{"id":258310,"date":"2024-03-02T06:50:30","date_gmt":"2024-03-01T22:50:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=258310"},"modified":"2024-03-01T15:55:49","modified_gmt":"2024-03-01T07:55:49","slug":"jacs%ef%bc%9a%e4%b8%80%e7%a7%8d%e6%96%b0%e5%9e%8b%e8%af%b1%e5%af%bc%e5%bc%80%e9%97%a8%e6%9c%ba%e5%88%b6%ef%bc%81%e6%9f%94%e6%80%a7%e8%8f%b1%e5%bd%a2%e9%85%8d%e4%bd%8d%e7%bd%91%e7%bb%9c%e4%b8%ad","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=258310","title":{"rendered":"JACS\uff1a\u4e00\u79cd\u65b0\u578b\u8bf1\u5bfc\u5f00\u95e8\u673a\u5236\uff01\u67d4\u6027\u83f1\u5f62\u914d\u4f4d\u7f51\u7edc\u4e2d\u4e59\u70f7\u8bf1\u5bfc\u7684\u5f00\u95e8\u673a\u5236"},"content":{"rendered":"

\u5bfc\u8bfb<\/p>\n

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\u6210\u679c\u63a0\u5f71<\/p>\n

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\"\"<\/p>\n

\u6838\u5fc3\u521b\u65b0\u70b9<\/p>\n

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\u56fe2.\uff08A\uff0cB\uff09\u5206\u522b\u4e3aX-dia-1-Ni\u7684LP\u548cNP\u76f8\u7684\u5b54\u7ed3\u6784\u7684\u56fe\u793a\u3002\u00a9 202<\/b><\/strong>4<\/b><\/strong>\u00a0JACS<\/b><\/strong><\/p>\n

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\"\"<\/p>\n

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\u5728\u4f4e\u538b\uff08<40.3 kPa\uff09\u4e0b\uff0cNP\u76f8\u5728263 K\u65f6\u5bf9C2<\/sub>H6<\/sub>\u5438\u9644\u65e0\u5b54\uff0c\u4f46\u572840.3 kPa\u65f6\u53d1\u751f\u5411LP\u76f8\u7684\u76f8\u53d8\u3002\u5438\u6536C2<\/sub>H6<\/sub>\u7136\u540e\u968f\u7740\u538b\u529b\u7684\u589e\u52a0\u7a81\u7136\u8df3\u8dc3\u5e76\u7a33\u5b9a\u5728\u7ea6100Kpa\u3002\u76f8\u53cd\uff0cNP\u76f8\u5728263 K\u4e0b\u5bf9C2<\/sub>H4<\/sub>\u5438\u9644\u662f\u591a\u5b54\u7684\uff0c\u4f46\u6ca1\u6709\u660e\u663e\u7684\u5f00\u95f8\u548c44.8 cm3<\/sup>g-1<\/sup>\u7684\u5438\u6536\u3002X-dia-1-Ni\u4fdd\u6301\u4e86\u5bf9C2<\/sub>H6<\/sub>\u7684\u4f18\u5148\u5438\u9644\u3002X-dia-1-Ni\u5728273 K\u4e0b\u7684C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>\u5438\u6536\u6bd4\u4e3a3.51\uff0c\u9ad8\u4e8e\u5f53\u524d\u57fa\u51c6C2<\/sub>H6<\/sub>\u9009\u62e9\u6027\u5438\u9644\u5242Fe2<\/sub>\uff08O2<\/sub>\uff09\uff08dobdc\uff09\u548cCu\uff08Qc\uff092<\/sub>\u5728273\u6216298 K\u4e0b\u7684\u5438\u6536\u6bd4\u3002\u5bf9\u4e8eX-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\uff0cC2<\/sub>H6<\/sub>\u548cC2<\/sub>H4<\/sub>\u8bf1\u5bfc\u7684\u5f00\u95f8\u538b\u529b\u589e\u52a0\uff0c\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u9608\u503c\u538b\u529b\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8Ni\/Co\u7684\u6bd4\u7387\u6765\u8c03\u8282\u3002\u964d\u4f4e\u76f8\u53d8\u6240\u9700\u7684\u80fd\u5792\u662f\u7528Co\u4ee3\u66ffNi\u7684\u52a8\u673a\u3002X-dia-1-Co\u548cX-dia-1-Ni0.32<\/sub>Co0.68<\/sub>\u90fd\u4e0d\u5438\u9644C2<\/sub>H6<\/sub>\u6216C2<\/sub>H4<\/sub>\uff0c\u5e76\u4e14\u5b83\u4eec\u5728263\u6216273 K\u4e0b\u6ca1\u6709\u8868\u73b0\u51fa\u95e8\u6253\u5f00\u3002\u5728263 K\u548c100 kPa\u4e0b\uff0c\u53d1\u73b0X-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\u5438\u9644\u7684C2<\/sub>H6<\/sub>\u7684\u91cf\u4e3a141.08 cm3<\/sup>g-1<\/sup>\uff0c\u800cC2<\/sub>H4<\/sub>\u5438\u6536\u91cf\u4ec5\u4e3a55.1 cm3<\/sup>g-1<\/sup>\u3002\u5f53\u6e29\u5ea6\u5347\u9ad8\u5230273 K\u65f6\uff0cX-dia 1-Ni0.89<\/sub>Co0.11<\/sub>\u5bf9C2<\/sub>H6<\/sub>\u7684\u5438\u6536\u662f\u5bf9C2<\/sub>H4<\/sub>\u7684\u5438\u6536\u7684\u5927\u7ea69.1\u500d\uff0c\u8868\u660e\u5bf9C2<\/sub>H6<\/sub>\u7684\u9ad8\u9009\u62e9\u6027\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0cX-dia-1-Ni\u5bf9C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\u548cC<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u5438\u9644\u4eb2\u548c\u529b<\/b><\/strong>\u3002\u5b9e\u9645\u5e94\u7528\u9700\u8981\u51fa\u8272\u7684\u5faa\u73af\u548c\u518d\u73b0\u6027\uff0c\u56e0\u6b64\u8fdb\u884c\u4e86\u591a\u6b21\u5438\u9644-\u89e3\u5438\u8bd5\u9a8c\uff0c\u8fd9\u4e9b\u6d4b\u8bd5\u8868\u660e\uff0cX-dia-1-Ni\u5728\u4e94\u4e2a\u5438\u9644-\u89e3\u5438\u5faa\u73af\u4e2d\u4fdd\u6301\u5176C2<\/sub>H6<\/sub>\u5438\u6536\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4.\uff08A\uff0cB\uff09\u5728263 K\u4e0b\u4e59\u70f7\u5438\u9644\u548c\u89e3\u5438\u540e\u6240\u9009\u56fe\u6848\u7684\u6bd4\u8f83\u3002X-dia-1-Ni\u5728\u52a0\u5165\u4e59\u70f7\u540e\u7ecf\u5386\u4e86\u4eceNP\u76f8\u5230LP\u76f8\u7684\u53ef\u9006\u8f6c\u53d8\u3002\uff08C\uff0cD\uff09\u5728263 K\u4e0b\u6536\u96c6\u7684\u539f\u4f4dPXRD\u56fe\u6848\uff0c\u8868\u660eC<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\u88ab\u6d3b\u5316\u76f8\u5438\u9644\uff0c\u4f46C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\u76f4\u5230\u53d1\u751f\u76f8\u53d8\u624d\u88ab\u5438\u9644\u3002\u00a9 202<\/b><\/strong>4<\/b><\/strong>\u00a0JACS<\/b><\/strong><\/p>\n

X-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\u5728273 K\u548c1 bar\u4e0b\u5177\u6709\u663e\u8457\u9ad8\u7684C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>\u5438\u6536\u6bd4\uff089.1\uff09\uff0c\u9ad8\u4e8eX-dia-1-Ni\uff083.51\uff09\u3002X-dia-1-Ni\u548cX-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\u57281bar\u4e0b\u5bf9\u4e8c\u5143C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>\uff081\/1\u62161\/9\uff0cv\/v\uff09\u6df7\u5408\u7269\u4e5f\u663e\u793a\u51fa\u975e\u5e38\u9ad8\u7684IAST\u9009\u62e9\u6027\u3002\u901a\u8fc7X-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\u5728C2<\/sub>H6<\/sub>\u4e0eC2<\/sub>H4<\/sub>\u7684\u4e0d\u540c\u6bd4\u7387\u4e0b\u7684IAST\u9884\u6d4b\u7684\u6df7\u5408\u6c14\u4f53\u7b49\u6e29\u7ebf\uff0c\u8868\u660eX-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\u662f\u4ee51\/9\u6bd4\u7387\u5206\u79bbC2<\/sub>H6<\/sub>\u4e0eC2<\/sub>H4<\/sub>\u7684\u5019\u9009\u7269\u3002\u5728263 K\u65f6\uff0cX-dia-1-Ni\u5438\u9644C2<\/sub>H6<\/sub>\uff0c\u5728\u5438\u9644\u5f00\u59cb\u65f6\u6ca1\u6709\u663e\u8457\u53d8\u5316\uff0c\u4e0e\u4f4e\u538b\u4e0b\u7684NP\u76f8\u4e00\u81f4\u3002\u968f\u538b\u529b\u7684\u589e\u52a0\uff0c\u57282\u03b8 = 5.76\u300110.31\u300117.34\u548c18.65\u00b0\u5904\u7684\u7279\u5f81NP\u884d\u5c04\u5cf0\u9010\u6e10\u6d88\u5931\uff0c\u800c\u57287.27\u00b0\u5904\u51fa\u73b0LP\u76f8\u7684\u7279\u5f81\u884d\u5c04\u5cf0\u3002\u5728\u8131\u9644\u8fc7\u7a0b\u4e2d\uff0cPXRD\u56fe\u6848\u6062\u590d\u5230NP\u76f8\u7684\u56fe\u6848\uff0c\u8868\u660eNP\u548cLP\u76f8\u4e4b\u95f4\u7684\u53ef\u9006\u8f6c\u53d8\u3002PXRD\u56fe\u8c31\u5728C2<\/sub>H4<\/sub>\u5438\u9644-\u89e3\u5438\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u4e0d\u53d8\uff0c\u4e0eNP\u76f8\u7684\u4fdd\u7559\u4e00\u81f4\u3002\u5728\u5438\u9644\u7684\u521d\u59cb\u9636\u6bb5\uff0cX-dia-1-Ni\u7684PXRD\u56fe\u8c31\u4e0eNP\u76f8\u7684\u8ba1\u7b97PXRD\u56fe\u8c31\u4e0d\u7cbe\u786e\u5339\u914d\u3002\u8fd9\u79cd\u5dee\u5f02\u53ef\u80fd\u662f\u7531\u8d77\u6e90\u4e8eNP\u9636\u6bb5\u7684\u77ac\u6001\u9636\u6bb5\u5f15\u8d77\u7684\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u4e59\u70f7\u53ef\u4ee5\u8bf1\u5bfcXdia-1-Ni\u4eceNP\u76f8\u5230LP\u76f8\u7684\u8f6c\u53d8\u3002\u6b64\u5916\uff0c\u8fd8\u5229\u7528\u539f\u4f4d\u53d8\u538bPXRD\u7814\u7a76\u4e86X-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\u7684\u76f8\u53d8\u8fc7\u7a0b\u3002X-dia-1<\/b><\/strong>–Ni<\/b><\/strong>0.89<\/b><\/sub><\/strong>Co<\/b><\/strong>0.11<\/b><\/sub><\/strong>\u5728\u4e59\u70f7\u5438\u9644\u8fc7\u7a0b\u4e2d\uff0c\u7531NP\u76f8\u8f6c\u53d8\u4e3aLP\u76f8\u3002\u76f8\u53cd\uff0c\u5728\u4e59\u70f7\u89e3\u5438\u8fc7\u7a0b\u4e2d\uff0cX-dia-1<\/b><\/strong>–Ni<\/b><\/strong>0.89<\/b><\/sub><\/strong>Co<\/b><\/strong>0.11<\/b><\/sub><\/strong>\u4eceLP\u76f8\u56de\u590d\u5230NP\u76f8\u3002\u5728C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\u7684\u6574\u4e2a\u5438\u9644\u548c\u89e3\u5438\u5faa\u73af\u4e2d\uff0cXdia-1-Ni<\/b><\/strong>0.89<\/b><\/sub><\/strong>Co<\/b><\/strong>0.11<\/b><\/sub><\/strong>\u59cb\u7ec8\u4fdd\u6301\u5728NP\u76f8\u4e2d\u3002\u8fd9\u4e00\u73b0\u8c61\u4e0e\u5176\u5bf9C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\u548cC<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u4e00\u81f4\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe5.\u5806\u53e0\u7684Pre-Opt\u548cPost-Opt\u56fe\u663e\u793a\u914d\u4f53\u7684\u73af\u65cb\u8f6c\uff0c\u8868\u660e\uff08A\uff09C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\u548c\uff08B\uff09C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\u4e0e\u9aa8\u67b6\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u3002\u901a\u8fc7\u4f7f\u7528CP2K\u83b7\u5f97\u7684X-dia-1-Ni-NP\u7684\u4f18\u5316\u6676\u80de\u7684\u6b63\u6295\u5f71c\u8f74\u89c6\u56fe\uff0c\u5176\u4e2d\uff08C\uff09C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\u548c\uff08D\uff09C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\u4f4d\u4e8e\u6750\u6599\u4e2d\u3002\u539f\u5b50\u989c\u8272\uff1aC\uff08MOF\uff09=\u7070\u8272\uff0cC\uff08C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\/C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\uff09=\u6a59<\/b><\/strong>\u8272<\/b><\/strong>\uff0cH =\u767d\u8272\uff0cN =\u84dd\u8272\uff0cO =\u7ea2\u8272\uff0cNi =\u6de1\u7d2b\u8272\u3002(E)X-dia-1-Ni-LP\u4e2d\u7684C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\u548c\uff08F\uff09C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\u7ed3\u5408\u4f4d\u70b9\uff0c\u5982\u4ece\u5206\u5b50\u6a21\u62df\u786e\u5b9a\u7684\u3002C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\/C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\u5206\u5b50\u548cX-dia-1-Ni\u663e\u793a\u4e3a\u5706\u73e0\u7b14\u6a21\u578b\uff08\u989c\u8272\u4ee3\u7801\uff1aN\uff0c\u84dd\u8272; Ni\uff0c\u7eff\u8272; O\uff0c\u7ea2\u8272; H\uff0c\u9ec4\u8272;\u548cC\uff0c\u7070\u8272\uff09\u3002\u56fe\u4e2d\u8ddd\u79bb\u7684\u5355\u4f4d\u662f\u5398\u7c73\u3002\u00a9 202<\/b><\/strong>4<\/b><\/strong>\u00a0JACS<\/b><\/strong><\/p>\n

\u56fe5A\u3001B\u663e\u793a\u4e86\u5806\u53e0\u7684\u9009\u62e9\u524d\u548c\u9009\u62e9\u540e\u56fe\uff0c\u5176\u663e\u793a\u914d\u4f53\u7684\u73af\u65cb\u8f6c\uff0c\u8868\u660e\u6c14\u4f53\u5206\u5b50\u548c\u9aa8\u67b6\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u3002\u4f3c\u4e4e\u6bcf\u4e2a\u5438\u9644\u7269\u53ea\u6709\u4e00\u4e2a\u5206\u5b50\u53ef\u4ee5\u5360\u636eNP\u76f8\u63d0\u4f9b\u7684\u7a7a\u95f4\u3002\u4e0e\u4f53\u79ef\u8f83\u5927\u7684C2<\/sub>H6<\/sub>\u76f8\u6bd4\uff0cC2<\/sub>H4<\/sub>\u7684D2<\/sub>h\u5bf9\u79f0\u6027\u5141\u8bb8\u66f4\u597d\u7684\u62df\u5408\uff0c\u8fd9\u610f\u5473\u7740\u5728\u4f4e\u538b\u4e0bNP\u76f8\u5bf9C2<\/sub>H4<\/sub>\u7684\u9009\u62e9\u6027\u8d85\u8fc7C2<\/sub>H6<\/sub>\u3002\u9884\u671fC2<\/sub>H6<\/sub>\u7684\u66f4\u597d\u7684\u5f62\u72b6\u62df\u5408\u5c06\u9a71\u52a8\u6784\u8c61\u8f6c\u53d8\uff0c\u4ece\u800c\u89e3\u91ca\u6444\u53d6\u6c34\u5e73\u7684\u7a81\u7136\u589e\u52a0\uff08\u5373\u5f00\u95e8\uff09\uff0c\u8fd9\u662f\u5b9e\u9a8c\u89c2\u5bdf\u5230\u7684\u3002LP\u76f8\u8868\u73b0\u51fa\u66f4\u6709\u5229\u7684\u76f8\u4e92\u4f5c\u7528\u548c\u66f4\u9ad8\u7684\u7ed3\u5408\u80fdC2<\/sub>H6<\/sub>\u6bd4C2<\/sub>H4<\/sub>\u3002\u8fd8\u8fdb\u884c\u4e86GCMC\u6a21\u62df\uff0c\u4ee5\u786e\u5b9a\u6c14\u4f53\u5206\u5b50\u7684\u7ed3\u5408\u4f4d\u70b9\u3002\u8ba1\u7b97\u7684C2<\/sub>H6<\/sub>\u4e0eX-dia-1-Ni-LP\u7ed3\u5408\u7684\u6784\u578b\u6d89\u53ca2.40\u548c3.61\u00a0\u00c5\u7684\u591a\u4e2aC-H\u00b7\u00b7\u00b7O\u952e\u5408\u8ddd\u79bb\u3002\u53e6\u4e00\u65b9\u9762\uff0cC2<\/sub>H4<\/sub>\u5f62\u6210\u4e86\u4e24\u4e2aC-H\u00b7\u00b7\u00b7O\u952e\uff0c\u5b83\u4eec\u4e4b\u95f4\u7684\u8ddd\u79bb\u5206\u522b\u4e3a3.75\u548c3.83 \u00c5\uff0c\u6bd4C2<\/sub>H6<\/sub>\u957f\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6.\uff08A\uff0cB\uff09\u5728263 K\u548c100 kPa\u4e0b\u6d4b\u91cf\u7684C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\/C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\u4e8c\u5143\u6df7\u5408\u7269\uff081\/1\u548c1\/9\uff09\u7684\u7a7f\u900f\u66f2\u7ebf\u3002(C)\u7528X-dia-1-Ni\u5728100\u548c263 K\u4e0b\u5bf9C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\/C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\uff081\/9\uff09\u6df7\u5408\u7269\u8fdb\u884c\u4e86\u5faa\u73af\u7a7f\u900f\u5206\u79bb\u5b9e\u9a8c\u3002(D)\u5728100 kPa\u548c263 K\u4e0b\uff0c\u7528X-dia-1-Ni<\/b><\/strong>0.89<\/b><\/sub><\/strong>Co<\/b><\/strong>0.11<\/b><\/sub><\/strong>\u5bf9C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\/C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>6<\/b><\/sub><\/strong>\uff081\/9\uff09\u6df7\u5408\u7269\u8fdb\u884c\u4e86\u5faa\u73af\u7a7f\u900f\u5206\u79bb\u5b9e\u9a8c\u3002\u00a9 202<\/b><\/strong>4<\/b><\/strong>\u00a0JACS<\/b><\/strong><\/p>\n

C2<\/sub>H4<\/sub>\u9996\u5148\u4f5c\u4e3a\u7eafC2<\/sub>H4<\/sub>\u6d17\u8131\uff0c\u800cC2<\/sub>H6<\/sub>\u968f\u540e\u6d17\u8131\u3002\u4e3a\u4e86\u6d4b\u8bd5X-dia-1-Ni\u7684\u53ef\u518d\u5faa\u73af\u6027\uff0c\u7528\u53cc\u7ec4\u5206\u6c14\u4f53\u6df7\u5408\u7269\u8fdb\u884c\u4e94\u4e2a\u5faa\u73af\u7684\u7a7f\u900f\u5b9e\u9a8c\u3002X-dia-1-Ni\u901a\u8fc7\u4e94\u6b21\u5faa\u73af\u7a81\u7834\u5b9e\u9a8c\u4fdd\u6301\u5176C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>\u5206\u79bb\u6027\u80fd\u3002<\/p>\n

\u6210\u679c\u542f\u793a<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4e24\u79cd\u67d4\u6027\u914d\u4f4d\u7f51\u7edc\uff0cX-dia-1-Ni\u548cX-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\uff0c\u53ef\u4ee5\u901a\u8fc7\u8c03\u8282\u6e29\u5ea6\u7684\u5f00\u95e8\u538b\u529b\u6765\u8868\u73b0\u51faC2<\/sub>H6<\/sub>\u4e0eC2<\/sub>H4<\/sub>\u5206\u79bb\u7684\u57fa\u51c6\u6027\u80fd\u3002\u8fd9\u79cd\u65b9\u6cd5\u4f7f\u4e59\u70ef\u7684\u5171\u5438\u9644\u6700\u5c0f\u5316\uff0c\u540c\u65f6\u4fdd\u6301\u9ad8\u7684C2<\/sub>H6<\/sub>\u5438\u6536\uff0c\u5bfc\u81f4\u53cd\u5411C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>\u5206\u79bb\u3002\u901a\u8fc7\u539f\u4f4d\u53d8\u538bXRD\u7814\u7a76\u548c\u7406\u8bba\u8ba1\u7b97\uff0c\u7814\u7a76\u4e86X-dia-1-Ni\u548cX-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\u5bf9C2<\/sub>H6<\/sub>\u8bc6\u522b\u7684\u5f00\u95e8\u673a\u7406\u3002\u91cd\u8981\u7684\u662f\uff0cX-dia-1-Ni0.89<\/sub>Co0.11<\/sub>\u7684LP\u76f8\uff08273 K\u548c100 kPa\uff09\u7684C2<\/sub>H6<\/sub>\u5438\u6536\u80fd\u529b\u88ab\u786e\u5b9a\u4e3a\u6bd4C2<\/sub>H4<\/sub>\u9ad89.1\u500d\uff0c\u8fdc\u8fdc\u4f18\u4e8e\u5148\u524d\u62a5\u9053\u7684\u5438\u9644\u5242\u3002\u4eceC2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>\u6df7\u5408\u7269\u751f\u4ea7\u9ad8\u7eaf\u5ea6C2<\/sub>H4<\/sub>\uff08\u7eaf\u5ea6\u226599.9%\uff09\uff0c\u5177\u6709\u4f4e\u80fd\u91cf\u8db3\u8ff9\u3002\u672c\u65b9\u6cd5\u91c7\u7528\u4eceNP\u76f8\u5207\u6362\u5230LP\u76f8\u7684\u67d4\u6027MOF\uff0c\u5e76\u4e14\u53ef\u4ee5\u8c03\u8282\u5b83\u4eec\u7684\u91d1\u5c5e\u542b\u91cf\u4ee5\u63d0\u9ad8\u7279\u5b9a\u6c14\u4f53\u6df7\u5408\u7269\u7684\u5206\u79bb\u6548\u7387\u3002\u603b\u7684\u6765\u8bf4\uff0c\u672c\u9879\u7814\u7a76\u8868\u660e\uff0c\u67d4\u6027MOFs\u53ef\u4ee5\u6709\u6548\u5730\u7528\u4e8eC2<\/sub>H4<\/sub>\u7684\u7eaf\u5316\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a<\/b><\/strong>J. Am. Chem. Soc.<\/i><\/em>\u00a02024, 146, 6, 4153\u20134161\u00a0Publication Date:February 1, 2024<\/p>\n

https:\/\/doi.org\/10.1021\/jacs.3c13117<\/u><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u5bfc\u8bfb \u4eceC2H4\u4e2d\u5206\u79bbC2H6\u662f\u5316\u5de5\u4e2d\u5fc5\u4e0d\u53ef\u5c11\u7684\u9ad8\u80fd\u8017\u8fc7\u7a0b\u3002\u4e3a\u4e86\u89e3\u51b3\u6b64\u95ee\u9898\uff0c\u7231\u5c14\u5170\u5229\u83ab\u745e\u514b\u5927\u5b66Michael J. Zaworotko\u56e2\u961f\u548c\u65e5\u672c\u4eac\u90fd\u5927\u5b66Susu…<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-258310","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/258310"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=258310"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/258310\/revisions"}],"predecessor-version":[{"id":258320,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/258310\/revisions\/258320"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=258310"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=258310"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=258310"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}