{"id":258624,"date":"2024-03-17T06:54:56","date_gmt":"2024-03-16T22:54:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=258624"},"modified":"2024-03-17T08:46:09","modified_gmt":"2024-03-17T00:46:09","slug":"angew-chem-int-ed-%ef%bc%9a%e5%88%a9%e7%94%a8%e6%b0%a2%e9%86%8c-%e8%8b%af%e9%86%8chq-bq%e6%b0%a7%e5%8c%96%e6%80%81%e6%8e%a7%e5%88%b6%e5%ae%9e%e7%8e%b0%e9%ab%98%e8%bf%81%e7%a7%bb%e7%8e%87","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=258624","title":{"rendered":"Angew. Chem. Int. Ed. \uff1a\u5229\u7528\u6c22\u918c\/\u82ef\u918c(HQ\/BQ)\u6c27\u5316\u6001\u63a7\u5236\u5b9e\u73b0\u9ad8\u8fc1\u79fb\u7387\u5171\u8f6d\u914d\u4f4d\u805a\u5408\u7269\u7684\u80fd\u5e26\u8c03\u5236"},"content":{"rendered":"

\u80cc\u666f\u4ecb\u7ecd<\/strong><\/p>\n

\u5171\u8f6d\u914d\u4f4d\u805a\u5408\u7269\uff08conjugated coordination polymers, c-CPs\uff09\u56e0\u5176\u4f18\u5f02\u7535\u5b66\u6027\u80fd\u3001\u53ef\u8bbe\u8ba1\u7684\u5206\u5b50\u7ed3\u6784\u3001\u53ef\u8c03\u63a7\u7684\u80fd\u7ea7\u4ee5\u53ca\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u5728\u51dd\u805a\u6001\u7269\u7406\u7684\u63a2\u7d22\u548c\u5148\u8fdb\u5149\u7535\u5668\u4ef6\u548c\u7eff\u8272\u80fd\u6e90\u5668\u4ef6\u7684\u5e94\u7528\u5f00\u53d1\u4e2d\u90fd\u5177\u6709\u5e7f\u9614\u7684\u524d\u666f\u3002c-CP\u901a\u8fc7\u5e73\u9762\u5171\u8f6d\u914d\u4f53\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u4e4b\u95f4\u7684\u6709\u5e8f\u81ea\u7ec4\u88c5\u8fdb\u884c\u6784\u7b51\uff0c\u516d\u5def\u57fa\u82ef\uff08BHT\uff09\uff0c\u516d\u7f9f\u57fa\u4e09\u4e9a\u82ef\uff08HHTP, \u516d\u6c28\u57fa\u4e09\u4e9a\u82ef\uff08HATP\uff09\u7b49\u5e73\u9762\u5171\u8f6d\u914d\u4f53\u5df2\u88ab\u8bc1\u660e\u5b9e\u73b0\u8fd9\u7c7b\u6750\u6599\u9ad8\u7535\u5bfc\u7387\u3001\u9ad8\u8fc1\u79fb\u7387\u7684\u5173\u952e\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u5982\u4f55\u5b9e\u73b0\u5171\u8f6d\u914d\u4f4d\u805a\u5408\u7269\u7684\u80fd\u5e26\u5de5\u7a0b\uff0c\u5f97\u5230\u80fd\u5e26\u53ef\u8c03\u7684\u9ad8\u8fc1\u79fb\u7387\u534a\u5bfc\u4f53\u4ecd\u662f\u9886\u57df\u5185\u7684\u91cd\u8981\u6311\u6218\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u56fe1. Ag4<\/sub>TTHQ vs. Ag4<\/sub>TTBQ \u00a0\u00a9 2024 John Wiley & Sons.<\/p>\n

\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n

\u901a\u8fc7\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\u7684\u51af\u65b0\u4eae\u6559\u6388\u3001\u5c71\u4e1c\u5927\u5b66\u7684\u8463\u4eba\u8c6a\u6559\u6388\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u7684\u5f90\u4f1f\u7814\u7a76\u5458\u548c\u5357\u4eac\u5927\u5b66\u9ece\u5065\u6559\u6388\u7684\u8054\u5408\u7814\u7a76\uff0c\u8fd9\u4e00\u96be\u9898\u5b9e\u73b0\u4e86\u7a81\u7834\u3002\u4ed6\u4eec\u5f00\u53d1\u4e86\u57fa\u4e8e\u201c4+2\u201d\u82ef\u57fa\u914d\u4f53TTHQ\uff08\u56db\u5def\u57fa\u5bf9\u6c22\u918c\uff09\u548cTTBQ\uff08\u56db\u5def\u57fa\u5bf9\u82ef\u918c\uff09\u7684\u94f6\u57fa\u5171\u8f6d\u914d\u4f4d\u805a\u5408\u7269\uff0c\u547d\u540d\u4e3aAg4<\/sub>TTHQ\u548cAg4<\/sub>TTBQ\u3002\u8fd9\u7c7b\u6750\u6599\u5728\u6781\u9ad8\u7684\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\uff08>130 cm2<\/sup>\/V\u00b7s\uff09\u7684\u540c\u65f6\u8fd8\u5b9e\u73b0\u4e86\u80fd\u5230\u57280.5\u81f31.5 eV\u8303\u56f4\u5185\u7684\u8c03\u5236\u3002\u901a\u8fc7\u5206\u6790\u8fd9\u4e24\u79cd\u5177\u6709\u4e0d\u540c\u6c27\u5316\u72b6\u6001\u7684\u914d\u4f4d\u805a\u5408\u7269\u7684\u5355\u6676\u7ed3\u6784\uff0c\u6b64\u5de5\u4f5c\u6df1\u5165\u63ed\u793a\u4e86\u82ef\u918c\/\u6c22\u918c\u6c27\u5316\u72b6\u6001\u5bf9\u5171\u8f6d\u914d\u4f4d\u805a\u5408\u7269\u80fd\u5e26\u7ed3\u6784\u8c03\u63a7\u7684\u673a\u5236\u3002<\/p>\n

\u56fe\u6587\u7b80\u4ecb<\/strong><\/p>\n

\"\"<\/a><\/p>\n

\u56fe2. Ag4<\/sub>TTHQ\u548cAg4<\/sub>TBBQ\u7684\u5408\u6210\u65b9\u6cd5\u3001\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u3001\u7ea2\u5916\u53ca\u62c9\u66fc\u8868\u5f81 \u00a9 2024 John Wiley & Sons.<\/p>\n

\u5728\u5408\u6210\u65b9\u9762\uff0c\u4f7f\u7528\u785d\u9178\u94f6\u548cTTHQ\u5728\u6c2f\u82ef\/\u6c34\u754c\u9762\u53cd\u5e94\uff0c\u901a\u8fc7\u7f13\u6162\u7684\u6c27\u5316\u8fc7\u7a0b\uff0cTTHQ\u53ef\u88ab\u6c27\u5316\u4e3aTTBQ\uff0c\u6700\u7ec8\u5f62\u6210Ag4<\/sub>TTBQ\u3002\u800c\u5728\u65e0\u6c27\u73af\u5883\u4e0b\uff0c\u4f7f\u7528\u918b\u9178\u94f6\u548cTTHQ\u5728\u7532\u9187\u4e2d\u53cd\u5e94\u53ef\u76f4\u63a5\u5408\u6210Ag4<\/sub>TTHQ\u3002\u8fd9\u4e24\u79cd\u7ed3\u6784\u5c55\u793a\u4e86\u663e\u8457\u4e0d\u540c\u7684\u5149\u5b66\u5e26\u9699\uff0c\u63ed\u793a\u4e86\u5176\u7535\u5b50\u7ed3\u6784\u7684\u6f5c\u5728\u5dee\u5f02\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u56fe3. Ag4<\/sub>TTHQ\u548cAg4<\/sub>TTBQ\u7684\u5355\u6676\u7ed3\u6784\u5bf9\u6bd4 \u00a9 2024 John Wiley & Sons.<\/p>\n

\u5229\u7528\u65cb\u8f6c\u7535\u5b50\u884d\u5c04\u6280\u672f\u5bf9\u5355\u6676\u7ed3\u6784\u8fdb\u884c\u89e3\u6790\u53d1\u73b0Ag4<\/sub>TTHQ\u548cAg4<\/sub>TTBQ\u5177\u6709\u76f8\u4f3c\u7684\u7531Ag \u539f\u5b50\u5c42\u548c\u6709\u673a\u5c42\u6784\u5efa\u7684\u5c42\u72b6\u6742\u5408\u7ed3\u6784\u3002\u5355\u6676\u7ed3\u6784\u663e\u793a\u4e24\u8005\u5177\u6709\u540c\u6837\u7684\u62d3\u6251\u8fde\u63a5\u65b9\u5f0f\u548c\u76f8\u4f3c\u7684\u65e0\u673a\u5c42\u539f\u5b50\u6392\u5e03\uff0c\u4f46\u6709\u673a\u5c42\u4e2dC-O\u952e\u957f\u5ea6\u7684\u4e0d\u540c\u7ed3\u5408\u62c9\u66fc\u5149\u8c31\u4e2d\u78b3\u6c27\u53cc\u952e\u7279\u5f81\u5cf0\u7684\u5206\u6790\u63ed\u793a\u4e86Ag4<\/sub>TTHQ\u548cAg4<\/sub>TTBQ\u5206\u522b\u5177\u6709\u6c22\u918c\uff08HQ\uff09\u548c\u82ef\u918c\uff08BQ\uff09\u5355\u5143\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u56fe4. Ag4<\/sub>TTHQ(a) \u548cAg4<\/sub>TTBQ(b)\u7684\u80fd\u5e26\u7ed3\u6784\uff0c\u53ca\u7535\u5bfc\u585e\u8d1d\u514b\u7cfb\u6570\u5bf9\u6bd4 \u00a9 2024 John Wiley & Sons.<\/p>\n

\u57fa\u4e8eAg4<\/sub>TTBQ\u548cAg4<\/sub>TTHQ\u6676\u4f53\u7ed3\u6784\u7684\u80fd\u5e26\u7ed3\u6784\u8ba1\u7b97\u53ef\u77e5\uff0c\u82ef\u918c\/\u6c22\u918c\u5355\u5143\u5bf9\u4e8e\u80fd\u5e26\u7ed3\u6784\u7684\u53d8\u5316\u8d77\u51b3\u5b9a\u6027\u7684\u4f5c\u7528\u3002\u800c\u8fd9\u79cd\u7535\u5b50\u7ed3\u6784\u7684\u5dee\u5f02\u4e5f\u901a\u8fc7\u5bf9\u4e8e\u6750\u6599\u7535\u5bfc\u7387\u548c\u585e\u8d1d\u514b\u7cfb\u6570\u7684\u8868\u5f81\u4e2d\u5f97\u5230\u4e86\u8bc1\u5b9e\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u56fe5. Ag4<\/sub>TTHQ\u548cAg4<\/sub>TTBQ\u7684\u65f6\u95f4\u5206\u8fa8\u592a\u8d6b\u5179\u5149\u8c31\u8868\u5f81 \u00a9 2024 John Wiley & Sons.<\/p>\n

\u4f5c\u8005\u4e5f\u5229\u7528\u5229\u7528\u65f6\u95f4\u5206\u8fa8\u592a\u8d6b\u5179\u5149\u8c31\u7814\u7a76\u4e86 Ag4<\/sub>TTHQ \u548c Ag4<\/sub>TTBQ \u4e2d\u5149\u751f\u8f7d\u6d41\u5b50\u52a8\u529b\u5b66\u548c\u5fae\u89c2\u7535\u8377\u4f20\u8f93\u673a\u5236\u3002\u9996\u5148\uff0c\u8fd9\u4e24\u79cd\u6750\u6599\u7684\u9891\u7387\u5206\u8fa8\u590d\u5408\u5149\u7535\u5bfc\u7b26\u5408Drude-Smith\u4f20\u8f93\u6a21\u578b\u3002\u7ed3\u5408\u62df\u5408\u5206\u6790\u5f97\u5230Ag4<\/sub>TTHQ \u548c Ag4<\/sub>TTBQ\u7684\u76f4\u6d41\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u5206\u522b\u4e3a137\u00a0\u00b1 7\u00a0 cm2<\/sup>\/V\u00b7s\u548c130\u00a0\u00b1\u00a09 cm2<\/sup>\/V\u00b7s\u3002\u66f4\u4e3a\u91cd\u8981\u7684\u662f\uff0cAg4<\/sub>TTHQ \u548c Ag4<\/sub>TTBQ \u5c55\u73b0\u51fa\u622a\u7136\u4e0d\u540c\u7684\u5149\u751f\u8f7d\u6d41\u5b50\u52a8\u529b\u5b66\u3002\u5176\u4e2dAg4<\/sub>TTHQ \u663e\u793a\u51fa\u4e0e\u6cf5\u6ce8\u91cf\u65e0\u5173\u7684\u5149\u7535\u5bfc\u8870\u51cf\u7387\uff0c\u5149\u7535\u5bfc\u8870\u51cf\u7531\u7f3a\u9677\u8f85\u52a9\u590d\u5408\u673a\u5236\u4e3b\u5bfc\uff1b\u800c Ag4<\/sub>TTBQ \u5728\u6cf5\u6ce8\u91cf\u5347\u9ad8\u65f6\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u5149\u7535\u5bfc\u8870\u51cf\u7387\uff0c\u5149\u7535\u5bfc\u8870\u51cf\u53d7\u7f3a\u9677\u8f85\u52a9\u590d\u5408\u673a\u5236\u548c\u7535\u5b50-\u7a7a\u7a74\u91cd\u7ec4\u673a\u5236\u5171\u540c\u5f71\u54cd\u3002<\/p>\n

\u7ed3\u8bed<\/strong><\/p>\n

\u6b64\u7814\u7a76\u4e0d\u4ec5\u5c55\u73b0\u4e86\u5982\u4f55\u901a\u8fc7\u7ec6\u81f4\u7684\u7ed3\u6784\u8bbe\u8ba1\u548c\u6c27\u5316\u72b6\u6001\u63a7\u5236\u6765\u5b9e\u73b0\u914d\u4f4d\u805a\u5408\u7269\u534a\u5bfc\u4f53\u7684\u80fd\u5e26\u8c03\u8282\uff0c\u8fd8\u8bc1\u660e\u4e86\u8fd9\u4e9b\u65b0\u578b\u6750\u6599\u5728\u9ad8\u6027\u80fd\u5149\u7535\u5668\u4ef6\u548c\u7535\u5316\u5b66\u80fd\u91cf\u5b58\u50a8\u4e2d\u7684\u6f5c\u5728\u5e94\u7528\u4ef7\u503c\u3002\u9ec4\u5e78\u535a\u58eb\uff08\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\uff09\u3001\u674e\u6d0b\u535a\u58eb\uff08\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\uff09\u548c\u4ed8\u5e05\u535a\u58eb\uff08\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\uff09\u4e3a\u672c\u6587\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\u4f5c\u8005\u4ecb\u7ecd<\/strong><\/p>\n

\u9ec4\u5e78\u535a\u58eb\u957f\u671f\u81f4\u529b\u4e8e\u5171\u8f6d\u914d\u4f4d\u805a\u5408\u7269\u7535\u5b50\u5b66\u6750\u6599\u7684\u5f00\u53d1\u3001\u57fa\u4e8e\u914d\u4f4d\u805a\u5408\u7269\u7684\u524d\u6cbf\u7269\u6001\u63a2\u7d22\u548c\u5176\u5728\u80fd\u6e90\u9886\u57df\u7684\u5e94\u7528\u7814\u7a76\u3002\u8bbe\u8ba1\u5e76\u5f00\u53d1\u4e86\u8bf8\u5982\u57fa\u4e8e\u516d\u5def\u57fa\u82ef\uff08BHT\uff09\u7684Cux<\/sub>BHT(x=3\u30014\u3001 5.5)\u548cAgx<\/sub>BHT(x=3\u30015)\uff1b\u57fa\u4e8e\u201c4+2\u201d\u82ef\u57fa\u914d\u4f53\u7684Cu4<\/sub>DHTTB, Ag4<\/sub>TTBQ, Ag4<\/sub>TTHQ\u7b49\u591a\u79cd\u7ed3\u6784\u6027\u8d28\u5404\u5f02\u7684\u5171\u8f6d\u914d\u4f4d\u805a\u5408\u7269\u3002\u8fd9\u4e9b\u6750\u6599\u4e0d\u4ec5\u4ec5\u5177\u6709\u4f18\u5f02\u7684\u7535\u5bfc\u7387\u548c\u8fc1\u79fb\u7387\uff0c\u4e5f\u5305\u542b\u7740\u53d1\u73b0\u51dd\u805a\u6001\u65b0\u5947\u7269\u76f8\u7684\u53ef\u80fd\u6027\uff0c\u5982Cu3<\/sub>BHT \u662f\u9996\u4e2a\u57fa\u4e8e\u914d\u4f4d\u805a\u5408\u7269\u57fa\u8d85\u5bfc\u6750\u6599\u3002\u6b64\u7c7b\u5171\u8f6d\u914d\u4f4d\u805a\u5408\u7269\u5728\u517c\u5177\u7535\u78c1\u5b66\u6027\u8d28\u548c\u9ad8\u7a33\u5b9a\u6027\u7684\u540c\u65f6\uff0c\u4e5f\u5177\u5907\u4f20\u7edf\u914d\u4f4d\u805a\u5408\u7269\u6613\u5408\u6210\u3001\u5b54\u7ed3\u6784\u53ef\u63a7\u548c\u5177\u6709\u5f00\u653e\u7684\u6d3b\u6027\u4f4d\u70b9\u7b49\u7279\u70b9\uff0c\u53ef\u4ee5\u88ab\u7528\u6765\u6784\u5efa\u65b0\u578b\u591a\u529f\u80fd\u7535\u5b50\u5b66\u5668\u4ef6\uff0c\u5728\u7535\u50ac\u5316\u3001\u7535\u6781\u6750\u6599\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u7b49\u8bf8\u591a\u80fd\u6e90\u4fe1\u606f\u6750\u6599\u7814\u7a76\u4e2d\u4e5f\u6709\u7740\u91cd\u8981\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u672c\u6587\u4ee5\u201cControl of the Hydroquinone\/Benzoquinone Redox State in High-Mobility Semiconducting Conjugated Coordination Polymers\u201d\u53d1\u8868\u4e8eAngewandte Chemie International Edition<\/em>. https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202320091<\/p>\n","protected":false},"excerpt":{"rendered":"

\u80cc\u666f\u4ecb\u7ecd \u5171\u8f6d\u914d\u4f4d\u805a\u5408\u7269\uff08conjugated coordination polymers, c-CPs\uff09\u56e0\u5176\u4f18\u5f02\u7535\u5b66\u6027\u80fd\u3001\u53ef\u8bbe\u8ba1\u7684\u5206\u5b50\u7ed3\u6784\u3001\u53ef\u8c03\u63a7\u7684\u80fd\u7ea7\u4ee5\u53ca\u7535…<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-258624","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/258624"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=258624"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/258624\/revisions"}],"predecessor-version":[{"id":258630,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/258624\/revisions\/258630"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=258624"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=258624"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=258624"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}