{"id":259038,"date":"2024-03-31T06:57:10","date_gmt":"2024-03-30T22:57:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=259038"},"modified":"2024-03-30T22:52:14","modified_gmt":"2024-03-30T14:52:14","slug":"%e5%b9%bf%e4%b8%9c%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%e7%89%9f%e4%b8%ad%e9%a3%9e%e8%af%be%e9%a2%98%e7%bb%84lpr%ef%bc%9a%e8%93%9d%e5%85%89%e6%bf%80%e5%8f%91%e4%b8%8bnir-%e2%85%a0%e5%92%8c%e2%85%a1","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=259038","title":{"rendered":"\u5e7f\u4e1c\u5de5\u4e1a\u5927\u5b66\u725f\u4e2d\u98de\u8bfe\u9898\u7ec4LPR\uff1a\u84dd\u5149\u6fc0\u53d1\u4e0bNIR-\u2160\u548c\u2161\u8d85\u5bbd\u5e26\u53d1\u5c04\uff0c\u94ec\u954d\u5171\u63baSr2GaTaO6\uff0c\u53cc\u4f4d\u70b9\u5360\u636e\u548c\u6709\u6548\u7684\u80fd\u91cf\u8f6c\u79fb"},"content":{"rendered":"

\u4e00\u3001\u7814\u7a76\u80cc\u666f<\/strong><\/p>\n

\u8fd1\u7ea2\u5916\u5149\u8c31\u6280\u672f\u7531\u4e8e\u5728\u98df\u54c1\u68c0\u6d4b\u3001\u533b\u5b66\u6210\u50cf\u3001\u5316\u5408\u7269\u9274\u5b9a\u548c\u6e29\u5ea6\u4f20\u611f\u7b49\u65b9\u9762\u7684\u5e7f\u6cdb\u5e94\u7528\uff0c\u5f15\u8d77\u4e86\u7814\u7a76\u4eba\u5458\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u8fd1\u7ea2\u5916\u7684\u5177\u4f53\u6ce2\u957f\u8303\u56f4\u4e3a780-2526 nm\u3002\u5176\u4e2d\uff0c700-1000 nm\u5c5e\u4e8eNIR-I, 1000-1700 nm\u5c5e\u4e8eNIR-II\u3002\u8fd1\u7ea2\u5916\u5149\u8c31\u5206\u6790\u8bbe\u5907\u6b63\u671d\u7740\u5c0f\u578b\u5316\u3001\u4fbf\u643a\u5316\u7684\u65b9\u5411\u53d1\u5c55\u3002\u4f20\u7edf\u7684\u8fd1\u7ea2\u5916\u5149\u6e90\uff0c\u5982\u767d\u70bd\u706f\u548c\u5364\u7d20\u706f\uff0c\u5177\u6709\u5e7f\u6cdb\u7684\u5149\u8c31\u8986\u76d6\u8303\u56f4\uff0c\u4f46\u5b83\u4eec\u5b58\u5728\u4e25\u91cd\u7684\u95ee\u9898\uff0c\u5982\u4f53\u79ef\u5927\uff0c\u6548\u7387\u4f4e\uff0c\u6e29\u5ea6\u9ad8\uff0c\u5bff\u547d\u77ed\u3002\u8fd1\u7ea2\u5916\u53d1\u5149\u4e8c\u6781\u7ba1\u5177\u6709\u6548\u7387\u9ad8\u3001\u4f53\u79ef\u5c0f\u7684\u7279\u70b9\uff0c\u4f46\u5b83\u4eec\u901a\u5e38\u8868\u73b0\u4e3a\u7a84\u5e26\u53d1\u5c04\uff0c\u8fd9\u9650\u5236\u4e86\u5b83\u4eec\u5728\u5149\u8c31\u5b66\u4e2d\u7684\u5e94\u7528\u3002\u8fd1\u5e74\u6765\uff0c\u5c06\u5bbd\u5e26\u8fd1\u7ea2\u5916\u8367\u5149\u7c89\u4e0e\u5927\u529f\u7387LED\u82af\u7247\u76f8\u7ed3\u5408\u5f62\u6210\u7684\u8fd1\u7ea2\u5916\u78f7\u5149\u8f6c\u6362\u53d1\u5149\u4e8c\u6781\u7ba1(NIR pc-LED)\u5f88\u597d\u5730\u89e3\u51b3\u4e86\u4e0a\u8ff0\u95ee\u9898\uff0c\u663e\u793a\u51fa\u6210\u672c\u4f4e\u3001\u5bbd\u5e26\u53ef\u8c03\u3001\u6548\u7387\u9ad8\u3001\u5bff\u547d\u957f\u7b49\u4f18\u70b9\u3002<\/p>\n

\u8fd1\u7ea2\u5916\u53d1\u5149\u8367\u5149\u7c89\u4e2d\u63ba\u6742\u7684\u6fc0\u6d3b\u5242\u79bb\u5b50\u5927\u81f4\u53ef\u5206\u4e3a\u4e09\u4ef7\u9567\u7cfb\u79bb\u5b50\u548c\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u3002\u4e09\u4ef7\u9567\u7cfb\u79bb\u5b50(Er3+<\/sup>\u3001Pr3+<\/sup>\u3001Yb3+<\/sup>\u3001Tm3+<\/sup>\u548cNd3+<\/sup>)\u7531\u4e8e4f-4f\u7981\u6b62\u81ea\u65cb\u8dc3\u8fc1\uff0c\u5177\u6709\u7a84\u5e26\u8fd1\u7ea2\u5916\u53d1\u5c04\u7279\u6027\uff0c\u53d1\u5149\u6548\u7387\u8f83\u4f4e\u3002\u76f8\u53cd\uff0cMn2+<\/sup>\u3001Fe3+<\/sup>\u3001Cr3+<\/sup>\u3001Cr4+<\/sup>\u548cNi2+<\/sup>\u7b49\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u7531\u4e8e3d-3d\u81ea\u65cb\u5141\u8bb8\u8dc3\u8fc1\u800c\u83b7\u5f97\u5bbd\u5e26\u8fd1\u7ea2\u5916\u53d1\u5c04\u3002\u5176\u4e2d\uff0cMn2+<\/sup>\u3001Fe3+<\/sup>\u3001Cr3+<\/sup>\u7684\u53d1\u5c04\u533a\u4f4d\u4e8eNIR-\u2160\uff0c\u800cCr4+<\/sup>\u3001Ni2+<\/sup>\u7684\u53d1\u5c04\u533a\u4f4d\u4e8eNIR- ii\u3002Cr3+<\/sup>\u79bb\u5b50\u56e0\u5176\u5bf9\u7d2b\u5916\u7ebf\u3001\u84dd\u5149\u548c\u7ea2\u5149\u7684\u5e7f\u6cdb\u5438\u6536\u800c\u5907\u53d7\u9752\u7750\uff0c\u4f7f\u5176\u6210\u4e3a\u9ad8\u6548\u3001\u5ec9\u4ef7\u7684\u5546\u7528\u84dd\u5149LED\u82af\u7247\u7684\u5b8c\u7f8e\u642d\u914d\u3002\u8fd1\u5e74\u6765\uff0c\u6709\u5927\u91cf\u5173\u4e8eCr3+<\/sup>\u63ba\u6742\u8fd1\u7ea2\u5916\u8367\u5149\u7c89\u7684\u7814\u7a76\u62a5\u9053\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u5728\u516b\u9762\u4f53\u5f31\u6676\u4f53\u573a\u4e2d\u63ba\u6742Cr3+<\/sup>\u79bb\u5b50\u53ef\u4ea7\u751f\u7ea6600-1200nm\u7684\u5bbd\u5e26\u53d1\u5c04\u3002<\/p>\n

\u4e0eNIR-I\u76f8\u6bd4\uff0cNIR-II\u80fd\u66f4\u597d\u5730\u5339\u914dC-H\u3001O-H\u3001N-H\u7b49\u5316\u5b66\u952e\u7684\u5438\u6536\uff0c\u5177\u6709\u66f4\u9ad8\u7684\u63a2\u6d4b\u7075\u654f\u5ea6\u548c\u7a7a\u95f4\u5206\u8fa8\u7387\u3002\u6b64\u5916\uff0cNIR-II\u8367\u5149\u7c89\u7684\u5bbd\u5e26\u53d1\u5c04\u4e3b\u8981\u8986\u76d61000-1700 nm\uff0c\u66f4\u7b26\u5408In-GaAs\u63a2\u6d4b\u5668\u7684\u63a2\u6d4b\u8303\u56f4(900-1700 nm)\uff0c\u56e0\u6b64\u5728\u751f\u7269\u6210\u50cf\u548c\u5316\u5408\u7269\u9274\u5b9a\u65b9\u9762\u5177\u6709\u66f4\u5e7f\u6cdb\u7684\u5e94\u7528\u3002Ni2+<\/sup>\u662fNIR-II\u533a\u7406\u60f3\u7684\u53d1\u5149\u4e2d\u5fc3\uff0c\u56e0\u4e3a\u5177\u67093d8<\/sup>\u7535\u5b50\u6784\u578b\u7684Ni2+<\/sup>\u5bf9\u6676\u4f53\u573a\u73af\u5883\u975e\u5e38\u654f\u611f\u3002\u76f8\u5bf9\u4e8eCr3+<\/sup>\uff0c\u76ee\u524d\u5bf9Ni2+<\/sup>\u7684\u7814\u7a76\u8f83\u5c11\u3002<\/p>\n

\u7efc\u5408\u4ee5\u4e0a\u5206\u6790\uff0c\u5f53\u524d\u8fd1\u7ea2\u5916\u8367\u5149\u6750\u6599\u7684\u7814\u7a76\u5b58\u5728\u8fd9\u6837\u4e00\u4e2a\u56f0\u5883\uff1aCr3+<\/sup>\u63ba\u6742\u6750\u6599\u53ef\u4ee5\u88ab\u84dd\u5149\u82af\u7247\u6fc0\u53d1\uff0c\u4f46\u5176\u53d1\u5c04\u4f4d\u4e8eNIR-I\u533a(650-1000 nm)\u3002Ni2+<\/sup>\u63ba\u6742\u6750\u6599\u4e3b\u8981\u4f4d\u4e8eNIR-II\u533a(1000-1700 nm)\uff0c\u4f46\u4e0d\u80fd\u88ab\u84dd\u5149\u82af\u7247\u6709\u6548\u6fc0\u53d1\u3002<\/p>\n

\u4e8c\u3001\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n

\u57fa\u4e8e\u4e0a\u8ff0\u7814\u7a76\u80cc\u666f\uff0c\u672c\u5de5\u4f5c\u5408\u6210\u4e86\u4e00\u7cfb\u5217Cr3+<\/sup>\u3001Ni2+<\/sup>\u5355\u63ba\u6742\u548c\u5171\u63ba\u6742\u7684Sr2<\/sub>GaTaO6<\/sub>\u8fd1\u7ea2\u5916\u53d1\u5149\u8367\u5149\u7c89\uff0c\u5e76\u5bf9\u5176\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u7814\u7a76\u3002<\/p>\n

Cr3+<\/sup>\u548cNi2+<\/sup>\u79bb\u5b50\u5360\u636eGa3+<\/sup>\u548cTa5+<\/sup>\u7684\u4e24\u4e2a\u516b\u9762\u4f53\u4f4d\u7f6e\u3002Cr3+<\/sup>\u79bb\u5b50\u5171\u63ba\u6742\u53d6\u5f97\u4e86\u4e24\u4e2a\u7a81\u7834\u3002\u4e00\u79cd\u662f\u4eceCr3+<\/sup>\u5230Ni2+<\/sup>\u7684\u80fd\u91cf\u8f6c\u79fb(\u6548\u7387\u9ad8\u8fbe70%)\uff0c\u5c06\u6700\u4f73\u6fc0\u53d1\u6ce2\u957f\u4ece\u7d2b\u5149\u8f6c\u79fb\u5230\u84dd\u5149\u3002\u4e8c\u662f\u5b9e\u73b0NIR-I\u548cNIR-II\u533a\u57df(650 ~ 1700 nm)\u7684\u5bbd\u5e26\u8fde\u7eed\u53d1\u5c04\uff0c\u534a\u5cf0\u5168\u5bbd(FWHM)\u4e3a410 nm (173 nm + 237 nm)\u3002<\/p>\n

\u6240\u5236\u5907\u7684\u8fd1\u7ea2\u5916\u8367\u5149\u7c89\u5177\u6709\u826f\u597d\u7684\u53d1\u5149\u70ed\u7a33\u5b9a\u6027(\u5728373 K\u65f6\uff0c\u53d1\u5c04\u5f3a\u5ea6\u76f8\u5bf9\u4e8e\u5ba4\u6e29\u4fdd\u630170%)\u3002<\/p>\n

\u5c06\u5236\u5907\u7684Sr2<\/sub>GaTaO6<\/sub>: 0.02Cr3+<\/sup>\uff0c\u00a00.01Ni2+<\/sup>\u8367\u5149\u7c89\u4e0e\u5546\u7528460 nm\u84dd\u82af\u7247\u76f8\u7ed3\u5408\uff0c\u5b9e\u73b0\u4e86\u5176\u5728\u6709\u673a\u5316\u5408\u7269\u8bc6\u522b\u3001\u591c\u89c6\u548c\u751f\u7269\u6210\u50cf\u7b49\u65b9\u9762\u7684\u5e94\u7528\u3002<\/p>\n

\u672c\u7814\u7a76\u4e3a\u672a\u6765\u9ad8\u6548\u8d85\u5bbd\u5e26\u8fd1\u7ea2\u5916\u53d1\u5149\u6750\u6599\u7684\u53d1\u5c55\u6307\u660e\u4e86\u65b9\u5411\u3002<\/p>\n

\u4e09\u3001\u56fe\u6587\u5bfc\u8bfb<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1. a)Sr\u3001Ga\u3001Ta\u7684SGTO\u6676\u4f53\u7ed3\u6784\u3001\u914d\u4f4d\u73af\u5883\u793a\u610f\u56fe\u3002b)SGTO\u3001SGTO\uff1a0.01Ni2+<\/sup>\u3001SGTO\uff1a0.02Cr3+<\/sup>\u3001YNi2+<\/sup>\u7684XRD\u6a21\u5f0f\uff08Y = 0\u30010.006\u30010.01\u30010.02\u30010.04\uff09\u3002c)SGTO\u7684\u89c6\u7f51\u819c\u7ec6\u5316\uff1a0.02Cr3+<\/sup>\uff0c0.01Ni2+<\/sup>\u3002d)\u6676\u683c\u53c2\u6570\uff08a\u3001V\u3001d\uff08Ta\u2500O\uff09\u548cd\uff08Ga\u2500O\uff09\uff09\u4f5c\u4e3aNi2+<\/sup>\u6d53\u5ea6\u7684\u51fd\u6570\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2. a)SGTO\uff1a0.02Cr3+<\/sup>\u30010.01Ni2+<\/sup>\u548cSr\u3001Ga\u3001Ta\u3001O\u3001Cr\u3001Ni.b\u7684EDS\u5143\u7d20\u56fe\u8c31)(i)SGTO\u7684XPS\u5168\u8c31\uff1a0.02Cr3+<\/sup>\u30010.01Ni2+<\/sup>\uff0c\uff08ii\uff09XPS\uff1aCr 2p\u8c31\uff0c\uff08iii\uff09XPS\uff1aNi 2p\u8c31\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3. a)SGTO\u7684DR\u5149\u8c31\uff0cSGTO\uff1a0.02Ni2+<\/sup>\uff0cSGTO\uff1a0.01Cr3+<\/sup>\uff0cSGTO\uff1a0.02Cr3+<\/sup>\uff0c0.01Ni2+<\/sup>\u3002b)SGTO\uff1a0.02Cr3+<\/sup>\u5728783 nm\u6fc0\u53d1\u5149\u8c31\u76d1\u6d4b\uff0cSGTO\uff1a0.01Ni2+<\/sup>\u57281295 nm\u6fc0\u53d1\u5149\u8c31\u76d1\u6d4b\u3002c)SGTO\uff1axCr3+<\/sup>\u5728455 nm\u6fc0\u53d1\u4e0b\u7684\u6d53\u5ea6\u4f9d\u8d56\u6027\u53d1\u5c04\u5149\u8c31\u3002d)SGTO\uff1ayNi2+<\/sup>\u5728398 nm\u6fc0\u53d1\u4e0b\u7684\u6d53\u5ea6\u4f9d\u8d56\u6027\u53d1\u5c04\u5149\u8c31\u3002e)SGTO\u53d1\u5c04\u5149\u8c31\u7684\u9ad8\u65af\u62df\u5408\uff1a0.02Cr3+<\/sup>\u3002f)\u5bf9SGTO\uff1a0.01Ni2+<\/sup>\u7684\u53d1\u5c04\u5149\u8c31\u8fdb\u884c\u9ad8\u65af\u62df\u5408\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4. a)(i)SGTO 0.02Cr3+<\/sup>\u7684\u53d1\u5c04\u5149\u8c31\u548cSGTO 0.01Ni2+<\/sup>\u7684\u6fc0\u53d1\u5149\u8c31\uff0c\uff08ii\uff09SGTO 0.02Cr3+<\/sup>\uff0c0.01Ni2+<\/sup>\u7684\u53d1\u5c04\u548c\u6fc0\u53d1\u5149\u8c31\u3002b)SGTO\uff1aXCr3+<\/sup>\uff0c0.01Ni2+<\/sup>\uff08X=0.002\u20130.04\uff09\u7684\u6fc0\u53d1\u5149\u8c31\u3002c)SGTO\uff1a0.02Cr3+<\/sup>\uff0cYNi2+<\/sup>\uff08Y=0.002\u20130.04\uff09\u3002d)Cr3+<\/sup>\u548cNi2+<\/sup>\u5728SGTO\u4e2d\u7684\u80fd\u91cf\u4f20\u9012\uff08ET\uff09\u8fc7\u7a0b\u56fe\u3002e)SGTO\uff1a0.02Cr3+<\/sup>\uff1aYNi2+<\/sup>\uff08Y=0,0.006,0.01,0.02,0.04\uff09\u6837\u54c1\u7684Cr3+<\/sup>\u7684\u8367\u5149\u5bff\u547d\u8870\u51cf\u66f2\u7ebf\u3002f)Cr3+<\/sup>\u7684\u8367\u5149\u5bff\u547d\u548c\u80fd\u91cf\u8f6c\u79fb\u6548\u7387\u53d8\u5316\uff1a0.02Cr3+<\/sup>\u3001YNi2+<\/sup>\uff08Y = 0\u30010.006\u30010.01\u30010.02\u548c0.04\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5. a)SGTO\u7684\u6e29\u5ea6\u76f8\u5173\u66f2\u7ebf\u56fe\uff1a0.02Cr3+<\/sup>\u3002b)SGTO\uff1a0.01Ni2+<\/sup>\u3002c)SGTO\u7684\u6e29\u5ea6\u76f8\u5173\u7b49\u503c\u7ebf\u56fe\uff1a0.02Cr3+<\/sup>\uff0c0.01Ni2+<\/sup>\u3002d)\u8367\u5149\u7c89\u7efc\u5408\u53d1\u5c04\u5f3a\u5ea6\u968f\u6e29\u5ea6\u7684\u53d8\u5316\u8d8b\u52bf\u53ca\u70ed\u6dec\u706d\u6d3b\u5316\u80fd\u7684\u8ba1\u7b97\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6. a)\u6709\u673a\u6eb6\u6db2\u7684NIR\u5438\u6536\u6d4b\u91cf\u793a\u610f\u56fe\u3002b)\u4e0d\u540c\u6709\u673a\u6eb6\u6db2\u7684NIR\u900f\u5c04\u5149\u8c31\u3002c)\u4e0d\u540c\u6d53\u5ea6\u4e0b\u6c28\u548c\u6c34\u6df7\u5408\u7269\u7684NIR\u900f\u5c04\u5149\u8c31\u3002d)\u5bf9\u6c28\u548c\u6c34\u6df7\u5408\u7269\u4e2d\u4e09\u79cd\u4e0d\u540c\u7684\u5438\u6536\u5cf0\u7684\u62df\u5408\u7ed3\u679c\u3002<\/p>\n

\"\"<\/p>\n

\u56fe7. a)\u4e0d\u540c\u7535\u6d41\u4e0bNIR\u82af\u7247\u7684EL\u5149\u8c31\u3002b)\u5728\u9ed1\u6697\u4e2d\u6b63\u5e38\u76f8\u673a\u6355\u83b7\u7684NIR\u82af\u7247\u3001\u9e21\u86cb\u548c\u82f9\u679c\u7684\u5e94\u7528(i)\uff1bVIS\uff08ii\uff09\u4e2d\u666e\u901a\u76f8\u673a\u6355\u83b7\u7684\u9e21\u86cb\u548c\u82f9\u679c\uff08ii\uff09\uff1b\u5728\u9ed1\u6697\u4e2dNIR\u76f8\u673a\u6355\u83b7\u7684\u9e21\u86cb\u548c\u82f9\u679c\uff08iii\uff09\uff1b\u624b\u6307\u4e2d\u8840\u7ba1\u7684\u5206\u5e03\uff08iv\uff09\u3002<\/p>\n

\u56db\u3001\u8bba\u6587\u4fe1\u606f<\/strong><\/p>\n

Laser & Photonics ReviewsSuper Broadband Emission Across NIR-I and NIR-II Under Blue Light Excitation of Cr3+<\/sup>, Ni2+<\/sup> Co-Doped Sr2<\/sub>GaTaO6<\/sub> Phosphor Achieved by Two-Site Occupation and Effective Energy Transfer<\/p>\n

Yifu Zhuo, Fugen Wu, Yaping Niu, Yun Wang, Qi zhang, Yun Teng, Huafeng Dong, Zhongfei Mu<\/p>\n

First published: 20 March 2024<\/p>\n

https:\/\/doi.org\/10.1002\/lpor.202400105<\/p>\n

March 2024https:\/\/doi.org\/10.1002\/lpor.202400105<\/p>\n","protected":false},"excerpt":{"rendered":"

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