{"id":258322,"date":"2024-03-10T06:29:28","date_gmt":"2024-03-09T22:29:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=258322"},"modified":"2024-03-09T21:30:00","modified_gmt":"2024-03-09T13:30:00","slug":"nature-catalysis%ef%bc%9a%e5%9c%a8%e5%ae%a4%e6%b8%a9%e5%85%89%e5%92%8c%e6%97%a0%e6%a0%bc%e6%b0%8f%e8%af%95%e5%89%82%e7%9a%84%e6%9d%a1%e4%bb%b6%e4%b8%8b%e4%bf%83%e8%bf%9b%e9%93%81%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=258322","title":{"rendered":"Nature Catalysis\uff1a\u5728\u5ba4\u6e29\u5149\u548c\u65e0\u683c\u6c0f\u8bd5\u5242\u7684\u6761\u4ef6\u4e0b\u4fc3\u8fdb\u94c1\u50ac\u5316\u82b3\u70c3C-H\u952e\u70ef\u57fa\u5316"},"content":{"rendered":"<p>\u4e00\u3001 \u3010\u79d1\u5b66\u80cc\u666f\u3011 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Ackermann\u7b49\u7814\u7a76\u8005\u5728<em>Nature Catalysis<\/em>\u53d1\u8868\u4e86\u9898\u4e3a\u201c<strong>Room temperature photo-promoted iron-catalysed arene C\u2013H alkenylation without Grignard reagents<\/strong>\u201d\u7684\u8bba\u6587\uff0c\u8be5\u9879\u7814\u7a76\u8bbe\u8ba1\u5b9e\u73b0\u4e86\u5728\u5ba4\u6e29\u4e0b\u901a\u8fc7\u5149\u8f85\u52a9\u4fc3\u8fdb\u94c1\u50ac\u5316\u82ef\u4e9a\u80fa\u7684C-H\u6d3b\u5316\u3002\u8be5\u53cd\u5e94\u4e0d\u9700\u8981\u683c\u6c0f\u8bd5\u5242\u7b49\u50ac\u5316\u5242\uff0c\u4ec5\u4f9d\u9760\u4e00\u79cd\u8010\u7a7a\u6c14\u4e14\u65e0\u6bd2\u7684\u9884\u50ac\u5316\u5242\u6765\u9a71\u52a8\u8be5\u8fc7\u7a0b\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u7684\u65b9\u6cd5\u5305\u94c1C-H\u6d3b\u5316\u590d\u5408\u7269\u7684\u5408\u6210\uff0c\u5206\u79bb\u548c\u6676\u4f53\u5b66\u8868\u5f81\u3002\u6838\u78c1\u5171\u632f(NMR)\u5149\u8c31\u7814\u7a76\u4e5f\u4fc3\u8fdb\u4e86\u52a8\u529b\u5b66\u5206\u6790\u548c\u53cd\u5e94\u8c31\u5206\u6790\uff0c\u4e3a\u94c1\u50ac\u5316\u7684\u78b3\u6c22\u6d3b\u5316\u673a\u5236\u63d0\u4f9b\u4e86\u6709\u4ef7\u503c\u7684\u89c1\u89e3\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full 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Springer Nature<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-258325\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/03\/3.png\" alt=\"\" width=\"710\" height=\"740\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/03\/3.png 710w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/03\/3-288x300.png 288w\" sizes=\"(max-width: 710px) 100vw, 710px\" \/><\/strong><\/p>\n<p><strong>\u56fe3 <\/strong>\u4e8c\u6c22\u5316\u94c1\u9884\u50ac\u5316\u5242\u7684\u5316\u5b66\u8ba1\u91cf\u53cd\u5e94 \u00a9 2024 Springer Nature<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-258326\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/03\/4.png\" alt=\"\" width=\"717\" height=\"717\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/03\/4.png 717w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/03\/4-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/03\/4-300x300.png 300w\" sizes=\"(max-width: 717px) 100vw, 717px\" \/><\/strong><\/p>\n<p><strong>\u56fe4 <\/strong>\u539f\u4f4dled\u6838\u78c1\u5171\u632f\u6ce2\u8c31\u5b9e\u9a8c \u00a9 2024 Springer Nature<\/p>\n<p>\u672c\u7814\u7a76\u91c7\u7528\u987a\u5f0f-[Fe(H)<sub>2<\/sub>(dppe)<sub>2<\/sub> (\u5176\u4e2ddppe\u4e3a1,2-\u4e8c(\u4e8c\u82ef\u57fa\u81a6)\u4e59\u70f7)\u4f5c\u4e3a\u5355\u7ec4\u5206\u9884\u50ac\u5316\u5242\uff0c\u5728\u73af\u5883\u53cd\u5e94\u6e29\u5ea6\u4e0b\uff0c\u5b9e\u73b0\u4e86\u84dd\u5149\u8f85\u52a9\u94c1\u50ac\u5316\u916e\u4e9a\u80faC-H\u7684\u6d3b\u5316\u3002\u8fd9\u79cd\u94c1\u50ac\u5316\u7684C\u2013H\u70ef\u57fa\u5316\u5177\u6709\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u539f\u5b50\u7ecf\u6d4e\u6027\u9ad8\u5e76\u4e14\u4e0d\u9700\u8981\u4f7f\u7528\u683c\u6c0f\u8bd5\u5242\u7b49\u663e\u8457\u7279\u5f81\u3002\u540c\u65f6\uff0c\u672c\u7814\u7a76\u901a\u8fc7\u6c18\u6807\u8bb0\u3001\u6709\u673a\u91d1\u5c5e\u4e2d\u95f4\u4f53\u7684\u5206\u79bb\u548c\u53d1\u5149\u4e8c\u6781\u7ba1\u6838\u78c1\u5171\u632f\u6ce2\u8c31\u7684\u8be6\u7ec6\u673a\u7406\u7814\u7a76\uff0c\u63ed\u793a\u4e86\u5149\u548cFe(0)\u914d\u5408\u7269\u5bf9C-H\u6c27\u5316\u52a0\u6210\u8fdb\u884cC-H\u6d3b\u5316\u7684\u4f5c\u7528\u3002<\/p>\n<p><strong>\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n<p>\u5f00\u53d1\u4e86\u4e00\u79cd\u5728\u6e29\u548c\u7684\u53ef\u89c1\u5149\u4e0b\u6761\u4ef6\u4e0b\u4fc3\u8fdb\u94c1\u50ac\u5316C-H\u6d3b\u5316\u7684\u65b9\u6cd5\uff0c\u5e76\u5bf9\u5176\u673a\u7406\u8fdb\u884c\u4e86\u63cf\u8ff0\u3002\u8be5\u53cd\u5e94\u662f\u5c11\u6570\u51e0\u4e2a\u9ad8\u5ea6\u53ef\u6301\u7eed\u7684\u94c1\u50ac\u5316\u78b3\u6c22\u6d3b\u5316\u7684\u65b9\u6cd5\u4e4b\u4e00\uff0c\u56e0\u4e3a\u6240\u4f7f\u7528\u7684\u9884\u50ac\u5316\u5242\u4ef7\u683c\u4f4e\u5ec9\uff0c\u6613\u4e8e\u5408\u6210\u548c\u8010\u7a7a\u6c14\uff0c\u52a0\u4e0a\u4e0d\u9700\u8981\u683c\u6c0f\u8bd5\u5242\uff0c\u5177\u6709\u9ad8\u5b98\u80fd\u56e2\u8010\u53d7\u6027\uff0c\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u548c\u5168\u539f\u5b50\u7ecf\u6d4e\u6027\u7b49\u4f18\u52bf\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u5bf9\u5149\u548c\u94c1\u5728\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u4f5c\u7528\u89e3\u8bfb\u548c\u76f8\u5173\u673a\u7406\u7684\u7406\u89e3\uff0c\u5c06\u6709\u52a9\u4e8e\u8fdb\u4e00\u6b65\u53d1\u5c55\u5149\u50ac\u5316\u4e0b\u53ef\u6301\u7eed\u7684\u94c1\u50ac\u5316\u78b3\u6c22\u6d3b\u5316\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1ahttps:\/\/www.nature.com\/articles\/s41929-023-01105-0<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001 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