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\"\"<\/p>\n

\u56fe3. \u915e\u83c1\u94b4\u5728\u4e0d\u540c\u78b3\u7eb3\u7c73\u7ba1\u4e0a\u7684\u5f62\u8c8c\u3002[3]<\/sup><\/p>\n

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\"\"<\/p>\n

 <\/p>\n

\u56fe 4. BP\/BWO \u5f02\u8d28\u7ed3\u7684\u6784\u9020\u793a\u610f\u56fe\u3002[4]<\/sup><\/p>\n

\u8fc7\u6e21\u91d1\u5c5e\u4e8c\u786b\u5c5e\u5316\u7269\uff08transition metal dichalcogenides\uff09\u4f5c\u4e3a\u50ac\u5316\u5242\u8f7d\u4f53\u5177\u6709\u4ee5\u4e0b\u51e0\u4e2a\u4f18\u52bf\u548c\u7279\u5f81\uff1a\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\uff1a\u8fc7\u6e21\u91d1\u5c5e\u4e8c\u786b\u5c5e\u5316\u7269\u5177\u6709\u4e30\u5bcc\u7684\u8fc7\u6e21\u91d1\u5c5e\u539f\u5b50\u548c\u786b\u539f\u5b50\uff0c\u8fd9\u4e9b\u539f\u5b50\u53ef\u4ee5\u63d0\u4f9b\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u8fd9\u79cd\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u53ef\u4ee5\u5438\u9644\u53cd\u5e94\u7269\u5206\u5b50\u5e76\u4fc3\u8fdb\u50ac\u5316\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u53ef\u8c03\u63a7\u7684\u7535\u5b50\u7ed3\u6784\uff1a\u8fc7\u6e21\u91d1\u5c5e\u4e8c\u786b\u5c5e\u5316\u7269\u7684\u7535\u5b50\u7ed3\u6784\u53ef\u4ee5\u901a\u8fc7\u8c03\u8282\u8fc7\u6e21\u91d1\u5c5e\u539f\u5b50\u7684\u79cd\u7c7b\u3001\u786b\u539f\u5b50\u914d\u4f4d\u65b9\u5f0f\u4ee5\u53ca\u5916\u52a0\u7535\u573a\u7b49\u624b\u6bb5\u8fdb\u884c\u8c03\u63a7\u3002\u901a\u8fc7\u8c03\u63a7\u7535\u5b50\u7ed3\u6784\uff0c\u53ef\u4ee5\u6539\u53d8\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff1a\u7531\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u4e8c\u786b\u5c5e\u5316\u7269\u8868\u9762\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u53ef\u8c03\u63a7\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u5b83\u4eec\u901a\u5e38\u5177\u6709\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u4f7f\u5f97\u5b83\u4eec\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u80fd\u591f\u6709\u6548\u5730\u50ac\u5316\u53cd\u5e94\u7269\u8f6c\u5316\u4e3a\u6240\u9700\u4ea7\u7269\u3002\u826f\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff1a\u8fc7\u6e21\u91d1\u5c5e\u4e8c\u786b\u5c5e\u5316\u7269\u5177\u6709\u826f\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u53ef\u4ee5\u8010\u53d7\u4e00\u5b9a\u7684\u50ac\u5316\u53cd\u5e94\u6761\u4ef6\uff0c\u5982\u9ad8\u6e29\u3001\u9ad8\u538b\u548c\u5f3a\u9178\u78b1\u6761\u4ef6\u3002\u8fd9\u4f7f\u5f97\u5b83\u4eec\u5177\u6709\u8f83\u957f\u7684\u4f7f\u7528\u5bff\u547d\u3002\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u5f20\u534e\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u62a5\u9053\u4e86\u9ad8\u7eaf\u5ea6\u76f8\u7684MoS2<\/sub>\u7eb3\u7c73\u7247\u7684\u5236\u5907\uff0c\u5e76\u5c55\u793a\u4e862H\u76f8\u6a21\u677f\u4fc3\u8fdb\u4e86Pt\u7eb3\u7c73\u9897\u7c92\u7684\u5916\u5ef6\u751f\u957f\uff0c\u800c1T’\u76f8\u5219\u652f\u6301\u7740\u8d1f\u8f7d\u91cf\u9ad8\u8fbe10wt%\u7684\u5355\u539f\u5b50\u5206\u6563\u7684Pt\uff08s-Pt\uff09\u539f\u5b50\u3002\u6211\u4eec\u53d1\u73b0\uff0c\u5728\u8fd9\u79cds-Pt\/1T’-MoS2<\/sub>\u7cfb\u7edf\u4e2d\uff0cPt\u539f\u5b50\u5360\u636e\u4e09\u4e2a\u4e0d\u540c\u7684\u4f4d\u7f6e\uff0c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u663e\u793a\uff0c\u4f4d\u4e8eMo\u539f\u5b50\u4e0a\u65b9\u7684Pt\u539f\u5b50\u7684\u6c22\u5438\u9644\u81ea\u7531\u80fd\u63a5\u8fd1\u96f6\u3002\u8fd9\u53ef\u80fd\u6709\u52a9\u4e8e\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u9ad8\u6548\u7684\u7535\u50ac\u5316\u4ea7\u6c22\uff0c\u6211\u4eec\u6d4b\u5f97s-Pt\/1T’-MoS2<\/sub>\u5728\u8fc7\u7535\u4f4d\u4e3a-50mV\u65f6\u7684\u8d28\u91cf\u6d3b\u6027\u4e3a85\u00b123A\/mgPt<\/sub>\uff0c\u8d28\u91cf\u5f52\u4e00\u5316\u7684\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\u4e3a127A\/mgPt<\/sub>\uff0c\u5e76\u4e14\u5728\u5ba4\u6e29\u4e0b\u7684H\u578b\u7535\u6c60\u548c\u539f\u578b\u8d28\u5b50\u4ea4\u6362\u819c\u7535\u89e3\u69fd\u4e2d\u8868\u73b0\u51fa\u7a33\u5b9a\u7684\u6027\u80fd\u3002\u5c3d\u7ba1\u76f8\u7a33\u5b9a\u6027\u9650\u5236\u4e86\u5728\u9ad8\u6e29\u4e0b\u7684\u5e94\u7528\uff0c\u4f5c\u8005\u4eec\u9884\u8ba11T’-TMDs\u4e5f\u5c06\u662f\u5176\u4ed6\u91cd\u8981\u53cd\u5e94\u7684\u6709\u6548\u8f7d\u4f53\u50ac\u5316\u5242\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5. s-Pt\/1T’-MoS2<\/sub>\u7684\u7ed3\u6784\u8868\u5f81\u3002[5]<\/sup><\/p>\n

MXene\u662f\u4e00\u79cd\u65b0\u578b\u7684\u4e8c\u7ef4\u6750\u6599\uff0c\u4f5c\u4e3a\u50ac\u5316\u5242\u8f7d\u4f53\u5177\u6709\u4ee5\u4e0b\u51e0\u4e2a\u4f18\u52bf\u548c\u7279\u5f81\uff1a\u591a\u5b54\u7ed3\u6784\uff1aMXene\u5177\u6709\u591a\u5b54\u7684\u4e8c\u7ef4\u5c42\u72b6\u7ed3\u6784\uff0c\u8fd9\u4f7f\u5f97\u5b83\u5177\u6709\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\u548c\u591a\u5b54\u7ed3\u6784\uff0c\u63d0\u4f9b\u4e86\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u53cd\u5e94\u901a\u9053\uff0c\u4ece\u800c\u589e\u52a0\u4e86\u50ac\u5316\u53cd\u5e94\u7684\u6548\u7387\u3002\u7535\u5bfc\u7387\u548c\u5bfc\u7535\u6027\uff1aMXene\u5177\u6709\u826f\u597d\u7684\u7535\u5bfc\u7387\u548c\u5bfc\u7535\u6027\u3002\u8fd9\u79cd\u7535\u5bfc\u6027\u53ef\u4ee5\u6539\u5584\u50ac\u5316\u5242\u7684\u7535\u5b50\u4f20\u8f93\u6027\u80fd\uff0c\u5e76\u4fc3\u8fdb\u53cd\u5e94\u7269\u7684\u8f6c\u5316\u3002\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff1a\u7531\u4e8eMXene\u8868\u9762\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u5bfc\u7535\u6027\uff0c\u5b83\u901a\u5e38\u5177\u6709\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u4f7f\u5f97\u5b83\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u80fd\u591f\u6709\u6548\u5730\u50ac\u5316\u53cd\u5e94\u7269\u8f6c\u5316\u4e3a\u6240\u9700\u4ea7\u7269\u3002\u826f\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff1aMXene\u5177\u6709\u826f\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u53ef\u4ee5\u8010\u53d7\u67d0\u4e9b\u6076\u52a3\u7684\u50ac\u5316\u53cd\u5e94\u6761\u4ef6\uff0c\u5982\u9ad8\u6e29\u3001\u9ad8\u538b\u548c\u5f3a\u9178\u78b1\u6761\u4ef6\u3002\u8fd9\u4f7f\u5f97\u5b83\u5177\u6709\u8f83\u957f\u7684\u4f7f\u7528\u5bff\u547d\u3002\u53ef\u8c03\u63a7\u7684\u8868\u9762\u6027\u8d28\uff1aMXene\u7684\u8868\u9762\u6027\u8d28\u53ef\u4ee5\u901a\u8fc7\u8868\u9762\u4fee\u9970\u3001\u63ba\u6742\u7b49\u624b\u6bb5\u8fdb\u884c\u8c03\u63a7\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u50ac\u5316\u53cd\u5e94\u4e2d\u53cd\u5e94\u7269\u5438\u9644\u548c\u53cd\u5e94\u8fc7\u7a0b\u7684\u63a7\u5236\uff0c\u63d0\u9ad8\u50ac\u5316\u6548\u7387\u548c\u9009\u62e9\u6027\u3002\u6e56\u5357\u5927\u5b66\u8c2d\u52c7\u6587<\/strong>\u6559\u6388\u8bfe\u9898\u7ec4\u901a\u8fc7\u4e00\u79cd\u539f\u4f4d\u751f\u957f\u65b9\u6cd5\uff0c\u6784\u5efa\u4e86\u4e00\u79cd\u72ec\u7279\u7684Pd metallene\/Ti3<\/sub>C2<\/sub>Tx<\/sub> MXene\uff08Pdene\/ Ti3<\/sub>C2<\/sub>Tx<\/sub>\uff09\u8d1f\u8f7d\u7535\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u9ad8\u6548\u7684\u4e59\u9187\u6c27\u5316\u53cd\u5e94\u3002\u7ed3\u679c\u8868\u660e\uff0c\u6240\u5f97\u5230\u7684Pdene\/ Ti3<\/sub>C2<\/sub>Tx<\/sub>\u50ac\u5316\u5242\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e86\u8d85\u9ad8\u7684\u8d28\u91cf\u6d3b\u6027\uff0c\u4e3a7.47 A mgPd-1<\/sup>\uff0c\u5e76\u4e14\u5177\u6709\u9ad8\u8010\u53d7CO\u4e2d\u6bd2\u7684\u80fd\u529b\u3002\u539f\u4f4d\u8870\u51cf\u5168\u53cd\u5c04\u7ea2\u5916\u5149\u8c31\u7814\u7a76\u7ed3\u5408\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cPdene\/ Ti3<\/sub>C2<\/sub>Tx<\/sub>\u50ac\u5316\u5242\u7684\u4f18\u5f02EOR\u6d3b\u6027\u5f52\u56e0\u4e8e\u72ec\u7279\u800c\u7a33\u5b9a\u7684\u754c\u9762\uff0c\u964d\u4f4e\u4e86*<\/sup>CH3<\/sub>CO\u4e2d\u95f4\u4f53\u6c27\u5316\u7684\u53cd\u5e94\u80fd\u969c\u5e76\u901a\u8fc7\u589e\u52a0Pd-OH\u952e\u5408\u5f3a\u5ea6\u4fc3\u8fdb\u4e86CO\u6709\u6bd2\u7269\u8d28\u7684\u6c27\u5316\u53bb\u9664\u3002[6]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe 6. Pd\u91d1\u5c5e\u70ef\/Ti3<\/sub>C2<\/sub>Tx<\/sub>\u5f02\u8d28\u7ed3\u7684\u5408\u6210\u4e0e\u8868\u5f81\u3002[6]<\/sup><\/p>\n

\u9664\u6b64\u4e4b\u5916\uff0cMOF\uff0cCOF\uff0cLDH\u7b49\u6750\u6599\u4e5f\u53ef\u4ee5\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u6709\u6548\u8f7d\u4f53\uff0c\u901a\u8fc7\u590d\u5408\uff0c\u5236\u5907\u51fa\u9ad8\u6027\u80fd\u7684\u50ac\u5316\u6750\u6599\u3002<\/strong><\/p>\n

\u5148\u770b\u770bMOF\u548cCOF\u3002<\/strong><\/p>\n

\u9999\u6e2f\u5927\u5b66\u7684<\/strong>Jian He<\/strong>\u6559\u6388\u8bfe\u9898\u7ec4\u63d0\u51fa<\/strong>\u4e00\u79cd\u6709\u6548\u7684\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u652f\u6301\u7684\u94dc(I)\u5149\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u591a\u4e2a\u4e9a\u80fa\u57fa\u81ea\u7531\u57fa\u4ecb\u5bfc\u7684\u53cd\u5e94\u3002\u7531\u4e8e\u4f4d\u70b9\u9694\u79bb\u6548\u5e94\uff0c\u8fd9\u79cd\u56fa\u5b9a\u5316\u7684\u94dc\u5149\u654f\u5242\u5177\u6709\u6bd4\u5176\u5747\u76f8\u5bf9\u5e94\u7269\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002\u4f7f\u7528\u7f9f\u809f\u9178\u8fde\u63a5\u5242\u5c06\u94dc\u7269\u79cd\u56fa\u5b9a\u5728MOF\u652f\u6491\u4e0a\uff0c\u83b7\u5f97\u4e86\u5177\u6709\u9ad8\u518d\u751f\u80fd\u529b\u7684\u975e\u5747\u76f8\u50ac\u5316\u5242\u3002\u5728MOF\u8868\u9762\u7684\u540e\u5408\u6210\u4fee\u9970\u5e8f\u5217\u53ef\u7528\u4e8e\u5236\u5907\u4ee5\u524d\u4e0d\u53ef\u7528\u7684\u5355\u4f53\u94dc\u7269\u79cd\u3002\u7814\u7a76\u7ed3\u679c\u51f8\u663e\u4e86\u5229\u7528\u57fa\u4e8eMOF\u7684\u975e\u5747\u76f8\u50ac\u5316\u7cfb\u7edf\u6765\u89e3\u51b3\u5408\u6210\u65b9\u6cd5\u5b66\u548c\u8fc7\u6e21\u91d1\u5c5e\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u673a\u7406\u7814\u7a76\u4e2d\u7684\u57fa\u672c\u6311\u6218\u7684\u6f5c\u529b\u3002[7]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe7. MOF\u8d1f\u8f7d\u94dc\u57fa\u5149\u50ac\u5316\u5242\u7684\u5408\u6210\u4e0e\u7ed3\u6784\u793a\u610f\u3002[7]<\/sup><\/p>\n

\u800c<\/strong>COF<\/strong>\u65b9\u9762\u82cf\u5dde\u5927\u5b66\u674e\u5f66\u5149\u8bfe\u9898\u7ec4<\/strong>\u9996\u6b21\u5c55\u793a\u4e86\u4e00\u79cd\u57fa\u4e8e\u4e8c\u7ef4\u954d\u535f\u5549\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COF\uff09\uff0c\u4f5c\u4e3a\u6f5c\u5728\u7684\u5019\u9009\u6750\u6599\u3002\u8be5\u4ea7\u7269\u5177\u6709\u9ad8\u5ea6\u6709\u5e8f\u7684\u5206\u5b50\u7ed3\u6784\u548c\u4e30\u5bcc\u7684\u65b9\u5f62\u7eb3\u7c73\u5b54\u9053\u3002\u5728\u4e2d\u6027\u6eb6\u6db2\u4e2d\uff0c\u4ee5\u8f83\u4f4e\u8fc7\u7535\u4f4d\u5b9e\u73b0\u4e86\u4e0d\u540c\u6d53\u5ea6\u785d\u9178\u76d0\u79bb\u5b50\u4ece\u6c28\u8fd8\u539f\uff0c\u9009\u62e9\u6027\u8fbe\u523090%\u4ee5\u4e0a\uff1b\u4ea7\u7387\u9ad8\u8fbe\u6bcf\u5e73\u65b9\u5398\u7c732.5\u6beb\u514b\/\u5c0f\u65f6\uff0cTOF\u9ad8\u8fbe\u6bcf\u79d23.5\u6b21\uff1b\u8109\u51b2\u7535\u89e3\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u6700\u4f73\u7684\u5185\u5728\u7a33\u5b9a\u6027\u3002\u8fd9\u79cd\u9634\u6781\u53cd\u5e94\u8fd8\u53ef\u4ee5\u4e0e\u6c27\u91ca\u653e\u53cd\u5e94\u8026\u5408\uff0c\u5b9e\u73b0\u9ad8\u6548\u7684\u5168\u7535\u6c60\u7535\u89e3\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u954d\u4e2d\u5fc3\u80fd\u7a33\u5b9a\u5438\u9644\u785d\u9178\u76d0\uff0c\u5e76\u901a\u8fc7\u964d\u4f4e\u901f\u7387\u63a7\u5236\u6b65\u9aa4\u7684\u80fd\u5792\u4fc3\u8fdb\u5176\u540e\u7eed\u8fd8\u539f\u3002[8]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe8. NiPr-TPA-COF\u7684\u7ed3\u6784\u8868\u5f81\u3002[8]<\/sup><\/p>\n

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\u4e3b\u8981\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n

[1] Hydrophobic zeolite modification for in situ peroxide formation in methane oxidation to methanol. Science <\/em>2020, <\/strong>367<\/em>, 193-197.<\/p>\n

[2] Ruthenium-cobalt single atom alloy for CO photo-hydrogenation to liquid fuels at ambient pressures. Nat. Commun.<\/em><\/a> 2023, <\/strong>14,\u00a01909.<\/p>\n

[3] Strain enhances the activity of molecular electrocatalysts via carbon nanotube supports. Nat<\/em>. Catal<\/em>.<\/a> 2023,<\/strong> 818\u2013828.<\/p>\n

[4] Coupling Benzylamine Oxidation with CO2<\/sub> Photo conversion to Ethanol over a Black Phosphorus and Bismuth Tungstate S-Scheme Heterojunction. Angew. Chem.<\/em> 2023, <\/strong>135, e2023029.<\/p>\n

[5] Phase-dependent growth of Pt on MoS2<\/sub> for highly efficient H2<\/sub> evolution. Nature<\/em><\/a> 2023<\/strong>,\u00a0<\/strong>621, 300\u2013305.<\/p>\n

[6] Palladium metallene confined on MXene with increased hydroxyl binding strength for highly efficient ethanol electrooxidation. PNAS<\/em>, 2023<\/strong>, 120, e2222096120.<\/p>\n

[7] Metal-Organic Framework Supported Copper Photoredox Catalysts for Iminyl Radical-Mediated Reactions. Angew. Chem. Int. Ed.<\/em> 2023, <\/strong>62, e20230023.<\/p>\n

[8] Near-unity electrochemical conversion of nitrate to ammonia on crystalline nickel porphyrin-based covalent organic framework. Energy Environ. Sci.<\/em>, 2023, <\/strong>16, 201.<\/p>\n

[9] Enhanced Carbon Monoxide Electroreduction to >1\u2005A\u2009cm\u22122<\/sup> C2+<\/sub> Products Using Copper Catalysts Dispersed on MgAl Layered Double Hydroxide Nanosheet House-of-Cards Scaffolds. Angew. Chem. Int. Ed.<\/em> 2023,<\/strong> 62, e20221725.<\/p>\n

\u672c\u6587\u7531\u8e0f\u6d6a<\/strong>\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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