{"id":257990,"date":"2024-02-20T07:34:00","date_gmt":"2024-02-19T23:34:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=257990"},"modified":"2024-02-19T22:40:09","modified_gmt":"2024-02-19T14:40:09","slug":"%e6%97%a5%e6%9c%ac%e4%ba%ac%e9%83%bd%e5%a4%a7%e5%ad%a6angew-chem-int-ed-%e4%b8%80%e7%a7%8d%e4%b8%89%e7%bb%b4%e6%8b%93%e5%b1%95%e7%9a%84%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a2%af%e5%9e%8b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=257990","title":{"rendered":"\u65e5\u672c\u4eac\u90fd\u5927\u5b66Angew. Chem. Int. Ed.: \u4e00\u79cd\u4e09\u7ef4\u62d3\u5c55\u7684\u91d1\u5c5e\u6709\u673a\u68af\u578b\u5316\u5408\u7269\u53ca\u5176\u8d28\u5b50\u4f20\u5bfc"},"content":{"rendered":"<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-257992\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72471-2.png\" alt=\"\" width=\"973\" height=\"445\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72471-2.png 973w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72471-2-300x137.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72471-2-768x351.png 768w\" sizes=\"(max-width: 973px) 100vw, 973px\" \/><\/b><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><strong><b> \u7814\u7a76\u80cc\u666f\uff1a<\/b><\/strong><\/p>\n<p>\u8de8\u8d8a\u4e00\u7ef4\uff081D\uff09\u548c\u4e8c\u7ef4\/\u4e09\u7ef4\uff082D\/3D\uff09\u7535\u5b50\u7cfb\u7edf\u7684\u68af\u578b\u5316\u5408\u7269\u5f15\u8d77\u4e86\u5e7f\u6cdb\u5173\u6ce8\uff0c\u56e0\u4e3a\u5b83\u4eec\u7684\u7535\u5b50\u72b6\u6001\u548c\u7269\u7406\u6027\u8d28\u5f3a\u70c8\u5730\u4f9d\u8d56\u4e8e\u5176\u7ec4\u6210\u817f\u4e4b\u95f4\u7684\u7535\u5b50\u76f8\u5173\u6027\u3002\u4f8b\u5982\uff0c\u4f5c\u4e3a\u4ee3\u8868\u6027\u7684\u68af\u578b\u6750\u6599\u4f53\u7cfb\uff0c\u5bf9\u4e24\u817f\u548c\u4e09\u817f\u7684\u6c27\u5316\u94dc\u68af\u578b\u6750\u6599\u7684\u7814\u7a76\u8868\u660e\uff0c\u5176\u7535\u5b66\u548c\u78c1\u6027\uff0c\u5982\u8d85\u5bfc\u548c\u91cf\u5b50\u81ea\u65cb\u6001\u4e0e\u5176\u7ec4\u6210\u817f\u7684\u6570\u91cf\u76f8\u5173\u3002\u4e3a\u4e86\u5f7b\u5e95\u7406\u89e3\u8fd9\u7c7b\u6750\u6599\u72ec\u7279\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\uff0c\u79d1\u5b66\u5bb6\u5e0c\u671b\u5f97\u5230\u57fa\u4e8e\u68af\u578b\u4f53\u7cfb\u7684 2D\/3D \u6269\u5c55\u3002\u7136\u800c\uff0c\u7531\u4e8e\u9ad8\u6e29\u9ad8\u538b\u7b49\u6781\u7aef\u5408\u6210\u6761\u4ef6\uff0c\u57fa\u4e8e\u8fd9\u79cd\u4e24\u817f\u6216\u4e09\u817f\u7684\u68af\u578b\u7cfb\u7edf\u7684\u7ef4\u5ea6\u6269\u5c55\u662f\u5341\u5206\u56f0\u96be\u7684\u3002<\/p>\n<p>\u4e0e\u6c27\u5316\u7269\u4f53\u7cfb\u76f8\u6bd4\uff0c\u5229\u7528\u914d\u4f4d\u5316\u5b66\u7684\u81ea\u4e0b\u800c\u4e0a\u7ec4\u88c5\u662f\u5b9e\u73b0\u7ef4\u5ea6\u6269\u5c55\u7684\u53ef\u884c\u65b9\u6cd5\u3002\u914d\u4f4d\u7ec4\u88c5\u7684\u4f18\u70b9\u662f\u6709\u610f\u7684\u7ed3\u6784\u8bbe\u8ba1\uff0c\u4f8b\u59821D\u7eb3\u7c73\u7ebf\u30012D\u7eb3\u7c73\u7247\u3001\u548c 3D\u6846\u67b6\u3002\u5728\u914d\u4f4d\u5316\u5408\u7269\u4e2d\uff0c\u4e00\u7ef4\u5364\u7d20\u6865\u63a5\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\u94fe\uff08MX-chain\uff09\u5341\u5206\u6709\u8da3\uff0c\u56e0\u4e3a\u5176\u7535\u5b50\u72b6\u6001\u53ef\u4ee5\u901a\u8fc7\u91d1\u5c5e\u79bb\u5b50\u3001\u5364\u7d20\u79bb\u5b50\u3001\u6709\u673a\u914d\u4f53\u548c\u6297\u8861\u9634\u79bb\u5b50\u7b49\u7ed3\u6784\u6210\u5206\u5b9e\u73b0\u8c03\u63a7\u3002\u6700\u8fd1\uff0c\u5c06MX-chain\u901a\u8fc7\u6709\u673a\u914d\u4f53\u7684\u8fde\u63a5\uff0c\u83b7\u5f97\u4e86\u591a\u79cd\u7ef4\u5ea6\u62d3\u5c55\u7684\u91d1\u5c5e\u6709\u673a\u68af\u578b\u5316\u5408\u7269\uff08MX-ladder\uff09\uff1b\u5305\u62ec\u4e24\u817f\u68af\u3001\u56db\u817f\u68af\/\u7ba1\u3001\u548c 2D \u62d3\u5c55\u7684\u4e24\u817f\u68af\u3002\u5728\u8fd9\u4e9b MX-ladder\u5316\u5408\u7269\u4e2d\uff0c\u89c2\u5bdf\u5230\u72ec\u7279\u7684\u7535\u5b50\u6001\u3001\u5438\u9644\u7279\u6027\u548c\u9ad8\u8d28\u5b50\u7535\u5bfc\u7387\u3002\u7136\u800c\uff0c\u8fdb\u4e00\u6b65\u76843D\u6269\u5c55MX-ladder\u4f53\u7cfb\u5c1a\u672a\u5b9e\u73b0\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u6210\u679c\u4ecb\u7ecd\uff1a<\/b><\/strong><\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u57fa\u4e8eMX-chain\u7684\u7ef4\u5ea6\u62d3\u5c55\uff0c\u4eac\u90fd\u5927\u5b66\u5317\u5ddd\u5b8f\uff08Hiroshi\u00a0Kitagawa\uff09\u6559\u6388\u8bfe\u9898\u7ec4\u8bbe\u8ba1\u5e76\u6210\u529f\u5236\u5907\u4e86\u591a\u79cd\u68af\u578b\u5316\u5408\u7269\uff0c\u5982\u4e24\u817fMX-ladder\uff08<em><i>Inorg. Chem.<\/i><\/em>\u00a02014, 53, 1229\uff1b<em><i>J. Am. Chem. Soc<\/i><\/em>. 2006, 128, 12066\uff09\uff0c\u56db\u817fMX-ladder\/tube\uff08<em><i>J. Am. Chem. Soc.<\/i><\/em>\u00a02023, 145, 9454\uff1b\u00a0<em><i>Nat. Commun.<\/i><\/em>\u00a02020, 11, 843\uff1b<em><i>Nat. Mater<\/i><\/em>. 2011, 10, 291\uff09\u4ee5\u53ca2D\u62d3\u5c55\u7684\u4e24\u817fMX-ladder\uff08<em><i>Angew. Chem. Int. Ed.<\/i><\/em>\u00a02017, 56, 3838\uff09\u3002\u6b64\u6b21\uff0c\u8be5\u8bfe\u9898\u7ec4\u6210\u529f\u6784\u7b51\u4e86\u4e00\u79cd3D \u62d3\u5c55\u7684\u4e24\u817fMX-ladder\u5316\u5408\u7269\uff0c\u00a0[Pt(en)(dpye)I]<sub>2<\/sub>(NO<sub>3<\/sub>)<sub>4<\/sub>\u00b72H<sub>2<\/sub>O\uff08en = ethylenediamine\uff1bdpye = 1,2-Di(4-pyridyl)ethane\uff09 (\u5316\u5408\u7269<strong><b>1<\/b><\/strong>)\u3002\u5355\u6676 X \u5c04\u7ebf\u884d\u5c04\u7814\u7a76\u8bc1\u5b9e\u4e86\u72ec\u7279\u7684 3D \u6269\u5c55\u6676\u683c\u662f\u7531 1D \u6df7\u5408\u4ef7\u5364\u7d20\u6865\u63a5\u91d1\u5c5e\u94fe (\u00b7\u00b7\u00b7Pt\u2013I\u2013Pt\u2013I\u00b7\u00b7\u00b7) \u548c\u87ba\u65cb\u6392\u5217\u7684\u73af\u578b\u914d\u5408\u7269\u5355\u5143\u4f5c\u4e3a\u817f\u548c\u68af\u7ea7\u7ec4\u6210\u3002X\u5c04\u7ebf\u6f2b\u6563\u5c04\u5206\u6790\u548c\u5149\u5b66\u6d4b\u8bd5\u63ed\u793a\u4e86\u8be5\u68af\u578b\u5316\u5408\u7269\u5185\u7684\u5f02\u76f8 Pt<sup>2+<\/sup>\/Pt<sup>4+<\/sup>\u00a0\u6df7\u5408\u4ef7\u6392\u5217\uff08\u5f02\u76f8\u7535\u8377\u5bc6\u5ea6\u6ce2\uff1aout-of-phase CDW\uff09\uff0c\u8fd9\u662f\u7531\u4e8e\u76f8\u90bb\u817f\u4e4b\u95f4\u7684\u94fe\u95f4\u76f8\u5173\u6027\u8f83\u5f31\u3002\u8fd9\u79cd\u72ec\u7279\u76843D\u62d3\u5c55\u7ed3\u6784\u662f\u901a\u8fc7\u4f7f\u7528\u5143\u7d20 I<sub>2<\/sub>\u00a0\u5bf9\u5c0f\u5c3a\u5bf8\u7684\u53cc\u6838Pt\u57fa\u73af\u578b\u914d\u5408\u7269\u8fdb\u884c\u7b80\u5355\u7684\u6c27\u5316\u805a\u5408\u800c\u610f\u5916\u5730\u83b7\u5f97\uff0c\u8fd9\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u4e24\u817f\u68af\u578b\u4f53\u7cfb\u660e\u663e\u4e0d\u540c\uff0c\u539f\u56e0\u53ef\u80fd\u662f\u5c0f\u7684\u73af\u578b\u914d\u5408\u7269\u5355\u5143\u5177\u6709\u8f83\u5927\u7684\u7a7a\u95f4\u4f4d\u963b\u3002\u7531\u4e8e\u5316\u5408\u7269<strong><b>1<\/b><\/strong>\u7684\u5b54\u9699\u4e2d\u5177\u6709\u4e30\u5bcc\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u4f5c\u8005\u7814\u7a76\u4e86\u5176\u8d28\u5b50\u4f20\u5bfc\u7279\u6027\u3002\u963b\u6297\u6d4b\u8bd5\u8868\u660e\uff0c\u8be5\u5316\u5408\u7269\u7684\u8d28\u5b50\u4f20\u5bfc\u7387\u53ef\u968f\u7740\u6e7f\u5ea6\u7684\u589e\u52a0\u800c\u63d0\u9ad81000 \u500d\u3002\u76f8\u5e94\u5730\uff0c\u5176\u8d28\u5b50\u4f20\u5bfc\u8def\u5f84\u4e5f\u901a\u8fc7\u5355\u6676X \u5c04\u7ebf\u884d\u5c04\u5f97\u5230\u4e86\u7814\u7a76\u3002\u6b64\u5916\uff0c\u4eceMOFs\u7684\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u5316\u5408\u7269<strong><b>1<\/b><\/strong>\u4e5f\u662f\u4e00\u79cd\u5341\u5206\u7f55\u89c1\u7684\u5177\u67093D\u6269\u5c55\u6846\u67b6\u7ed3\u6784\u7684\u5355\u91d1\u5c5ePt\u57faMOF\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cA Three-Dimensionally Extended Metal\u2013Organic Ladder Compound Exhibiting Proton Conduction\u201d\u4e3a\u9898\u53d1\u8868\u5728<em><i>An<\/i><\/em><em><i>gew. Chem. Int. Ed.<\/i><\/em>\u4e0a\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p><strong><b>\u56fe\u6587\u89e3\u6790\uff1a<\/b><\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-257993\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72472-2.png\" alt=\"\" width=\"732\" height=\"664\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72472-2.png 732w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72472-2-300x272.png 300w\" sizes=\"(max-width: 732px) 100vw, 732px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>\u00a01<\/b><\/strong><strong><b>\uff1a<\/b><\/strong>\u4e24\u817fMX-ladder\uff0c\u00a02D\u62d3\u5c55\u548c 3D\u62d3\u5c55\uff08\u672c\u7814\u7a76\uff09\u7684\u8bbe\u8ba1\u53ca\u7ed3\u6784\u8bf4\u660e\u3002<\/p>\n<p>\u8bbe\u8ba1\u4e24\u817fMX-ladder\u5316\u5408\u7269\u7684\u7b56\u7565\u5982\u56fe1\u6240\u793a\u3002\u901a\u5e38\uff0c\u53cc\u6838\u91d1\u5c5e\u6709\u673a\u914d\u5408\u7269\u5728\u5364\u7d20\u7684\u6c27\u5316\u805a\u5408\u4f5c\u7528\u4e0b\u5bf9\u51c6\u6392\u5217\u5f62\u6210\u68af\u5b50\u7ed3\u6784\uff08\u56fe1\u5de6\u4e0b\uff09\u3002\u4f46\u67d0\u4e9b\u60c5\u51b5\u4e0b\uff0c\u53cc\u6838\u91d1\u5c5e\u6709\u673a\u914d\u5408\u7269\u65e0\u6cd5\u5bf9\u51c6\u6392\u5217\u800c\u5f62\u62102D\u62d3\u5c55\u7ed3\u6784\uff08\u56fe1\u53f3\u4e0a\uff09\uff0c\u5373\u4e00\u6761\u68af\u5b50\u817f\uff08MX-chain\uff09\u88ab\u4e24\u4e2a\u4e24\u817f\u68af\u800c\u5171\u6709\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u9996\u6b21\u5b9e\u73b0\u4e863D\u62d3\u5c55\u7ed3\u6784\uff08\u56fe1\u53f3\u4e0b\uff09\u3002\u5728\u8fd9\u4e2a\u7ed3\u6784\u4e2d\uff0c\u4e00\u6761\u68af\u5b50\u817f\uff08MX-chain\uff09\u88ab\u56db\u4e2a\u4e24\u817f\u68af\u800c\u5171\u6709\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-257994\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72473-2.png\" alt=\"\" width=\"1057\" height=\"1008\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72473-2.png 1057w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72473-2-300x286.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72473-2-768x732.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72473-2-1024x977.png 1024w\" sizes=\"(max-width: 1057px) 100vw, 1057px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>\u00a02<\/b><\/strong><strong><b>\uff1a<\/b><\/strong>\u5316\u5408\u7269<strong><b>1<\/b><\/strong>\u7684\u6676\u4f53\u7ed3\u6784\u3002(a) <strong><b>1<\/b><\/strong>\u7684\u53cc\u6838Pt\u73af\u7ed3\u6784\u5355\u5143\u7684\u5316\u5b66\u7ed3\u6784\u3002(b) \u4e24\u79cd\u5bf9\u6620\u4f53\uff08<em><i>P<\/i><\/em>4<sub>1<\/sub>2<sub>1<\/sub>2 \u548c <em><i>P<\/i><\/em>4<sub>3<\/sub>2<sub>1<\/sub>2 \u5f62\u5f0f\uff09\u7684\u6bd4\u8f83\u3002 (c)<strong><b>\u00a01<\/b><\/strong>\u7684\u771f\u5b9e3D\u62d3\u5c55\u7ed3\u6784\uff08<em><i>P<\/i><\/em>4<sub>3<\/sub>2<sub>1<\/sub>2 \u7a7a\u95f4\u7fa4\uff09\u3002 (d) <strong><b>1<\/b><\/strong>\u76843D\u62d3\u5c55\u7ed3\u6784\u793a\u610f\u56fe\uff08<em><i>P<\/i><\/em>4<sub>3<\/sub>2<sub>1<\/sub>2 \u7a7a\u95f4\u7fa4\uff09\u3002\u4e3a\u4e86\u6e05\u695a\u8d77\u89c1\uff0c\u7701\u7565\u4e86H<sub>2<\/sub>O \u548c NO<sub>3<\/sub><sup>\u2013<\/sup>\u3002<\/p>\n<p>\u6309\u7167\u81ea\u4e0b\u800c\u4e0a\u7684\u7ec4\u88c5\u53cc\u817fMX-ladder\u5316\u5408\u7269\u7684\u7b56\u7565\uff0c\u6211\u4eec\u4f7f\u7528\u4e00\u79cd\u5c0f\u7684Pt \u73af\u5f62\u914d\u5408\u7269 [Pt(en)(dpye)]<sub>2<\/sub>(NO<sub>3<\/sub>)<sub>4<\/sub>\u00b74H<sub>2<\/sub>O \u6765\u6784\u5efa\u65b0\u7684 MX-ladder\u5316\u5408\u7269\uff08 \u56fe 2a\uff09\u3002 \u5728\u5ba4\u6e29\u4e0b\uff0c\u901a\u8fc7\u5c06 I<sub>2<\/sub>\u84b8\u6c14\u7f13\u6162\u6269\u6563\u5230 Pt\u73af\u5f62\u914d\u5408\u7269\u7684\u6c34\/\u7532\u9187 (1:1) \u6df7\u5408\u7269\u4e2d\uff0c\u6210\u529f\u83b7\u5f97\u4e86<strong><b>1<\/b><\/strong>\u7684\u5355\u6676\u3002 <strong><b>1<\/b><\/strong>\u7684\u6676\u4f53\u7ed3\u6784\u901a\u8fc7\u5355\u6676X\u5c04\u7ebf\u884d\u5c04(SCXRD)\u6d4b\u5b9a\u3002<strong><b>1<\/b><\/strong>\u75311D MX-chain\u00a0(\u00b7\u00b7\u00b7Pt\u2013I\u2013Pt\u2013I\u00b7\u00b7\u00b7)\u548c\u73af\u5f62\u914d\u5408\u7269\u5355\u5143\u7ec4\u6210\uff0c\u5e76\u4e14\u7531\u4e8e\u81ea\u53d1\u62c6\u5206\uff0c\u5728<em><i>P<\/i><\/em>4<sub>3<\/sub>2<sub>1<\/sub>2\u6216<em><i>P<\/i><\/em>4<sub>1<\/sub>2<sub>1<\/sub>2\u7a7a\u95f4\u7fa4\u4e2d\u7ed3\u6676\uff08\u56fe\u00a02b\uff09\u3002\u4ee5\u00a0<strong><b>1<\/b><\/strong>\u7684\u00a0<em><i>P<\/i><\/em>4<sub>3<\/sub>2<sub>1<\/sub>2\u5f62\u5f0f\u4e3a\u4f8b\uff0c\u73af\u5f62\u914d\u5408\u7269\u5355\u5143\u6cbf<em><i>c<\/i><\/em>\u8f74\u5448\u73b0\u56db\u91cd\u5de6\u624b\u87ba\u65cb\u7684\u5468\u671f\u6027\u6392\u5217\uff0c\u5e76\u4e14\u73af\u5355\u5143\u7684\u4e24\u4e2a Pt \u4f4d\u70b9\u901a\u8fc7I<sup>\u2212<\/sup>\u76f8\u4e92\u6865\u63a5\u5f62\u6210 MX-chain\uff0c\u4ece\u800c\u5f62\u6210 3D \u62d3\u5c55\u7684\u4e24\u8db3\u68af\u578b\u7ed3\u6784\u3002\u4ece\u53e6\u4e00\u4e2a\u89d2\u5ea6\u6765\u770b\uff0c\u6676\u4f53\u4e2d\u6240\u6709\u76841D MX-chain\u90fd\u6cbf\u7740<em><i>c<\/i><\/em>\u8f74\u4f20\u64ad\uff0c\u5e76\u901a\u8fc7 <em><i>a-b<\/i><\/em>\u00a0\u5e73\u9762\u4e2d\u7684\u73af\u5f62\u914d\u5408\u7269\u5355\u5143\u76f8\u4e92\u8fde\u63a5\uff08\u56fe 2c \u548c 2d\uff09\u3002\u5173\u6ce8\u4e8e\u5176\u7ec4\u6210\u817fMX-chain\u90e8\u5206\uff0c\u6865\u63a5 I<sup>\u2212<\/sup>\u5728\u76f8\u90bbPt\u79bb\u5b50\u4e4b\u95f4\u7684\u4e2d\u70b9\u4f4d\u7f6e\u5448\u65e0\u5e8f\u6392\u5217\uff08\u4e24\u4fa7\u5360\u6709\u7387\u540450%\uff09\uff0c\u8868\u660e\u4e00\u4e2aMX-chain\u5185\u7684\u7535\u5b50\u72b6\u6001\u5904\u4e8e\u00a0Pt<sup>2+<\/sup>\/Pt<sup>4+<\/sup>\u00a0\u6df7\u5408\u4ef7\u6001\uff08\u5373\u7535\u8377\u5bc6\u5ea6\u6ce2CDW\uff1a\u00b7\u00b7\u00b7Pt<sup>2+<\/sup>\u00b7\u00b7\u00b7I\u2013Pt<sup>4+<\/sup>\u2013I\u00b7\u00b7\u00b7\uff09\u3002 \u6cbfMX-chain\u7684Pt-Pt\u8ddd\u79bb\u4e3a5.925(1) \u00c5\uff0c\u6bd4\u4e4b\u524d\u62a5\u9053\u7684MX\u5316\u5408\u7269\u66f4\u957f\u3002\u6b64\u5916\uff0c\u6297\u8861\u9634\u79bb\u5b50\uff08NO<sub>3<\/sub><sup>\u2212<\/sup>\uff09\u548c\u7ed3\u6676H<sub>2<\/sub>O\u5206\u5b50\u901a\u8fc7\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u5b58\u5728\u4e8e\u9633\u79bb\u5b503D\u6846\u67b6\u7684\u5b54\u9699\u4e2d\u3002\u8fd9\u4e2a3D \u62d3\u5c55\u7684\u4e24\u8db3\u68af\u578b\u7ed3\u6784\u51fa\u4e4e\u610f\u6599\u5730\u7531\u5c0f\u7684\u00a0Pt\u73af\u578b\u914d\u5408\u7269\u805a\u5408\u800c\u5f97\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u805a\u5408\u8fc7\u7a0b\u4e2d\u73af\u5355\u5143\u4e4b\u95f4\u5b58\u5728\u8f83\u5927\u7684\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\u3002\u901a\u8fc7\u6539\u53d8\u6709\u673a\u914d\u4f53\u7684\u5c3a\u5bf8\u548c\u4f53\u79ef\uff0c\u9884\u671f\u53ef\u4ee5\u5b9e\u73b0\u5404\u79cd\u5177\u6709\u4e0d\u540c\u5b54\u5f84\u7684\u8fdb\u4e00\u6b653D\u5ef6\u4f38\u7ed3\u6784\u3002\u8fd9\u79cd\u60c5\u51b5\u4e5f\u53cd\u6620\u5728\u4e00\u6761MX-chain\u5185\u76f8\u5bf9\u8f83\u957f\u7684 Pt-Pt \u8ddd\u79bb\u4e0a\uff0c\u5982\u4e0a\u6240\u8ff0\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-257995\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72474-3.png\" alt=\"\" width=\"723\" height=\"739\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72474-3.png 723w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72474-3-294x300.png 294w\" sizes=\"(max-width: 723px) 100vw, 723px\" \/>\u00a0<\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong><strong><b>\uff1a<\/b><\/strong>\u5316\u5408\u7269<strong><b>1<\/b><\/strong>\u7684\u7535\u5b50\u7ed3\u6784\u3002(a) (<em><i>hhl<\/i><\/em>)\u6676\u9762\u7684X\u5c04\u7ebf\u6563\u5c04\u5f3a\u5ea6\u56fe\u3002 \u9664\u4e86\u5e03\u62c9\u683c\u53cd\u5c04\u4e4b\u5916\uff0c\u5728 <em><i>l<\/i><\/em>\u00a0= 6\u300110 \u548c 14 \u5904\u8fd8\u89c2\u5bdf\u5230\u6e05\u6670\u7684\u6f2b\u53cd\u5c04\u6761\u7eb9\u3002(b) (<em><i>hk<\/i><\/em><u>10<\/u>) \u6676\u9762\u4e0a\u7684\u5f3a\u5ea6\u56fe\u3002 \u53f3\u4fa7\u663e\u793a\u4e86\u6700\u8fd1\u90bb\u94fe\u4e4b\u95f4 8% \u8d1f\u76f8\u5173\u7684\u7ed3\u6784\u7684\u6a21\u62df\u6f2b\u53cd\u5c04\u5f3a\u5ea6\u5206\u5e03\u3002 (c) <strong><b>1<\/b><\/strong>\u4e2d\u7684\u4ef7\u6001\u6392\u5217\u793a\u610f\u56fe\uff0c\u5176\u4e2d Pt<sup>2+<\/sup>\u00a0\u548c Pt<sup>4+<\/sup>\u00a0\u5206\u522b\u7528\u7ea2\u8272\u5927\u7403\u548c\u7eff\u8272\u7403\u4f53\u8868\u793a\u3002 (d) \u6cbf\u7740\u56fe 3b\u4e2d\u865a\u7ebf\u7684\u5f3a\u5ea6\u5206\u5e03\u4ee5\u53ca\u8ba1\u7b97\u7684\u5f3a\u5ea6\u5206\u5e03\uff08\u7ea2\u7ebf\uff09\u3002 -2\u3001-1 \u548c 0 \u5904\u7684\u9ad8\u5f3a\u5ea6\u5cf0\u6e90\u81ea\u5e03\u62c9\u683c\u53cd\u5c04\u800c\u4e0d\u662fX \u5c04\u7ebf\u6f2b\u6563\u5c04\u3002<\/p>\n<p>\u5728<strong><b>1<\/b><\/strong>\u7684\u6f2b\u53cd\u5c04\u5149\u8c31\u4e2d\u548c\u62c9\u66fc\u5149\u8c31\u4e2d\uff0c\u5747\u89c2\u6d4b\u5230\u4e86\u4e0e\u4ef7\u95f4\u7535\u8377\u8f6c\u79fb\u8dc3\u8fc1(IVCT\uff0cMX-chain\u5185\u4ecePt<sup>2+<\/sup>\u5230\u76f8\u90bbPt<sup>4+<\/sup>)\u76f8\u5173\u7684\u4fe1\u53f7\u3002\u8fd9\u6e05\u695a\u5730\u8868\u660e <strong><b>1 <\/b><\/strong>\u7684\u7535\u5b50\u6001\u662f Pt<sup>2+<\/sup>\/Pt<sup>4+<\/sup>\u00a0CDW \u6001\uff0c\u5982\u7ed3\u6784\u5206\u6790\u4e2d\u6240\u793a\u3002 \u56e0\u6b64\uff0c<strong><b>1<\/b><\/strong>\u5bf9\u5e94\u4e8e Robin\u2013Day \u5206\u7c7b\u7684\u00a0II \u7c7b\u6df7\u5408\u4ef7\u5316\u5408\u7269\u3002\u7136\u800c\uff0c\u7531\u4e8e\u6676\u4f53\u7ed3\u6784\u4e2dI<sup>\u2212<\/sup>\u4e3a\u65e0\u5e8f\u72b6\u6001\uff0c\u901a\u8fc7\u5149\u5b66\u6d4b\u8bd5\u548c\u7ed3\u6784\u5206\u6790\u65e0\u6cd5\u786e\u5b9a\u94fe\u95f4\u7684\u4ef7\u6001\u6392\u5e03\u65b9\u5f0f\u3002<\/p>\n<p>\u7531\u4e8e<strong><b>1<\/b><\/strong>\u5177\u6709\u72ec\u7279\u7684 3D \u6269\u5c55\u4e24\u8db3\u68af\u578b\u7ed3\u6784\u548c\u65e0\u9650MX-chain\u7ec4\u6210\u817f\uff0c\u56e0\u6b64\u6211\u4eec\u4f7f\u7528X \u5c04\u7ebf\u6f2b\u6563\u5c04\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u94fe\u95f4\u7535\u5b50\u76f8\u5173\u6027\uff08\u56fe 3a\uff09\u3002\u4e00\u65b9\u9762\uff0c\u5bf9\u70b9\u578b\u53cd\u5c04\u7684\u89c2\u5bdf\u8868\u660e\u6676\u4f53\u5185\u7684\u957f\u7a0b\u6709\u5e8f\u3002\u53e6\u4e00\u65b9\u9762\uff0cPt-I \u8ddd\u79bb\u7531\u76f8\u90bb Pt \u79bb\u5b50\u7684\u4ef7\u6001\u51b3\u5b9a\uff1b\u56e0\u6b64\uff0cI<sup>\u2212<\/sup>\u7684\u4f4d\u79fb\u53ef\u4ee5\u901a\u8fc7X\u5c04\u7ebf\u6563\u5c04\u63ed\u793aCDW\u72b6\u6001\u3002\u6b63\u5982\u9884\u671f\u7684\u90a3\u6837\uff0c\u89c2\u5bdf\u5230\u4e86\u6709\u9650\u7ebf\u5bbd\u7684\u6f2b\u6563\u5c04\uff0c\u8fd9\u8868\u660e\u5b58\u5728\u77ed\u7a0b\u6709\u5e8f\u3002 \u4ece(<em><i>hhl<\/i><\/em>)\u5e73\u9762\u4e0a\u7684X\u5c04\u7ebf\u6563\u5c04\u5f3a\u5ea6\u56fe\u4e2d\uff0c\u5728<em><i>l<\/i><\/em>=4n+2(n\uff1a\u6574\u6570)\u4f4d\u7f6e\u5904\u89c2\u5bdf\u5230\u6e05\u6670\u7684\u6f2b\u6563\u5c04\u6761\u7eb9\u3002\u00a0(<em><i>hk<\/i><\/em><u>10<\/u>) \u5e73\u9762\u4e0a\u7684\u5f3a\u5ea6\u56fe\u5982\u56fe 3b \u6240\u793a\u3002\u5728<em><i>h<\/i><\/em>+<em><i>k<\/i><\/em>\u4e3a\u5947\u6570\u7684\u4f4d\u7f6e\u5468\u56f4\u53d1\u73b0\u4e86\u5f88\u5f3a\u7684\u6f2b\u6563\u5c04\u5f3a\u5ea6\u3002\u56fe 3d \u663e\u793a\u4e86\u6cbf\u7740\u56fe 3b \u6240\u793a\u7684\u7ebf\u7684\u6f2b\u53cd\u5c04\u5f3a\u5ea6\u7684\u7ebf\u8f6e\u5ed3\uff0c\u4ee5\u53ca\u8ba1\u7b97\u7684\u6f2b\u53cd\u5c04\u8f6e\u5ed3\uff0c\u7ed3\u679c\u663e\u793a\u7b2c\u4e00\u76f8\u90bb\u94fe\u4e4b\u95f4\u5b58\u5728 8% \u7684\u8d1f\u76f8\u5173\u6027\u3002\u8fd9\u79cd\u5f3a\u5ea6\u6ce2\u52a8\u8868\u660e\u76f8\u90bb\u94fe\u4e4b\u95f4\u7684CDW\u76f8\u4f4d\u5448\u8d1f\u76f8\u5173\uff0c\u5e76\u4e14\u76f8\u5173\u6027\u4ec5\u9650\u4e8e\u77ed\u7a0b\u3002\u56e0\u6b64\uff0c\u5f31\u7684\u94fe\u95f4\u76f8\u4e92\u4f5c\u7528\u5bfc\u81f4 3D \u9636\u68af\u5185\u7684\u5f02\u76f8Pt<sup>2+<\/sup>\/Pt<sup>4+<\/sup>\u4ef7\u6001\u6392\u5217\uff08out-of-phase CDW\uff09\uff08\u56fe 3c\uff09\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-257997\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72475-1.png\" alt=\"\" width=\"695\" height=\"568\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72475-1.png 695w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/\u56fe\u72475-1-300x245.png 300w\" sizes=\"(max-width: 695px) 100vw, 695px\" \/>\u00a0<\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4<\/b><\/strong><strong><b>\uff1a<\/b><\/strong>30% \u548c 95% \u76f8\u5bf9\u6e7f\u5ea6\u6761\u4ef6\u4e0b<strong><b>1<\/b><\/strong>\u00a0\u7684\u8d28\u5b50\u7535\u5bfc\u7387\u7684\u963f\u4f26\u5c3c\u4e4c\u65af\u56fe\u8c31\u3002<b><\/b><\/p>\n<p>\u7531\u4e8e\u7ed3\u6676H<sub>2<\/sub>O\u5206\u5b50\u4e0e\u00a0NO<sub>3<\/sub><sup>&#8211;<\/sup>\u76f8\u4e92\u4f5c\u7528\u5f62\u6210\u6c22\u952e\u7f51\u7edc\uff0c\u9884\u8ba1<strong><b>1<\/b><\/strong>\u4f1a\u53d1\u751f\u6709\u6548\u7684\u8d28\u5b50\u4f20\u5bfc\u3002\u901a\u8fc7\u4ea4\u6d41 (AC) \u963b\u6297\u6d4b\u91cf\u6765\u68c0\u67e5<strong><b>1<\/b><\/strong>\u7684\u8d28\u5b50\u4f20\u5bfc\u7387\u3002\u8fd8\u8bc1\u5b9e\u4e86\u5176\u76f4\u6d41\u7535\u5bfc\u7387\u5c0f\u4e8e\u6d4b\u91cf\u4e0b\u9650\uff0c\u8fd9\u8868\u660e\u53ef\u4ee5\u6392\u9664\u7535\u5b50\u4f20\u5bfc\u7684\u8d21\u732e\u3002\u7531\u4e8e\u8d28\u5b50\u7535\u5bfc\u7387\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u6e7f\u5ea6\uff08\u4ece30%\u5230\u00a095% \u76f8\u5bf9\u6e7f\u5ea6\uff08RH\uff09\uff0c\u8d28\u5b50\u7535\u5bfc\u7387\u589e\u52a0\u7ea61000\u500d\uff09\uff0c\u56e0\u6b64\u7814\u7a76\u4e86\u00a0<strong><b>1<\/b><\/strong>\u00a0\u7684 H<sub>2<\/sub>O \u84b8\u6c14\u5438\u9644\u7b49\u6e29\u7ebf\u3002\u7ed3\u679c\uff0c\u5728\u9ad8\u6e7f\u5ea6\u4e0b\u89c2\u5bdf\u5230 H<sub>2<\/sub>O\u5206\u5b50\u7684\u9ad8\u5438\u6536\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u8d28\u5b50\u4f20\u5bfc\u673a\u5236\u53ef\u5206\u4e3a\u4e24\u7c7b\uff1aGrotthuss\u673a\u5236\uff08\u8d28\u5b50\u901a\u8fc7\u6c22\u952e\u6269\u6563\uff09\u548cVehicle\u673a\u5236\uff08\u79fb\u52a8\u8f7d\u6d41\u5b50\u76f4\u63a5\u6269\u6563\uff09\u3002 \u6839\u636e\u8d28\u5b50\u7535\u5bfc\u7387\u7684\u963f\u4f26\u5c3c\u4e4c\u65af\u56fe\uff0c\u572830%\u548c95%RH\u6761\u4ef6\u4e0b\uff0c<strong><b>1<\/b><\/strong>\u7684\u6d3b\u5316\u80fd (<em><i>E<\/i><\/em><sub>a<\/sub>) \u4f30\u8ba1\u5206\u522b\u4e3a0.39 eV\u548c0.64 eV\uff08\u56fe 4\uff09\u3002 \u56e0\u6b64\uff0c<strong><b>1<\/b><\/strong>\u7684\u8d28\u5b50\u4f20\u5bfc\u673a\u5236\u63a5\u8fd1\u4e8eGrotthuss\u578b\uff0c\u5176\u4e2d\u8d28\u5b50\u4f20\u8f93\u4e3b\u8981\u662f\u901a\u8fc7\u6676\u4f53\u5185NO<sub>3<\/sub><sup>\u2212<\/sup>\u3001H<sub>2<\/sub>O\u548cen\u914d\u4f53\u4e4b\u95f4\u7684\u6c22\u952e\u6765\u4e3b\u5bfc\u3002<\/p>\n<p>\u4e3a\u4e86\u8be6\u7ec6\u9610\u660e\u8d28\u5b50\u4f20\u5bfc\u8def\u5f84\uff0c\u5728\u00a030% \u548c 95% RH \u6761\u4ef6\u4e0b\u5bf9<strong><b>1<\/b><\/strong>\u8fdb\u884c SCXRD\u6d4b\u5b9a\u3002\u5728\u8fd9\u4e24\u79cd\u6761\u4ef6\uff0c<strong><b>1<\/b><\/strong>\u7684\u7ed3\u6784\u4e0e\u5236\u5907\u5f97\u5230\u7684\u76f8\u4f3c\uff0c\u4f46\u6574\u4f53\u6c22\u952e\u7f51\u7edc\u5b58\u5728\u5dee\u5f02\u3002\u6839\u636e<strong><b>1<\/b><\/strong>\u572830%\u548c95%RH\u6761\u4ef6\u4e0b\u7684\u4ea4\u6d41\u963b\u6297\u6d4b\u91cf\u548c\u7ed3\u6784\u5206\u6790\u7684\u7ed3\u679c\uff0c\u8d28\u5b50\u7535\u5bfc\u7387\u589e\u52a0\u4e09\u4e2a\u6570\u91cf\u7ea7\u53ef\u4ee5\u89e3\u91ca\u5982\u4e0b\uff1a\u572830%RH\u4e0b\uff0cO14\u548cO16\u4e4b\u95f4\u6ca1\u6709\u660e\u663e\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u8d28\u5b50\u4e0d\u6613\u6269\u6563\u3002\u5f53\u76f8\u5bf9\u6e7f\u5ea6\u589e\u52a0\u523095%\u65f6\uff0c<strong><b>1<\/b><\/strong>\u5bb9\u7eb3\u66f4\u591a\u7684H<sub>2<\/sub>O\u5206\u5b50\uff0c\u4ece\u800c\u5f62\u6210O14\u00b7\u00b7\u00b7O16\u548cO14\u00b7\u00b7\u00b7O17\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u66f4\u5bb9\u6613\u8fdb\u884c\u8d28\u5b50\u4f20\u8f93\u3002\u6b64\u5916\uff0c\u989d\u5916\u7684\u5b64\u7acbH<sub>2<\/sub>O\uff08O18\uff09\u4e5f\u53ef\u80fd\u901a\u8fc7Vehicle\u6a21\u5f0f\u6709\u52a9\u4e8e\u8d28\u5b50\u7535\u5bfc\u7387\u7684\u589e\u52a0\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p><strong><b>\u7ed3\u8bba\u4e0e\u5c55\u671b\uff1a<\/b><\/strong><\/p>\n<p>\u4f5c\u8005\u5408\u6210\u4e86\u7b2c\u4e00\u4e2a\u00a03D \u62d3\u5c55\u4e24\u817f\u91d1\u5c5e\u6709\u673a\u68af\u578b\u5316\u5408\u7269\u7684\u4f8b\u5b50\u3002\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u63ed\u793a\u4e86\u72ec\u7279\u76843D\u62d3\u5c55\u4e24\u817f\u68af\u578b\u7ed3\u6784\uff0c\u75311D\u6df7\u5408\u4ef7\u5364\u7d20\u6865\u63a5\u91d1\u5c5e\u94fe\uff08\u00b7\u00b7\u00b7Pt\u2013I\u2013Pt\u2013I\u00b7\u00b7\u00b7\uff09\u548c\u87ba\u65cb\u6392\u5217\u7684Pt\u73af\u5355\u5143\u7ec4\u6210\u4f5c\u4e3a\u7ec4\u6210\u817f\u548c\u68af\u7ea7\uff0c\u8fd9\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u4e24\u817f\u68af\u578b\u4f53\u7cfb\u4e0d\u540c\u3002X \u5c04\u7ebf\u6f2b\u6563\u5c04\u5206\u6790\u548c\u5149\u5b66\u6d4b\u91cf\u8bc1\u5b9e\u4e86\u68af\u5185\u7684\u5f02\u76f8 Pt<sup>2+<\/sup>\/Pt<sup>4+<\/sup>\u00a0\u6392\u5217\u3002 \u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u8868\u5f81\u4e86\u8fd9\u79cd\u68af\u578b\u5316\u5408\u7269\u7684\u8d28\u5b50\u7535\u5bfc\u7387\u53ef\u968f\u6e7f\u5ea6\u7684\u589e\u52a0\u800c\u63d0\u9ad81000 \u500d\u3002\u4eceMOFs\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u5177\u67092D\/3D\u6269\u5c55\u6846\u67b6\u7684\u5355\u91d1\u5c5ePt\u57faMOF\u4ecd\u7136\u5f88\u5c11\u89c1\u3002\u8fd9\u9879\u7814\u7a76\u7684\u53d1\u73b0\u5c06\u6709\u52a9\u4e8e\u68af\u578b\u6750\u6599\u4f53\u7cfb\u7684\u7cfb\u7edf\u6027\u7ef4\u5ea6\u62d3\u5c55\u8bbe\u8ba1\uff0c\u6709\u671b\u83b7\u5f97\u72ec\u7279\u7684\u7ed3\u6784\uff0c\u5b9e\u73b0\u72ec\u7279\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\uff0c\u6bd4\u5982\u7535\u5316\u5b66\u5e94\u7528\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1002\/anie.202400162<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; \u7814\u7a76\u80cc\u666f\uff1a \u8de8\u8d8a\u4e00\u7ef4\uff081D\uff09\u548c\u4e8c\u7ef4\/\u4e09\u7ef4\uff082D\/3D\uff09\u7535\u5b50\u7cfb\u7edf\u7684\u68af\u578b\u5316\u5408\u7269\u5f15\u8d77\u4e86\u5e7f\u6cdb\u5173\u6ce8\uff0c\u56e0\u4e3a\u5b83\u4eec\u7684\u7535\u5b50\u72b6\u6001\u548c\u7269\u7406\u6027\u8d28\u5f3a\u70c8\u5730\u4f9d\u8d56\u4e8e\u5176\u7ec4\u6210\u817f\u4e4b\u95f4\u7684\u7535&#8230;<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-257990","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/257990"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=257990"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/257990\/revisions"}],"predecessor-version":[{"id":257998,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/257990\/revisions\/257998"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=257990"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=257990"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=257990"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}