{"id":256679,"date":"2023-12-22T07:09:29","date_gmt":"2023-12-21T23:09:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=256679"},"modified":"2023-12-21T21:16:34","modified_gmt":"2023-12-21T13:16:34","slug":"%e5%85%a8%e6%96%b0omn%e6%9d%90%e6%96%99%ef%bc%8c%e4%b8%80%e4%b8%aa%e6%bc%94%e5%91%98%ef%bc%8c%e4%b8%a4%e4%b8%aa%e8%a7%92%e8%89%b2%ef%bc%81%ef%bc%81%e5%9c%a8%e9%92%99%e9%92%9b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=256679","title":{"rendered":"\u5168\u65b0OMN\u6750\u6599\uff0c\u201c\u4e00\u4e2a\u6f14\u5458\uff0c\u4e24\u4e2a\u89d2\u8272\u201d\uff01\uff01\u5728\u9499\u949b\u77ff\u8584\u819c\u5236\u5907\u8fc7\u7a0b\u4e2d\u540c\u65f6\u5b9e\u73b0\u7ed3\u6676\u8c03\u63a7\u548c\u7f3a\u9677\u949d\u5316\uff0c\u4e3a\u5ba2\u5236\u5316\u529f\u80fd\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u65b9\u6cd5\u3002"},"content":{"rendered":"
\u4e00\u3001\u00a0\u3010\u5bfc\u8bfb\u3011 \u00a0<\/p>\n
\u5c3d\u7ba1\u901a\u8fc7\u4e0d\u540c\u7684\u7b56\u7565\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u4f0f\u6027\u80fd\u5f97\u5230\u4e86\u6781\u5927\u7684\u6539\u5584\uff0c\u4f46\u4e0e\u4f20\u7edf\u7ed3\u6784\u76f8\u6bd4\uff0c\u5728\u4e00\u81f4\u6027\u548c\u6548\u7387\u65b9\u9762\u4ecd\u6709\u5f88\u5927\u5dee\u8ddd\u3002\u76ee\u524d\u88ab\u5e7f\u6cdb\u63a5\u53d7\u7684\u949d\u5316\uff0c\u9499\u949b\u77ff\u7f3a\u9677\u7684\u65b9\u6cd5\u4ee5\u53ca\uff0c\u9499\u949b\u77ff\u6676\u7c92\u7684\u53ef\u63a7\u751f\u957f\u4ecd\u7136\u662f\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5b9e\u9645\u5e94\u7528\u8bbe\u5907\u6027\u80fd\u7684\u6311\u6218\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u97e9\u56fd\u56fd\u7acbPukyong<\/i><\/em><\/strong>\u00a0<\/i><\/em><\/strong>National<\/i><\/em><\/strong>\u00a0<\/i><\/em><\/strong>University<\/i><\/em><\/strong>\u00a0<\/i><\/em><\/strong>\u7684Fengwu<\/i><\/em><\/strong>\u00a0<\/i><\/em><\/strong>Liu\uff08\u7b2c\u4e00\u4f5c\u8005\uff09\uff0c<\/i><\/em><\/strong>Sung Heum Park<\/i><\/em><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/i><\/em><\/strong>\u7b49\u4eba\u8bbe\u8ba1\u5e76\u5f00\u53d1\u4e86\u591a\u529f\u80fd\u6c27\u57fa\u5c01\u7aefmelem\u7eb3\u7c73\u7c92\u5b50\uff08OMN\uff09\u6539\u6027\u5242\uff0c\u5e76\u901a\u8fc7\u53cd\u6eb6\u5242\u5de5\u7a0b\u5c06\u5176\u52a0\u5165\u5230\u4e86\u9499\u949b\u77ff\u4e2d\u3002OMN \u7684\u5927\u6bd4\u8868\u9762\u79ef\u786e\u4fdd\u4e86\u901a\u8fc7\u8c03\u8282\u7ed3\u6676\u8fc7\u7a0b\u5e76\u901a\u8fc7\u53cd\u6eb6\u5242\u5f7b\u5e95\u949d\u5316\u5927\u91cf\u7f3a\u9677\u6765\u751f\u4ea7\u51fa\u9ad8\u8d28\u91cf\u7684\u9499\u949b\u77ff\u8584\u819c\u3002melem\u7eb3\u7c73\u7c92\u5b50\u63d0\u9ad8\u4e86 PSC \u7684\u5149\u4f0f\u6027\u80fd\u3002\u6b64\u5916\uff0c\u9ad8\u8d28\u91cf\u7684\u9499\u949b\u77ff\u8584\u819c\u548c\u51fa\u8272\u7684\u7f3a\u9677\u949d\u5316\u76f8\u7ed3\u5408\uff0c\u63d0\u9ad8\u4e86\u5668\u4ef6\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n \u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n \u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cOxyl-terminated Melem Nanoparticles as Crystallization Modulators and Passivating Anchors for High-Performance Perovskite Solar Cells\u201d\u4e3a\u9898\u53d1\u8868\u5728Nano\u00a0Energy\u4e0a\u3002\u97e9\u56fd\u56fd\u7acb\u91dc\u5e86\u5927\u5b66\uff08Pukyong<\/strong>\u00a0<\/strong>National<\/strong>\u00a0University<\/strong>\uff09Fengwu<\/strong>\u00a0<\/strong>Liu\u4e3a\u4e00\u4f5c\uff0c<\/strong>Sung Heum Park<\/strong>\u6559\u6388\u4e3a\u901a\u8baf\u4f5c\u8005<\/strong>\u3002<\/p>\n \u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n 1.\u91c7\u7528\u81ea\u4e0a\u800c\u4e0b\u7684\u65b9\u6cd5\uff0c\u7531\u6c2e\u5316\u78b3\u6210\u529f\u5408\u6210\u4e86\u529f\u80fd\u5316melem\u7eb3\u7c73\u9897\u7c92\u3002<\/p>\n 2.\u5b9a\u5236\u7684\u7eb3\u7c73\u7c92\u5b50\u5b9e\u73b0\u4e86\u9499\u949b\u77ff\u7ed3\u6676\u7684\u8c03\u8282\u548c\u7f3a\u9677\u949d\u5316\u3002<\/p>\n 3.\u901a\u8fc7\u7eb3\u7c73\u7c92\u5b50\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\u5b9e\u73b0\u6700\u6709\u6548\u7684\u63a5\u89e6\u53cd\u5e94\u3002<\/p>\n 4.\u6709\u6548\u63d0\u5347\u9499\u949b\u77ff\u5012\u7f6e\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u6027\u80fd\u3002<\/p>\n \u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/p>\n Fig. 1. (a) Schematic diagram of OMN preparation process. (b)XRD of CCN. (c) FTIR of the powder of CCN and OMN. SEM (d) and (e) TEM images of CCN. (f) TEM of OMN. (g) TEM-EDS mappings of OMN.<\/p>\n Fig. 2. (a) OMN molecular structure and visualization of the ESP result; (b) A schematic illustration of the interaction between OMN and perovskite; (c) Theoretical calculation of molecular interaction between the perovskite precursors (MAI, PbI2) and OMN. The formation energies of OMN-MAI, OMN-PbI2, and PbI2-MAI molecular structures, calculated by DFT.<\/p>\n Fig. 3. (a) Schematic diagram of the preparation process of MA-based perovskite thin film; SEM (b) and XRD (c) of the MA-based perovskite film without and with OMN before the annealing. SEM (d) and XRD (e) of the MA-based perovskite film without and with OMN after annealing.<\/p>\n Fig. 4. FTIR spectra of (a) PbI2, OMN and OMN with PbI2; (b) MAI, OMN and OMN with MAI. XPS spectra of (c) C 1s, (d) Pb 4f and (e) I 3d with and without OMN; NMR spectra of (f) OMN, MAI and OMN with MAI, (g) OMN and OMN with PbI2 and (h) OMN, MAPbI3 and OMN with MAPbI3.<\/p>\n Fig. 5. SEM (a), XRD (b), PL (c) and (d) UV\u2013vis absorption spectra of MA-based perovskite film prepared with different OMN concentrations on glass. (e) UV\u2013vis absorption spectra of the control and the OMN-perovskite film, respectively. (f) Contact angle of MA-based control and with 1.0mg\/ml OMN-perovskite film on CB.<\/p>\n Fig. 6. (a) Schematic structure of the MA-based device. Cross-sectional SEM of the (b) Control and (c) modified MA-based device. J-V curves of the PSC devices using different OMN concentrations optimized for (d) MA-based and (g) CsFAMA-based active layers. Forward and reverse J-V scans of the best performing control devices and OMN-modified (e) MA-based and (h) CsFAMA-based PSCs. IPCE spectra and integrated photocurrents of the best performing control devices and OMN-modified (f) MA-based and (i) CsFAMA-based PSCs.<\/p>\n Fig. 7. Different irradiation intensities for MA-based device of (a) JSC<\/sub>\u00a0and (b) Voc. (c) Dark J-V curves for MA-based control and OMN-modified PSCs. Dark J\u2013V characteristics of MA-based (d) control and (e) OMN-modified device (the inset shows the device structure). (f) Stability testing of MA-based PSC devices at room temperature and in a nitrogen environment (H2<\/sub>O 30 ppm, O2<\/sub>\u00a030 ppm).<\/p>\n <\/p>\n \u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/p>\n \u5ba2\u5236\u5316\u5177\u6709\u591a\u529f\u80fd\u949d\u5316\u80fd\u529b\u7684\u6c27\u57fa\u5c01\u7aef melem \u7eb3\u7c73\u7c92\u5b50\uff0c\u5e76\u5c06\u5176\u7528\u4f5c\u6539\u6027\u5242\u3002\u7136\u540e\uff0c\u901a\u8fc7\u4e0e\u6297\u6eb6\u5242\u5de5\u7a0b\u76f8\u7ed3\u5408\uff0c\u5c06\u8fd9\u4e9b\u7eb3\u7c73\u9897\u7c92\u878d\u5165\u5230\u4e86\u9499\u949b\u77ff\u5c42\u4e2d\u3002\u8fd9\u9879\u5de5\u4f5c\u5f3a\u8c03\u4e86OMN \u5982\u4f55\u4fc3\u8fdb\u4e2d\u95f4\u76f8\u7684\u751f\u6210\uff0c\u4ee5\u53ca\u5982\u4f55\u5728\u672a\u9000\u706b\u9636\u6bb5\u51cf\u7f13\u9499\u949b\u77ff\u6676\u4f53\u7684\u7ed3\u6676\u901f\u5ea6\u3002\u540c\u65f6\uff0c\u5728\u9000\u706b\u8fc7\u7a0b\u4e2d\uff0cOMN \u4e2d\u7684\u5404\u79cd\u5b98\u80fd\u56e2\u53ef\u949d\u5316\u9499\u949b\u77ff\u8584\u819c\u4e2d\u7684\u5404\u79cd\u5185\u90e8\u7f3a\u9677\uff0c\u4ece\u800c\u663e\u8457\u964d\u4f4e\u7f3a\u9677\u5bc6\u5ea6\u3002\u56e0\u6b64\uff0c\u57fa\u4e8e MA \u548c CsFAMA \u5668\u4ef6\u7684 p-i-n \u578b\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684 JSC<\/sub>\u3001VOC<\/sub>\u00a0\u548c FF \u90fd\u5f97\u5230\u4e86\u6709\u6548\u6539\u5584\u3002<\/p>\n \u5728 DFT \u8ba1\u7b97\u7684\u5e2e\u52a9\u4e0b\uff0c\u8fd9\u9879\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u65b9\u6cd5\uff0c\u901a\u8fc7\u5236\u5907\u5b9a\u5236\u529f\u80fd\u5316\u7eb3\u7c73\u7c92\u5b50\uff0c\u5b9e\u73b0\u66f4\u6709\u6548\u7684\u949d\u5316\u548c\u66f4\u9ad8\u8d28\u91cf\u7684\u9499\u949b\u77ff\u8584\u819c\u3002\u5b83\u8bc1\u5b9e\u4e86\u901a\u8fc7\u8bbe\u8ba1\u6b63\u786e\u7684\u6dfb\u52a0\u5242\u6765\u5e2e\u52a9\u5668\u4ef6\u5236\u9020\uff0c\u53ef\u4ee5\u5728 P-I-N \u7ed3\u6784\u5668\u4ef6\u4e2d\u5b9e\u73b0\u7a33\u5b9a\u7684\u5149\u4f0f\u6027\u80fd\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a\u201c<\/i><\/em><\/strong>Oxyl-terminated Melem Nanoparticles as Crystallization Modulators and Passivating Anchors for High-Performance Perovskite Solar Cells<\/i><\/em><\/strong>\u201d\uff08Nano<\/i><\/em><\/strong>\u00a0<\/i><\/em><\/strong>Energy\uff0c<\/i><\/em><\/strong>https:\/\/doi.org\/10.1016\/j.nanoen.2023.109220<\/i><\/em><\/strong>\uff09<\/i><\/em><\/strong><\/p>\n \u672c\u6587\u7531W\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":" \u4e00\u3001\u00a0\u3010\u5bfc\u8bfb\u3011 \u00a0 \u5c3d\u7ba1\u901a\u8fc7\u4e0d\u540c\u7684\u7b56\u7565\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u4f0f\u6027\u80fd\u5f97\u5230\u4e86\u6781\u5927\u7684\u6539\u5584\uff0c\u4f46\u4e0e\u4f20\u7edf\u7ed3\u6784\u76f8\u6bd4\uff0c\u5728\u4e00\u81f4\u6027\u548c\u6548\u7387\u65b9\u9762\u4ecd\u6709\u5f88\u5927\u5dee\u8ddd\u3002\u76ee\u524d\u88ab\u5e7f\u6cdb\u63a5\u53d7\u7684\u949d\u5316\uff0c\u9499\u949b…<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-256679","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/256679"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=256679"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/256679\/revisions"}],"predecessor-version":[{"id":256688,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/256679\/revisions\/256688"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=256679"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=256679"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=256679"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
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