{"id":257743,"date":"2024-02-06T06:01:21","date_gmt":"2024-02-05T22:01:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=257743"},"modified":"2024-02-05T21:06:55","modified_gmt":"2024-02-05T13:06:55","slug":"%e8%8e%b1%e6%96%af-%e6%b8%85%e5%8d%8e-%e7%a7%91%e5%b0%94%e4%b8%87%e5%a4%a7%e5%ad%a6%e5%90%88%e4%bd%9cadv-mater-%ef%bc%9a%e5%8a%a8%e5%8a%9b%e5%ad%a6%e6%8e%a7%e5%88%b6%e5%90%88%e6%88%90%e9%87%91","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=257743","title":{"rendered":"\u83b1\u65af\/\u6e05\u534e\/\u79d1\u5c14\u4e07\u5927\u5b66\u5408\u4f5cAdv. Mater.\uff1a\u52a8\u529b\u5b66\u63a7\u5236\u5408\u6210\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u9093\u5175\uff0c\u738b\u54f2<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u9093\u5175\uff0c\u8d75\u7389\u5cf0\uff0cJames M. Tour<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u6e05\u534e\u5927\u5b66\uff0c\u79d1\u5c14\u4e07\u5927\u5b66\uff0c\u83b1\u65af\u5927\u5b66<\/p>\n<p>\u8bba\u6587\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.202309956<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-257747\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/1-7.png\" alt=\"\" width=\"554\" height=\"216\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/1-7.png 554w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/1-7-300x117.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p>\u3010\u7814\u7a76\u80cc\u666f\u3011<\/p>\n<p>\u91d1\u5c5e\u73bb\u7483\u662f\u4e00\u7c7b\u5177\u6709\u65e0\u5b9a\u5f62\u539f\u5b50\u7ed3\u6784\u7684\u56fa\u4f53\u91d1\u5c5e\u6750\u6599\u3002\u6839\u636e\u73bb\u7483\u5f62\u6210\u80fd\u529b\u7684\u5dee\u522b\uff0c\u91d1\u5c5e\u73bb\u7483\u8868\u73b0\u51fa\u8bb8\u591a\u7ef4\u5ea6\u5f62\u5f0f\u3002\u4f8b\u5982\uff0c\u901a\u8fc7\u5408\u91d1\u7194\u878d\u7684\u5feb\u901f\u6dec\u706b\u5236\u5907\u7684\u91d1\u5c5e\u73bb\u7483\u5e26\u72b6\u6750\u6599\uff0c\u901a\u8fc7\u7269\u7406\u6c14\u76f8\u6c89\u79ef\u5236\u5907\u7684\u91d1\u5c5e\u73bb\u7483\u8584\u819c\uff0c\u4ee5\u53ca\u901a\u8fc7\u94f8\u9020\u5f97\u5230\u7684\u5757\u4f53\u91d1\u5c5e\u73bb\u7483\u3002\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u7ed3\u6784\u56e0\u5176\u72ec\u7279\u7684\u539f\u5b50\u7ed3\u6784\u548c\u7269\u7406\u5316\u5b66\u6027\u8d28\u5f15\u8d77\u4e86\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5728\u589e\u6750\u5236\u9020\u3001\u7eb3\u7c73\u538b\u5370\u3001\u73af\u5883\u548c\u80fd\u6e90\u50ac\u5316\u9886\u57df\u4e2d\u5177\u6709\u91cd\u8981\u7684\u6f5c\u5728\u5e94\u7528\u3002\u76ee\u524d\u7684\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u7ed3\u6784\u7684\u81ea\u4e0a\u800c\u4e0b\u5236\u5907\u5305\u62ec\u70ed\u5851\u6027\u6210\u5f62\u3001\u70ed\u62c9\u4f38\u6280\u672f\u3001\u9009\u62e9\u6027\u8150\u8680\u548c\u6fc0\u5149\u70e7\u8680\u7b49\u3002\u7136\u800c\uff0c\u81ea\u4e0a\u800c\u4e0b\u7684\u65b9\u6cd5\u4f9d\u8d56\u4e8e\u5757\u4f53\u91d1\u5c5e\u73bb\u7483\u7684\u53ef\u5f97\u6027\uff0c\u8fd9\u6781\u5927\u9650\u5236\u4e86\u91d1\u5c5e\u73bb\u7483\u6750\u6599\u548c\u7ec4\u6210\u7684\u9009\u62e9\u8303\u56f4\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u81ea\u4e0b\u800c\u4e0a\u7684\u7eb3\u7c73\u91d1\u5c5e\u73bb\u7483\u7684\u5408\u6210\uff0c\u5982\u5316\u5b66\u8fd8\u539f\u3001\u7535\u5316\u5b66\u5408\u6210\u7b49\u53ef\u5b9e\u73b0\u66f4\u597d\u7684\u5c3a\u5bf8\u3001\u5f62\u6001\u548c\u7ec4\u6210\u53ef\u8c03\u6027\u3002\u7136\u800c\uff0c\u57fa\u4e8e\u6e7f\u5316\u5b66\u7684\u8fc7\u7a0b\u901a\u5e38\u5bfc\u81f4\u7531\u8868\u9762\u6d3b\u6027\u5242\u5f15\u8d77\u7684\u6c61\u67d3\u3002\u56e0\u6b64\uff0c\u4e9f\u5f85\u53d1\u5c55\u53d1\u5c55\u4e00\u79cd\u81ea\u4e0b\u800c\u4e0a\u7684\u65b9\u6cd5\u6765\u5408\u6210\u5177\u6709\u53ef\u8c03\u7ec4\u6210\u3001\u5c0f\u5c3a\u5bf8\u548c\u826f\u597d\u5f62\u6001\u7684\u7eb3\u7c73\u5c3a\u5bf8\u91d1\u5c5e\u73bb\u7483\u3002<\/p>\n<p>\u3010\u5185\u5bb9\u7b80\u4ecb\u3011<\/p>\n<p>\u5728\u6b64\u80cc\u666f\u4e0b\uff0c<strong>\u83b1\u65af\u5927\u5b66<\/strong><strong>James Tour<\/strong><strong>\u3001\u6e05\u534e\u5927\u5b66\u9093\u5175\u548c\u79d1\u5c14\u4e07\u5927\u5b66\u8d75\u7389\u5cf0<\/strong>\u5408\u4f5c\u5f00\u53d1\u4e86\u4e00\u79cd\u95ea\u5149\u78b3\u70ed\u53cd\u5e94\uff08Flash Carbothermic Reaction\uff09\u65b9\u6cd5\u5b9e\u73b0\u4e86Pd\u57fa\u548cPt\u57fa\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u901a\u7528\u5236\u5907\u3002\u9996\u5148\u5728\u78b3\u57fa\u5e95\u4e0a\u8d1f\u8f7d\u91d1\u5c5e\u524d\u4f53\uff0c\u901a\u8fc7\u91c7\u7528\u6beb\u79d2\u7ea7\u7535\u6d41\u8109\u51b2\uff0c\u901a\u8fc7\u7126\u8033\u52a0\u70ed\u8fc5\u901f\u5c06\u6e29\u5ea6\u5347\u81f3\u7ea61800 K\uff08\u5347\u6e29\u901f\u7387&gt;10<sup>5<\/sup> K s<sup>-1<\/sup>\uff09\uff0c\u5f62\u6210\u5408\u91d1\u7194\u4f53\uff0c\u968f\u540e\u901a\u8fc7\u70ed\u8f90\u5c04\u8d85\u5feb\u51b7\u5374\uff08\u964d\u6e29\u901f\u7387&gt;10<sup>4<\/sup> K s<sup>-1<\/sup>\uff09\u73bb\u7483\u5316\u6210\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u3002\u8be5\u65b9\u6cd5\u53ef\u5b9e\u73b0\u5408\u6210Pd\u548cPt\u57fa\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u901a\u7528\u5408\u6210\uff0c\u5305\u62ecPdNiP\u3001PdCuP\u3001PdCuNiP\u3001PtCuP\u3001PtCuNiP\u4ee5\u53ca\u9ad8\u71b5PtPdCuNiP\u3002\u8fdb\u4e00\u6b65\u7684\uff0c\u901a\u8fc7\u7ec4\u5408\u5b9e\u9a8c\u7814\u7a76\u6784\u5efa\u4e86PdNiP\u7eb3\u7c73\u9897\u7c92\u7684\u76f8\u56fe\uff0c\u5e76\u53d1\u73b0\u7eb3\u7c73\u5c3a\u5ea6\u4e0b\u7684\u91d1\u5c5e\u73bb\u7483\u7684\u7ec4\u5206\u7a7a\u95f4\u76f8\u6bd4\u5757\u4f53\u91d1\u5c5e\u73bb\u7483\u5927\u5927\u6269\u5c55\uff0c\u8fd9\u610f\u5473\u7740\u7eb3\u7c73\u5c3a\u5bf8\u6548\u5e94\u589e\u5f3a\u4e86\u5176\u73bb\u7483\u5f62\u6210\u80fd\u529b\u3002\u7ed3\u6784\u6a21\u62df\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86\u7eb3\u7c73\u5c3a\u5ea6\u548c\u5757\u4f53\u91d1\u5c5e\u73bb\u7483\u4e4b\u95f4\u77ed\u7a0b\u5e8f\u5dee\u5f02\u3002\u8fd9\u79cd\u201c\u7eb3\u7c73\u5c3a\u5bf8\u589e\u5f3a\u73bb\u7483\u5f62\u6210\u80fd\u529b\u201d\u6548\u5e94\u4f7f\u5f97\u4e00\u4e9b\u4ece\u672a\u5728\u5757\u4f53\u4e2d\u5b9e\u73b0\u7684\u91d1\u5c5e\u73bb\u7483\u7ec4\u5206\u5f97\u4ee5\u5728\u7eb3\u7c73\u5c3a\u5ea6\u5408\u6210\uff0c\u4f8b\u5982PdCoP\u3001PdSnP\u548c\u9ad8\u71b5PdCuFeNiP\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u5c55\u793a\u4e86\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u5728\u5f02\u8d28\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n<p>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n<p>\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u5408\u6210\u5305\u62ec\u4e09\u4e2a\u6b65\u9aa4\uff08<strong>\u56fe<\/strong><strong>1<\/strong>\uff09\u3002\u9996\u5148\uff0c\u91d1\u5c5e\u524d\u4f53\u6eb6\u89e3\u5728\u4e59\u9187\u4e2d\uff0c\u5e76\u6d78\u6e0d\u5230\u78b3\u9ed1\u4e0a\uff0c\u78b3\u9ed1\u65e2\u5145\u5f53\u5bfc\u7535\u6dfb\u52a0\u5242\u53c8\u4f5c\u4e3a\u652f\u6491\u57fa\u5e95\u3002\u5176\u6b21\uff0c\u8109\u51b2\u76f4\u6d41\u8f93\u5165\u8fc5\u901f\u63d0\u9ad8\u4e86\u6837\u54c1\u7684\u6e29\u5ea6\uff0c\u5bfc\u81f4\u91d1\u5c5e\u76d0\u524d\u4f53\u5feb\u901f\u5206\u89e3\u5f62\u6210\u5408\u91d1\u7194\u4f53\u3002\u6700\u540e\uff0c\u7531\u4e8e\u78b3\u57fa\u5e95\u7684\u5f3a\u70c8\u70ed\u8f90\u5c04\u548c\u4f4e\u70ed\u5bb9\u91cf\uff0c\u6837\u54c1\u8fc5\u901f\u51b7\u5374\uff0c\u5bfc\u81f4\u5408\u91d1\u7194\u4f53\u73bb\u7483\u5316\u6210\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u3002\u7531\u4e8e\u4e09\u5143\u94af-\u954d-\u78f7\uff08PdNiP\uff09\u5177\u6709\u826f\u597d\u7684\u73bb\u7483\u5316\u80fd\u529b\uff0c\u56e0\u6b64\u9009\u62e9\u5176\u8fdb\u884c\u521d\u59cb\u8bd5\u9a8c\u300290 A\u3001\u6301\u7eed\u65f6\u95f450 ms\u7684\u8109\u51b2\u7535\u6d41\u5c06\u6837\u54c1\u6e29\u5ea6\u8fc5\u901f\u4e0a\u5347\u5230\u7ea61760 K\u3002\u6839\u636e\u6700\u5927\u6e29\u5ea6\u548cPdNiP\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff08Tg\uff0c\u7ea6600 K\uff09\uff0c\u53ef\u8ba1\u7b97\u51fa\u51b7\u5374\u901f\u7387\u7ea6\u4e3a1.5 \u00d7 10<sup>4<\/sup> K s<sup>-1<\/sup>\u3002\u6839\u636e\u6e29\u5ea6-\u65f6\u95f4-\u8f6c\u53d8\u56fe\uff0c\u51b7\u5374\u901f\u7387\u51b3\u5b9a\u4e86\u73bb\u7483\u6001\u6216\u6676\u4f53\u76f8\u7684\u5f62\u6210\u3002\u5728\u95ea\u5149\u78b3\u70ed\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u5feb\u901f\u51b7\u5374\u5bfc\u81f4\u4e86\u73bb\u7483\u76f8\u7684\u5f62\u6210\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-257748\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/2-8.png\" alt=\"\" width=\"800\" height=\"465\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/2-8.png 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/2-8-300x174.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/2-8-768x446.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1. <\/strong><strong>\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u5408\u6210\u3002<\/strong><\/p>\n<p>\u968f\u540e\uff0c\u4f5c\u8005\u91c7\u7528\u4e86\u591a\u79cd\u624b\u6bb5\u5bf9\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u8fdb\u884c\u4e86\u8868\u5f81\uff0c\u4ee5\u8bc1\u660e\u5176\u65e0\u5b9a\u5f62\u539f\u5b50\u7ed3\u6784\uff08<strong>\u56fe<\/strong><strong>2<\/strong>\uff09\u3002XRD\u663e\u793a\u5176\u9664\u4e86\u5728~40\u00b0\u9644\u8fd1\u5b58\u5728\u4e00\u4e2a\u5bbd\u5cf0\u5916\uff0c\u6ca1\u6709\u5176\u4ed6\u7684\u7ed3\u6676\u884d\u5c04\u5cf0\u3002\u9ad8\u5206\u8fa8\u7535\u5b50\u663e\u5fae\u955c\u3001\u7535\u5b50\u884d\u5c04\u3001\u7eb3\u7c73\u7535\u5b50\u675f\u884d\u5c04\u8bc1\u660e\u4e86\u5176\u65e0\u5b9a\u5f62\u7684\u7ed3\u6784\u3002\u5408\u6210\u7684\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u5c3a\u5bf8\u5927\u7ea6\u4e3a10.6 nm\uff0c\u5176\u5e73\u5747\u7ec4\u5206\u4e3aPd43Ni26P31\u3002\u8fdb\u4e00\u6b65\u91c7\u7528XPS\u7814\u7a76\u4e86\u5176\u7535\u5b50\u7ed3\u6784\uff0c\u53d1\u73b0\u5176\u5b58\u5728\u5404\u79cd\u5316\u5b66\u952e\u7ed3\u6784\uff0c\u5305\u62ecPd-Pd, Pd-Ni, Pd-P, Ni-P\u7b49\uff0c\u8fd9\u53ef\u4ee5\u5f52\u7ed3\u4e8e\u5176\u65e0\u5b9a\u5f62\u7684\u539f\u5b50\u7ed3\u6784\u5bfc\u81f4\u4e86\u5404\u79cd\u5316\u5b66\u952e\u7684\u5b58\u5728\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-257749\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/3-6.png\" alt=\"\" width=\"554\" height=\"513\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/3-6.png 554w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/3-6-300x278.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2. <\/strong><strong>\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u8868\u5f81\u3002<\/strong><\/p>\n<p>\u7531\u4e8ePd-P\u548cPt-P\u7cfb\u7edf\u4e2d\u5b58\u5728\u4f4e\u5171\u7194\u70b9\uff0cPd\u548cPt\u57fa\u7684\u91d1\u5c5e\u73bb\u7483\u53ef\u4ee5\u5728\u5e7f\u6cdb\u7684\u7ec4\u6210\u8303\u56f4\u5185\u5408\u6210\u3002\u4e3a\u4e86\u5c55\u793a\u65b9\u6cd5\u7684\u901a\u7528\u6027\uff0c\u4f5c\u8005\u5408\u6210\u4e86\u4e00\u7cfb\u5217Pd\u548cPt\u57fa\u7684\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\uff08<strong>\u56fe<\/strong><strong>3<\/strong>\uff09\uff0c\u5e73\u5747\u7ec4\u6210\u4e3aPd43Ni26P31\u3001Pd48Cu30P22\u3001Pt34Cu38P28\u3001Pd49Cu13Ni8P30\u3001Pt48Cu14Ni11P27\u548c\u4e94\u5143\u9ad8\u71b5Pt21Pd32Cu11Ni9P27\u91d1\u5c5e\u73bb\u7483\u3002\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08HAADF-STEM\uff09\u56fe\u50cf\u548c\u5143\u7d20\u5206\u5e03\u56fe\u5c55\u793a\u4e86\u5143\u7d20\u7684\u5747\u5300\u5206\u5e03\u3002\u7eb3\u7c73\u9897\u7c92\u8868\u73b0\u51fa\u7ed3\u6784\u548c\u5143\u7d20\u7684\u5747\u5300\u6027\u3002\u95ea\u5149\u78b3\u70ed\u53cd\u5e94\u4e3a\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u5408\u6210\u5728\u9897\u7c92\u5c3a\u5bf8\u3001\u5206\u6563\u6027\u3001\u7ec4\u6210\u548c\u57fa\u5e95\u65b9\u9762\u63d0\u4f9b\u4e86\u5e7f\u6cdb\u7684\u53ef\u8c03\u6027\u3002\u901a\u8fc7\u6539\u53d8\u524d\u9a71\u4f53\u52a0\u8f7d\u91cf\u6216\u53cd\u5e94\u6301\u7eed\u65f6\u95f4\uff0c\u53ef\u4ee5\u8c03\u8282\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u5c3a\u5bf8\u3002\u6b64\u5916\uff0c\u8be5\u65b9\u6cd5\u5bf9\u4e8e\u57fa\u5e95\u4e5f\u5177\u6709\u826f\u597d\u7684\u666e\u9002\u6027\uff0c\u4f5c\u8005\u4f7f\u7528\u4e86\u78b3\u9ed1\u3001\u78b3\u7eb3\u7c73\u7ba1\u7b49\u4f5c\u4e3a\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u5408\u6210\u7684\u57fa\u5e95\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-257750\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/4-6.png\" alt=\"\" width=\"800\" height=\"522\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/4-6.png 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/4-6-300x196.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/4-6-768x501.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3. <\/strong><strong>\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u901a\u7528\u5408\u6210\u3002<\/strong><\/p>\n<p>\u901a\u8fc7\u53ef\u8c03\u7684\u524d\u9a71\u4f53\u8d1f\u8f7d\u548c\u8d85\u5feb\u901f\u5408\u6210\uff0c\u95ea\u5149\u78b3\u70ed\u53cd\u5e94\u63d0\u4f9b\u4e86\u5e7f\u6cdb\u7ec4\u5206\u7a7a\u95f4\u7684\u91d1\u5c5e\u73bb\u7483\u7684\u5408\u6210\u9014\u5f84\uff08<strong>\u56fe<\/strong><strong>4<\/strong>\uff09\u3002\u901a\u8fc7\u7ec4\u5408\u5b9e\u9a8c\uff0c\u4f5c\u8005\u5408\u6210\u4e86\u6570\u767e\u4e2a\u4e09\u5143PdNiP\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u5e93\uff0c\u5176\u76f8\uff08\u6676\u4f53\u6216\u73bb\u7483\u6001\uff09\u548c\u7ec4\u6210\u5206\u522b\u901a\u8fc7TEM\u548cEDS\u786e\u5b9a\u3002Pd-Ni-P\u76f8\u56fe\u663e\u793a\u7ea654%\u7684\u7eb3\u7c73\u9897\u7c92\u5f62\u6210\u73bb\u7483\u76f8\uff0c\u6db5\u76d6\u4e86\u7ea610\u81f355 at%\u7684P\u8303\u56f4\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u91d1\u5c5e\u73bb\u7483\u5e26\u548c\u5757\u72b6\u91d1\u5c5e\u73bb\u7483\u7684\u7ec4\u6210\u63a5\u8fd1P ~20 at%\u3002\u56e0\u6b64\uff0cPdNiP \u91d1\u5c5e\u73bb\u7483\u5728\u7eb3\u7c73\u5c3a\u5ea6\u4e0a\u7684\u7ec4\u5206\u7a7a\u95f4\u6bd4\u5176\u5757\u72b6\u5bf9\u5e94\u7269\u8981\u5927\u5f88\u591a\uff0c\u5373\u7eb3\u7c73\u5c3a\u5bf8\u6548\u5e94\u589e\u5f3a\u4e86\u5176\u73bb\u7483\u5f62\u6210\u80fd\u529b\u3002\u4e3a\u4e86\u89e3\u91ca\u7eb3\u7c73\u5c3a\u5bf8\u548c\u5757\u4f53\u91d1\u5c5e\u73bb\u7483\u7684\u7ed3\u6784\u5dee\u5f02\uff0c\u4f5c\u8005\u91c7\u7528\u4e86\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u6765\u7814\u7a76\u4e24\u8005\u7684\u5f62\u6210\u3002\u76f8\u6bd4\u4e8e\u5757\u4f53\u91d1\u5c5e\u73bb\u7483\uff0c\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u663e\u5f97\u66f4\u52a0\u201c\u65e0\u5e8f\u201d\uff0c\u8fd9\u53ef\u80fd\u662f\u56e0\u4e3a\u7eb3\u7c73\u9897\u7c92\u5177\u6709\u66f4\u5927\u7684\u8868\u9762\u79ef\uff0c\u4ece\u800c\u4f7f\u5f97\u5176\u539f\u5b50\u66f4\u52a0\u65e0\u5e8f\u5316\u3002\u8fd9\u4e5f\u662f\u7eb3\u7c73\u5c3a\u5bf8\u91d1\u5c5e\u73bb\u7483\u5177\u6709\u66f4\u5927\u7684\u73bb\u7483\u5f62\u6210\u80fd\u529b\u7684\u8d77\u6e90\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-257751\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/5-5.png\" alt=\"\" width=\"800\" height=\"591\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/5-5.png 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/5-5-300x222.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/5-5-768x567.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4. <\/strong><strong>\u7eb3\u7c73\u5c3a\u5bf8\u6548\u5e94\u589e\u5f3a\u7684\u73bb\u7483\u5f62\u6210\u80fd\u529b\u3002<\/strong><\/p>\n<p>\u7eb3\u7c73\u5c3a\u5bf8\u6548\u5e94\u589e\u5f3a\u73bb\u7483\u5f62\u6210\u80fd\u529b\u7684\u7ed3\u8bba\u6709\u4e24\u4e2a\u91cd\u8981\u7684\u63a8\u8bba\u3002\u9996\u5148\uff0c\u5bf9\u4e8e\u7ed9\u5b9a\u7684\u5408\u91d1\u4f53\u7cfb\uff0c\u4e0d\u80fd\u5f62\u6210\u5757\u4f53\u91d1\u5c5e\u73bb\u7483\u7684\u7ec4\u5206\u6bd4\u4f8b\u53ef\u80fd\u5728\u7eb3\u7c73\u5c3a\u5ea6\u5f62\u6210\u73bb\u7483\u6750\u6599\u3002\u5bf9\u4e8e\u81ea\u4e0b\u800c\u4e0a\u7684\u7eb3\u7c73\u5c3a\u5ea6\u91d1\u5c5e\u5408\u6210\uff0c\u5bf9\u4e8e\u5757\u4f53\u91d1\u5c5e\u73bb\u7483\u7684\u4e25\u683c\u7ec4\u5206\u8981\u6c42\u4f1a\u51cf\u5f31\uff0c\u6b63\u5982\u4f5c\u8005\u5408\u6210\u5177\u6709\u5e7f\u6cdb\u53ef\u8c03\u7ec4\u6210\u7684Pd-Ni-P\u3002\u5176\u6b21\uff0c\u5757\u4f53\u91d1\u5c5e\u73bb\u7483\u65e0\u6cd5\u5b9e\u73b0\u7684\u5408\u91d1\u4f53\u7cfb\u53ef\u80fd\u5728\u7eb3\u7c73\u5c3a\u5ea6\u5f62\u6210\u91d1\u5c5e\u73bb\u7483\u3002\u57fa\u4e8e\u8fd9\u4e00\u70b9\uff0c\u4f5c\u8005\u8fdb\u4e00\u6b65\u6269\u5c55\u4e86\u57fa\u4e8ePd\u7684\u91d1\u5c5e\u73bb\u7483\u7684\u7ec4\u5206\u7a7a\u95f4\uff0c\u5b9e\u73b0\u4e86Pd-Co-P\u548cPd-Sn-P\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u5408\u6210\uff08<strong>\u56fe<\/strong><strong>5<\/strong>\uff09\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u5f15\u5165\u4e86Fe\u5e76\u5408\u6210\u4e86\u9ad8\u71b5PdCuNiFeP\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u3002\u8fd9\u4e9b\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u7ec4\u6210\u5728\u5757\u4f53\u4e2d\u5747\u5c1a\u672a\u62a5\u9053\u8fc7\u3002<\/p>\n<p>\u603b\u7ed3\u800c\u8a00\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u4e00\u79cd\u95ea\u5149\u78b3\u70ed\u53cd\u5e94\u65b9\u6cd5\uff0c\u5b9e\u73b0\u4e86Pd\u57fa\u548cPt\u57fa\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u901a\u7528\u5236\u5907\uff0c\u5305\u62ecPdNiP\u3001PdCuP\u3001PdCuNiP\u3001PtCuP\u3001PtCuNiP\u3001PdCoP\u3001PdSnP\u3001\u9ad8\u71b5PtPdCuNiP\u548cPdCuFeNiP\u3002\u4f5c\u8005\u8fd8\u53d1\u73b0\u4e86\u201c\u7eb3\u7c73\u5c3a\u5bf8\u589e\u5f3a\u73bb\u7483\u5f62\u6210\u80fd\u529b\u201d\u8fd9\u4e00\u6548\u5e94\uff0c\u8fd9\u4f7f\u5f97\u4e00\u4e9b\u4ece\u672a\u5728\u5757\u4f53\u4e2d\u5b9e\u73b0\u7684\u91d1\u5c5e\u73bb\u7483\u7ec4\u6210\u7cfb\u7edf\u5f97\u4ee5\u5728\u7eb3\u7c73\u5c3a\u5ea6\u5408\u6210\uff0c\u8fd9\u5bf9\u4e8e\u7814\u7a76\u91d1\u5c5e\u73bb\u7483\u7684\u5f62\u6210\u3001\u7279\u6b8a\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u90fd\u6709\u4e00\u5b9a\u7684\u6307\u5bfc\u610f\u4e49\uff0c\u5e76\u4e3a\u91d1\u5c5e\u73bb\u7483\u7eb3\u7c73\u9897\u7c92\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u6750\u6599\u57fa\u7840\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-257752\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/6-5.png\" alt=\"\" width=\"491\" height=\"467\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/6-5.png 491w, \/\/m.iemloyee.com\/wp-content\/uploads\/2024\/02\/6-5-300x285.png 300w\" sizes=\"(max-width: 491px) 100vw, 491px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5. <\/strong><strong>\u5408\u6210\u4e00\u4e9b\u4e4b\u524d\u4ece\u672a\u5b9e\u73b0\u8fc7\u7684\u91d1\u5c5e\u73bb\u7483\u7ec4\u5206\u3002<\/strong><\/p>\n<p>\u3010\u4f5c\u8005\u4ecb\u7ecd\u3011<\/p>\n<p><strong>\u9093\u5175<\/strong>\uff0c\u6e05\u534e\u5927\u5b66\u52a9\u7406\u6559\u6388\u3001\u7279\u522b\u7814\u7a76\u5458\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u5f00\u53d1\u57fa\u4e8e\u7535\u80fd\u7684\u65b0\u578b\u4f4e\u78b3\u7535\u6c14\u5316\u65b9\u6cd5\uff08\u5305\u62ec\u7535\u70ed\u6280\u672f\u548c\u7535\u5316\u5b66\u6280\u672f\uff09\u7528\u4e8e\u6218\u7565\u5173\u952e\u91d1\u5c5e\u5faa\u73af\u56de\u6536\u3001\u56fa\u4f53\u5e9f\u5f03\u7269\u8d44\u6e90\u5316\u5229\u7528\u3001\u529f\u80fd\u7eb3\u7c73\u6750\u6599\u7684\u5236\u5907\u53ca\u5728\u73af\u5883\u548c\u80fd\u6e90\u50ac\u5316\u9886\u57df\u7684\u5e94\u7528\u7b49\u3002\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<a href=\"https:\/\/www.x-mol.com\/groups\/deng_bing\">https:\/\/www.x-mol.com\/groups\/deng_bing<\/a><\/p>\n<p><strong>\u8d75\u7389\u5cf0<\/strong>\uff0c\u79d1\u5c14\u4e07\u5927\u5b66\u6559\u6388\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u57fa\u4e8e\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u548cDFT\u65b9\u6cd5\u7684\u65e0\u673a\u7eb3\u7c73\u6750\u6599\u76f8\u53d8\u8fc7\u7a0b\u548c\u7535\u50ac\u5316\u673a\u7406\u7b49\u65b9\u9762\u7684\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u3002\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<a href=\"https:\/\/www.corban.edu\/faculty\/dr-yufeng-zhao\/\">https:\/\/www.corban.edu\/faculty\/dr-yufeng-zhao\/<\/a><\/p>\n<p><strong>James M. Tour<\/strong>\uff0c\u83b1\u65af\u5927\u5b66\u6559\u6388\u3002Tour\u6559\u6388\u5728\u7eb3\u7c73\u79d1\u5b66\u6280\u672f\u9886\u57df\u505a\u51fa\u4e86\u5e7f\u6cdb\u7684\u8d21\u732e\uff0c\u5305\u62ec\u7eb3\u7c73\u7535\u5b50\u3001\u78b3\u6750\u6599\u3001\u7eb3\u7c73\u533b\u5b66\u3001\u5206\u5b50\u673a\u5668\u3001\u7528\u4e8e\u7535\u6c60\u7535\u50ac\u5316\u548c\u73af\u5883\u4fee\u590d\u7684\u7eb3\u7c73\u6750\u6599\u5236\u5907\u7b49\u3002\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<a href=\"https:\/\/www.jmtour.com\">https:\/\/www.jmtour.com<\/a><\/p>\n<p>\u3010\u6587\u732e\u4fe1\u606f\u3011<\/p>\n<p>Bing Deng<sup>#,<\/sup>*, Zhe Wang<sup>#<\/sup>, Chi Hun Choi, Gang Li, Zhe Yuan, Jinhang Chen, Duy Xuan Luong, Lucas Eddy, Bongki Shin, Alexander Lathem, Weiyin Chen, Yi Cheng, Shichen Xu, Yimo Han, Boris I. Yakobson, Yufeng Zhao,* James M. Tour*, Kinetically Controlled Synthesis of Metallic Glass Nanoparticles with Expanded Phase Space, <em>Advanced Materials<\/em>, <strong>2024<\/strong>, doi: 10.1002\/adma.202309956.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u9093\u5175\uff0c\u738b\u54f2 \u901a\u8baf\u4f5c\u8005\uff1a\u9093\u5175\uff0c\u8d75\u7389\u5cf0\uff0cJames M. Tour \u901a\u8baf\u5355\u4f4d\uff1a\u6e05\u534e\u5927\u5b66\uff0c\u79d1\u5c14\u4e07\u5927\u5b66\uff0c\u83b1\u65af\u5927\u5b66 \u8bba\u6587\u94fe\u63a5\uff1ahttps:\/\/onlinelib&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-257743","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/257743"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=257743"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/257743\/revisions"}],"predecessor-version":[{"id":257753,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/257743\/revisions\/257753"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=257743"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=257743"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=257743"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}