\u83b7\u2013\u91ca\u653e\u5faa\u73af\u540e\uff0c\u5176CO2<\/sub>\u5438\u8131\u9644\u80fd\u529b\u6ca1\u6709\u660e\u663e\u4e0b\u964d\uff08\u56fe5B\uff09\u3002\u4f7f\u7528\u5e72\u71e5\u7a7a\u6c14\u65f6\uff0c\u8fde\u7eed\u8fdb\u884c5\u4e2a\u5faa\u73af\u540e\uff0c\u5176CO2<\/sub>\u7684\u5438\u8131\u9644\u80fd\u529b\u57fa\u672c\u4fdd\u6301\u4e0d\u53d8\uff08\u56fe5C\uff09\u3002\u63a5\u7740\u5bf9\u91ca\u653eCO2<\/sub>\u7684\u8fdb\u884c\u6536\u96c6\uff0c\u6d4b\u8bd5\u5176CO2<\/sub>\u542b\u91cf\u9ad8\u8fbe83%\uff08\u56fe5E\uff09\u3002<\/p>\n \u56fe5\u8d85\u85431<\/strong>\u8fde\u7eed\u6355\u83b7\/\u91ca\u653eCO2<\/sub>\u7684\u5faa\u73af\u80fd\u529b \uff08A\uff09\u6a21\u62df\u70df\u6c14\uff0812% CO2<\/sub> + 88%\u7a7a\u6c14\uff09\u3001\uff08B\uff09\u547c\u51fa\u6c14\u4f53\u548c\uff08C\uff09\u5e72\u71e5\u7a7a\u6c14\u3002\uff08D\uff09 CO2<\/sub>\u6d53\u5ea6\u7cfb\u7edf\u793a\u610f\u56fe\u3002\uff08E\uff09\u6c14\u76f8\u8272\u8c31\u5cf0\u4e0eCO2<\/sub>\u542b\u91cf\uff08\u4ee5\u4f53\u79ef\u8ba1\uff09\u79ef\u5206\u5f97\u5230\u7684\u5f3a\u5ea6\u53d8\u5316\u3002\u6d4b\u5f97\u547c\u51fa\u7a7a\u6c14\u4e2dCO2<\/sub>\u7684\u4f53\u79ef\u542b\u91cf\u7ea6\u4e3a6%\uff0c\u800c\u5728\u547c\u51fa\u7a7a\u6c14\u901a\u8fc7\uff08D\uff09\u4e2d\u7684CO2<\/sub>\u6d53\u5ea6\u8bbe\u7f6e\u540e\uff0c\u8ba1\u7b97\u51fa\u6d53\u7f29CO2<\/sub>\u7684\u4f53\u79ef\u542b\u91cf\u4e3a83%\u3002<\/p>\n \u673a\u7406\u7814\u7a76<\/strong><\/p>\n \u6700\u540e\uff0c\u4f5c\u8005\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u4e86\u8d85\u85431<\/strong>\u5438\u9644CO2<\/sub>\u673a\u7406\uff0c\u7ed3\u679c\u8868\u660e\u5177\u6709\u8fd1\u5c01\u95ed\u5916\u58f3\u7684\u8d85\u85431<\/strong>\u53ef\u88ab\u89c6\u4e3a\u8868\u9762\u9644\u7740\u591a\u4e2a\u80fa\u5355\u5143\u7684\u4f2a\u9897\u7c92\uff08\u56fe6A\uff09\uff0cCO2<\/sub>\u6355\u83b7\u8f6c\u6362\u53ef\u4ee5\u5728\u201c\u9897\u7c92\u8868\u9762\u201d\u4e0a\u76f8\u90bb\u7684\u4e24\u4e2a\u80fa\u4e4b\u95f4\u8fdb\u884c\u3002\u5728\u5f62\u6210\u6c28\u57fa\u7532\u9178\u916f\u7edc\u5408\u7269\uff08\u590d\u5408\u72691\uff09\u7684\u60c5\u51b5\u4e0b\uff0c\u51fa\u73b0\u4e86\u516d\u5143\u73af\u8fc7\u6e21\u6001\uff08TS1\uff09\uff0c\u5176\u53cd\u5e94\u80fd\u5792\u4ec5\u4e3a6.4 kcal\/mol\uff0c\u53ef\u9006CO2<\/sub>\u91ca\u653e\u6d3b\u5316\u80fd\u4ec5\u4e3a8.7 kcal\/mol\uff0c\u8fd9\u53ef\u4ee5\u89e3\u91ca\u89c2\u5bdf\u5230\u7684\u4f18\u5f02CO2<\/sub>\u6355\u83b7\u548c\u91ca\u653e\u80fd\u529b\uff08\u56fe6A, 6B\uff09\u3002\u540c\u6837\uff0c\u5728\u5f62\u6210\u78b3\u9178\u6c22\u76d0\u7edc\u5408\u7269\uff08\u590d\u5408\u72692\uff09\u7684\u60c5\u51b5\u4e0b\uff0c\u89c2\u5bdf\u5230\u7a0d\u9ad8\u7684\u6d3b\u5316\u80fd\uff08\u4e8c\u6c27\u5316\u78b3\u6355\u83b711.8 kcal \/mol\uff0cCO2<\/sub>\u91ca\u653e13.4 kcal \/mol\uff09\u3002MD\u7ed3\u679c\u8868\u660e\uff0c\u5f62\u6210\u6c28\u57fa\u7532\u9178\u916f\u7684\u8d85\u85431<\/strong>\u4e0eCO2<\/sub>\u590d\u5408\u7269\u5728\u524d500 ps\uff0c\u8fc5\u901f\u805a\u96c6\u6210\u5c0f\u5206\u5b50\u7c07\uff08\u56fe6C\u3001D\uff09\uff0c\u5e76\u4e14\u5c0f\u5206\u5b50\u7c07\u5408\u5e76\u6210\u66f4\u5927\u7684\u805a\u96c6\u4f53\uff0c\uff08\u56fe6E\u3001 6F\uff09\uff0c\u5370\u8bc1\u4e86CO2<\/sub>\u6355\u83b7\u8fc7\u7a0b\u4e2d\u6c89\u6dc0\u7684\u4ea7\u751f\u3002\u603b\u7684\u6765\u8bf4\uff0c\u8f83\u4f4e\u7684\u8d85\u85431<\/strong>\u4e0eCO2<\/sub>\u7ed3\u5408\u548c\u91ca\u653e\u80fd\u5792\u4ee5\u53ca\u76f8\u53d8\u8fc7\u7a0b\uff08CO2<\/sub>\u6355\u83b7:\u4ece\u6eb6\u6db2\u5230\u6c89\u6dc0; CO2<\/sub>\u91ca\u653e:\u4ece\u6c89\u6dc0\u5230\u6eb6\u89e3\uff09\u5728\u5229\u7528\u673a\u68b0\u529b\u4fc3\u8fdbCO2<\/sub>\u5728\u5ba4\u6e29\u91ca\u653e\u4e2d\u53d1\u6325\u5173\u952e\u4f5c\u7528\u3002<\/p>\n
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